regiodivergent synthesis of trisubstituted furans through tf o- … · 2011. 11. 3. · daniela...
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Regiodivergent synthesis of trisubstituted furans through Tf2O-
catalyzed Friedel-Crafts acylation: a tool for access to
tetrahydrofuran lignan analogues
Daniela Comegna,* Marina DellaGreca,* M. Rosaria Iesce, Lucio Previtera, Armando Zarrelli, and Simona Zuppolini
Dipartimento di Chimica Organica e Biochimica, Università Federico II, Complesso Universitario di Monte
S. Angelo, via Cinthia 4, I-80126 Naples, Italy. Fax: +39 081 6741393; Tel: +39 081 674162; E-mail:
[email protected]; [email protected].
SUPPORTING INFORMATION
Table of contents
1D NMR Spectra:
1H and
13C NMR of compounds 3a-e, 4a-e, 5,7-9……………..……….pg. S2-S15
2D NMR Spectra:
HMQC of compound 3a…………………………………………………. pg. S16
HMBC of compound 3a………………………………………………… pg. S16
HSQC of compound 4a..…………………………………………………. pg. S17
HMBC of compound 4a..………………………………………………….pg. S17
HMBC of compound 5…………………………………………………….pg. S18
COSY of compound 9…………………………………………………… pg. S18
HMBC of compound 9………………………………………………….. pg. S19
NOESY of compound 9…………………………………………………. pg. S19
Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011
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Electronic Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is © The Royal Society of Chemistry 2011