relationships between iops and biogeochemical …

1
Since 2003, the BOUSSOLE mooring is deployed in Case 1 waters of the NW Mediterranean Sea (Fig. 1). It is acquiring a long-term time series of in-situ bio-optical measurements. A program of monthly cruises provides complementary measurements including underwater radiometry profiles and discrete rosette sampling for biogeochemical parameters. Here we show the relationships between both the Particulate Organic Carbon (POC) and the Suspended Particulate Matter (SPM) and the inherent optical properties (IOPs) measured at the BOUSSOLE site (beam attenuation coefficient, c p , and backscattering coefficient, b bp ). Biogeochemical parameters: o [TChl-a] (0-400 m) from Nov. 2005 to Dec. 2015. o [SPM] (0-5 m) from Nov. 2005 to Dec 2015. o [POC] (0-400 m) from Oct. 2011 to Dec 2013. Fig.1 : Map of the NW Mediterranean Sea showing the location of the BOUSSOLE site (left). R/V Tethys II and CTD Rosette + IOPs package deployment at the BOUSSOLE site (right). IOPs : o Wetlabs C-Star Transmissometer: beam attenuation coefficient c p (660) profile (0-400m). o Hobilabs Hydroscat-VI : backscattering coefficient b b at 420, 442, 488, 550, 620, 700 nm profiles (0-400 m). Melek Golbol 1* , Vincenzo Vellucci 1 , David Antoine 2 , Bernard Gentili 1 , Annick Bricaud 1 and Emilie Diamond 1 1 Sorbonne Universités, UPMC Univ. Paris 06, INSU-CNRS, Laboratoire d'Océanographie de Villefranche, 06230 Villefranche-sur-mer, France 2 Remote Sensing and Satellite Research Group, Department of Physics & Astronomy, Curtin University, Perth, WA 6845, Australia RELATIONSHIPS BETWEEN IOPS AND BIOGEOCHEMICAL PARAMETERS IN THE NW MEDITERRANEAN SEA *[email protected] RESULTS DATA ACQUISITION Fig.2 : a) [TChl-a] from in situ measurements and from MERIS observations (OC4Me algorithms). b) Ratio [TChl-a]/[SPM] and [TChl-a]/[POC] from in situ surface measurements, and ratio [TChl-a]/[SPM] from MERIS observations (OC4Me and NN algorithms for [TChl-a] and [SPM] respectively). Fig.4 : Regressions between [SPM] and c p (660), b bp (550) and b bp (700) . y = 0.7525x + 0.0503 R² = 0.6096 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 [SPM] (g.m -3 ) c p (660) (m -1 ) y = 109.16x + 0.066 R² = 0.3921 0 0.1 0.2 0.3 0.4 0.5 0.6 0.E+00 1.E-03 2.E-03 3.E-03 4.E-03 [SPM] (g.m -3 ) b bp (550) (m -1 ) o Bio-optical relationships between both [POC] and [SPM] and IOPs (c p , b bp ) have been established with in situ measurements in the Mediterranean Sea (BOUSSOLE site). o The ratio between absorption coefficients (a p and a cdom ) and c p (660) will be examined and compared with the ratio [TChl-a] / [POC] and [TChl-a] / [TSM] measured at the BOUSSOLE site. o These parameters will be compared with in situ AOPs measurements (reflectance) at BOUSSOLE site in order to assess current remote-sensing algorithms. Fig. 3 : Regressions between [POC] and c p (660), b bp (550) b bp (442) and b bp (700). The relations [POC] vs c p (660) and [POC] vs b bp (550) were compared to other published relations. o Significant correlation between [POC] and c p (660) and [POC] vs b bp . o Conversion factor: carbon-specific attenuation coefficient c c *(660)= 3.07 m 2 g C -1 consistent with estimations from various oceanic areas (2 - 3.2 m 2 g C -1 ). o Correlation between [POC] and b bp : determination coefficient (R 2 ) similar for all the wavelenghts. BIO-OPTICAL RELATIONSHIPS o Seasonal cycle for [TChla-a] / [SPM] and [TChla-a] / [POC] at surface. o Decreasing trend of [TChl-a] / [SPM]. o Maximum in winter Photoacclimation? CONCLUSIONS & PERSPECTIVES AKNOWLEDGEMENTS o Significant correlation between [SPM] and c p (660). o More dispersion between [SPM] and b bp. c p (660) vs [SPM] b bp vs [SPM] log 10 c p = 0.65 log 10 [SPM]-0.26 (r= 0.7476) log 10 b bp = 0.55 log 10 [SPM]-2.62 (r= 0.639) log 10 c p = 0.81 log 10 [SPM]-0.14 (r= 0.967) log 10 b bp = 1.03 log 10 [SPM]-2.06 (r= 0.974) Tab. 1 : Regressions between c p (660) and [SPM], and between b bp (650) and [SPM] at BOUSSOLE* (red) and from Neukermans et al., 2012 (Case 1+Case 2 waters) (black). *For BOUSSOLE, b bp (650) was estimated by interpolation between b bp (620) and b bp (700). y = 122.23x + 0.0606 R² = 0.3438 0 0.1 0.2 0.3 0.4 0.5 0.6 0.E+00 1.E-03 2.E-03 3.E-03 4.E-03 [SPM] (g.m -3 ) b bp (700) (m -1 ) (BOUSSOLE SITE) o Antoine D. et al., 2006. NASA/TM N°2006- 214147, NASA/GSFC, Greenbelt, MD, 61pp. o Claustre H. et al., 1999. Journal of Geophysical Research-Oceans, 104, 3401-3422. o Gardner W. D. et al., 2006. Deep-Sea Research Part II -Topical Studies in Oceanography, 53, 718-740. o Loisel H. et al., 2001. Geophysical Research Letters, 28, 4203-4206. o Loisel H. et al., 2011. Biogeosciences, 8, 3295-3317. o Neukermans G. et al., 2012. Limnology and Oceanography, 57, 124-144. o Stramski D. et al., 2008. Biogeosciences, 5, 171-201. REFERENCES Visit stands # 15, # 103 & # 183 for other posters on BOUSSOLE. y = 325.82x + 4.7283 R² = 0.7925 0 50 100 150 200 250 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 [POC] (mg.m -3 ) c p (660) (m-1) Boussole Claustre et al., 1999 Stramski et al., 2008 Gardner et al., 2006 Loisel et al., 2011 y = 43886x + 3.5829 R² = 0.6272 0 50 100 150 200 250 0.E+00 1.E-03 2.E-03 3.E-03 4.E-03 5.E-03 [POC] (mg.m -3 ) b bp (550) (m -1 ) Boussole Loisel et al, 2001 y = 46943x + 3.8882 R² = 0.6347 0 50 100 150 200 250 0.E+00 1.E-03 2.E-03 3.E-03 4.E-03 5.E-03 [POC] (mg.m -3 ) b bp (700) (m -1 ) y = 39619x - 7.6691 R² = 0.6723 0 50 100 150 200 250 0.E+00 1.E-03 2.E-03 3.E-03 4.E-03 5.E-03 [POC] (mg.m -3 ) b bp (442) (m -1 ) POC SPM a b

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Page 1: RELATIONSHIPS BETWEEN IOPS AND BIOGEOCHEMICAL …

Since 2003, the BOUSSOLE mooring is deployed in Case 1 waters of the NW Mediterranean Sea (Fig. 1). It is acquiring a long-term time series of in-situ bio-optical

measurements. A program of monthly cruises provides complementary measurements including underwater radiometry profiles and discrete rosette sampling for

biogeochemical parameters. Here we show the relationships between both the Particulate Organic Carbon (POC) and the Suspended Particulate Matter (SPM) and the

inherent optical properties (IOPs) measured at the BOUSSOLE site (beam attenuation coefficient, cp, and backscattering coefficient, bbp).

Biogeochemical parameters:

o [TChl-a] (0-400 m) from Nov. 2005 to Dec. 2015.

o [SPM] (0-5 m) from Nov. 2005 to Dec 2015.

o [POC] (0-400 m) from Oct. 2011 to Dec 2013.

Fig.1 : Map of the NW Mediterranean Sea showing

the location of the BOUSSOLE site (left). R/V Tethys

II and CTD Rosette + IOPs package deployment at

the BOUSSOLE site (right).

IOPs:

o Wetlabs C-Star Transmissometer: beam attenuation

coefficient cp (660) profile (0-400m).

o Hobilabs Hydroscat-VI : backscattering coefficient bb at

420, 442, 488, 550, 620, 700 nm profiles (0-400 m).

Melek Golbol1*, Vincenzo Vellucci1, David Antoine2, Bernard Gentili1, Annick Bricaud1 and Emilie Diamond1

1 Sorbonne Universités, UPMC Univ. Paris 06, INSU-CNRS, Laboratoire d'Océanographie de Villefranche, 06230 Villefranche-sur-mer, France2 Remote Sensing and Satellite Research Group, Department of Physics & Astronomy, Curtin University, Perth, WA 6845, Australia

RELATIONSHIPS BETWEEN IOPS AND BIOGEOCHEMICAL PARAMETERS IN THE NW MEDITERRANEAN SEA

*[email protected]

RESULTSDATA ACQUISITION

Fig.2 : a) [TChl-a] from in situ

measurements and from MERIS

observations (OC4Me

algorithms).

b) Ratio [TChl-a]/[SPM] and

[TChl-a]/[POC] from in situ

surface measurements, and ratio

[TChl-a]/[SPM] from MERIS

observations (OC4Me and NN

algorithms for [TChl-a] and [SPM]

respectively).

Fig.4 : Regressions between [SPM] and cp(660), bbp(550) and bbp(700) .

y = 0.7525x + 0.0503R² = 0.6096

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

[SP

M]

(g.m

-3)

cp(660) (m-1)

y = 109.16x + 0.066R² = 0.3921

0

0.1

0.2

0.3

0.4

0.5

0.6

0.E+00 1.E-03 2.E-03 3.E-03 4.E-03

[SP

M]

(g.m

-3)

bbp(550) (m-1)

o Bio-optical relationships between both [POC] and [SPM] and IOPs (cp, bbp) have been established with in situ measurements in the Mediterranean Sea (BOUSSOLE site).

o The ratio between absorption coefficients (ap and acdom) and cp(660) will be examined and compared with the ratio [TChl-a] / [POC] and [TChl-a] / [TSM] measured at the BOUSSOLE site.

o These parameters will be compared with in situ AOPs measurements (reflectance) at BOUSSOLE site in order to assess current remote-sensing algorithms.

Fig. 3 : Regressions between [POC] and cp(660), bbp(550) bbp(442) and bbp(700). The relations

[POC] vs cp(660) and [POC] vs bbp(550) were compared to other published relations.

o Significant correlation between [POC]

and cp(660) and [POC] vs bbp.

o Conversion factor: carbon-specific

attenuation coefficient

cc*(660)= 3.07 m2 g C-1

consistent with estimations from various

oceanic areas (2 - 3.2 m2 g C-1).

o Correlation between [POC] and bbp :

determination coefficient (R2) similar for

all the wavelenghts.

BIO-OPTICAL RELATIONSHIPS

o Seasonal cycle for [TChla-a] / [SPM] and [TChla-a] / [POC] at surface.

o Decreasing trend of [TChl-a] / [SPM].

o Maximum in winter Photoacclimation?

CONCLUSIONS & PERSPECTIVES

AKNOWLEDGEMENTS

o Significant correlation between

[SPM] and cp(660).

o More dispersion between [SPM]

and bbp.

cp(660) vs [SPM] bbp vs [SPM]

log10 cp = 0.65 log10 [SPM]-0.26

(r= 0.7476)

log10 bbp = 0.55 log10 [SPM]-2.62

(r= 0.639)

log10 cp = 0.81 log10 [SPM]-0.14

(r= 0.967)

log10 bbp = 1.03 log10 [SPM]-2.06

(r= 0.974)

Tab. 1 : Regressions between cp(660) and [SPM], and between bbp(650) and [SPM] at

BOUSSOLE* (red) and from Neukermans et al., 2012 (Case 1+Case 2 waters) (black).

*For BOUSSOLE, bbp(650) was estimated by interpolation between bbp(620) and bbp(700).

y = 122.23x + 0.0606R² = 0.3438

0

0.1

0.2

0.3

0.4

0.5

0.6

0.E+00 1.E-03 2.E-03 3.E-03 4.E-03

[SP

M]

(g.m

-3)

bbp(700) (m-1)

(BOUSSOLE SITE)

o Antoine D. et al., 2006. NASA/TM N°2006- 214147, NASA/GSFC, Greenbelt, MD, 61pp.

o Claustre H. et al., 1999. Journal of Geophysical Research-Oceans, 104, 3401-3422.

o Gardner W. D. et al., 2006. Deep-Sea Research Part II -Topical Studies in Oceanography, 53, 718-740.

o Loisel H. et al., 2001. Geophysical Research Letters, 28, 4203-4206.

o Loisel H. et al., 2011. Biogeosciences, 8, 3295-3317.

o Neukermans G. et al., 2012. Limnology and Oceanography, 57, 124-144.

o Stramski D. et al., 2008. Biogeosciences, 5, 171-201.

REFERENCES

Visit stands # 15, # 103 & # 183 for other posters on BOUSSOLE.

y = 325.82x + 4.7283R² = 0.7925

0

50

100

150

200

250

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

[PO

C]

(mg.

m-3

)

cp(660) (m-1)

Boussole

Claustre et al., 1999

Stramski et al., 2008

Gardner et al., 2006

Loisel et al., 2011

y = 43886x + 3.5829R² = 0.6272

0

50

100

150

200

250

0.E+00 1.E-03 2.E-03 3.E-03 4.E-03 5.E-03

[PO

C]

(mg.

m-3

)

bbp(550) (m-1)

Boussole

Loisel et al, 2001

y = 46943x + 3.8882R² = 0.6347

0

50

100

150

200

250

0.E+00 1.E-03 2.E-03 3.E-03 4.E-03 5.E-03

[PO

C]

(mg.

m-3

)

bbp(700) (m-1)

y = 39619x - 7.6691R² = 0.6723

0

50

100

150

200

250

0.E+00 1.E-03 2.E-03 3.E-03 4.E-03 5.E-03

[PO

C]

(mg.

m-3

)

bbp(442) (m-1)

POC SPM

a

b