report: analytical data report, prepared for mr. joe

GOMPUCHEMLABORATORIES

301009

GOMPUCHEMlABORATORIES

March 1, 1988

Mr. Joe FromalEnvironmental Strategy CorporationSuite 6508521 Leesburg PikeVienna, VA 22180

Dear Mr. Fromal:

We at CompuChem* are pleased to provide our report for the analysis you requested.Data for the following sample are enclosed:

Your ID Our ID Analysis Order Description of WorkNumber Number Code Number Requested

041 13309 Volatiles + Library SearchMethod 624 - Tier I

TELEDNPR-5TELEDNPR-6TELEDNPR-7TELEDNPR-8

170199170200170201170202

In this report we have included the analytical results, the method reference, andthe quality control summary. If any anomalies were encountered in this analysis,they would be referenced in an attached Quality Assurance Notice(s). Instrumentdocumentation is provided with reports purchased in our Gold Report format.

To obtain additional technical information concerning this report, please contactyour Sales Representative. In addition to resolving your questions, they canprovide you with a complete overview of our line of services and assist you inidentifying those services which w i l l effectively and efficiently support yourmonitoring program.

For your convenience, your Customer Service Representative can help you place anew order, obtain information about a sample's status or obtain assistance withsample logistics. Your Sales Representative and your Customer Service Represen-tative can be reached at 1/919-549-8263.

301010COMPUCHEM LABORATORIES, INC. P.O. Box 12652 3308 Chapel Hill/Nelson Highway Research Triangle Park, NC 27709 (919)549-8263

GOMPUCHEM

Thank you for choosing CompuChem*. We would like to continue providing youanalytical support and services. We would appreciate your comments regardingthe quality of services you have received from CompuChem*; client satisfactionis important to us. Please address your comments to your Sales or CustomerService Representative at the address given below.

Sincerely,

Mary/t. MitchellSupervisor, Report Deliverables

cc: Accounting(Cover letter only)

Page Two - March 1, 1988


301011

COMPUCHEMLABORATORIES

ANALYTICAL DATA REPORT


Deli vocable's nator

301012


- TABLE OF CONTENTS -

Chain of Custody*

Laboratory Chronicle

Method Reference and Summary

Quality Control Summary

Quality Assurance Notices**

Sample Data Package

• Volatile Compound List & Detection Limits. List of Tentatively Identified Compounds. Surrogate Recovery Data. Sample Chromatograms (TIC) (If Applicable). Quantitative Report

Quality Control Data Package

. Blank Summary & Detection LimitsSurrogate Recovery Data

. Blank Chromatogram. Matrix Spike Comparison. Calibration Check

Tuning Performance Summary

*When the original chain of custody is submitted with the sample(s), a copyof it is included with the report.

**These notices are included where appropriate for data qualification.

301013


LABORATORY CHRONICLE

ITEMNO.

1.2.3.4.

SAMPLEIDENTIFIER

TELEDNPR-5TELEDNPR-6TELEDNPR-7TELEDNPR-8

COMPUCHEM*NUMBER

170199170200170201170202

DATESAMPLERECEIVED

12/05/8712/05/8712/05/8712/05/87

DATEVOLATILEFRACTIONANALYZED

12/09/8712/09/8712/09/8712/09/87

(Instrument Blank) VB871209A03 12/09/87

301014

METHOD REFERENCE

CompuChem® employs the Modified Environmental Monitoring and SupportLaboratory-Cincinnati (EMSL-CI) Procedure to be Used for Low Levels of Volatilesin Soils and Sediments for the preparation of solid samples and instrumentoperating parameters for volatile library search. This procedure is a modifica-tion of the published USEPA Method 624, Volume 49 of the October 26, 1984 FederalRegister.

Method Summary

A 5 gram sample is weighed and transferred with 10 mis of water to a speciallydesigned impinger. The impinger is then heated to 55°C and this temperature ismaintained while purging for 12 minutes. "After purging is completed, the sor-bent column is heated and backflushed with the inert gas to desorb thepurgeables onto a gas chromatographic column...which are then detected with amass spectrometer."

Semi-quantitative analysis (library search) is performed by automatic comparisonof the unknown peak spectrum to the National Bureau of Standards (NBS) massspectral library. Estimated concentration is calculated using the known con-centration and peak area of the closest internal standard while assuming aresponse factor of one for the unknown compound.

30J015

Q U A L I T Y CONTROL SUMMARY

In a d d i t i o n to the control measures specified by Methods 624and o u t l i n e d in the method summary of t h i s report, t h i s v o l a t i l ea n a l y s i s e n t a i l s the introduction of client/case s p e c i f i e dq u a l i t y control samples. These QC samples are a u t o m a t i c a l l yintroduced by CompuChem's laboratory management systems at arate of at least one set for every twenty samples b e a r i n g thesame case ID received in a thirty day time period. The exactrate of QC sample i n t r o d u c t i o n is c o n t r o l l e d by the c l i e n tt h r o u g h the a s s i g n m e n t of case i d e n t i f i e r s . The QC samples,c o n s i s t i n g of d u p l i c a t e sample spikes and a s i n g l e b l a n k s p i k e ,are i n t r o d u c e d w i t h the first sample in each series of twentyfor each i d e n t i f i e d case.

The sample spikes processed for the samples associated w i t ht h i s report were prepared u s i n g an o r i g i n a l sample selectedfrom the sample c l i e n t defined case. The a n a l y t i c a l datao b t a i n e d for the o r i g i n a l sample, both s a m p l e s p i k e s , the s p i k ec o n c e n t r a t i o n , percent recoveries, the s p i k s s and r e l a t i v epercent difference have been i n c l u d e d in t h i s report in the formof the S p i k e Summary Table. The control l i m i t s for i n d i v i d u a lcompound recoveries and r e l a t i v e percent differences are i n c l u d e din the summary table. Sample m a t r i x can a d v e r s e l y affect therecovery and precision data. Whenever a m a t r i x problem isencountered w h i c h adversely affects the sample s p i k e s , ther e s u l t s o b t a i n e d for the b l a n k s p i k e are i n c l u d e d in the reportw i t h a Q u a l i t y Assurance Notice.

30101?

QUALITY ASSURANCE NOTICE

SAMPLE IDENTIFIER: TELEDNPR-5, TELEDNPR-6, TELEDNPR-7, TELEDNPR-8COMPUCHEM* SAMPLE NUMBER: 170199, 170200, 170201, 170202

Blank 1.0. VB871209A03

Following the conventions established by the EPA for qualifying common labora-tory artifacts in samples analyzed under the Contract Laboratory Program (CLP)Caucus Organics Protocols, we have reported the following compound with the"B" footnote:

blankcommon laboratory artifact concentration units

Methylene Chloride ___23____ ug/kg

The "B" indicates that this analyte was also detected in the associated MethodBlank (and/or Instrument Blank). This footnote is only used for the commonlaboratory solvent, methylene chloride.

When both an Instrument Blank and a Method Blank are prepared, the "B" foot-note is applied to associated sample data if a common artifact is detected ineither blank. Compositing Blanks are prepared with samples that require com-positing of all as-received sample containers. Since the entire sample isconsumed in the process, repreparation and reanalysis of a composited sampleis not possible. Therefore, exceptions are made to allowable levels of blankcontamination in such instances.

The EPA-CLP protocols permit up to 25 ug/1 of methylene chloride in volatileblanks. Our policy is much more stringent for non-CLP requirements. Themaximum allowable level for methylene chloride in Instrument Blanks is 5 ug/1(2 ug/1 for blanks associated with Lower Detection Limit sample) unless suc-cessive blanks indicate a consistent background level of methylene chloride.The concentration of methylene chloride in solid Method Blanks may not exceed25 ug/kg. Exceptions to these policies are made only when sample HoldingTimes are in jeopardy of being exceeded.

Data Interpretation: General EPA Guidelines

In evaluating data usability, the EPA uses certain general guidelines forassessing the presence of common laboratory artifacts in samples. If the con-centration of an artifact in a sample is greater than ten times that in theblank, the blank contribution is considered negligible. If blank and sampleconcentrations are comparable (sample level not greater than twice the blanklevel), the presence of that compound in the sample is considered suspect.

Robert J. WhiteheadManager, Quality Assurance

301017

N2 007941 CHAIN OF CUSTODY RECORDGOMPUCHEM LABORATORIES

MKU. NO. PROJECT NAME

IT A. MO. OATi J fTATION LOCATIONTAMWM

a*

SO:/?

ThM

UbWMory by: OM/ThM

COMPOUND LIST - VOLATILE ORGANICS

SAMPLE IDENTIFIER:COMPUCHEM* SAMPLE NUMBER:

IV. CHLOROMETHANE2V. BROMOMETHANE3V. VINYL CHLORIDE4V. CHLOROETHANE5V. METHYLENE CHLORIDE6V. ACROLEIN7V. ACRYLONITRILE8V. 1,1-DICHLOROETHENE9V. 1,1-DICHLOROETHANE

10V. 1,2-DICHLOROETHENE,(TOTAL)11V. CHLOROFORM12V. 1,2-DICHLOROETHANE13V. 1,1,1-TRICHLOROETHANE14V. CARBON TETRACHLORIDE15V. BROMODICHLOROMETHANE16V. 1,2-DICHLOROPROPANE17V. TRANS-1.3-DICHLOROPROPENE18V. TRICHLOROETHENE19V. DIBROMOCHLOROMETHANE20V. 1,1,2-TRICHLOROETHANE21V. BENZENE22V. CIS-1,3-DICHLOROPROPENE23V. 2-CHLOROETHYL VINYL ETHER24V. BROMOFORM25V. TETRACHLOROETHENE26V. 1,1,2,2-TETRACHLOROETHANE27V. TOLUENE28V. CHLOROBENZENE29V. ETHYLBENZENE

TELEDNPR-5170199

CONCENTRATION(ug/kg)

BDLBDLBDLBDL

39 B*BDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDL

28BDLBDL

DETECTIONLIMIT

(ug/kg)

1010101010

100100

10101010101010101010101010101010101010101010

Surrogate Recoveries - Introduced at the instrument, volatile surrogate standardsare deuterated and/or select compounds that analytically mimic the response ofcertain analytes. Known concentrations of these surrogates are added to thesample and a percent recovery is calculated. This recovery acts as a barometer ofmethod efficiency for the individual sample.

D4-l,2-Dichloroethane4-Bromof1uorobenzeneDg-Toluene

% Recovery

989499

Control RangeX

(70-121)(74-12D(81-117)

BDL= BELOW DETECTION LIMIT*See Quality Assurance Notice.

301019

TENTATIVELY IDENTIFIED COMPOUNDS

SAMPLE IDENTIFIER:COMPUCHEM NUMBER:

TELEDNPR-5170199

CASNumber

1.

2.

3.

4.

5.

Compound Name

NO VOLATILE COMPOUNDS FOUND

ScanNumber

EstimatedConcentration

(ug/kg)

301020

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Q'JANTITATIQN REPORT FILE: VP070199B03DATA VR070l9c?E03 TI12/09/87 IS.07 00SAMPLE 5. 02G CC*170199CHNDS :

M1TTED BY- 03 ANALYST: 1263

AMOUNT=AREA<HGHT> * REF AMNT/(REF.AREA(HGHT)* RESP.FACT)RESP. FAC. FROM AVERAGE OF WHOLE . RL

NO NAME1 *234 BROMOCHLOROMETHANE (IS)2 221 CHLOROMETHANE3 220 BPOMOMETHANE4 231 VINYL CHLORIDE5 209 CHLOROETHANE6 222 METHYLENE CHLORIDE7 201 ACROLE1N8 202 ACRYLONITRILE9 216 1.1-DICHLOROETHYLENE

10 214 1-1-DICHLOROETHANE11 226 TRANS-1,2-DICHLOROETHYLENE12 211 CHLOROFORM13 215 1 -2-DICHLOROETHANE14 *248 1.4 DIFLUOROBENZENE (IS>15 227 1.1, 1-TRICHLOROETHANE16 206 CARBON TETRACHLORIDE17 212 BROMODICHLOROMETHANE18 217 1, 2-DICHLOROPP.OPANE19 250 TRAN3-1,3-DICHLOROPROPENE°0 229 TRICHLOROETHYLENE

203 CHLORODIBROMOMETHANE•22 228 1,1,2-TR1CHLOROETHANE23 203 BENZENE24 218 CIS-1,3-DICHLOROPROPENE25 210 2-CHLOROETHYL VINYL ETHER26 205 BROMOFORM27 *270 D5-CHLQROBENZENE (IS)28 224 TETRACHLOROETHENE29 223 1,1,2,2-TETRACHLOROETHANE30 225 TOLUENE31 207 CHLQROBENZENE32 219 ETHYLBENZENE33 *258 D4-1,2-DICHLOROETHANE34 *247 BRQMOFLUOROBENZENE35 #233 D8-TOLUENE

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT */.TOT

301022

NO1c.

•- — -»56789

10111213141516171819202122232425262728

7

_ J3132333435

NO123456789

10111213141516179

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M/E SCAN TIME REF RRT METH129 279 9 32 1 1 OOO A BB50 NOT FOUND94 NOT FOUND62 NOT FOUND64 NOT FOUND84 181 611 1 0 649 A BB56 NOT FOUND53 NOT FOUND96 NOT FOUND63 NOT FOUND96 NOT FOUND83 344 11:45 1 1.233 A BB62 NOT FOUND

114 590 20:09 14 1 OOO A BB97 NOT FOUND

117 NOT FOUND83 NOT FOUND63 NOT FOUND75 NOT FOUND

130 NOT FOUND129 NOT FOUND97 NOT FOUND78 NOT FOUND75 NOT FOUND63 NOT FOUND

173 NOT FOUND117 742 25:21 27 1.000 A BB164 669 22: 51 27 O 902 A BB83 NOT FOUND92 708 24 11 27 0.954 A BB

112 NOT FOUND106 NOT FOUND65 362 12:22 1 1 297 A BB95 920 31:26 27 1.240 A BB98 702 23 59 27 0. 946 A BB

RET(L) RATIO RRT(L) RATIO AMNT9: 32 1 OO 1O OOO O. 1O 3O. OO1: 28 10 OOO2: 21 10 0002 56 1O 0003: 56 10 0006:05 1.02 10. OOO 0. O6 39.046: 38 100 OOO7: 23 10O. OOO8: 57 10. OOO

10: 21 1O. OOO11 04 10 OOO11 43 l.OO 10. OOO 0.12 3.9412: 28 1O. OOO20 12 l.OO 10.000 0.10 3O. 0013: 48 1O. OOO14: 13 10. 00014 48 10. OOO16: 12 10 OOO17: 48 10 OOO

AREAtHGHT)40921.

51317

12914.

23O888.

-

2O0330.2865

94352.

73910.167893211788

AMNT(L) R.30. OO 1.

160 00160 0016O. OO160. 00160. OO 0.

16OO. OO1600. OO

160. 0016O OO160 00160 OO 0.16O. 0030.00 1.

160 OO160 OO160 0016O. OO16O. 00

AMOUNT30. 000

39 043

3. 941

30. 000

30. OOO0. 894

27. 852

29 32528. 26629. 831

UG/L

UG/L

UG/L

UG/L

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FAC R. FAC(L)OOO 1.

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0007322288605499640541349635390454O2541000471448450185195

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CGMPUCHEM LABSDUAL HASS SPECTRUM12 •'09/37 13:07:60-1- 6:11SAMPLE: 5.02G CC#17019'3ENHANCED (S 15B 2H>

DATA: UR070133B03 #181 BASE M/E: 43/ 49RIC: 41855./ 43135.

THYLEHE CHLORIDE- 11216.

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COMPUCHEM LABiLIBRARY SEARCH12-'09 '37 13:07:00 + 6:11SAMPLE: 5.02G CC*170199ENHANCED (S 156 2N 8T>

DATA: UR070199B03 * 181 BASE M/E: 49RIC: 41855.

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50 60 76 80 90 109 110 120


SAMPLE IDENTIFIER: TELEDNPR-6COMPUCHEM* SAMPLE NUMBER: 170200

DETECTIONCONCENTRATION LIMIT

(iig/kg) (ug/kg)

IV. CHLOROMETHANE BDL 102V. BROMOMETHANE BDL 103V. VINYL CHLORIDE BDL 104V. CHLOROETHANE BDL 105V. METHYLENE CHLORIDE 30 B* 106V. ACROLEIN BDL 1007V. ACRYLONITRILE BDL 1008V. 1,1-DICHLOROETHENE BDL 109V. 1,1-DICHLOROETHANE BDL 10

10V. 1,2-DICHLOROETHENE,(TOTAL) BDL 1011V. CHLOROFORM BDL 1012V. 1,2-DICHLOROETHANE BDL 1013V. 1,1,1-TRICHLOROETHANE BDL 1014V. CARBON TETRACHLORIDE BDL 1015V. BROMODICHLOROMETHANE BDL 1016V. 1,2-DICHLOROPROPANE BDL 1017V. TRANS-1,3-DICHLOROPROPENE BDL 1018V. TRICHLOROETHENE BDL 1019V. DIBROMOCHLOROMETHANE BDL 1020V. 1,1,2-TRICHLOROETHANE BDL 1021V. BENZENE BDL 1022V. CIS-1,3-DICHLOROPROPENE BDL 1023V. 2-CHLOROETHYL VINYL ETHER BDL 1024V. BROMOFORM BDL 1025V. TETRACHLOROETHENE BDL 1026V. 1,1,2,2-TETRACHLOROETHANE BDL 1027V. TOLUENE BDL 1028V. CHLOROBENZENE BDL 1029V. ETHYLBENZENE BDL 10


% Recovery Control Range%

D4-l,2-Dichloroethane 104 (70-121)4-Bromofluorobenzene 9 1 ( 7 4 - 1 2 1 )D8-Toluene 100 (81-117)


301029



TELEDNPR-6170200

CASNumber

1.

2.

3.

4.

5.

Compound Name


ScanNumber


(ug/kg)

301030

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QUANT I TAT ION REPORT FILE VHC70200A03DATA VHC70'2:>OA03. T!12/09/8T 11 41 : 00SAMPLE 10Mi_ CC*170200r '"NDS

MITTED EY 03 ANALYST 819

AMOUNT=AREA(HGHT) * REF AMNT/<REF. AREA(HGHT)* RESP.FACT)RESF FAC FROM AVERAGE OF WHOLE RL

NO NAME1 *234 BROMOCHLOROMETHANE (IS)2 221 CHLOROMETHANE3 220 BROMOMETHANE4 231 VINYL CHLORIDE5 209 CHLOROETHANE6 222 METHYLENE CHLORIDE7 201 ACROLE1N8 202 ACRYLONITRILE9 216 1, 1-DICHLOROETHYLENE

10 214 1, 1-DICHLOROETHANE11 226 TRANS-1,2-DICHLOROETHYLENE12 231 CHLOROFORM13 215 1, 2-DICHLOROETHANE14 *24S 1,4 DIFLUOROBEN2ENE (IS)15 227 1 , 1 , 1-TRICHLQROETHANE16 20fc CAR3QN TETRACHLORIDE17 212 BROMODICHLOROMETHANE18 217 1, 2-DICHLQROPROPANE19 250 TRANS-1,3-D1CHLOROPROPENE"0 229 TRICHLOROETHYLENE

208 CHLORODIBROMOMETHANE"•25 223 1- 1, 2-TRKHLOROETHANE23 203 BENZENE24 21S CIS-1,3-DICHLOROPROPENE25 210 2-CHLOROETHYL VINYL ETHER26 205 BROMOFQRM27 *270 D5-CHLORODENZENE (IS)28 224 TETPACHLOROETHENE29 223 1,1,2,2-TETRACHLOROETHANE30 225 TOLUENE31 207 CHLOROBENZENE32 219 ETHYLBENZENE33 #258 D4-1,2-DICHLOROETHANE34 #247 BROMOFLUOROBENZENE35 #233 D8-TOLUENE

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT 7.TOT

301032.

NO1f-\C.

3•

_~>6789

101 112131415161718192O212223242526272829

>*_•!32333435

NO123456789

101112131415161718

•)

M/E SCAN TIME REF RRT METH128 230 9 34 11 000 A BD

50 NOT FOUND94 NOT FOUND62 NOT FOUND64 NOT FOUND84 182 6. 13 1 0 650 A BB56 NOT FOUND53 NOT FOUND96 NOT FOUND63 NOT FOUND96 NOT FOUND83 344 11:45 1 1.229 A BB62 NOT FOUND

114 59O 20: O9 14 1 . OOO A BB97 NOT FOUND


130 NOT FOUND129 NOT FOUND97 NOT FOUND78 NOT FOUND75 NCT FOUND63 NOT FOUND

173 NOT FOUND117 743 25:23 27 1 OOO A BV164 NOT FOUND83 NOT FOUND92 709 24 13 27 0 954 A BB

112 NOT FOUND106 NOT FOUND65 362 12 22 11 293 A BB95 920 31:26 27 1.238 A BB93 703 24 01 27 O. 946 A BB

RET(L) RATIO RRT(L) RATIO AMNT9 32 1 OO 10 OOO 0 10 3O. OO1 28 1O OOO2: 21 10 0002 56 10 0003: 56 1O. OOO6 05 1.02 10. OOO 0. O6 29.816: 38 10O OOO7: 23 100. OOO8: 57 10. 000

10: 21 10. OOO11: 04 10. 00011:43 1.00 1O. OOO O. 12 1.5512: 28 1O. OOO20:12 1.00 10.000 O. 10 30. OO13: 48 1O. OOO14: 13 10. OOO14:48 10 00016 12 10. OOO17 48 1O. OOO

AREA(HC455^4.

43650.

5643

229711

197888

7198

87980.160626.210077

AMNT < L )30 OO

160. OO160. OO16O 00160 0016O. OO

160O. OO1600. OO

16O. OO160. OO16O. 0016O. OO16O OO30. oo

160. OO16O. 00160 OO160. OO160 OO

AMOUNT 7.TOT30. 000 UG/L 14. 14

29 806 UG/L 14 05

1. 546 UG/L 0 73

30. OOO UG/L 14 14

3O. 000 UG/L 14 14

2. 151 UG/L 1 01

31 33O UG/L 14 7727. 376 UG/L 12 9029. 955 UG/L 14. 12

R FAC R1. 000

O. 180

0 O23

1 OOO

FAC'L)1.O.1.0.0.0OOO1.1.2.11.O.O.0.OO.

000732228B6O549964054134963539O454O2541OOO471448450185195

RATIO1 00

0 19

0. 01

1. 00

301039

NG R E T - , L > R2021

272829303132333435

RATIO RRT(L) RATIO AMNT17 01 10 000IT-44 1O 00017 50 10 00017 32 10 OOO16 28 10 OOO18 54 10.00020:34 10. OOO25 27 1 OO 10 000 0 1O 30 0022 56 10. 00022 53 10 00024 18 1 00 10.000 0.10 2.1525 35 10. 00028 07 10. OOO12:22 1.00 10000 0 1331:36 O 99 10 000 0.1224:05 1.00 10.000 0.09

31.3327.3829 96

AMNT (16016016016O160160160.30

160160160.16016030.30.30.

L)0000OOOO0000000000000000000000OO

R. FAC R FAC'L)000O0.0.0.

1 OOO 1 .00

0 O07 0O0

1. 930 1.0. 812 01 . 062 1 .

342333202525392118367000427428507781395848890063

RATIO

1. 00

0 01

1. 040 911. OO

301034-

98.1-1

49.1H

106.0-1

50.0H

M/E

COMPUCHEM LABSDUAL MASS SPECTRUM12/69/87 11:41:00 + 6:13SAMPLE: 10ML CC#170200 —vENHANCED (S 15B 2N> C 222>ETHYLEHE CHLORIDE

DATA: UH070200A03 #182 BASE M/E: 49/ 49RIC: 36543./ 37695.

T60 70

I80

9963.

inCOCD

CO

- 10160.

1266SAMPLE

C.H2.CL2P

M WTB PK 43R«NK 1IN 373PUR 34o

C2.H2.02.CL2H Iff'ISB PK 48PrtHK 2IN 3135PUR 488

COMPUCHEM LHBSLIBRARY SEnRCH12/09/87 11:41:00 + 6:13SAMPLE: ItfML CC*178200EHHAHCED (S 15B 2N 6T>

DATA: UH070200A03 # 182 BASE M/E: 43RIC: 36543.

iC15.H1/.H.S

..M WT 243B FK 84RrtNK 3IH 17416PUR 473 ]

M-E

CC

METHANE,01CHLORO- CAS* 75-09-2

ACETICACID>DICHLORO- CHS*

l lPYRIDIHE,3-(TERT-BUTYLTH10 >-4-PHENYL- CHS» 18794-40-b

50 109 150 200




10V. 1,2-DICHLOROETHENE,(TOTAL)11V. CHLOROFORM12V. 1,2-DICHLOROETHANE13V. 1,1,1-TRICHLOROETHANE14V. CARBON TETRACHLORIDE15V. BROMODICHLOROMETHANE16V. 1,2-DICHLOROPROPANE17V. TRANS-1,3-DICHLOROPROPENE18V. TRICHLOROETHENE19V. DIBROMOCHLOROMETHANE20V. 1,1,2-TRICHLOROETHANE21V. BENZENE22V. CIS-1,3-DICHLOROPROPENE23V. 2-CHLOROETHYL VINYL ETHER24V. BROMOFORM25V. TETRACHLOROETHENE26V. 1,1,2,2-TETRACHLOROETHANE27V. TOLUENE28V. CHLOROBENZENE29V. ETHYLBENZENE

TELEDNPR-7170201


BDLBDLBDLBDL

26 B*BDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDL

DETECTIONLIMIT

(ug/kg)

1010101010

10010010101010101010101010101010101010101010101010


D4-l,2-Dichloroethane4-Bromof1uorobenzeneDs-Toluene

% Recovery

10695

101

Control Range%

(70-121)

(81-117)

BOL= BELOW DETECTION LIMIT*See Quality Assurance Notice.

301037



TELEDNPR-7170201

CASNumber

1.

2.

3.

4.

5.

Compound Name


ScanNumber


(ug/kg)

301038

en »

•:•en

o<s- co

*.

cn

to

•'?> !'s Cto - j

co

<S'

( I

10

-•»

-•25 to

U3 LD

UT CO CO

CO

o UT

— :

or

t j -

Z 3

•- i~

O ~

n O --J

3 f

or-

••

o o

.-o

••

-* »2

)13

1 o

o I m co

o 2 o m o r <S-

CO go o CE-

m i

CO 3010

39

QUANT I TAT ION REPORT FILE VHG70201A03DATA: VH070201A03 TI12/09/87 12: 33: 00SAMPLE: 10ML CCK170201CONDS :

MITTED BY: O3 ANALYST: 819

AMOUNT=AREA(HGHT) * REF. AMNT/(REF. AREACHGHT)* RESP FACT>RESP. FAC FROM AVERAGE OF WHOLE . RL

NO NAME1 *234 BROMOCHLOROMETHANE (IS)2 221 CHLOROMETHANE3 220 BROMOMETHANE4 231 VINYL CHLORIDE5 2O9 CHLOROETHANE6 222 METHYLENE CHLORIDE7 2O1 ACROLEIN8 202 ACRYLONITRILE9 216 1,1-DICHLOROETHYLENE

10 214 1,1-DICHLOROETHANE11 226 TRANS-1,2-DICHLOROETHYLENE12 211 CHLOROFORM13 215 1,2-DICHLOROETHANE14 *248 1,4 DIFLUOROBENZENE <IS)15 227 1,1,1-TRICHLOROETHANE16 206 CARBON TETRACHLORIDE17 212 BROMODICHLOROMETHANE18 217 1,2-DICHLOROPROPANE19 250 TRANS-1,3-DICHLOROPROPENE20 229 TRICHLOROETHYLENE

208 CHLORODIBROMOMETHANE-*? 228 1, 1, 2-TRI CHLOROETHANE23 203 BENZENE24 218 CIS-1, 3-DICHLOROPROFENE25 21O 2-CHLOROETHYL VINYL ETHER26 205 BROMOFORM27 *270 D5-CHLORQBENZENE (IS>28 224 TETRACHLOROETHENE29 223 1, 1,2,2-TETRACHLOROETHANE30 225 TOLUENE31 207 CHLOROBENZENE32 219 ETHYLBENZENE33 #258 D4-1,2-DICHLOROETHANE34 #247 BROMOFLUOROBENZENE35 #233 D8-TOLUENE

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT 7.TOT

30104<J

NO12>

• ^56789

10111213141516171819202122232425262728

•»_ 03132333435

NO123456789

10111213141516178

-i 9

M/E SCAN TIME REF RRT128 278 9: 30 1 1 OOO50 NOT FOUND94 NOT FOUND62 NOT FOUND64 NOT FOUND84 178 6: 05 1 0 64056 NOT FOUND53 NOT FOUND96 NOT FOUND63 NOT FOUND96 NOT FOUND83 342 11:41 1 1.23062 NOT FOUND

114 589 20:07 14 1 , OOO97 NOT FOUND



173 NOT FOUND117 741 25: 19 27 1. OOO164 NOT FOUND83 NOT FOUND92 NOT FOUND

112 NOT FOUND106 NOT FOUND65 361 12 20 1 1 29995 918 31: 22 27 1 23998 702 23: 59 27 O 947

RET(L) RATIO RRT(L) RATIO9: 32 1. OO 1O OOO O 1O1:28 10.0002: 21 1O OOO2 56 10. OOO3 56 10. 0006: 05 1. OO 1O. OOO 0. 066: 38 100. OOO7: 23 100. OOO8: 57 10. OOO

10: 21 10. OOO11:04 10. OOO11: 43 1. OO 1O. OOO 0. 1212 28 10. OOO20: 12 1. 00 10. 000 0. 1013: 48 1O. OOO14: 13 10. OOO14: 48 10. OOO16 12 1O. OOO17: 48 10 OOO

METHA BB

A BB

A BB

A BB

A BB

A BBA BBA BB

AMNT30. 00

26. 19

1 60

30. OO

AREA(HGHT) AMOUNT '/.TOT44232 30.000 UG/L 14 39

37204.

5664.

232035.

201320.

86478.171002.216508.

AMNT(L)3O. OO

160. 0016O. OO16O OO16O. 00160. OO

160O. OO160O. OO

l o 00160. OO160. 0016O 00160. 003O. OO

160. 0016O. OO160 OO16O OO16O. OO

26 187 UG/L 12

1. 599 UG/L 0. 77

30. 000 UG/L 14 39

30.000 UG/L 14 39

31 743 UG/L 15 2328. 647 UG/L 13 7430. 346 UG/L 14 55

R. FAC R. FAC(L) RATIO1 . OOO

O. 158

1 0000. 7321. 228O 860O 549O 9640 054O. 1340. 963

1. OO

0 16

0. 024

1 . 000

112.11.

5390454 O2341OOO

O. 471O. 4480. 450O. 185O. 195

0 01

1. 00

301041

RET(L> RATIO RRT(L) RATIO AMNT2021

d242526272829303132333435

1717:171716.18:20:252222:242528:12:31.24

01445032285434275658183507223605

101O10101010.1O

O. 99 1O10.10.10.10.10

1. 00 100. 99 10.1 00 10

000000000ooooooooo000000000oooooo000oooooo000ooo

0. 10

0. 130. 120. 09

30. 00

31. 7428. 6530. 35

AMNT(L)16O OO160 OO160 00160 OO160 00160 00160 OO30 00

160 00160 OO16O OO160. 0016O 0030 0030. OO30 00

FAC R. FAC(L>0. 342O 38800O

RATIO

1. OOO

1. 9550. 8491. 075

202525392

O. 118O 367

OOO427428

100.

O 781O. 3951 8480. 8901 063

1. 00

1. 060 951. 01

301042

98.3-1

49. H

iee. 0-1

58.0H

M/E

DUAL MASS SPECTRUM12/69/87 12:33:06 + 6:85SAMPLE: 10ML CC*170281EHHAHCED (S 15B 2N> 222

COHPUCHEH LABSDATA: UH070201A03 #178 BASE M/E: 49/ 49

RIC: 3811I./ 31183.

•THYLENE CHLORIDE3123.

CO

cCO

40 50 70I38

1277SHMPLE

C.H2.CL2

M UT "84B PK 49RHNK iIN 379PUR 948

C2.H2.02.CL2M in1 illB PK 48RHHK 2HI 31H5PUR 483

LIBRARY SEwRCH12-'09''87 12:33:00 + 6:05SAMPLE: 10ML CC#170201ENHANCED <S 15B 2N 0T>

COMPUCHEM LABiDATA: UH070201A03 * 178 BASE M/E: 49

RIC: 30111.

C15.H17.N.SM HI 24JB Ft. 84PHHK 3III 17416PUP 479

1

METHANE, D I CHLORO- CAS* 75-09-2

HCETICACID,DICHLORO- CAS* 73-43-b

P¥RIDUe>3-«'TERT-BUTYLTHIO>-4-PHEHVL- 1S734-40-6

M t 50 100 150 200





TELEDNPR-8170202


BDLBDLBDLBDL

30 B*BDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDL

DETECTIONLIMIT

(ug/kg)

1010101010

10010010101010101010101010101010101010101010101010


D4-l,2-Dichloroethane4-Bromof1uorobenzeneDo-Toluene

% Recovery

1059798

Control Range%

(70-121)(74-12D(81-117)


301045


SAMPLE IDENTIFIER: TELEDNPR-8COMPUCHEM NUMBER: 170202

CASNumber

1.

2.

3.

4.

5.

Compound Name


ScanNumber


(ug/kg)

301046

•3>O

-t

oo-I E

S£a:or-j<xUJc-

9a.o

r--

r" o

,-. (Si

rri ..

..

>T\ _J OT

o a

. o<_• \ z: z•— r-j cr oa: —

co (_•

*ren

ITiC-4

ffi*O1

01

T-

r--

<Ti-IT'

l£l-

C«4

CO

O*—i

a:

__

_J•T\r-_

J-i

CN

IT.'

COIT*

cc-oT'3•<»•

_ O

£iJ*~^ I

I

QUANT I TAT I ON REPORT FILE. YHC70202A03DATA VH070202A03 TI12/09/97 13; 07 00SAMPLE 10ML CC#170202

OS.BY: O3 ANALYST: 819

AMOUNT=AREAlHGHT> * REF AMNT/ (REF AREA (HGHT )* RESP FACT)RESP. FAC FROM AVERAGE OF WHOLE . RL

NO NAME1 *234 BROMOCHLOROMETHANE (IS)2 221 CHLOROMETHANE3 220 BROMOMETHANE4 231 VINYL CHLORIDE3 209 CHLOROETHANE6 222 METHYLENE CHLORIDE7 201 ACROLE1N8 202 ACRYLONITRILE9 216 1, 1-DICHLOROETHYLENE

10 214 1, 1-D I CHLOROETHANE11 226 TPANS-1, 2-D I CHLOROETH YLENE12 211 CHLOROFORM13 215 1, 2-D I CHLOROETHANE14 *248 1,4 DIFLUOROBENZENE (IS)15 227 1,1, 1-TRICHLOROETHANE16 206 CARBON TETRACHLQR IDE17 212 BROMODICHLOROMETHANE18 217 1, 2-DICHLOROPROPANE19 250 TRANS-1, 3-DICHLOROPROPENE

229 TRICHLOROETHYLENE^_* 208 CHLOROD I BROMOMETHANE22 228 1- 1, 2-TR I CHLOROETHANE23 203 BENZENE24 218 CIS-1, 3-D1CHLOROPROPENE25 210 2-CHLOROETHYL VINYL ETHER26 205 BROMOFORM27 *270 D5-CHLQROBENZENE (IS>28 224 TETRACHLOROETHENE29 223 1, 1, 2, 2-TETRACHLOROETHANE30 225 TOLUENE31 207 CHLQROBENZENE32 219 ETHYLBENZENE33 *258 D4-1, 2-DICHLOROETHANE34 *247 BROMOFLUOROBENZENE35 *233 D8-TOLUENE

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT */.TOT

301048

NO121

""'"s6789

101112131415161718192021222324252627289

"Si32333435

NO123456789

10111213141516179;

M/E SCAN TIME REF RRT METH128 278 9:30 1 1 000 A BB

50 NOT FOUND94 NOT FOUND62 NOT FOUND64 NOT FOUND84 178 6: 05 1 O 640 A BB56 NOT FOUND53 NOT FOUND96 NOT FOUND63 NOT FOUND96 NOT FOUND83 343 11 43 1 1. 234 A BB62 NOT FOUND

114 591 20:12 14 1 . OOO A BV97 NOT FOUND



173 NOT FOUND117 744 25:25 27 1 OOO A BB164 NOT FOUND83 NOT FOUND92 NOT FOUND

112 NOT FOUND106 NOT FOUND65 361 12: 20 11. 299 A BB95 921 31:28 27 1 238 A BB96 704 24:03 27 0.946 A BB

RET(L) RATIO RRT(L) RATIO AMNT9:32 1 OO 1O OOO 0 1O 3OOO1 : 28 10 OOO2: 21 1O. 0002: 56 10 0003 56 10 OOO6:05 1. OO 10 OOO 0.06 30 546: 38 10O. 0007: 23 10O. OOO8: 57 10. OOO

10: 21 10. OOO11:04 1O. 00011:43 1 00 1O 000 0.12 2.8212: 28 10. OOO20:12 1.00 10000 0.10 30.0013 48 10. OOO14 13 10 OOO14: 48 1O. 00016: 12 1O OOO17: 48 1O. OOO

AREA(HGHT)44075.

43238.

9947.

231040.

209296.

85541.18O61O.21905O

AMNT(L) R.3O OO 1.

16O. OO160 OO160. OO160. 0016O. OO 0.

1600 001600. OO

160. 0016O. OO160. 00160. OO 0.16O. OO

3O. OO 1 .160. 0016O. 00160. 0016O OO160. 00

AMOUNT30 OOO

30 542

2 318

30 OOO

30 000

31. 51129. 10429. 532

UG/L

UG/L

UG/L

UG/L

UG/L

UG/LUG/LUG/L

FAC R. FAC(L)000 1.

O.1.O.O.

184 0.0.0.O.11.

O42 2.1.

000 1.O.O.0.O.O.

00073222886O549964054134963539045402541000471448450185195

7.TOT14 05

14 31

1. 32

14. 05

14 05

14 7613 6313 83

RATIO1 00

0. 19

0. O2

1. 00

i

301049

NO202122p-»

2 3'26272829303132333435

RE"!1717.17:17:1618:2O :25:2222.2425:28:12:31.24:

• < i _ J RATIO RRT(L) RATIO01445032255434275558183507223605

10101010.101010

1 00 1O1O101010.10

1 00 1O1. 00 101 00 10

000000000000000000000OOO O 10000OOO000OOOOOO000 0 13000 0 12OOO 0 09

AMNT AMNT<160160160160.16O160160

30. OO 30.160160.160.160160

31. 51 3029. 10 30.29. 53 30.

:L>000000000000000000000000OO000000

R FAC R. FAC(L>O0O00.00.

1 OOO 10.0.o.0o.

1. 941 1.0. 863 01. O47 1

3423882O2525392118367OOO427428482781395848890063

RATIO

1 00

1. 050. 970. 98

301050

96.1-1

48,0-

106.0-1

50.0-

M/E

COMPUCHEM LABSDUAL MASS SPECTRUM12/09/87 13:07:00 + 6:05SAMPLE: 10ML CC#170202ENHANCED (S 15B 2N)

DATA: UH070202A03 #178 BASE M/E: 49/ 49RIC: 3571I./ 36991.

THYLEHE CHLORIDE

40 56 1 80

9458.

3348.

1300SAMPLE

C.H2.CL2H MT13§3 1B PK 49RANK 1IN 379PUR 946

C2.H2.02.CL2N Hl'!SB PK 48RANK 2IN 3135PUR 495

C15.H17.H.SM WT $JB PK 84RANK 3IN 17416PUR 480 -I

H E

COMPUCHEM LABSLIBRARY SEARCH12/09/87 13:07:00 + 6:05SnMPLE: 10ML CC*170202ENHANCED (S 156 2N 0T>

DATA: VH070202A03 « 178 BASE M/E: 43RIC; 35711.

li50

1METHANE, D I CHLORO- CAS* 75-0y-2

ACETICACID^DICHLORO- CAS# 9-43-6

i Hi__il llPYRIDINE, 3-<TERT-BUTYLTHIO;-4-PHEHYL- CAS# 18794-40-6

-—————,—————r-4-r-

100 150 200


COMPUCHEM INSTRUMENT BLANK 10: V8871209A03


TELEDNPR-5, TELEDNPR-6, TELEDNPR-7, TELEDNPR-8170199, 170200, 170201, 170202



CONCENTRATION(ug/L)

BDLBDLBDLBDL

23BDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDL

DETECTIONLIMIT

(ug/L)

1010101010

10010010101010101010101010101010101010101010101010


% Recovery

D4-l,2-Dichloroethane4-Bromof1uorobenzeneDs-TolueneBDL= BELOW DETECTION LIMIT

94

95

Control RangeX

(70-121)(74-121)(81-117)

301053

i r j i'

r.-

i.':

to

o? to i

3010

54'

H

-^ -O .'I

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N r« ru ra ru ra r.i

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COMMERCIAL SPIKE RECOVERY

CHLOROMETHANEBROMOMETHANEVINYL CHLORIDECHLOROETHANEMETHYLENE CHLORIDEACROLEINACRYLONITRILEI.I-DICHLOROETHYLENE1.1-DICHLOROETHANETRANS-1 ,2-DICHLOROETHENECHLOROFORM1.2-DICHLOROETHANE1.1,1-TRICHLOROETHANECARBON TETRACHLORIDEBROMODICHLOROMETHANE1,2-DICHLOROPROPANETRANS-I,3-DICHLOROPROPENETRICHLOROETHENEOIBROMOCHLOROMETHANEI,1,2-TRICHLOROETHANEBENZENECIS-1 ,3-DICHLOROPROPENE2-CHLOROETHYLUINYLETHERBROMOFORMTETRACHLOROETHENE1 ,1 ,2.2-TETRACHLOROETHANETOLUENECHLOROBENZENEETHYLBENZENE

SPIKECC 1

170681

21.423.122.222.855.7

189228

22.122.322.426.424. 121 .320.1

2022.220.522.4

2024.4

2320.622.917.323.423.522.121 .422.2

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RECOVERY RANGE P/F

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21 .423.122.222.825.2

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DDD

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- 54.6-48.4-50.2-46.0- 44.2- 300.0- 300.0-46.8- 31 .0- 31 .2- 27.6- 31 .0-32.4- 28.0- 31 .0-42.0-36.6- 31 .4- 28.8-30.0- 30.2-45.4- 61 .0- 33.8- 29.6- 31 .4-30.0- 32.0-32.4

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30105S

CALIBRATION CHECK/TUNING COMPARISON - BF871209A03

Associated Samples:

SAMPLE IDENTIFIERS: COMPUCHEM* SAMPLE NUMBERS:

TELEDNPR-5 170199TELEDNPR-6 170200TELEDNPR-7 170201TELEDNPR-8 170202

301053

125.0-

RIC12/03/87 10:02:80SAMPLE: STDfl873 (20)CONDS.:

SSI1

COMPUCHEM LABSCOMPUCHEM DATA: UT871209A03 SCAWS 33 TO I860

I512 IS«3

SS#2 .

188160.

OCJD

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RIC

279362 417

46613:46

521

553

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1035

100034:10

QUANTITATION REPORT FILE: VT871209A03DATA: VT871209A03. TI12/09/87 10:02:00SAMPLE: STD#1B73 (20)CONDS. :f FITTED BY: 03 ANALYST: 819

AMOUNT-AREA(HGHT) * REF.AMNT/(REF. AREA(HGHT)* RESP. FACT)RESP. FAC. FROM AVERAGE OF WHOLE . RL

NO NAME1 «234 BROMOCHLOROMETHANE (IS)2 221 CHLOROMETHANE3 220 BROMOMETHANE4 231 VINYL CHLORIDE5 209 CHLOROETHANE6 222 METHYLENE CHLORIDE7 201 ACROLEIN8 202 ACRYLONITRILE9 216 1, 1-DICHLOROETHYLENE

10 214 1,1-DICHLOROETHANE11 226 TRANS-1.2-D1CHLOROETHYLENE12 211 CHLOROFORM13 215 1, 2-DICHLOROETHANE14 *248 1,4 DIFLUOROBENZENE (IS)15 227 1,1,1-TRICHLOROETHANE16 206 CARBON TETRACHLORIDE17 212 BROMODICHLOROMETHANE18 217 1,2-DICHLOROPROPANE19 23O TRANS-1, 3-DICHLOROPROPENE20 229 TRICHLOROETHYLENE

208 CHLORODIBROMOMETHANE^ 228 1,1,2-TRICHLOROETHANE23 203 BENZENE24 218 CIS-1,3-DICHLOROPROPENE25 210 2-CHLOROETHYL VINYL ETHER26 205 BROMOFORM27 *270 D5-CHLOROBENZENE (IS)28 224 TETRACHLOROETHENE29 223 1,1,2,2-TETRACHLOROETHANE30 225 TOLUENE31 207 CHLOROBENZENE32 219 ETHYLBENZENE33 #258 D4-1,2-DICHLOROETHANE34 «247 BROMOFLUOROBENZENE35 #233 D8-TOLUENE36 251 STYRENE37 24O M-XYLENE38 271 O, P XYLENE

NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT XTOT1 128 279 9:32 1 l.OOO A BB 45589. 3O. OOO UG/L 2.562 50 43 1:28 1 0.154 A BB 28981. 24.144 UG/L 2.063 94 69 2:21 1 O. 247 A BB 51516. 23.837 UG/L 2.034 62 86 2:56 1 0. 3O8 A BB 35911. 24.224 UG/L 2.065 64 115 3:56 1 O. 412 ABB 21719. 23. 445 UG/L 2.006 84 178 6: OS 1 O. 638 A BB 4O483. 27.648 UG/L 2.36

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13012997787563

1731171648392

112106659598

1O41061O6

RET(L9: 341:282:263: OO4: O26: 136: 467:299:01

10:2311:0611:4512:3020: 1213: 5014: 1514: 5016: 1217: 4817:0117: 4417: 50

SCAN TIME REF194 6: 38 1216 7:23 1262 8: 57 1303 10. 21 1324 1 1 : 04 1343 1 1 : 43 1365 12:28 1591 20: 12 14404 13:48 14416 14: 13 14433 14:48 14474 16: 12 14521 17:48 14498 17: Ol 14519 17:44 14522 17: 50 14513 17:32 14482 16:28 14553 18: 54 14602 20:34 14745 25: 27 27671 22: 56 27672 22: 58 27711 24:18 27749 25: 35 27823 28: 07 27362 12:22 1925 31:36 27705 24: 05 27982 33: 33 27994 33: 58 27

1035 35:22 27

RRT0 6950. 7740. 9391. 0861. 1611. 2291. 3O81. 0000. 6840. 7040. 7330. 8020. 8820. 843O. 8780. 8830. 8680. 8160. 9361. 0191. 000O. 9O1O. 9O20. 9541. 0051. 1O51. 2971. 2420. 9461. 3181. 3341. 389

) RATIO RRT(L) RATIO1. OO 10. OOO O.1. 00 10. 000 0.0. 97 10. OOO O.0. 98 10. 000 0.O. 97 1O. OOO 0.0. 98 10. 000 0.O. 981OO. OOO O.0. 9910O. OOO 0.0. 99 10. OOO 0.1. 00 10. OOO 0.1. OO 10. OOO 0.1. OO 1O. OOO 0.1. OO 1O. OOO 0.1. OO 1O. OOO O.l.OO 1O. OOO 0.1. 00 10. OOO 0.1. OO 1O. 000 0.1. 00 10. OOO 0.1. 00 10. OOO 0.1. 00 10. OOO 0.1. 00 10. OOO 0.1. OO 10. OOO 0.

10020203O406Ol0109111212131O0707O70809080909

METHA BBA BBA BBA BBA BBA BBA BBA BBA BBA VBA BBA BBA VBA BBA BBA BBA BVA VBA BBA BBA BBA BBA BBA BBA BBA BBA BBA BBA BBA BBA BBA BB

AMNT30. OO24. 1423. 8424. 2223. 4527. 65

164. 13178. 55

19. 812O. 5420.6922. 032O. 483O. OO20. 1419. 3818.8619. 7417. 8421. 7418. 9721. 69

AREA(HGHT)15254.42417.30652.5015O.34395.80428.49824.

245048.82248.74286.71423.31747.30128.66143.63053.39471.97363.62468.18394.51531.

219517.84451.64700.76094.

124671.65855.81849.

188903.227068.126543.89023.

148267.

AMNT ( L )30. 00

160. 00160. 00160. 0016O. OO160. 00

1600. OO160O. OO

16O. OO160. OO160. OO160. OO160. OO30. OO

16O. OO160. OO16O. OO16O. OO16O. OO160. 00160. OO160. OO

R.1.0.0.0.O.O.0.0.O.O.0.o.o.1.o.0.0.o.0.0.0.o.

AMOUNT164.178.

19.20.20.22.20.30.20.19.18.19.17.21.18.21.21.18.18.17.30.24.19.20.2O.21.29.29.29.20.23.43.

FACOOO1192121480891670060171262O6141331203OOOO63037033O24023031O4803O

13154681554068503148000013738O855743844743965688172647487039OOO051525499737226150023188872150166

UC/LUG/LUC/LUC/LUC/LUG/LUC/LUC/LUC/LUC/LUC/LUC/LUC/LUC/LUG/LUC/LUC/LUC/LUC/LUC/LUC/LUC/LUG/LUC/LUG/LUC/LUC/LUC/LUC/LUG/LUC/LUC/L

R. FAC<L)1.0.1.0.0.0.O.O.1.1.1.2.1.1.O.O.O.o.0.0.o.o.

OOO790422976610964061156O186070944O26O1OOOSOO4694641972O73724O7223

XTOT13. 9813. 21

11111211

111221111222113

. 69

. 73

. 76

. 88

. 74

. 36

. 72

. 65

. 61

. 68

. 52

. 85

. 62

. 83

. 80

. 39

. 57

. 43

. 56

. 03

. 66

. 73

. 77

. 81

. 48

. 47

. 49

. 78

. 9768

RATIO1.0.0.0.O.0.0.O.0.0.0.0.0.1.0.O.0.0.0.0.0.0.

OO131315151710111213131413OO1312121211141214

30106

NO23242526

"*

2!9303132333435363738

RET(L)17: 3216: 2818: 5420: 3425: 2522: 5622: 5624: 1525: 3328:0312:2431:3024: 0333: 2733: 5435: 14

RATIO RRT(L)1. 001. 001. 001. 001. 001. 001. OO1. 001. 001. 001. 001. OO1. 001. 001. 001. OO

10. 00010. 00010. 00010. OOO10. 00010. 00010. ooo10. ooo10. 00010. 00010. OOO10. OOO10. ooo

5. OOO5. 0005. 000

RATIO0. 090. 080. 090. 100. 1O0. O90. 090. 1O0. 100. 110. 130. 120. 09O. 260. 270. 28

AMNT21.18.18.17.30.24.19.20.20.21.29.29.29.20.23.43.

1765490400OS53507423150219871517

AMNT(L)160.160.160.160.30.

160.160.160.160.160.30.30.30.

160.160.320.

00000000000000000000OO000000OO00

R. FAC R. FAC(L)0. 0740. 0480. 0140. 0391. 0000. O720. 0550. 0650. 1060. 0561. 7950. 8611. 034O. 1O80. 076O. O63

0. 5630. 410O. 122O. 37O1. OOO0. 480O. 453O. 5070. 8220. 4241. 8480. 89O1. 0630. 829O. 526O. 469

RATIO0. 130. 120. 120. 111. 000. 15O. 120. 130. 130. 130. 970. 970. 970. 130. 140. 13

3010G3

SPECTRUM: BF8712O9A03 # 338SAMPLE: 2UL BFB LOT#24361TIME OF INJECTION: 8: 18 12/09/87ENHANCEMENT:

TOTAL ION:ANALYST.

36928819

SPECTRUM FIT TO BFB CRITERIA

M/E INTEN. LIMITS ROUND RA

50 1180. 15-40% OF 95 16. 10 OK75 3076. 30-60% OF 95 41.98 OK95 7328 1OOV. (BASE PK) 100. OO OK96 504. 5-9% OF 95 6. 88 OK173 0 < 1% OF 95 0. 00 OK174 6672. > 50% OF 95 91.05 OK175 514 5-9% OF 174 7. 7O OK176 6608. 95-101% OF 174 99.04 OK177 388. 5-9% OF 176 5. 87 OK

3^1004

MASS LIST12/09/87 8:18:00 + 11:33SAMPLE: 2UL BFB LOT#24361

COMPUCHEM LABSDATA: BF871209A03 * 338 BASE M/E: 95

RIC: 36928.

37*~207MASS

37383940414344493O5155565761626368697173747576

~~>9818788929394959697

1741751761772O 7

0.*

*

4.3.2.2.3.8.8.2.

16.5.1.2.3.3.2.2.9.

1011.

5.14.41.

4.2.2.2.3.1.3.8.

100.6.1.

91.7.

90.5.3.

00 MINIMA0 MAXIMARA

93384262943931511O345422297878764492678419980162962897837588OO8830050117293O

MIN INTEN: O. MAX INTEN: 7328.

301065

fCQMPUCHEM LABS

MASS SPECTRUM12/69/87 8:18:66+11:33SAMPLE: 2UL BFB LOT124361

DATA: BF871269A63 1338 BASE N/E: 95RIC: 36928.

95

53.8 H

75

,—>.oCTCJ)

53

M/E

71

57

I66

81

86

88

174

196 126

267

7328.16.

140 166 188 266

report: analytical data report, prepared for mr. joe

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