research activity: 2002-04-29 wd/we ozone obs. in · pdf file3 4 5 6 benz 0 8 16 24 hour 0 1 2...

71
K-1 APPENDIX K BOX PLOTS BY DAY OF WEEK This appendix contains notched box-whisker plots (as described in Section 4 of this report) of concentrations of selected hydrocarbons by hour, by day of week (all hours of data included), and by day of week for specific hours for the PAMS and PAMS-like sites in the SoCAB. The plots are organized alphabetically by site. Plots that are missing from the sequence are included in Section 4. Other box plots were investigated as a part of the analyses; this appendix provides examples of the types of plots prepared.

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Page 1: Research Activity: 2002-04-29 WD/WE Ozone Obs. in · PDF file3 4 5 6 BENZ 0 8 16 24 HOUR 0 1 2 3 4 5 6 MXYL 0 8 16 24 HOUR 0 4 8 12 16 NBUTA ... Vol. III: Anal ysis of Summer 2000

K-1

APPENDIX K

BOX PLOTS BY DAY OF WEEK

This appendix contains notched box-whisker plots (as described in Section 4 of this report) of concentrations of selected hydrocarbons by hour, by day of week (all hours of data included), and by day of week for specific hours for the PAMS and PAMS-like sites in the SoCAB. The plots are organized alphabetically by site. Plots that are missing from the sequence are included in Section 4. Other box plots were investigated as a part of the analyses; this appendix provides examples of the types of plots prepared.

Page 2: Research Activity: 2002-04-29 WD/WE Ozone Obs. in · PDF file3 4 5 6 BENZ 0 8 16 24 HOUR 0 1 2 3 4 5 6 MXYL 0 8 16 24 HOUR 0 4 8 12 16 NBUTA ... Vol. III: Anal ysis of Summer 2000

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Page 3: Research Activity: 2002-04-29 WD/WE Ozone Obs. in · PDF file3 4 5 6 BENZ 0 8 16 24 HOUR 0 1 2 3 4 5 6 MXYL 0 8 16 24 HOUR 0 4 8 12 16 NBUTA ... Vol. III: Anal ysis of Summer 2000

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Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by time of day (PST) at Azusa in 1999 and 2000.

Page 4: Research Activity: 2002-04-29 WD/WE Ozone Obs. in · PDF file3 4 5 6 BENZ 0 8 16 24 HOUR 0 1 2 3 4 5 6 MXYL 0 8 16 24 HOUR 0 4 8 12 16 NBUTA ... Vol. III: Anal ysis of Summer 2000

K-4

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by time of day (PST) at Banning in 1999 and 2000.

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K-5

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by time of day (PST) at Burbank in 1999 and 2000.

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K-6

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NUBTA), and isoprene (ISPRE) concentrations (ppbC) by time of day (PST) at Hawthorne in 1999 and 2000.

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Page 7: Research Activity: 2002-04-29 WD/WE Ozone Obs. in · PDF file3 4 5 6 BENZ 0 8 16 24 HOUR 0 1 2 3 4 5 6 MXYL 0 8 16 24 HOUR 0 4 8 12 16 NBUTA ... Vol. III: Anal ysis of Summer 2000

K-7

Notched box-whisker plots of benzene (BENZ), m-&p-xylene (M_PXY), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by time of day (PST) at Los Angeles in1999 and 2000.

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Notched box-whisker plots of benzene (BENZ), m-&p-xylene (M_PXY), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by time of day (PST) at Pico Rivera in 1999 and 2000.

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K-9

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by time of day (PST) at Santa Clarita in 1999 and 2000.

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Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by time of day (PST) at Upland in 1999 and 2000.

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K-11

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Azusa in 1999 and 2000 at 0200 PST.

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K-12

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Azusa in 1999and 2000 at 0200 PST.

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Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Azusa in 1999 and 2000 at 0500 PST.

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Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Azusa in 1999and 2000 at 0500 PST.

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Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Azusa in 1999and 2000 at 1100 PST.

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Page 16: Research Activity: 2002-04-29 WD/WE Ozone Obs. in · PDF file3 4 5 6 BENZ 0 8 16 24 HOUR 0 1 2 3 4 5 6 MXYL 0 8 16 24 HOUR 0 4 8 12 16 NBUTA ... Vol. III: Anal ysis of Summer 2000

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Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Azusa in 1999and 2000 at 1100 PST.

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Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Banning in 1999 and 2000. All time periods are included.

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Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE), and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Banning in 1999 and 2000. All time periods are included.

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Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Banning in 1999and 2000 at 0200 PST.

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Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Banning in 1999and 2000 at 0200 PST.

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Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Banning in 1999and 2000 at 0500 PST.

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Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Banning in 1999and 2000 at 0500 PST.

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Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Banning in 1999and 2000 at 1100 PST.

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Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Banning in 1999and 2000 at 1100 PST.

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Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE), andn-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Burbank in 1999 and 2000. All time periods are included.

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K-26

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Burbank in 1999and 2000 at 0200 PST.

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K-27

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Burbank in 1999and 2000 at 0200 PST.

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K-28

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Burbank in 1999and 2000 at 0500 PST.

Mon Sun Mon Sun

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K-29

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Burbank in 1999and 2000 at 0500 PST.

Mon Sun Mon Sun

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K-30

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week at Burbank in 1999and 2000 at 1100 PST.

Mon Sun Mon Sun

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K-31

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week at Burbank in 1999and 2000 at 1100 PST.

Mon Sun Mon Sun

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K-32

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Hawthorne in 1999 and 2000. All time periods are included.

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K-33

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Hawthorne in 1999and 2000 at 0200 PST.

Mon Sun Mon Sun

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K-34

0200 PST

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Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Hawthorne in 1999and 2000 at 0200 PST.

Mon Sun Mon Sun

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K-35

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Hawthorne in 1999and 2000 at 0500 PST.

Mon Sun Mon Sun

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K-36

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Hawthorne in 1999and 2000 at 0500 PST.

Mon Sun Mon Sun

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K-37

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Hawthorne in 1999and 2000 at 1100 PST.

Mon Sun Mon Sun

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K-38

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Hawthorne in 1999and 2000 at 1100 PST.

Mon Sun Mon Sun

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K-39

Notched box-whisker plots of benzene (BENZ), m- & p-xylene (M_PXY), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Los Angeles in 1999 and 2000. All time periods are included.

0 1 2 3 4 5 6 7 8DOW

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K-40

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE), and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Los Angeles in 1999 and 2000. All time periods are included.

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K-41

Notched box-whisker plots of benzene (BENZ), m- & p-xylene (M_PXY), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Los Angeles in 1999and 2000 at 0500 PST.

Mon Sun Mon Sun

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K-42

Notched box-whisker plots of benzene (BENZ), m-& p-xylene (M_PXY), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Pico Rivera in 1999and 2000 at 0200 PST.

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K-43

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Pico Rivera in 1999and 2000 at 0200 PST.

Mon Sun Mon Sun

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K-44

Notched box-whisker plots of benzene (BENZ), m- & p-xylene (M_PXY), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Pico Rivera in 1999and 2000 at 0500 PST.

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K-45

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Pico Rivera in 1999and 2000 at 1100 PST.

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K-46

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Pico Rivera in 1999and 2000 at 1100 PST.

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K-47

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Santa Clarita in 1999 and 2000. All time periods are included.

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K-48

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE), andn-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Santa Clarita in 1999 and 2000. All time periods are included.

0 1 2 3 4 5 6 7 8DOW

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K-49

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA), and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Santa Clarita in 1999and 2000 at 0200 PST.

Mon Sun Mon Sun

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K-50

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Santa Clarita in 1999and 2000 at 0200 PST.

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K-51

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Santa Clarita in 1999and 2000 at 0500 PST.

Mon Sun Mon Sun

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K-52

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Santa Clarita in 1999and 2000 at 0500 PST.

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20

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40

PR

OP

A

0 1 2 3 4 5 6 7 8DOW

0.0

0.2

0.4

0.6

0.8

1.0

1.2

V1P

NT

E

0 1 2 3 4 5 6 7 8DOW

0.5

1.0

1.5

2.0

2.5

ND

EC

Mon SunMon Sun

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K-53

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Santa Clarita in 1999and 2000 at 1100 PST.

Mon Sun Mon Sun

1100 PST

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

5

6

7

BE

NZ

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

MX

YL

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

20

NB

UT

A

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

5

6

7

8

ISP

RE

Mon SunMon Sun

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K-54

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Santa Clarita in 1999and 2000 at 1100 PST.

Mon Sun Mon Sun

1100 PST

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

5

ST

YR

0 1 2 3 4 5 6 7 8DOW

0

10

20

30

40

PR

OP

A

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

V1P

NT

E

0 1 2 3 4 5 6 7 8DOW

0.0

0.4

0.8

1.2

1.6

ND

EC

Mon SunMon Sun

Page 55: Research Activity: 2002-04-29 WD/WE Ozone Obs. in · PDF file3 4 5 6 BENZ 0 8 16 24 HOUR 0 1 2 3 4 5 6 MXYL 0 8 16 24 HOUR 0 4 8 12 16 NBUTA ... Vol. III: Anal ysis of Summer 2000

K-55

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Upland in 1999 and 2000. All time periods are included.

0 1 2 3 4 5 6 7 8DOW

0

5

10

15B

EN

Z

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

20

25

MX

YL

0 1 2 3 4 5 6 7 8DOW

0

10

20

30

40

50

NB

UT

A

0 1 2 3 4 5 6 7 8DOW

0

5

10

15IS

PR

E

Mon SunMon Sun

Mon Sun Mon Sun

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K-56

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Upland in 1999and 2000 at 0200 PST.

Mon Sun Mon Sun

0200 PST

0 1 2 3 4 5 6 7 8DOW

1

2

3

4

5

6

7

8

9

10

BE

NZ

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

20

MX

YL

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

20

NB

UT

A

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

ISP

RE

Mon SunMon Sun

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K-57

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Upland in 1999and 2000 at 0200 PST.

Mon Sun Mon Sun

0200 PST

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

5

6

7

8

9

10

ST

YR

0 1 2 3 4 5 6 7 8DOW

0

10

20

30

40

PR

OP

A

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

V1P

NT

E

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

5

ND

EC

Mon SunMon Sun

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K-58

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Upland in 1999and 2000 at 0500 PST.

Mon Sun Mon Sun

0500 PST

0 1 2 3 4 5 6 7 8DOW

1

2

3

4

5

6

7

8

9

10

11

BE

NZ

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

20

25

MX

YL

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

20

NB

UT

A

0 1 2 3 4 5 6 7 8DOW

0

2

4

6

8

10

12

ISP

RE

Mon SunMon Sun

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K-59

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Upland in 1999and 2000 at 0500 PST.

Mon Sun Mon Sun

0500 PST

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

5

6

7

8

9

10

ST

YR

0 1 2 3 4 5 6 7 8DOW

0

10

20

30

40

50

PR

OP

A

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

V1P

NT

E

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

5

ND

EC

Mon SunMon Sun

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K-60

Notched box-whisker plots of benzene (BENZ), m-xylene (MXYL), n-butane (NBUTA),and isoprene (ISPRE) concentrations (ppbC) by day of week (DOW) at Upland in 1999and 2000 at 1100 PST.

Mon Sun Mon Sun

1100 PST

0 1 2 3 4 5 6 7 8DOW

1

2

3

4

5

6

7

8

BE

NZ

0 1 2 3 4 5 6 7 8DOW

0

5

10

15

MX

YL

0 1 2 3 4 5 6 7 8DOW

0

10

20

30

40

50

NB

UT

A

0 1 2 3 4 5 6 7 8DOW

0

2

4

6

8

10

12

ISP

RE

Mon Sun Mon Sun

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K-61

Notched box-whisker plots of styrene (STYR), propane (PROPA), 1-pentene (V1PNTE),and n-decane (NDEC) concentrations (ppbC) by day of week (DOW) at Upland in 1999and 2000 at 1100 PST.

Mon Sun Mon Sun

1100 PST

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

5

6

7

8

9

10

ST

YR

0 1 2 3 4 5 6 7 8DOW

0

10

20

30

40

50

60

PR

OP

A

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

4

V1P

NT

E

0 1 2 3 4 5 6 7 8DOW

0

1

2

3

ND

EC

Mon SunMon Sun

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L-1

APPENDIX L

FINGERPRINT PLOTS OF DATA COLLECTED AT LOS ANGELES N. MAIN DURING THE SPECIAL STUDY (SEPTEMBER-OCTOBER 2000)

This appendix contains fingerprint plots of hydrocarbon samples collected at Los Angeles N. Main in September-October 2000. These plots compare concentrations between a weekday (Monday, October 2) and a weekend day (Sunday, October 8). Three types of data are plotted: concentration (ppbC), weight percent (normalized by the total nonmethane organic compound [TNMOC] mass), and reactivity-weighted weight percent (where each weight percent is multiplied by a maximum incremental reactivity-MIR factor). Historical data (1999 and 2000 PAMS season) for Los Angeles N. Main are also included in one plot for perspective.

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L-3

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L-4

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L-5

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L-6

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L-7

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L-8

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L-9

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L-10

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ntr

atio

n (p

pb

C)

10/2 MON (TNMOC=175.6)

10/8 SUN (TNMOC=500)

SUN historical

MON historical