rj04 resonance and revivals i. quantum rotor and infinite-well dynamics william g. harter and...

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RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville Physics Department and Microelectronics-Photonics Program m=0 ±1 ±2 ±3 ±4 ±5 ±6 n=1 2 3 4 5 6

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Page 1: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

RJ04

RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS

William G. Harter and Alvason Zhenhua LiUniversity of Arkansas - Fayetteville

Physics Department and Microelectronics-Photonics Program

m=0±1±2

±3

±4

±5

±6

n=1

2

3

4

5

6

Page 2: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

RJ04

RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS

William G. Harter and Alvason Zhenhua LiUniversity of Arkansas - Fayetteville

Physics Department and Microelectronics-Photonics Program

m=0±1±2

±3

±4

±5

±6

n=1

2

3

4

5

6

Rotor revival structure includes anything ∞-well can do…. …and is easier to explain.

Won’t talk about ∞-well

Page 3: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

RJ04

RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS

William G. Harter and Alvason Zhenhua LiUniversity of Arkansas - Fayetteville

Physics Department and Microelectronics-Photonics Program

m=0±1±2

±3

±4

±5

±6

n=1

2

3

4

5

6

Rotor revival structure includes anything ∞-well can do…. …and is easier to explain.

Some Early History of Quantum RevivalsJ.H. Eberly et. al. Phys. Rev. A 23,236 (1981) Laser QuantumCavityDynamic revivalsR.S. McDowell, WGH, C.W. Patterson LosAlmos Sci. 3, 38(1982) Symmetric-top revivalsS.I. Vetchinkin, et. al. Chem. Phys. Lett. 215,11 (1993) 1D ∞-Square well revivalsAronstein, Stroud, Berry, …, Schleich,.. (1995-1998) “ “ “ “WGH, J. Mol. Spectrosc. 210, 166 (2001) Bohr-rotor revivals

So we thought we’d put this revival business to bed! Then...

Won’t talk about ∞-well

Page 4: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

More recent story of Quantum RevivalsAnne B. McCoy Chem. Phys. Lett. 501, 603(2011)...reminds me that Morse potential is integer-analytic.

Some Early History of Quantum RevivalsJ.H. Eberly et. al. Phys. Rev. A 23,236 (1981) Laser QuantumCavityDynamic revivalsR.S. McDowell, WGH, C.W. Patterson LosAlmos Sci. 3, 38(1982) Symmetric-top revivalsS.I. Vetchinkin, et. al. Chem. Phys. Lett. 215,11 (1993) 1D ∞-Square well revivalsAronstein, Stroud, Berry, …, Schleich,.. (1995-1998) “ “ “ “WGH, J. Mol. Spectrosc. 210, 166 (2001) Bohr-rotor revivals

So we thought we’d put this revival business to bed! Then this...

Leads to cool Morse revivals in: Following Talk RJ05 by Li:Resonance&Revivals II. MORSE OSCILLATOR AND DOUBLE MORSE WELL DYNAMICS.

So now we’re having a revival-revival!

...and, in words by Joannie Mitchell, I find: “I didn’t really know... revivals … at all.”

Page 5: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

What do revivals look like?(...in space-time…)

Page 6: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville
Page 7: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

What do revivals look like?(...in space-time…)

OK,let’s try that again...

withquantum revivals...

Page 8: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Time t (units of fundamental period ) τ1

Coordinate φ (units of 2π )

0/1

1/10

1/5

3/10

2/5

1/2

3/5

7/10

4/5

9/10

1/1

3/4

1/4

1/21/40-1/4-1/2

1/2

1/4

0-1/4

-1/2

(Imagine "wrap-around" φ-coordinate) +π /2

−π /2

+π−π

3/4

1/4

0/1

1/2

1/1

Time t

Page 9: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Observable dynamics of N-level-system state Depends on Fourier spectrum of probability distribution

Ψ = e−iωnt

n=0

N

∑ ψ n

ω 0 ω1 ω 2 ω 3 ω 4

...But individual eigenfrequencies are not directly observable...

ω n

ΨΨ Ψ

Page 10: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Ψ = e−iωnt

n=0

N

∑ ψ n

Ψ = e+iωmt

m=0

N

∑ ψ *m

ω 0 ω1 ω 2 ω 3 ω 4

ω 4

ω 3

ω 2

ω1

ω 0

...But individual eigenfrequencies are not directly observable...

Observable dynamics of N-level-system state Depends on Fourier spectrum of probability distribution

ΨΨ Ψ

Page 11: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Ψ = e−iωnt

n=0

N

∑ ψ n

Ψ = e+iωmt

m=0

N

∑ ψ *m

Ψ Ψ = ei(ωm −ωn )t

n=0

N

∑ ψ *mψ n

= eiΔm nt

m,n=0

N

∑ ρ mnω 0 ω1 ω 2 ω 3 ω 4

ω 4

ω 3

ω 2

ω1

ω 0

...But individual eigenfrequencies are not directly observable...

Observable dynamics of N-level-system state Depends on Fourier spectrum of probability distribution

ΨΨ Ψ

Page 12: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

ω3

Ψ = e−iωnt

n=0

N

∑ ψ n

Ψ = e+iωmt

m=0

N

∑ ψ *m

ω0 ω1 ω2 ω3 ωN

ω0

ω1

ω2

ωN

Ψ Ψ = ei(ωm −ωn )t

n=0

N

∑ ψ *mψ n

= eiΔm nt

m,n=0

N

∑ ρ mn

...But individual eigenfrequencies are not directly observable...

Observable dynamics of N-level-system state Depends on Fourier spectrum of probability distribution

ΨΨ Ψ

Page 13: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Ψ = e−iωnt

n=0

N

∑ ψ n

Ψ = e+iωmt

m=0

N

∑ ψ *m

Ψ Ψ = ei(ωm −ωn )t

n=0

N

∑ ψ *mψ n

= eiΔm nt

m,n=0

N

∑ ρ mnω 0 ω1 ω 2 ω 3 ω 4

ω 4

ω 3

ω 2

ω1

ω 0

...But individual eigenfrequencies are not directly observable… ...only differences Δmn = (ωm −ωn )

Δ04

Δ14

Δ03

Δ23

Δ13

Δ4 0 Δ41

Observable dynamics of N-level-system state Depends on Fourier spectrum of probability distribution

ΨΨ Ψ

Page 14: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Ψ = e−iωnt

n=0

N

∑ ψ n

Ψ = e+iωmt

m=0

N

∑ ψ *m

Ψ Ψ = ei(ωm −ωn )t

n=0

N

∑ ψ *mψ n

= eiΔm nt

m,n=0

N

∑ ρ mnω 0 ω1 ω 2 ω 3 ω 4

ω 4

ω 3

ω 2

ω1

ω 0

...But individual eigenfrequencies are not directly observable… ...only differences Δmn = (ωm −ωn )

Δ04

Δ14

Δ03

Δ23

Δ13

Δ4 0 Δ41

N=5 eigenfrequenciesgives: N(N-1)/2=10 positive and : N(N-1)/2=10negative

Δm>n = ωm −ωn

Δm<n = ωm −ωn

Observable dynamics of N-level-system state Depends on Fourier spectrum of probability distribution

ΨΨ Ψ

Page 15: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Ψ = e−iωnt

n=0

N

∑ ψ n

Ψ = e+iωmt

m=0

N

∑ ψ *m

Ψ Ψ = ei(ωm −ωn )t

n=0

N

∑ ψ *mψ n

= eiΔm nt

m,n=0

N

∑ ρ mnω 0 ω1 ω 2 ω 3 ω 4

ω 4

ω 3

ω 2

ω1

ω 0

...But individual eigenfrequencies are not directly observable… ...only differences Δmn = (ωm −ωn )

Δ04

Δ14

Δ03

Δ23

Δ13

Δ4 0 Δ41

N=5 eigenfrequenciesgives: N(N-1)/2=10 positive and : N(N-1)/2=10negative

Δm>n = ωm −ωn

Δm<n = ωm −ωn

...that is, N(N-1)/2=10 observable beats Δm<n = ωm −ωn

Observable dynamics of N-level-system state Depends on Fourier spectrum of probability distribution

ΨΨ Ψ

Page 16: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Observable dynamics of 2-level-system state Fourier spectrum of has ONE beat frequency

Ψ = e−iωnt

n=0

N

∑ ψ n

Ψ = e+iωmt

m=0

N

∑ ψ *m

Ψ Ψ = ei(ωm −ωn )t

n=0

N

∑ ψ *mψ n

= eiΔm nt

m,n=0

N

∑ ρ mnω1 ω 2

ω 2

ω1

Δ12

Δ21

N=2 eigenfrequenciesgives: N(N-1)/2=1 positive and : N(N-1)/2=1negative

Δ2>1 = ω2 −ω1

Δ1<2 = ω1 −ω2

...that is, N(N-1)/2=1 observable beat Δm<n = ωm −ωn

ΨΨ Ψ Δ21 = −Δ12

Page 17: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

2-level-system and C2 symmetry beat dynamics

symmetric A1

vs.

antisymmetric A2

C2 Character Table describes eigenstates

1=r0 r =r1

0mod21 1

±1mod2 1 −1

Page 18: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

2-level-system and C2 symmetry beat dynamics

symmetric A1

vs.

antisymmetric A2

C2 Character Table describes eigenstates

1=r0 r =r1

0mod21 1

±1mod2 1 −1

Phasor C2 Characters describe local state beats

Initial sum

C2 Phasor-Character Table

Page 19: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

2-level-system and C2 symmetry beat dynamics

symmetric A1

vs.

antisymmetric A2

C2 Character Table describes eigenstates

1=r0 r =r1

0mod21 1

±1mod2 1 −1

Phasor C2 Characters describe local state beats

Initial sum

1/4-beat

C2 Phasor-Character Table

Page 20: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

2-level-system and C2 symmetry beat dynamics

symmetric A1

vs.

antisymmetric A2

C2 Character Table describes eigenstates

1=r0 r =r1

0mod21 1

±1mod2 1 −1

Phasor C2 Characters describe local state beats

Initial sum

1/4-beat

1/2-beat

C2 Phasor-Character Table

Page 21: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

2-level-system and C2 symmetry beat dynamics

symmetric A1

vs.

antisymmetric A2

C2 Character Table describes eigenstates

1=r0 r =r1

0mod21 1

±1mod2 1 −1

Phasor C2 Characters describe local state beats

Initial sum

1/4-beat

1/2-beat

3/4-beat

C2 Phasor-Character Table

Page 22: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

2-level-system and C2 symmetry beat dynamics

m=+1, 0, -1

C2 Phasor-Character Table

Page 23: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

What do revivals look like?...in per-space-time…

(… that is:frequency radian/sec.

vs

k-vector km radian/cm)

ωm

Page 24: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

N-level-system and revival-beat wave dynamics Bm2=B42

Bm2=B32

Bm2=B22

Bm2=B

Page 25: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

N-level-system and revival-beat wave dynamics

Page 26: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

N-level-system and revival-beat wave dynamics

Page 27: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

0123456789

1011121314151617

Harmonic Oscillator level spectrum contains the Rotor Levels as a subset

N-level-system and revival-beat wave dynamics

Page 28: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

N-level-system and revival-beat wave dynamics (Just 2-levels (0, ±1) (and some ±2) excited)

Page 29: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

N-level-system and revival-beat wave dynamics (Just 2-levels (0, ±1) (and some ±2) excited) (4-levels (0, ±1,±2,±3) (and some ±4) excited)

Page 30: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

N-level-system and revival-beat wave dynamics (9 or10-levels (0, ±1, ±2, ±3, ±4,..., ±9, ±10, ±11...) excited)

Zeros (clearly) and “particle-packets” (faintly) have paths labeled by fraction sequences like: 0

7,1

7,2

7,3

7,4

7,5

7,6

7,1

1

1

7

2

7

3

7

4

7

5

7

6

7

4

7

5

7

6

7

1

1

0

1

Page 31: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Farey Sum algebra of revival-beat wave dynamicsLabel by numerators N and denominators D of rational fractions N/D

Page 32: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Farey Sum algebra of revival-beat wave dynamicsLabel by numerators N and denominators D of rational fractions N/D

Page 33: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

A Lesson in Rational Fractions N/D (...that you can take home for your kids!)

Page 34: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Farey Sum related to vector sum

andFord Circles1/1-circle has

diameter 1

Page 35: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Farey Sum related to vector sum

andFord Circles

1/2-circle hasdiameter 1/22=1/4

1/1-circle hasdiameter 1

Page 36: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Farey Sum related to vector sum

andFord Circles

1/2-circle hasdiameter 1/22=1/4

1/3-circles havediameter 1/32=1/9

Page 37: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Farey Sum related to vector sum

andFord Circles

1/2-circle hasdiameter 1/22=1/4

1/3-circles havediameter 1/32=1/9

n/d-circles havediameter 1/d2

Page 38: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Farey Sum related to vector sum

andFord Circles

1/2-circle hasdiameter 1/22=1/4

1/3-circles havediameter 1/32=1/9

n/d-circles havediameter 1/d2

Page 39: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Cm algebra of revival-phase dynamics

Page 40: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Cm algebra of revival-phase dynamics

Page 41: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Summary

Quantum rotor revivals obey wonderfully simplegeometry, number, and group theoretical analysis

andas the next talk will show...

Page 42: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

Summary

Quantum rotor revivals obey wonderfully simplegeometry, number, and group theoretical analysis

andas the next talk will show…

“I still don’t really know... revivals … at all.”

Page 43: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

QuickTime™ and aH.264 decompressor

are needed to see this picture.

Simulation of revival-intensity dynamics

Page 44: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville

QuickTime™ and aH.264 decompressor

are needed to see this picture.

Page 45: RJ04 RESONANCE AND REVIVALS I. QUANTUM ROTOR AND INFINITE-WELL DYNAMICS William G. Harter and Alvason Zhenhua Li University of Arkansas - Fayetteville