rrt&* chemical safety and pollutio n preventio · 2011-09-14 · use mild steei, nylon, brass,...

9
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, DC 20460 OFFICE OF rrt&* CHEMICAL SAFETYAND PRO POLLUTION PREVENTION SSI Corporation c/o Crystal Layton SEP 0'1 20ft Landis International PO Box 5126 Valdosta, GA31603-5126 Subject: Coperlate EPA Reg No. 65109-1 Decision No. 452019 Submission date: Jun 29,2011 Application for Pesticide Notification (PRN 98-10) Dear Ms Layton: The Agency is in receipt of your Application for Pesticide Notification under Pesticide Registration Notice (PRN) 98-10. The Registration Division (RD) has conducted a review of this request for its applicability under PRN 98-10 and finds that the action requested falls within the scope of PRN 98-10. The Agency acknowledges the alternate brand name "Coperlate II Non-Crop" and the alternate brand name label with the STET of the "Agricultural Use Requirements" box and the directions for use in rice fields. The label submitted with the application has been stamped "Notification" and will be placed in our records. If you have questions concerning this letter, please contact Dominic Schuler at (703) 347-0260 or via email at [email protected]. Sincerely, )TonyKish Product Manager 22 Fungicide Branch Registration Division (7504P)

Upload: others

Post on 03-Apr-2020

0 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYWASHINGTON, DC 20460

OFFICE OFrrt&* CHEMICAL SAFETY AND

PRO POLLUTION PREVENTION

SSI Corporationc/o Crystal Layton SEP 0'1 20ftLandis InternationalPO Box 5126Valdosta, GA31603-5126

Subject: CoperlateEPA Reg No. 65109-1Decision No. 452019Submission date: Jun 29,2011Application for Pesticide Notification (PRN 98-10)

Dear Ms Layton:

The Agency is in receipt of your Application for Pesticide Notification under PesticideRegistration Notice (PRN) 98-10. The Registration Division (RD) has conducted a review ofthis request for its applicability under PRN 98-10 and finds that the action requested falls withinthe scope of PRN 98-10.

The Agency acknowledges the alternate brand name "Coperlate II Non-Crop" and thealternate brand name label with the STET of the "Agricultural Use Requirements" box and thedirections for use in rice fields.

The label submitted with the application has been stamped "Notification" and will beplaced in our records. If you have questions concerning this letter, please contact DominicSchuler at (703) 347-0260 or via email at [email protected].

Sincerely,

)TonyKishProduct Manager 22Fungicide BranchRegistration Division (7504P)

Page 2: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

r rPlease reed iiisintctiorison rav0rs&..t>6fore comfrial'iriQ form. Fctm Approved. OMB No. 2D7(M)Q6Q, Aotiroual expires 2-28-95

vvEPAUnited States

Environmental Protection AgencyWashington, DC 20460

Registration

Amendment

Other

QPR Identifier Number

Application for Pesticide - Section I1 / Comfjany^Pfaduct NumberSSl Corporation 65109-1

4. Company/Product {Name);SSI ^oVporation/Pi'lrtttiy Brand Name "Coperlate* and Alternate BrandName "Gbpeflate il Non-Crop"'5, Mania and Add'ess; of Applicant (include ZIP Gods)SSI Corporation P.O. Bi>x Si Jutesbu/g, CO 80737c/o LiaridisInternational, inc. P.O. Box 5126 Valdosta, GA 31603

Check if this is anew address

2. EPA Product ManagerTony kish

PMtf22

3. Proposed Classification

None Restricted

6, Expedited Review In•«cpl#yri{e|ifR) Jj| | ^W(cX3Xb)(i), myproduct is similar or identical in compos Itfcn "and labeling to:

EPA Re9. NO. 8EP 0 1 2011Product Name

Section ~ It

Amendment- Explain Below

ResubmiSsion !n Response to Agency letter dated,

•if^1 Notification - Explain Below

Final printed labels in response toAgency letter dated

"Me Toe" Application

Other - Explain Below

Explanation: Use adcitiprial pase(s) if'tieciessary.^For Section 1 ario Section II.)Nptfficsilian of AffernataBrarid ISilsme/addiiioh "Coperlate II Non^Crop" to EPA Reg. No. 65109-1 and removal of agricultural uses fer the Alternate BrandName Label per PR NofipB 98-10. This nptificalt'on is .consistent witftthe provisions of PRMotsca S8-1D anci EPA regulattorts at 40 CFR 152:46, arid n<>other chanigais: have been bade to th9;jabeliHg or |He confidential statement of foririu's of'lhis product, I uncierslandtriat II is a violation of 16 U.S.C, Sec.100.1 to..willfiilljf make, any false• siate'msntlo EPA,* I further understand thsi't:iMhis iidlification Is,np1 cbrtsatenl with the terrrts of PR Notice 98-10 and t!0CFR 152.46. this prod net may be in vielatiofl or HIFRA and I may.be subject to^enforcemfent action and pgnaife under sections 12andl4ofFIFRA.

Section - 1111. Material This PrpdUGt Will Be Packarjecl IrvChild-Resistanl Pack&g'frig

Yes

X No

Certification must besubmitted

Unit Packaging

Yes

If "Yss" UnitPacxaging Wg(.

No. perconlainer

3. LocBtion of Net Contents Infoimation

X Ubel. Container

VVatef Soluble Packaging

Yes

If "Yes"Pachage Wgl.

Mo. perecnieiner

4. Size(s) Retail Container

55; 30,5, 2.5, and 1 Gallon

2. Type of ContainerMetal

_X_ Plastic

, Glass

__ Paper

_ Other (Specify).

5. Location of Label Directions

On labelOn leaflet aocompaninng labef

6. Manner in VUhich Label Is Affixed to Product LilhpgraphedPaper gluedStenciled'

Other

Section-IV1. Contact PointfC<w.>xte,te.tons(tirectt/belov/farltlcniiricalion ontxiividuailo t>g contacted. !!• necessary. l_oprotean l/»s dfta'fc'a

NameCrystal Layton

Tille.Regulatory Agent

Telephone No. (Include Area Code)229-247-6472

CertificatiQnI certify thatBie statements I have made on this form and all attachmentsthereto are true, accurate and ccmplete.

I acknp.wledge thai any knowingly false or misleading stafeiTient rnEy be punishable by fine or imp'risohment or both- .under applicable law.

2. Signature

4. Typed NameCrystal Laytort

3. TitleRegulatory Agent

5; DateJune 29,20T1

8. Date ApplicationReceived

^Stamped)

EPA Form 857(5-1 (Rev. 3-94) Previous editions are obsolete. White- EPA File Copy (original) Vel low-Applicant Copy

Page 3: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

r <

* LANDIS1MNTI-.RNAIIONAI,

!( .•(, 15 VAN At. i l i iV1l . -NT

June 29,2011

Mr. Tony KishDocument Processing Desk (MOTIF)Office of Pesticide Programs (7505P)U.S. Environmental Protection AgencyRoom S-4900, One Potomac Yard2777 South Crystal DriveArlington, VA 22202-4501

Subject: EPA Reg. No. 65109-1 Alternate Brand Name Addition "Coperlatc II Non-Crop" andremoval of Agricultural Uses per PRN 98-10

Dear Mr. Kish,

We are submitting this Notification per Pesticide Registration Notice 98-10 on behalf of SSICorporation. The purpose of this Notification is to add the Alternate Brand Name "Coperlale IINon-Crop" to EPA Reg. No. 65109-1 (primary brand name Coperlate). The agricultural uses(rice) have been removed for the Alternate Brand Name Label (Coperlate II Non-Crop). Pleasefind the following enclosed:

» Application for Pesticide (EPA Form 8570-1)• Coperlate II Label showing the removal of the Agricultural Uses and Alternate

Brand Name mark-up labelo Coperlate II Label clean copyo Coperlate Master Label for reference

Thank you for your assistance, If you need any additional information please contact me at 229-247-6472 or [email protected].

Sincerely,

Crystal LaytfRegulatory Agent for SSI Corporation

S18S MtfMA Highway • H.0. B o x 5 i / < . i ! VW<toste,8»orota31$03^5f2SUSA • (?23)JM7-6-t72 e F«(226)242-1662 l;nul is" 'hiKiw i l l . n r i '

Page 4: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

TM

COPERLATE!!Non-Crop

ALGAEGIDE/BACTERICIDE*FOR LAKES, PONDS, RESERVOIRS, CANALS/LAGOONS, AND OTHER WATER SYSTEMS

Won Public Health

9:9 LbsPer Gallon '1.1:88 Kg.'L

ACTIVE INGREDIENTS Manufactured By:Copper Sulfate Pentahydrate*'* ..... .......... 20% SSI CorporationInert ingredients. ............ ... ...... ..... ....... .... 80% 210 S. CedarTOTAL ........... v.,. .„.,..,„..,.;.,: .......... ... .......... 100% Julesburg, CO 80737

"Metallic Qppper Equivalent... ...'5 % 970.474.0974CAS # 7758-99-8

KEEP OUT OF REACH OF CHILDRENDANGER/PELIGRO

(Si usted no entiende la etiqueta, b usque a algnien para qua se la explique a usted en details).(If you do not understand this lab.ei, find someone to explain it to you in detail).

PRECAUTIONARY STATEMENTSHazards to Humans and Domestic Animals

N on-Flammable. bo Not Freeze. SEP 0 j 2011

DANGERCorrosive. Causes irreversible eye damage. Do not gel in eyes or on clothing. Wear goggles or safely glasses. Harmful if swallowed. Inhaled,or absorbed through shin. May cause (allergic skin reactions. Avoid contact with si<ln. Wash 'thoroughly with soap and wafer after iiaridliiig,

FIRST AIDIF IN EVES: Hold eye open and rinse slowly; arid genlly with wgler for 15-20 minutes. Remove contact lenses, if present, after the first

5 minutes, then continue rinsing. Gall a:pqisan cantrorcenleror doctor for IfBalrinant advice.

JF ON SKIN Take off contaminated clothing. Rinse skin. immediately vyith plenty of waler for 1 5-20 minutes, Call a poisonOR CLOTH ING: control center or doctor for treatment advice.

IP SWALLOWED: Call a poison control center or doclorfmrriediately tor treatrrient advice, Have person sip a glass of waler if able to swallow.Do nol induce vomiting unless told to do so by a poison control center or doctor, Do not give anything t>y mouth to anunconscious person.

IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambufance, then give artificial respiration, preferablyby mouth lo mouth, if possible. Call a poisorl cbnlrol -center or doctor for treatment advice.

NOTE TO PHYSICIAN: Probabje i muCosal darhaga may coritraindicate the use oif gastric lav age,

EPA Reg. No, 65109-1 EPA Eat. No. 65109-CO-001

Net Contents: FIFTY-FIVE (55) U.S. GALLONS

Pagel of 6

Page 5: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

rPERSONAL PROTECTIVE EQUIPMENT (PPE)

Mixers, Loaders, Applicators, and other handlers inust wear the following:.» Long-sleeved shirt,* Ldng.parits,« Ciiamical resistanl glbves, made of. any waterproof material,'«• Prbtfttive eyewear, and» Shoes, plus socks.

Sojrie materials (Harare. cJ^mical-re'sistant to this.product ate'.nltril.e and polyvinyl chloride, if yo»i want more options, follow the instruclions forCategory Adrian EPA chemicaf-iesisftnce catego;ry selection; chart,

Follow manufiaelgfef'S'inslructfons for:ctear>ihg/ma(htaining PPE. If no. such instrtictions for wasfiabies are given, uss detergent and hot water.Kaep. and' wash; PPE: sep,arat|ly froni' other laundry:, Di£c_artr ;clolhing and olher absorbent .materials that have teen drenched or heavilycohtamlnated with this,product's concentrate. Do nbtTeiise them.

USER SAFETY REG01WMENDATIQNSUser should Wash hands before eating, drmkirig, chev/iiig giirn, using Iciliacco, or using Ih'e toltetUsershoXikJ re'tripve itothin^PEjm/nediate.lyl .stlcHis^Q'ejs.Inside, than wash' Ihordiighly and put on;c!ean cloihlng,User.should fembvS PPE immediatel/'after Nandlihg liia producL As soon as possible, wash thoraiighly.and change intocle^n olbtliing.Wash'lh'a outside of gloves before rerr»oving.

ENyiRONWENTAL HAZARDSFISH AND AQtUATIC ORGANISMiS; Waters treated wilh this prad'uci may be hazardous to .aquatiq organisms. Treatment of aquatic v;eedsan,d algae can result In oxygen Joss frbni de<;ompositior| of dead .algae aha weadii.: This dxygen (p?s <*gii cause fish and invertebratesiiffocatiom to minimize haiard, do noMteat niore i'.thari i % Pf .the water body to .avoki depfetiqri of pxygen diie to afeaying,vegeta1iori. Wait atleast 10 to 14 days between treatments. Beigin. treat ment aiong; tlie shore anij proceed dulwards, in bands to allow fish to move Inlo'untfeatedareas. In regions wheire ponds freeze in win ter, treatment ;ShoulS be done:d tovfl weeks before expected freeze tae to prevent mssses ofdecaying algae .linderkn ica Mter; Corlsupublic waters, ti> clefermins if a permit: is required/ Certain water conditions jhcJud&ig tow pH (=/< 6,5); low dissolved organic carbon (DOC)levels (3.6 nig/L ;6r •(ojWf). and 'soft" waters (i.e., dlKalinily less: than 50 rngil), increase • potential acute toxicily to non-target aquatic organisms.Trout and other species 'of fish rrisy.be killed- al application rates rBcprnrnendad on the label, especially, iri soft or acidic watsrs as describedabowe. Do not contaminate water when disposing of equipment vvash-watefs or rinsate.

E r.cJ angered Species Restrictions : It is a violation, cf Federal laws to use any pesticide in a manner 1ha* results in Llie death of an endangeredspecies or ac'versempditlcatipn of their liabitat. Tlie iis^pf tH|s;prbc(uctrnay pose a hazard to certain federally designated endangered speciesknown 'Ib '.occur In specaflc areas of the foliowirig cpunties arfdj their nesp.ective'siates: Sblarto {GA); Lawrerice. Wayne, Hancock; Claibome,Hawhins. Suilivan (TN};, Laiuaeifdate, Lfrnwlonei Madison (A'L); iSraVspn, Smyth, Scbti, Washin^on, Lee (

APPLICATION AND HANDLIN<3 EQUIPMENTApplitiation, hanbling or stor.age equipnneni MUST consist :bf either fjberBlass, R\/Gs, polypropyJen^s, most plaslies, or stainless s(e&l. Neveruse mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strength COPERLATE. Always rinse equipment free andclean of COPERLATE each night w.th plenty of, fresh clean waleV.

Alv/ays store .COPERLATE. above 3'2 degrees F, Freezing may causa product separation. Seller makes no warranty for the perfoirnance ofproduct which has been frozen.

Page 2 of 6

Page 6: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

( ( JDIRECTIONS FOR USE v ,

It is a violation of Federal law to use this product in a manner inconsistent with. its labeling. Do not apply this product in a way that will contact \workers or other persons, either Directly or through drift. Only protected handlers may be In the area during application, Fcr any requirementspecific to your State of Triiie, consult the agency responsible for pest!cfde:regulatian.

GENERAL INFORMATIONCOPERLATE is an innovattye;uniqije formulation used for the suppression of bacterial odors gnc'.loxicgasesfnsev.'agelggDpns.feedbt run-offpils, arilrrial confjnennient facilities and other.poncls containing organ ic matter or ,algae*baeleri|. GOPEftLATE may also ta used to control algaeand bacteria ih ifrigatibf! rsseryoirs, poridS; and potebls water supplies, lii still waters, COPERLATE has a vertical dispersion rate of 20 feet perhour and a horizontal dispersion rate of 25 feat per hour. In flowing waters, dispersion Is faster depending on turbulence and velocity of fiow,;Do npi apply mpraihart 1.0 ppm as metallic copper;

Note: Effectiveness of COPERLATE decreases as the alkalinity Increases, and is significantly reduced whsn Ihe alkalinity exceeds' . S . As alkalinity increases, .application rate's towards the higher end of stated lisa ranges may be .required.

Do not apply CQPERLATE to water lesslthan 40 ppm alkalinity without first doing a preliminary toxicity test on fish in the water. Perform loistest in 0 separate container. COPERLATE may be very toxic to trout arid other species in soft or acidic waters. This preliminary lasting isriesessary,

For potable water systems: if the impiaunded waler ;is a source of pptatile wcter or for potable water systems Of for live'Sti>dksystems, dip not ejibfiied one gallon ifs 60,000 galjohs und.er ariy orpurnsfehpes (1 ppm metallic copper), P.blabte water sources treated withcopperprcducls.may.be used as c'rinking v^aler only after proper additional potable v/aler trealmenls, (Review Cerieral Algae Control Sectionof this label before proceeding).

If COPERLA? E is Ib be sprayed:

Do Not apply during temperature inversions;Apply only :wheri wind Velocity favors ;6h/-ta?g.el deposilion {approximately 3 to 1 0 mph}DoNot Apply' if wind Velocity exceeds 15 inpli;Use only m¥diumcr coarse spray nozzles in boat mounted-booms, ground booms, or hand sprayers.For boat mounted bo.oms, booms shouki b« moiinled so nozzle tipis are no more lnan:2 fact above the watGr's surface

GENERAL ALGAE CONTROL: 'far algae conlrol, appfy In I ale spring or earlyisummor when algae first appsar. The dosages are variable anddepend upon algae speciles, waterhardrtess. weSe'rtemperature; ;airipurit of algae present, as well as whether waler is clear, lurbid, flowing orstatfc PrereraHyi.'the^^^^ F (15.5 ci&grees C). Higher dosages are required at lowerwater ternperattirw,.higher aigae'epncehtrations.and hard voters. Effective control df most alg?e spe'cies.cen b.e'pbtained with copper levelsbetween 0.2- 1,0 pphrrTiQtaliic copper Applida'iibn sh'ouid be dona > by.:pouriiig or sprayiriig COPERLATE DJRE'cftY FROM THE CONTAINERINTO THE LAKES. PONDS, and RSSERVOlFtS £>R iRRIGATjON CANALS. SaveraiapplicaBan points' speed up dispei'sai. In irrigation canals.the pieferred applicatipn is via the.Orip Irrigationsaiid Injection insUuctioos contained on this label. Static water requires less chemical for algaeponirpl than doe&flcw'ing water; tlss:highe"r dosages (p .control 'ch'ara.-.nltella, and filamentous; silgae (pond scum) and lower :dosages to controlplanKtdriic algae.; If inere;| :uncertaiii1y about the,.dosiasS begin jvith a lovwr, dose arid ihcrease until conlKil is Achieved or until the maximumallowable level has been reached. Do not apply more' than 1.0 ppin as metallic copper

Before treating bodies of water, consult proper state authorities such as the Fisheries; Commission or Conservation' Department <o obtain anynecessary permits. NOTE: If treated water Is to be used as a souiwe of potable v/ater, the metallic copper residual must riatexceedl ppm,

CALCULATIONS FQ$ THE AMOUNT (VOUJME IN CUBIC;FEET) OF WATER IMPOUNDEP; If the amount of water to be treated is unknown,calculate yvatelr volume as follows; (1) Obtain surface .area by rheasun'ng of regular sliaped ponds pr mapping of Irregular ponds or by referenceto previoMsiy racbrdediengrneeJinQ.data or maps. (2) Calculate average depth by ''sounding in a regular patierri and taking the mean of thesereadings or by. reference to previously obtained data. (3) ii/lultiply surfatiis araa in feet by average dap Ih in feet to obtain cubic feet of vastervolume. £4} Alternatively, multiply surface area Iri acre's, by average depth 'in fee? tb obtain total acre/feet of vyater. (5) For circular or ellipticalshaped bodies of water, volume.cBn be obtained by. mulllplylng 3:14 X the radius of the body ofwater squared (radius :X radius) X the averagedepth 1(2)

Page 3 of 6

Page 7: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

C CCALCULATION OF WATER FLOW IN DITCHES. STREAMS, AND IRRIGATION SYSTEMS: hi ditches, streams, and canal, type irrigafon °\systems the amoifnt of wate? flow in.cubic feet per second is. found by means of a weir of other measuring device. Multiply the water volume inea (I lirries';7.5 to obtain gallons. If 'ho weir or otter measuring device is aya liable, water flew arid volume can be estimated as: Average width XDepth X Velocity in feet/Sec » Cubjc Feet Per Second (CFS). Velocity can be (determined by trie time it takes for a Roaiing object to move agiven distance. This rneasuremenLshouU be rriadethres.lo four times and the results sriould be averaged. Note: i C.F.S./Hr! = 27,000 .Gats'.

CALCULATE SALLONS OF WATER TO BE TREATED AS FOLLOWS: ri}To;find the capacity of a water storage. containment or impoundedwaters in gallon?, muffipiy-tfia wate, volume in cubic feejl tlrries 7.5. cr (2) if Acre/ft calculations were used ,TiuH|ply Acre/ft by 326,000 to obtaintotal gallons of water. (3) For flowing .water, measure in Cubic Feet Per Second- 1 C.F.Si,'HR = 27,000 gallons of Water.

CALCULATIONS OF ACTIVE INGREDIENT TO BE ADDED. IF RECOMMENDED USAGE RATE IS. EXPRESSED IN PARTS PER MILLION(PPM): 1 Gallon of COPERtATE: in 80,000 gallons Of water yields 1 ppm of dissolved copper (metaiilc copper). If desired application rate isexpressed ih'pfirii: <1): Divide lotargalions to be treated by 6.0,000 to yielditotal caiibns of COPERUATE required to yield 1 ppm rtietaHic copper.(2) Mullijity the foregoing by .We de&iresd ppm treatment [evej to yield actual gallons required.- Example: 240,000 gallons |o be treated divided by60,0(30 = 4 Gallons COPERLAJE .-'to. achieve 1 ppjm metallic copper, if -a 0.2 ppm level .is fequire'd then; A X 0.2 = 0.8 Gallons GOPERLATE is

to achieve a 0.2 ppm metallic" copper ciincentration.

SPECIFIC INSTRUCi^O ISTo Cbntrol Algae in Imppundea .waters* lakeis, Ponds, and RMerypIrs: Apply. 1 pint of GOPERLATE in each 7,500-300.COO gallons ofwaier to be treated. One prit [16 oufices) of C0PERLATE pe;r each 7;50p to 300,pG-6 gallons yieWsa range of 1 ppm (7,500 gallonsj metalilccopperdowh to 6:025 ppm (300iOOO gallons) irialallibcoppar. FoV best results, apply to 'warm, still wster on a sunny clay when algae are nearthe surface.

There are several methods by .wbicli 1p..app|y CGPERLAfE <o impoundedwalei'; II may be applied from either the shoreline or from a boat. Insmaller lakes, pcihds.iand reseryoirs; ((bodies of water) shoreline application through an eleclrically or itianually operated hand spray device isprefeired. In larger lakes, ponds .and reseryoirs. application by boat or direct ihjeclion into the Influent Stream is preferred.

Shoreline Application.In srnaijer lakes, p'on ls, and .reservoirs, Cp.PE.RLATE Is most easily applied by using either ari ejecfrteally or manually operated hand spraydeyiceCsprayetf. REMWthan a spVey pattern. This will rhihirnize or elirii ihate; {he potential for any drift and enab'te you to project ihifrdisp.erised slreBm of COPERLATEfuriher-aSvay fnjfn the shore: line than ff'the spray nozzle ^e attached,: Afyvaya use: a sprayer vviiich is constructed of materials listed in theStorage and Handling Equipment listed on'thjs labiel. Qnly';use-'tWs method on'calrri days or when wind is less liian 10 mph. Never use thismeihod of 'appiicatio'ri when .wirid is'in exec's? of 16. mph or \vhen you rri Li si stand doy/n wind of ihe direction of application or. in any position thatcould expose you to drift; Never treat more than % of the bpdy of water at one tinie. Wait 10 16 14 days between applications.

1 Based ^oniyourdevsloped/kiiowlatfgepfthe^odyofwater, mark two points on opposing shorelines where, when drawing an imaginaryline-betvyeeri therh, ^the.yolurneiofwaterjson eachsiida pflriejine. Verify ,ypurwater've>!ums calculations.

2. Dalernfiinig line i 'arnpunt of CpPERLATE feguired'to ireatthe borjion ofjtiie body of water, selected in #i above. Dilution ofCpPERLAfEWinlclean water prior to applieatipn r^ay b8;dprie so that uniform 'dlstribiition is more easily accomplished.

3. Begirfning at one mark on the shoreline, sfrriiiltari bjiisly ; begin walking towards the ot h'ar rnsrk ,'wlilte projecting a. stream ofCOPERLATE^^COPERLATEso/utiOjilOia point ap;bfp'xirnateiy.5feelfrpi the:,shofe!ine.

4; When the ppposlng rn ark' has 'been reached, reverse couise and whlte.'walking.Sack to tlie beginning marh, project a strearnep'prpxfinatefy \Q feet-froro'.trie s'loreli'1,?,

5. ffepea} steps 3 &.'4, Irtcreasing.the distaripe of stream projeclion-frorn the shoreline by 5 feet each lime, until all COPERLATE isdispensed.

Boat Application;In la/ger bodies of water, probably the most satisfactory and simplest .rnethbd is to app.ly COPERLATE within the body of watest from.a Soal. Asmall pump'mountecl in the be at'can easily be used forthis purpose. iA'heri Lisihg;1h(s;riiethod, COPERLATE is 'pumped from either itso/iginalcontainer or a nurse tank;.(cpnta(ning.t of lipses) wherehbsa(sj are Irailthg bye r the side or stern (tack) of the boat artd wfjere. [Me hose outjet is just below the surface of the water. WhiteCOPERLATE may be sprayed over the surface'Df the water, application' through hoses Bliftiinatas or minimizes risk of cfriift.

if spraying, rerread abput'Spfaying: application in the General Information p.oitipn of Ihis. label. Mount spray bo'oin or nozzles so that nozzleheight ls;np more than 2.ifeerabpve' water surface. AltBrnatively, begin treatment- along the-shoreline and proceed putwi-ard until one-third <6 one-half af the ictararea iias been treated; Follow; procedure outlined for share:applicallon for lakes, ponds, arid reservoirs conlaine'd on Ihis label.

Page 4 of 6

Page 8: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

c rTo apply by boat, .the customa.ry method is to make successive parallel applications across Hie body of water where the distance between eachparallel line or application is from 20 to 200 Feel Initial application should ba made along a line following the shoreline, with subsequent lines ofapplication being parallel to the Initial line ofapplicalio 'and made progressively further away from the shoreline.

Basad on your developed knowledge of Ihe body of Water, mark two points on opposing shorelines where, when drawing an imaginaryline between thenv, not more than Kihe total voliirne of water.iyithin the lake, pond, 'or reservoir Is on each side of the line.Determine the.total amount of COPERkATE required for treating the selected p'ortion of Ihe body'of. water, (Example: 40 gallons)Determine trie djslance between your parallel lines of application.Based on the surface area of trie portion and shape of the- body of water to be Ireatedand lha intended distance between parallel linesof application -o be made, determino the number of parallel lines of application to be made. Plot these lines reasonably to scale onchart paper.Sum the length {in feet) of all parallel lines of application. The result is the total distance you will travel during application. (Example:20,oqdfeet) . . ' .',Determine the speed (in mph). at which your boat '.vifl be traveling during application and convert this to Feet Per Minute (fpm] bymultiplying rripri X 88 (Example: 5 rnph X 88 = 440 fprn) or refer to the following table:

MPH

fpm2

176

3

264

4

352

5

440

6

528

7

ei6. B704

9

792

10

880

1.

2,3.4.

5.

6.,

7. Diyide-ihe total gallons of CQPERLATE you intend tp apply lo the selected section of body cf water by the total distance, detamiiriedin #5 atibye. This resuluwill provide you the fractional g'allons of COPERLATE pec foot you will apply. (Example: 40 divided by20.000: .004 gallons/ft)

8. Multiply trie fractional gallons of C0PERLATE you w|l apply per fool as carciiialecl in #7 above times your travel speed In FPM. Thisresult 1s,th^ galions per minute (gprn) at which you must sjet your pump. (Example 44D fpm X .004 - 0.88 gpm)

9. Navigaie to your"starting point; engage ybijrpiijiip,.and begin applying COPERLATE at your Intended speed beginning close to thesho.^ellna and proceeding outward ID parallel lines of application,

10. |f, at the eiid:oFapplica|iprii all COPERLATE.requifed. for the application.has not been dispensed, return to a lire of application which,on yqijrapplicalion chart.. iSrabput :Vt ofthe way outframthe shpreline. Then, foilov;ing your navigation chart, continue* applying untilail COPERLATE has been used.

CONTROL OF ALGAE AND BACTERIAL ODOR IN SEWAGE LASOONS AND PITS (Except California): Application rates may varydepending on amounts of organic matter (sewage) in lagoons and pits. Application should be done by pouring COPERLATE directly from thecphiainer into the pil:or iasooii. Several epplicaiion ppWsspeiBd.up:disp.er5a'S. Usa one.gallon of firfl strength CQPERLATE in 60,000 gallons(4,pi30 cublcTeetJ.pf sew&ge; Fpr>est results disperse COPERLATE evenly throughoul sey/age: Bacterial odors should ha. noticeably' reducedIn 1 or 2\'»'eeks. Repeat ap'plicalion whan odors reoccui.

Feedlot Riin-off.Lagoons: Add a portion of the required dosage of COPERLATE at several locations around the.Jagocn to speed dispersal ofthe.product. A.minimum of itwo applications per year (spring and fal0;is.recommended. Addiiibnal applications iTiayibe required "as needed orwhen the lagoon is purriped. Animal Gpntainment.Prts: lf:pite are located, under Ihsconfinemert bulldingSi sidcl COPERLATE directly to thesepits, if the pits, ara outside, insert or inject GOP,ERLATE into; the Iransfer line to the. pit. Other Organic Sludges; COPERLATE must bethoroughly mixed with sludge, Apply'at ihe rate of one gallon CbPERLATE ln.30,000 gallons'bf sludge.

In Irrigation Conveyance Systems: For .continuous addition, add one pint COPERLATE for each 7,500-300,000 gailons of water. Repeal onapproximale 2-week Intervals as required. For conveyance systems longer thari 3d miles, it is reoonimended that Ihe above dosage bedispersed among injection points, every."5 to 30 mi|es. However, if the irrigation conveyance system is used for potable water, do not excesd thetotal dosage of one gallon in 56,000'gallons of water:

Sprinkler, Drip, or Other Types of irrigation Equipment: COPERLATE mus= be applied continuously for the duration of the waterapplication. Mixing Instructions for dilutions of COPERLATE are 1 pint for each 7,500 to 300,000 gallons of water. Do not mix rtith basicsubstances. No ••agitation is required;

Page 5 of 6

Page 9: rrt&* CHEMICAL SAFETY AND POLLUTIO N PREVENTIO · 2011-09-14 · use mild steei, nylon, brass, B.tornl.rium or oppper ar.piind, of tO;Stone5or handle ..full strengt h COPERLATE. Always

Drip Irrigation & Injection Instructions; Calculate Ihe amount of GOPERLATe needed to maintain Ilia drip rate for a period of 4 hours bymultiplying Pints/Hr by 4 OR Fluid Ounces/Minute; by 240. This dosage will maintain the copper level at the required ppm for 4 hours,COPERLATE must be introduced at a point of lurbulerice to. insure proper dispersion. Race the required amount of COPERLATE Into a tankequipped with a needle valve and set tlie'drip rate as required using ^ stop watch and a measuring device. Alternatively, use a chemigaljon ordpsirig device .calibrated and adjusted to inject the desired amounts of COPERLATE. Readjust as required if floiv ratss change; Distance ofcontrol will vary, freat.fnerit points should be determined in Ihe field and piacad at required intervals for control. Periodic maintenancetreatmentsmay be required.

COPERLATE DRIP OR INJECTION RATE

Water Flow Rale

CFS1

2

3

4

5

GaL/Mln.

450

900

1,350

1 ,600

2,250

Algae GrowthModerate

(1 pom as copper)

Pints/Hour

3',6'

7,2

ib:a14.4

1-8

Oz./Min,

i.o1.9

2;s3.8

4.8

Light(0.2 ppm as cop per)

Pints/Hr.

0.7

1.42.22:9

3.S

OzVMin.

0,2

0.4C.6

0.3

1.0

STORAGE AND DISPOSALProhibited, Do nol contaminate water,,- food or feed by storage or disposal.

Pe3t!cide.Storage: Store in a safe place away from pelstandKEEP OUT OF THE REACH OF CHILDREN. Store away frorn excessive heat.COPERLATE wjll freeze. "Aiw^ys^eep-cqntainer closed. Store .COPERLATE in ils original container only, Bulk COPERLATE shall be storedand handled |n stainless steel, fibergleis, polypropylene, :PVCs orgiastic equipment. Keep sway from galvanized pipe, brass, copper, and anynylon or aluminum storage han'dllng.equlprrient,

Pesticide Disposal: Excess GOPERLATE should be disposed of'through .use.. Do not contaminate lakes; rivers or streams as this may causefish kill. Pesticide wastes,are acL'leiy hazardous. Improper disposal of excess peslicide, mixture or residue is a violation of Federal Law, Ifthese w0stes,canno| 6e disposed of by use, according to labeUnslryctions,,contact your Stale Pesticide or Environmenlaf Conlrol Agency or theHazardous Waste representative at tlila oearest EPA Regional Office for guidance. In the event of a spill, neutralize with limestone or bakingedda before dis'pbsal. May deteriofate cpncrete. Dp not're-use:empty ixintainer.

Container Handling: Nonrefillable container. Do not reuse or refill this container.{For containersi greateMhah i5 gallons) TriplaTinse as follows: Empty the remaining contents into application equipment -or a mix tank, Fill thecontainer K full *fth water. Replace and.fighten closures. Tipcoritainer on iis.side and roll It back and forth, ensuring at least one completerevolution, for 3.6.:seconds. Stand the container pn'ils end and lip it back and forth several iirnes; Turn the container over onto its other end endtip it back and forth several times. Empty the rinsate into application equipment or a mix tank or store linsate for later USD or disposal. Repeatthis procedure two rindre times:(For. conlaine/s.less than or equal to 5 gallons) Triple rinse as fpllows: Empty, tlie rentsining ccnlents into application equipment or a mix tank.FilMhe container '/Vfull wittv water and recap: Shake tor 10 seconds. Pour rinsate into applicalldn equipment or a mix tank or store rinsa!e fcrI ate ruse or disposal. Drain for 10seconds after trie flow begins to drip. Repeat this procedure I'M) more times.Then offer tor rec^clhgor.recoridifioning if available, or puncture, and dispose of'in a sariiiaiy landfill, or by incineralion, or, if allowed by localauthorises by burning. If burned, stay out of smoke.

HWIITED WARRANTY AND LIMITATION OF REWIEDIES

To the: extent consistent with applicable law: Seller warrants that the product conforms to the chemical description and is reasonably fit for thepurpose slated on the label for the use under normal conditions bui makes no ether warranties of FITNESS OR MERCHANTABILITY,expressed or Implied, or any olher warranty if Ihe product is used contrary to the label instructions, or under abnormal conditions or underconditions not foreseeable to the seller. In ho case shall the seller be liable for more than Ins cost of this product lo the buyer and will, in noevent, ba liable for any cdnsijquenliai, special or indirect damages (Including lost profits) connected wilh the use or handling of this product.This product is offered and the buyer or user accepts it subject to the foregoing terms which may not be varied.

Page 6 of 6