ry, - oneontaemployees.oneonta.edu/gallagkr/chem112_s10/lecture4_notes.pdf · chem llz...

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CHEM LLz Thermalsnergryr and Phase Ghanges rA q' fanua ry ZT,ZLLA f,.:)tu si}.,.;) 'Lr.xrf sl lr I -l HFs {u a, s tr $ F ,.r{F ETAMPLE: How m1lh total energy does it take to convert 40.0 g of ice at -.30 oC to steam at l2S oC? D.atE .y.pu.nsed tg knqw: AHn'. s ggg llg AH.*ap = 2gSA!/g Ci** a f,,06 Ilg*C C**to = {. tS y/gdC Heat ice to rnelting point Q_= Tn 'e , .Nf' 40J' t,# . (O.C + 3ot") : TqqL T Melt ice Yt q= AHr.*.,14 = ry, ,-.lo,OJ = l332OS Heat water to boiting point t' 1= ?n,c ./.f "- '{OJ,tdry , ('*'C - 0"c)= ltaTTDf Vaporize water \ t= Aft" np""fr= /e5to5$' tlog = lor+o5 Heat steam to te$ oC Q : rn ,f , a:r F t{t},Oq ., }$"t"f , L 'll \* r->' J W .J C*t*a* = l.ge J/g*C es"rya- 133 ec, tb?sc' to&qc' lq##' ..*.* {'trb to#"c ): r?ster vapsr AFlv*f Liquid wntsr and vffpsr {vaBorieetion} i f*dr*n\ w#,rluinq KE + AT= f 'r# Liquid wat$r h-t6*} lcs and fiquid wnter{melting} Hest added {ea*h divisisn ssrrsspsnds ts 4 kJ} l?L* 5 ri'r 6+Lr

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Page 1: ry, - Oneontaemployees.oneonta.edu/gallagkr/CHEM112_S10/lecture4_notes.pdf · CHEM LLz Thermalsnergryr and Phase Ghanges rA q' fanua ry ZT,ZLLA f,.:)tu si}.,.;) 'Lr.xrf sl lr I HFs-l

CHEM LLz

Thermalsnergryr and Phase Ghanges

rA q'

fanua ry ZT,ZLLAf,.:)tu si}.,.;)

'Lr.xrf

sllrI

-lHFs{ua,str$F ,.r{F

ETAMPLE: How m1lh total energy does it take to convert 40.0 g of ice at -.30oC to steam at l2S oC?D.atE .y.pu.nsed tg knqw:AHn'. s ggg llg AH.*ap = 2gSA!/gCi** a f,,06 Ilg*C C**to = {. tS y/gdCHeat ice to rnelting point

Q_= Tn 'e , .Nf' 40J' t,# . (O.C + 3ot") : TqqL TMelt ice Yt

q= AHr.*.,14 = ry, ,-.lo,OJ = l332OSHeat water to boiting point t'

1= ?n,c ./.f "- '{OJ,tdry , ('*'C - 0"c)= ltaTTDfVaporize water \

t= Aft" np""fr= /e5to5$' tlog = lor+o5Heat steam to te$ oC

Q : rn ,f , a:r F t{t},Oq ., }$"t"f ,L 'll \* r->' J W.J

C*t*a* = l.ge J/g*C

es"rya-133 ec,tb?sc'to&qc'

lq##' ..*.*

{'trb to#"c ):

r?ster vapsr

AFlv*fLiquid wntsr and vffpsr{vaBorieetion}

if*dr*n\ w#,rluinq KE + AT= f'r#Liquid wat$r

h-t6*} lcs and fiquid wnter{melting}

Hest added {ea*h divisisn ssrrsspsnds ts 4 kJ}

l?L* 5ri'r 6+Lr

Page 2: ry, - Oneontaemployees.oneonta.edu/gallagkr/CHEM112_S10/lecture4_notes.pdf · CHEM LLz Thermalsnergryr and Phase Ghanges rA q' fanua ry ZT,ZLLA f,.:)tu si}.,.;) 'Lr.xrf sl lr I HFs-l

CHEM LLz |anuary 27,2AIA

$lickef Ouestion:S0g of ethanol is at 20oC. I add 6385J of heat. What is the frnal temperatureand state of the ethanol? (Tup=?g.4oC, Ce.ohE l.4$/g-oC, Afloo=g3i.ayg>

UUgf Jot +?B,q"C

q* AH-* . fn 3

t-B3?,*J & 5t # q{,84*s

{*5_Lf" {v*,$r*J$.f,) " q,f Tn, bs,fs.{' ffi,4

sS*,grr+fd u*, I {k b eSnS

-.:{ } ?*53-;.*l sf

Celprimetqr H 6 *l. Constant Pressure

Gve s *Fl

f . ^ r- -t*. urr fi]"ri?€-n#+ €-not4qh {-s vnt€TT',S* g.r{t

""M-o I'qp'd & 1S'4*C'"-+-0 tt;*f'Wle #*

t Zerp rtn c&n*br*{ P ni*v"s-*.'-mn

fpf

Thermomet€rThts

&fi

rrf n'-

Y, 'rri

Al-t * f

r a1,C-'AT.*-".trildry*A, f;$rrl-1 #6

U

nl3 Jc*tes t-YUr45*trfr{dbi_.d*"':r !'dt,#ai*'+dt

t

nftde3 n****l*ff

***JSJ- " aTslq

-lffiS

{$q: e4,t#&3f*{#

m.0= trq #,H)5t' ': * f.{.Dt

Page 3: ry, - Oneontaemployees.oneonta.edu/gallagkr/CHEM112_S10/lecture4_notes.pdf · CHEM LLz Thermalsnergryr and Phase Ghanges rA q' fanua ry ZT,ZLLA f,.:)tu si}.,.;) 'Lr.xrf sl lr I HFs-l

CHEM LLz

'1d f,tf.*^{t= ,;- I

|anuary 27,2010

fPach\ns fnct udL (flonYz^der I7,.

,'d*d.;'

t-v,''n -

v

' ;,,i''fr.#i* n''

i' ""'!r.. '} **.*{it--t!1 :t, i

{1l*:*';. . Y,"j

i -'-

il .*,- i't''"'J'" i

"tr r'l{t

i F.'J ,'' *T*i.+'") :j **.- \i

| *'-

f'""=- T:I

exothermic endothermicAT + 'iffi

AHr*"ctlon rq$'s +{[system {Frl{trF .*+-

*

![snrroundings tt

f

34dF.*f:jlt+s

Cwstar*

Hesst lrawF Enthalpy is a state function.) rf a reaction can be rwitten as the sum of two or more

reactions, the AH for the net reaction is the sum of theAH's for the individual steps.

> rf a reaction is reversed, the sign of AH is reversed.F If the coefficients of the reactants/products are multiplied

by a number, then the AH must be multiplied by thatnumber, as well.