safety data sheet for chemical products · 2016. 11. 23. · safety data sheet for chemical...

1/4 Creation Date : February 13, 2013

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UMN-138 Black [ uni-ball Signo RT ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363

Creation Date : February 13, 2013Revision DateFile No. : 068244A Rev.2.5.01.01

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Information of components.

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

[Ink quantity of product : about 0.4g]

MAJOR HEALTH HAZARDS: suspect cancer hazard (in animals)

Resins

Additives


5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.Extinguishing media:

Suitable : regular dry chemical, carbon dioxide, water, regular foam.Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.Environmental precautions : Do not wash away into shower or water way.Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Don't shake.

: Keep out of the reach of infants.

: Avoid contact with skin and eyes.

Precautions : Not available.Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Packaging materials : Not applicable.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHAACGIHEC

Personal protective equipment : Not required.

3.5mg/m3 TWA Carbon Black

oxidizing materials, halogens Carbon Black



-UMN-138_Black-


9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state : Liquid.Color : Black.Odor : None odor.pH : about 8.0Boiling point : Not available. [Water/ 100 C]Melting point : Not available.Flash point : Not available.Autoignition temperature : Not available.Explosion limits : Not applicable.Density : about 1.1 / 25 CVapor density (air=1) : Not available.Solubility in water : Not available.Evaporation rate : Not available.Volatile : 70-73%

10. STABILITY AND REACTIVITY

Stability : Stability.Hazardous reactions : Will not occur.Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Hazardous decomposition products : (Information of components.)

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptoms of overexposure and aggravated by exposure

InhalationSkin contactEye contact

Ingestion

Specific effects

Carbon Blackirritation

Carbon Black

Carbon BlackIrritant;inhalation, skin

Carbon Blackmechanical irritation,

discoloration of lids


Carbon BlackIARC Group 2B

Not available.

Carbon Black>3000mg/kg-Rabbit

Not available.

Carbon Black>10000mg/kg-Rat

Carbon Black

common decomposition products

oxidizing materials, halogens

sulfur compounds

oxides of carbon, water

Lungs may be affected by repeated or prolonged exposure at

very high concentrations.

Carbon Black

-UMN-138_Black-


12. ECOLOGICAL INFORMATION

Not available.

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Carbon Black

EU labeling : Noｔ restricted.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over Carbon Black

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (February 13, 2013). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UMN-138_Black-




Product name: UMN-138 Blue [ uni-ball Signo RT ]











Inhalation:

Skin contact:


Eye contact:

Ingestion:














: Don't shake.





high temperature.





acids, bases, combustible materials,

halo carbons, metals, metal salts,

oxidizing materials, reducing agents

1,2-Propanediol

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

If swallowed, seek medical advice, and show the MSDS to the physician then.

acids, metals, oxidizing materials Triethanolamine

-UMN-138_Blue-





OSHAACGIHEC




Physical state : Liquid.Color : Blue.Odor : None odor.pH : about 8.0Boiling point : Not available. [Water/ 100 C]Melting point : Not available.Flash point : Not available. [1,2-Propanediol/ 99 C]Autoignition temperature : Not available. [1,2-Propanediol/ 371 C]Explosion limits : Not applicable.

[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% ]

Density : about 1.1 / 25 CVapor density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]Solubility in water : Not available.Evaporation rate : Not available.Volatile : 72-75%


Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.Avoid contact with incompatible materials.



Not available.

Not available.

Not available.

Triethanolamineacids, metals, oxidizing materials

1,2-Propanediolacids, bases, combustible materials, halo

carbons, metals, metal salts, oxidizing

materials, reducing agents

Triethanolamineoxides of nitrogen.

common decomposition productsoxides of carbon, water

-UMN-138_Blue-




Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects



Inhalation

Skin contact

Eye contact

Ingestion

Specific effects


Not available.





HS Code : 960810

TriethanolamineIrritant;skin, eye

1,2-Propanediol20800mg/kg-Rabbit

TriethanolamineRepeated or prolonged contact may cause skin sensitization.

1,2-PropanediolRepeated or prolonged contact may cause skin sensitization.

Triethanolaminesore throat,difficulty breathing

1,2-Propanediolnausea,headache

irritation,pain

Triethanolamineirritation,redness

1,2-Propanediolirritation,allergic reaction

TriethanolamineIARC Group 3

Triethanolamineburns,gastrointestinal irritation

1,2-Propanediolallergic reaction,vomiting

Triethanolamineirritation,corneal swelling

1,2-Propanediol

20000mg/kg-Rat

Triethanolamine>16mL/kg-Rat

Not available.

Triethanolamine2200mg/kg-Rabbit

5846mg/kg-Mouse

1,2-Propanediol

-UMN-138_Blue-



Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Triethanolamine


CANADA Hazardous Products Act - Ingredient Disclosure List1%over 1,2-Propanediol/ Triethanolamine








-UMN-138_Blue-




Product name: UMN-138 Red [ uni-ball Signo RT ]











Inhalation:

Skin contact:

2034733

Coloring agent Registered

Registered Registered 10- 30

Resins Registered Registered


Eye contact:

Ingestion:














: Don't shake.





high temperature.







oxidizing materials, bases, acids,

reducing agents, metals

Ethylene glycol




1,2-Propanediol

-UMN-138_Red-





OSHAACGIHEC




Physical state : Liquid.Color : Red.Odor : None odor.pH : about 8.0Boiling point : Not available. [Water/ 100 C]Melting point : Not available.Flash point : Not available. [1,2-Propanediol/ 99 C]Autoignition temperature : Not available. [1,2-Propanediol/ 371 C]Explosion limits : Not applicable.









ceiling 100mg/m3 (particulate)(aerosol) Ethylene glycol

Not available.

Ethylene glycol

acids, bases, combustible materials, halo



oxidizing materials, bases, acids, reducing

agents, metals

52mg/m3(20ppm) TWA(skin)

104mg/m3(40ppm) STEL(skin)Ethylene glycol


1,2-Propanediol

-UMN-138_Red-




Acute toxicity

Ingestion LD50


Local effects



Inhalation

Skin contact

Eye contact

Ingestion

Specific effects


Not available.





HS Code : 960810

1,2-Propanediol

Ethylene glycol

Repeated or prolonged contact may cause skin sensitization .

The substance may have effects on the central nervous

system, resulting in abnormal eye movements (nystagmus).

1,2-Propanediol

Ethylene glycol

nausea,headache

irritation,cough

1,2-Propanediol

Ethylene glycol

irritation,allergic reaction

irritation,dry

1,2-Propanediol

Ethylene glycol

irritation,pain

irritation,redness

Not available.

1,2-Propanediol

Ethylene glycol

allergic reaction,vomiting

nausea,vomiting

Irritant;inhalation, skin, eye

20000mg/kg-Rat

Ethylene glycol

Ethylene glycol


Not available.

9530uL/kg-Rabbit

Ethylene glycol1650mg/kg-Cat

4700mg/kg-Rat

1,2-Propanediol

-UMN-138_Red-



Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Ethylene glycol

EU labeling25%




Product name: UMN-138 Orange [ uni-ball Signo RT ]











Inhalation:

Skin contact:


Eye contact:

Ingestion:














: Don't shake.





high temperature.









Ethylene glycol

acids, bases, oxidizing materials, metal

oxides, peroxides, reducing agents

Glycerine

-UMN-138_Orange-





OSHA

ACGIH

EC




Physical state : Liquid.Color : Orange.Odor : None odor.pH : about 8.0Boiling point : Not available. [Water/ 100 C]Melting point : Not available.Flash point : Not available.Autoignition temperature : Not available.Explosion limits : Not applicable.Density : about 1.1 / 25 CVapor density (air=1) : Not available.Solubility in water : Not available.Evaporation rate : Not available.Volatile : 77-80%







5mg/m3 TWA(respirable dust fraction)

15mg/m3 TWA (total dust)Glycerine



ceiling 100mg/m3 (particulate)(aerosol) Ethylene glycol10mg/m3 TWA(mist) Glycerine

Glycerineacids, bases, oxidizing materials, metal oxides,

peroxides, reducing agents

Ethylene glycoloxidizing materials, bases, acids, reducing

agents, metals

Glycerinecorrosive acrolein.


-UMN-138_Orange-




Acute toxicity

Ingestion LD50


Local effects



InhalationSkin contact

Eye contact

Ingestion

Specific effects


Not available.





HS Code : 960810

Ethylene glycolThe substance may have effects on the central nervoussystem, resulting in abnormal eye movements (nystagmus).

Glycerine

9530uL/kg-Rabbit

>10000mg/kg-Rabbit


irritation,redness

Ethylene glycolirritation,dry

Glycerineirritation,difficulty breathing

Not available.

Ethylene glycol / Glycerinenausea,vomiting

Glycerinetearing,stinging

Ethylene glycolirritation,redness

Glycerine

Ethylene glycol

Ethylene glycol

Glycerine>570mg/m3-1H-Rat

Ethylene glycol

Glycerine

1650mg/kg-Cat

4700mg/kg-Rat

4090mg/kg-Mouse

-UMN-138_Orange-



Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Ethylene glycol / Glycerine

EU labeling25%




Product name: UMN-138 Blue black [ uni-ball Signo RT ]











Inhalation:

Skin contact:

Registered

Registered

Resins

Carbon Black

Registered Registered

1,2-Propanediol 57-55-6 Registered 2003380

Coloring agent Registered Registered

range (wt%)


Eye contact:

Ingestion:














: Don't shake.





high temperature.








1,2-Propanediol



oxidizing materials, halogens Carbon Black

-UMN-138_Blue black-





OSHAACGIHEC




Physical state : Liquid.Color : Blue black.Odor : None odor.pH : about 8.0Boiling point : Not available. [Water/ 100 C]Melting point : Not available.Flash point : Not available. [1,2-Propanediol/ 99 C]Autoignition temperature : Not available. [1,2-Propanediol/ 371 C]Explosion limits : Not applicable.









3.5mg/m3 TWA Carbon Black3.5mg/m3 TWA Carbon Black3.5mg/m3 TWA Carbon Black




Carbon Blackoxidizing materials, halogens


Carbon Blacksulfur compounds





Acute toxicity

Ingestion LD50


Local effects



Inhalation

Skin contact

Eye contact

Ingestion

Specific effects


Not available.





HS Code : 960810

1,2-Propanediol20000mg/kg-Rat

Carbon Black>10000mg/kg-Rat

Not available.


Carbon BlackIrritant;inhalation, skin

Carbon Black>3000mg/kg-Rabbit


Carbon BlackLungs may be affected by repeated or prolonged exposure atvery high concentrations.





1,2-Propanediolirritation,pain

Carbon Blackmechanical irritation,

discoloration of lids

1,2-Propanediolallergic reaction,vomiting

Carbon BlackIARC Group 2B




Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Carbon Black


CANADA Hazardous Products Act - Ingredient Disclosure List1%over Carbon Black












Product name: UMN-138 Light blue [ uni-ball Signo RT ]











Inhalation:

Skin contact:

Eye contact:

Ingestion:















: Don't shake.





high temperature.








OSHA

ACGIHEC





1,2-Propanediol





Glycerine

Not available.

10mg/m3 TWA(mist) Glycerine

-UMN-138_Light blue-




Physical state : Liquid.Color : Black.Odor : None odor.pH : about 8.5Boiling point : Not available. [Water/ 100 C]Melting point : Not available.Flash point : Not available. [1,2-Propanediol/ 99 C]Autoignition temperature : Not available. [1,2-Propanediol/ 371 C]Explosion limits : Not applicable.











Acute toxicity

Ingestion LD50


Local effects









>570mg/m3-1H-Rat

Glycerine4090mg/kg-Mouse

1,2-Propanediol


Not available.

20000mg/kg-Rat

Glycerine>10000mg/kg-Rabbit


Glycerine




Inhalation

Skin contactEye contact

Ingestion

Specific effects


Not available.





HS Code : 960810


Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine


CANADA Hazardous Products Act - Ingredient Disclosure List1%over 1,2-Propanediol












1,2-Propanediolirritation,pain

Not available.

1,2-Propanediol

Glycerine


nausea,vomiting





Product name: UMN-138 Lavender black [ uni-ball Signo RT ]











Inhalation:

Skin contact:

Eye contact:

Ethylene glycol 107-21-1 Registered 2034733

56-81-5 Registered 2002895


Ingestion:














: Don't shake.





high temperature.








1,2-Propanediol




Ethylene glycol



Glycerine

-UMN-138_Lavender black -





OSHA

ACGIH

EC




Physical state : Liquid.Color : Lavender black.Odor : None odor.pH : about 8.5Boiling point : Not available. [Water/ 100 C]Melting point : Not available.Flash point : Not available. [1,2-Propanediol/ 99 C]Autoignition temperature : Not available. [1,2-Propanediol/ 371 C]Explosion limits : Not applicable.
















1,2-Propanediol

Ethylene glycol





agents, metals







Acute toxicity

Ingestion LD50


Local effects



Inhalation

Skin contact

Eye contact

Ingestion

Specific effects


Not available.





HS Code : 960810

1,2-Propanediol

20800mg/kg-Rabbit


Ethylene glycol

Glycerine

1650mg/kg-Cat

4700mg/kg-Rat

4090mg/kg-Mouse

1,2-Propanediol

Ethylene glycol

Repeated or prolonged contact may cause skin sensitization.




1,2-Propanediol

Ethylene glycol

nausea,headache

irritation,cough

Glycerineirritation,redness

1,2-Propanediol

Ethylene glycol


irritation,dry

tearing,stinging

1,2-Propanediol

Ethylene glycol

irritation,pain

irritation,redness

No data available.

1,2-Propanediol

Ethylene glycol / Glycerine


nausea,vomiting

Glycerine


20000mg/kg-Rat

Ethylene glycol

Ethylene glycol

Glycerine

9530uL/kg-Rabbit

>10000mg/kg-Rabbit

1,2-Propanediol





EU labeling25%




Product name: UMN-138 Pink [ uni-ball Signo RT ]











Inhalation:

Ethylene glycol 107-21-1 Registered 2034733

1-Propanol,2-amino-2-methyl 124-68-5


Skin contact:

Eye contact:

Ingestion:














: Don't shake.





high temperature.



Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.



-UMN-138_Pink-







OSHA

ACGIH

EC




Physical state : Liquid.Color : Pink.Odor : None odor.pH : about 8.5Boiling point : Not available. [Water/ 100 C]Melting point : Not available.Flash point : Not available. [1,2-Propanediol/ 99 C]Autoignition temperature : Not available. [1,2-Propanediol/ 371 C]Explosion limits : Not applicable.










1,2-Propanediol



Ethylene glycol



Glycerine



acids, oxidizing materials 1-Propanol,2-amino-2-methyl




-UMN-138_Pink-






Acute toxicity

Ingestion LD50


Local effects



Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

Ethylene glycol / 1-Propanol,2-amino-2-methyl



1,2-Propanediol

Ethylene glycol





agents, metals


1-Propanol,2-amino-2-methylacids, oxidizing materials

1,2-Propanediol

1-Propanol,2-amino-2-methyloxides of nitrogen.


Ethylene glycol

Glycerine

1650mg/kg-Cat

4700mg/kg-Rat

4090mg/kg-Mouse


1-Propanol,2-amino-2-methyl2150mg/kg-Mouse

1,2-Propanediol

Ethylene glycol

Repeated or prolonged contact may cause skin sensitization.




1,2-Propanediol

Ethylene glycol

1-Propanol,2-amino-2-methyl

nausea,headache

irritation,cough

1,2-Propanediol

Ethylene glycol


irritation,dry

1-Propanol,2-amino-2-methylirritation,burn

Glycerineirritation,redness

1,2-Propanediol

Ethylene glycol

irritation,pain

irritation,redness

1-Propanol,2-amino-2-methylirritation,eye damage


Not available.

1-Propanol,2-amino-2-methylsensation,headache

1,2-Propanediol

Ethylene glycol / Glycerine


nausea,vomiting


20000mg/kg-Rat

Ethylene glycol

Glycerine

9530uL/kg-Rabbit

>10000mg/kg-Rabbit


-UMN-138_Pink-



Not available.





HS Code : 960810



EU labeling25%

safety data sheet for chemical products · 2016. 11. 23. · safety data sheet for chemical...

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