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Safety data sheet

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BASF Safety data sheet Date / Revised: 11.05.2013 Version: 2.0 Product: 35-M00 3,5L BASECOAT CONVERTER

(30284332/SDS_GEN_NZ/EN) Date of print 11.05.2013

1. Substance/preparation and company identification

35-M00 3,5L BASECOAT CONVERTER Manufacturer/supplier: BASF Australia Limited (ABN 62 008 437 867) Level 12, 28 Freshwater Place Southbank Victoria 3006, AUSTRALIA Contact address: BASF New Zealand Limited 3 Airpark Drive, Airport Oaks, Manukau P.O. Box 407, Auckland 1015 NEW ZEALAND Telephone: +64 9 255-4300 Telefax number: +64 9 255-4307 Emergency information: National Poisons Centre: 0800 764 766 BASF Emergency Advice Number: 0800 944 955 (24 hour advice in an emergency only) BASF Emergency Advice Number: +61 3 8855 6666 (If calling from outside New Zealand)

2. Hazard identification

Classification: Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001 (New Zealand)

Subclasses: Subclass 3.1 Category C - Substance that are flammable liquids Subclass 6.1 Category E - Substance which are acutely toxic Subclass 6.3 Category B - Substance which are skin irritants Subclass 6.4 Category A - Substance which are eye irritants

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3. Composition/information on ingredients

Chemical nature acrylic resin, polyester resin, cellulose ester, organic solvent Hazardous ingredients ethylbenzene

Content (W/W): >= 1 % - < 2 % CAS Number: 100-41-4 EC-Number: 202-849-4 INDEX-Number: 601-023-00-4 Hazard symbol(s): F, Xn, Xi R-phrase(s): 11, 20, 36/37/38, 48/20, 65

4-methylpentan-2-one

Content (W/W): >= 20 % - < 25 % CAS Number: 108-10-1 EC-Number: 203-550-1 INDEX-Number: 606-004-00-4 Hazard symbol(s): F, Xn R-phrase(s): 11, 20, 36/37, 66

n-Butyl acetate

Content (W/W): >= 50 % - < 75 % CAS Number: 123-86-4 EC-Number: 204-658-1 INDEX-Number: 607-025-00-1 R-phrase(s): 10, 66, 67

Propanoic acid, 3-ethoxy-, ethyl ester

Content (W/W): >= 3 % - < 5 % CAS Number: 763-69-9 EC-Number: 212-112-9

xylene

Content (W/W): >= 5 % - < 7 % CAS Number: 1330-20-7 EC-Number: 215-535-7 INDEX-Number: 601-022-00-9 Hazard symbol(s): Xn R-phrase(s): 10, 20/21, 38

The wording of the hazard symbols and R-phrases is specified in section 16 if dangerous ingredients are mentioned.

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4. First-Aid Measures

General advice: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If inhaled: Remove affected person from danger area. Keep warm, calm and covered up. If breathing is irregular or stopped, administer artificial respiration. Seek medical assistance. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). On skin contact: Remove contaminated clothing. Wash skin with soap and water, rinse abundantly. Do NOT use solvents or thinners. On contact with eyes: Contact lenses should be removed. Hold eyelids open and flush with copious amounts of clean, fresh water or a special eyewash solution. Seek medical assistance. On ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting.

5. Fire-Fighting Measures

Suitable extinguishing media: Foam (alcohol resistant), carbon dioxide, powders, water spray. Do not allow run-off from fire fighting to enter drains or water courses. Unsuitable extinguishing media for safety reasons: water jet Specific hazards: Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health. Special protective equipment: Appropriate breathing apparatus may be required. Further information: Cool closed containers in the vicinity of the source of fire.

6. Accidental Release Measures

Personal precautions: Avoid contact with skin and eyes. Keep away from sources of ignition. Avoid inhalation of vapour and spray mist. Ensure adequate ventilation. Avoid breathing vapours.

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Environmental precautions: Do not allow to enter drains or waterways. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environment Agency. Methods for cleaning up or taking up: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for diposal according with the waste regulations (see section 13). Clean preferably with a detergent; avoid the use of solvents.

7. Handling and Storage

Handling

Avoid contact with skin and eyes. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Avoid inhalation of dust from sanding. Smoking, eating and drinking are forbidden in application area. For personal protection see section 8. Comply with the health and safety at work laws. Product may charge electrostatically: always use earthing leads when transferring from one container to another and earth containers. It is recommended that operators should wear antistatic clothing and footwear. When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits. Solvent vapours are heavier than air and spread along floors. Vapour forms explosive mixtures with air. Keep container dry and tightly closed in a cool well-ventilated place. Avoid all sources of ignition: heat, sparks, open flame. Avoid inhalation of vapour and spray mist. Do not use any sparking tools.

Storage

Keep away from oxidising agents, from strongly alkaline and strongly acid materials. Suitable materials for containers: carbon steel (iron), tin (tinplate) Further information on storage conditions: Electrical equipment must be explosion-proof to the appropriate standard. Floors must be of conducting type and impermeable to the materials being stored. Keep container tightly closed. Never use pressure to empty; container is not a pressure vessel. Close containers carefully once opened and store upright in order to prevent any leakage. No smoking. Prevent unauthorized access. Detailed information can be gained from the relevant technical data sheets. Always keep in containers of same material as the original one. Observe label precautions. Store in a dry, well ventilated place. Protect from direct sunlight. Keep away from sources of ignition. Keep away from heat. Storage stability: Storage temperature: 5.00 - 35.00 °C

8. Exposure controls and personal protection

Components with occupational exposure limits

ethylbenzene, 100-41-4;

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TWA value 100 ppm (ACGIHTLV) STEL value 125 ppm (ACGIHTLV) TWA value 434 mg/m3 ; 100 ppm (OEL (NZ)) STEL value 543 mg/m3 ; 125 ppm (OEL (NZ))

4-methylpentan-2-one, 108-10-1; TWA value 20 ppm (ACGIHTLV)

STEL value 75 ppm (ACGIHTLV) TWA value 205 mg/m3 ; 50 ppm (OEL (NZ)) STEL value 307 mg/m3 ; 75 ppm (OEL (NZ)) (OEL (NZ)) Exposure can also be estimated by biological monitoring.

n-Butyl acetate, 123-86-4; TWA value 150 ppm (ACGIHTLV)

STEL value 200 ppm (ACGIHTLV) TWA value 713 mg/m3 ; 150 ppm (OEL (NZ)) STEL value 950 mg/m3 ; 200 ppm (OEL (NZ))

xylene, 1330-20-7; TWA value 100 ppm (ACGIHTLV)

STEL value 150 ppm (ACGIHTLV) TWA value 217 mg/m3 ; 50 ppm (OEL (NZ))

Personal protective equipment

Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres.

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General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.

9. Physical and Chemical Properties

Form: liquid Colour: colourlessOdour: specific boiling temperature: 114.00 - 165.00 °C Flash point: 23 °C

The product burns self-sustainingly

Flammability: not applicable Lower explosion limit: 36 g/m3 Vapour pressure: 2.00 hPa

(20 °C)

Density: 0.882 g/cm3 Miscibility with water:

immiscible

Viscosity, kinematic: 36.0 mm2/s Flow time: > 30 s (DIN EN ISO 2431; 4 mm)

10. Stability and Reactivity Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. The product is stable if stored and handled as prescribed/indicated. When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.

11. Toxicological Information Acute toxicity

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Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.

12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC and is not classified as dangerous for the environment. Do not allow to enter drains or waterways.

13. Disposal Considerations

Observe national and local legal requirements. Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. Dispose of in accordance with national, state and local regulations.

14. Transport Information

Domestic transport: Hazard class: 3 Packing group: III ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT Further information Hazchem Code:3Y IERG Number:14

Sea transport IMDG

Hazard class: 3

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Packing group: III ID number: UN 1263 Hazard label: 3 Marine pollutant: NO Proper shipping name: PAINT

Air transport IATA/ICAO

Hazard class: 3 Packing group: III ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT

15. Regulatory Information



Other regulations

Registration status: NZIOC, NZ released / listed GrpStd HSR002662

16. Other Information

Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: F Highly flammable. Xn Harmful. Xi Irritant. 11 Highly flammable. 20 Harmful by inhalation.

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36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure

through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin.

Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

Safety data sheet

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BASF Safety data sheet Date / Revised: 11.04.2013 Version: 1.0 Product: 35-M1990 0,5L BASECOAT



35-M1990 0,5L BASECOAT Manufacturer/supplier: BASF Australia Limited (ABN 62 008 437 867) Level 12, 28 Freshwater Place Southbank Victoria 3006, AUSTRALIA Contact address: BASF New Zealand Limited 3 Airpark Drive, Airport Oaks, Manukau P.O. Box 407, Auckland 1015 NEW ZEALAND Telephone: +64 9 255-4300 Telefax number: +64 9 255-4307 Emergency information: National Poisons Centre: 0800 764 766 BASF Emergency Advice Number: 0800 944 955 (24 hour advice in an emergency only) BASF Emergency Advice Number: +61 3 8855 6666 (If calling from outside New Zealand)



Subclasses: Subclass 3.1 Category C - Substance that are flammable liquids Subclass 6.1 Category E - Substance which are acutely toxic Subclass 6.3 Category A - Substance which are skin irritants Subclass 6.4 Category A - Substance which are eye irritants

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Chemical nature resin modified, fillers, polyester resin, cellulose ester, organic solvent, pigment Hazardous ingredients ethylbenzene



Content (W/W): >= 12.5 % - < 15 % CAS Number: 108-10-1 EC-Number: 203-550-1 INDEX-Number: 606-004-00-4 Hazard symbol(s): F, Xn R-phrase(s): 11, 20, 36/37, 66

n-Butyl acetate


xylene

Content (W/W): >= 10 % - < 12.5 % CAS Number: 1330-20-7 EC-Number: 215-535-7 INDEX-Number: 601-022-00-9 Hazard symbol(s): Xn R-phrase(s): 10, 20/21, 38

graphite

Content (W/W): >= 5 % - < 7 % CAS Number: 7782-42-5 EC-Number: 231-955-3

stoddard solvent

Content (W/W): >= 0.1 % - < 0.2 % CAS Number: 8052-41-3 Hazard symbol(s): Xn, N R-phrase(s): 10, 51/53, 65, 66, 67


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Handling

Avoid contact with skin and eyes. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Avoid inhalation of dust from sanding. Smoking, eating and drinking are forbidden in application area. For personal protection see section 8. Comply with the health and safety at work laws. Product may charge electrostatically: always use earthing leads when transferring from one container to another and earth containers. It is recommended that operators should wear antistatic clothing and footwear. When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits. Solvent vapours are heavier than air and spread along floors. Vapour forms explosive mixtures with air. Keep container dry and tightly closed in a cool well-ventilated place. Avoid all sources of ignition: heat, sparks, open flame. Avoid inhalation of vapour and spray mist. Do not use any sparking tools. Protection against fire and explosion: Use antistatic tools. Exhaust fans should be explosion proof. Provide adequate ventilation to remove solvent vapors from lower levels or work areas and to prevent solvent contact with ignition sources. Sealed containers should be protected against heat as this results in pressure build-up. Risk of explosion if heated under confinement. Avoid all sources of ignition: heat, sparks, open flame.

Storage

Keep away from oxidising agents, from strongly alkaline and strongly acid materials. Suitable materials for containers: carbon steel (iron), tin (tinplate) Further information on storage conditions: Electrical equipment must be explosion-proof to the appropriate standard. Floors must be of conducting type and impermeable to the materials being stored. Keep container tightly closed. Never use pressure to empty; container is not a pressure vessel. Close containers carefully once opened and store upright in order to prevent any leakage. No smoking. Prevent unauthorized access. Detailed information can be gained from the relevant technical data sheets. Always keep in containers of same material as the original one. Observe label precautions. Store in a dry, well ventilated place. Protect from direct sunlight. Keep away from sources of ignition. Keep away from heat. Storage stability: Consult local fire marshal for storage requirements. Storage temperature: 5.00 - 35.00 °C

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ethylbenzene, 100-41-4; TWA value 100 ppm (ACGIHTLV)








graphite, 7782-42-5; TWA value 2 mg/m3 (ACGIHTLV), Respirable fraction

TWA value 3 mg/m3 (OEL (NZ)), Respirable dust

stoddard solvent, 8052-41-3; TWA value 100 ppm (ACGIHTLV)

TWA value 525 mg/m3 ; 100 ppm (OEL (NZ))


Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components.

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The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn. Contact lenses should not be worn. Remove contaminated clothing. Contaminated equipment or clothing should be cleaned after each use or disposed of. Hands and/or face should be washed before breaks and at the end of the shift.


Form: liquid Colour: black Odour: of the solvent contained in the product specific Boiling range:

not applicable

Flash point: 23 °C


Flammability: not applicable Lower explosion limit: 36 g/m3 Density: 0.942 g/cm3 Relative density: 0.9540

(20 °C)

Miscibility with water:

immiscible


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11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------

12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways.

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Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: stoddard solvent ----------------------------------





Sea transport IMDG

Hazard class: 3 Packing group: III ID number: UN 1263 Hazard label: 3 Marine pollutant: NO Proper shipping name: PAINT



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Other regulations



Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: F Highly flammable. Xn Harmful. Xi Irritant. N Dangerous for the environment. 11 Highly flammable. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure

through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment. Vertical lines in the left hand margin indicate an amendment from the previous version.

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The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

Safety data sheet

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BASF Safety data sheet Date / Revised: 06.04.2013 Version: 1.1 Product: 35-M1920 1L BASECOAT



35-M1920 1L BASECOAT Manufacturer/supplier: BASF Australia Limited (ABN 62 008 437 867) Level 12, 28 Freshwater Place Southbank Victoria 3006, AUSTRALIA Contact address: BASF New Zealand Limited 3 Airpark Drive, Airport Oaks, Manukau P.O. Box 407, Auckland 1015 NEW ZEALAND Telephone: +64 9 255-4300 Telefax number: +64 9 255-4307 Emergency information: National Poisons Centre: 0800 764 766 BASF Emergency Advice Number: 0800 944 955 (24 hour advice in an emergency only) BASF Emergency Advice Number: +61 3 8855 6666 (If calling from outside New Zealand)




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Chemical nature polyester resin, cellulose ester, organic solvent, pigment Hazardous ingredients ethylbenzene

Content (W/W): >= 2 % - < 2.5 % CAS Number: 100-41-4 EC-Number: 202-849-4 INDEX-Number: 601-023-00-4 Hazard symbol(s): F, Xn, Xi R-phrase(s): 11, 20, 36/37/38, 48/20, 65



n-Butyl acetate


xylene




General advice: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.

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If inhaled: Remove affected person from danger area. Keep warm, calm and covered up. If breathing is irregular or stopped, administer artificial respiration. Seek medical assistance. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). On skin contact: Remove contaminated clothing. Wash skin with soap and water, rinse abundantly. Do NOT use solvents or thinners. On contact with eyes: Contact lenses should be removed. Hold eyelids open and flush with copious amounts of clean, fresh water or a special eyewash solution. Seek medical assistance. On ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting.




Personal precautions: Avoid contact with skin and eyes. Keep away from sources of ignition. Avoid inhalation of vapour and spray mist. Ensure adequate ventilation. Avoid breathing vapours. Environmental precautions: Do not allow to enter drains or waterways. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environment Agency.

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Methods for cleaning up or taking up: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for diposal according with the waste regulations (see section 13). Clean preferably with a detergent; avoid the use of solvents.


Handling


Storage






4-methylpentan-2-one, 108-10-1;

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TWA value 20 ppm (ACGIHTLV) STEL value 75 ppm (ACGIHTLV) TWA value 205 mg/m3 ; 50 ppm (OEL (NZ)) STEL value 307 mg/m3 ; 75 ppm (OEL (NZ)) (OEL (NZ)) Exposure can also be estimated by biological monitoring.






Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations

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at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.


Form: liquid Colour: black Odour: specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


immiscible



11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in

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adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------






Sea transport

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IMDG







Other regulations



Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: F Highly flammable. Xn Harmful. Xi Irritant.

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11 Highly flammable. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure



Safety data sheet

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2-butoxyethanol

Content (W/W): >= 1 % - < 2 % CAS Number: 111-76-2 EC-Number: 203-905-0 INDEX-Number: 603-014-00-0 Hazard symbol(s): Xn R-phrase(s): 20/21/22, 36/38

n-Butyl acetate


xylene

Content (W/W): >= 12.5 % - < 15 % CAS Number: 1330-20-7 EC-Number: 215-535-7 INDEX-Number: 601-022-00-9 Hazard symbol(s): Xn R-phrase(s): 10, 20/21, 38


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Handling


Storage





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2-butoxyethanol, 111-76-2; TWA value 20 ppm (ACGIHTLV)

TWA value 121 mg/m3 ; 25 ppm (OEL (NZ)) Skin Designation (OEL (NZ)) Skin absorption can be significant.






Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm

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Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.


Form: liquid Colour: black Odour: specific boiling temperature: 114.00 - 145.00 °C Flash point: 23 °C



(20 °C)


immiscible


10. Stability and Reactivity Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. The product is stable if stored and handled as prescribed/indicated.

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When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.

11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.





Domestic transport: Hazard class: 3 Packing group: III ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT Further information

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Hazchem Code:3Y IERG Number:14

Sea transport IMDG







Hazard determining component(s) for labelling: XYLENE

Other regulations


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Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: F Highly flammable. Xn Harmful. Xi Irritant. 11 Highly flammable. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure

through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. 36/38 Irritating to eyes and skin. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin.


Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage




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Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact.

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Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn. Contact lenses should not be worn. Remove contaminated clothing. Contaminated equipment or clothing should be cleaned after each use or disposed of. Hands and/or face should be washed before breaks and at the end of the shift.


Form: liquid Colour: green Odour: of the solvent contained in the product specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)

Density: 0.950 g/cm3 Relative density: 0.9530

(20 °C)


immiscible



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In case of fire may produce hydrogen halide vapours., When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.


12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC and is not classified as dangerous for the environment. Do not allow to enter drains or waterways. Additional information Add. remarks environm. fate & pathway: The product contains organic halogen compounds which may contribute to the AOX value.


Observe national and local legal requirements. Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

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Dispose of in accordance with national, state and local regulations.



Sea transport IMDG







Other regulations

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Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage







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Form: liquid Colour: green Odour: specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


immiscible


10. Stability and Reactivity Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. The product is stable if stored and handled as prescribed/indicated. In case of fire may produce hydrogen halide vapours., When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.

11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component

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solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------





Domestic transport: Hazard class: 3 Packing group: III ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT

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Further information Hazchem Code:3Y IERG Number:14

Sea transport IMDG







Other regulations


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Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage







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Form: liquid Colour: blue Odour: specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


immiscible




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Sea transport

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IMDG







Other regulations




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Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage







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Form: liquid Colour: blue Odour: specific Flash point: 23 °C


Flammability: not applicable Lower explosion limit: 36 g/m3 Density: 0.921 g/cm3 Miscibility with water:

immiscible



11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy,

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signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------






Sea transport IMDG

Hazard class: 3 Packing group: III ID number: UN 1263

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Hazard label: 3 Marine pollutant: NO Proper shipping name: PAINT






Other regulations




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Safety data sheet

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Version: 2.0 BASF Safety data sheet Date / Revised: 03.04.2015 Product: baslac 35-M1521 1L BASECOAT



baslac 35-M1521 Basecoat BlueManufacturer/supplier: BASF New Zealand Limited Level 4, 4 Leonard Isitt Drive, Auckland Airport, Auckland 2022 PO Box 407 Shortland Street, Auckland 1140, NEW ZEALAND Telephone: +64 9 255-4300 Telefax number: +64 9 255-4307

Emergency information: National Poisons Centre: 0800 764 766 BASF Emergency Advice Number: 0800 944 955 (24 hour advice in an emergency only) BASF Emergency Advice Number: +61 3 8855 6666 (If calling from outside New Zealand)



Subclasses: Subclass 3.1 Category C - Substance that are flammable liquids Subclass 6.1 Category E - Substance which are acutely toxic Subclass 6.3 Category A - Substance which are skin irritants Subclass 6.4 Category A - Substance which are eye irritants Subclass 6.9 Category B - Substance which are target organ systemic toxicants Subclass 9.1 Category D - Substance that are ecotoxic to aquatic environment

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Chemical nature

polyester resin, cellulose ester, organic solvent, pigment

Hazardous ingredients

ethylbenzene Content (W/W): >= 2 % - < 2.5 % CAS Number: 100-41-4 EC-Number: 202-849-4 INDEX-Number: 601-023-00-4 Hazard symbol(s): F, Xn, Xi R-phrase(s): 11, 20, 36/37/38, 48/20, 65

4-methylpentan-2-one Content (W/W): >= 15 % - < 20 % CAS Number: 108-10-1 EC-Number: 203-550-1 INDEX-Number: 606-004-00-4 Hazard symbol(s): F, Xn R-phrase(s): 11, 20, 36/37, 66

n-Butyl acetate Content (W/W): >= 30 % - < 50 % CAS Number: 123-86-4 EC-Number: 204-658-1 INDEX-Number: 607-025-00-1 R-phrase(s): 10, 66, 67

xylene Content (W/W): >= 10 % - < 12.5 % CAS Number: 1330-20-7 EC-Number: 215-535-7 INDEX-Number: 601-022-00-9 Hazard symbol(s): Xn, Xi R-phrase(s): 10, 20/21, 48/20, 65, 36/38




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If inhaled: Remove affected person from danger area. Keep warm, calm and covered up. If breathing is irregular or stopped, administer artificial respiration. Seek medical assistance. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position).

On skin contact: Remove contaminated clothing. Wash skin with soap and water, rinse abundantly. Do NOT use solvents or thinners.

On contact with eyes: Contact lenses should be removed. Hold eyelids open and flush with copious amounts of clean, fresh water or a special eyewash solution. Seek medical assistance.

On ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting.


Suitable extinguishing media: Foam (alcohol resistant), carbon dioxide, powders, water spray. Do not allow run-off from fire fighting to enter drains or water courses.

Unsuitable extinguishing media for safety reasons: water jet

Specific hazards: Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health.

Special protective equipment: Appropriate breathing apparatus may be required.

Further information: Cool closed containers in the vicinity of the source of fire.



Environmental precautions: Do not allow to enter drains or waterways. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environment Agency.

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Handling


Storage

Keep away from oxidising agents, from strongly alkaline and strongly acid materials.

Suitable materials for containers: Carbon steel (Iron), tinned carbon steel (Tinplate) Further information on storage conditions: Electrical equipment must be explosion-proof to the appropriate standard. Floors must be of conducting type and impermeable to the materials being stored. Keep container tightly closed. Never use pressure to empty; container is not a pressure vessel. Close containers carefully once opened and store upright in order to prevent any leakage. No smoking. Prevent unauthorized access. Detailed information can be gained from the relevant technical data sheets. Always keep in containers of same material as the original one. Observe label precautions. Store in a dry, well ventilated place. Protect from direct sunlight. Keep away from sources of ignition. Keep away from heat.

Storage stability: Storage temperature: 5.00 - 35.00 °C



ethylbenzene, 100-41-4; TWA value 434 mg/m3 ; 100 ppm (OEL (NZ)) STEL value 543 mg/m3 ; 125 ppm (OEL (NZ)) TWA value 20 ppm (ACGIHTLV)


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n-Butyl acetate, 123-86-4; TWA value 150 ppm (ACGIHTLV) STEL value 200 ppm (ACGIHTLV) TWA value 713 mg/m3 ; 150 ppm (OEL (NZ)) STEL value 950 mg/m3 ; 200 ppm (OEL (NZ))

xylene, 1330-20-7; TWA value 100 ppm (ACGIHTLV) STEL value 150 ppm (ACGIHTLV) TWA value 217 mg/m3 ; 50 ppm (OEL (NZ))


Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols.

Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm

Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact.

Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres.

General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations

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Form: liquid Colour: blue Odour: specific

boiling temperature: 119.00 - 139.00 °C

Flash point: 23 °C Flammability: not applicableLower explosion limit: 36 g/m3

Vapour pressure: 8.40 hPa (20 °C)

Density: 0.912 g/cm3

Miscibility with water: immiscible

Viscosity, kinematic: 305.0 mm2/s

Flow time: > 45 s (DIN EN ISO 2431; 6 mm)

10. Stability and Reactivity

Substances to avoid:Keep away from highly acidic or alkaline substances as well as oxidants in order to preventexothermal reactions.

Hazardous reactions:No hazardous reactions if stored and handled as prescribed/indicated.The product is stable if stored and handled as prescribed/indicated.

When exposed to high temperatures hazardous decomposition products such as carbon monoxide,carbon dioxide, smoke, oxides of nitrogen may be produced.

11. Toxicological Information

Acute toxicity

Assessment of acute toxicity:The preparation has been assessed following the conventional method of the DangerousPreparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to componentsolvent vapour concentrations in excess of the stated occupational exposure limit may result inadverse health effects such as mucous membrane and respiratory system irritation and adverseeffect on kidney, liver and central nervous system. Symptoms and signs include headache,

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dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.

12. Ecological Information

Ecotoxicity

Assessment of aquatic toxicity:Do not allow to enter drains or waterways. No data available.

Persistence and degradability

Assessment biodegradation and elimination (H2O):Biological degradability of hazardous substances mentioned in section 3:

Information on: xyleneElimination information: 87.8 % BOD of the ThOD (28 d) (OECD Guideline 301 F) (aerobic, activated sludge, domestic, non-adapted)The product has not been tested. The statement has been derived from substances/products of asimilar structure or composition.

Information on: ethylbenzeneElimination information: 70 - 80 % TIC of the ThIC (28 d) (ISO 14593) (aerobic, activated sludge) Readily biodegradable (according to OECD criteria).----------------------------------

Additional information

Add. remarks environm. fate & pathway:The product contains organic halogen compounds which may contribute to the AOX value.


Observe national and local legal requirements.

Contaminated packaging:Contaminated packaging should be emptied as far as possible and disposed of in the same manneras the substance/product.Dispose of in accordance with national, state and local regulations.


Domestic transport:Hazard class: 3

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Packing group: III ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT


Sea transport IMDG






Subclasses: Subclass 3.1 Category C - Substance that are flammable liquids Subclass 6.1 Category E - Substance which are acutely toxic Subclass 6.3 Category A - Substance which are skin irritants Subclass 6.4 Category A - Substance which are eye irritants Subclass 6.9 Category B - Substance which are target organ systemic toxicants Subclass 9.1 Category D - Substance that are ecotoxic to aquatic environment

Hazard determining component(s) for labelling: ETHYLBENZENE, ISOBUTYL METHYL KETONE, N-BUTYLACETATE, XYLENE

Other regulations

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Registration status:

NZIOC, NZ released / listed GrpStd HSR002662


Recommended use: Sprayable

For multi-pack systems observe material safety data sheets of all components. Restricted to professional users.

Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: F Highly flammable.Xn Harmful.Xi Irritant.11 Highly flammable.20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure

through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 65 Also harmful: may cause lung damage if swallowed. 36/38 Irritating to eyes and skin.

Vertical lines in the left hand margin indicate an amendment from the previous version.


Safety data sheet

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Chemical nature polyester resin, cellulose ester, Rosin derivative, organic solvent, pigment Hazardous ingredients ethylbenzene




n-Butyl acetate


xylene





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Handling


Storage




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Form: liquid Colour: blue Odour: of the solvent contained in the product specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible



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Sea transport IMDG







Other regulations


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Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage




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Form: liquid Colour: blue Odour: specific boiling temperature: > 100.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible

Viscosity, kinematic: 411.6 mm2/s Flow time: > 60 s (DIN EN ISO 2431; 6 mm) Solids content: 25.51 %

10. Stability and Reactivity Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated.

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The product is stable if stored and handled as prescribed/indicated. When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.






Domestic transport:

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Hazard class: 3 Packing group: III ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT Further information Hazchem Code:3Y IERG Number:14

Sea transport IMDG







Other regulations


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Safety data sheet

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The product contains: alkylamines May produce an allergic reaction.

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n-Butyl acetate


xylene


alkylamines

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Content (W/W): >= 0.1 % - < 0.2 % CAS Number: 72162-46-0 EC-Number: 276-432-0 Hazard symbol(s): C, N R-phrase(s): 22, 35, 43, 51/53






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Personal precautions: Avoid contact with skin and eyes. Keep away from sources of ignition. Avoid inhalation of vapour and spray mist. Ensure adequate ventilation. Avoid breathing vapours. Environmental precautions: Do not allow to enter drains or waterways. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environment Agency. Methods for cleaning up or taking up: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for diposal according with the waste regulations (see section 13). Clean preferably with a detergent; avoid the use of solvents.


Handling


Storage


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Form: liquid Colour: blue Odour: specific boiling temperature: > 100.00 °C Flash point: 23 °C



(20 °C)


immiscible



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11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ---------------------------------- The product contains: alkylamines May produce an allergic reaction.

12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: alkylamines ----------------------------------

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Additional information Add. remarks environm. fate & pathway: The product contains organic halogen compounds which may contribute to the AOX value.





Sea transport IMDG




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Other regulations



Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: F Highly flammable. Xn Harmful. Xi Irritant. C Corrosive. N Dangerous for the environment. 11 Highly flammable. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure

through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 22 Harmful if swallowed. 35 Causes severe burns. 43 May cause sensitization by skin contact. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

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Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage







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Form: liquid Colour: red Odour: specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


immiscible




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Sea transport

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IMDG







Hazard determining component(s) for labelling: ISOBUTYL METHYL KETONE

Other regulations



Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: F Highly flammable.

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Xn Harmful. Xi Irritant. 11 Highly flammable. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure



Safety data sheet

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Chemical nature fillers, polyester resin, cellulose ester, organic solvent, pigment Hazardous ingredients ethylbenzene




n-Butyl acetate


xylene





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Handling


Storage




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Form: liquid Colour: violet Odour: of the solvent contained in the product specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible



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12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC and is not classified as dangerous for the environment. Do not allow to enter drains or waterways. Additional information Other ecotoxicological advice: Acutely toxic for aquatic organisms.



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Sea transport IMDG







Other regulations


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Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage




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Form: liquid Colour: violet Odour: of the solvent contained in the product specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible



Page: 7/9








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Sea transport IMDG







Other regulations


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Safety data sheet

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n-Butyl acetate


xylene





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Page: 4/9





Handling


Storage







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Page: 6/9








(20 °C)


immiscible




Page: 7/9









Sea transport

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IMDG








Other regulations




Page: 9/9






Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene





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Page: 4/9





Handling


Storage







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Page: 6/9





Form: liquid Colour: red Odour: specific Flash point: 23 °C



immiscible




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signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------






Sea transport IMDG

Hazard class: 3 Packing group: III ID number: UN 1263

Page: 8/9



Hazard label: 3 Marine pollutant: NO Proper shipping name: PAINT






Other regulations




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Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene





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Handling


Storage







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Page: 6/9








(20 °C)


immiscible




Page: 7/9



adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.






Sea transport IMDG


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Other regulations




through inhalation.

Page: 9/9



65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin.


Safety data sheet

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n-Butyl acetate


xylene





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Page: 4/9





Handling


Storage







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(20 °C)


immiscible




Page: 7/9









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Sea transport IMDG







Other regulations


Page: 9/9







Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene





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Handling


Storage




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Form: liquid Colour: orange Odour: of the solvent contained in the product specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible



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In case of fire may produce hydrogen halide vapours., When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.





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Sea transport IMDG







Other regulations

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Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene





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Handling


Storage







Page: 5/9










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(20 °C)


immiscible




Page: 7/9









Sea transport

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IMDG







Other regulations




Page: 9/9






Safety data sheet

Page: 1/9








Page: 2/9








n-Butyl acetate


xylene





Page: 3/9








Page: 4/9





Handling


Storage







Page: 5/9










Page: 6/9








(20 °C)


immiscible




Page: 7/9









Sea transport

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IMDG








Other regulations




Page: 9/9






Safety data sheet

Page: 1/9








Page: 2/9








n-Butyl acetate


xylene





Page: 3/9








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Handling


Storage







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Form: liquid Colour: orange Odour: specific boiling temperature: 114.00 - 145.00 °C Flash point: 23 °C



(20 °C)


immiscible




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solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.






Sea transport IMDG

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Other regulations



Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: F Highly flammable. Xn Harmful. Xi Irritant. 11 Highly flammable.

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20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 48/20 Harmful: Danger of serious damage to health by prolonged exposure



Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage







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Form: liquid Colour: yellow Odour: specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


immiscible




Page: 7/9









Page: 8/9




Sea transport IMDG







Other regulations


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Safety data sheet

Page: 1/11








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Chemical nature polyester resin, cellulose ester, organic solvent, pigment Hazardous ingredients 1,2,4-trimethylbenzene

Content (W/W): >= 0.5 % - < 1 % CAS Number: 95-63-6 EC-Number: 202-436-9 INDEX-Number: 601-043-00-3 Hazard symbol(s): Xn, N R-phrase(s): 10, 20, 36/37/38, 51/53

ethylbenzene



Content (W/W): >= 10 % - < 12.5 % CAS Number: 108-10-1 EC-Number: 203-550-1 INDEX-Number: 606-004-00-4 Hazard symbol(s): F, Xn R-phrase(s): 11, 20, 36/37, 66

mesitylene

Content (W/W): >= 0.1 % - < 0.2 % CAS Number: 108-67-8 EC-Number: 203-604-4 INDEX-Number: 601-025-00-5 Hazard symbol(s): Xi, N R-phrase(s): 10, 37, 51/53

n-Butyl acetate


xylene

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Solvent naphtha (petroleum), light arom.

Content (W/W): >= 0.5 % - < 1 % CAS Number: 64742-95-6 EC-Number: 265-199-0 INDEX-Number: 649-356-00-4 Hazard symbol(s): Xn R-phrase(s): 65, 66, 67, 12, 38, 62

naphtha (petroleum), hydrotreated light, Kp>140oC

Content (W/W): >= 5 % - < 7 % CAS Number: 64742-49-0 EC-Number: 265-151-9 Hazard symbol(s): Xn R-phrase(s): 10, 65, 66, 67





Suitable extinguishing media:

Page: 4/11



Foam (alcohol resistant), carbon dioxide, powders, water spray. Do not allow run-off from fire fighting to enter drains or water courses. Unsuitable extinguishing media for safety reasons: water jet Specific hazards: Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health. Special protective equipment: Appropriate breathing apparatus may be required. Further information: Cool closed containers in the vicinity of the source of fire.




Handling


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Protection against fire and explosion: Use antistatic tools. Exhaust fans should be explosion proof. Provide adequate ventilation to remove solvent vapors from lower levels or work areas and to prevent solvent contact with ignition sources. Sealed containers should be protected against heat as this results in pressure build-up. Risk of explosion if heated under confinement. Avoid all sources of ignition: heat, sparks, open flame.

Storage




1,2,4-trimethylbenzene, 95-63-6; TWA value 25 ppm (ACGIHTLV)






mesitylene, 108-67-8; TWA value 25 ppm (ACGIHTLV)


n-Butyl acetate, 123-86-4;

Page: 6/11







Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn. Contact lenses should not be worn. Remove contaminated clothing. Contaminated equipment or clothing should be cleaned after each use or disposed of. Hands and/or face should be washed before breaks and at the end of the shift.

Page: 7/11




Form: liquid Colour: yellow Odour: aromatic specific Boiling range:

not applicable

boiling temperature: 114.00 - 145.00 °C Flash point: 23 °C



(20 °C)

Density: 0.975 g/cm3Relative density: 0.9790

(20 °C)


immiscible




Page: 8/11




12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: mesitylene Elimination information: 0 % BOD of the ThOD (14 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted) 96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted)

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----------------------------------





Sea transport IMDG




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Other regulations



Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: Xn Harmful. N Dangerous for the environment. F Highly flammable. Xi Irritant. 10 Flammable. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment. 11 Highly flammable. 48/20 Harmful: Danger of serious damage to health by prolonged exposure

through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 37 Irritating to respiratory system. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility.

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Safety data sheet

Page: 1/9







Subclasses: Subclass 3.1 Category C - Substance that are flammable liquids Subclass 6.1 Category E - Substance which are acutely toxic Subclass 6.3 Category B - Substance which are skin irritants Subclass 6.4 Category A - Substance which are eye irritants Subclass 9.1 Category C - Substance that are ecotoxic to aquatic environment

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n-Butyl acetate


xylene


zinc phosphate

Content (W/W): >= 1 % - < 2 % CAS Number: 7779-90-0 EC-Number: 231-944-3 INDEX-Number: 030-011-00-6 Hazard symbol(s): N R-phrase(s): 50/53


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Handling


Storage





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Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres.

Page: 6/9



General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.




Flammability: not applicable Lower explosion limit: 36 g/m3 Ignition temperature: > 200.00 °C Vapour pressure: 8.40 hPa

(20 °C)


immiscible



11. Toxicological Information

Page: 7/9



Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------

12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See sections 2 and 15 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: zinc phosphate ----------------------------------



Page: 8/9





Sea transport IMDG






Subclasses: Subclass 3.1 Category C - Substance that are flammable liquids Subclass 6.1 Category E - Substance which are acutely toxic Subclass 6.3 Category B - Substance which are skin irritants Subclass 6.4 Category A - Substance which are eye irritants Subclass 9.1 Category C - Substance that are ecotoxic to aquatic environment

Other regulations


Page: 9/9






through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment. Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage




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Form: liquid Colour: yellow Odour: aromatic specific Boiling range:

not applicable




(20 °C)


(20 °C)


immiscible


10. Stability and Reactivity Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions.

Page: 7/9



Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. The product is stable if stored and handled as prescribed/indicated. When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.





Page: 8/9



Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. Dispose of in accordance with national, state and local regulations.



Sea transport IMDG







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Other regulations






Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage




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Page: 6/9





Form: liquid Colour: yellow Odour: aromatic specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible



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Sea transport IMDG







Other regulations


Page: 9/9








Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene





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Handling


Storage







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(20 °C)


immiscible




Page: 7/9









Sea transport

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IMDG








Other regulations




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Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene





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Handling


Storage







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Form: liquid Colour: white Odour: specific Flash point: 23 °C



immiscible




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signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.






Sea transport IMDG



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Other regulations





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Safety data sheet

Page: 1/10








Page: 2/10





Content (W/W): >= 0.3 % - < 0.5 % CAS Number: 95-63-6 EC-Number: 202-436-9 INDEX-Number: 601-043-00-3 Hazard symbol(s): Xn, N R-phrase(s): 10, 20, 36/37/38, 51/53

ethylbenzene




mesitylene


n-Butyl acetate


xylene

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Suitable extinguishing media: Foam (alcohol resistant), carbon dioxide, powders, water spray. Do not allow run-off from fire fighting to enter drains or water courses. Unsuitable extinguishing media for safety reasons: water jet Specific hazards:

Page: 4/10



Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health. Special protective equipment: Appropriate breathing apparatus may be required. Further information: Cool closed containers in the vicinity of the source of fire.




Handling


Storage

Keep away from oxidising agents, from strongly alkaline and strongly acid materials. Suitable materials for containers: carbon steel (iron), tin (tinplate) Further information on storage conditions: Electrical equipment must be explosion-proof to the appropriate standard. Floors must be of conducting type and impermeable to the materials being stored. Keep container tightly closed. Never use pressure to empty; container is not a pressure

Page: 5/10



vessel. Close containers carefully once opened and store upright in order to prevent any leakage. No smoking. Prevent unauthorized access. Detailed information can be gained from the relevant technical data sheets. Always keep in containers of same material as the original one. Observe label precautions. Store in a dry, well ventilated place. Protect from direct sunlight. Keep away from sources of ignition. Keep away from heat. Storage stability: Storage temperature: 5.00 - 35.00 °C
















Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting)

Page: 6/10



should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.


Form: liquid Colour: colourless Odour: specific Flash point: 23 °C



immiscible


Page: 7/10




11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: toluene Assessment of teratogenicity: Indications of possible developmental toxicity/teratogenicity were seen in animal studies. Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------

12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as

Page: 8/10



dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: mesitylene Elimination information: 0 % BOD of the ThOD (14 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted) 96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted) ----------------------------------





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Sea transport IMDG







Other regulations



Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users.

Page: 10/10



Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: Xn Harmful. N Dangerous for the environment. F Highly flammable. Xi Irritant. 10 Flammable. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the


through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 37 Irritating to respiratory system. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility.


Safety data sheet

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n-Butyl acetate


xylene





Page: 3/9








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Handling


Storage




Page: 5/9













Page: 6/9





Form: liquid Colour: white Odour: of the solvent contained in the product specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible



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Sea transport IMDG







Other regulations


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Safety data sheet

Page: 1/9








Page: 2/9




Chemical nature polyester resin, cellulose ester, organic solvent, pigment, polyurethane Hazardous ingredients ethylbenzene


1-methoxypropan-2-ol

Content (W/W): >= 3 % - < 5 % CAS Number: 107-98-2 EC-Number: 203-539-1 INDEX-Number: 603-064-00-3 R-phrase(s): 10, 67



n-Butyl acetate


xylene



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Handling


Storage





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1-methoxypropan-2-ol, 107-98-2; TWA value 100 ppm (ACGIHTLV)










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(20 °C)


immiscible



Page: 7/9



When exposed to high temperatures hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen, hydrogen cyanide, monomeric isocyanates may be produced.






Domestic transport: Hazard class: 3 Packing group: III ID number: UN 1263Hazard label: 3 Proper shipping name: PAINT

Page: 8/9




Sea transport IMDG







Other regulations


Page: 9/9





through inhalation. 65 Harmful: may cause lung damage if swallowed. 10 Flammable. 67 Vapours may cause drowsiness and dizziness.36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin.


Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage




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Form: liquid Colour: red Odour: aromatic specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible



Page: 7/9









Domestic transport: Hazard class: 3

Page: 8/9



Packing group: III ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT Further information Hazchem Code:3Y IERG Number:14

Sea transport IMDG







Other regulations


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Safety data sheet

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n-Butyl acetate


xylene



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Handling


Storage





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Form: liquid Colour: orange Odour: specific boiling temperature: 114.00 - 145.00 °C Flash point: 23 °C



(20 °C)


immiscible



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Sea transport IMDG







Other regulations


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Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene



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Handling


Storage





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(20 °C)


immiscible



Page: 7/9










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Sea transport IMDG







Other regulations


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Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene


stoddard solvent



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Handling


Storage





Page: 5/9














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Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.





(20 °C)


immiscible



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12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: stoddard solvent ----------------------------------



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Sea transport IMDG







Other regulations

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aquatic environment. Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

Safety data sheet

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n-Butyl acetate


xylene


stoddard solvent



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Handling


Storage





Page: 5/9














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(20 °C)


immiscible



Page: 7/9







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Sea transport IMDG







Other regulations

Page: 9/9








Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene





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Handling


Storage







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(20 °C)


immiscible




Page: 7/9









Sea transport

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IMDG







Other regulations




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Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene



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Handling


Storage





Page: 5/9














Page: 6/9








(20 °C)


immiscible



Page: 7/9










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Sea transport IMDG







Other regulations


Page: 9/9







Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene



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Handling


Storage





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Form: liquid Colour: violet Odour: specific boiling temperature: 114.00 - 145.00 °C Flash point: 23 °C



(20 °C)


immiscible



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Sea transport IMDG







Other regulations


Page: 9/9







Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene



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Handling


Storage





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(20 °C)


immiscible



Page: 7/9










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Sea transport IMDG







Other regulations


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Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene





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Handling


Storage







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(20 °C)


immiscible




Page: 7/9









Sea transport

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IMDG







Other regulations




Page: 9/9






Safety data sheet

Page: 1/10








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n-Butyl acetate


xylene


naphtha (petroleum), hydrotrea

Content (W/W): >= 2.5 % - < 3 % CAS Number: 64742-48-9 EC-Number: 265-150-3 Hazard symbol(s): Xn R-phrase(s): 10, 65, 66

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Aluminum

Content (W/W): >= 3 % - < 5 % CAS Number: 7429-90-5 EC-Number: 231-072-3 INDEX-Number: 013-002-00-1 Hazard symbol(s): F R-phrase(s): 11, 15





Suitable extinguishing media: Foam (alcohol resistant), carbon dioxide, powders, water spray. Do not allow run-off from fire fighting to enter drains or water courses. Unsuitable extinguishing media for safety reasons: water jet Specific hazards: Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health. Special protective equipment: Appropriate breathing apparatus may be required.

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Further information: Cool closed containers in the vicinity of the source of fire.




Handling


Storage

Keep away from oxidising agents, from strongly alkaline and strongly acid materials. Suitable materials for containers: carbon steel (iron), tin (tinplate) Further information on storage conditions: Electrical equipment must be explosion-proof to the appropriate standard. Floors must be of conducting type and impermeable to the materials being stored. Keep container tightly closed. Never use pressure to empty; container is not a pressure vessel. Close containers carefully once opened and store upright in order to prevent any leakage. No smoking. Prevent unauthorized access. Detailed information can be gained from the relevant technical data sheets. Always keep in containers of same material as the original one. Observe label precautions. Store in a dry, well ventilated place. Protect from direct sunlight. Keep away from sources of ignition. Keep away from heat.

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Storage stability: Storage temperature: 5.00 - 35.00 °C













Aluminum, 7429-90-5; TWA value 1 mg/m3 (ACGIHTLV), Respirable fraction

TWA value 10 mg/m3 (OEL (NZ)), dust Measured as: aluminum (Al) TWA value 5 mg/m3 (OEL (NZ)), Welding fume Measured as: aluminum (Al) TWA value 5 mg/m3 (OEL (NZ)), Pyrophoric powder Measured as: aluminum (Al) TWA value 5 mg/m3 (OEL (NZ)) Measured as: aluminum (Al) TWA value 2 mg/m3 (OEL (NZ)) Measured as: aluminum (Al)

Page: 6/10




Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.




Flammability: not applicable Lower explosion limit: 36 g/m3

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Vapour pressure: 6.70 hPa (20 °C)


immiscible


10. Stability and Reactivity Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. The product is stable if stored and handled as prescribed/indicated. When exposed to high temperatures hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen, hydrogen cyanide, monomeric isocyanates may be produced.


12. Ecological Information Ecotoxicity Assessment of aquatic toxicity:

Page: 8/10



There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC and is not classified as dangerous for the environment. Do not allow to enter drains or waterways.





Sea transport IMDG




Page: 9/10






Other regulations




through inhalation. 65 Harmful: may cause lung damage if swallowed. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 15 Contact with water liberates extremely flammable gases.

Vertical lines in the left hand margin indicate an amendment from the previous version.

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Safety data sheet

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n-Butyl acetate


xylene



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Handling


Storage





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(20 °C)


immiscible



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Sea transport IMDG







Other regulations


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Safety data sheet

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n-Butyl acetate


xylene


stoddard solvent



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Handling


Storage





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(20 °C)


immiscible



Page: 7/9








Domestic transport: Hazard class: 3 Packing group: III

Page: 8/9



ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT Further information Hazchem Code:3Y IERG Number:14

Sea transport IMDG







Other regulations


Page: 9/9





through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system.66 Repeated exposure may cause skin dryness or cracking. 10 Flammable. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the


Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage

Keep away from oxidising agents, from strongly alkaline and strongly acid materials. Suitable materials for containers: carbon steel (iron), tin (tinplate), High density polyethylene (HDPE), Low density polyethylene (LDPE), Polyethylenetherephtalate (PET), Polypropylene Further information on storage conditions: Electrical equipment must be explosion-proof to the appropriate standard. Floors must be of conducting type and impermeable to the materials being stored. Keep container tightly closed. Never use pressure to empty; container is not a pressure vessel. Close containers carefully once opened and store upright in order to prevent any leakage. No smoking. Prevent unauthorized access. Detailed information can be gained from the relevant technical data sheets. Always keep in containers of same material as the original one. Observe label precautions. Store in a dry, well ventilated place. Protect from direct sunlight. Keep away from sources of ignition. Keep away from heat. Storage stability: Storage temperature: 5.00 - 35.00 °C





Page: 5/9











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(20 °C)


immiscible




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Sea transport

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IMDG







Other regulations




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Safety data sheet

Page: 1/9








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n-Butyl acetate


xylene



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Handling


Storage





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Form: liquid Colour: white Odour: specific boiling temperature: 114.00 - 145.00 °C Flash point: 23 °C



(20 °C)


immiscible



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Sea transport IMDG







Other regulations


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Safety data sheet

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n-Butyl acetate


xylene





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Handling


Storage




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Form: liquid Colour: white Odour: specific Boiling range:

not applicable




(20 °C)


(20 °C)


immiscible


10. Stability and Reactivity Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated.

Page: 7/9



The product is stable if stored and handled as prescribed/indicated. When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.





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Sea transport IMDG







Other regulations

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Safety data sheet

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n-Butyl acetate


xylene


stoddard solvent



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Handling


Storage


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Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream).

Page: 6/10



Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn. Contact lenses should not be worn. Remove contaminated clothing. Contaminated equipment or clothing should be cleaned after each use or disposed of. Hands and/or face should be washed before breaks and at the end of the shift.


Form: liquid Colour: white Odour: aromatic specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


(20 °C)


immiscible


10. Stability and Reactivity

Page: 7/10



Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. The product is stable if stored and handled as prescribed/indicated. When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.


12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3:

Page: 8/10



Information on: stoddard solvent ----------------------------------





Sea transport IMDG




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Other regulations





aquatic environment. Vertical lines in the left hand margin indicate an amendment from the previous version.

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Safety data sheet

Page: 1/10








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ethylbenzene




n-Butyl acetate


xylene



Page: 3/10



Content (W/W): >= 0.3 % - < 0.5 % CAS Number: 64742-95-6 EC-Number: 265-199-0 INDEX-Number: 649-356-00-4 Hazard symbol(s): Xn R-phrase(s): 65, 66, 67, 12, 38, 62

Aluminum


stoddard solvent

Content (W/W): >= 0.5 % - < 1 % CAS Number: 8052-41-3 Hazard symbol(s): Xn, N R-phrase(s): 10, 51/53, 65, 66, 67





Suitable extinguishing media: Foam (alcohol resistant), carbon dioxide, powders, water spray. Do not allow run-off from fire fighting to enter drains or water courses.

Page: 4/10



Unsuitable extinguishing media for safety reasons: water jet Specific hazards: Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health. Special protective equipment: Appropriate breathing apparatus may be required. Further information: Cool closed containers in the vicinity of the source of fire.




Handling


Storage

Keep away from oxidising agents, from strongly alkaline and strongly acid materials.

Page: 5/10



Suitable materials for containers: carbon steel (iron), tin (tinplate) Further information on storage conditions: Electrical equipment must be explosion-proof to the appropriate standard. Floors must be of conducting type and impermeable to the materials being stored. Keep container tightly closed. Never use pressure to empty; container is not a pressure vessel. Close containers carefully once opened and store upright in order to prevent any leakage. No smoking. Prevent unauthorized access. Detailed information can be gained from the relevant technical data sheets. Always keep in containers of same material as the original one. Observe label precautions. Store in a dry, well ventilated place. Protect from direct sunlight. Keep away from sources of ignition. Keep away from heat. Storage stability: Storage temperature: 5.00 - 35.00 °C













Aluminum, 7429-90-5;

Page: 6/10



TWA value 1 mg/m3 (ACGIHTLV), Respirable fraction TWA value 10 mg/m3 (OEL (NZ)), dust Measured as: aluminum (Al) TWA value 5 mg/m3 (OEL (NZ)), Welding fume Measured as: aluminum (Al) TWA value 5 mg/m3 (OEL (NZ)), Pyrophoric powder Measured as: aluminum (Al) TWA value 5 mg/m3 (OEL (NZ)) Measured as: aluminum (Al) TWA value 2 mg/m3 (OEL (NZ)) Measured as: aluminum (Al)




Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Eye protection not required., Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.

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Form: liquid Colour: metallic Odour: specific boiling temperature: 114.00 - 145.00 °C Flash point: 24 °C



(20 °C)


immiscible



11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the

Page: 8/10



development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.

12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted) 96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted) Information on: stoddard solvent ----------------------------------




Domestic transport: Hazard class: 3

Page: 9/10



Packing group: III ID number: UN 1263 Hazard label: 3 Proper shipping name: PAINT Further information Hazchem Code:3Y IERG Number:14

Sea transport IMDG







Other regulations


Page: 10/10






through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility. 15 Contact with water liberates extremely flammable gases.


Safety data sheet

Page: 1/10








Page: 2/10






ethylbenzene




mesitylene


n-Butyl acetate


xylene

Page: 3/10






Aluminum






Suitable extinguishing media:

Page: 4/10



Foam (alcohol resistant), carbon dioxide, powders, water spray. Do not allow run-off from fire fighting to enter drains or water courses. Unsuitable extinguishing media for safety reasons: water jet Specific hazards: Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health. Special protective equipment: Appropriate breathing apparatus may be required. Further information: Cool closed containers in the vicinity of the source of fire.




Handling


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Storage














xylene, 1330-20-7;

Page: 6/10



TWA value 100 ppm (ACGIHTLV) STEL value 150 ppm (ACGIHTLV) TWA value 217 mg/m3 ; 50 ppm (OEL (NZ))





Page: 7/10




Form: liquid Colour: metallic Odour: specific Flash point: 23 °C



immiscible



11. Toxicological Information Acute toxicity Assessment of acute toxicity: The preparation has been assessed following the conventional method of the Dangerous Preparation Directive 1999/45/EC. See Sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated and prolonged exposure to solvents at levels significantly above OELs may lead to the development of long-lasting central nervous system disorders such as chronic toxic encephalopathy, signs of toxicity include changes in behaviour and memory. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may

Page: 8/10



cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------

12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: mesitylene Elimination information: 0 % BOD of the ThOD (14 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted) 96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted) ----------------------------------



Page: 9/10






Sea transport IMDG







Page: 10/10



Other regulations





through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 37 Irritating to respiratory system. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility. 15 Contact with water liberates extremely flammable gases.


Safety data sheet

Page: 1/11








Page: 2/11






ethylbenzene




mesitylene


n-Butyl acetate


xylene

Page: 3/11






Aluminum


stoddard solvent

Content (W/W): >= 0.5 % - < 1 % CAS Number: 8052-41-3 Hazard symbol(s): Xn, N R-phrase(s): 10, 51/53, 65, 66, 67



General advice: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If inhaled: Remove affected person from danger area. Keep warm, calm and covered up. If breathing is irregular or stopped, administer artificial respiration. Seek medical assistance. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). On skin contact: Remove contaminated clothing. Wash skin with soap and water, rinse abundantly. Do NOT use solvents or thinners. On contact with eyes: Contact lenses should be removed. Hold eyelids open and flush with copious amounts of clean, fresh water or a special eyewash solution. Seek medical assistance.

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On ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting.






Handling

Avoid contact with skin and eyes. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Avoid inhalation of dust from sanding. Smoking, eating and drinking are forbidden in application area. For personal protection see section 8. Comply with the health and safety at work laws. Product may charge electrostatically: always use earthing leads when transferring from one container to another and earth containers. It is recommended that operators should wear antistatic clothing and footwear. When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely

Page: 5/11



to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits. Solvent vapours are heavier than air and spread along floors. Vapour forms explosive mixtures with air. Keep container dry and tightly closed in a cool well-ventilated place. Avoid all sources of ignition: heat, sparks, open flame. Avoid inhalation of vapour and spray mist. Do not use any sparking tools.

Storage












n-Butyl acetate, 123-86-4;

Page: 6/11











Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Eye protection not required., Required when there is a risk of eye contact.

Page: 7/11





Form: liquid Colour: metallic Odour: of the solvent contained in the product specific boiling temperature: 114.00 - 145.00 °C Flash point: 24 °C



(20 °C)


immiscible



Page: 8/11




12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: mesitylene Elimination information: 0 % BOD of the ThOD (14 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted)

Page: 9/11



96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted) Information on: stoddard solvent ----------------------------------





Sea transport IMDG




Page: 10/11






Other regulations





through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 37 Irritating to respiratory system. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility. 15 Contact with water liberates extremely flammable gases.

Page: 11/11




Safety data sheet

Page: 1/11








Page: 2/11






ethylbenzene


propylbenzene

Content (W/W): >= 0.1 % - < 0.2 % CAS Number: 103-65-1 EC-Number: 203-132-9 INDEX-Number: 601-024-00-X Hazard symbol(s): Xn, N R-phrase(s): 10, 37, 51/53, 65



mesitylene


n-Butyl acetate

Page: 3/11




xylene





Content (W/W): >= 1 % - < 2 % CAS Number: 64742-48-9 EC-Number: 265-150-3 Hazard symbol(s): Xn R-phrase(s): 10, 65, 66

Aluminum




General advice: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If inhaled: Remove affected person from danger area. Keep warm, calm and covered up. If breathing is irregular or stopped, administer artificial respiration. Seek medical assistance. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position).

Page: 4/11



On skin contact: Remove contaminated clothing. Wash skin with soap and water, rinse abundantly. Do NOT use solvents or thinners. On contact with eyes: Contact lenses should be removed. Hold eyelids open and flush with copious amounts of clean, fresh water or a special eyewash solution. Seek medical assistance. On ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting.





Page: 5/11




Handling


Storage









Page: 6/11













Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves.

Page: 7/11



The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.





immiscible



Page: 8/11





12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: propylbenzene Elimination information:

Page: 9/11



34.4 % BOD of the ThOD (8 d) (other) (aerobic, activated sludge, domestic) Information on: mesitylene Elimination information: 0 % BOD of the ThOD (14 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted) 96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted) ----------------------------------





Sea transport IMDG


Page: 10/11








Other regulations





through inhalation.

Page: 11/11



65 Harmful: may cause lung damage if swallowed. 37 Irritating to respiratory system. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility. 15 Contact with water liberates extremely flammable gases.


Safety data sheet

Page: 1/11







Subclasses: Subclass 3.1 Category C - Substance that are flammable liquids Subclass 6.1 Category E - Substance which are acutely toxic Subclass 6.3 Category A - Substance which are skin irritants Subclass 8.3 Category A - Substance corrosive to ocular tissue

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Chemical nature polyester resin, cellulose ester, amino resins, organic solvent, pigment Hazardous ingredients n-butanol

Content (W/W): >= 2 % - < 2.5 % CAS Number: 71-36-3 EC-Number: 200-751-6 INDEX-Number: 603-004-00-6 Hazard symbol(s): Xn R-phrase(s): 10, 22, 37/38, 41, 67

isobutyl alcohol

Content (W/W): >= 1 % - < 2 % CAS Number: 78-83-1 EC-Number: 201-148-0 INDEX-Number: 603-108-00-1 Hazard symbol(s): Xi R-phrase(s): 10, 37/38, 41, 67

1,2,4-trimethylbenzene


ethylbenzene




mesitylene

Page: 3/11




n-Butyl acetate


xylene





Content (W/W): >= 1 % - < 2 % CAS Number: 64742-48-9 EC-Number: 265-150-3 Hazard symbol(s): Xn R-phrase(s): 10, 65, 66

Aluminum



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Page: 5/11





Handling


Storage




n-butanol, 71-36-3;

Page: 6/11



TWA value 20 ppm (ACGIHTLV) CLV 150 mg/m3 ; 50 ppm (OEL (NZ)) Skin Designation (OEL (NZ)) Skin absorption can be significant.

isobutyl alcohol, 78-83-1; TWA value 50 ppm (ACGIHTLV)















Page: 7/11






Page: 8/11







immiscible




Page: 9/11



Developmental toxicity Information on: xylene Assessment of teratogenicity: A teratogenic potential cannot be excluded. ----------------------------------

12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: mesitylene Elimination information: 0 % BOD of the ThOD (14 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted) 96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted) ----------------------------------



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Sea transport IMDG






Subclasses: Subclass 3.1 Category C - Substance that are flammable liquids Subclass 6.1 Category E - Substance which are acutely toxic Subclass 6.3 Category A - Substance which are skin irritants Subclass 8.3 Category A - Substance corrosive to ocular tissue

Other regulations

Page: 11/11





Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: Xn Harmful. Xi Irritant. N Dangerous for the environment. F Highly flammable. 10 Flammable. 22 Harmful if swallowed. 37/38 Irritating to respiratory system and skin. 41 Risk of serious damage to eyes. 67 Vapours may cause drowsiness and dizziness. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the


through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 37 Irritating to respiratory system. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility. 15 Contact with water liberates extremely flammable gases.


Safety data sheet

Page: 1/11








Page: 2/11




Chemical nature polyester resin, cellulose ester, amino resins, organic solvent, pigment Hazardous ingredients n-butanol

Content (W/W): >= 1 % - < 2 % CAS Number: 71-36-3 EC-Number: 200-751-6 INDEX-Number: 603-004-00-6 Hazard symbol(s): Xn R-phrase(s): 10, 22, 37/38, 41, 67

1,2,4-trimethylbenzene


ethylbenzene


propylbenzene

Content (W/W): >= 0.1 % - < 0.2 % CAS Number: 103-65-1 EC-Number: 203-132-9 INDEX-Number: 601-024-00-X Hazard symbol(s): Xn, N R-phrase(s): 10, 37, 51/53, 65



mesitylene

Page: 3/11




n-Butyl acetate


xylene




Aluminum




General advice: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If inhaled: Remove affected person from danger area. Keep warm, calm and covered up. If breathing is irregular or stopped, administer artificial respiration. Seek medical assistance. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position).

Page: 4/11



On skin contact: Remove contaminated clothing. Wash skin with soap and water, rinse abundantly. Do NOT use solvents or thinners. On contact with eyes: Contact lenses should be removed. Hold eyelids open and flush with copious amounts of clean, fresh water or a special eyewash solution. Seek medical assistance. On ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting.





Page: 5/11




Handling


Storage




n-butanol, 71-36-3; TWA value 20 ppm (ACGIHTLV)

CLV 150 mg/m3 ; 50 ppm (OEL (NZ)) Skin Designation (OEL (NZ)) Skin absorption can be significant.




Page: 6/11















Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove.

Page: 7/11



Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn.





immiscible


10. Stability and Reactivity Substances to avoid: Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions.

Page: 8/11



Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. The product is stable if stored and handled as prescribed/indicated. When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced.


12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C))

Page: 9/11



Literature data. Information on: propylbenzene Elimination information: 34.4 % BOD of the ThOD (8 d) (other) (aerobic, activated sludge, domestic) Information on: mesitylene Elimination information: 0 % BOD of the ThOD (14 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted) 96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted) ----------------------------------





Sea transport IMDG

Hazard class: 3 Packing group: III ID number: UN 1263 Hazard label: 3

Page: 10/11



Marine pollutant: NO Proper shipping name: PAINT






Other regulations



Recommended use: Sprayable For multi-pack systems observe material safety data sheets of all components. Restricted to professional users. Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3: Xn Harmful. N Dangerous for the environment. F Highly flammable. Xi Irritant. 10 Flammable. 22 Harmful if swallowed. 37/38 Irritating to respiratory system and skin. 41 Risk of serious damage to eyes.

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67 Vapours may cause drowsiness and dizziness. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the


through inhalation. 65 Harmful: may cause lung damage if swallowed. 37 Irritating to respiratory system. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility. 15 Contact with water liberates extremely flammable gases.


Safety data sheet

Page: 1/10








Page: 2/10






ethylbenzene




n-Butyl acetate


xylene



Page: 3/10



Content (W/W): >= 0.2 % - < 0.3 % CAS Number: 64742-95-6 EC-Number: 265-199-0 INDEX-Number: 649-356-00-4 Hazard symbol(s): Xn R-phrase(s): 65, 66, 67, 12, 38, 62

Aluminum

Content (W/W): >= 2.5 % - < 3 % CAS Number: 7429-90-5 EC-Number: 231-072-3 INDEX-Number: 013-002-00-1 Hazard symbol(s): F R-phrase(s): 11, 15





Suitable extinguishing media: Foam (alcohol resistant), carbon dioxide, powders, water spray. Do not allow run-off from fire fighting to enter drains or water courses. Unsuitable extinguishing media for safety reasons: water jet Specific hazards:

Page: 4/10



Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health. Special protective equipment: Appropriate breathing apparatus may be required. Further information: Cool closed containers in the vicinity of the source of fire.




Handling


Page: 5/10



Storage















Page: 6/10





Respiratory protection: Respiratory protection not required. When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet (sanding/ flatting) should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Use A1P2 breathing-protection half mask in case of contact with aerosols. Hand protection: Further information on penetration time is available from the manufacturer of the glove. Data are based on information from the glove manufacturer, the raw material manufacturer or according to specifics of the product components. The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties). Follow manufacturer's advice on use, storage, maintenance and replacement of gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Wear protective gloves. Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves - material thickness: 1,25 mm Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166), Required when there is a risk of eye contact. Body protection: Body protection not required., Personnel should wear antistatic, flame-retardant clothing made of natural fibres and/or heat-resistant synthetic fibres. General safety and hygiene measures: The country-specific occupational exposure limits applicable to the substances specified in section 3 must be taken into account. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn. Contact lenses should not be worn. Remove contaminated clothing. Contaminated equipment or clothing should be cleaned after each use or disposed of. Hands and/or face should be washed before breaks and at the end of the shift.

Page: 7/10




Form: liquid Colour: metallic Odour: aromatic specific Boiling range:

not applicable




(20 °C)

Density: 0.917 g/cm3Relative density: 0.9130

(20 °C)


immiscible




Page: 8/10




12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There are no test results available for this product. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details. Do not allow to enter drains or waterways. Persistence and degradability Assessment biodegradation and elimination (H2O): Biological degradability of hazardous substances mentioned in section 3: Information on: 1,2,4-trimethylbenzene Elimination information: < 20 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum conforming to MITI requirements (OECD 301C)) Literature data. Information on: SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; LOW BOILING POINT NAPHTHA - UNSPECIFIED Elimination information: 77 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic, non-adapted) 96 % CO2 formation relative to the theoretical value (28 d) (ISO 14593) (aerobic, activated sludge, domestic, adapted) ----------------------------------



Page: 9/10






Sea transport IMDG







Page: 10/10



Other regulations





through inhalation. 65 Harmful: may cause lung damage if swallowed. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 67 Vapours may cause drowsiness and dizziness. 20/21 Harmful by inhalation and in contact with skin. 38 Irritating to skin. 12 Extremely flammable. 62 Possible risk of impaired fertility. 15 Contact with water liberates extremely flammable gases.


Safety data sheet

Page: 1/9








Page: 2/9




Chemical nature polyester resin, cellulose ester, organic solvent Hazardous ingredients ethylbenzene




n-Butyl acetate


xylene





Page: 3/9








Page: 4/9





Handling


Storage







Page: 5/9










Page: 6/9





Form: liquid Colour: white Odour: specific boiling temperature: 119.00 - 139.00 °C Flash point: 23 °C



(20 °C)


immiscible




Page: 7/9









Sea transport

Page: 8/9



IMDG







Other regulations




Page: 9/9






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