sampling & analysis data, collected 2/8/96, w/tl to a … · · 2017-02-09ko/nd* bchaive dua...

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!

SFUND RECORDS CTR

5093-00002

6Ct t I 00 J I tVIS iOt 96— I I —CO I9S7 982 OIS

1 California Department ofToxteSubatanee. Control

hazardous matemals laboratory 2151 Bmkaley Way, Barkaley, CA 94704, Ph (510)540-3101 Laboratory Ropotl For _ Organoehlotfna PaiUokla.

Cotlaotor: Albart FuWaubo

Sampling Location; T3»Huohoo Froano ,

Oata Collected: _ Data RaccNed: _ Data Exbactad: _ Data Analyiad:

02/06/96 02/14/96

HML # . to

Paga: ot

950891 950904

1 5

Extraction Mathod a:

Cleanup Method: Analyfcal Method;

v<n i /ww ~ 02121/98** Extraction Mithod: EPA 0590

03/04/98* Analysis Method: EPA 8091 ExtractiorTHoldtng Thna Met t: V— Analysis Holding Tsne Met 7: Ye»

ESSE ZT

ZK 606? - ZZH by OB-tTOt^pUUrr column OC/ECO 6 eonflmtabon by D8-8 e cokann

^Jole; OL =UuanUatnn limit - Lowest eauorabon atanoard * dilution mcior. D - Deteoted but below Ql_ NO » Not Detected. NS - Not Spiked

Comments: NS • not a piked, due to high background eonoanbaflon OL for eample HML# 950902 - 2 *w/w for Mltex. OLfor a ample HML# 950902 - 4 *w/w for Metheachlor. OLfor eample HML* 950902 - 1 *w/w tor e» other compunda.

NT - Nontarget peak.

SFUND RECORDS CTR

88224370

Analyst Supervisor

fuBst s, tebalonde Jamafl S. Garcha

|Vqpro4/BS0002/LABRPTDB1701 KP.WQ1

Signature: Signature: M

ad&jy* If atfuLi

Date: Date: .2J

Post-ll" brand fax transmittal memo 7671 #olpages »

To alL,*£ f.ii.Uuko From bo/tck*,_

" «.J IP H*t! Ait*!*. Phone < C

Per ff' Fix#

I 'd 1991 981 019 "ON XVd SHOUVMdO US 10 HY £1 :01 KOFI 96 - lHYR

6C# Z004 HVI 9 :0 I 96—1t -CO I9S» 98Z OIS

Callornla Department ot Toxic Subataneoe Control HAZARDOUS MATERIALS LABORATORY

2161 Berkeley Way, Berkeley 94704, Ph. 5KW4O4H01

L^oratory Quality Control Report Method Standard Raeovary

For HML#: to:

Page: of:

950891 950904

noqueetur: Sampling location:

Albert FuBeubo

733 Hughea

Fraano

For eamplee ooHaeted: QC Sempla extraction data: OC 8ampla analyala data: Extraction method no.: Cteanup method no.: Analyala method no.:

02108/96 02/21/96 03/04/96 EPA35SO

EPA 8091

Analyala tor Chlorinated PoaOctdec

Matrix: Solvent

retrachlortHneta Deeachloroblghenjrt gamma BHC (Lindane)

leptachlof Aldrin gemm»CHordarw_ abha-Chlorriano

4/F-DDE

Oletdrln Endrin 4,4'-DDD 4/4'-DDT Mrex [Methoxychlor

Commanta: • - Surrogate etandard

Spike

Added

mg/Kg

Method Blank Reeutt rog/Kg

1.00 1.00

1.00 1.00

1.00

ND ND ND ND NO ND

NO ND ND NO

Splka Recovery

m&/KjL 0.890 0.762 1.00 0995 0.987 1.00 1.03 0996

1,03 1.14

0940 1.04

4.07

9.51

QL

mg^_ 0.100

0.100 0,100 0.100

Spike Recovery

%

99.6

0.100

0.100 0.100 o.ioo 0.100

0.100

96.7

100 103 99.6

103 114

0,100 0.100

94.0 104

Reeoveiy Control Urnlta

Min.

%

QL - quanftatlon Bm» - lorreetceJbrallon atenderd x dilution Meter

D - detected but batew QL ND - not detected

NR - notCeoovered N/A « not applicable (see oommente). (x) m estimated value •• Method blank reeult ta not ueed to correct the method etandard aplke recovery @ Method etandard eptke reoovary b outalda ot the raeovary control Omlte. (NOT DETERMINED YET)

Andyat hrtiot a. tabalonda

SupVer. Jarnall 8. Qarcha

|t/qpro4/950902/MSTD.WQ1

3/<i/9 >

Signature *f4 96

Date

6C8 6004 RV1 9 101 86 -11 -60 I99» 88Z 019

California Department of Toxic Substances Control HAZARDOUS MATERIALS LABORATORY

2151 Borkoloy Way, Berk.ley 84704. Ph. 510-540J101

Laboratory Quality Control Report Replicate Analytls (High Cone. Samples)

HML #: to

Page: of

950691 950904

Requestor.

Sampling location:

Analysis ion

Albert Fulltflubo

733 Hughes Fresno

Date Collected: Dote Extracted: Dale Analyzed: Extraction Math.: Cleanup Method: Analysis Method:

02/08/96 02/21/96 03/04/96 EPA3550

EPA8081

Chlorinated Pesticides

D = detected but below QL ND m not detected RSD m Relative standard dev

Comments:

Analyst: luliet s. tabalonda Supervisor. Jafnail S. Oarcha

jt/qpro4/950902/REPUCATE

ilgnature

3 / t t7 9 I /Date

C ' A IQCl 007 flic 71U TV J o i t n t t u t i s t n 1> t o rn s iu n -n t i i r rn no t t svn t

State of Califomia-Heaith and Welfare Agency i f i -nazaroous Laboratoiy

HAZARDOUS MATERIALS

SAMPLE ANALYSIS REQUEST u

1. Authorization Number

1 12 212 w

HML No. -\CjC£f\ 1

. T o

u

2. Page

2o , e_

I.Requestor r f -A Address (To Receive Results): / T^y ' T». « r* J 11

5. Priority . a. Authorized by Z:

6. Date Sampled 2 £ -/ T7;.Tin» Sampled -; () Hours

9.Activity: ESEB DSMB DFPB _.DATD DPASD • Other

8. Codes (fill in all applicable codes)

a.STC

10. SAMPUNGtflCATlON

.xss- »•?: -v

|-?JK--S2'r •i*2s*5-5> • •• .vt b. Site

31

:— :. _-.T i EPA ID No. • > -2J-.

A H o T

B t - • ( j

c i - «• \:

D rt - L

« E I ' •» "t

- F ei r s .

G H

Container " TsS

l

- '-J •' :~3-\ . . . g. Field Information

S.V-

*. f." . i

'I i • 'll

. i

i - • : V* / » f U - A

12. ANALYSIS REQUESTED

a. 0 pH: K2

i~. <r *• b. G Metal Scan

c.O Metals (Spec) i

d . • W.E .T .

f. • PCS

g. • VOA-H/S

/

h J3 VOA 8240 _JH

i. • VOA-8260

j. • SVO-8270

k. G Ext Org-^Screening)

i.H'Flash A Point

m. • •' c

n .0 • U ~

r Cha»c l )^ t2 - r 1—

X. !- I

0.~a - • * • < v . - v ' - . , / •

#•

13. SUPPLEMENTAL . • A J i REQUESTS »* _

>>>,;' •• , , o

D

•

14. CHAIN OF CUSTODY

a. r t 1 ' '> < •

A / / - f i

v/

- / * / / / / \

h. v

c. _

d- _

15. SPECIAL REMARKS:

' h6UL_J . c-*-~ Tc CO I t "EviOC > •• CA"> -A^Q (.'L/)4 //fo- / 7

Ko/nd* bchaive Dua

^ / - /—L KWTitk bdviwe Dates

^ / - / L Nootflfe bctohwDsiM

16. ASSIGNED TO: _

17. LAB REMARKS:

• Date

DHS 8002 (Rev 10190) Original-Lab • Duplicate-File • Triplicate-Inspector NLY (HML)

i + •„•

.... •.*... .•»•• v. -

fort IP

ainulsoa

;EtEr^^b ObS | -

•ONTnawv

9303WI

\ KVPHOM (COMPANY NAME)• - -- --

r STATI-gF-CALIFgRNIA 93004

3MUOa%l!f^

«OREqgpA OTSC REGION I

1515 T0LLH0ySE.R0 3OTY ~~ swre

r

,oyis CA PHONE

ZIP COOE (REC

.9^11

^^r^TSUBO (209) 297-3949 'TO (COMPANY NAME)

" HAZARDOUS .MATERIALS. LAB - DTSC . . r

f *niiA- Dt-i I'»KAU:H P.O H:i'< I . . , . . . ..

700 rgp COOE (REQUIRED) r i*L«a iwu.

jJT'1 MLTinww »r — . ;—

•sender Qrecener ABtjorn. Account Na

Oacktfe' I Amort

RNON ' ; I advance - — - •* ' —

NtOMO •/

94710 2737 OTY

- BERKELEY AimtNAME/OEPT.) /TTVTn e/n-imi

PAM SCHIRO (415) 540-3101

oEi.. i.i.juUJ0r Xerana Hannon

SWTE

CA PHONE

T T

rMO_ffPllCS.lWEIGHX |LB&)y^C"CW<\ r •

2 ®55ffeia=i

—1

V .3 | *•? a t

SPECIAL INSTRUCTIONS

• s s synSsgD^ ' OSS '

• ....... ••— THAMK mi FOR SMIPPt^Z irtTH AIRBORNE EXPRESS

Qjjr- lu~"

r ' USE THtS A1RBBJL FOR ' SHPMEN1S WITHINTHE US • TO ANO FROU PUERTO RtCtt 1 ABSENT A HK3FCR SHIPMENT VCUAHON. CARRERTS UABUir •• ts LIMITED TO $100 PER '

'• PACKAGE. OR ACTUAL VALUE. w^*«R IS LESS. SPECKS

OR CONSEQUENTIAL DAMAGM • ARE NOT RECOVERABLE. SE» ..1^AND<»Oi™3«IO».

REVERSE SOE OP THE ,T -NON-NEGOTIABLE NRSU-. SCAC **** ren ia NQ fli-og37'*

"1C „ I ...HOUIt ~

DROP OFF LOCATION • AIRBORNE TCRMNAL • '

Q DROP BOX •.. • *

t n

>%

Haza rdous Ma te r i a l s Labora to ry

2151 Be rke l ey -Way

. Be rke l ey , CA 94704

(415 ) 540 -3003

Sample Rece ip t

Au thorization. No. Mm -rrsq

HML Sample No(s) • Collector's No(s) .

Custody seals V-P Presen t Absen t Broken

•W. -r--: — -W. .» •

I f p r e sen t , l oca t i on on sample ( s ) l \C \ ,

Sample Cond i t i on

Accep tab l e

Sample con t a ine r r ece ived damaged ^

S ample s r ece ived i n imprope r con t a ine r

I n su f f i c i en t s ample vo lume /we igh t f o r ana ly s i s

Sample Ana lys i s Reques t fo rm no t r ece ived w i th t he

sample ( s ) . . _ .

D i sc r epanc i e s be tween t he Au tho r i za t i on Reques t

Fo rm(ARF) and t he Sample Ana lys i s Reques t (SAR)

D i sc r epanc i e s be tween SAR i n fo rma t ion and t he

sample s

Sample Ana lys i s Reques t no t comple t e

Sample con t a ine r s no t numbered/or i l l eg j.br/^ l abe l ed

TP— Cha in -o f - cus tody no t comple t e unCh-c=> t i /<^

Sample s r ece ived w i thou t p rope r p r e se rva t i on

No i n fo rma t ion o f s ample p r e se rva t i on ac^ r fZQ.^

^ Othe r ( spec i fy ) r a lkc4o r^» <sn <350^5

Ac t ion t aken -

TT

None

Sample ana ly se s on ho ld fo r fu r the r i n fo rma t ion

Inform sample collector of problem (.•=*! ;

Samples ana lyzed a s r ece ived

O the r ( spec i fy ) -

Name (P r in t ) I n i t i a l . Da te S t a t e i f Cor r ec t ed

Tpmrv.^nm C r (§7

Supe rv i so r s app rova l

EHLB Lab. Number: 60067 Page 1 of 2

EHLB Analytical Report MICROSCOPY UNIT

Samples Received: 02/20/96

Total Samples Analyzed: 2

Date Reported dS&

Sample Description: Solid

Analysis Requested: Asbestos

Method: Polarized Light Microscopy & Dispersion Staining

References: The Particle Atlas Two, Volume II, Walter McCrone, Ann Arbor Science Publishers, Inc., Ann Arbor (1973). Asbestos Identification by Walter McCrone, McCrone Research Institute Chicago (1987).

Instruments: Bausch and Lomb Stereo Zoom 4 with intralux 5000 fiber optic light source for IX - 30X reflected light microscopy. Zeiss Standard Polarized Light Microscope with Unitron 10X Central Stop Objective Lens for dispersion staining.

Name of Submitter: Submitting Agency:

Sampling Location:

Albert Fujitsubo Department of Toxic Substance Control Region IF 1515 Tollhouse Clovis, CA 93611 733 Hughes Fresno, CA

EHLB Laboratory Number: 60067

<

Page 2 of 2

Analytical Results

Field Number Laboratory Results

H04-950894 No Asbestos detected (less than one percent by polarized light microscopy and dispersion staining). Sample contains a trace of plant fibers. Sample is entirely matrix material. (No fibers present)

H10-950900 Sample contains 90 - 100% Chrysotile Asbestos. Sample also contains a trace of paper fibers.

Heinz S t . , Su i t e 150 , Be rke l ey , CA 94710

SAMPLE/SAMPLE EXTRACT TRANSPORT LOG

[4trU2T7 59

lginal sample container; SS= split sample A= aliquot; C= citrate WET; 0= acid digest; E» extract; T= TCLP extract.

Release for transport bvlffflnCi ^.. @ 0 / 0 2 - \ 6 ^

Transported to Berkeley Way By ~7€r".rrt M C L T M - P - , • n < . . / n . t e l 0 4 ^ / P 2 - / ( f l

Received Bv ^TA Mvvi/l "ame /

9) . _ T ime /Da te jj 2y/z*/£, <? ' Name Released By

Returned to A q . P k . B y . Name

Name

.Time/Date.

^Tine/Date.

ps/wpS.1/transpo

HAZARDOUS MATERIALS SAMPLE ANALYSIS REQUEST


-

Requestor: yQ] Y" f 4. Phone - 3»f^t %f *» Address (To Receive Results): \ ^(. 5 *T^ V \ Vfrwl g.

7. Time Sampled y ^ • f d Hours 6. Date Sampled ^ —§•- *)

9.Activity: ETSEB DSMB DFPB OATD OPASO

10. SAMPLING LOCATION • I A/I OMl

• Other

QJ a. EPA ID No.

'. b. Site'

"7 33-e. Address.

11. SAMPLES

a. ID b. Collector's No.

Car

'a-.STC; '

k Region?

c_ t fC«

d. INDEX

e. PCA

f.srrE g. County

aSS53i

98231

BHESa

sinta

Bo I B M-0 2-

_fcfcS-L

•Ror

<* H H o r

Sample

d. Type

Container

e. Type f. Size «• • '*"• , — _____ > ^ Q K '

H —1.

g. Field Information

12. ANALYSIS REQUESTED £ f. • PCB k. • Ext. Org

a.8pH 9-D VOA-H/S

b/B" Metal ^ g Fty* h^VOA-8240 ^

Scan '

cO Metals

fScreenine)

• g . t S H -

Point > 7 Point - • - ^

m.3; Arlwtes U

i. • VOA-8260

d.C3 W.E.T. . j . • SVO-8270

n. D

o .D

IE

L

1X SUPPLEMENTAL

/ t REQUESTS - s-'

• Initials:.

Date*

frl/

rtaHfenr^^Aab^- i—L.

i f - /—£-KaWIld*

t - t • t NaWTid*


IS. ASSIGNED TO: .

17. LAB REMARKS:

Date

L

A

3 DHS 8002: (Rev 10/90) Originai-lab • Duplicate-file • Triplicate-Inspector

NLY (HML)

T" ''•.Svr:

rT • ' : • • •

ataiB OT wauiomia-neann ana waiara agency . . . .>••• .r wF«uiwnigi neannservices Hazardous Materials Laboratory

HAZARDOUS MATERIALS * SAMPLE ANALYSIS REQUEST _T_

1. Authorization Number V HMLNo.q^^q I . To qecftoA-";

2. Page HAZARDOUS MATERIALS * SAMPLE ANALYSIS REQUEST _T_ h\ H L- 3 <T 5

HMLNo.q^^q I . To qecftoA-";

2. Page

3. Requestor: ^ j '.jr. r U<y;--;4. Phone {*£ )M "i • •

Address (To Receive Results): \ "T o 1V-V» v • vl"\ <o f u * • "I • J ' a Authorized by.

6; Date Sampled _ . *•_ -L ' t " i t

. 7. Time Sampled ^ ^ • p £> Hours

9.Activity: DSEB DSMB dFPB . OATD dPASD dOther

8. Codes (fill in all applicable codes) .

a.STC

10. SAMPUNG LOCATION 1 tr -

b.Site

:i..-Jt .ia. EPA ID No. ..-jr--:»i *" r.:; ••

V —«'• — «• \ Z-^ .XX<£*w %*. ' * , . s. w-j

11.SAMPLES Vv .• •„.'£&'£•&•' -•' * • . - • ; • • • : • " S a m p l e v . ___

a. ID " " b. Collector's No. c. Lab No.~r

' samoie •.• uor "•".d. Type e. type

>

T

a

1 I * »j •

B 1 • e 2_ 7_ - r. t. r\

C :-> C ^

D y < t '•( A S

- E |4r- < 1 '' u • I

« F t- A. f - cir>D9)ciCc> > . . • 1

G - ' . . . 1 )

H '-!«:V mia SS jj,J • cfi

' i

Z N C l-

12. ANALYSIS REQUESTED f f. • PCB

a.ElpH k j . P £ ^ g.• VOA-H/S

b. • Metal Scan

c. • Metals

h-0[vOA-824O - I

(Spec) . . . \ ) >./ f •" A •' f' d. • W.E.T.

^ i. • VOA-8260

j. • SVO-8270

k. • ExL Org (Screening)

i..S'Flash A C,£ M" Point ' ' '

i .Q / - • ;• U m

n. •

o.D

13. SUPPLEMENTAL REQUESTS

• • • D:

Initials. ;|§Mlf!

Date

14. CHAIN OF CUSTODY »' - ' ; ( b 7L

L

b.>:tLG harr^G w Tertlfc-floTvW-ab/ta l - 01/14^-°" / V Sivan

C.

K«vn« ' » hd«w>D—

/ / - / / Si^Aur*

d.

Nna/m* hdssive Deaa

/ / - / /

Ntmoftifie


16. ASSIGNED TO: .

17. LAB REMARKS:

Date

DHS 8002 (Rev 10/90) Original-Lab • Duplicate-File • Triplicate-Inspector NLY (HML)

, HAZARDOUS MATERIALS SAMPLE ANALYSIS REQUEST

3. Requestor J ft"* Address (To Receive Results): f T > 1


faaa.iias .(STtJi

. Time Sampled j Hours

HMLNo.qg0 l|

• •• To

SlFriority Lr~^37

ZPage

'itonty LJ >> . Authorized bv ' •

8. Date Sampled "Z. X 7.

9.Activity: j8f$ES DSMB DFPB OATD DPASD DOther

I juf 01M gl

; 8. Codes (fin in all applicable codbs)

a.STC SES3

10. SAMPLING LOCATION 1 • ' r

a. EPA ID No.

b. Site

c. Address.

11. SAMPLES

"7 3 _J> /~^5 n ^ 1MB 1M •/ Cqr

a. ID b; Collector's No. a Lab No.

A I4di <&6

B i-H G QfbO^OO

C rt-i I C&OQO I

D H \ 2_, 4^<?02-• E- • H"l 6 •

F •H r^ ciQ^qcA-

G » H

Sample d. Type

Z¥

Container e. Type- f. Size

32SII '• ! i_

g. Fold Information

S'oM-w.

12. ANALYSIS REQUESTED..

a^pH € P*

bvB Metal ft , E" Scan

c. O Metals ' (Spec) .

d. • W.EJL Pg K

f. • PCS

g. • VOA-H/S

hygfvOA-8240

i. • VOA-8260

j. • SVO-8270

rTUWdr^-r-

USfFash A Point rwini | Q

- s A^Wt- r -D-s

n.'fl^TTfcrS'O

»/• 15"

1XSUPPLEMENTAL-*

" " REQUESTS- %

r"7\

O

D

. . •

14. C a. _

initials:;

Data

b: ^

c.

d.

JLc Ch^w

4fU^fcS 2/ go&w /

.Z / - /—L Hmm/Of

1 ( ' f t


16. ASSIGNED TO: _

17. LAB REMARKS:

Date

DHS 8002 (Rev 1090) Original-Lab • Duplicate-File • Triplicate-Inspector NLY(HML)

• • • 'i'l'.Tw ••• 'J* r •• : .*••• • \

California Department of Toxic Substances control Hazardous Materials Laboratory 2151 Berkeley Way, Berkeley/ CA 94704 (510) 540-3003

LABORATORY REPORT

Collector's Name: albert Fuiitsubo Location: 795 Huaes. Fresno

HML f t 95Q391 To: 950904

Auth. No.: HMT.2759 Activity: SEB Date Sampled*3^08/96 Date Received:2/ldX2£

Analytical Procedure Used: rw determined using ftccmnp.t. 935NP PK meter calibrated with pH buffers 1.4.7.10 and 13*

Reference: Rpa Methods 9040 & 9045

Analysis Results:

HML NO.

^950891 $50892 960894 950895 950896 950897 950898 950899

/

COLLECTOR'S SAMPLE NO.

H01 H02 H04 H05 H06 H07 H08 H09

TYPE OF SAMPLE

jfclLY LIQUID /SOLID ' SOLID OILY LIQUID AQUEOUS LIQ. TAR OILY LIQUID OILY LIQUID

PH

7.0 /* >13.0 >13.0 9.49 <1.00 4.26 7.0 * <1.00

DILUTION [fi» smpl + ml DIHjO)

10 + 10

10 + 10

NOTE: ' * — pH paper was used because samples are oily.

I

* ) i ' Signatures:

lJL ida R. IIejpXJ alyst

\ S-95X

DatS Milad Iskander Supervisor

ate

510 286 4561 03-06-96 03:59PM P005

California Department of Toxic substances control Hazardous Materials Laboratory 2151 Berkeley Way, Berkeley, ca 94704

Quality Assurance pH

Procedure: bY elert-rometrir; ffletnod

I. Calibration Standard Data

Reference: 9040 & 9Q45

4

1

| ID Vendor | PN

Lot No.

Exp. Date

Buffer Type

pH Buffer

mv Reading

Efficiency

I Merck 91532742 cap. 1.00 197.2

EMS 34199 7/96 sol'n 4.00 37.7 0.91000 1

EMS 34066 3/96 sol' n 7.00 -135.9

34115 7/96 sol'n 10.0 -307.0

EMS . 33228 ,7/96 sol'n 1

13.0 1

-470.6 0.93319 |

I

'TT T,-iVi«r-n+-m-v Control Sample i ======5

b« I 1 pH n nuffer-

Lot No.

Source \

Expected /Result

Observed Result

Absolute Diff. 1

1 7.0 : 9508152 VWR 7.00 6.94 0.06

1 12.45 9508186 VWRI i

T

12.45

!

4

12.26 0.19 ]

pH of DI H20 used in dilution fi.59

Duplicate Sample_Results

B - 9 5 X 5 1 0 2 8 6 4 5 6 1 0 3 - 0 6 - 9 6 0 3 : 5 9 P M P 0 0 6 8 1 7

k

California Environmental Protection Agency department ,of Toxic Substances Control lazardous Materials Laboratory (inorganic Section) 1151 Berkeley way, Berkeley, CA 94704

Pbone: (510) 540-3003 or (ATSS) 571-3003

collector's Name: ALBERT FUJITSUBO Site of Sampling: 733 HUGHES

FRESNO

HKL #: 950891 to 9S0904

Auth. No.: HHL2759 Activity : 8EB Date collected:2/8/96 Date Received: 2/14/96

Analytical samples are digested with. 1:1 HN03 (and 30% H202, and HI SCI, Procedure: if applicable) over a hot plate. Digests are cooled, filtered 3PA-SW 846 and made to final volume vith deionized H20. Metal analysis of

the digests is by ICPAES (EPA #6010). units are mg/Jcg.

Cethod: 3050 for solids; 3010 for liquids; 3005 for clean water.

3ML Number: collector's Sample No.: sample Ty^e:

As-Arsenic" Ba-BaOrium Be-Bery Ilium Cdr-Cadtaium Co-Gobalt Cr-Chromium Cu-Copper' Mo--Mo lybd enum Ni-Nickel Pb-Lead SerSelenium Tl-Thallium V-Vanadium Zn-Zinc

950891

K01 OILY LIQUIj)

<2.00 <0.10 <0.05 <0.20 <1.00 <1.50 0.69 <1.50 <1.50 <2.50 <4.00 <7.50 <1.25 12.1

950892

HO 2 SOLID

<2.00 2.31 <0.05 <0.20 <1.00 <1.50 8.16 <1.50 <1.50 <2.50 <4.00," <7.50 <1.'25 121 .

950893

H03 OILY LIQUID

<2.00 1.84 <0.05 0.40 <1.00 2.89 3.63 1

<1.50 2.21 6.20 <4.00 <7.50 <1.25 36.4

950894

H04 SOLID

10.6 22.4 <0.15 <0.45 <2.50 <4.00 3.25 <3.75 <2.50 1.86 <7.50 <15.0 <3.00 6.49

950895

HO 5 OILY LIQUID

3.21 0.47 <0.05 <0 .20

<1 .00

<1.50 1.47 <1.50 , <1.50 <2.50 <4.00 <7.50 <1.25 5.52

Notes: < « below detection limit, of method

I

I

Jrs&Ujj ^ ICPl Analyst,

Post-It™ brand fax transmittal memo 7671 » of p*g«s • f-

T#i ftMct'Sui/r '"Tint, Ca J Co.

Dept. p8t fsve-vc i FM#

i far

:ft • iemist's sig^atjdr - „ re . Date

jfeida R. Ilejay, Chemist

Date

5 1 0 2 8 6 4 5 6 1 0 3 - 0 6 - 9 6 0 3 : 5 9 P M P 0 0 1 # 1

California Environmental Protection Agency Department of Toxic Substances Control Hazardous Materials Laboratory (Inorganic Section) 2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

Collector's Name: ALBERT FUJITSUBO Site of Sampling: 733 HUGHES

FRESNO

HML /: 950891 to 950904

Auth. No.: HKL27S9 Activity : SEB Date Collected:2/8/96 Date Received: 2/14/96

•Analytical Procedure: EPA-SW 846

Method:

Samples are digested with 1:1 HN03 (and 30% H202 , and 1:1 HC1, if applicable) over a hot plate. Digests are cooled, filtered and made to final volume with deionised H20. Metal analysis of the digests is by ICPAES (EPA #6010). Units are mg/kg.

3050 for solids; 3010 for liquids; 3005 for clean water.

HML Number: Collector's Sample No.: Sample Type:

As-Arsenic Ba-Barium, Be-BeryIlium Cd-Cadiaium Co-CObalt Cr-Chromium Cu-Copper Mo-Molybdenum Ni-Nickel Pb-Lead Se-Selenium TlrThallium V-jvanadium Zn-Zinc

950896

HO 6 iAQUEOUS I <0.40 0.04 <0.01 <0.04 <0.20 I.29 2.45 <0.30 <0.30 0.97

<0 .80

<1.50 <0.25 II.1

1

1

950897

H07 TAR

<4.00 1.69 <0.10 2.83 <2.00 <3.00 ' 1.21 <3.00 <3.00 >63200 <8.00 <15.0 <2.50 ' 28.5

I

950898

H08 OILY LIQUID

<2.00 <0.10 <0.05 <0.20 <1.00 <1.50 6.46 <1.50 <1.50 19.5 <4.00 <7.50 <1.25 41.5

950899

H09 OILY LIQUID

4.17 0.14 <0.05

0.22 <1.00 55.6 1.09 <1.50 • 1.94 <2.50 <4.00 <7.50 <1.25 20.1

950903

H13 SOIL

7.87 151 <0.15 47.7 4.19 39.5 2450 <3.75 25.7 1090 10.9 <15.0 9.86 966

| ! Notes: < = below detection limit of method.

I >-st- beyond standard calibration curve; ^ . 1W.

(to be confirmed; an additional report will follow)

^ J emist's Sigtfa Date

Zaida R. Ilejay, Chemist

wilad S'. Iskander, Supervisor i , *

aa&tji */*/»> '

Date

2-95X y 5 1 0 2 8 6 4 5 6 1 0 3 - 0 6 - 9 6 0 3 : 5 9 P M P 0 0 2

California Environmental Protection Agency Department of Toxic Substances Control Hazardous Materials Laboratory (Inorganic Section) 2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

Collector's Name: ALBERT FUJITSUBO Site of Sampling: 733 HUGHES

FRESNO

HML /: 950891 to 950904

Auth. No.: HML2759 Activity : SEB Date Collected:2/8/96 Date Received: 2/14/96

Analytical Procedure: EPA-SW 846

Method:

Samples are digested with 1:1 HN03 (and 30% H202, and 1:1 SCI, if applicable) over a hot plate. Digests are cooled, filtered ^•nii made to final volume with deioniaed H20. Metal analysis of the digests is by XCPAES (EPA #6010). Units are mg/kg.

•

3050 for solids;. 3010 for liquids; 3003 for clean water.

HML Number: Collector's Sample No.: Sjnnple Ty^e:

As-Xrsenic Ba-Bfcrium* Be-Beryllium Cd-Cadmium Co-Cobalt ' Cr-Chromium Cu-Copper Mo-Molybdenum Ni-Nickel Pb-Lead Se-Selenium Tl-Thallium V-Variadium Zn-Zinc

Notes

;

j.

950904

H14 SOIL i

8.37 326 0.25 139 8.34 70.3 3080 <3.75 76.6 621 38.2 <15.0

I 14.1 2490

C V

below detection limit of method.

1 ICP Analyst,

Milad S. Iskander, Supervisor

fi/dT A A . date C^remis femiet's S igftature Date

Zaida R. Ilejay, Chemist

3W& Date

A*

R-j95X

) 510 286 4561

2

03-06-96 03:59PM P003 8

I

7^CalifornlaDopartmonti>f-Toxic Substances Control * ^ S Hazardous Materials Laboratory * » *

inorganic section -—-Quality Assurance Summary for ICP

HML Number: to

950891' 950904

w»-

tvj CO 0> * (It o>

o G> I o o> I (0 o>

(It (O •o K

o o

100j WiGS:ZI 96-S t-EO SOEZOtSOIS %96-H

DEPARTMENT OF TOXIC SUBSTANCES CONTROL

HAZARDOUS MATERIALS LABORATORY 2151 Berkeley Way, Room 515

Berkeley, CA 94704-1011 Office (510) 540-3003 or CALNET 8-571-3003 FAX (510) 540-2305 or CALNET 8-571-2305

TELECOPIER MESSAGE

DATE: g //T /1996

PLEASE DELIVER ASAP

TO :

FAX # 5/79-

FROM: ff'M L

Phone # JTJl)'^Vt)'300'Z>

NUMBER OF PAGES INCLUDING THIS COVER SHEET:

SPECIAL INSTRUCTIONS OR COMMENTS:

20

VW:rl/wp5.1 FAXHML

10'd soesofrsois 'ON xud am STVINHIVH snoaavzvH zs'Z\ m 96-51-MI

19# 2002 WJCS:21 96-SI-EO soezotsots XS6-H


Hazardous Materials Laboratory

2151 Berkeley Way, Berkeley, California 94704

cc/xs LABORATORY RETORT

HHL Sample HHitler; 950891

Authorization No.; HHL2759

COLLECTOR<8 HAKE: JAMPLIHC SITE:

ALBERT ruJlTSUBO 733 HUGHES - FRBSHO

TEST: CC/HS Purge and Trap Volatile Organic Analysis ANALYTICAL PROCEDURE: The volatile organic eexpounds are Introduced

into v&W OB™ 'Of,, 3 pis x O.SSraq 1.0 colixn GC/MS system ulth a purge-and-trap apparatus. Water saiples are purged directly, loll samples and oil slirloe sanploe sro extraeted with purge and trap grada methanol reagent. An aliquot of clear extract la diluted to vol we and Introduced Into purge-and-trap vessel for P/T CC/HS analysis, electron Inpact, full scan mess spectrometry la used for the analysis of tha eluent.

jOC/HS NETHOQ REFERENCE: EPA Hsthod 8240 GC/MS Volatile Organic Analysis.

BATE SAMPLED; 3/08/94 DATE RECEIVED AT KML: 2/14/96 PRIORITY: 92

DATE GC/MS ANALYSIS REQUESTED: 7709/96

DATE RECEIVED AT CC/IB LAB: 7/16/96

DATE(S) OF CC/HS ANALT3I9: » 2/29/94

ac/ns ANALYST!S)l LUCT HARK. 0. CARB1H. LL

CC/HS VOLATILE ORGANIC ANALYSIS Cpaga _1_ of I

CAB BUMBES

VOLATILE ORGANIC ANALYTES

WL * 950891 Method Blank

Quantitation Limit CAB

BUMBES VOLATILE ORGANIC ANALYTES

COLLECTOR'S t H01

Method Blank

Quantitation Limit CAB

BUMBES VOLATILE ORGANIC ANALYTES

UNITS mg/L ng/L ng/L

CAB BUMBES


MATRIX liquid

ng/L ng/L

74-87-3 CHLOROMETHANE m ND 5.0

! 74-83-9 BRONOMETHANE NO NO S.O

75-01-4 VINYL CHLORIDE ICHLOROETHENE) U> ND 5.0

75-00-3 CHI flRnpTHANF ND ND 5.0

75-09-2 METHYLENE CHLORIDE NO HO 5.0

67-64-1 ACETONE ND ND 5.0

75-15-0 CAROON OISULPloe NU ND 5.0

75-69-4 TRICHLOROFLUORONETHAWE ND ND 8.0

75-35-4 1.1-0ICHLOROETHENE ND ND 5.0

75-34-5 1,1-DICHLOROETHANE NO NO 5.0

156-60-5 TRANS-1.2-DICHL0R0ETHENE NO ND 5.0

67-66-3 CHLOROFORM ND ND 5.0

78-93-3 2-BUTANOHE (METHYL ETHYL KETONE) ND ND 5.0

107-06-2 1.2-D1CHLOROETHANE ND • NO 5.0

71-55-6 1.1.1-TRICHLORQETHANE ND NO 5.0

108-05-4 VINYL ACETATE ND ND S.O

50-23-5 UAKUUR IfcTRACHLORIDE NO ND S.O

75-27-4 BROMOOICHLOROMETHANE ND ND S.O

78-87-5 1.2-OtCHLOROPROPANE ND MO 5.0

10061-01-5 C1S-1,3-OICHLOROPROPENE ND MD 5.0

Nolo: no c not detected; HA = not analyzed; 0 • detected below quantitation limit

(continue on page 2) Analyst:

Supervisor:

•SOE20W015 'ON m avi srviaBiw snoaavzvH £3:31 IHJ 96-Sl-HVH

It# COOd iwcs:2t 96-ST-CO SOEZOtSOlS XS6-H

HML Sample Nurber; 950891

OEPARTRENT Of TOXIC SUBSTANCES COnieOL

HAZARDOUS MATERIALS LABORATORY

2151 BERKLEY UAY, BERKELEY, CALIFORNIA 94704

BC/MS Laboratory Report I continued)

COLLECTOR'S RAMC; ALBERT fUJlTSUBO SAMPLING SITE: '733 HUSHES - FRESNO

6C/HS VOLATIlg ORGANIC AHALYTES IP ACE 2 OF 2 1

CAS NUMBER

VOLATILE ORGANIC ANALYSIS

mi * 950891 Method Blank

Quantitation limit

CAS NUMBER

VOLATILE ORGANIC ANALYSIS COLLECTOR'S • H01

Method Blank

Quantitation limit

CAS NUMBER


UNITS »a/L ng/L ng/L

CAS NUMBER


KATRIX Uould

ng/L ng/L

7V-01-6 TRICHIOROETHENE NO NO 5.0

71-43-2 BENZENE NO NO 5-0

5.0 10061-02-6 TRANS-1,3-DICHLOROPROPENE NO NO

5-0

5.0

79-00-5 1.1.2-TRICHIOROETHANE HD RO 3.0

75-25-2 < BR0M0F0RM NO HD 5.0

108-10-1 4-METHYL-2-PENTANONE NO ND 5.0

591-78-6 2-HEXANONE NO NO S.O

127-18-4 TETRACHLOROETHEHE NO NO 5.0

79-34-5 1.1.E.2-TETRACHLOHOEYHANE NO ND 3.0

108T88-3 TOLUENE NO ND 5.0

108-90-7 CHLDR08ENZEHE ND ND 5.0

100-41-4, ETHYLBENZEHE NO NO S.O

100r42-5 STYRENE ND ND 5.0

106-36-3 XYLENE-HSP ND NO 5.0 |

95-47-6: O-XYLENE HD NO 5.0

124-48-1 DlBRONOCHLORCMETHANE HO ND 5.0

106-44-7 1.4-0ICHL0R0BEN2CNC HO NO 3.0

156-59-2 CIS-1.2-0ICHLOROETHEHE NO ND 5.0

1 •nte: HO • not HA - n«e analysed; 0 • detected bale* quant1tatIon llnlt

QL * Quantitation Limit • conc. of lowest standard x sample dilution factor ng/L » milligram per liter

Comnent(s): HHL 950891 (s a dark oily liquid.

GC/HS AnatysrCn): nrl enrln Garlnl n Slgnature(c)i Cji Report Datoi -1/13/96

Reviewer: Willi am Lin Signature: C- \ OiL. _ Review Date: 3/14/96

Supervisor: Will 1am S. Lun Signature: C V. T V- 0ate: V1*/96

A-VKJHUMMITM * *

80 "i 30820 2019 'ON m 8TI S1VIHLVH SnOQHVZVH frS:2t IHJ 96-3I-HVH

IP# POOi IWES'-Zl 96-SI-EO soczorsois XS6-H

DEPARTMENT Of TOTIC SRSTANCSS CONTROL

' Kazardoua Materials Laboratory

2151 Berkalay Way, Berkeley, California 94704

GC/MS LABORATORY REPORT

HML Sample Hunfeer: 950893

COLLECTOR'S XAMEi ALBERT FUJITSUBO DATE SANPIED: 2/08/96 fiAnrfclaO iitii , 733 hughes • FRESNO DATE RECEIVED AT HNL: ?/14/96,

PRIORITY: #2

TEST: CC/MS Puroe and Trap Valattle Srganla Analysts ANALYTICAL PROCEDURE: The volatile organic ccnpounda art Introduced

Into J&U OB -624, 3 pn x 0,S3ni 1.0 eolum GC/MS system with a purae-ond-trap apporatue. Voter aomplu era purged Ulrwlly. Soil sonples and oil atudge aanplea are extracted with purgo-and-trap grade methanol reagent. An aliquot of clear extract fa diluted to volume and Introduced Into purg»Mxf-trip veaeai for P/T GC/HS analysts. Electron Impact, full scan masa spectrometry Is used for the analysis of the aluent.

GC/MS HETHOO REFERENCE: EPA Nethod 8240 OC/MS Volatile 0manic Analysis.

DATE RC/MS ANALTSIS REQUESTED: 2/09/96

DATE RECEIVED AT GC/HS LAfli 2/16/96

DATE(S) OP GC/HS ANALYSIS: 2/29/96

GC/HS ANALYSTtSl: LUCY MARK. 0. 6ARBIN. LL

GC/HS VOLATILE ORGANIC ANALYSIS [page JL af -2- J

CAS NUH8ER


HML f 950693 Method Olank

Quantitation Limit CAS

NUH8ER VOLATILE ORGANIC ANALYTES

COLLECTOR'S # H03

Method Olank


NUH8ER VOLATILE ORGANIC ANALYTES

UNITS em/i mv/L •S/L

CAS NUH8ER


MATRIX liquid

mv/L •S/L

74-B7-3 CHLOROHETHANE HO NO 460

74-83-9 BROMOMFYHANF WD ND 460

75-01-4 VINYL CHLORIDE (CHLOROETHENE) NO ND 460

75-OO-S CHLOROETHANE NO ND 460

75-09-2 METHYLENE CHLORIDE NO NO 460

67-64-1 ACETONE ND ND 460

I 75,15-0 CARROtl 01SULFT0S AB ND 460

0 75-69-4 TRICHLOROFLUOROMETHANE NO ND 460

| 75-35-4 1.1-DICHLOROETHENE NO ND 460

75-34-3 1.1-OICHLOROETHANE NO M> 460

156-60-5 TRANS-1.2-DICHL0R0ETHENE ND NO 460

67-66-3 CXLOROrORM NO ND 460

78-93-3 2-BUTANONE (METHTL ETHYL KETONE} ND 440 " |

107-06-2 1.2-0ICHLOROETHANE ND ' ND 460 |

71-55-6 1.1 -1-TRtrHI nsriETHANE NO NO 460

108-05-4 VINYL ACETATE ND ND 460

56-ZJ-S CARBON TETRACHLORIDE ND ND 460

75-27-4 BR0M00tCHLOROHETHANE ND ND 4AA

78-87-5 1.2-OICHLOROPROPANE ND NO 460

10061-01-5 CIS 1,3 DICHLOROPXOPENE ND NO 460

Nota: ND • not detected; NA » not analyzed; 0 = detected below quantitation limit

(continue on page 2) Analyst:

Stpervlsor: C.S&2

W'd soesot'sois *on xvj avi sra3J,vn snoaayzvH ssisi m 96-si-xvh

* tt sooa n d t s ' • zi 96-si-eo SOEZOPSOIS XS6-X

NHL Sample Hunfcer: 950693


HAZARDOUS MATERIALS LAB0RA70RT

2151 BERKELEY UAT, BERKELEY, CALIFORNIA 94794

ac/m Laboratory Report (continued)

COURCTOR'S NAME: SAMPLING SITE:

ALFLCRT FUJITSUOO 733 HUGHFS FRESNO

CAS NUMBER

VOLATILE ORGANIC AMALTOIO

urn. « 950893 1 Method Quantitation llnlt

CAS NUMBER

VOLATILE ORGANIC AMALTOIO an.LECTOR'S 9 R03

•lar* Quantitation

llnlt

CAS NUMBER


UNITS •g/l eoA na/L

CAS NUMBER


MATRIX liquid

eoA na/L

I 79-01-6 IRICHLOROETHENE ND ND 460

71-43-2 BENZENE ND ND 460

10061-02-6 TRANS-1,3-OICRLOROPRCPERE m NO 460

79-00-3 1.1.2-TRICHLOnoeTUAMC ND ND 460

75-25-2 ' 8R0M0F0RM ND NO 460

106-10-1 4-METHTL-2-PENTAN0NE NO NO 460

391-7B-6 2-HEXANONB NO un 1611

127-18*4 TETRACH10S0ETHENE ND ND 460

79 34 5 1,1.2,2-TCTRACMLOROETNANC mi NO 460

108-88-3 TOLUENE D ND 460

108-90-7 CHL0R0BENZENE ND ND 460

100-41-4 ETHTtBENZENE 0 NO 460

100-42-5 STTRENE ND ND 460

108-36-3 XYLENE-MBP 620 NO 460

95-47-6 O-XTLENE D NO 460 '

124-48-1 DIBROMOCHLOROMETRANE NO ND 460

106-44-7 1,4-01CHL0R0BEN2EME. NO ND 460

156-59-2 CIS-1.2-DICHLOftOEThCNE ND ND 460

•

Mote: ND » not Utietod) RA — not analysed; D • detect ad bo low quantitation Unit QL a Quantitation Unit • eonc. of lowest standard x sample dilution factor

Carment(B):

9S0H93 In a Aart nil Oua to the praaanes of high lavols of non-tarsat volatile eeoBoundo, a high dilution factor was needed. For toluene, athylbenzena and o*xylenes, each conpound Is estimated to be less than 300 mg/L.

GC/MS ANNLYARTSJT ORLANDO CARBLN

Reviewer: UlUlaw LUN

Supervisor: _ Willi BIB 8, lun

SLGNATURA(A): XM,

SIGNATURE: Ti

Signature: L i

AnnarYngioutr.no

Report Date: _.?/12/06_

Review Date: 3/14/96

Data: 3/14/96

SOSZOT'SOIS 'ON XVJ m STVIHHIVH SNOAAVZVH SS:ZI IHJ 96-SI-HVH

It# 900J HdCS:ZI 96-SI-EO S0t20»90lS XS6-H

OEPAWCNT OF TOXIC SUBSTANCES CONTROL

Bazardout KaCerlali Laboratory

2151 Berkeley Way, Barkelay, California 94704

GC/NS LABORATORT REPORT

HML Sample Ntnber: 950895

8 COLLECTOR'S NAME: ALBERT RUITSUBO

i I.,.. . —•

DATE SAMPLED: 2/08/96 , 8 1 SAMPLING SITE: 733 Hl^Hes • TKESNO OA lb RtCblVkD AT HML: 2/14/yO., 1 H PRIORITY: #2

11 TISTi CC/MS Purge and Trap Volatile Organic Analysis | ANALYTICAL PROCEDURE: The vol at I la organic coapowdt are Introduced | Into JEW OB1* *624, 3 pa x 0.53sn I.D eolian CC/MS tystem with | a purge-and-trap apparatus. Water eanplea are purged directly.

H Soil Knplea and oil iluige samples are extracted with purge*and-| trap grada nothanol reagent. An aliquot of clear extract fa | diluted to vol una and Introduced Into purge-and-trap vaaaal for | P/T CC/MS analysis. Electron Inpaet, full scan mass spectrometry

I fs used for the analysis of the eluent. R GC/MS NETMCO REFERENCE: EPA Method 8240 GC/MS Volatile Organic Analysis.

DATC CC/MS ANALYSIS BCOUrSTTBl 2/09/96

DATE RECEIVED AT GC/NS LAB: 2/16/96

DATEfSl OF GC/MS ANALYSTS: 2/29/96

GC/MS ANALYSTfSl: LUCT NARK. 0. GARB IN. 11

GC/MS VOLATILE ORGANIC ANALYSIS Jpage, of _2_ 3

CAS NUMBER


HML # 950B95 Method Blank

Quantitation Lialt CAS

NUMBER VOLATILE ORGANIC ANALYTES

COLLECTOR'S f H05

Method Blank

Quantitation Lialt CAS

NUMBER VOLATILE ORGANIC ANALYTES

UNITS •9/L •O/L ng/L

CAS NUMBER


MATRIX liquid

•O/L ng/L

74-87-3 CHIOROMETHABE NO ND 1.2

74-83-9 BRONGMCTHAME NO ND 1.2

75-01-4 VINYL CHLORIDE CCHLOROETHENE) NO ND 1.2

75-00-3 CHLOROEYHANE ND ND 1.2

75-09-2 METHYLENE CRLORIDC D K> 1.2

67-64-1 ACETONE 1.6* W> 1.2

75-15-0 CAROCN OlSUtrtDC NO ND 1.2

75-69-4 TRICHLOROFLUOROMETHAIE NO NO 1.2

75-35-4 1.1-01CHLOROETHENE ND ' ND 1.2

75-34-3 1.1-OICHLOROETHANE NO ND 1.2

156-60-5 TRANS-1.2-01CHLOROETHENE NO ND 1.2

6/-66-S CHLOROFORM NO NU 1.2

78-93-3 2-BUTANONE (METHYL ETHYL KETONE) ND ND 1.2

107-06-2 1.2-OICHLQROEYHANE NO ND 1.2

B 71-55-6 1.1.1-fRlCMtOftOGTHANE ND ND 1.2

I 108-05-4 : VINYL ACETATE NO ND 1.2

| 56-23-5 CARBON TETRACHLORIDE ND ND 1.2

75-27-4 BRONODICHLOHOMETNANE ND ND 1.2

78-87*3 1.2-DICHLOROPROPANE ND ND 1.2

10061-01-9 CI3-1,3*0ICHLOROPaOPENe ND ND 1.2

Note: W • not detected; HA - not analyzed; 0 • detected below quantitation limit

(continue on page 2} Analyst:

Supervisor

SOEAORAO-IS 'ON XVJ A\N STVIMVH SNOAAVZVH 93:21 m 96-SI-HVH

17# LOOd WJESJZt 96-Sl-CO S0C20VS01S XS6-H

HHL San te Nunber; 950895

OEPARTTlEJiT OF TOXIC SUBSTANCES COBTKO.

HAZARDOUS MATERIALS I MORATORY

2151 BESXELET HAY, BERKELET. CALIFORNIA 94704

uu/ns Laboratory Report (Continued)

COLLICTOII'S NAME: SAMPLING SlTEi

ALBERT FUJtTSUBO 733 HUGHES - FRESNO ]

CAS RIMER


HHL * 950895 Method Quantitation limit

'

CAS RIMER

VOLATILE ORGANIC ANALYSIS COLLECTOR'S « H03

Blank Quantitation

limit

'

CAS RIMER


UNITS mg/L mgyi •OA I

CAS RIMER


MATRIX llauid

mgyi •OA I

79-01-6 TRICHLOROETRENE NO . NO 1.2

71-43-2 BENZENE NO Nl) 1.Z

10061-02-6 TRANS-1.3-01CHLOROPR0PENE HO ND 1.2

70-00-S 1.1.2-TRIcniORoCTHANe NU ND 1.2

73-25-2 BROHOFGRM M0 ND 1.2

108-10-1 6-METHYL-2-PENTANONE NO ND 1.2

591-78-6 2-HEXANONE HO ND 1.2

1Z7-18-4 TETRACHLOROETHENE NO ND 1.2

79-3* 5 1,1,2,2-TtTRACHLOAOeTMANE NO ND 1.2

108-88-3 TOLUENE ND ND 1.2

108-90-7 CHLOROBENZENE ND NO 1.2 y 100-41-4 ETHYLBEH7NNF NO NO 1.2

100-42-5 STYRENE ND ND 1.2

106-38-3 XTIENE-H4P NO ND 1.2

95-47-6 O-XYLENE NO ND 1.2

1Z4-48-1 01BRCH0CHLOR0METHANE NO HO 1.2

106-46-7 1,4-OICHLOROBENZCNC ND ND 1.2

136-59-2 CIS-1.2-0ICHL0R06THENE to ND 1.2

• •

Not a j NO a not dot•«tod; NA • not analysed; D - iNrlcclcd below quantitation Unit OL a Quantitation Limit • conc. of loue*t standard x sample dilution factor •9/L « milligram per liter

Coanent(s): * 950895 la a gel-like liquid. Value for acetone la an approximation.

GC/MS Analyst(a): nrUndo c»rbi»

Reviewers William Lun

Supervisors Will 1am S. lun

cignature(e)

Signature

SIgnature

AIW/IMUMNI MO

T^j2sZt-{ Report date: —3/12/96

Review Date: 3/14/96

Date: 3/14/96

LO'i SO£2OWOTS 'ON m AVI SIVIMVW SNOAAVZVH 95:21 m 96-SI-HVH

V# 8004 YI4ES :ZI 96-SI-CO soezovsots XS6-3

DEPARTMENT OF TOXIC SUBSTANCES CONTRm


215! Berkeley Way, Berkeley, California 94704

CC/MC LABORATORY RETORT

•ML Sample Butbert 950B96

COLLECTOR'S KAHC: ALBC T MJtTSUBO

Autnorization NO.: HNLZ/DV

DATE SAMPLED: 7/08/96 3AWL18G SITE! 753 HUGHES - FRESNO DAIS RECEIVED AT HML: 2/14/96

PRIORITY*

TEST: GC/MS Purge end Trap Volatile Organle Analysts ANALYTICAL PROCEDURE: The volatile organic emipounde era Introduced

Into J8W OB"" -624, 3 pa x 0.53m I.D coluan GC/HS system with a purge-and*trap apparatus. Water samples are purged directly. Boil emrpleo and oil aludja eoflptes ore Mlrevled with purge*and* trap grade methanol reagent. An aliquot of clear extract Is diluted to volume end Introduced Into purge*and-trap vessel for P/J analr»la. electron lopacr, full scan mess spectrometry la used for the analytic of the eluont.

6C/HS METHOD REFERENCE: EPA Method 8240 GC/HS Volatile Organic Analysis.

DATE CC/MS ANALTSIS REQUESTED: 2/09/96

DATE RECEIVED AT GC/MS LAS: 2/16/96

OATEIS) or CC/KS ANALTSIS: 2/2V/V6

GC/HS ANALTSTISI: IUCT NARK. 0. GARB IN. LL

GC/HS VOLATILE ORGANIC ANALYSIS Ipage of JL 1

CAS NUMBER

VULAIILC ORGANIC ANALYTES

HML 0 950896 Marhnrt Onentltitlon CAS

NUMBER VULAIILC ORGANIC ANALYTES

COLLECTOR'S 9 H06 Blank Limit VULAIILC

ORGANIC ANALYTES

UNITS mg/L mg/L mg/L

MATRIX liquid

I 74-87-3 CHIOROMPTHANE NO ND o.ooo

I 74-83*9 BROMOMETBANE HD NO 0.050

73-01-4 VINYL CHLORIDE (CH10R0ETHENE) NO ND 0.050

75-00-3 CHLOROGTRANE no ND 0.050

75-09-2 METHYLENE CHLORIDE ND •

ND 0.050

67-64-1 ACETONE 0.37* ND 0.050

73-13-0 CARNCm DISULHOb ND ND 0.050

75-69-4 TRICHLOROFLUOROMETHANE ND - NO 0.050

75-35-4 1.1-DICHLQROETHENE NO ND 0.050 1

73-34-3 1,1-OICHLOROETHANE NO ND 0.050

156-A0-5 TRANS-I.2-OtCHLOROETHENE ND ND 0.030


78-93-3 2-BUTANONE (HETHTL ETHYL KETONE) 0.075 NO 0.050

107 06-2 1,2-FIICHLOROCTHANE NO * ND 0.050

71-55-6 1.1.1-TRICHL0R0ETHANB ND HD 0.050

108-05-4 VINYL ACETATE M> . NO 0.050

36-23-3 CARBON TETRACHLORIDE ND ND 0.050

75-27-4 BR0M00ICHLOROMETHANE 181 ND O.OSO

78-87-5 1,2-OICHLOROPROPAHE ND ND 0.050

10061-01-5 CIS-1,3-DICHLOROPROPENE ND ND 0.050

Note: NO • not detected; NA * not analyzed; D • detected below quantitation limit

(continue en page 2) Analyst: 32 Supervisor:

80'd SOEZOWOIS 'ON XVI 8V1 STVIH3.1VH SNODNYZVH £3:21 M 96-S1-HVH

600<£ IWES:ET 96-Sl-CO ' S0E20YS0IS XS6-H

E:CTO*"9 HMC< .IMG SITE:

—.

8ML Saaple Ruifcer: 950B96

DEPARYHEIT OF TOXIC SUBSTAXCES CONTROL

HAZARDOUS KATEIIALS LABORATORY

2151 BERKELEY MAY, BERKELEY, CALIFORNIA 94704

wi/rc; Laboratory Report (Continued)

ALBERT PUJITSUBO 733 HUGHES - FRESNO •

CAS BUH8ER


RML * 950896 Hettiod Blank

Quantitation Unit

CAS BUH8ER

VOLATILE ORGANIC ANALYSIS COLLECTOR'S t H06

Hettiod Blank

Quantitation Unit

CAS BUH8ER


UNITS •tg/l M/l M/L

CAS BUH8ER


MATRIX liquid

M/l M/L

79-01-5 TRICHtOROETHENE. Ml ND 0.050

71-43-2 BENZENE ND ND 0.050

10061-02-6 TRANS-1.3-DICHLOROPROPEME NO NO 0.050

79-00-5 1.1,2-rntCNLOAOCTIIANC NO ND U.U50

75-25-2 BROMOFORH ND ND 0.050

108-10-1 4-METHTL-2-PENTANONE ND NO 0.050

591-75-6 2-HEXANONE ND ND o.oso

127-18-4 1 tetrachloroethene: NO HO 0.050

79 54-5 1,1,Z,Z-TETRACHLOROCTHAN6 ND ND 0.050

108-BB-3 TOLUENE ND ND 0.050

108-90-7 CH10R0BEHZEHE ND ND O.OSO

100-41-4 E1HYLBEN7FtlF ND ND 0.050

100-42-5 S1YREHE ND NO 0.050

108-38-3 XYLENE-M&P ND ND 0.050

95-47-6 Q-XTLENE ND NO 0.050

124-48-1 01BR0H0CHLOR0MET HANE ND NO 0.050

106-46-7 i 1,4-DlCllLOROOCHZCHC ND ND 0.050

156-59-2 CIS-1,2rOICHtOROETHENE ND NO O.OSO

Hotat RD - net detected) MA • not' analyted; D - detected below quantitative! limit 01 » Quantitation Limit =• cone. of loueat standard x sample dilution factor

Canment(s): • 950896 fa a clear colorless liquid. Value lor acetone Is an approximation.

GC/KS Analyst(a): Orlando Carfafn

Reviewer: will TAW LUN

Supervisor: William 3. lun-

Sl9nature(o)<

Signature: \AjJi )<

Signature

£ T T R E P O R T O E T E T _ J 5 K L 2 Z 2 £ _

: V|~»y.r- - i^ Review Date: 3/14/96

A • - — 3/14/96

AwarwfictocotJriD

SOSEOfrSOIS "ON XVi 8U1 STVIH3IVH SnOOTON 13:21 IH3 96-3I-HVH

IV# 0104 HJES'ZI 96-St-CO S0E20VS01S X56-H

DEPARTMENT OF Tfttrr SUBSTANCES CONTROL


2151 Berkeley Way, Barkeley, California 9*704

GC/MS LABORATORY REPORT

WL Sanpla Nuwbsri 950898

If COLLECTOR'S HARE: ALBERT FUJITSURO DATE SAMPLED: P/OR/OA OATE RECEIVED AT KML: 2/14/96

TEST: CC/TI9 Purge end Trap Volatile Organic Aiwlvalm AHALYTICAL PROCHJURE: The volatile organic compounds are Introduced '

Into Jtu OB -624, 3 pa x 0.53am l.D colutn CC/KS aysteo elth a purge-and-trap apparatus. Meter a tuples are purged directly. °ll #lud«e ""P1" «re extracted with purgc-and-

dilStM «thanol rewent. An a Iquat of clear extract la P/T GC/MS «^K^?." I ,n"ocfcfd into purao-ond-trsp vassal for Is uSd B!n!irU-,Elf:tr?,J,,'>aft' »can Mmaa jpcctrooatry

rr/w. imr^„yy for analyala of tba alusnt. CC/MS METHOD REFERENCE: EPA Method 8240 CC/MS Val.til. Orosnia An.lvaL

PRIORI TV: ' so

DATB CC/MS ANALYSIS REQUESTED: 2/09/96

DATE IECEIVB) AT CC/MS LAB: 2/16/96

OATE(S) OF GC/NS AHALTSIS: 2/29/96

CC/MS ANALYST(3): LUCY MARC. O. GARBtH. LL

CAS NUMBER

VOLATILE ORGANIC ANALTTES

Wl # 950898 ' —•

Method Quantitation Limit

CAS NUMBER


COLLECTOR'S # 808 at.A.

Quantitation Limit

CAS NUMBER


UNITS mg/L ap/L 109/L

CAS NUMBER


MATRIX IfQuid

109/L

74-87-3 CHLOROMETHANE ND 76-A1-0 8ROMONGTHAUG

*u 46U 75-01-4 YINYL CHLORIDE (CHLOROETHEHE) HD ND 460 75-00-3 CHLOROETHANE ND ND 460 75-09-2 METHYLENE CHLORIDE ND NO 4AO 67i64--T ACETONE HO ND 460 75-IS 0 CARBON DISULFIDE ND HD 460 75-69-4 TRICHLOROfLUORCHETHANE HO HD 460 75-35-4 1.1-01CHLOROETHEHE ND NO 460

> 75-34-3 I.VOICHLOROETHANE uo HD 440

156-60-5 TRANS-1.2-01CHLOROETHENE ND ND 460 67-66-3 CHLOROFORM ND ND 460

78-93-3 2-BUTANOHE (NETHTL ETHVL KETONE) ND ND 460 I 107*06-2 1,2-DICHLOROETHANE NO * ND 460 I 71-53-6 1 ,.1.1-tr i CHLOnoer iianc ND HU 460 108-05-4 VINTL ACETATE ND ND 460 56-23-5 CARBON TETRACHLORIDE NO ND 460

1 75-27-4 BROMOD1CHLOROMETHANE ND m 440

1 78-87-5 1.2-DICHLOROPROPAHE ND NO 460 1 10061-01-3 CI S-1,3-OICHLOROPRUKtRh HD ND 460 8

Note: 80 • not detected; BA • not analyzed; 0 • detected below quantitation liratr

(continue on page 2) Analyst

Supervisor sor: —

Ol'd S0620W0IS 'ONXyj avi* STVIiELVH SnoaaVZVH 83:21 m 96-Sl-MI

9# ttOi Hit ' s -Zl 96-SI-CO soezotsots XS6-H

HHl Sample Number: 950898

DEPARHEXT OF TOXIC SUBSTAHCES CONTROL

HAZARDOUS HATFRIAIS IAMNUTORY

2151 BERKELEY RAY, RERKEUET, CALIFORNIA 947D4

CC/NS Laboratory Report (Continued)

b COLLECTOA'J NAHfc: SAMPLING SITE: ALBERT FUJITSUBO 723 HUGHES - FRESNO

CAS NUMBER


RNL 0 950898 Method Quantitation CAS NUMBER

VOLATILE ORGANIC ANALYSIS COLLECTOR'S 0 ROB

Blank 1 lair

UNITS ma/L aq/L mg/L

MATRIX liquid

79-01-6 TRlCHLOROETHENE NO NO 460

71-43-2 BENZENE NO an 460

10061-02-6 TRANS-1.3-0ICHLOROPROPENE NO NO 460

79-00-5 1.1.2-TRICm.OROeTNANE NO ND 460

75-25-2 BRCN0FGRM NO NO *. 108-10-1 4-METHYL-2-PEHTAN0NE NO NO 460

591-78r6 2.-HEXANONE HO NO 460

127-18t4 TETRACHLOROETHENE ND NO 460

T9-34.-3 1.T,Z,2-TETRACHLOR0ETHANE NO ND 460

: 108-88-3 TOLUENE NO ND 460

108-90-7 : CHL0R08EHZENE NO NO 460

100-41-4 ETMTLBENZENE NO NO 460

100-42-5 STYRENE NO ND 460

108-38r3 XYLEHE-M4P 0 NO 460

95-47-6 ' O-XYLENE ND NO 460

124-48-1; 0IBROMOCHLORONETHANE ND ND 460

j 106 46 7 1.4-0 ICHLOItOBCNZCME NO ND 460

156-59-2 ClS-1,2-DlCHLOROETHENE ND ND 460

I

Rote: ND - not detected, KA - nut otwlyced; D » detected DelOU quantitation limit QL.» Quantitation Limit » cone, of lowest standard x sample dilution factor mg/L • milligram per liter

Comment(s): •950890 Is a dark oil liquid. Due to the high levels of non-target volatile compounds present in the sample, a lower quantitation limit cannot be achieved. Xylene* ere evilnoted to be less than 140 mg/L.

CC/NS Analyst(s): Orlando Garbin

Reviewer: m i I ion itm

Supervisor: _

ASHCJMMOtUt lis

Wi I Haw S. tun

SlonaturaltlCReport Date: —3/12/96

Review Dote: 3/14/90

KTJ/ <CL DATE: 3/14/96

I I'd S0E20W01S mm svi stvimlvh snoaavzvH 8s:si m 96-si-hvh

I 9# ZIOd KdC'S'tZl 96-St-EO S0EZ09S01S XS6-H


Hazardous Haterfala Laboratory

2151 Berkeley Hay, Berkeley, California 94704

HMl Sample Ktwberi 9S0899

COLLECTOR'S NAME: ALBERT FUJITSUBO DATE SAMPLED: 2/06/96

PRIORITY: #2

TEST: CC/NS Purge end Trap Volatile Org onto Anolyofa ANALYTICAL PROCEDURE: The volatile organic caqMwds era Introduced

Into JIU 01™ *024, 3 pa x 0.53na I.D coluan GC/HS system with a purge end trap apparatus. Votor aanplca era pureed directly. Soil canplea and oil sludge aaoplce are extracted with purga-and-trap grade methanol reagent. An aliquot of clear extract la

1 diluted ta vnlimn and Introduced Into purge-and-trap vassal for I , ?H CC/NS analysis. Electron Impact, full scan ease spectrometry | 1s used for the analysis of the eluant.

J SC/HS METHOD REFERENCE» EPA Method 8240 GC/HS volatile Organic Analysts.

BATS OC/MC ANALYSIS REQUESTED] 2/00/96

DATE RECEIVED AT BC/MS LAB: 2/16/96

OATPfS) OF CC/NS AHALYSIS: 2/29/96

BP/US ANSI YSTfS): LUCY MARK. O. GARBIN. LL

BC/MS VOLATILE ORGANIC ANALYSIS [page _1_ of 1

CAS NUMBER

VDI4TIL8 ORGANIC ANAIYTES

IN. # 950899 Method Blank


NUMBER VDI4TIL8 ORGANIC ANAIYTES

COLLECTOR'S S H09

Method Blank


NUMBER VDI4TIL8 ORGANIC ANAIYTES

UNITS rs/L "S/1 mo/L

CAS NUMBER

VDI4TIL8 ORGANIC ANAIYTES

MATRIX liquid

"S/1 mo/L

74-87-3 CHLOR Oil ETHANE KD ND 0,050

74-B3-9 BBOMOMETHANE X) ND O.OSO

75-01-4 VINYL CHLORIDE (CHL0R0ETHENE) ND ND 0.050

75-00-3 CHLOROETHANE «> ND o.uou

75-09-2 METHYLENE CNL0R10E ND • ND 0.050

67-64-1 ACETONE 1.0- NO 0.050

73r13-0 CARBON DISULFIDE ND ND 0.050

75-69-4 TRICHLOROFLUOROMETHAN E ND NO 0.050

75-35-4 1.1-DICHLOROETHENE ND ND 0.050

75-34-3 1.1-01CHLOROETHANE ND NO 0.050

156-60-5 TRANS-1,2-0ICHLOROETHENE ND ND 0.050


78-93-3: 2-BUTANONE CHETHTL ETHYL KETONE) 0.14 NO 0.050

107-06-2 1,2-DICHLOROETHANE ND ND 0.050

71-55-6 1,1.1-TR1CHLOROETHANE ND ND 0.050

108-05-4 VIUYL ACETATE ND ND 0.050

56-23-5 CARROH TETRACHLORIDE ND '

ND 0.050

75-27-4 BROHODICNLORONETHANE HD ND 0.050

1 78-87-5 1.2-0ICHLOROPROPANE NO ND 0.050 1

1 10061-01-9 CIS-1,3-0 ICHLOROFROrENC HO ND 0.060 1

Notei ND » not detected; NA " not analysed; D » detected below quant 1 tatlon Ifmlt

(continue on pago 2) Analyst:

Supervisor:

21 *d S0820W01S 'ON XVd evi STVUELVH snoaavzvH 65:21 m 96-SI-WH

19# CtOd 96-Sl-CO SOCZOtSOIS XS6-H

[ecLUCToa's NAMES SAMPLING SITE:

KHL SAMPLE Number: 93QB99

DEPARTMENT OP TOXIC SUBSTANCES CONTROL


2151 6BUELEY UAY, BERKELEY, CALIFORIIA 94704

GC/ifs Laboratory Report (Continued)

M£5B£ _?33 HU

ruJiTwao HUGHES - FRESNO

1 CAS 1 NUMBER


BNL 9 I 950899 Method Blank

Quantitation Unit

1 CAS 1 NUMBER

VOLATILE ORGANIC ANALYSIS COLLECTOR'S 9 H09

Method Blank

Quantitation Unit


UNITS ra/L na/L «Q/I.


MATRIX Mould

na/L «Q/I.

79-01-6 TRICHLOROETHENe W NO 0.060

71 -<3-2 BEN2EN8 NO ND 0.050

10061-02-6 TRAMS-1,3-Dt CHLOROPROPENE ND ND 0.050

70-00-J 1.1,2-TR I CHLOROETIIANC NO NO 0.050

75-25-2 BR0K0F0RM ND NO 0.050

108-10-1 4-NETHTl-2* PENTANONE M> NO 0.050

591-78-6 2-HEXANONE ND HO 0,050

127-18-4 TETRACHLGROETHENE ND HO 0.050

1 79-34-5 1.1,2.2-TCTRACM.tmutlHAflt ND ND 0.050

108-88-3 TOLUENE ND ND 0.050

! 108-90-7 CHL0R0BEN2EME ND HO 0.050

100-41-4 ETHYLBENZEME ND ND 0.050

100-42-3 STTREHE ND HD 0.050

108-38-3 XYLENE-MSP. - ND ND 0.050

93-47-6 0-XTLENE ND ND 0.050

124-48-1 OIBROMOCHLOROMETRANE ND ND 0.050

106-46-7 1.4-D1 CltLOROOCNZCNE ND ND 0.050

156-59-2 CIS-1.2-DtCNLOROETKENE ND NO 0.050

.

Not* NO • not deteetcd; HA • not onolyced; D • detected below queiit I to l lu i i UMH QL • Quantitation Limit » conc. of lowest standard x sanple dilution factor

Ccnment(S)t * 950899 la a clear liquid. Value for acetone Is an approximation.

6C/KS ARA(YSR(N): ORLANDO OARBLN SIREPORT BATE: 3^12/96,

Reviewer: William Lum Signature: IAA ^T/ - Review Date: . 3/14y96..

signature: . CQj K< -Supervisor: William S. turn Data: 3/14/96

A.-vnumatc*3irja

SOEEOWOIS "ON m avi sivimvH snoawvH 00:81 m 96-S1-WH

i t# t io<j lues '• zi 96-st-eo SOGZOtSOIS XS6-H

DEPARTMENT OF TOVTR SUBSTANCES CONTROL

Hazardous Material. Laboratory *"*«" ?50°" to 9?0_Bg>

2151 Barkeley Way, Berkeley, California 94704

CC/MS LABORATORY REPORT

COLLECTOR'1 NAME: ALBERT FUJITsusn

Authorization No,; HML2759

DATE SAMPLED: •J/f)A/OA CAlk RECEIVED At HMLi 2/14/94 PRIORITY: SP

amvTiSu'.SS&J!?' T"P Volatfla Offl-nlc Analysis AJ<ALTTICU PROCn)UR The volatile organic compounds are Introduced

1 Into JM na -624, 3 Jia * O.S3on t.O coluen CC/ng system with Wat<: ara Erectly.

"11 fSi™ 'J1 ltud3" amples are estracted ulth purge-ami-! ®tth«iol rMg#n(. An alfcpjot of clear extract It

P/TBe/M°J2i!I?; *ntro<*Jc«d Into purga-snd-trcp vessel for I P/T GC/MS analysis. Electron Impact, full scan oasa spectrometry

for «n«1y*fs of theeluent. »P»«r«iniry [_CC/Ms HhiMP HEFEREWCE; EPA Method 8240 GC/NS Volatile Oroanlc Analysis.

OATE GC/HS ANALYSIS REQUESTED: 2/09/96

DATE RECEIVED AT BC/MS LAB: 2/14/%

DATE(S) OF CC/MS ANALYSIS: 2/29/96

GC/MS ANALYST(S): LUCT MARE. 0. GARB IN. LL

'

CAS NUMBER


MMt a Method Suantltatlwi Limit

CAS NUMBER


COLLECTOR'S * Blank Blank

Suantltatlwi Limit

CAS NUMBER


UNITS M/L R9/L M9/L

CAS NUMBER


MATRIX water

M9/L

74-87-3 CHLOROMETHAHE NO ND 5.0

i 74-83-9 BRCMOMETHANE NO NO 5.0

75-01-} . VINYL CHLORIDE (CHL0R0ETHENE1 NO WD 5.0 75-00-3 CHLOROETHAHE

ND NO 3.0 75-09-2 METHYLENE CHLORIDE

NO ND 5 0 67-64-1 ACETONE

NO NO 5.0 73-15-0 CARBON DISULFIDE

ND NO 5.0 75-69-4 TR1CXLOROFLUOROMETHANE NO ND 5.0 73-35-4 1.1-0ICHL0R0ETHENE M) ND 5.0 75-34-3 1,1*DICHLOROETHANE NO NO 5.0 156-60-3 TRANS-1.2-01CHLOROETHENE ND ND 5.0 67-66-3 CHLOROFORM

ND HD 5.0 70 93-3 2-BUTAHONE tMETHTL ETMTL KElUNfci ND • ND 3.0

107-06-2. 1.2-OlCHLOROETHANE ND HD 5.0 71-55-6 1,1,1-TRICHLOROETHANE ND NO 5.0

108-05-4 VINYL ACFTAtS NO MO S.O

56-23-5 CARBON TETRACHLORIDE ND ND 5.0 T3-27-4 BROHOOICHLOROMETHAME NO HD 5.0

78-87-5 1.2-0ICHLOROPROPANE ND ND

NO

5.0

10061-01-3 CIS-1.3-0ICHLOROPROPENE NO

ND

NO 5.0

Note: ND • not detected; HA • net analyzed; D ° detected below quant ItatIon l imit

(continue on page zj Analyst:

Supervisor:

nri so£20wois 'on xvj m stohhiw snoaavzvH oojei m 96-si-avw

XYtt StOi IMtS-ZI 96-St-CO S0C20TS0IS XS6-H

HML Sample Nuifeer: 950B91 to 950899



2151 BERKELEY UAT, BERKELEY, CALIFORNIA 94704

GC/IQ Laboratory Icporc (Continued)

COLLECTOR*3 KA1C] SAMPLING SITEj

ALBERT fUJtTSUBO 733 HUGHE5 • FRESNO

CM mencR

VOLATILE ORQAMIC

- ANALYSIS

HML # Storage Method elane

Quantitation limit

CM mencR

VOLATILE ORQAMIC

- ANALYSIS COLLECTOR'S 8 Blank

Method elane

Quantitation limit

CM mencR

VOLATILE ORQAMIC

- ANALYSIS

imus *g/L M/L M/l

CM mencR

VOLATILE ORQAMIC

- ANALYSIS

MATRIX water

M/L M/l

79-01-6 TRICHLORGETHENE ' ND ND 5.D

71-43-2 BENZeNE ND ND 5.0

10061-02-6 TRANS-1.3-01CHL0R0PROPEHE NO NO S.O

79-00-3 1.1.2-TRICHlOROETHANE NO NO 3.0

75-25-2 BRCMOFORM NO NO 3.0

10E-1Q-1 4-MET HTL-2-PENTAN0NE M> ND 5.0

! 591-75-6 2-HEXAHONE ND NO 3.0

127-18-6 TETRACRLOROETHENE ND ND 5.0

79-34-5 1.1.2,2-TETRACHLOROETHANE ND ND 5.0

108-88-3 YOLUENE ND NO S.O

108-90-7 CH10R0BEN2ENE ND NO 3.0

100-41-4 ETHYL8ENZENE ND NO 5.0

100-42 5 STYREME ND NO 5.0

108-3B-3 XYLENE-K&P ND ND 5.0

9IM7-6 0-XYLENE ND ND 5.0

124-48-1 DIBROHOCHLOROHETHANE ND ND 5.0

106-46-7 ! 1.4-D1CHLOROBENZENE NO ND 5.0

1S4-59-3 CIS-1,2-DICHLOROBTHENE ND ND 5.0

1 *

Mote: ; »• not detected; HA • not analyzed; « Quantitation Limit a cone, of lowest

D - detected below quantitation Unit standard x sample dilution factor

GC/N5 Anelyst(s): Orlando Garbin

ReviewerI WILLIAM IN.

Supervisor:

A-ve/mn iiraM

William S. turn •

Sfgnature(s): Report Date: 3/1fr«6

Slaneture:

Signature:

Review Date:

Date:

3/14/96

3/14/96

SI'd so£2owois *on m svvstwihhivh snoaayzvH io:st m 96-si-hvw

910 J K<ies:ZT 96-Sl-CO SOEZOtSOIS XS6-H

DEPARTMENT OP TOXIC SUBSTANCES CONTROL


Q.C. Summary of Matrix Spike Analysis

HML SAMPLB NUMBER(S): 9?>nftqi. 950R93- 9Bnfl9B- 950896. 9SQflQfl. 9SOS99 COLLECTOR'S NUMBER/31 : HOI. H03, HQS. H06.H08.H09 — COLLECTOR'S NAMEl ALBERT FUJITSUBO SAMPLING SITE; 733 HUCHES FRESNO

Analysis for; volatila organic Sample Spiked: HML Mo. 950896 Matrix: llould coropounda

Matrix spike QC applicable to the following samples ; HML #950891. 9S0893. 950895. 950896. 950898.

•

COMPOUNDS

(ANALTTES)

UNSPIKED

HML No.

AMOUNT

ADDED

AMOUNT

FOUND

AMOUNT

FOUND

AVERAGE

AMOUNT

AVERAGE

PERCENT

RPD QHAN

LIMIT

•

COMPOUNDS

(ANALTTES) #950896 SPIKE DUPL FOUND RECOVER!

»*****»*«*«»* mg/L mg/L mg/L mg/L mg/L % \ mg/L

1/1-DICBLOROBTHENE . CQC LMbi :•% IB*)

ND 0.500 0.673 0.585 0.629 126 14.0 0.0500

BENZENE IOC Unlm; If* . Ul\)

ND 0.500 0.513 0.461 0.487 97.4 10.7 0.0500 |

: TRICHLOROETHENE /ecu**,.-»t. U7%j

ND o.soo 0 . 556 0.494 0.525 10S I I . E 0.0500

TOLUENE tDCUmttK41 * . |W*J

ND 0.500 0.516 0.457 0.487 97.4 12.1 0.0500

CHLOROBENZENE (QCUMu:t?i -MOJO |

ND, 0.500 0.567 0.500 0.534 107 12.5 0.0500 |

Note: ND ~ not detected NA «* not analyzed D » detected below quantitation Unit. Amount Found •= (amount found in spiked sample - amount found in unapiked sample)

Comment:

RPD « Relative Percent Difference ]RUN 1 - RUN 2|

(RUN 1 • RUN 2)/2 X 100

Sample HML #950896 la an oily liquid cample. It was spiked at an equivalent of 0.500 milligram per liter.

Analyst:

Signature:

Orlando Garbln

Date: 3/12/96

—L^lJLOr Date: 3/14/96

**wxroMstac:tc!hii

soezottois 'on m avi stohivh snoaavzvH to:ei m 96-si-hvh

It# UOJ TldCS = 21 96-SI-EO SOGZOtSOIS X96-H



LABORATORY REPORT

SURROGATE COMPOUND RECOVERY RESULTS

HML SAMPLE NUMBER(SJ; 9S0891. 950893. 950895. 950896. 950B98. 950899 COLLECTOR'S NUMBER(S} i HOI. H03 . HQS. H06. BOH. HQS COLLECTOR' 3 NAME J ALBERT PUJITSPBO SAMPLING SITES 733 HUGHES - FRESNO

HML Sample Number

Description/ Col, Number

Matrix % Recovery 1,2-dichloro-ethane-d4

[SURR. #1] QC Limit:

ft Recovery dO-toluene

(SURR. #2] QC Limit: U%-1I0*

ft Recovery 4—broiso t luoro— benzene

(SURR. #3] QC Umlt: tS%-11St

BLANK GC/MS Method water 93.4 95.3 97.9

BLANK Stgrage water 97.7 98.4 100

#950891 HOI liquid 102 90.7 97.0

#950893 H03 liquid 102 101 101

#950895 H05 liquid 98.6 100 97.0

#950896 H06 liquid 100 100 100

#950896 Matrix epika liquid 101 102 102

#950896 Spike dupl. liquid 101 102 101

#950898 H08 liquid 100 100 99.8

#950899 H09 liquid 102 101 102

COMMENTS:

Aoalyeti Orlando Garbln Signature

Supervising chemist! William mm signature:

JLAttCJWUX QC HCfrtSt

ZS£ BATE: 3/12/96

D«LM. 3/14/96

S0620W01S 'ON XVd ' 8W1 STVIMLVH SfKXKVZVH S0:£l IHd 96-SI-HVH

I*# 8104 K4£S:2l 96-SI-CO S0C20»S0tS XS6-H


tUZANUUUN MAlkKIALS LABORATORY • CC/MS ANALYTICAL SECTION

GC/KS ANALYTICAL REPORT FOR RON-TARGET COMPOUND AIALTSIS - VOLATILE ORGANIC ANALYSIS

RNL 8AMPLE NUHBERIS): COLLECTOR'S NUMBERCSJ! COLLECTOR'S NAME: SAMPLING SITE:

950891. 950893. 930899. 950896. 950898. 950899 W01. M03. MPS. HU6. HUB. H09 ALBERT FUJITSUBO 733 HUGHES - FRESNO

NETHOO: Initially «och sanple was analyzed for target volatlla organic compounds by EPA Method 8240. A Telunar Purge and Trap apparatus KM UMHJ to Isolate tho volaclta compounds. nasa spectra or cnrenatograpnic pedes which were not Identified as target conpounds were compared by a computer against 42,000 reference spectra in a mesa spectral data base published by the Netianel Bureau of Standards (BBS). Usually the resulting Identification arc tentative since pure reference compounds ere often not available for direct compel Ifcuti,

Page 1 of 2.

GC/W3 REPORT FOR HOW—TTfflCTT COMPOUNUM AHALYSJLM VOLATILE ORGANICS'*-+

HML No. CollecLuc'H No i

Retention Time(rain.) Compounds Detected**

Estimated conc. Level""'

mg/L

950891 EOl (liquid) None detected

950893 E03 (liquid) 13:06 13:52 14:04 14:38 15:17 19:43 16:02 16:13 17 i IS 17:27 17:41 17:56 18:23 19:04 19 >14 19:35 19:52

mathylcyclohexane 400 C8 alkane 340 c8 alkane 230 octane 750 C9 alkane 150 ethyl uyululiuxcue 440 C9 alkane 800 C9 alkane 450 CIO hydrocarbon 720 Cll alkane 720 C9 alkane 1,700 CIO alkane 2,100 Cll hydrocarbon 430 CIO alkane 1,300 trimethylbenzene 1,400 CIO hydrocarbon 1,600 trimethylbenzene (isomer) 390

950895 H05 (liquid) 16:46 17:20 18:22 18:39 181 SO 19:09 19:16 19:21 19:33 19139

c9 alkane C9 alkane Cll hydrocarbon decana 2,2,4,4-Leti:ameLhyl-3-pentanone CI3 alkane trimethylbenzene 0—nonnnol unknown alcohol CIO hydrocarbon •

1.5 o.o 1.6 4.4 2.5 1 .8 1.1 1.0 2.9 1.4

••NON-TARGET COMPOUNDS ARE THOSE NOT CURRENTLY ON THE TARGET COMPOUND LIST FOR HNL METHOD 8240. (See attached report for results of target compound analysis). _ Unknown exhibited mass spectral and chrooatograpnic properties which were Identical to tnoso of authentic conpouna analyzed under identical conditions. Unknown exhibited some mass spectral and/or chromatographic properties which are consistent with proposed Identity. Idvnltf{union are lenlollvc and are bused on comparison of the sample mass spectra wllh 42,000 rofai-wwe spectra in the EPA/NIH Noss Spectral Data Basa cospded by tha NBS. For comparison purposes, unknown non-target eeopound levats are astlmated based on the RIC area of chromatographic peak relative to tna RIC oral of Internal otandord used In the OC/ns analyses, bromochloromethane, 1,4-difluorobcn2ene or chlorobenzene-d5.

MOTE: (1)

(2) (3)

(4) tho unknown usual ly

ANALYST SIGNATURE: Orlando Garbln (tOa

(aO P : KIIIImi 3. t««V-h»*Jl< XI [-

^ PATE* 03/12/96

SIGNATURE OF SUPCRVIsINQ CHOUST: datf: 3/1A/-76

A-YrtS>mte IHTJKIBBII

BI'd soEsofrsots 'on xvj avi swiiawH snoaavzvH zo:si ihj 96-si-hvh

trn 6^1 oJ n^cs:zi 96-si-co soczoysots XS6-H


HA2ARDOUS MATERIALS LABORATORY • 6C/MS ANALYTICAL SECTION

GC/rtS ANALYTICAL REPORT FOR NON-TAAfiCT COWOUND ANALYSIS - VOLATILE ORGANIC ANALYSIS

SKL SAMPLE NUM8ER<3): 9S0691. 950893. 950895. 950896, 950898. 950899 Mlirnnil* -AI um una •!<> OIK ana COLLECTOR'S HUHBERf3>: HQ1. HQS. HW. It06- HUB. HOT COLLECTOR'S NAME: ALBERT FUJITSUBO SAMPLING SITE: 733 HUGHES - FRESNO

METHOD: Initially each aarpla ins analyzed for target volatile organic cenpounda by EPA Method 8240. A Tekmar Purg» and Trap apparatus aea used to isolate tnt volatile compounds. Mass spectra of chromatographic peaks which were not Identified at target compounds were compared by a computer against 42.000 reference spectre In a mess spectral data base publlahcd by the National Bureau of Standards (NBS). Usually the resulting Identification are tentative since pure reference coepoinds are often not available for dlract CMipwUwi.

Page 2 of 2.

KML Ho.

950896

CC/Mfl RTTPORT row WOW-TRHCET COMPOUNDS AN ALT 3 IS VOI^TILg QRGAHIC3'""

Compounds Detected** Collector' s

Ho.

HO6 (liquid)

Xatantion Time(min.)

St 27 acetaldehyde

Estimated Cone. Level*4

mg/L

0.046

960898 RO0 (liquid) 10:42 19:02 19:15 19:21 19:40 19:53

rrimechylbenzene 190 ethylmethylbcnzena 2,800 trimethylbsnzene (isomer) 1,800 etbylmstnylbenzene 900 C9 oxygenated compound 1,600 trimethylbenzene (isomer) 8S0

950899 R09 (liquid) 8:12 13:16 18:16 19:11 19:18

2-propancl 1,3,6-trioxocane 3-methyl-3-heptanol 4-occanol 6-raethyl-3-heptanol

570 5.1 0.02 0.11 0.03

**N0N-TARGET COMPOUNDS ARE THOSE NOT CURRENTLY CM THE TARGET COMPOUND LIST FOR HML METHOD 8240. (See attached report for result* of target compound analysis). Unknown exhibited mass spectral and chromatographic propsrtles which were Identical to those af authentic corcomd wwlyzcd wider identical conditions. ' Unknown exhibited sane rase epeetrel and/or chromatographic properties which ers consistent with proposed Identity. Identification ara tentative and are based on eosiparison of the sanple mass spectra with 42.000 reference spectra in the ePA/Nin nsss spectral Data Base compiled by the BBS. For comparison purposes, unknown non-target compound levels are estimated based on the RIC area of the unknown chromatographic peak relative to the Rlc area of Internal standard used In the GC/MS analyses, usually bromochtorcmethane, 1,*-diTluoroberuene or chloroberu«ne-d5.

NOTE: (1)

(2) (3)

<4>

ANALYST SIGNATURE: Orlando Carbln _ DATE: 3/12/96

"uKL JC SIGNATURE OF SUPERVISING CHEMIST:' William S. Luw DATE: 3/14£26_

61 'd S0E20W01S 'ON X¥J SV1 SHVIMIVH SflOOHVZVH 20!El IHJ 86-S1-WH

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v HAZARDOUS MATERIALS sample analysis;

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10. SAMPLING LOCATION • •

7. Time Sampledy.-rA Hours, "i

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12. ANALYSIS REQUESTEDjl

aBpH Gfr) H S VCA-H* -

b/S* Metal A , C/\ 5 h VOA-a240 *,i fcWfa? V-Opium " __

L • VOA-B260 - l-LJ Scan

cD Metab (Spec) . * . / l" A ' rt [—i

d.• W.E.T. -H* I- • SVO-6270 <>.• .

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Tftri Snhfilance ConlrqL

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sampling & analysis data, collected 2/8/96, w/tl to a … · · 2017-02-09ko/nd* bchaive dua...

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