school: science programme: master of science (m.sc.) year : …€¦ · course outcomes 1 student...

School: Science Programme: Master of Science (M.Sc.)

Year : First Year Semester - II

Course: Physical Chemistry II Course Code:PCH201

Theory: 4 Hrs/Week Max. University Theory Examination: 50

Marks

Max. Time for Theory Exam.: 3 Hrs Continuous Internal Assessment: 50

Marks

Course Objectives

1 To understand the fundamental of the various Spectroscopic techniques with

Physical aspects

2 To Learn the principle behind the various spectroscopic techniques

3 To study the detail idea about Nuclear chemistry and its application

4 To learn the detail concept on radioactivity and its medical applications

5 To understand the various phenomena related to the radioactivity

Unit

Number Details Hours

1 Molecular Spectroscopy

A. Recapitulation: Width and intensity of spectral transitions, Fourier

transform, microwave spectroscopy, rotation spectra of di – and poly-

atomic molecules, Stark effect.

B. Infrared spectroscopy: Harmonic and anharmonic oscillator,

vibrational spectra of di– and poly- atomic molecules, coarse and fine

structure, Nuclear spin effect, applications.

C. Raman Spectroscopy: Introduction, Rotational Raman spectra,

vibrational Raman Spectra, polarization of light and Raman effect,

structure elucidation from combined Raman and IR spectroscopy,

applications in structure elucidation.

18

2 Electronic Spectroscopy of Molecules

A. Born – Oppenheimer approximation, electronic spectra of diatomic

molecules, vibrational coarse structure, rotational fine structure

dissociation energy and dissociation products, electronic structure of

diatomic molecules, molecular photoelectron spectroscopy,

application.

B. ESR and Mossbaur Spectroscopy Applications

C. NMR: Principles of NMR – Chemical applications of PMR in

structure elucidation.

12

3 Nuclear and Radiation Chemistry

A. Radio Chemistry: Recapitulation–type of radioactive decay,

Decay Kinetics, Detection & measurement of radiation (G.M. &

Scintillation counter).

11

B. Elements of Radiation Chemistry: Radiation chemistry,

interaction of radiation with miller, passage of nucleous through

matter, interaction of radiation with matter, Units for measuring

radiation absorption, Radiation dosimetry, Radiolsis of water, free

radiation in water Radiolsis, Radiolysis of some aqueous solution.

4 Nuclear Reactor

The fission energy, The Natural uranium reactor, the four factor

formula- The reproduction factor K, the classification of reactor.

Reactor power, Critical size of thermal reactor, excess reactivity &

control, the Breeder reactor, The Indians nuclear energy programme,

processing of spent fuel.

Recovery of Uranium & Plutonium, Nuclear waste management,

Natural nuclear reactor.

Isotopes for Nuclear Reactors

Isotope separation, separation of selected isotopes, plutonium.

12

5 Applications of Radioactivity

Typical reaction involved in preparation of radioisotopes: 3H, 14C, 22Na, 32P, 35S and 137I. General principles of using radioisotopes.

Analytical applications- neutron activation analysis, dilution analysis,

radiometric titration. Industrial applications– radiation gauging,

friction and wear out, gamma radiography.

7

Total 60

Course Outcomes

1 Students able to understand the concept of various spectroscopic phenomena with

physical aspects

2 Students able to understand the application of spectroscopic techniques in various

fields

3 Students able to explain concept regarding IR, Raman, Uv-Vis, ESR, NMR

4 Students able to understand the radioactivity and its application in various fields

5 Students able to understand the energy and various phenomena related to nuclear

reactor

Resources

Recommended

Books

Chemical Applications of Radioisotopes by H. J. M . Brown Buffer &

Jammer Ltd.

Reference

Books

1. Fundamentals of Molecular Spectroscopy by C.N. Banewell and

E.Mc. Cash, 4th edition.

2. Elements of Nuclear Chemistry by H. J. Arnikar, Wiley Estern

Ltd, 4th edition.

3. Source Book of Atomic Energy by S. Glasstanc, D. Van Norton

company.



Course: Inorganic Chemistry II Course Code:PCH202

Theory: 4 Hrs/Week Max. University Theory Examination:50

Marks

Max. Time for Theory Exam.:3 Hrs Continuous Internal Assessment: 50

Marks

Course Objectives

1 To understand the basic concepts of co-ordination chemistry

2 To learn the electron spectroscopy of various complexes

3 To understand the splitting of d orbital

4 To learn the basic concept of bio-inorganic chemistry

5 To learn the basic concept of catalysis

Unit


1 Co-ordination Chemistry

Concept and Scope of ligand fields.

Energy levels of transition metal ions, free ion terms, term wave

functions, and spin-orbits coupling.

Effect of ligand field on energy levels of transition metal ions, weak

cubic ligand field effect on Russell- Saunders terms, strong field

effect, correlation diagrams, Tanabe-Sugano diagrams, Spin-pairing

energies.

16

2 Electronic spectra of complexes-I Band intensities, band energies, band width & shapes, spectra of

1st , 2nd & 3rd row ions and rare earth ion complexes,

spectrochemical & nephlauxetic series, charge transfer &

luminescence, spectra, calculations of Dq, B, parameters. Magnetic

properties of complexes-paramagnetism 1st & 2nd Ordered Zeeman

effect.

10

3 Electronic spectra of complexes-II

Magnetic properties of complexes-paramagnetism 1 st& 2nd Ordered

Zeeman effect, quenching of orbital angular momentum by ligand

fields, Magnetic properties of A, E & T ground terms in complexes,

spin free spin paired equilibria

4

4 Bio-inorganic Chemistry

Overviews of Bio-inorganic Chemistry.

Principles of Coordination Chemistry related to Bio-inorganic–

Protein, Nucleic acids and other metal binding biomolecules.

11

5 Bio-inorganic Chemistry Choice, uptake and assembly of metal containing units in Biology

Catalysis : Introduction and its types

15

Total 60

Course Outcomes

1 Student able to explain the basic concept of coordination chemistry

2 Student able to analyze the electronic spectra of metal complex

3 Student able to describe the magnetic properties various coordination

compounds

4 Student able to explain the basic concept of bioinorganic chemistry

5 Student able to explain the types of catalysis

Resources

Reference

Books

1. Inorganic Electronic spectroscopy by A.B . P. Level, Elsevier

Science Publishers New York, 2nd edition 1984.

2. Biological Chemistry of the Elements by R. J. P. Williams and

F. R. Desalvia, Oxford University Press, 1991.

3. Bioinorganic Chemistry: Inorganic elements in the Chemistry

of life: An introduction & guide by W. Kaim and B .

Schwederski, VCH, 1991.



Course: Organic Chemistry II Course Code:PCH203

Theory: 4 Hrs/Week Max. University Theory Examination:50

Marks

Max. Time for Theory Exam.: 3 Hrs Continuous Internal Assessment: 50

Marks

Course Objectives

1 To learn the various oxidizing and reducing reagents

2 To learn the rearrangements reactions

3 To understand various spectroscopic techniques related to organic chemistry

4 To study problems in UV, IR and NMR

Unit


1 Oxidation and Reduction

CrO3 (Jones reagent), PDC, PCC, KMnO4, MnO2, Swern, SeO2,

Pb(OAc)4, Pd/C, OsO4, mCPBA, O3, NaIO4, HIO4, R3SiH, Bu3SnH,

Boranes & Hydroboration reactions, MVP, H2/ catalyst, Wilkinson’s

catalyst, NaCNBH3, NH2NH2, DIBAL etc.

12

2 A. Rearrangements

Reactive intermediates, carbocations, carbanions, carbenes, nitrenes,

Beckmann, Hofmann, Curtius, Schmidt, Wolf, Lossen, Baeyer–

Villiger, Sommelet, Favorskii, Pinacole–Pinacolone, Benzil–

Benzillic acid, Claisen and Cope Rearrangements, Fries Migration.

B. Phosphorous, Nitrogen and Sulphur Ylids

Phosphorous, Nitrogen and Sulphur ylids and stereochemistry of

compounds containing Phosphorous, Sulfur and Nitrogen

C. Enamines–formation and applications

18

3 Spectroscopy

A. Ultraviolet (U. V.) Spectroscopy

Electronic transitions, chromophores, auxochromes, Bathochromic

and hypsochromic shifts, Solvent effects, Woodward–Fieser Rules

for dienes, enones and aromatic compounds, Applications of U.V.,

instrumentation of recording of spectra.

B. Infrared (IR) Spectroscopy

Vibrational Transitions, Important group frequencies, Factors

affecting IR group frequency, Applications of I.R., Instrumentation

and recording of spectra.

10

4 Nuclear Magnetic Resonance (NMR) Spectroscopy 12

Elementary ideas of NMR Integration, Chemical shifts Factors

affecting, Chemical shifts, Coupling (First order, analysis),

Instrumentation & recording of spectra.

5 Problems in UV, IR and NMR. 8

Total 60

Course Outcomes

1 Students able to understand application of various oxidizing and reducing

reagents

2 Students able to explain various rearrangements reactions

3 Knowledge of various organic spectroscopic techniques related will help student

to elucidate structures

4 Student able to solve problems in UV, IR and NMR

Resources

Recommended

Books

1. Organic Chemistry by J. Clayden, N.Greeveset. al.

2. Stereochemistry by Eliel.

3. Stereochemistry of Organic Compounds by D. Nashipuri,

4. Spectroscopy of Organic Compounds by Pavia.

Reference

Books

1. Adv. Organic Chemistry by Carey and Sundberg, Edition III,

Part B.

2. Synthetic Organic Chemistry by H.O. House.

3. Mechanis and Structure in Organic Chemistry by E. S. Gould.

4. Organic Chemistry by R. O. C. Norman.

5. Advanced Organic Chemistry by J. March, Edition IV.

6. Spectrometric Identification of Organic Compounds by

Silversteine and Basser.

7. Organic Spectroscopy by Kalsi.

8. Infrared spectra of Complex molecules by J. Bellamy.

9. Organic Spectroscopy by I Fleming.



Course: Analytical Chemistry II Course Code: PCH204

Theory: 4 Hrs/Week Max. University Theory Examination: 50

Marks

Max. Time for Theory Exam: 3 Hrs Continuous Internal Assessment: 50 Marks

Course Objectives

1 To understand basic principle, and working of different gravimetric analysis

2 To learn and analyses the instrumentation and working principle of the absorption

and emission spectroscopic techniques

3 To understand polarography technique for micro analysis of elctroactive analyte

4 To study different chromatographic technique

Unit


1 Physico- Chemical techniques : Types of reference electrodes,

conductance by electrolytes, Kohlrauch's law, conductometric

titrations, strong acid – strong base pH metric titration, titration

of mixture of weak and strong acids, titration of mixtures of

strong acids, potentometric titrations and differential plots,

potentiometric titration of Fe +2 and Ce+4, numerical, .principle ,

theory, working, pH metry, conductometry, potentiometry

12

2 Thermal Methods of Analysis :Thermogravimetric Analysis –

Introduction – Principle, Instrumentation Techniques of TGA ,

Factors influencing the TGA thermograms, thermobalance –

precaution measures, applications of TGA , Differential Thermo

Analysis – theory and principle , Differential Thermo Analysis

– Instrumentation, Differential Thermo Analysis – applications

12

3 Optical methods-I : Principle , theory, working Atomic

Absorption Spectroscopy, Flame emission spectroscopy,

Turbidometry and Nephelometry, applications

12

4 Electro analytical Techniques-I: Polarography, Polarisable

and non polarisable electrodes, basic principles, residual

current, diffusion current, limiting current, dropping mercury

electrode, supporting electrolyte half wave potential, derivation

of the polarographic wave equation for a reversible reaction.

Ilkovic equation, polarographic cell, qualitative and quantitative

12

analysis, calibration curve and standard addition method,

applications.

5 Green Chemistry

Principles of Green Chemistry, Need of green Chemistry, Goals

and importance of green Chemistry, reaction efficiency

parameters, Concept of atom economy, Alternative feed

stocks/starting materials, Reagents, Solvents, Product/target

molecules, Catalysis and process analytical chemistry.

Evaluation of chemical product or process for its effect on

human health and environment, Evaluation of reaction types

and methods to design safer chemicals. Evaluating the effects

of Chemistry: Toxicity to humans, Toxicity to wildlife, Effects

on local environment, Global environmental effects. Planning a

green synthesis.

12

Total 60

Course Outcomes

1 Student will able to understand and analyses different gravimetric and

electrochemical analysis

2 Knowledge about the absorption and emission spectroscopic techniques will

help student in academic as well as in research

3 Students will come to know about polarogram, calibration curves method and

its applications

4 Theoretical concept of different chromatographic technique will help to

separate different organic and inorganic mixtures

Resources

Reference Books 1. D. Harvey, Modern Analytical Chemistry, The McGraw-Hill

Pub. 1st Edition (2000)

2. D.A. Skoog, D.M. West and F.J. Holler, Fundametals of

Analytical Chemistry, 7thEdition (printed in India in 2001)

ISBN Publication.

3. Analytical Chemistry, J.G. Dick,1973 Tata McGraw Hill

Publishing Co. Ltd. New Delhi.

4. Quantitative analysis, Dey & Underwood, Prentice Hall of

India, Pvt. Ltd. New Delhi

5. Instrumental Methods of Analysis H. H. Willard, L.L. Merritt

Jr., J.A. Dean and F.A. Settle, CBS Publisher, 7th edition.

6. Fundamentals of Analytical Chemistry by D. A. Skoog, D.M.

West, F . J. Holler and S. R. Crouch, 8th edition.

7. Principles of Instrumental Analysis, D. A. Skoog, F. J. Holler

and J.A. Niemann, (1998)

8. Standard Methods of Chemical Analysis, Eds. F. J. Welcher,

Robert E. Krieger Publishing Company, (A series of volumes)

9. Polarographic Methods in Analytical Chemistry, M. G. Arora,

Anmol Publications Pvt Ltd


Year: First Year Semester - II

Course: Physical and Inorganic chemistry

practical Laboratory II

Course Code: PCH211

Practical: PG – 4 Hrs./Batch (20 Students) Practical Examination:50 Marks

Term Work: 50 Marks

Course Objectives

1 To study the various chemical reactions using instrumental methods

2 To learn inorganic synthesis

3 To learn synthesis of inorganic complexes

4 To learn nano-material synthesis

Sr.

No. Description

1 Conductometry : Hydrolysis of NH4Cl or CH3COONa or aniline hydrochloride

2 Potentiomerty : Solubility of a sparingly soluble salt

3 Potentiomerty: Determine the stability constant silver-ammonia complex

4 pH metry : Determination of the acid and base dissociation constant of an amino

acid and hence the isoelectric point of the acid

5 pH metry : Determine the dissociation constant of tribasic acid

6 Non- Instrumental: Statistical treatment of experimental data.

7 Inorganic Synthesis : To prepare Tris(acetylacetonato) iron(III)

8 Inorganic Synthesis : To preparebis-ethylene diamine copper (II) sulphate

9 Synthesis of potassium trisoxalato chromate (III) trihydrate

10 Colorimetry: Determine the composition of complex between Fe and salicyclic acid

by Job’s continuous variation method

11 Nano-Chemistry: Synthesis and Characterization of graphene oxide

12 Table Work : Characterization of metal ligand bonding using IR spectroscopy

Course Outcomes

1 Students are able to analyze the various chemical reactions using instrumental

methods

2 Students are able to perform the various inorganic synthesis

3 Students are able to perform synthesis of various inorganic complexes

4 Students are able to perform the nano material synthesis

Term Work:

Term Work assessment shall be conducted for the Project, Tutorials and Seminar. Term work

is continuous assessment based on work done, submission of work in the form of

report/journal, timely completion, attendance, and understanding. It should be assessed by

subject teacher of the institute. At the end of the semester, the final grade for a Term Work

shall be assigned based on the performance of the student and is to be submitted to the

University.

Practical/Oral/Presentation:

Practical/Oral/Presentation shall be conducted and assessed jointly by internal and external

examiners. The performance in the Practical/Oral/Presentation examination shall be assessed

by at least a pair of examiners appointed as examiners by the University. The examiners will

prepare the mark/grade sheet in the format as specified by the University, authenticate and

seal it. Sealed envelope shall be submitted to the head of the department or authorized person.

Notes

1 Two experiments from the regular practical syllabus will be conducted. (Total 40

Marks).

2 Complete laboratory journal/records (05 Marks).

3 Viva-voce (05 Marks).

Notes

1 The experiments from the regular practical syllabus will be performed (30 Marks).

2 The regular attendance of students during the syllabus practical course will be

monitored and marks will be given accordingly (10 Marks).

3 Good Laboratory Practices (10 Marks)


Year: First Year Semester - II

Course: Organic and Analytical Chemistry

Practical Laboratory II

Course Code: PCH212

Practical: PG – 4 Hrs./Batch (20 Students) Practical Examination: 50 Marks

Term Work: 50 Marks

Course Objectives

1 To learn single-stage/double stage preparations of organic compounds

2 To learn synthesis of organic compounds using green chemistry approach

3 To learn analytical techniques

4 To learn chemistry related software’s

Sr.

No. Description

1 Preparations: Single Stage

1. Benzalacetophenone from benzaldehyde and acetophenone (Claisen-Scmidt

Reaction)

2. Benzaldehyde to dibenzylidene acetone

3. Benzhydrol from bezophenone

4. Praparation of p-nitrobenzoic acid from p-nitrotoluene

5. Preparation of borneol from camphor (Reduction)

2 Preparations: Two-stage

1. Phthalic Acid-Phthallic anhydride – Phthallimide

2. Cyclohexanone---Cyclohexane Oxime---Caprolactum

3. Acetanilide – p – Bromoacetanilide –--- p – Bromoaniline

3 Green Chemistry Experiments:

1. Bromoxynil Synthesis (Selective Herbicide)

2. Preparation of Acetanilide from aniline by using ZnO/AcOH (Acylation)

4 pH Metry: To titrate the solution of Na2CO3 against HCl pH- metrically and hence

to select appropriate indicators for two equivalence point.

5 Spectrophotometry : Spectrophotometric analysis of potassium permanganate

solutions

6 Determination of strength of commercial phosphoric acid by potentiometric titrations

using standard solution of sodium hydroxide

7 Use of Computer

Chem Draw Chem-Sketch, ISI–Draw: Draw the structure of simple aliphatic,

aromatic, heterocyclic compounds with different subsistent. Get the correct IUPAC

name and predict the 1H NMR signals.

Course Outcomes

1 Student will able to perform single and double stage preparations of organic

compounds

2 Student will able to prepare organic compound by green chemistry approach

3 Student will able to analyze concentration of unknown species by using

Electrochemical and absorption spectroscopic techniques

4 Student will learn draw structure using Chem Draw

Term Work:

Term Work assessment shall be conducted for the Project, Tutorials and Seminar. Term work

is continuous assessment based on work done, submission of work in the form of

report/journal, timely completion, attendance, and understanding. It should be assessed by

subject teacher of the institute. At the end of the semester, the final grade for a Term Work

shall be assigned based on the performance of the student and is to be submitted to the

University.

Notes

1 The experiments from the regular practical syllabus will be performed (30 Marks).

2 The regular attendance of students during the syllabus practical course will be

monitored and marks will be given accordingly (10 Marks).

3 Good Laboratory Practices (10 Marks)

Practical/Oral/Presentation:

Practical/Oral/Presentation shall be conducted and assessed jointly by internal and external

examiners. The performance in the Practical/Oral/Presentation examination shall be assessed

by at least a pair of examiners appointed as examiners by the University. The examiners will

prepare the mark/grade sheet in the format as specified by the University, authenticate and

seal it. Sealed envelope shall be submitted to the head of the department or authorized person.

Notes

1 Two experiments from the regular practical syllabus will be conducted. (Total

40 Marks).

2 Complete laboratory journal/records (05 Marks).

3 Viva-voce (05 Marks).

school: science programme: master of science (m.sc.) year : …€¦ · course outcomes 1 student...

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