sodium coco-sulfate n tc-308 material safety data sheet · 2018-10-07 · sodium coco-sulfate n...

Sodium Coco-sulfate N TC-308 MATERIAL SAFETY DATA SHEET According to Regulation (EC) No. 1907/2006 and No. 453/2010 Version 1.2 Revision Date 09/12/2015 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Chemical type: Trade name: Synonyms: INCI Name: Substance name: Substance CAS No.: Substance EC No.:

Substance (anionic surfactant naturally derived from coconut oil.) Sodium Coco-sulfate N Sulfuric acid, monococo alkyl esters, sodium salts Sodium C12-18 Alkyl Sulfate, Sodium coco-sulfate Sulfuric acid, mono-C12-18-alkyl esters, sodium salts 68955-19-1 , 97375-27-4 273-257-1, 306-683-4

1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses: Prohibited uses: 1.3. Company identification Company identification :

Anionic surfactant. Detergents. It can be combined with surfactants commonly used in the laundry and cleaning industry to make products such as dishwashing liquids and liquid/powder laundry detergents. Sunstance can also be incorporated into shampoos, body washes, liquid hand soaps, facial cleansers, shaving foams, bar soaps, and other personal care applications to provide a more rapid viscosity response than other anionic surfactants (Sodium Lauryl Sulfate, Sodium Lauryl Ether Sulfate, and Alpha Olefin Sulfonate) and cost savings while maintaining product performance. For industrial use only. No additional information available.

UK: Forbury Direct England Ltd,Units 26-27, The Harrow Way, Basingstoke, Hants, RG224BJ, England, www.forbury-direct.co.uk

GERMANY, AUSTRIA: Forbury Direct Global Gbr, Grossenbaumer Allee 98, 47269, Duisburg, Germany, www.forbury-direct.de, www.seifenbasis.de

Sodium Coco-sulfate N TC-308

MATERIAL SAFETY DATA SHEET According to Regulation (EC) No. 1907/2006 and No. 453/2010

Version 1.2 Revision Date 09/12/2015

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1.4.Emergency telephone number Country Official advisory

body

Address Emergency number

Belarus The Belarus Republican Poisons

Centre Minsk Municipal Hospital of Emergency Medical Aid

Kizhevatova str. 58

220115 Minsk

+375 (0)17 201 9158

Bulgarija

National Toxicological

Information Centre

National Clinical Toxicology Centre, Emergency Medical

Institute "Pirogov"

21 Totleben Boulevard

1606 SOFIA

+359 2 9154 409

Croatia Poison Control Centre Institute of Medical Research &

Occupational Health

Ksaverska Cesta 2 P.O. Box 291

HR-10000 Zagreb

+385 1 234 8342

CZECH

REPUBLIC

Poisons Information Centre

Clinic For Occupational Medicine, 1st Medical Faculty,

Charles University

Na Bojisti 1

128 00 Prague 2

+42 2 2491 9293

+42 2 2491 5402

DENMARK

Poisons Information Centre Bispebjerg Hospital

Bispebjerg Bakke 23, 60, 1 DK-2400 Copenhagen NV

+45 82 12 12 12 +45 35 31 55 55

FINLAND Poisons Information Centre

P.O.B 790 (Tukholmankatu 17)

HUS SF - 00029 Helsinki

+358 9 471 977

Greese Poisons Information Centre 11527 Athens +30 10 779 3777

Greese Department of Forensic Medicine

& Toxicology

Aristotle University of

Thessaloniki, Medical Faculty

54006 Thessaloniki

HUNGARY

Országos Kémiai Biztonsági

Intézet (National Institute of

Chemical Safety) Egészségügyi Toxikológiai

Tájékoztató Szolgálat (Health

Toxicological Information Service)

1437 Budapest PO Box 839

1097 Budapest, Nagyvárad tér 2

+36 80 20 11 99

Iceland Iceland Poisons Information

Centre Landspitali University Hospital

Fossvogi

108 Reykjavik

+354 525 111

+354 543 2222

IRELAND (REPUBLIC OF) National Poisons Information

Centre

Beaumont Hospital

Beaumont Hospital Beaumont

Road

9 Dublin

: +353 1 8379964

ISRAEL Israel Poisons Information Centre

Rambam Medical Centre

PO Box 9602

31096 Haifa

+972 4 854 1900

ITALY Centro Antiveleni (Poisons

Centre) Dipartimento di Tossicologia

Clinica, Universita Cattolica del

Sacro Cuore

Largo Agostino Gemelli 8

I-00168 Roma

+39 06 305 4343

Kazakhstan Republican Toxicology Centre

City Emergency Medicine

Hospital

Tole-bi 93

480083 Almaty

KAZAKHSTAN

LATVIA Latvian Poisons Information Centre

Clinical Hospital "Gailezers"

2 Hipocrate Street LV 1038 Riga

+371 704 2468

LITHUANIA Poisons Control and Information Bureau

Siltnamiu 29 2043 Vilnius

+370 2 36 20 52 +370 2 36 20 92

NORWAY Poisons Information Directorate of Health and Social

Affairs

P.O. Box 7000 St. Olavs Plass

130 Oslo

+47 22 591300

Country Official advisory

body

Address Emergency number

POLAND Warsaw Poison Control and

Information Centre

Al.Solidarnosci 67

P-03 401 Warszawa

+48 22 619 66 54

+48 22 619 08 97

PORTUGAL Centro de Informação

Antivenenos – Dra Arlinda

Borges Instituto Nacional de Emergência

Médica (INEM)

Rua Almirante Barroso, 36

1000-013 Lisboa

808 250 143 (for use only

in Portugal),

+351 21 330 3284




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ROMANIA TOXAPEL Emergency Clinical Hospital for

Children "Grigore Alexandrescu"

Boulevardul Iancu de Hunedoara 30-32

Bucharest

+40 2121 06282 +40 2121 06183

RUSSIAN FEDERATION Toxicology Information and

Advisory Centre (RTIAC) Ministry of Health of the Russian

Federation

3 Sukharevskaya Ploshad

Block 7 129090 Moscow

+7 095 928 16 87 (Russian only)

SLOVAKIA National Toxicological Information Centre

University Hospital Bratislava

Limbová 5 833 05 Bratislava

+421 2 54 77 4 166

SLOVENIA Poison Centre

Division of Internal Medicine

University Clinical Centre

Zaloska 7 1525 Ljubljana

+ 386 41 650 500

SPAIN Servicio de Información

Toxicológica Instituto Nacional de Toxicología,

Departamento de Madrid

Calle Luis Cabrera 9

E-28002 Madrid

+34 91 562 04 20

SWEDEN Giftinformationscentralen Swedish Poisons Information

Centre, Karolinska Hospital

Box 60 500 SE-171 76 Stockholm

+46 8 33 12 31 (International) 112 (National)

UNITED KINGDOM National Poisons Information

Service (Belfast Centre) Royal Victoria Hospital

Grosvenor Road

BT12 6BA Belfast

0870 600 6266 (UK only),


Service (Birmingham Centre)

City Hospital

Dudley Road

B18 7QH Birmingham

0870 600 6266 (UK only),


Service (Cardiff Centre) Gwenwyn Ward, Llandough

Hospital

Penarth CF64 2XX Cardiff

0870 600 6266 (UK only),

UNITED KINGDOM NPIS Edinburgh (Scottish

Poisons Information Bureau)

Royal Infirmary of Edinburgh

51 Little France Crescent

EH16 4SA

Edinburgh

0870 600 6266 (UK only)

UNITED KINGDOM Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Guy's

& St Thomas' Hospital Trust

Avonley Road SE14 5ER London

0870 243 2241

UNITED KINGDOM National Poisons Information Service (Newcastle Centre)

Regional Drugs and Therapeutics

Centre, Wolfson Unit

Claremont Place Newcastle-upon-Tyne

NE1 4LP Newcastle

0870 600 6266 (UK only)

2. Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] : hazardous substance Adverse physicochemical, human health and environmental effects

2.1.1. Physical hazards: Not classified

2.1.2. Health hazards: Eye Dam.1, H318; Skin Irrit. 2, H315

2.1.3. Environmental hazards: Aquatic Chronic 3, H412 2.1.4. Other hazards: Combustible dust

2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP]:

GHS piktogrammas un

signālvārds:

GHS05 GHS07

Danger




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Klasifikācija un bīstamības

apzīmējums

Eye Dam.1

Skin Irrit. 2

Aquatic Chronic 3

H318 Causes serious eye damage. H315 Causes skin irritation.

H412 Harmful to aquatic life with long lasting effects.

Drošības prasību apzīmējums

Novēršana

P 264 Pēc izmantošanas rokas kārtīgi

nomazgāt.

P280 Izmantotaizsargcimdus/aizsargdrēbes/

acu aizsargus/sejas aizsargus.


Reakcija

P302+P352 SASKARĒ AR ĀDU: nomazgāt

ar lielu ziepju un ūdensdaudzumu.

P305 + P351 + P338 SASKARĒ AR ACĪM:

uzmanīgi izskalot ar ūdeni vairākas

minūtes. Izņemt kontaktlēcas, ja tās ir

ievietotas un ja to ir viegli izdarīt.

Turpināt skalot.

P310 Immediately call a POISON CENTER/ doctor


Iznīcināšana

P501 Dispose of contents/container in accordance with local/regional/national/

international regulations.

Papildus drošuma brīdinājumi Combustible dust

2.3 Other hazards : This substance is not considered to be persistent, bioaccumulating and toxic

(PBT). This substance is not considered to be very persistent and very

bioaccumulating (vPvB).

3. Composition / information on ingredients 3.1 Product Type: Substance

Ingredients:

Chemical name

Product identifier

CAS Nr. Weight, %

Sulfuric acid, mono-C12-18-alkyl esters,

sodium salts

68955-19-1 (alt. CAS No.: 97375-27-4) >= 90.0 %

Impurities ans stabilising additives :

-Alcohols, C12-1 (EC No.: 267-006-5) 67762-25-8

< = 5.0 %

- Water 7732-18-5 3-5 %

4. First aid measures

4.1 Description of first-aid measures

General advice: In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Ensure that medical personnel are aware of the material(s)

involved, and take precautions to protect themselves.

First aid

- Inhalation : If dust from the material is inhaled, remove the affected person immediately to fresh air. Call a physician if symptoms develop or persist.

- Skin contact : Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/




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attention. Take off contaminated clothing and wash before reuse.

- Eye contact : Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical

attention immediately.

- Ingestion : Rinse mouth. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Do not induce vomiting without advice from poison control center.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms: Dusts may irritate the respiratory tract, skin and eyes. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Hazards: Permanent eye damage including blindness could result. Skin irritation. May cause

redness and pain.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment: Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.

Symptoms may be delayed.

5. Fire - fighting measures

Suitable extinguishing media : Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Apply extinguishing media carefully to avoid

creating airborne dust.

Unsuitable extinguishing media: Water with full jet 5.2 Special hazards arising from the substance or mixture

Specific hazards during fire fighting: Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations and in the presence of an ignition

source is a potential dust explosion hazard. During fire, gases

hazardous to health may be formed: sulphur dioxide (SO2),

carbon monoxide (CO).

Special protective equipment for Self-contained breathing apparatus and full protective clothing

firefighters : must be worn in case of fire.

Fire fighting equipment/ In case of fire and/or explosion do not breathe fumes. In the

instructions : event of fire, cool tanks with water spray. Move containers from fire area if you can do so without risk.

Specific methods: Cool containers exposed to flames with water until well after

the fire is out.

General fire hazards: May form combustible dust concentrations in air.

6. Accidental release measures




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6.1 Personal precautions, protective equipment and emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Dust deposits should

not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into

the atmosphere in sufficient concentration. Use only non-sparking tools. Use a NIOSH/ MSHA approved

respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Wear

appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or

spilled material unless wearing appropriate protective clothing. Avoid inhalation of dust from the spilled

material. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot

be contained. For personal protection, see section 8 of the SDS.

6.2 Environmental precautions

Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic

environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid

discharge into drains, water courses or onto the ground.

6.3 Methods and materials for containment and cleaning up

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary

measures against static discharge. Use only non-sparking tools. This product is miscible in water.

Large Spills: Collect spillage. If sweeping of a contaminated area is necessary use a dust suppressant

agent which does not react with the product. Sweep up or vacuum up spillage and collect in suitable

container for disposal. Collect dust using a vacuum cleaner equipped with HEPA filter. Avoid dispersal of

dust in the air (i.e., clearing dust surfaces with compressed air). Minimize dust generation and

accumulation. Prevent entry into waterways, sewer, basements or confined areas. Following product

recovery, flush area with water. For waste disposal, see section 13 of the SDS.

7. Handling and storage

7.1 Precautions for safe handling

Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material

from direct sunlight. Ground/bond container and receiving equipment. Minimize dust generation and

accumulation. Provide appropriate exhaust ventilation at places where dust is formed. Do not get this

material in contact with eyes. Do not get this material in contact with skin. Avoid breathing dust. Do not

get this material on clothing. Wear positive pressure self-contained breathing apparatus (SCBA). Wear

personal protective equipment. Wash thoroughly after handling. Avoid release to the environment.

7.2 Conditions for safe storage, including any incompatibilities

Keep away from heat, sparks and open flame. Dry powders can build static electricity charges when

subjected to the friction of transfer and mixing operations. Provide adequate precautions, such as electrical

grounding and bonding, or inert atmospheres. Store in original tightly closed container. Store in a well-

ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Guard against dust

accumulation of this material. Routine housekeeping should be instituted to ensure that dusts do not

accumulate on surfaces

7.3 Specific end use(s): See Section 1.2.,Development of Exposure Scenarios for such use are not

required by the REACH Regulation other than what is provided in other sections of this SDS. No use-

specific Risk Management Measures are proposed.

8. Exposure controls / personal protection

8.1 Control parameters




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Ingredients with workplace control parameters

Occupational exposure limits: No exposure limits noted for ingredient(s).

Biological limit values: No biological exposure limits noted for the ingredient(s).

8.2 Exposure controls

Engineering measures

Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumes that may

be generated during handling or thermal processing. Eye wash facilities and emergency shower must be

available when handling this product.

Personal protective equipment

Respiratory protection :

Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding

the exposure limits.

Thermal hazards:

Wear appropriate thermal protective clothing, when necessary.

Hand protection : Wear appropriate chemical resistant gloves.

Eye and face protection :

Wear safety glasses with side shields (or goggles) and a face shield. Use tight fitting goggles if dust is

generated.

Skin and body protection :

Wear appropriate chemical resistant clothing.

Hygiene measures :

When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing

after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and

protective equipment to remove contaminants.

Environmental exposure controls

General advice : See section 6.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : Solid, needle

Color : White to off-white

Odor : Characteristic

Odour threshold: Not determined

pH: > 7 (@ 10% aqueous) Flash point : > 201.0 °F (> 94 °C) Flammability (solid, gas) : Not available

Upper/lower flammability or explosive limits :

Flammability limit - lower (%) Not available

Flammability limit - upper (%) Not available

Explosive limit - lower (%) Not available




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Explosive limit - upper (%) Not available

Vapor pressure: Not available

Vapor density: Not applicable, needle

Relative density: Not available

Solubility(ies) :

Solubility (water) >250 g/l at 20°C . Fully miscible with water.

Surface tension: 24.6 (145.6 mg/L, dynes/cm at 25°C)

Autoignition temperature: 250 °C

Decomposition temperature: >208 °C

Viscosity: Not available.

Oxidizing properties : The substance is not classified as oxidizing.

Melting point/range : 36-183 °C

Boiling point/boiling range : 208 °C - initial boiling point

Density : approx. 0,60 g/ml

Explosive properties : Product is not explosive. However, formation of explosive air/vapour mixtures are possible. 9.2 Other information Critical Micelle Concentration, mg/l: 145.6

10. Stability and reactivity

10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions : Note: This material is stable when properly handled and stored

10.4 Conditions to avoid

Conditions to avoid : Keep away from heat, sparks and open flame. Avoid temperatures exceeding the flash point. Contact with

incompatible materials. Avoid dispersal of dust in the air (i.e.,

clearing dust surfaces with compressed air). Minimize dust

generation and accumulation.

10.5 Incompatible materials

Materials to avoid : Strong acids. Strong oxidizing agents. 10.6 Hazardous decomposition products: Thermal decomposition : Upon decomposition, this product may yield sulfur dioxide and oxides of carbon.

Possible decomposition product in

case of hydrolysis is : NaHSO4

11. Toxicological information




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11 .1 Information on toxicological effects

Acute toxicity Acute oral toxicity : LD50 Oral: > 2000 mg/kg (Species: Rat)

Acute inhalation toxicity : Not classified. Dust will cause irritation.

Acute dermal toxicity : Based on acute toxicity values, not classified.

LD50 Dermal: > 10000 mg/kg (Species: Rabbit)

Skin corrosion/irritation : Cause skin irritation.

Serious eye damage/eye irritation: Causes serious eye damage. Dust in the eyes will cause irritation.

Respiratory or skin sensitization: Respiratory sensitization: not classified. No study available.

Skin sensitization: not classified. No adverse effect observed.

Chronic toxicity Carcinogenicity : Not classified. No adverse effect observed.

Germ cell mutagenicity : Not classified. No adverse effect observed.

Reproductive toxicity Effects on fertility/ Not classified. Male rats and female mice ingesting multi-gram

Effects on or via lactation: quantities of dipropylene glycol for 90-days exhibited changes in testis and estrous cycle that appeared secondary to clinical- and

systemic toxicity, debilitation and death. Data available on

related homologues suggest it is unlikely to affect fertility or

reproduction at lower exposures that do not cause morbidity

or mortality.

Effects on Development : Not classified. No adverse effect observed.

Target Organ Systemic Toxicant - Single exposure: Based on single exposure toxicity values, not classified.

Target Organ Systemic Toxicant - Repeated exposure: Based on repeated exposure toxicity values, not classified.

Aspiration hazard : Based on physico-chemical values or lack of human evidence,

not classified.

12. Ecological information

12.1 Toxicity: Toxic to aquatic life. Harmful to aquatic life with long lasting effects.

Toxicity to fish : LC50: 3 - 20 mg/l, 96 hours

Toxicity to daphnia and

other aquatic invertebrates: EC50: 56 mg/l, 48 hours

Toxicity to algae : EC50: 42 mg/l, 72 hours

Toxicity to bacteria : No data available. LC50 = 11.1 mg/L (approx.) – liter. data for




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aquatic life

Toxicity to fish (Chronic No data available. Harmful to aquatic life with long lasting

toxicity): effects.

Toxicity to daphnia and

other aquatic invertebrates No data available. Harmful to aquatic life with long lasting

(Chronic toxicity): effects.

Ecotoxicology Assessment

Acute aquatic toxicity : Harmful to aquatic life with long lasting effects.

Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.

12.2 Persistence and degradability

Biodegradability : Radily biodegradable.

12.3 Bioaccumulative potential

Bioaccumulation : This material is not expected to bioaccumulate.

12.4 Mobility in soil Adsorbtion to solid soil phase: Expected

12.5 Results of PBT and vPvB This substance is not considered to be persistent, assessment: bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).

12.6 Other adverse effects Adsorbable organically-bound

halogen (AOH) None

Additional ecological information: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption,

global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions: Dispose of contents/container in accordance with local/ regional/national/international regulations.

13.1 Waste treatment methods

Product : Fire residues and contaminated fire extinguishing water

must be disposed of in accordance with local regulations.

Do not dispose of waste into sewer. Do not contaminate

ponds, waterways or ditches with chemical or used

container. Consult and comply with local, provincial and

federal regulations that may apply. Dispose of in accordance

with local regulations. Empty containers or liners may retain

some product residues. This material and its container must

be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging : Empty containers should be taken to an approved waste




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handling site for recycling or disposal. Since emptied

containers may retain product residue, follow label warnings

even after container is emptied.

Packaging may be reused or recycled after cleaning.

If recycling is not possible, dispose according to the local regulations.

Recommended cleansing agents: Water, if necessary together with cleansing agents.

14. Transport information

Not regulated for transport

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Labelling according to Regulation (EC) No 1272/2008

This safety data sheet is in compliance with the Regulation (EC) N° 1907/2006

Other international regulations

Global Inventory Status The ingredients of this product are compliant with the following chemical inventory requirements or

exemptions.

*Additional Explanatory Status Statements follow the table, as necessary.

Country/Region Inventory Status Description

Australia AICS Compliant

Canada DSL Compliant

China IECSC Compliant

Europe REACH Compliant

Japan ENCS Compliant

Korea KECI Compliant

New Zealand NZIoC Compliant

Philippines PICCS Compliant

United States of America TSCA Compliant

Taiwan TCSCA Compliant

15.2. Chemical safety assessment\

A Chemical Safety Assessment has been performed

16. Other information

Material safety datasheet sections which have been updated: Revised Section(s): 1 11 12 15 December 9 2016

DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources which we believe are

reliable. However, the information is provided without any warranty, express or implied, regarding its correctness.

The conditions or methods ofhandling, storage, use or disposal of the product are beyond our control and may be

beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability




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for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the

product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in

another product, this MSDS information may not be applicable.

sodium coco-sulfate n tc-308 material safety data sheet · 2018-10-07 · sodium coco-sulfate n...

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