soil and water pollution monitoring, protection and remediation978-1-4020-4728... · 2017-08-29 ·...

Monitoring, Protection and RemediationSoil and Water Pollution

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Series IV: Earth and Environmental Sciences – Vol. 69

edited by

Irena TwardowskaPolish Academy of Sciences,

Institute of Environmental Engineering,

Zabrze, Poland

Herbert E. Allen

ggblom

Pollution

Monitoring, Protection

and Remediation

Published in cooperation with NATO Public Diplomacy Division

Center for Study of Metals in the Environment,

Department of Civil and Environmental Engineering,

University of Delaware,

Managing editor

Biotechnology Center for Agriculture and the Environment,

Polish Academy of Sciences,

Institute of Environmental Engineering,

Zabrze, Poland

ä

Newark, DE, U.S.A.

Rutgers, The State University of New Jersey,

Department of Biochemistry and Microbiology,

New Brunswick, NJ, U.S.A.

Max M. H

Sebastian Stefaniak

Soil and Water

A C.I.P. Catalogue record for this book is available from the Library of Congress.

ISBN-10 1-4020-4727-4 (PB)ISBN-13 978-1-4020-4727-5 (PB)ISBN-10 1-4020-4726-6 (HB)ISBN-13 978-1-4020-4726-8 (HB)ISBN-10 1-4020-4728-2 (e-book)ISBN-13 978-1-4020-4728-2 (e-book)

Published by Springer,P.O. Box 17, 3300 AA Dordrecht, The Netherlands.

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Printed on acid-free paper

All Rights Reserved© 2006 SpringerNo part of this work may be reproduced, stored in a retrieval system, or transmitted inany form or by any means, electronic, mechanical, photocopying, microfilming,recording or otherwise, without written permission from the Publisher, with the exceptionof any material supplied specifically for the purpose of being entered and executed on acomputer system, for exclusive use by the purchaser of the work.

Proceedings of the NATO Advanced Research Workshop onViable Methods of Soil and Water Pollution Monitoring, Protection and RemediationKrakow, Poland27 June - 1 July 2005

CONTENTS

1. Introduction: Spread and Distribution of Hazardous

Chemicals in Soils and Water – A Global Problem

1.1. Diagnosis and prognosis of the distribution

Uri Mingelgrin and Ahmed Nasser

Mohamed Tawfic Ahmed

2. Fate and Behavior of Anthropogenic Pollutants in Soils

and Water

2.1. Fundamental Issues in Sorption Related to Physical

Joseph J. Pignatello

2.2. The role of humic substances in the fate of anthropogenic

organic pollutants in soil with emphasis on endocrine

Elisabetta Loffredo and Nicola Senesi

Herbert E. Allen and Colin R. Janssen

2.4. The metal uptake and accumulation in fish living

Barbara Jezierska and Ma gorzata Witeska

Preface............................................................................................................ xi Acknowledgements..................................................................................... xviiContributors ................................................................................................. xix

v

of contaminants in the geosphere...................................................3

1.2. Persistent organic pollutants in Egypt - an overview.................25

and Biological Remediation of Soils.............................................41

disruptor compounds ....................................................................69

2.3. Incorporating bioavailability into criteria for metals ................93

in polluted waters.........................................................................107

vi Contents

3. Advances in Chemical and Biological Techniques

for Environmental Monitoring and Predicting

3.1. Sensoristic approach to biological damage

Luigi Campanella and Cecilia Costanza

Guenther Proll, Jens Tschmelak, Joachim Kaiser, Peter Kraemmer, Frank Sacher, Jan Stien and Guenther Gauglitz

3.3. Genetically engineered microorganisms for pollution

Shimshon Belkin

3.4. Some advances in environmental analytics

Agata Kot-Wasik and Jacek Namie nik

Anna G. Mignani, Andrea A. Mencaglia and Leonardo Ciaccheri

Hao Zhang and William Davison

3.7. On conceptual and numerical modeling of flow

and transport in groundwater with the aid of tracers:

Jaroslaw Kania, Kazimierz Rozanski, Stanislaw Witczakand Andrzej Zuber

4. Novel Physico-Chemical Techniques of Soil and Water

Protection and Remediation

4.1. Current and future in situ treatment techniques for the

remediation of hazardous substances in soil, sediments,

Robert A. Olexsey and Randy A. Parker

and risk assessment......................................................................117

monitoring ....................................................................................147

and monitoring..............................................................................161

3.5. Fiber optic system for water spectroscopy................................175

3.6. Predicting metal uptake by plants using DGT technique ........187

a case study...................................................................................199

and groundwater..........................................................................211

3.2. Advanced environmental biochemical sensor for water monitoring: Automated Water Analyser Computer Supported System (AWACSS) ................................................... 131

Contents vii

4.2. Long-term performance of permeable reactive barriers:

lessons learned on design, contaminant treatment, longevity,

Robert W. Puls

Irena Twardowska, Joanna Kyziol, Yoram Avnimelech, Sebastian Stefaniak and Krystyna Janta-Koszuta

Irina V. Perminova, Natalia A. Kulikova, Denis M. Zhilin, Natalia Yu. Grechischeva, Dmitrii V. Kovalevskii, Galina F. Lebedeva, Dmitrii N. Matorin, Pavel S. Venediktov,

4.5. Metal binding by humic substances and dissolved

Yona Chen, Pearly Gat, Fritz H. Frimmel

4.6. The effect of organic matter from brown coal on

Piotr Sk odowski, Alina Maciejewska and Jolanta Kwiatkowska

Galina K. Vasilyeva, Elena R. Strijakova and Patrick J. Shea

4.8. Adsorption of anions onto sol-gel generated double

Natalia I. Chubar, Valentyn A. Kanibolotskyy,Volodymyr V. Strelko, Volodymyr S. Kouts and Tetiana O. Shaposhnikova

Fritz H. Frimmel and Tusnelda E. Doll

Andrey I. Konstantinov, Vladimir A. Kholodov,

and Gudrun Abbt-Braun

Valery S. Petrosyan

performance monitoring and cost – an overview ......................221

organic matter derived from compost .......................................275

bioavailability of heavy metals in contaminated soils ..............299

4.7. Use of activated carbon for soil bioremediation .......................309

hydrous oxides..............................................................................323

4.3. Using abundant waste and natural materials for soil and groundwater protection against contamination with heavy metals: Prospects and areas of application ........... 231

4.4. Mediating effects of humic substances in the contaminated

environments: Concepts, results, and prospects.......................249

4.9. Xenobiotic pharmaceuticals in water and methods to prevent their appearance in drinking water: Photolytic and Photocatalytic Degradation of Pharmaceuticals ...............339

viii Contents

4.10. UV/VIS light-enhanced photocatalysis for water

Jan Hupka, Adriana Zaleska, Marcin Janczarek,Ewa Kowalska, Paulina Górska and Robert Aranowski

Dinesh O. Shah and Monica A. James

Kenneth S. Sajwan, Siva Paramasivam, Ashok K. Alva and Shivendra V. Sahi

5.1. Phytoremediation and phytotechnologies: a review

Nelson Marmiroli, Marta Marmiroli and Elena Maestri

5.2. Constructed wetlands and their performance

for treatment of water contaminated with arsenic

Ulrich Stottmeister, Sasidhorn Buddhawong, Peter Kuschk, Arndt Wiessner and J rgen Mattusch

5.3. Disposal of sewage effluent and biosolids in eucalyptus

Pinchas Fine, Nir Atzmon, Fabrizio Adani, and Amir Hass

Thomas Vanek, Ales Nepovim, Radka Podlipna, Anja Hebner, Zuzana Vavrikova, Andre Gerth, Hardmuth Thomas and Stanislav Smrcek

5.5. Floating aquatic macrophytes as a decontamination

Cinzia Forni, Caterina Patrizi and Luciana Migliore

5. Biosystems for Non-Destructive Remediation and Immobilization of Pollutants in Soils, Sediments and Detoxification of Industrial Wastes

treatment and protection ............................................................351

4.12. Fly ash-organic byproduct mixture as soil amendment ..........387

for the present and the future.....................................................403

and heavy metals..........................................................................417

plantations: a lysimeter simulation study .................................433

5.4. Phytoremediation of explosives in toxic wastes ........................455

tool for antimicrobial drugs........................................................467

4.11. New horizons in purification of liquids: Novel colloidal and

interfacial strategies to remove hazardous molecules, viruses and other microorganisms from water......................................369

ű

Contents ix

5.6. Plant tolerance to heavy metals, a risk for food toxicity

or a means for food fortification with essential metals:

Avi Golan-Goldhirsh

6. Assembled Plant and Microbial Technologies

for Bioremediation of Pollutants

6.1. Ecoremediation. Cooperation between plants and soil

Michel Tissut, Muriel Raveton and Patrick Ravanel

6.2. Anaerobic dehalogenation of halogenated organic

compounds: novel strategies for bioremediation

Max M. Häggblom, Donna E. Fennell, Young-Beom Ahn, Beth Ravit, and Lee J. Kerkhof

6.3. Molecular tools for microbial remediation - contaminants

Eliora Z. Ron

6.4. Role of mycorrhizal fungi in phytoremediation

and toxicity monitoring of heavy metal rich industrial

Katarzyna Turnau, Elzbieta Orlowska, Przemyslaw Ryszka, Szymon Zubek, Teresa Anielska, Stefan Gawronski and Anna Jurkiewicz

6.5. Biodegradation of petroleum hydrocarbons

Krzysztof Ulfig, Wioletta Przysta , Gra yna P azaand Korneliusz Miksch

7. Management strategies for large-area contaminated sites

7.1. Integrated management strategy for complex groundwater

Grzegorz Malina, Janusz Krupanek, Judith Sievers, Jochen Grossmann, Jeroen ter Meer and Huub H.M. Rijnaarts

the Allium Schoenoprasum model .............................................479

microorganisms, molecular aspects and limits .........................489

of contaminated sediments..........................................................505

uptake, metabolism and biosensing ...........................................523

by keratinolytic fungi ..................................................................553

contamination at a megasite scale ..............................................567

wastes in Southern Poland ..........................................................533

x Contents

7.2. Management options for regionally contaminated

Holger Weiss, Birgit Daus, Susanne Heidrich, Arno Kaschl, Mario Schirmer, Peter Wycisk, Jochen Grossmann and Martin Keil

aquifers: a case study at Bitterfeld, Germany ..........................579

Subject Index .............................................................................................. 591

PREFACE

In every respect, human development and human security are closely linked to the

productivity of ecosystems. Our future rests squarely on their continued viability.

UNDP, UNEP, World Bank, World Resources Institute: World Resources 2000-

2001.People and Ecosystems. The Fraying

Web of Life.

1. OBJECTIVE OF THE BOOK

Soil, surface waters/sediments and shallow unprotected groundwater aquifers are interrelated compartments of the environment that are particularly easy to compromise, sensitive to short- and long-term pollution and directly affect sustainability of ecosystems and human health. Routine human activity such as application of fertilizers and pesticides in agriculture and forestry, or wet and dry deposition of atmospheric pollutants emitted from industrial plants, waste disposal and other practices adversely affect soil and water quality that already increasingly suffers from mismanagement in many areas. The predominant sources of pollution result in non-point contamination that is particularly difficult to reduce and control. Wars, accidents and natural emergency cases such as catastrophic floods that occur partly due to anthropogenically disturbed global water balance also add to overall increase of diverse contaminant loads in soil and water. Beneficial properties of some bulk waste materials such as biosolids (sewage sludge), biowaste (e.g. municipal waste composts) or fly ash from coal combustion

xi

xii Preface

encourage applying these waste to land as a source of nutrients and organic matter, or as a soil amendment. All these human activities result in soil being a sink for all possible chemicals, also new ones, that belong to many groups of xenobiotics - organic compounds such as halogenated organics (AOX), linear alkylbenzene sulfonates (LAS), Di(2-ethylhexyl)phtalate (DEHP),

polychlorinated dibenzo-dioxins and furans (PCDD/F), organotins (MBT, DBT, TBT), and various pharmaceuticals. Heavy metals and metalloids, and some organic compounds, e.g. polycyclic aromatic hydrocarbons (PAH)

concern due to their persistence and toxicity. There is growing evidence of mutagenicity, genotoxicity and endocrine disruption impact of many chemicals on soil and aquatic organisms – primary receptors of soil and water contaminants - and their declining biodiversity. Other organisms – participants of the food web, including humans – have been also endangered. During the history of human development and industrial revolution, mankind for a longer time ignored warning signs that its activity might damage the capacity of ecosystems to sustain us. Now, at the beginning of the third Millennium we are much more aware of our utter dependence on the productivity of ecosystems that is largely determined by the quality of their essential compartments: soil and water, and of the costs of their degrading and restoration. We also know much more about the processes that govern the fate and migration of contaminants in the environment. Nevertheless, we still know surprisingly little to be able to answer the basic question set up in the special millennial edition of the World Resources Report, World Resources 2000-2001 (UNDP-UNEP-World Bank-World Resources Institute, 2000): "How best can we manage ecosystems so that they remain healthy and productive in the face of increasing human demands?" And how best can we manage soil and water resources to keep them healthy and productive? We inherited a huge number of contaminated sites that have to be efficiently and cost-effectively restored, of different size and origin. We still continue to make mistakes in view of current benefits, and ignoring the precautionary principle and our limited knowledge. The development of this knowledge to enable correct prognosis of environmental behavior, bioavailability and impact of chemicals on living organisms is a priority task

The data on long-term environmental behavior of many xenobiotics and efficient methods of their control are still scarce. Also data on heavy metals of anthropogenic origin are insufficient, in particular with respect to metals mobility, bioavailability and its alteration in time. New concepts and approaches in science that merge biology and chemistry will provide better simulation of contaminant bioavailability in real soil and aquatic systems, and thus a better basis for correct decisions.

for better environmental management.

nonylphenol and ethoxylates (NPE), polychlorinated biphenyls (PCBs),

that occur in nature but in much lower concentrations, are also of particular

Preface xiii

A prerequisite of sound ecosystem management decisions is monitoring of soil and waters that should provide reliable data for solid scientific assessment and its validation, and for supporting and verifying environmental management decisions. Another emerging task of soil and water screening/monitoring comes from the hazards of eco-terrorism, as these compartments are particularly easily available for an attack, consisting of hazardous chemical, microbiological and biochemical poisoning of water. The specific nature of ecoterrorist’s attack requires application of specific techniques, in particular identifying unknown substances and mixtures, type of hazardous action, as well as the extent of acute toxicity and its spatial and temporal extinction. Such topics as advanced “field” and “on-site” analytical techniques, optical sensors and immunochemical-based methods, the miniaturization of instrumentation to permit its use in a field setting for screening/ monitoring is of particular timeliness and urgent need. In all cases, soil and water monitoring tools should provide an early warning, to prevent, intercept or minimize contamination before the environmental damage proceeds too far. Minimization of potential of soil and water contamination, also due to use of waste materials such as sewage sludge and other biosolids for soil amendment requires source control of contaminants’ emission not only from large industries, but also from small artisan enterprises. For this purpose, simple and inexpensive methods, preferably with use of abundant waste materials, e.g. as efficient and cost-effective sorbents of pollutants may be

treatment plants could be efficiently reduced, therefore reducing also sewage sludge (biosolids) non-point pollution potential to amended soils. In turn, the opportunities that are brought about by application of many rapidly developing techniques such as permeable reactive barriers for either cutting off the accessibility of reagents causing generation of hazardous

already known solutions might find a new area of application. Permeable reactive barrier techniques and new sorbents might be equally applicable both for prevention of pollution through control of contaminant generation or transformation them into non-hazardous compounds, but also for efficient remediation of soil and/or water contamination or neutralization of an acute toxicity that might result from accident or eco-terrorism. In all cases, the mechanism of action is of the first priority, but optimization of technical construction/application details are of no lesser importance for assuring efficiency and cost-effectiveness. In the permeable reactive barriers, and other preventive/remediation measures, a number of novel integrated physicochemical and biochemical methods can be used.

used. In this way the contaminant loads in sewage sludge from municipal

or decomposing, or transforming them into non-hazardous substances are not contaminants, or reacting with hazardous substances that results in bonding,

fully utilized. Many novel solutions might be found in this area, or yet

xiv Preface

The remediation solutions for water/sediments and soil pollution should be focused on non-destructive methods that would allow preservation of soil properties during and after decontamination. One such non-destructive method is phytoremediation, i.e. selection of the best contaminant scavengers applicable in the relevant environment and climatic conditions. for contaminant uptake by plants from water/sediment/soil.

Remediation of soils, water/sediments and groundwater contaminated by complex mixtures of organic pollutants and heavy metals is one the greatest challenges facing environmental restoration. There is therefore a significant demand for environmentally safe and economically feasible technologies for treatment of contaminated ecosystems. Although fundamental and applied studies have provided many novel treatment technologies, we must improve the means to bridge between research and practice, and means to combine different capabilities.

Microbial biotransformations of organic contaminants have been widely observed in soils and sediments, while heavy metal contaminants may be immobilized by the action of metal-reducing bacteria or through sulfide precipitation by sulfate-reducing bacteria. Microbial processes are especially attractive, since biodegradation can result in complete mineralization of organic contaminants or lead to significant reduction in their toxicity. Plant based technologies, phytoremediation, are of interest in the ability of plants sequester contaminants on the one hand, and enhance microbial activities in their root zone, on the other. Accelerated in situ decontamination and/or detoxification through stimulation of desirable microbial and plant-mediated processes can shorten the time frame needed for site remediation, thereby reducing the costs of long term monitoring. Remediation that exploits these natural in situ biological processes, combined with in-place containments, potentially avoids redistribution of the contaminants.

The objective of this book is to summarize and critically assess the

current status, development trends and needs of three basic defensive

elements that safeguard the quality and environmental safety of soil and

water/sediments: early warning monitoring, protection and remediation

measures, with particular regard to the viability of methods and

technologies, i.e. easiness-to-use, reliability, cost-effectiveness, high

efficiency and non-destructive character of remediation that is of

particular importance considering the scale of application.

The priority aim of the book is to contribute to the improving maintenance of ecosystems, and specifically to summarize and add to information on how best to protect our soils and aquifers, prevent movement and mobilization of pollutants and how to enhance their degradation and/or immobilization. The remediation solutions for soil pollution are focused on non-destructive methods that would preserve soil properties during and after decontamination.

Preface xv

2. THE SCOPE OF THE BOOK

The book comprises seven major topics that constitute consecutive parts of the book, which contain 38 chapters covering the issues in accordance with its objective and aims:

Spread and distribution of hazardous chemicals in soils and water as a global problem. This part is an introduction into a global character of contaminants of anthropogenic origin and consists of two chapters: one of them discuses the present and the future of contaminants distribution in the whole geosphere. Another is a case study that exemplifies this problem in one developing country where lack of balanced development of industry and environment protection leads to the degradation of ecosystems and has already taken a toll on local economy. Fundamental issues concerning fate and behavior of anthropogenic pollutants in soils and water are presented in four state-of the-art chapters showing mechanisms of sorption and bioavailability of metals and anthropogenic organic pollutants in the terrestrial and aquatic environments.Advances in chemical and biological techniques for environmental monitoring and predicting are addressed in seven chapters focused on the novel multi-stage sensoristic approach and sensors for environmental monitoring, as well as new techniques, systems and methods for pollutant analysis, simulation of uptake and modeling of transport in environmental compartments.Novel physico-chemical techniques of soil and water protection and remediation comprise twelve chapters that present an overview of various treatment techniques and applications, based on permeable reactive or insulation barriers, and on using various sorbents, mostly abundant waste and natural materials or sorbents derived from such materials for metal binding from soils, water and sediments. Other techniques (photolytic, photocatalytic, colloidal/interfacial) for prevention of water contamination by xenobiotic hazardous substances, viruses and other microorganisms are also presented.A review of phytoremediation and phytotechnologies and use of different plants – contaminant scavengers for remediation, detoxification, and even for food fortification purposes is discussed in six chapters. Assembled plant and microbial technologies for bioremediation and biosensing of soils, sediments and industrial wastes contaminated with heavy metals and organic pollutants is the topic of the subsequent six chapters.

xvi Preface

The final two chapters of the book are devoted to integrated remediation strategies developed for complex management of large-area historically contaminated areas - "megasites". This issue has been exemplified in site-specific strategies applied in three European contaminated sites - port Rotterdam (the Netherlands), Bitterfeld (Germany) and Tarnowskie Gory (Poland).

These, and many other cases of different scale and specificity where contamination identification, monitoring, prevention and remediation is required, show the need of close collaboration of scientists representing different disciplines – chemists, toxicologists, ecotoxicologists, biologists, hydrogeologists, and soil scientists. One of the main messages of this book is thus a call for a better integration between ecology, biology, geology, hydrogeology, chemistry, and soil science: the interaction between these disciplines must become a means for enhanced complementary and mutual contributions to provide optimum practical solutions and technologies for monitoring, prevention and remediation of terrestrial and aquatic environmental contamination.

The contributors to the book are internationally recognized experts, and present both state-of-the art and novel approaches in the above fields, that makes the book unique with respect to the scope. The book is addressed to the vide range of professionals and decision-makers involved in the soil and water pollution monitoring, prevention and remediation issues, as well as to academic teachers and university students.

ACKNOWLEDGEMENTS

The idea of this book has arisen from the mutual experience, contacts and discussions of specialists from different countries involved in the problems of anthropogenic contamination of the terrestrial and aquatic environment, bioavailability, risk assessment, screening, monitoring and prognosis of contaminant migration, prevention and non-destructive remediation measures. The editors, on behalf of the authors and themselves, express their deep gratitude to NATO Science Affairs Division for the financial support, which made it feasible to organize a meeting of 49 invited prominent specialists within the NATO Advanced Research Workshop (NATO-ARW) entitled "Viable Methods of Soil and Water Pollution Monitoring, Protection

to publish this book that is an outcome of this remarkable meeting. The editors thank the Co-director of NATO ARW Prof. Dr. Elisha Tel-Or from the Hebrew University of Jerusalem, for his organizational efforts, the contributing authors for perfect cooperation, and the referees for their contribution into the book quality. The invaluable assistance and hard work of PhD student Sebastian Stefaniak at organizing the Workshop and involvement in preparing this volume for publication as Managing Editor is highly appreciated.

Irena Twardowska Herbert E. Allen

xvii

and Remediation" held from June 26 to July 1, 2005 in Krakow, Poland, and

Max M. H ggblom ä

CONTRIBUTORS

Abbt-Braun, Gudrun

Division of Water Chemistry, Engler-Bunte-Institut, Universität Karlsruhe, Engler-Bunte-Ring 1, 76131 Karlsruhe, Germany

Adani, Fabrizio

Dipartimento di Produzione Vegetale, Università Degli Studi di Milano, Via Celoria 2, 20133 Milano, Italy

Ahn, Young-Beom

Department of Biochemistry and Microbiology & Biotechnology Center

Allen, Herbert E.

Center for the Study of Metals in the Environment, Department of Civil and Environmental Engineering, University of Delaware, Newark, DE 19716-3120, U.S.A.

Alva, Ashok K.

Bunn Road, Prosser, WA 99350, U.S.A.

Anielska, Teresa

Institute of Environmental Sciences of the Jagiellonian University, 7 Gronostajowa Street, 30-387 Kraków, Poland

Aranowski, Robert

Department of Chemical Technology, Gdansk University of Technology, 11 Narutowicza Street, 80-952 Gdansk, Poland

xix

USDA-ARS, Vegetables and Forage Crops Research Unit, 24106 North

Jersey, New Brunswick, NJ 08901, U.S.A. for Agriculture and the Environment, Rutgers, The State University of New

xx Contributors

Atzmon, Nir

Institute of Field and Garden Crops, The Volcani Center, ARO, PO Box 6, Bet-Dagan 50250, Israel

Avnimelech, Yoram

Department of Civil and Environmental Engineering, TECHNION – Israel Institute of Technology, Haifa 32000, Israel

Belkin, Shimshon

Institute of Life Sciences, Hebrew University of Jerusalem, Edmond Safra Campus – Givat Ram, Jerusalem 91904, Israel

Buddhawong, Sasidhorn

King Mongut´s University of Technology, Chalongkrung Road, Ladkrabang Bangkok, 10520 Thailand

Campanella, Luigi

Department of Chemistry, University of Rome "La Sapienza"- Piazzale Aldo Moro 5- 00185 Rome, Italy

Chen, Yona

Faculty of Agricultural Food and Environmental Quality Sciences, The Hebrew University of Jerusalem, P.O. Box 12, Rehovot 76100, Israel

Chubar, Natalia I.

Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Street, 03164, Kiev, Ukraine

Ciaccheri, Leonard

NR-Institute of Applied Physics ‘Nello Carrara’, Via Panciatichi 64, 50127 Firenze, Italy

Costanza, Cecilia

Department of Chemistry, University of Rome "La Sapienza"- Piazzale Aldo Moro 5- 00185 Rome, Italy

Daus, Birgit

Department of Groundwater Remediation, UFZ Centre for Environmental Research Leipzig-Halle, Permoserstr. 15, 04318 Leipzig, Germany

Contributors xxi

Davison, William

Department of Environmental Science, Lancaster University, Lancaster, LA1 4YQ, UK

Doll, Tusnelda E.

Engler-Bunte-Institut, Bereich Wasserchemie, Universität Karlsruhe (TH), Kaiserstr. 12, 76131 Karlsruhe, Germany

Fennell, Donna E.

Fine, Pinchas

Institute of Soil, Water and Environmental Sciences, ARO, PO Box 6,

Forni, Cinzia

Scientifica, I-00133 Roma, Italy

Frimmel, Fritz H.

Division of Water Chemistry, Engler-Bunte-Institut, Universität Karlsruhe, Engler-Bunte-Ring 1, 76131 Karlsruhe, Germany

Gat, Pearly

Faculty of Agricultural Food and Environmental Quality Sciences, The Hebrew University of Jerusalem, P.O. Box 12, Rehovot 76100, Israel

Gauglitz, Guenther

Eberhard-Karls-University of Tuebingen, Institute of Physical and Theoretical Chemistry (IPTC), Auf der Morgenstelle 8, 72076 Tuebingen, Germany

Gawro ski, Stefan

Institute of Botany of the Jagiellonian University, Lubicz 46, 31-512 Krakow, Poland

Dipartimento di Biologia, Università “Tor Vergata”, Via della Ricerca

of New Jersey, New Brunswick, NJ 08901, U.S.A. Department of Environmental Sciences, Rutgers, The State University

Bet-Dagan 50250, Israel

xxii Contributors

Gerth, Andre

BioPlanta GmbH, Deutscher Platz 5, D-04103 Leipzig, Germany

Golan-Goldhirsh, Avi

Ben Gurion University of the Negev, Jacob Blausetin Institutes for Desert Research, Albert Katz Department of Dryland Biotechnologies, Sede Boqer Campus 84990, Israel

Górska, Paulina


Grechischeva, Natalia Yu.

Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia

Grossmann, Jochen

Grossmann Engineer Consult (GICON), Tiergartenstr. 48, 01219 Dresden, Germany

Häggblom, Max M.


Hardmuth, Thomas

Hass, Amir

Institute of Soil, Water and Environmental Sciences, ARO, PO Box 6, Bet-Dagan 50250, Israel

Hebner, Anja


Heidrich, Susanne




Contributors xxiii

Hupka, Jan


James, Monica A.

Engineering Research Center for Particle Science and Technology, Departments of Chemical Engineering and Anesthesiology, University of Florida, Gainesville, Florida 32611, U.S.A.

Janczarek, Marcin


Janssen, Colin R.

Laboratory of Environmental Toxicology and Aquatic Ecology, Ghent University, Jozef Plateaustraat 22, B-9000 Gent, Belgium

Janta-Koszuta, Krystyna

Polish Academy of Sciences, Institute of Environmental Engineering, 34 M. Sklodowska-Curie Street., 41-819 Zabrze, Poland

Jezierska, Barbara

Department of Animal Physiology, University of Podlasie, 12 Prusa Street, 08-110 Siedlce, Poland

Jurkiewicz, Anna

Institute of Molecular Biology, University of Aarhus, Gustav Wiedsvej 10C, 8000 Aarhus C, Denmark

Kaiser, Joachim

Siemens AG, CT PS 6, Paul-Gossen-Str. 100, 91050 Erlangen, Germany

Kania, Jaros aw

AGH – University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. Mickiewicza 30, 30-059 Krakow, Poland

Kanibolotskyy, Valentyn A.


xxiv Contributors

Kaschl, Arno


Keil, Martin

Landesanstalt für Altlastenfreistellung des Landes Sachsen-Anhalt, Postfach 32 02 49, 39041 Magdeburg, Germany

Kerkhof, Lee J.

Institute for Marine and Coastal Sciences, Rutgers, The State University of New Jersey, 71 Dudley Road, New Brunswick, NJ 08901-8521, U.S.A.

Kholodov, Vladimir A.

Department of Soil Science, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia

Konstantinov, Andrey I.


Kot-Wasik, Agata

Department of Analytical Chemistry, Chemical Faculty,Gda skUniversity of Technology (GUT),11 Narutowicza Street. 80-952 Gda sk,Poland

Kouts, Volodymyr S.


Kovalevskii, Dmitrii V.


Kowalska, Ewa


Kraemmer, Peter

Siemens AG, CT PS 6, Paul-Gossen-Str. 100, 91050 Erlangen, Germany

Contributors xxv

Krupanek, Janusz

IETU, 6 Kossutha Street, 40-844 Katowice, Poland

Kulikova, Natalia A.


Kuschk, Peter

UFZ Centre for Environmental Research Leipzig-Halle, Department of Bioremediation, Permoserstr. 15, 04318 Leipzig, Germany

Kwiatkowska, Jolanta

Department of Soil Science and Soil Conservation, Warsaw University of Technology, 1 Politechniki Sq., 00-661 Warsaw, Poland

Kyziol, Joanna

Polish Academy of Sciences, Institute of Environmental Engineering, 34 M. Sklodowska-Curie Street., 41-819 Zabrze, Poland

Lebedeva, Galina F.


Loffredo, Elisabetta

Dipartimento di Biologia e Chimica Agroforestale e Ambientale, Università di Bari, Via Amendola, 165/A, 70126-Bari, Italy

Maciejewska, Alina


Maestri, Elena

University of Parma, Department of Environmental Sciences, Parco Area delle Scienze 11/A, 43100 Parma, Italy

Malina, Grzegorz

Institute of Environmental Engineering, TUC, 73 Dabrowskiego Street, 42-200 Czestochowa, Poland

xxvi Contributors

Marmiroli, Marta


Marmiroli, Nelson


Matorin, Dmitrii N.

Department of Biology, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia

Mattusch, Jurgen

UFZ Centre for Environmental Research Leipzig-Halle, Department of Analytical Chemistry, Permoserstr. 15, 04318 Leipzig, Germany

Meer, ter Jeroen

TNO-MEP, Technopartner TNO, Postbus 342, 7300 AH Apeldoorn, The Netherlands

Mencaglia, Andrea A.


Migliore, Luciana

Dipartimento di Biologia, Università “Tor Vergata”, Via della Ricerca Scientifica, I-00133 Roma, Italy

Mignani, Anna G.


Miksch, Korneliusz

Environmental Biotechnology Department, Silesian University of Technology, 2 Akademicka Street, 44-100 Gliwice, Poland

Mingelgrin, Uri

Institute of Soils, Water and Environmental Sciences, Volcani Center, ARO, P.O.Box 6, Bet Dagan 50250, Israel

Contributors xxvii

Namie nik, Jacek

Department of Analytical Chemistry, Chemical Faculty,Gda skUniversity of Technology (GUT),11 Narutowicza Street, 80-952 Gdansk, Poland

Nasser, Ahmed

Institute of Soils, Water and Environmental Sciences, Volcani Center, ARO, P.O.Box 6, Bet Dagan 50250, Israel

Nepovim, Ales

Department of Plant Tissue Cultures, Institute of Organic Chemistry and Biochemistry, AS CR, Flemingovo nám. 2, 166 10, Praha 6, Czech Republic

Olexsey, Robert A.

National Risk Management Research Laboratory, Office of Research and Development, U. S. Environmental Protection Agency, 26 W. Martin Luther Drive, Cincinnati, OH 45268,U.S.A.

Orlowska, Elzbieta

Materials Research Group, iThemba LABS, PO Box 722, Somerset West 7129, South Africa

Paramasivam, Siva

Department of Natural Sciences and Mathematics, Savannah State University, 3219 College Street, P.O. Box 20600, Savannah, GA 31404, U.S.A.

Parker, Randy A.

National Risk Management Research Laboratory, Office of Research and Development, U. S. Environmental Protection Agency,26 W. Martin Luther Drive, Cincinnati, OH 45268, U.S.A.

Patrizi, Caterina

Dipartimento di Biologia, Università “Tor Vergata”, Via della Ricerca Scientifica, I-00133 Roma, Italy

Perminova, Irina V.


xxviii Contributors

Petrosyan, Valery S.


Pignatello, Joseph J.

The Connecticut Agricultural Experiment Station, Department of Soil and Water, 123 Huntington St., New Haven, CT 06504, and Environmental Engineering Program, Yale University, P.O. Box 208241, New Haven, CT 06520-8241, U.S.A.

P aza, Gra yna

Environmental Microbiology Department, Institute for Ecology of Industrial Areas, 6 Kossutha Street, 40-844 Katowice, Poland

Podlipna, Radka


Proll, Guenther


Przysta , Wioletta


Puls, Robert W.

U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, Ground Water and Ecosystems Restoration Division, 919 Kerr Research Drive, Ada, Oklahoma 74820, U.S.A.

Ravanel, Patrick

Perturbations environnementales et xénobiotiques (PEX), LECA, CNRS-UJF n° 5553, F-38041, Grenoble, France

Raveton, Muriel


Contributors xxix

Ravit, Beth


Rijnaarts, Huub M.

TNO-MEP, Technopartner TNO, Postbus 342, 7300 AH Apeldoorn, The Netherlands

Ron, Eliora Z.

Department of Molecular Microibology and Biotechnology, Tel Aviv University, Tel Aviv 69978, Israel

Ró a ski, Kazimierz

AGH – University of Science and Technology, Faculty of Physics and Nuclear Techniques, al. Mickiewicza 30, 30-059 Krakow, Poland

Ryszka, Przemys aw

Institute of Environmental Sciences of the Jagiellonian University, 7 Gronostajowa Street, 30-387 Kraków, Poland and Institute of Botany of the Jagiellonian University, Lubicz 46, 31-512 Krakow, Poland

Sacher, Frank

DVGW-Technologiezentrum Wasser, Karlsruher Str. 84, 76139 Karlsruhe, Germany

Sahi, Shivendra V.

Department of Biology, Western Kentucky University, 1906 College Heights Boulevard, Bowling Green, KY 42101, U.S.A.

Sajwan, Kenneth S.

Department of Natural Sciences and Mathematics, Savannah State University, 3219 College Street, P.O. Box 20600, Savannah, GA 31404, U.S.A.

Schirmer, Mario

Department of Hydrogeology, UFZ Centre for Environmental Research Leipzig-Halle, Theodor-Lieser-Str. 4, 06120 Halle (Saale), Germany


xxx Contributors

Senesi, Nicola

Dipartimento di Biologia e Chimica Agroforestale e Ambientale, Università di Bari, Via Amendola, 165/A, 70126-Bari, Italy

Shah, Dinesh O.

Engineering Research Center for Particle Science and Technology, Departments of Chemical Engineering and Anesthesiology, University of Florida, Gainesville, Florida 32611, U.S.A.

Shaposhnikova, Tetiana O.


Shea, Patrick J.

University of Nebraska-Lincoln, School of Natural Resources, Lincoln, NE 68583-0758, U.S.A.

Sievers, Judith

GICON, Tiergartenstr. 48, 01219 Dresden, Germany

Sk odowski, Piotr


Smrcek, Stanislav

Department of Nuclear Chemistry, Faculty of Natural Sciences, Charles University, Hlavova 8, Praha 2, Czech Republic

Stefaniak, Sebastian

Polish Academy of Sciences, Institute of Environmental Engineering, 34 M. Sklodowska-Curie Street, 41-819 Zabrze, Poland

Stien, Jan

DVGW-Technologiezentrum Wasser, Karlsruher Str. 84, 76139 Karlsruhe, Germany

Stottmeister, Ulrich

UFZ Centre for Environmental Research Leipzig-Halle, Permoserstr. 15, 04318 Leipzig, Germany

Contributors xxxi

Strelko, Volodymyr V.


Strijakova, Elena R.

Institute of Physicochemical and Biological Problems in Soil Science, Pushchino 142290, Russia,

Tawfic, Mohamed Ahmed

Environmental Impact Assessment Unit, Faculty of Agriculture, Suez Canal University, 4, Tag El Dien El Soubky St. 3rd District, Nasr City Cairo 11341, Ismailia, Egypt


Tschmelak, Jens


Turnau, Katarzyna

Institute of Environmental Sciences of the Jagiellonian University, 7 Gronostajowa Street, 30-387 Kraków, Poland

Twardowska, Irena

Polish Academy of Sciences, Institute of Environmental Engineering, 34 M. Sklodowska-Curie Street, 41-819 Zabrze, Poland

Ulfig, Krzysztof


Vanek, Thomas


Vasilyeva, Galina K.

Institute of Physicochemical and Biological Problems in Soil Science, Pushchino 142290, Russia,

Tissut, Michel

xxxii Contributors

Vavrikova, Zuzana


Venediktov, Pavel S.

Department of Biology, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia

Weiss, Holger


Wiessner, Arndt

UFZ Centre for Environmental Research Leipzig-Halle, Department of Bioremediation, Permoserstr. 15, 04318 Leipzig, Germany

Witczak, Stanis aw

AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. Mickiewicza 30, 30-059 Krakow, Poland

Witeska, Ma gorzata

Department of Animal Physiology, University of Podlasie, 12 Prusa Street, 08-110 Siedlce, Poland

Wycisk, Peter

Institute for Geological Sciences, Martin Luther University, von Seckendorff-Platz 3, 06120 Halle (Saale), Germany

Zaleska, Adriana

Department of Chemical Technology, Gdansk University of Technology, ul. Narutowicza 11/12, 80-952 Gdansk, Poland

Zhang, Hao

Department of Environmental Science, Lancaster University, Lancaster, LA1 4YQ, UK

Zhilin, Denis M.


Contributors xxxiii

Zubek, Szymon

Institute of Environmental Sciences of the Jagiellonian University, 7 Gronostajowa Street, 30-387 Krakow, Poland

Zuber, Andrzej

Polish Geological Institute, Carpathian Branch, 1 Skrzatow Street, 31-560 Krakow, Poland

soil and water pollution monitoring, protection and remediation978-1-4020-4728... · 2017-08-29 ·...

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