soil organic matter determination
DESCRIPTION
Soil Organic Matter Determination. Soil organic matter quantity - Can be express ed as a percentage - Can be express ed as mg.g -1 The wet oxidation of SOM using acid dichromate (K 2 Cr 2 O 7 ) is followed by the potentiometric titration with ferrous ammonium sulfate – Tjurin method - PowerPoint PPT PresentationTRANSCRIPT
![Page 1: Soil Organic Matter Determination](https://reader036.vdocument.in/reader036/viewer/2022082317/56812c4a550346895d90cd33/html5/thumbnails/1.jpg)
Soil Organic Matter Determination
Soil organic matter quantity- Can be expressed as a percentage- Can be expressed as mg.g -1
The wet oxidation of SOM using acid dichromate (K2Cr2O7) is followed by the potentiometric titration with ferrous ammonium sulfate – Tjurin method
Soil organic matter quality- Can be evaluated by C:N ratio- Can be evaluated by Humic acid and Fulvic acid ratio
Measuring of soil extract absorbance
![Page 2: Soil Organic Matter Determination](https://reader036.vdocument.in/reader036/viewer/2022082317/56812c4a550346895d90cd33/html5/thumbnails/2.jpg)
SOM Quantity Determination
1. Grind the soil and sieve it through 0.25 mm sieve2. Weight 0.3 g into 100-150 ml beaker3. Add 10 ml of K2Cr2O7 into the beaker3. Stir the soil with K2Cr2O7 carefully4. Cover the beaker using the watch glass5. Insert the beaker into the oven (125°C) for 45 min.6. Wash the beaker side and watch glass using distilled
water7. Titration with (NH4)2Fe(SO4)2
![Page 3: Soil Organic Matter Determination](https://reader036.vdocument.in/reader036/viewer/2022082317/56812c4a550346895d90cd33/html5/thumbnails/3.jpg)
Tjurin method
Equation2 K2Cr2O7 + 8 H2SO4 →
K2SO4 + 2 Cr2(SO4)3 + 8 H2O + 3 O2
3 O2 + 3 C → 3 CO2
K2Cr2O7 + 7 H2SO4 + 6 Fe(NH4)2(SO4)2 → K2SO4 + Cr2(SO4)3 + 3 Fe2(SO4)3
+ 6 (NH4)2SO4 + 7 H2O
Acid dichromate
Mohr salt
![Page 4: Soil Organic Matter Determination](https://reader036.vdocument.in/reader036/viewer/2022082317/56812c4a550346895d90cd33/html5/thumbnails/4.jpg)
Calculation
• Factor of Mohr salt
• Cox
• Humus content
40f
a
100(12 0,3 )Cox S f
n
% 1,724humus Cox
.
.
.
.
![Page 5: Soil Organic Matter Determination](https://reader036.vdocument.in/reader036/viewer/2022082317/56812c4a550346895d90cd33/html5/thumbnails/5.jpg)
Evaluation of Cox/Humus Content
Cox (%) Humus (%) Evaluation
< 0.6 < 1.0 very low
0.6 – 1.1 1.0 – 2.0 low
1.1 – 1.7 2.0 – 3.0 medium
1.7 – 2.9 3.0 – 5.0 high
> 2.9 > 5.0 very high