solute transport into shark river slough poinciana... · 13 conclusions • wrtds is a promising...

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Solute transport into Shark River Slough Troy D. Hill 1 , Kevin Kotun 2 1 National Park Service, Department of the Interior 2 United States Geological Survey, Department of the Interior

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Page 1: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

Solute transport into Shark River Slough

Troy D. Hill1, Kevin Kotun2

1National Park Service, Department of the Interior2United States Geological Survey, Department of the Interior

Page 2: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

2

1. Application of WRTDS to stations at ENP northern boundary, 1992 - 2017

2. Trends in nutrients (TP, TKN) and geogenic solutes (Ca, Mg, Na)

Outline

Page 3: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

3

> 5000 sampling locations

Page 4: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

4

S151

S333

S12A S12BS12D

S12C

Page 5: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

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Why model concentrations?

Sampling events may not be representative

Page 6: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

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C-Q relationships are not uniform

Page 7: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

WRTDS – WTF?• Weighted Regression on Time, Discharge, and Season (EGRET)

• Allows time and discharge relationships to vary• Estimates raw and flow-normalized concentrations

• What are the trends? How confident are we?• Do trends differ by season? By discharge magnitude?

7Hirsch et al. 2010; Hirsch et al. 2015

Page 8: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

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TP time series for S333

- estimated· observed

TP (m

g·L-1

)

Page 9: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

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· annual mean conc- flow-normalized conc (FNc)

TP a

t S33

3 (m

g·L-1

)Bootstrapped trend in FNc 1992-2017

Dens

ityComparison

Page 10: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

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Water quality trends: 1992-2017

Page 11: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

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TP at different flows (S333)1987 - 1991 2015 - 2019

TP (m

g·L-1

)

Page 12: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

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Ca+Mg at different flows (S333)1987 - 1991 2015 - 2019

Hard

ness

as C

aCO

3(m

g·L-1

)

Page 13: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

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Conclusions

• WRTDS is a promising tool

• Water quality gains more dramatic for nutrient concentrations vs. fluxes

• Concentrations of geogenic solutes are also declining – less groundwater

• Nutrient reductions more dramatic at low flows

[email protected]

DataForEver data requests: [email protected]

Page 14: Solute transport into Shark River Slough Poinciana... · 13 Conclusions • WRTDS is a promising tool • Water quality gains more dramatic for nutrient concentrations vs. fluxes

S151 S333 S12A

S12B S12C S12D

TP (m

g·L-1

)