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Page 1: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Solutions Chapter 7: Solutions

Page 2: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Educational Goals 1.  Compare and contrast mixtures and pure substances. 2.  Understand, compare, and contrast the terms homogeneous mixture

and heterogeneous mixture. For a homogeneous mixture, explain the difference between solute(s) and solvent.

3.  Predict the effect of temperature and pressure on the solubility of gases in water and the effect of temperature on the solubility of solids in water.

4.  Be able to use the Solubility Rules Table to determine if an ionic compound will significantly dissolve in water.

5.  Predict whether a precipitation reaction will occur when two specified aqueous solutions of ionic compounds are mixed; if a precipitation reaction will occur, write a balanced chemical equation for the reaction.

6.  Compare the relative solubilities of organic molecules based on the functional groups or the relative sizes of the hydrocarbon (nonpolar) regions.

Page 3: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Educational Goals 7.  Explain, compare, and contrast the terms hydrophilic, hydrophobic,

and amphipathic, and give examples of compounds that belong to each category.

8.  Be able to calculate the concentration of a solution using various concentration units of measurements. (%, parts per thousand, ppm, ppb, molarity, molality, osmolality, osmolarity, and Eq/L)

9.  Given the concentration, be able to convert from the volume of solution to the amount of solute (and vice versa).

10. Given a solution’s initial concentration, be able to use the dilution equation to determine the concentration of the solution after dilution.

11.  Compare and contrast solutions, suspensions, and colloids. 12.  Describe the processes of diffusion and osmosis. Define osmotic

pressure and predict the effect of solute concentration on the osmotic pressure.

Page 4: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Classification of Matter

•  Matter can be classified into one of two groups: 1) Mixtures 2) Pure Substance

Page 5: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

A pure substance can be either an element (just one type of atom) or a compound.

mercury

silver

oxygen

water NaCl

sucrose

elements compounds

Pure Substances

Page 6: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Mixtures •  Most objects around us are mixtures.

–  Example: most foods and beverages, air, the chair you are sitting in.

•  The components are physically mixed together and can be separated by physical methods. •  The properties of mixtures depend on the identity and

amount of each component in the mixture –  Therefore to fully describe a mixture, the composition of the

mixture must be stated. •  Example: 5% Starch solution, 75:25% Zinc/Copper Alloy

Page 7: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Mixtures

•  Mixtures can be either uniform in composition (homogeneous) or the composition can vary throughout the sample (heterogeneous).

Page 8: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

•  Homogeneous mixtures = uniform throughout, appears to be one thing – Homogenous mixtures are called solutions. – Solutions can be liquid, gas, or solid – Examples: Sugar dissolved in water (liquid)

Air (gas) 14-karat gold (solid mixture of gold, silver, and

copper)

•  Heterogeneous mixtures = non-uniform, contains regions with different properties than other regions – Examples: chocolate chip cookies

sand in water

Page 9: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Types of Mixtures

•  solution—a homogenous mixture •  suspension—a solution that appears uniform

while being stirred but separates quickly after stirring

•  colloid—a mixture in which small particles are suspended throughout

We will discuss solutions first, later we will come back to briefly describe suspensions and colloids

Page 10: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Solutions •  The primary ingredient in a solution is called the

solvent. •  The other ingredients are the solutes and are said to

be dissolved in the solvent. •  Water is the most common solvent. •  Water is a unique solvent because so many

substances can dissolve in it. •  Solutions in which water is the solvent are called

aqueous solutions.

Page 11: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Solutions •  Example: Solution of ethanol in water

Page 12: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Electrolyte Solutions •  Electrolytes are compounds that dissolve

in water to form ions.

– The consequences of having too much or too little of a particular electrolyte can have profound effects on your health.

– Ions important to your health: • Na+, K+ = transmission of nerve impulses • Ca2+ = muscle contraction and blood clotting

Page 13: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Electrical conductivity of aqueous solutions

(a) Pure water does not conduct an electric current. (b) When an ionic compound is dissolved in water, current flows and the lamp lights.

Page 14: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Dissolving: Dissolution of CuCl2

CuCl2:

Strong Electrol

yte

Page 15: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Dissolving: Dissolution of NaCl

NaCl: Strong Electrolyte

Page 16: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Aqueous ethanol solution

Ethanol molecules are solvated, but do not ionize!!!

• Ethanol is not an ionic compound

• Non electrolyte

Page 17: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Aqueous sugar solution

Sugar molecules are solvated, but do not ionize!!!

Non Electrolyte

Page 18: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Solutions: Solubility The formation of liquid solutions, such as Kool Aid or dissolved NaCl, requires that solute particles be able to interact with the solvent molecules through noncovalent interactions.

“like dissolves like”

Page 19: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Solubility •  Solubility refers to the amount of solute that will

dissolve in a given amount of solvent at a given temperature.

•  Temperature can affect solubility. –  For all gaseous solutes (O2, CO2, etc.), an increase in

temperature leads to a decrease in solubility.

–  Most liquid and solid solutes become more soluble in water as temperature increases.

Page 20: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Solubility

Some ionic compounds are highly soluble in water solutions. Other ionic compounds are insoluble or only slightly soluble.

Page 21: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

With ionic compounds, it is not so easy to predict if they will dissolve in water!

•  We need to look it up in a solubility table

Page 22: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

For homework problem 7.7:

• CuS Copper (II) sulfide is insoluble

Page 23: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Group Work Indicate whether each ionic compound is soluble or insoluble in water.

a.  KNO3 b.  BaSO4 c.  LiI

Strategy: Refer to Table

Page 24: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Saturated Solution At some point, even with highly soluble compounds, a solution will reach it’s capacity to dissolve.

If more of solute is added to a saturated solution it will not dissolve.

• At that point, solute particles are re-crystallizing at the same rate that they are dissolving.

• equilibrium

Page 25: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Example: a. If 45.0 g of NaCl are added to 100g of

water at 20 °C, will all of the NaCl dissolve?

b. Is the resulting mixture homogeneous or heterogeneous?

Page 26: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

The Solubility of Gases in Water

Page 27: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

The solubility of gases in solution depend on:

1) Temperature

2) Pressure

Gas Solubility

Page 28: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Henry’s Law

The solubility of a gas in a liquid is proportional to the pressure of the gas over the liquid.

The higher the pressure of a gas above a liquid, the greater its solubility.

Page 29: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Any Fishermen in the Class? On a hot day, it is often easier to catch fish by casting your line into a deep, cool part of a lake than into a shallow, warm spot. One reason that fish gather in cool water may be related to the levels of oxygen dissolved in the water. Explain.

Page 30: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Double Replacement Reactions

In a double replacement reaction, two substances “switch partners.” The general form of a double replacement reaction, where compounds AX and BY switch partners, is:

AX + BY → AY + BX

Reactions of Ions in Aqueous Solutions

Page 31: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Reactions of Ions in Aqueous Solutions

Double Replacement Reactions: 1) Precipitation reactions 2) Gas Producing Reactions

Page 32: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

1) Precipitation Reactions

Precipitation reactions may occur when two solutions that contain dissolved ions are mixed.

In a precipitation reaction, two compounds in aqueous solution appear to exchange ions.

A+ X- + B+ Y- → A+ X- + B+ Y-

If one of the new pairs formed is insoluble, a new substance (solid/precipitate) is formed.

Page 33: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

For a precipitation reaction to occur, at least one of the products formed is insoluble in water. Therefore, a solid is always formed in a precipitation reaction.

Often, many tiny crystals are formed and this gives the mixture a cloudy appearance. The cloudy appearance may be white, black, or some other color, depending on the identity of the particular solid that is formed.

We say the solid “precipitated” from the solution.

The appearance of the solid precipitate indicates the formation of new ionic bonds and that a reaction has occurred.

Page 34: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

The educational goals for precipitation reactions are:

•  Predict if a precipitation reaction will occur when two aqueous ionic compounds are combined.

•  Write the balanced chemical equation for the reaction.

Page 35: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Method for Predicting if a Precipitation Reaction will Occur and Writing the Balanced Chemical Equation for Precipitation Reactions

Step 1: Write reactants’ names and arrow for the chemical equation using word form (not the chemical formula).

lead(II) nitrate + potassium chromate → Step 2: Add the “possible” products to the word equation by switching anions.

Example: The reaction of lead(II) nitrate and potassium chromate.

lead(II) nitrate + potassium chromate → lead(II) chromate + potassium nitrate

Page 36: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Method for Predicting if a Precipitation Reaction will Occur and Writing the Balanced Chemical Equation for Precipitation Reactions

Step 3: Convert the word equation to a formula equation. Note: Students often need to review the section in chapter 3 that discusses naming ionic compounds in order to perform Step 3. Step 4: Balance the equation:

lead(II) nitrate + potassium chromate → lead(II) chromate + potassium nitrate

Pb(NO3)2 + K2CrO4 → PbCrO4 + KNO3

Pb(NO3)2 + K2CrO4 → PbCrO4 + 2 KNO3

Pb(NO3)2 (aq) + K2CrO4 (aq) → PbCrO4 (s) + 2 KNO3 (aq)

Step 5: Add the phase of each of the reactants and “possible” products to the chemical equation.

Page 37: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Method for Predicting if a Precipitation Reaction will Occur and Writing the Balanced Chemical Equation for Precipitation Reactions

Pb(NO3)2 (aq) + K2CrO4 (aq) → PbCrO4 (s) + 2 KNO3 (aq)

Step 5: Add the phase of each of the reactants and “possible” products to the chemical equation.

•  In all precipitation reactions, the reactants are always aqueous.

• Use the Solubility Rules Table to determine the phase of the “possible” products.

•  If a compound is water soluble, it remains dissolved and we write “(aq).”

•  If a compound is water insoluble, it precipitates as a solid and we write “(s).”

Page 38: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Method for Predicting if a Precipitation Reaction will Occur and Writing the Balanced Chemical Equation for Precipitation Reactions

Example: The reaction of sodium chloride and silver nitrate.

Step 1: Write reactants’ names and arrow for the chemical equation using word form (not the chemical formula).

sodium chloride + silver nitrate → Step 2: Add the “possible” products to the word equation by switching anions.

sodium chloride + silver nitrate → sodium nitrate + silver chloride

Page 39: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Method for Predicting if a Precipitation Reaction will Occur and Writing the Balanced Chemical Equation for Precipitation Reactions

Step 3: Convert the word equation to a formula equation.

NaCl + AgNO3 → NaNO3 + AgCl

Step 4: Balance the equation: • In this example, the equation is already balanced; each of the coefficients is “1.”

NaCl + AgNO3 → NaNO3 + AgCl

sodium chloride + silver nitrate → sodium nitrate + silver chloride

Step 5: Add the phase of each of the reactants and “possible” products to the chemical equation.

NaCl (aq) + AgNO3 (aq) → NaNO3 (aq) + AgCl (s)

Page 40: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Step 1: Write reactants’ names and arrow for the chemical equation using word form (not the chemical formula).

sodium chloride + potassium nitrate → Step 2: Add the “possible” products to the word equation by switching anions.

sodium chloride + potassium nitrate → sodium nitrate + potassium chloride

Example: Determine if a precipitation reaction would occur when a sodium chloride solution is mixed with a potassium nitrate solution.

Page 41: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Step 3: Convert the word equation to a formula equation.

NaCl + KNO3 → NaNO3 + KCl

Step 4: Balance the equation: In this example, the equation is already balanced; each of the coefficients is “1.”

NaCl + KNO3 → NaNO3 + KCl

sodium chloride + potassium nitrate → sodium nitrate + potassium chloride

Page 42: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Step 5: Add the phase of each of the reactants and “possible” products to the chemical equation.

NaCl (aq) + KNO3 (aq) → NaNO3 (aq) + KCl (aq) NO REACTION

IMPORTANT: If both of the “possible” products are water soluble, then no reaction occurred. There were solvated cations and anions in each the two solutions before mixing, then the solutions were mixed and the cations and anions remained solvated in the mixture. No new chemical bonds were made, therefore no chemical reaction occurred. When no reaction occurs in precipitation reaction problems such as this example, you can write “No Reaction” instead of the “possible” products.

Page 43: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

You try one:

Determine if a precipitation reaction would occur when a silver nitrate solution is mixed with a barium chloride solution and, if a reaction does occur, write the balanced chemical equation.

Page 44: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

HCl + NaHCO3 → HHCO3 + NaCl

2) Gas Producing Double Replacement Reactions

A gas producing double replacement reaction is a special type of double replacement in which a gas is produced.

Example: The reaction of aqueous hydrogen monochloride (HCl, also know as hydrochloric acid) and aqueous sodium bicarbonate (NaHCO3).

In this reaction, the bicarbonate and chloride anions switch partners to form aqueous carbonic acid (HHCO3) and sodium chloride.

Page 45: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

HCl (aq) + NaHCO3 (aq) → HHCO3 (aq) + NaCl (aq)

HCl (aq) + NaHCO3 (aq) → H2CO3 (aq) + NaCl (aq)

carbonic acid

Carbonic acid decomposes to H2O (l ) and CO2(g)

HCl (aq) + NaHCO3 (aq) → H2O (l ) + CO2 (g) + NaCl (aq)

Gas Producing Double Replacement Reaction

In the chemical equation on the previous slide, I wrote the formula of carbonic acid as HHCO3 in order to help you see how Cl- and HCO3

- “switched partners”; however the correct way to write the formula for carbonic acid is H2CO3, as described below.

Page 46: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Organic Compounds in Solutions

Note: a solution can be made in other solvents than water

Page 47: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

When will solutions be formed? “Like dissolves like”

Page 48: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms
Page 49: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms
Page 50: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

• Which pairs will form solutions? – CCl4 and water – Gasoline and MgSO4 – Hexane (C6H14) and heptane (C7H14) – Ethyl alcohol (C2H5OH) and heptanol (C7H15OH)

Page 51: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

The Solubility of Organic Compounds in Water

•  Although hydrocarbons are not soluble in water, many organic compounds are. – Hydrogen bonding with water helps. – Polar molecules can be soluble in water.

Page 52: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Example: Alcohols

•  The larger the hydrocarbon in an alcohol, the less soluble it is in water.

Soluble Slightly Soluble

3 2

Page 53: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Example: Carboxylic acids

• As with alcohols, the larger the hydrocarbon that a carboxylic acid has, the less soluble it is in water.

Soluble Slightly Soluble

Page 54: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Example: Esters

• A similar pattern is seen with esters

Slightly Soluble Not Soluble

Page 55: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Biochemical Compounds

Page 56: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

The compounds found in living things can be placed into one of three solubility classes.

1.  hydrophilic - those that are soluble in

water 2.  hydrophobic - those that are insoluble

in water 3.  amphipathic - have both hydrophilic

and hydrophobic parts

Page 57: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Hydrophilic Compounds

Since like dissolves like, to be hydrophilic, a molecule must resemble water: – polar groups and/or – those able to form hydrogen bonds

Page 58: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Examples of Hydrophilic Compounds

Carbohydrates

Page 59: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Examples of Hydrophilic Compounds

Amino Acids

Page 60: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Cholesterol is insoluble in water…therefore hydrophobic.

Examples of Hydrophobic Compounds

Page 61: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Triglycerides are insoluble in water….therefore hydrophobic.

Examples of Hydrophobic Compounds

Page 62: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Fatty acids (long hydrocarbon chain carboxylic acids) are insoluble in water

Examples of Hydrophobic Compounds

Page 63: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Example of Amphipathic Compounds

-

Polar “Head”

Nonpolar “Tail”

Amphipathic compounds have one part of the molecule that is hydrophilic and another part that is hydrophobic.

Very often the polar end of amphipathic compounds will have a formal charge.

Page 64: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Example of Amphipathic Compounds

-

Polar “Head”

Nonpolar “Tail”

Amphipathic compounds are often illustrated using the ball and stick model.

•  Ball = Polar Head •  Stick = Nonpolar Tail

Page 65: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Amphipathic Compounds in Water When added to water, amphipathic compounds can form a:

• (a) monolayer • (b) micelle

Page 66: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Emulsification by Amphipathic Compounds: Soaps

Oil Droplet

Page 67: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Based on its structure, do you expect vitamin C to be hydrophobic or hydrophilic? Explain.

Problem:

Page 68: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Sodium lauryl sulfate is a detergent often present in shampoos. Identify this molecule as hydrophilic, hydrophobic, or amphipathic.

Try another one:

Page 69: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Concentration:

Describing the amount of solute in a solution

Page 70: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

•  The term concentration is used to refer to the amount of solute that is dissolved in a solvent. – A saturated solution holds the maximum

amount of solute that can be dissolved at a particular temperature.

– An unsaturated solution holds less than a saturating amount of solute.

Page 71: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Concentration by Percent In general, percentage can be defined as:

Part

Whole % = x 100

Mass of Part

Total Mass % Mass = x 100

In chemistry, we are usually interested in percent by mass:

Page 72: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Concentration by Percent •  Percent means the same thing as “parts per

hundred”, so when percent is used as a concentration unit, the number of parts of solute present in every 100 parts of solution is being specified.

•  There are three commonly used percent measurements for concentration:

1.  weight/weight %(w/w) 2.  volume/volume %(v/v) 3.  weight/volume %(w/v)

Page 73: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

grams of Solute

grams of Solution % (Weight/Weight) = x 100%

mL of Solute

mL of Solution % (Vol/Vol) = x 100%

grams of Solute

mL of Solution % (Weight/Vol) = x 100%

Page 74: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Potassium iodide (KI) is used to tread iodine deficiencies. What is the %(w/v) of a 75 mL solution containing 2.0g of KI?

Example

grams of Solute

mL of Solution % (Weight/Vol) = x 100%

2.0 g of KI

75 mL of Solution % (Weight/Vol) = x 100%

= 2.7%(w/v)

Page 75: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Parts per thousand, parts per million, and parts per billion

These units are mostly used for very dilute solutions.

If 30 mg of sucrose is dissolved in a swimming pool, the sucrose concentration is 0.001 ppm and 1 ppb.

Page 76: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Parts per thousand, parts per million, and parts per billion

grams of Solute

mL of Solution % (w/v) = x 100%

Recall that % is parts per hundred:

We can easily calculate parts per thousand:

grams of Solute

mL of Solution parts per thousand =

(w/v) x 1000

Page 77: Solutions - Saddleback College · PDF fileChapter 7: Solutions . Educational Goals 1. Compare and contrast mixtures and pure substances. 2. Understand, compare, and contrast the terms

Parts per thousand, parts per million, and parts per billion

parts per million: grams of Solute

mL of Solution ppm (w/v) = x 106

parts per billion:

grams of Solute

mL of Solution ppb (w/v) = x 109

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Many cities add sodium fluoride to their drinking water to help reduce dental cavities. If 25 L of city water contains 0.018g of sodium fluoride, what is the concentration in parts per billion?

Example:

grams of Solute

mL of Solution ppb (w/v) = x 109

0.018g of NaF

25000 mL of Solution ppb (w/v) = x 109

= 720 ppb

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Chemists usually use molarity to describe the concentration of a solution

Molarity Molarity (M) is defined as the number of moles of solute present in each liter of solution.

moles of Solute

liters of Solution Molarity (M) =

Note: The unit M is the same as mole/L

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A solution is prepared by dissolving 0.10 moles of the amino acid alanine in enough water to give a final volume of 75 mL. What is the molarity of the solution?

Example

moles of Solute

liters of Solution Molarity (M) =

0.10 moles

.075 L Molarity (M) =

= 1.3 M or 1.3 moles/L

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A solution is prepared by dissolving 0.57 moles of the adrenaline in enough water to give a final volume of .018 L. What is the molarity of the solution?

You try it

= 32 M or 32 moles/L

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Concentration as a Conversion Factor

• Knowing the concentration allows us to convert between #moles of solute and volume of solution.

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Molarity as a Conversion Factor Since Molarity (M) is the relationship between moles of solute and volume for a solution, it can be used as a conversion factor.

# moles Volume (L)

Molarity (M) =

• convert between # of moles present and volume!

Volume (L) # moles

# moles Volume (L) Conversion

Factors

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A glucose solution has a concentration of .0500 moles/L. How may moles of glucose are in .0250 ml of this solution?

Molarity as a Conversion Factor Example :volume to moles

Strategy: The concentration of 0.0500 moles/L can be used as a conversion factor.

.025 L glucose =

.0500 moles glucose 1 L 1.25 x 10-3

moles glucose

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A sample of blood serum is tested and found to contain testosterone at a concentration of 0.0075 moles/L. What volume (L) of blood would contain 1.2 moles of testosterone?

Concentration as a Conversion Factor Example : volume to mass

160 L

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% Concentration as a Conversion Factor Since % is the relationship between solute and amount of a solution, it can be used as a conversion factor.

# grams 100. ml solution

% (w/v) =

• Example % (weight to volume, w/v)

• convert between # of grams present and volume!

100. ml # grams

# grams 100. ml Conversion

Factors

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If low fat milk is 2.00% (w/v) fat, how many grams of fat are contained in 275 mL of low fat milk?

% Concentration as a Conversion Factor Example : volume to grams

275 mL milk = 2.00 g fat 100. mL milk

5.50 g fat

100. ml milk 2.00 g fat

2.00g fat 100. ml milk Conversion

Factors

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Other Concentration

Units

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Osmolarity is the number of osmoles per liter of solution.

• An osmole is the number of moles of dissolved particles that are contained in a solution.

Concentration in Osmolarity

# osmoles

L of solution Osmolarity =

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Example: One mole of NaCl is equal to 2 osmole. (NaCl ionizes)

One mole of sucrose is equal to1 osmole.(non-ionizing)

How many osmole(s) in 1 mole of CuCl2? CuCl2 → Cu2+ + 2 Cl-

Concentration in Osmolarity

NaCl(s) → Na+ (aq) + Cl- (aq)

Sucrose (s) → Sucrose (aq)

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Example: 4.35 moles of CuCl2 is dissolved in enough water to make 5.80 L of solution. What is the osmolarity of the solution?

Concentration in Osmolarity

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Molality (m) is another way to express moles of solute in a solution.

Concentration in Molality

Molality is the number of moles of solute per kg of solvent (moles/kg).

# moles

kg of solvent Molality (m) =

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• Osmolality is the number of osmoles per kg of solvent.

Concentration in Osmolality

# osmoles

kg solvent Osmolality =

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In the case of dilute aqueous solutions, scientists often use the approximation:

Molarity (mol/L) = Molality (mole/kg solvent) This is a very close approximation for dilute solutions because: •  1) 1 kg of water = 1 L •  2) volume of solvent >> volume of solute therefore:

–  volume of solution ≅ volume of solvent – mass of solution ≅ mass of solvent

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An equivalent (Eq) is the number of moles of charge that a solute contributes to a solution.

Concentration in equivalents (Eq/L)

# equivalents

L of solution (Eq/L) =

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Example: One mole of NaCl is equal to 2 equivalents.

One mole of sucrose has no equivalents.(non-ionizing)

How many equivalents are in 1 mole of dissolved CuCl2? CuCl2 → Cu2+ + 2 Cl-

• 2 from Cu2+ and 1 from each Cl- 4

Concentration in Equivalents

NaCl(s) → Na+ (aq) + Cl- (aq)

Sucrose (s) → Sucrose (aq)

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Example: 4.35 moles of CuCl2 is dissolved in enough water to make 5.80 L of solution. • What is the concentration in Eq/L of the solution?

CuCl2 → Cu2+ + 2 Cl-

Concentration in Eq/L

4 Eq

1 moles CuCl2

4.35 moles CuCl2 = 17.4 Eq

17.4 Eq

5.80 L of solution (Eq/L) = = 3.00 Eq/L

# equivalents

L of solution (Eq/L) =

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Milliequivalents (or mEq) per liter is another way to express moles of solute in a volume of solution.

Concentration in mEq/L

An equivalent (Eq) is the number of moles of charges that one mole of a solute contributes to solution. Example: One mole of Ca2+ is equal to 2 Eq of Ca2+

One mole of Na+ is equal to 1 Eq of Na+

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The serum concentration of Ca2+, is sometimes reported in either mmol/L or mEq/L. The normal range of Ca2+ in blood serum is 1.15-1.30 mmol/L. Convert this range into mEq/L.

Example

1.15 mmole Ca2+

1 L =

1 mmole Ca2+

2 mEq Ca2+ 2.30 mEq Ca2+ L

1.30 mmole Ca2+

1 L = 1 mmole Ca2+

2 mEq Ca2+ 2.60 mEq Ca2+ L

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Dilution • When more solvent is added to a solution, it has been diluted.

• Dilution is an easy way to reduce the concentration of a solution.

• Dilution is also important in health care because some drugs must be diluted to the proper concentration before being administered.

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Voriginal x Coriginal = Vfinal x Cfinal

V = volume

C = concentration

Dilution Equation

Original mass or moles of solute

Final mass or moles of solute =

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You begin with 25 mL of a 1.8 M aqueous LiCl solution and add enough water to give a final volume of 35 mL. What is the new concentration?

Example

Strategy:

M1 x V1 = M2 x V2

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(35 mL)

(25 mL)

M1 = 1.8 M M2 = ?

V1 = 25 mL V2 = 35 mL

Solution

= 1.3 M V2

M2 M1

V2

V1 =

V2 M2 M1 V1 =

V2

= (1.8 M)

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25 mL of a 1.8 M aqueous LiCl solution is diluted to a final volume of 450 mL. What is the new concentration?

Group Work

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Colloids and Suspensions

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• Colloids and suspensions are mixtures that resemble solutions, but have some important differences: • A suspension contains large particles suspended in a liquid.

• The particles will eventually, slowly settle to the bottom in the absence of agitation

• In a colloid, the particles are larger than the typical solutes in a solution, but smaller than the particles that make up a suspension

• Therefore they will not settle to the bottom of the container.

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Suspensions: Muddy Water

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Suspensions: Orange Juice

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Examples of Colloids: Milk •  Milk appears to be homogeneous. But under a

microscope you see that milk contains globules of fat and small lumps of the protein casein dispersed in a liquid called whey. Milk is colloid because the particles of casein do not settle out after standing.

Other Examples of Suspensions Pepto Bismal is a suspension of bismuth subsalicylate

particles. Milk of magnesia is a suspension of magnesium hydroxide particles.

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Suspensions scatter light. Colloids often scatter light

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Common Examples of Colloids

Mayonnaise is a colloidal suspension of water and vinegar droplets in edible oil, emulsified by egg yolk Other Examples: fog, liquid foam, whipped cream, hand cream, paint, pigmented ink, solid foam, gelatin, jelly, cheese

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Summary of Solutions, Colloids, And Suspensions

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Diffusion and Osmosis

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Just like gases, liquids can diffuse. Liquid molecules travel randomly in all directions and mix quickly with other liquid molecules in a process called diffusion.

Diffusion is the movement of one substance within another substance until it is evenly distributed.

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Substances move from areas of higher concentration to those of lower concentration by diffusion.

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Certain membranes, called semipermeable membranes, are barriers to diffusion because they allow solvents, but not all solutes to pass through. •  The semipermeable membrane

in the image allows water to pass but not the Na+ or Cl- ions

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Although water moves back and forth through most semipermeable membranes, it flows more forcefully from the side of the membrane with lesser solute concentration to the side with greater solute concentration.

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The net movement of water across a membrane from a solution of lesser solute concentration to one of greater solute concentration is called osmosis.

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The pressure associated with the transport of water in the osmosis process is called: osmotic pressure. The greater the difference in solute concentrations across the semipermeable membrane, the greater the osmotic pressure.

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Cell membranes are semipermeable and are, therefore, affected by osmosis.

•  In an isotonic solution, the solute concentration is the same on each side the cell membrane and the cells retain their normal size and shape.

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•  In a hypertonic solution, the solute concentration is greater outside the cell membrane and the cell shrinks because osmosis pulls water out.

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•  In a hypotonic solution, the solute concentration is greater inside the cell membrane and the cell swells because osmosis brings water in.

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