stack emissions monitoring report · 2019-01-16 · socotec uk job number: report date: version: 1...
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SOCOTEC UK Job Number:Report Date:Version: 1Report By: Adam RussellMCERTS Number: MM 15 1360MCERTS Level: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Report Approved By: Andrew O'NeillMCERTS Number: MM 08 985Business Title: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Signature:
Sampling Date(s):23rd - 30th August
27th September 2018LEK 11283
Co. LeitrimIreland
Drumsna
Masonite Ireland
Carrick-on-Shannon
Release Point: SO2A
Your contact at SOCOTEC UK LTD
Operator & Address:
Derryoughter
2-4 Langlands PlaceKelvin South Business Park
East KilbrideG75 0YF
Tel: 01355 246 730Fax: 01355 249 669
Permit Reference:IPPC Licence: PO021-02
David HayBusiness Manager - North
Tel: 01355 246 730Email: [email protected]
STACK EMISSIONS MONITORING REPORT
SOCOTEC UK Reporting Template v1 Page 1 of 51
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EXECUTIVE SUMMARY
Stack Emissions Monitoring Objectives
- Plant
- Operator
- Stack Emissions Monitoring Test House
Emissions Summary
Monitoring Times
Process Details
Monitoring Methods
Analytical Methods
- Sampling Methods with Subsequent Analysis
- On-Site Testing
Sampling Location
- Sampling Plane Validation Criteria
- Duct Characteristics
- Sampling Lines & Sample Points
- Sampling Platform
- Sampling Location / Platform Improvement Recommendations
Sampling and Analytical Method Deviations
APPENDICES
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
CONTENTS
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Plant
SO2A
Operator
Masonite Ireland
Derryoughter
Drumsna
Carrick-on-Shannon
Co. Leitrim
Ireland
IPPC Licence: PO021-02
Stack Emissions Monitoring Test House
SOCOTEC UK - East Kilbride Laboratory2-4 Langlands PlaceKelvin South Business ParkEast KilbrideG75 0YFUKAS and MCERTS Accreditation Number: 1015
Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited.This test report shall not be reproduced, except in full, without written approval of SOCOTEC UK LTD.
MONITORING OBJECTIVES
SOCOTEC UK LTD were commissioned by Masonite Ireland to carry out stack emissions monitoring to determine the release of prescribed pollutantsfrom the following Plant under normal operating conditions.
Masonite Ireland operates a first stage fibre drier process at Carrick-on-Shannon which is subject to IPPC Licence PO021-02, under the EPA Act 1992.
EXECUTIVE SUMMARY
The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in thePlant's IPPC Licence, PO021-02.
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Parameter Units Result Calculated Uncertainty
Limit
+/-Total Particulate Matter mg/m³ 1.57 0.23 20Particulate Emission Rate kg/hr 0.32 0.05 2.1
Dioxins & Furans (NATO I-TEQ) ng/m³ 0.0084 0.0109 -Dioxins & Furans (NATO I-TEQ) Emission Rate µg/hr 1.2390 1.6095 -Dioxins & Furans (WHO TEQ Humans / Mammals) ng/m³ 0.0076 0.0099 -Dioxins & Furans (WHO TEQ H / M) Emission Rate µg/hr 1.1199 1.4548 -Dioxins & Furans (WHO TEQ Fish) ng/m³ 0.0089 0.0115 -Dioxins & Furans (WHO TEQ Fish) Emission Rate µg/hr 1.3067 1.6974 -Dioxins & Furans (WHO TEQ Birds) ng/m³ 0.0194 0.0252 -Dioxins & Furans (WHO TEQ Birds) Emission Rate µg/hr 2.8583 3.7129 -
Dioxins & Furans (NATO I-TEQ) ng/m³ 0.0075 0.0098 -Dioxins & Furans (NATO I-TEQ) Emission Rate µg/hr 1.1068 1.4378 -Dioxins & Furans (WHO TEQ Humans / Mammals) ng/m³ 0.0060 0.0077 -Dioxins & Furans (WHO TEQ H / M) Emission Rate µg/hr 0.8776 1.1401 -Dioxins & Furans (WHO TEQ Fish) ng/m³ 0.0072 0.0094 -Dioxins & Furans (WHO TEQ Fish) Emission Rate µg/hr 1.0644 1.3826 -Dioxins & Furans (WHO TEQ Birds) ng/m³ 0.0178 0.0231 -Dioxins & Furans (WHO TEQ Birds) Emission Rate µg/hr 2.6160 3.3982 -Formaldehyde mg/m³ 3.57 0.35 12Formaldehyde Emission Rate kg/hr 0.73 0.07 0.8CVOCs mg/m³ 9.14 1.87 100CVOCs Emission Rate kg/hr 1.87 0.38 6.7Total Aldehydes mg/m³ 5.83 1.24 20Total Aldehydes Emission Rate kg/hr 1.09 0.23 2Sulphur dioxide mg/m³ 0.25 0.04 40Sulphur dioxide Emission Rate kg/hr 0.05 0.01 4.3Oxides of Nitrogen (as NO2) mg/m³ 33.4 5.40 200Oxides of Nitrogen (as NO2) Emission Rate kg/hr 7.18 1.16 21.3Carbon Monoxide mg/m³ 12.6 2.91 100Carbon Monoxide Emission Rate kg/hr 2.71 0.63 10.7Oxygen (dry) % v/v 17.1 2.91 - P
Oxygen (Wet) % v/v 14.3 2.44Moisture % 16.0 0.66 - P
Stack Gas Temperature oC 56.0 - -Stack Gas Velocity m/s 10.24 0.24 -Gas Volumetric Flow Rate (Actual) m³/hr 154491 7886 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 129096 6589 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 108472 5537 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 215185 10984 -
P
Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
P
P
P
P
P
P
EXECUTIVE SUMMARY
EMISSIONS SUMMARY
P
ND = None Detected,Results at or below the limit of detection are highlighted by bold italic text.The above volumetric flow rate is calculated using data from the preliminary survey. Mass emissions for non isokinetic tests are calculated using these values. For all isokinetic testing the mass emission is calculated using test specific flow data and not the above values.
P
P
P
P
P
O
O
MCERTS accredited
result
Dioxins & Furans - UPPER Limits
Dioxins & Furans - LOWER Limits
P
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Total Particulate Matter Run 1
Formaldehyde Run 1CVOCs Run 1Total Aldehydes Run 1Sulphur dioxide Run 1Combustion Gases 28 August 2018 60 minutes
60 minutes
28 August 201814:21 - 15:25
Dioxins & Furans Run 160 minutes
30 August 2018 360 minutes11:12 - 17:1723 August 2018 15:35 - 16:38
Sampling TimesSampling Date(s)Parameter
EXECUTIVE SUMMARY
Sampling DurationMONITORING TIMES
23 August 201815:35 - 16:38
28 August 201823 August 2018
60 minutes
15:35 - 16:38 60 minutes
60 minutes
23 August 2018 15:12 -Preliminary Stack Traverse15:31 - 16:3115:40 - 16:45
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Description of process First stage fibre drier
Continuous or batch Continuous
Product Details Door skin manufacturing
Part of batch to be monitored (if applicable) N/A
Normal load, throughput or continuous rating Normal
Fuel used during monitoring N/A
Abatement Scrubber
EXECUTIVE SUMMARY
Process Details
PROCESS DETAILS
Parameter
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Species SOCOTEC UK UKAS Lab MCERTS Limit of CalculatedTechnical Number Accredited Detection MUProcedure Method (LOD) +/- %
TPM AE 104 1015 Yes 0.19 mg/m³ 14.7%PCDD/PCDF AE 109 1015 Yes 0.002 ng/m³ 129.9%
Formaldehyde AE 114 1015 Yes 0.01 mg/m³ 9.9%CVOCs AE112 1015 No 0.02 mg/m³ 20.5%
Total Aldehydes Based on AE114 1015 No 0.08 mg/m³ 21.3%Sulphur dioxide AE 112 1015 Yes 0.01 mg/m³ 16.3%
NOX AE 102 1015 Yes 0.26 mg/m³ 16.2%CO AE 102 1015 Yes 0.14 mg/m³ 23.2%O2 AE 102 1015 Yes 0.01% 17.1%
H2O AE 105 1015 Yes 0.01% 4.13%Velocity AE 154 1015 Yes 5 Pa 2.36%
Volumetric Flow Rate
AE 154 1015 Yes - 5.10%
- - - - - -
SRM - EN 15058:2017
SRM - EN 14790
Monitoring Methods
AM - EN 14789:2017
SRM - EN 1948 - Part 1
MONITORING METHODS
EN 14791
SRM - EN 14792:2017
Standard Reference Method / Alternative Method
The selection of standard reference / alternative methods employed by SOCOTEC UK is determined, wherever possible by the hierarchy of methodselection outlined in Environment Protection Agency Technical Guidance Note (Monitoring) AG2.
USEPA M0011
USEPA M316
SRM - EN ISO 16911-1
Method
SRM - EN ISO 16911-1
EXECUTIVE SUMMARY
-
SRM - EN 14791
SRM - EN 13284-1
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The following tables list the analytical methods employed together with the custody and archiving details:
Species Analytical UKAS Lab Analysis Lab Sample ArchiveProcedure Number Archive Period
Location
TPM AE 106 1015 YesSOCOTEC UK (East Kilbride)
SOCOTEC UK (East Kilbride)
8 Weeks
PCDD/PCDF MSOP1 1549 Yes CLS CLS 8 Weeks
Formaldehyde M103 0605 Yes RPS RPS 8 Weeks
CVOCs Based on AE112 1015 NoSOCOTEC UK -
(Bretby)SOCOTEC UK -
(Bretby)8 Weeks
Total AldehydesASC/SOP/237
Issue 11015 No
SOCOTEC UK - (Bretby)
SOCOTEC UK - (Bretby)
8 Weeks
Sulphur dioxide ASC/SOP/110 1015 YesSOCOTEC UK -
(Bretby)SOCOTEC UK -
(Bretby)8 Weeks
Species Analytical UKAS Lab MCERTS Laboratory Data ArchiveProcedure Number Accredited Archive Period
NOX AE 102 1015 YesSOCOTEC UK (East Kilbride)
SOCOTEC UK (East Kilbride)
5 years
CO AE 102 1015 YesSOCOTEC UK (East Kilbride)
SOCOTEC UK (East Kilbride)
5 years
O2 AE 102 1015 YesSOCOTEC UK (East Kilbride)
SOCOTEC UK (East Kilbride)
5 years
H2O AE 105 1015 YesSOCOTEC UK (East Kilbride)
- -
ON-SITE TESTING
Chemiluminescence
Gravimetric
Zirconia Cell
Spectrophotometry
Gas Chromatography - High Resolution Mass Spectometry
UKAS Accredited Lab Analysis
Non Dispersive Infra Red
SAMPLING METHODS WITH SUBSEQUENT ANALYSISAnalytical Technique
Analytical Methods
Gravimetric
HPLC/Diode Array Detection
Ion Chromatography
UV-Persulphate Oxidation/IR
Analytical Technique
EXECUTIVE SUMMARY
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Sampling Plane Validation Criteria Value Units Requirement Compliant Method
Lowest Differential Pressure 49 Pa >= 5 Pa Yes EN 15259
Lowest Gas Velocity 8.3 m/s - - -
Highest Gas Velocity 11.8 m/s - - -
Ratio of Gas Velocities 1.4 : 1 < 3 : 1 Yes EN 15259
Mean Velocity 10.2 m/s - - -
Maximum angle of flow with regard to duct axis <15 o < 15o Yes EN 15259
No local negative flow Yes - - Yes EN 15259
Value Units Isokinetic
Shape Circular -
Depth 2.31 m Sample port size 4" (Non BSP) 4" (Non BSP)
Width - m Number of lines used 2 1
Area 4.19 m2 Number of points / line 10 1
Port Depth 90 mm Duct orientation Vertical VerticalFiltration - In Stack
In Stack -
General Platform Information
Permanent / Temporary Platform / Ground level / Floor Level / Roof
Inside / Outside
AG1 Platform requirements
Is there a sufficient working area so work can be performed in a compliant manner
Platform has 2 levels of handrails (approximately 0.5 m & 1.0 m high)
Platform has vertical base boards (approximately 0.25 m high)
Platform has removable chains / self closing gates at the top of ladders
Handrail / obstructions do not hamper insertion of sampling equipmentDepth of Platform = >Stack depth / diameter + wall and port thickness + 1.5m
Sampling Platform Improvement Recommendations (if applicable)
Yes
Filtration for TPM
Yes
SAMPLING LINES & POINTS
Yes
Outside
Yes
Yes
DUCT CHARACTERISTICS
EXECUTIVE SUMMARY
Permanent
Yes
The sampling location meets all the requirements as specified in EA Guidance Note M1.
SAMPLING LOCATION
SAMPLING PLATFORM
Non-Iso & Gases
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Sampling Line B
Transfer Line
USEPA M316
USEPA M0011
A transfer line between the first impinger & filter holder was employed due to handrails hampering the insertion of sampling equipment.
Sampling & Analytical Method Deviations
EXECUTIVE SUMMARY
The full number of sampling points could not be completed on sampling line B due to probe overhang (see stack diagram)
Total Aldehyde samples were filtered at the request of Masonite therefore the monitoring does not completely adhere to US EPA Method0011.
Formaldehyde samples were filtered at the request of Masonite therefore the monitoring does not completely adhere to US EPA Method316.
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APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
APPENDICES
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
CONTENTS
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Species SOCOTEC UK UKAS Lab MCERTSTechnical Number AccreditedProcedure Method
TPM AE 104 1015 Yes 1PCDD/PCDF AE 109 1015 Yes 1Formaldehyde AE 114 1015 Yes 1
CVOCs AE112 1015 No 1Total Aldehydes Based on AE114 1015 No 1Sulphur dioxide AE 112 1015 Yes 1
NOx AE 102 1015 Yes 1CO AE 102 1015 Yes 1O2 AE 102 1015 Yes 1
H2O AE 105 1015 Yes 1Velocity AE 154 1015 Yes 1
Method
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
SRM - EN 1948 - Part 1
USEPA M0011EN 14791
SRM - EN 15058:2017
Number of Samples
SRM - EN 14791
MONITORING SCHEDULE
SRM - EN 14792:2017
SRM - EN ISO 16911-1SRM - EN 14790
Standard Reference Method / Alternative Method
USEPA M316
AM - EN 14789:2017
SRM - EN 13284-1
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Equipment I.D. Equipment I.D. Equipment I.D.
LEK 9.30 LEK 21-15 LEK 15.21
LEK 9.31 - LEK 20.5
LEK 9.31 - LEK 17.1
LEK 9.31 - -
LEK 17.17 - LEK 16.8
- - -
LEK 6.51 - LEK 2.11
- - LEK 3.15
- - -
- - LEK 29.9
LEK 6.51 - -
- - -
LEK 23.21 LEK 12.10 -
- LEK 8.22 -
- - -
LEK 15.1F - -
- - -
- - LEK 8.22
LEK 24.1 - -
NOTE: If the equipment I.D is represented by a dash (-), then this piece of equipment has not been used for this test.
Cylinder I.D Number
Supplier ppm %Analytical
Tolerance +/- %
Oxygen Fresh Air BOC - 20.9 2.0
Nitric Oxide LEK BOC 200 - 2.0
Carbon Monoxide LEK 163 BOC 166 - 2.0- - - - -
Level Expiry TE1 TE2 TE3 TE4 H&S
Hugh McMahon MM 15 1347MCERTS Level
2Sep-20 Feb-22 May-22 Jul-22 Feb-22 Sep-20
Shane Thompstone
MM 16 1395MCERTS Level
1Oct-21 - - - - Oct-21
Philip Conway MM 18 1474MCERTS Trainee
Mar-23 - - - - Mar-23
Bernath 3006 FID
Tape Measure
STACK EMISSIONS MONITORING TEAM
-
MCERTS Number
TE / H&S Qualifications and Expiry DateMCERTS
Chiller (JCT/MAK 10)Site Balance
5m Heated Line (1)
Small DGM
Heated Line Controller (1)
Site temperature Logger
Inclinometer (Swirl Device)
MONITORING TEAM
Equipment
Laboratory Balance
1m Heated Line (2)
Mass Flow Controller
Thermo FID
Digital Temperature Meter
Servomex
Probe Thermocouple
FT-IR Oven Box
1m Heated Line (3)
Callipers
20m Heated Line (2)
MFC Display module
Probe
Probe Thermocouple
Stackmaster
FTIR Heater Box for Heated Line
Meter Out Thermocouple
Control Box Timer
Stack Thermocouple
1m Heated Line (1)
L-Pitot
Oven Box
Probe JCT Heated Head Filter
Protractor
Digital Micromanometer
Heated Line Controller (2)
Meter In Thermocouple Stopwatch
Extractive Sampling
Control Box DGM
CALIBRATEABLE EQUIPMENT CHECKLIST
Equipment
Anemometer
Horiba PG-250 Analyser
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
Box Thermocouples
Signal 3030 FID
Instrumental Analyser/s
Personnel
CALIBRATION GASES
S-Pitot
FT-IR Gasmet
Barometer
Equipment
Ecophysics NOx Analyser
Heater Controller
Last Impinger Arm
Gas (traceable to ISO 17025)
Miscellaneous
Dioxins Cond. Thermocouple
10m Heated Line (2)
15m Heated Line (1)
10m Heated Line (1)
20m Heated Line (1)
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Uncertainty Limit Emissionmg/m³ mg/m³ Rate g/hr
0.23 20 322
Blank - - -Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
TestFilter & Probe Rinse Number
Filter Start Weight
Filter End Weight
Mass Gained on Filter
Probe Rinse Start Weight
Probe Rinse End Weight
Mass Gained on Probe
Combined Total Mass Gained
g g g g g g gRun 1 AC 9401 0.09337 0.09582 0.00245 202.72680 202.72760 0.00080 0.00325If total mass gained is less than the LOD then the LOD is reported
TestFilter & Probe
NumberFilter Start
WeightFilter End
WeightMass Gained
FilterProbe Start
WeightProbe End
WeightMass Gained
ProbeCombined Total
Mass Gained
g g g g g g gRun 1 AC9157 0.09478 0.09480 0.00002 201.95500 201.95490 -0.00010 0.00023If total mass gained is less than the LOD then the LOD is reported
Acceptable Value
mg/m³
mg/lmg/l
Sampling Times
BLANKS
SAMPLES
2.0 10
FILTER INFORMATION
15:35 - 16:3823 August 2018
1.57
TOTAL PARTICULATE MATTER SUMMARYParameter
0.19
Concentration
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Run 1
-
Acetone Blank Value
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ISOKINETIC SAMPLING EQUATIONS - RUN 1 TPM
Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md
Barometric pressure, Pb mm Hg 765.76 CO2 % 2.02Stack static pressure, Pstatic mm H2O -8.97 O2 % 14.33Ps = Pb + (Pstatic) mm Hg 765.10 Total % 16.35
N2 (100 -Total) % 83.65Vol. of water vapour collected, Vwstd Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90
g 159.2 Molecular weight of wet gas, Ms
Vwstd = (0.001246)(Vlc) m3 0.1983632 Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 27.16Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa
Volume of gas sample through gas meter, Vm m3 1.070 Area of stack, As m2 4.19
Gas meter correction factor, Yd 1.0487 Qa = (60)(As)(Vs) m³/min 2459.6Mean dry gas meter temperature, Tm
oC 23.881 Total flow of stack gas, Q36.132 Conversion factor (K/mm.Hg) 0.3592
Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 1.043 Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 1723.5 (Ts) +273
Volume of gas metered wet, Vmstw @O2ref 2875.27Vmstw = Vmstd + Vwstd m3 1.2417 (Ts) +273
Qstw = (Qa)Ps(0.3592) Wet 2051.15 (Ts) +273
No Percent isokinetic, %INozzle diameter, Dn mm 7.03
% oxygen measured in gas stream, act%O2 14.3 Nozzle area, An mm2 38.82% oxygen reference condition 17 Total sampling time, q min 60
1.67 %I = (4.6398E6)(Ts+273)(Vmstd) % 108.9 (Ps)(Vs)(An)(q)(1-Bwo)
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 2.0697 Acceptable isokinetic range 95% to 115% YesMoisture content, Bwo Particulate Concentration, CBwo = Vwstd 0.1598 Mass collected on filter, Mf g 0.00245
% 15.98 Mass collected in probe, Mp g 0.00080Moisture by FTIR % - Total mass collected, Mn g 0.00325Velocity of stack gas, Vs Cwet = Mn mg/m³ 2.617Pitot tube velocity constant, Kp 34.97 Vmstw
Velocity pressure coefficient, Cp 0.871 Cdry = Mn mg/m³ 3.115Mean of velocity heads, DPavg mm H2O 6.50 Vmstd
Mean square root of velocity heads, ÖDP 2.55 Cwet@X%O2 = Mn mg/m³ 1.570Mean stack gas temperature, Ts
oC 57Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 9.78 Particulate Emission Rates, E (Ms)(Ps) E = [(Cwet)(Qstw)(60)] / 1000 322.12
O2 Ref = 21.0 - act%O2
21.0 - ref%O2
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Moisture trap weight increase,Vlc
Tm + 273
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
Vmstd + Vwstd
Mean pressure drop across orifice, DH mmH2O
13.6
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
O2 Reference Factor
Vmstd@X%oxygen
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litre/min litre/min litre/min mm Hg litre/minRun 1 18.70 0.20 0.20 -381 0.37 Yes
% mg/m³ mg/m³Run 1 108.94 Yes Run 1 0.19 1.0 Yes
Acceptable isokinetic range 95% to 115% The above is based on both the Filter and rinse uncertainty
mg/m3 mg/m3 mg/m3 mg/m3
mm °CRun 1 Glass Fibre 47 59
0.19 Yes
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
5% ELV
LEAK RATE
2.0
Acceptable Isokineticity
FILTERS
°C
Leak Tests Acceptable?
Run
Filter SizeFilter Material
WEIGHING BALANCE UNCERTAINTYISOKINETICITY
Pre-sampling Leak Rate
Maximum Vacuum
Run
Pre-use Filter Conditioning Temperature
Max Filtration Temperature
°C
Blank 1
Mean Sampling Rate
160
Daily Emission Limit Value
Overall Blank Acceptable
Isokinetic Variation
LOD < 5% ELVRun
BLANK VALUE
TOTAL PARTICULATE MATTER QUALITY ASSURANCE CHECKLIST
20
Acceptable Leak Rate
Overall Blank Value
Post-use Filter Conditioning Temperature
Result
Post-sampling Leak RateRun
Run
180
Acceptable Blank Value
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LOD Limit Emissionng/m³ ng/m³ Rate µg/hr
Run 1 0.00242 - 1.24
Field Blanks Run 1 0.00082 - -
LOD Limit Emissionng/m³ ng/m³ Rate µg/hr
Run 1 0.00286 - 1.12
Field Blanks Run 1 0.00082 - -
LOD Limit Emissionng/m³ ng/m³ Rate µg/hr
Run 1 0.00320 - 1.31
Field Blanks Run 1 0.00090 - -
LOD Limit Emissionng/m³ ng/m³ Rate µg/hr
Run 1 0.00404 - 2.86
Field Blanks Run 1 0.00128 - -Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
Sampling Times
0.00090
ConcentrationTest
Test
Concentration
WHO TEQ (Humans / Mammals)
-
11:12 - 17:17 30 August 2018
ng/m³
Sampling Times ConcentrationWHO TEQ (Fish)
11:12 - 17:17 30 August 2018
Test
ng/m³
0.01943
0.00128
-
Concentration
0.00082
0.00761
Test
-
0.00082
-
NATO I-TEQ
DIOXINS & FURANS SUMMARY - UPPER LIMIT
ng/m³Sampling Times
0.00888
0.00842
11:12 - 17:17 30 August 2018
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Times
WHO TEQ (Birds)
ng/m³
11:12 - 17:17 30 August 2018
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LOD Limit Emissionng/m³ ng/m³ Rate µg/hr
Run 1 - - 1.11
Field Blanks Run 1 - - -
LOD Limit Emissionng/m³ ng/m³ Rate µg/hr
Run 1 - - 0.88
Field Blanks Run 1 - - -
LOD Limit Emissionng/m³ ng/m³ Rate µg/hr
Run 1 - - 1.06
Field Blanks Run 1 - - -
LOD Limit Emissionng/m³ ng/m³ Rate µg/hr
Run 1 - - 2.62
Field Blanks Run 1 - - -Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
-
WHO TEQ (Fish)
0.00000
ConcentrationTest
ng/m³11:12 - 17:17
30 August 2018
-
0.00752
DIOXINS & FURANS SUMMARY - LOWER LIMIT
11:12 - 17:17 30 August 2018
0.01778
Sampling Times Test
Concentration
ConcentrationWHO TEQ (Birds)
0.00723
Test
Concentration
0.00000
ng/m³
-
0.0059611:12 - 17:17
30 August 2018
Test
ng/m³
0.00000
0.00000
Sampling Times
-
WHO TEQ (Humans / Mammals)
NATO I-TEQ
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Times
Sampling Times
11:12 - 17:17 30 August 2018
ng/m³
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Congener Result NATO WHOI-TEQ TEQ Actual Permitted
ng ng ng % %Dioxins2378 Tetra CDD 0.006 0.006 0.006 77 50 - 13012378 Penta CDD < 0.015 0.0075 0.015 49 50 - 130123478 Hexa CDD 0.0094 0.00094 0.00094 114 50 - 130123678 Hexa CDD 0.011 0.0011 0.0011 95 50 - 130123789 Hexa CDD 0.01 0.001 0.0011234678 Hepta CDD 0.06 0.0006 0.0006 63 50 - 130OCDD Octa CDD 0.082 0.000082 0.0000246 106 20 - 150Total -Dioxins 0.1934 0.01722 0.02466Furans2378 Tetra CDF 0.081 0.0081 0.0081 94 50 - 13012378 Penta CDF 0.064 0.0032 0.00192 98 >=5023478 Penta CDF 0.071 0.0355 0.0213 38 50 - 130123478 Hexa CDF 0.048 0.0048 0.0048 100 50 - 130123678 Hexa CDF 0.057 0.0057 0.0057 71 50 - 130234678 Hexa CDF 0.063 0.0063 0.0063 87 50 - 130123789 Hexa CDF < 0.015 0.0015 0.0015 80 >=501234678 Hepta CDF 0.17 0.0017 0.0017 54 20 - 1501234789 Hepta CDF 0.025 0.00025 0.00025 67 >=50OCDF Octa CDF 0.1 0.0001 0.00003 71 20 - 150Total -Furans 0.694 0.06715 0.05160Mean Recoveries (%) 79Total Isomers 0.8874 0.08437 0.07626Total ITEQ (<LOD = 0) 0.07537 0.05976
NOTE: The Total Isomers result includes all isomers below the limit of detection. This gives a "worst case" Dioxins & Furans result.
NATO I-TEQ & WHO TEQ (Humans / Mammals)Extraction Recovery
DIOXINS & FURANS ANALYSIS SUMMARY - RUN 1
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Humans / Mammals
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Congener Result WHO WHOTEQ TEQ Actual PermittedFish Birds
ng ng ng % %Dioxins2378 Tetra CDD 0.006 0.006 0.006 77 50 - 13012378 Penta CDD < 0.015 0.015 0.015 49 50 - 130123478 Hexa CDD 0.0094 0.0047 0.00047 114 50 - 130123678 Hexa CDD 0.011 0.00011 0.00011 95 50 - 130123789 Hexa CDD 0.01 0.0001 0.00011234678 Hepta CDD 0.06 0.00006 0.00006 63 50 - 130OCDD Octa CDD 0.082 - - 106 20 - 150Total -Dioxins 0.1934 0.02597 0.02174Furans2378 Tetra CDF 0.081 0.00405 0.081 94 50 - 13012378 Penta CDF 0.064 0.0032 0.00064 98 >=5023478 Penta CDF 0.071 0.0355 0.071 38 50 - 130123478 Hexa CDF 0.048 0.0048 0.0048 100 50 - 130123678 Hexa CDF 0.057 0.0057 0.0057 71 50 - 130234678 Hexa CDF 0.063 0.0063 0.0063 87 50 - 130123789 Hexa CDF < 0.015 0.0015 0.0015 80 >=501234678 Hepta CDF 0.17 0.0017 0.0017 54 20 - 1501234789 Hepta CDF 0.025 0.00025 0.00025 67 >=50OCDF Octa CDF 0.1 0.00001 0.00001 71 20 - 150Total -Furans 0.694 0.06301 0.17290Mean Recoveries (%) 79Total Isomers 0.8874 0.08898 0.19464Total ITEQ (<LOD = 0) 0.07248 0.17814
NOTE: The Total Isomers result includes all isomers below the limit of detection. This gives a "worst case" Dioxins & Furans result.
WHO TEQ (Fish) & WHO TEQ (Birds)
DIOXINS & FURANS ANALYSIS SUMMARY - RUN 1
Extraction Recovery
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
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Congener Result NATO WHOI-TEQ TEQ Actual Permitted
ng ng ng % %Dioxins2378 Tetra CDD < 0.002 0.002 0.002 71 50 - 13012378 Penta CDD < 0.002 0.001 0.002 69 50 - 130123478 Hexa CDD < 0.002 0.0002 0.0002 80 50 - 130123678 Hexa CDD < 0.002 0.0002 0.0002 72 50 - 130123789 Hexa CDD < 0.002 0.0002 0.00021234678 Hepta CDD < 0.0075 0.000075 0.000075 78 50 - 130OCDD Octa CDD < 0.02 0.00002 0.000006 75 20 - 150Total -Dioxins 0.0375 0.00370 0.00468Furans2378 Tetra CDF < 0.0035 0.00035 0.00035 69 50 - 13012378 Penta CDF < 0.0025 0.000125 0.000075 101 >=5023478 Penta CDF < 0.003 0.0015 0.0009 68 50 - 130123478 Hexa CDF < 0.005 0.0005 0.0005 80 50 - 130123678 Hexa CDF < 0.004 0.0004 0.0004 79 50 - 130234678 Hexa CDF < 0.004 0.0004 0.0004 72 50 - 130123789 Hexa CDF < 0.0025 0.00025 0.00025 94 >=501234678 Hepta CDF < 0.05 0.0005 0.0005 78 20 - 1501234789 Hepta CDF < 0.007 0.00007 0.00007 96 >=50OCDF Octa CDF < 0.45 0.00045 0.000135 77 20 - 150Total -Furans 0.5315 0.004545 0.00358Mean Recoveries (%) 79Total Isomers 0.569 0.00824 0.00826Total ITEQ (<LOD = 0) 0.00000 0.00000
NOTE: The Total Isomers result includes all isomers below the limit of detection. This gives a "worst case" Dioxins & Furans result.
DIOXINS & FURANS ANALYSIS SUMMARY - FIELD BLANK RUN 1
Extraction Recovery
Humans / Mammals
NATO I-TEQ & WHO TEQ (Humans / Mammals)
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
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Congener Result WHO WHOTEQ TEQ Actual PermittedFish Birds
ng ng ng % %Dioxins2378 Tetra CDD < 0.002 0.002 0.002 71 50 - 13012378 Penta CDD < 0.002 0.002 0.002 69 50 - 130123478 Hexa CDD < 0.002 0.001 0.0001 80 50 - 130123678 Hexa CDD < 0.002 0.00002 0.00002 72 50 - 130123789 Hexa CDD < 0.002 0.00002 0.000021234678 Hepta CDD < 0.0075 0.0000075 0.0000075 78 50 - 130OCDD Octa CDD < 0.02 - - 75 20 - 150Total -Dioxins 0.0375 0.00505 0.00415Furans2378 Tetra CDF < 0.0035 0.000175 0.0035 69 50 - 13012378 Penta CDF < 0.0025 0.000125 0.000025 101 >=5023478 Penta CDF < 0.003 0.0015 0.003 68 50 - 130123478 Hexa CDF < 0.005 0.0005 0.0005 80 50 - 130123678 Hexa CDF < 0.004 0.0004 0.0004 79 50 - 130234678 Hexa CDF < 0.004 0.0004 0.0004 72 50 - 130123789 Hexa CDF < 0.0025 0.00025 0.00025 94 >=501234678 Hepta CDF < 0.05 0.0005 0.0005 78 20 - 1501234789 Hepta CDF < 0.007 0.00007 0.00007 96 >=50OCDF Octa CDF < 0.45 0.000045 0.000045 77 20 - 150Total -Furans 0.5315 0.00397 0.00869Mean Recoveries (%) 79Total Isomers 0.569 0.00901 0.01284Total ITEQ (<LOD = 0) 0.00000 0.00000
NOTE: The Total Isomers result includes all isomers below the limit of detection. This gives a "worst case" Dioxins & Furans result.
DIOXINS & FURANS ANALYSIS SUMMARY - FIELD BLANK RUN 1
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Extraction RecoveryWHO TEQ (Fish) & WHO TEQ (Birds)
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ISOKINETIC SAMPLING EQUATIONS - RUN 1 Dioxins & Furans
Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md
Barometric pressure, Pb mm Hg 752.26 CO2 % 2.02Stack static pressure, Pstatic mm H2O -8.97 O2 % 14.33Ps = Pb + (Pstatic) mm Hg Total % 16.35
751.60 N2 (100 -Total) % 83.65Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90
Vol. of water vapour collected, Vwstd Molecular weight of wet gas, Ms
g - Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 27.16Vwstd = (0.001246)(Vlc) m3 - Velocity of stack gas, Vs
Volume of gas metered dry, Vmstd Pitot tube velocity constant, Kp 34.97Velocity pressure coefficient, Cp 0.87
Volume of gas sample through gas meter, Vm m3 5.38 Mean of velocity heads, DPavg mm H2O 4.85
Gas meter correction factor, Yd 1.05 Mean square root of velocity heads, ÖDP 2.20Mean dry gas meter temperature, Tm
oC 29.87 Mean stack gas temperature, TsoC 58
Mean pressure drop across orifice, DH mmH2O 28.78 Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 8.54 (Ms)(Ps)
Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 5.05 Actual flow of stack gas, Qa
Area of stack, As m2 4.19Volume of gas metered wet, Vmstw Qa = (60)(As)(Vs) m³/min 2148.7
Total flow of stack gas, QVmstw = Vmstd + Vwstd m3 6.0111 Conversion factor (K/mm.Hg)
Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 1471.2 (Ts) +273
No @O2ref 2452 (Ts) +273
% oxygen measured in gas stream, act%O2 14.33 Qstw = (Qa)Ps(0.3592) Wet 1751% oxygen reference condition 17 (Ts) +273
O2 Ref = 21.0 - act%O2 1.67 Percent isokinetic, %I 21.0 - ref%O2 Nozzle diameter, Dn mm 7.0
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 10.02 Nozzle area, An mm2 38.8Moisture content, Bwo Total sampling time, q min 360.0
%I = (4.6398E6)(Ts+273)(Vmstd) % 103.0Bwo = Vwstd 0.1598 (Ps)(Vs)(An)(q)(1-Bwo)
% 15.98Moisture by FTIR % - Acceptable isokinetic range 95% to 115% Yes
O2 Reference Factor
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
Vmstd + Vwstd
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
Moisture trap weight increase,Vlc
Tm + 273
13.6
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litre/min litre/min litre/min mm Hg litre/min litre/min
15.68 0.25 0.25 -381 0.78 Yes
Isokinetic Criterion Compliance
mm °C
Quartz Fibre 47 123
Critical Sampling Requirement
Run 1 Yes Yes
- -
.
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Isokinetic Variation
Run 1
Acceptable Leak Rate
Leak Test Results Maximum Vacuum
23
Post-sampling Leak Rate
DIOXINS & FURANS QUALITY ASSURANCE CHECKLIST
Mean Sampling Rate
Pre-sampling Leak Rate
Leak Tests Acceptable
Run 1 103.0
Maximum Filtration
Temperature
Filter Size
Run 1
Yes
Filtration
Acceptable isokinetic range 95% to 115%
Maximum Temperature at Condenser / Adsorber
Acceptable Temperature?
< 20°C < 25°CAcceptance Criteria
Filter Material
Acceptable Temperature?
Maximum Temperature during storage / transit
°C°C
10
%Acceptable Isokineticity
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LOD Limit Emissionmg/m³ mg/m³ Rate g/hr
0.01 12 732.64
Field Blank - - -
Please note figures in bold italic font are at the limit of detectionReference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
Leak Test Results
l/min l/min l/min l/min
Run 1 18.7 0.02 0.10 0.37 Yes
Filter Material Filter Sizemm
°C °C
Run 1 Glass Fibre 47 161 20 Glass
Parameter Total IMP C Absorptionug ug Efficiency %
7392 - Not Determined Not DeterminedRun 1
-
FORMALDEHYDE SUMMARY
Acceptable leak rate
Run 115:35 - 16:38
23 August 20183.57
0.01
Max. Storage / Transit Temp.
ND - None Detected
Post sampling leak rate
Sampling Times
Acceptable ?
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Mean Sampling Rate
mg/m³
FORMALDEHYDE QUALITY ASSURANCE CHECKLIST
Concentration
Acceptable Absorption
Pre sampling leak rate
Leak Tests Acceptable?
Absorption EfficiencyEfficiency %
Not Determined
Absorption SolutionsType of Absorbers
FORMALDEHYDE ABSORPTION EFFICIENCY
Max. Filtration Temp.
HPLC Water
Test
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ISOKINETIC SAMPLING EQUATIONS 1 Formaldehyde
Absolute pressure of stack gas, Ps Velocity of stack gas, Vs
Barometric pressure, Pb mm Hg 766 Pitot tube velocity constant, Kp 34.97Stack static pressure, Pstatic mm H2O -9 Velocity pressure coefficient, Cp 0.871Ps = Pb + (Pstatic) mm Hg 765 Mean of velocity heads, DPavg mm H2O 6.50
Mean square root of velocity heads, ÖDP 2.55Vol. of water vapour collected, Vwstd Mean stack gas temperature, Ts
oC 57g -
Vwstd = (0.001246)(Vlc) m3 - Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 9.8 (Ms)(Ps)
Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa
Volume of gas sample through gas meter, Vm m3 1.0701 Area of stack, As m2 4.19
Gas meter correction factor, Yd 1.0487 Qa = (60)(As)(Vs) m³/min 2460Mean dry gas meter temperature, Tm
oC 23.88 Dry total flow of stack gas, Qstd
Mean pressure drop across orifice, DH mmH2O 36.13 Conversion factor (K/mm.Hg) 0.3592Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 1.04 Qstd = (Qa)Ps(0.3592)(1-Bwo) m³/min 1723
(Ts) +273Volume of gas metered wet, Vmstw Wet total flow of stack gas, Qstw
Vmstw = Vmstd + Vwstd m3 1.2417 Qstw = (Qa)Ps(0.3592) m³/min 2051 (Ts) +273
Nom³/min 2873
% oxygen measured in gas stream, act%O2 14.33 (Ts) +273% oxygen reference condition 17 Percent isokinetic, %I
O2 Ref = 21.0 - act%O2 1.67 Nozzle diameter, Dn mm 7.03 21.0 - ref%O2 Nozzle area, An mm2 38.82
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 2.0697 Total sampling time, q min 60Moisture content, Bwo %I = (4.6398E6)(Ts+273)(Vmstd) % 109Bwo = Vwstd 0.1598 (Ps)(Vs)(An)(q)(1-Bwo)
% 15.98 Acceptable isokinetic range 95% to 115% YesMoisture by FTIR % -Molecular weight of dry gas, Md Mass collected , M ug 7392CO2 2.02 Cwet = Mn mg/m³ 5.953O2 14.33 Vmstw
Total 16.35 Cdry = Mn mg/m³ 7.085N2 (100 -Total) 83.65 Vmstd
Cwet@X%O2 = Mn mg/m³ 3.571Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90Molecular weight of wet gas, Ms Formaldehyde Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 27.2 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 732.64
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
Vmstd + Vwstd
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
Vmstd@X%oxygen
Dry total flow of stack gas at X% O2, QstdO2
Tm + 273
Formaldehyde Concentration, C
Moisture trap weight increase,Vlc
O2 Reference Factor
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
13.6
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LOD Limit Emissionmg/m³ mg/m³ Rate g/hr
0.02 100 1875
Field Blank - - -
Please note figures in bold italic font are at the limit of detectionReference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
Leak Test Results
l/min l/min l/min l/min
Run 1 18.7 0.20 0.20 0.37 Yes
Filter Material Filter Sizemm
°C °C
Run 1 Glass Fibre 47 161 20 Glass
Parameter Total IMP C Absorptionug ug Efficiency %
18920 - Not Determined
CVOCS SUMMARY
Not Determined
Absorption Efficiency
-
Acceptable Absorption
HPLC Water
Concentrationmg/m³
Test
15:35 - 16:38 23 August 2018
Pre sampling leak rate
ND - None Detected
0.03
Post sampling leak rate
Max. Storage / Transit Temp.
Mean Sampling Rate
CVOCS QUALITY ASSURANCE CHECKLIST
Acceptable ?
9.14
CVOCS ABSORPTION EFFICIENCY
Acceptable leak rate
Sampling Times
Leak Tests Acceptable?
Max. Filtration Temp.
Run 1
Absorption Solutions
Efficiency %
Type of Absorbers
Run 1 Not Determined
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
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ISOKINETIC SAMPLING EQUATIONS 1 CVOCs
Absolute pressure of stack gas, Ps Velocity of stack gas, Vs
Barometric pressure, Pb mm Hg 766 Pitot tube velocity constant, Kp 34.97Stack static pressure, Pstatic mm H2O -9 Velocity pressure coefficient, Cp 0.871Ps = Pb + (Pstatic) mm Hg 765 Mean of velocity heads, DPavg mm H2O 6.50
Mean square root of velocity heads, ÖDP 2.55Vol. of water vapour collected, Vwstd Mean stack gas temperature, Ts
oC 57g -
Vwstd = (0.001246)(Vlc) m3 - Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 9.8 (Ms)(Ps)
Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa
Volume of gas sample through gas meter, Vm m3 1.0701 Area of stack, As m2 4.19
Gas meter correction factor, Yd 1.0487 Qa = (60)(As)(Vs) m³/min 2460Mean dry gas meter temperature, Tm
oC 23.85 Dry total flow of stack gas, Qstd
Mean pressure drop across orifice, DH mmH2O 38.02 Conversion factor (K/mm.Hg) 0.3592Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 1.04 Qstd = (Qa)Ps(0.3592)(1-Bwo) m³/min 1723
(Ts) +273Volume of gas metered wet, Vmstw Wet total flow of stack gas, Qstw
Vmstw = Vmstd + Vwstd m3 1.2421 Qstw = (Qa)Ps(0.3592) m³/min 2051 (Ts) +273
Nom³/min 2873
% oxygen measured in gas stream, act%O2 14.33 (Ts) +273% oxygen reference condition 17 Percent isokinetic, %I
O2 Ref = 21.0 - act%O2 1.67 Nozzle diameter, Dn mm 7.03 21.0 - ref%O2 Nozzle area, An mm2 38.82
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 2.0703 Total sampling time, q min 60Moisture content, Bwo %I = (4.6398E6)(Ts+273)(Vmstd) % 109Bwo = Vwstd 0.1598 (Ps)(Vs)(An)(q)(1-Bwo)
% 15.98 Acceptable isokinetic range 95% to 115% YesMoisture by FTIR % -Molecular weight of dry gas, Md Mass collected , M ug 18920CO2 2.02 Cwet = Mn mg/m³ 15.233O2 14.33 Vmstw
Total 16.35 Cdry = Mn mg/m³ 18.129N2 (100 -Total) 83.65 Vmstd
Cwet@X%O2 = Mn mg/m³ 9.139Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90Molecular weight of wet gas, Ms CVOCs Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 27.2 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 1874.68
Tm + 273
Vmstd + Vwstd
CVOCs Concentration, C
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
Vmstd@X%oxygen
O2 Reference Factor
Dry total flow of stack gas at X% O2, QstdO2
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
Moisture trap weight increase,Vlc
13.6
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LOD Limit Emissionmg/m³ mg/m³ Rate g/hr
0.08 20 1086
Field Blank - - -
Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
Leak Test Results
l/min l/min l/min l/min
Run 1 18.1 0.10 0.05 0.36 Yes
Filter Material Filter Sizemm
°C °C
Run 1 Glass Fibre 47 162 20 Glass
Parameter Total IMP C Absorptionug ug Efficiency %
11518 - Not Determined
Mean Sampling Rate
0.26
Test
14:21 - 15:25 28 August 2018
Absorption Efficiency
DNPH Solution
Run 1
Acceptable leak rate
Type of Absorbers
Acceptable Absorption
TOTAL ALDEHYDES SUMMARY
5.83
-
TOTAL ALDEHYDES ABSORPTION EFFICIENCY
Absorption SolutionsMax. Storage / Transit Temp.
Concentrationmg/m³
TOTAL ALDEHYDES QUALITY ASSURANCE CHECKLIST
Post sampling leak rate
Pre sampling leak rate
Run 1 Not Determined
Max. Filtration Temp.
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Acceptable ?
Not Determined
Efficiency %
Leak Tests Acceptable?
Sampling Times
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ISOKINETIC SAMPLING EQUATIONS 1 Total Aldehydes
Absolute pressure of stack gas, Ps Velocity of stack gas, Vs
Barometric pressure, Pb mm Hg 766 Pitot tube velocity constant, Kp 34.97Stack static pressure, Pstatic mm H2O -9 Velocity pressure coefficient, Cp 0.871Ps = Pb + (Pstatic) mm Hg 765 Mean of velocity heads, DPavg mm H2O 5.40
Mean square root of velocity heads, ÖDP 2.32Vol. of water vapour collected, Vwstd Mean stack gas temperature, Ts
oC 59g -
Vwstd = (0.001246)(Vlc) m3 - Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 9.0 (Ms)(Ps)
Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa
Volume of gas sample through gas meter, Vm m3 1.0340 Area of stack, As m2 4.19
Gas meter correction factor, Yd 1.0487 Qa = (60)(As)(Vs) m³/min 2252Mean dry gas meter temperature, Tm
oC 27.48 Dry total flow of stack gas, Qstd
Mean pressure drop across orifice, DH mmH2O 31.70 Conversion factor (K/mm.Hg) 0.3592Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 1.00 Qstd = (Qa)Ps(0.3592)(1-Bwo) m³/min 1564
(Ts) +273Volume of gas metered wet, Vmstw Wet total flow of stack gas, Qstw
Vmstw = Vmstd + Vwstd m3 1.1850 Qstw = (Qa)Ps(0.3592) m³/min 1862 (Ts) +273
Nom³/min 2607
% oxygen measured in gas stream, act%O2 14.33 (Ts) +273% oxygen reference condition 17 Percent isokinetic, %I
O2 Ref = 21.0 - act%O2 1.67 Nozzle diameter, Dn mm 7.03 21.0 - ref%O2 Nozzle area, An mm2 38.82
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 1.9752 Total sampling time, q min 60Moisture content, Bwo %I = (4.6398E6)(Ts+273)(Vmstd) % 115Bwo = Vwstd 0.1598 (Ps)(Vs)(An)(q)(1-Bwo)
% 15.98 Acceptable isokinetic range 95% to 115% YesMoisture by FTIR % -Molecular weight of dry gas, Md Mass collected , M ug 11518CO2 2.02 Cwet = Mn mg/m³ 9.720O2 14.33 Vmstw
Total 16.35 Cdry = Mn mg/m³ 11.568N2 (100 -Total) 83.65 Vmstd
Cwet@X%O2 = Mn mg/m³ 5.831Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90Molecular weight of wet gas, Ms Total Aldehydes Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 27.2 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 1085.66
O2 Reference Factor
13.6
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
Vmstd + Vwstd
Vmstd@X%oxygen
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
Total Aldehydes Concentration, C
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Tm + 273
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
Moisture trap weight increase,Vlc
Dry total flow of stack gas at X% O2, QstdO2
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LOD Limit Emissionmg/m³ mg/m³ Rate g/hr
0.01 40.0 46.7
Field Blank - - -
Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
Leak Test Results
l/min l/min l/min l/min
Run 1 17.8 0.10 0.20 0.36 Yes
Filter Material Filter Sizemm
°C °C
Run 1 Quartz Fibre 47 162 20 Glass
Parameter Total IMP C Absorptionug ug Efficiency %
470.7 10.2 98 Yes
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Absorption Efficiency
SULPHUR DIOXIDE ABSORPTION EFFICIENCY
Absorption Solutions
SULPHUR DIOXIDE QUALITY ASSURANCE CHECKLIST
Acceptable Absorption
SULPHUR DIOXIDE SUMMARY
mg/m³Concentration
0.07
0.25
Post sampling leak rate
Type of Absorbers
Max. Storage / Transit Temp.
Run 1
Efficiency %
Pre sampling leak rate
15:40 - 16:4528 August 2018
Test
-
Acceptable ?
Leak Tests Acceptable?
95
Max. Filtration Temp.
Sampling Times
0.3% Hydrogen Peroxide
Run 1
Acceptable leak rate
Mean Sampling Rate
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ISOKINETIC SAMPLING EQUATIONS 1 Sulphur dioxide
Absolute pressure of stack gas, Ps Velocity of stack gas, Vs
Barometric pressure, Pb mm Hg 766 Pitot tube velocity constant, Kp 34.97Stack static pressure, Pstatic mm H2O -9 Velocity pressure coefficient, Cp 0.871Ps = Pb + (Pstatic) mm Hg 765 Mean of velocity heads, DPavg mm H2O 5.50
Mean square root of velocity heads, ÖDP 2.35Vol. of water vapour collected, Vwstd Mean stack gas temperature, Ts
oC 60g -
Vwstd = (0.001246)(Vlc) m3 - Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 9.1 (Ms)(Ps)
Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa
Volume of gas sample through gas meter, Vm m3 0.9979 Area of stack, As m2 4.19
Gas meter correction factor, Yd 1.0487 Qa = (60)(As)(Vs) m³/min 2280Mean dry gas meter temperature, Tm
oC 28.98 Dry total flow of stack gas, Qstd
Mean pressure drop across orifice, DH mmH2O 32.41 Conversion factor (K/mm.Hg) 0.3592Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 0.96 Qstd = (Qa)Ps(0.3592)(1-Bwo) m³/min 1582
(Ts) +273Volume of gas metered wet, Vmstw Wet total flow of stack gas, Qstw
Vmstw = Vmstd + Vwstd m3 1.1380 Qstw = (Qa)Ps(0.3592) m³/min 1883 (Ts) +273
Nom³/min 2638
% oxygen measured in gas stream, act%O2 14.33 (Ts) +273% oxygen reference condition 17 Percent isokinetic, %I
O2 Ref = 21.0 - act%O2 1.67 Nozzle diameter, Dn mm 7.03 21.0 - ref%O2 Nozzle area, An mm2 38.82
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 1.8969 Total sampling time, q min 60Moisture content, Bwo %I = (4.6398E6)(Ts+273)(Vmstd) % 109Bwo = Vwstd 0.1598 (Ps)(Vs)(An)(q)(1-Bwo)
% 15.98 Acceptable isokinetic range 95% to 115% YesMoisture by FTIR % -Molecular weight of dry gas, Md Mass collected , M ug 471CO2 2.02 Cwet = Mn mg/m³ 0.414O2 14.33 Vmstw
Total 16.35 Cdry = Mn mg/m³ 0.492N2 (100 -Total) 83.65 Vmstd
Cwet@X%O2 = Mn mg/m³ 0.248Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90Molecular weight of wet gas, Ms Sulphur dioxide Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 27.2 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 46.74
Vmstd@X%oxygen
Tm + 273
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Dry total flow of stack gas at X% O2, QstdO2
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
Vmstd + Vwstd
Moisture trap weight increase,Vlc
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
Sulphur dioxide Concentration, C
O2 Reference Factor
13.6
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LOD Limit Emissionmg/m³ mg/m³ Rate g/hr
0.26 200 7179
0.14 100 2706
LOD%
0.01
Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.
Date Chiller Temperature (°C) 2.5
Start Time Requirement < 4°C
End Time Compliant Yes
Gas Range Zero Reading Span Reading Zero Check Zero Check Span Check Response Leak Rate(ppm / %) at analyser at analyser at analyser down line down line Time (Secs) %
NO 250 0.20 197.0 0.00 0.20 199.8 51 -1.42
CO 200 -1.00 161.0 -2.00 0.00 166.0 40 -3.11
O2 25 0.12 20.93 0.10 0.00 20.95 25 -0.10
Date Chiller Temperature (°C) 2.5
Start Time Requirement < 4°C
End Time Compliant Yes
Gas Zero Check Span Check Zero Drift Span Driftdown line down line (%) (%)
NO 1.00 197.0 0.32 -1.44
CO 1.00 170.0 0.50 1.50
O2 0.00 20.91 0.00 -0.16
O2
POST-SAMPLING CALIBRATION DATA
28 August 2018
Test
COMBUSTION GASES SUMMARY
16:51
14:23
Concentration
14.3
28 August 2018
NOx 33.4
CO
Sampling Time and Date Concentrationmg/m³
15:31 - 16:31 28 August 2018
12.6
Sampling Time and Date
15:31 - 16:31 28 August 2018
14:16
%Test
PRE-SAMPLING CALIBRATION DATA
16:39
15:31 - 16:31 28 August 2018
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
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CARBON MONOXIDE EMISSIONS CHART
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
OXIDES OF NITROGEN (as NO2) EMISSIONS CHART
0.0
50.0
100.0
150.0
200.0
250.0
15:31
15:33
15:35
15:37
15:39
15:41
15:43
15:45
15:47
15:49
15:51
15:53
15:55
15:57
15:59
16:01
16:03
16:05
16:07
16:09
16:11
16:13
16:15
16:17
16:19
16:21
16:23
16:25
16:27
16:29
16:31
Co
nce
ntr
atio
n m
g/m
³
Time
Oxides of Nitrogen NOx
Limit
0.0
20.0
40.0
60.0
80.0
100.0
120.0
15:31
15:33
15:35
15:37
15:39
15:41
15:43
15:45
15:47
15:49
15:51
15:53
15:55
15:57
15:59
16:01
16:03
16:05
16:07
16:09
16:11
16:13
16:15
16:17
16:19
16:21
16:23
16:25
16:27
16:29
16:31
Co
nce
ntr
atio
n m
g/m
³
Time
Carbon Monoxide CO
Limit
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OXYGEN EMISSIONS CHART
0.0
5.0
10.0
15.0
20.0
25.0
15:31
15:33
15:35
15:37
15:39
15:41
15:43
15:45
15:47
15:49
15:51
15:53
15:55
15:57
15:59
16:01
16:03
16:05
16:07
16:09
16:11
16:13
16:15
16:17
16:19
16:21
16:23
16:25
16:27
16:29
16:31
Co
nce
ntr
atio
n %
v/v
Time
O2
O2
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Test Number Start Weight End Weight Total gain Concentration LOD Uncertainty
kg kg kg % % %
Run 1 2.6353 2.7945 0.1592 16.0 0.01 4.13
Test NumberSampling Duration
Total Volume Sampled
Sampling Rate Start Leak Rate End Leak RateAcceptable Leak Rate
mins l l/min l/min l/min l/min
Run 1 60 1242 18.7 0.20 0.200 0.374 Yes
Stack Diameter / Depth, D 2.31 m
Stack Width, W - m
Stack Area, A 4.19 m2
Average stack gas temperature 56 oC
Stack static pressure -0.088 kPa
Barometric Pressure 102.1 kPa
Component Molar Density Conc Dry Volume Dry Conc Conc Wet Volume Wet ConcMass kg/m3 Dry Fraction kg/m3 Wet Fraction kg/m3
M p % Vol r pi % Vol r pi
CO2 44 1.963059 2.018361 0.020184 0.039622 1.695925 0.016959 0.033292
O2 32 1.427679 17.057500 0.170575 0.243526 14.332545 0.143325 0.204623
N2 28 1.249219 80.924139 0.809241 1.010920 67.996418 0.679964 0.849424
H2O 18 0.803070 - - - 15.975112 0.159751 0.128291
Where: p = M / 22.41 pi = r x p
Determinand
Dry Density (STP), P STD
Wet Density (STP), P STW
Dry Density (Actual), P Actual
Average Wet Density (Actual), P ActualW
Where:
P STD = sum of component concentrations, kg/m3 (not including water vapour) P Actual = P STD x (Ts / Ps) x (Pa / Ta)
P STW = (P STD + pi of H2O) / (1 + (pi of H2O / 0.8036)) P ActualW = P STW x (Ts / Ps) x (Pa / Ta)
PRELIMINARY STACK SURVEY
Leak Tests Acceptable?
1.016
kg/m3
Units
Sampling Time and Date
MOISTURE CALCULATIONS
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
1.2156
kg/m31.2941
kg/m3
Stack Gas Composition & Molecular Weights
Moisture Determination - Isokinetic
Moisture Quality Assurance
1.0813
Stack Characteristics
15:35 - 16:3823 August 2018
Result
kg/m3
Calculation of Stack Gas Densities
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TRAVERSE 1
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into mmH2O Pa oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
1 0.06 6.0 59 56 9.1 38.2 - <152 0.19 6.0 59 56 9.1 38.2 - <153 0.34 7.0 69 56 9.8 41.2 - <154 0.52 7.0 69 56 9.8 41.2 - <155 0.79 9.0 88 56 11.2 46.7 - <156 1.52 9.0 88 56 11.2 46.7 - <157 1.79 8.0 78 56 10.5 44.1 - <158 1.97 8.0 78 56 10.5 44.1 - <159 2.12 9.0 88 56 11.2 46.7 - <15
10 2.25 7.0 69 56 9.8 41.2 - <15Mean - 7.6 74 56 10.2 42.8 - -
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into mmH2O Pa oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
1 0.06 5.0 49 56 8.3 34.8 - <152 0.19 6.0 59 56 9.1 38.2 - <153 0.34 6.0 59 56 9.1 38.2 - <154 0.52 7.0 69 56 9.8 41.2 - <155 0.79 8.0 78 56 10.5 44.1 - <156 1.52 9.0 88 56 11.2 46.7 - <157 1.79 10.0 98 56 11.8 49.3 - <158 1.97 9.0 88 56 11.2 46.7 - <159 2.12 9.0 88 56 11.2 46.7 - <15
10 2.25 8.0 78 56 10.5 44.1 - <15
Start Value End Value Difference Start Value End Value DifferencePa Pa % Pa Pa %
Run 1 102 102 0.0 Pass 105 105 0.0 Pass
RunStagnation
(Pa)Reference
(Pa)Difference
(Pa)
Outcome(Permitted +/- 10 Pa)
Run 1 90 91 -1.0 Pass
Sampling Line B
15:1223 August 2018
Pre Traverse Leak Rate
To complete a compliant pitot leak check a pressure of over 80 mmH₂O (or 800 Pa) is applied and the pressure drop monitored over 5 mins. A drop of less than 5% must be observed.
S-Type Pitot Stagnation Check
Run OutcomePost Traverse Leak Rate
Sampling Line A
Outcome
PITOT LEAK CHECK
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
PRELIMINARY STACK SURVEY
Time of Survey
Volumetric Flow Rate
(actual)
Velocity Measurement Device: S-Type Pitot
Volumetric Flow Rate
(actual)
Date of Survey
PRELIMINARY STACK SURVEY QUALITY ASSURANCE CHECKLIST
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EA Technical Guidance Note (Monitoring) M1 Units Requirement Compliant
Lowest Differential Pressure Pa >= 5 Pa Yes
Lowest Gas Velocity m/s - -
Highest Gas Velocity m/s - -
Ratio of Gas Velocities - < 3 : 1 Yes
Maximum angle of flow with regard to duct axis o < 15o Yes
No local negative flow - - Yes
Velocity at Traverse Point, V = Kpt x (1-e) * Ö(2 * DP pt / P ActualW)
Where:Kpt = Pitot tube calibration coefficient(1-e) = Compressibility correction factor, assumed at a constant 0.998
Average Stack Gas Velocity, Va 10.2 m/s
Duct gas flow conditions Actual Reference UnitsTemperature 56 0 oCTotal Pressure 102.012 101.3 kPaOxygen (Wet) 14.3 17 %Moisture 15.98 15.98 %Pitot tube calibration coefficient, Kpt 0.871
Gas Volumetric Flowrate UnitsAverage Stack Gas Velocity (Va) m/sStack Area (A) m2
Gas Volumetric Flowrate (Actual), QActual m3/hr
Gas Volumetric Flowrate (STP, Wet), QSTP m3/hr
Gas Volumetric Flowrate (STP, Dry), QSTP,Dry m3/hr
Gas Volumetric Flowrate (REF), QRef m3/hr
Where:QActual = Va x A x 3600QSTP = Q (Actual) x (Ts / Ta) x (Pa / Ps) x 3600QSTP,Dry = Q (STP) / (100 - (100 / Ma)) x 3600QRef = Q (STP) x ((100 - Ma) / (100 - Ms)) x ((20.9 - O2a) / (20.9 - O2s))
Nomenclature:Ts = Absolute Temperature, Standard Conditions, 273 KPs = Absolute Pressure, Standard Conditions, 101.3 kPaTa = Absolute Temperature, Actual Conditions, KPa = Absolute Pressure, Actual Conditions, kPaMa = Water vapour, Actual Conditions, % VolMs = Water vapour, Reference Conditions, % VolO2a = Oxygen, Actual Conditions, % VolO2s = Oxygen, Reference Conditions, % Vol
108472
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Plane Validation Criteria
<15
8.3
1.4
PRELIMINARY STACK SURVEY (CONTINUED)
Yes
11.8
49
Calculation of Stack Gas Volumetric Flowrate, Q
4.19
Result
129096
215185
Calculation of Stack Gas Velocity, V
154491
10.24
Result
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Value UnitsStack Depth 2.31 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 4.19 m2 A 50 1.16 m
Sampling Distance Distance into SwirlPoint (% of Depth) Stack (m) o
1 2.6 0.06 < 152 8.2 0.19 < 153 14.6 0.34 < 154 22.6 0.52 < 15
5 34.2 0.79 < 15
6 65.8 1.52 < 15
7 77.4 1.79 < 15
8 85.4 1.97 < 159 91.8 2.12 < 15
10 97.4 2.25 < 15Point Not Used 2.6 0.06 < 15Point Not Used 8.2 0.19 < 15
Point Not Used 14.6 0.34 < 15
Point Not Used 22.6 0.52 < 15Point Not Used 34.2 0.79 < 15
16 65.8 1.52 < 15Isokinetic sampling point 17 77.4 1.79 < 15Isokinetic sampling points not used 18 85.4 1.97 < 15Non Isokinetic/Gases sampling point 19 91.8 2.12 < 15
20 97.4 2.25 < 15
STACK PHOTOS
STACK DIAGRAM
Non-Isokinetic/Gases Sampling
Isokinetic Sampling
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
1
2
3
4
5
6
7
8
9
10
20
19
14
17 15 13
12
11
18 16
Sampling Line A
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Limit of Detection
Leak Uncollected Mass
m³ K kPa % by volume % by volume % by mass % mgMU required < 2% < 2% < 1% < 1% < 10% < 5% of ELV < 2% < 10% of ELVRun 1 0.001 2.0 0.50 1.0 0.1 0.2300 - -as a % 0.10 0.61 0.49 1.0 0.70 0.55562 1.07 0.001compliant? Yes Yes Yes Yes Yes Yes Yes Yes
Run UncollectedMass
m³ mg - mg/m³ mgRun 1 0.87 3.2500 0.6 0.010 0.0001 -MU as mg/m3 0.02 0.1111 0.02 0.010 0.0001 0.12MU as % 1.27 7.0769 - 0.617 0.0041 -
0.23 mg/m³ 14.74 %(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Volume (STP) Mass of particulate
APPENDIX 3 - Measurement Uncertainty Budget Calculations
MEASUREMENT UNCERTAINTY BUDGET - TOTAL PARTICULATE MATTER
O2 Correction
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Leak
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Leak
m³ K kPa % by volume % by volume %MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.001 2.0 0.50 1.0 0.1 -as a % 0.02 0.7 0.50 1.0 0.70 1.59compliant? Yes Yes Yes Yes Yes Yes
Run Laboratoryanalysis
m³ - ng ng/m³ -Run 1 5.3600 0.6 0.8874 0.0001 - -MU as ng/m3 0.0001 0.0001 0.0054 0.0001 0.0008 0.0055MU as % 1.2982 - 64.1199 0.9204 10.00 -
R1 - Uncertainty expressed at a 95% confidence level (where k = 2) 0.011 ng/m³ 129.9 %
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Leak
MEASUREMENT UNCERTAINTY BUDGET - DIOXINS & FURANS
O2 CorrectionVolume (STP) Mass of Dioxin & Furan
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Limit of Detection
Leak
m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 2.070 296.9 101.2 1.0 14.33 7.392 -as a % 0.05 0.67 0.49 1.0 0.70 0.19 0.53compliant? Yes Yes Yes Yes Yes Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 1.9018 7.3920 0.5999 0.0110 - -MU as mg/m3
0.0466 0.0228 0.0536 0.0110 0.1607 0.1775MU as % 1.3041 0.6372 1.4998 0.3087 4.5 -
0.36 mg/m³ 9.94 %
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement
MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC FORMALDEHYDE
APPENDIX 3 - Measurement Uncertainty Budget Calculations
O2 Correction
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Volume (STP) Mass of Formaldehyde
Leak Combined uncertainty
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Limit of Detection
Leak
m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 2.07 296.85 101.22 1.0 14.3 18.92 -as a % 0.05 0.67 0.49 1.0 0.70 0.05 1.07compliant? Yes Yes Yes Yes Yes Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 1.9025 18.9200 0.5999 0.0564 - -MU as mg/m3
0.1192 0.0473 0.1371 0.0564 0.9139 0.9346MU as % 1.3041 0.5177 1.4998 0.6174 10.0 -
1.87 mg/m³ 20.45 %
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement
O2 CorrectionMass of CVOCs
MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC CVOCS
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Volume (STP)
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Leak Combined uncertainty
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Limit of Detection
Leak
m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 1.98 300.48 101.22 1.0 14.33 17.755 -as a % 0.05 0.67 0.49 1.0 0.70 1.38 0.28compliant? Yes Yes Yes Yes Yes Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 1.7931 17.7554 0.5999 0.0146 - -MU as mg/m3
0.1188 0.2757 0.1371 0.0146 0.9139 0.9717MU as % 1.3001 3.0166 1.4998 0.1597 10.0 -
1.94 mg/m³ 21.27 %
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Leak
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Mass of Total Aldehydes
Volume (STP)
MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC TOTAL ALDEHYDES
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
O2 Correction
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Limit of Detection
Leak
m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 1.90 302 101.22 1.0 14.33 0.6544 -as a % 0.05 0.66 0.49 1.0 0.70 0.04 1.12compliant? Yes Yes Yes Yes Yes Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 1.7135 0.6544 0.5999 0.0016 - -MU as mg/m3
0.0032 0.0155 0.0037 0.0016 0.0119 0.0202MU as % 1.2985 6.2548 1.4998 0.6488 4.8 -
0.04 mg/m³ 16.31 %
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Volume (STP) O2 Correction
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
LeakMass of Sulphur dioxide
Combined uncertainty
MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC SULPHUR DIOXIDE
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Leak
m³ K kPa % by volume % by volume %MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.001 2.0 0.50 1.0 0.1 -as a % 0.10 0.61 0.49 1.0 0.70 1.07compliant? Yes Yes Yes Yes Yes Yes
Run UncollectedMass
m³ mg - mg/m³ mgRun 1 0.87 159200 0.6 942.03 58 -MU as % v/v 0.24 0.01 0.29 0.12 0.007 0.40MU as % 1.27 0.06 1.50 0.62 0.04 -
0.79 % v/v 4.13 %
MEASUREMENT UNCERTAINTY BUDGET - MOISTURE
Volume (STP) Leak
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Mass Gained O2 Correction
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Combined uncertainty
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200 mg/m3
33.4 mg/m3
410 mg/m3
513 mg/m3
Value MU Met?51 Yes60 -60 -60 -
0.11 Yes0.1 Yes
-0.40 Yes0.32 Yes-1.44 Yes0.25 Yes0.25 Yes0.25 Yes3.00 Yes0.27 YesN/A -0.27 Yes
UncertaintyU r = S r
U lof
U d,z
U d,s
U t,z
U t,s
U p
U fit
U v
U i
U adj
33.36 mg/m3
2.70 mg/m3
5.40 mg/m3
2.7 % ELV
5.4 mg/m3
16.2 % value
Performance characteristic
<2 % range
Units
< 2% of value
Cal gas conc
MEASUREMENT UNCERTAINTY BUDGET - OXIDES OF NITROGEN
<2 % range
Logger sampling interval
Repeatability at zero-
specification
short term zero drift 0.185
% of value
Response time
Analyser Full Scale
% of full scale/3 kPa <2 % / 3 kPa
<2% range / 24hr
% of full scale/2 kPa
0.173
% full scale
Measurement uncertainty (Concentration Measured)
Combined Interfence
<2% range/24hr
-
0.004Uncertainty of Cal gas 2.000
<3% range / 10 K
short term span drift
Deviation from linearity
% full scale
% full scale/10V<4% of Range
Measurement period
<3% / 2 kPaambient temperature dependence zero / span
% of upper limit of Cal range
Number of readings in measurement
seconds
repeatability-0.2310.004
Developed for the STA by R Robinson, NPL
influence of sample gas pressure
Span drift
minutes
Expanded uncertainty expressed with a level of confidence of 95%
% range
% full scale
<2%
Combined interference
180
1.575influence of Ambient Temp at Span
0.000
% full scaleRepeatability at span level
losses in the line (leak) % of value
% full scale/10K
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Value of uncertainty quantity
0.000
0.088
Combined uncertaintyExpanded at a 95% confidence interval
influence of supply voltageinfluence of sample gas flow
Expanded uncertainty expressed with a level of confidence of 95%
lack of fit
seconds
< 0.1%vol /10 volt
Limit value
Influence of Vibrationdependence on voltage
<1 % range
-0.831
Concentration @ Ref conditions
-
Expanded uncertainty expressed with a level of confidence of 95%
influence of Ambient Temp at Zero
-
volume or pressure flow dependenceatmospheric pressure dependence
Zero drift
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100 mg/m3
12.6 mg/m3
207.5 mg/m3
250 mg/m3
Value MU Met?40 Yes60 -60 -60 -0.1 Yes0.2 Yes
0.61 Yes0.50 Yes1.50 Yes0.2 Yes
0.44 Yes1 Yes
0.03 Yes-0.70 YesN/A N/A-0.03 Yes1.00 Yes
N/A - Horiba's are not effected by Vibration
UncertaintyU r = S r
U lof
U d,z U d,s
U t,z
U t,s
U p
U fit
U v
U i
U adj
24.7 mg/m3
2.9 mg/m3
5.7 mg/m3
5.7 % ELV
5.7 mg/m3
23.2 % value
Number of readings in measurement--
specification
% full scale
% full scale/10V
Span drift
<2 % range
minutes
% full scale
180
-
Units
<3% range / 10 KCombined interferencedependence on voltage
<2 % range
secondsLogger sampling interval
Analyser Full Scale
Limit value
MEASUREMENT UNCERTAINTY BUDGET - CARBON MONOXIDE
% of Range0.36
% full scale
Deviation from linearity
volume or pressure flow dependence<2% range/24hr
-<1 % rangeRepeatability at zero
Concentration @ Ref conditions
Measurement period
% of full scale/2 kPa
secondsPerformance characteristicsResponse time
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Zero drift <2% range / 24hr% full scale
% of upper limit of Cal rangelosses in the line (leak)
<2 % / 3 kPa
< 0.1%vol /10 volt<4% of Range
0.12
short term span drift
Influence of Vibration
atmospheric pressure dependenceambient temperature dependence zero / span
repeatability
% of full scale/3 kPa
<2%
<3% / 2 kPa
Value of uncertainty quantity
0.29
% of value < 2% of value< 2% of value
lack of fitshort term zero drift
Measurement uncertainty (Concentration Measured)
Expanded uncertainty expressed with a level of confidence of 95%
0.35
Combined Interfence
influence of sample gas pressure0.13
Uncertainty of calibration gas
-2.310.14
% of value
Performance characteristic0.003
influence of sample gas flow
influence of Ambient Temp span
Repeatability at span level
Cal gas conc
% of value
0.35
influence of Ambient Temp zero
Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement
Developed for the STA by R Robinson, NPL
0.00influence of supply voltage
Combined uncertaintyExpanded uncertainty
1.34Uncertainty of Cal gas 0.83
Expanded uncertainty expressed with a level of confidence of 95%
Expanded uncertainty expressed with a level of confidence of 95%
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17 %vol17.06 %vol20.9 %vol25 %vol
Value MU Met?25 Yes60 -60 -60 -
0.25 Yes0.15 Yes0.13 Yes0.00 Yes-0.16 Yes0.03 Yes0.05 Yes-0.08 Yes0.14 Yes0.01 Yes0.14 Yes0.1 Yes
UncertaintyU r = S r
U lof
U d,z
U d,s
U t,z
U t,s
U p
U fit
U v
U i
U adj
17.06 %0.18 %0.35 %
0.3 %
0.06 % vol
0.0173
% full scale/10V < 0.1%vol /10 volt
0.1045
% of valuedependence on voltage
<2% range/24hr
Developed for the STA by R Robinson, NPL
0.0000
0.0751
short term span drift
% range <4% of Range
< 2% of value% of value
Value of uncertainty quantity
influence of supply voltageCombined Interfence
0.0083
APPENDIX 3 - Measurement Uncertainty Budget Calculations
seconds
Reference
Units
% of full scale/3 kPavolume or pressure flow dependence
4.5 <3% range / 10 K
lack of fit
Expanded uncertainty expressed with a level of confidence of 95%
Combined uncertainty
Expanded uncertainty expressed with a level of confidence of 95%
0.0485
minutesMeasurement period -
MEASUREMENT UNCERTAINTY BUDGET - OXYGEN
Reported ConcentrationCalibration gas
Span drift % full scale
Deviation from linearityRepeatability at span level
% of value
% full scale
Response time 180
Number of readings in measurement
specification
seconds
Analyser Full Scale
Logger sampling interval
<3% / 2 kPa
0.0000-0.0924
atmospheric pressure dependence
short term zero drift
Expanded uncertainty
Combined interference
Uncertainty of Cal gas
0.0006
influence of Ambient Temp at Zeroinfluence of Ambient Temp at Span
ambient temperature dependence
0.06300.0000
< 2% of value
Performance characteristicrepeatability
influence of sample gas pressureinfluence of sample gas flow
<2% range / 24hr
% of full scale/2 kPa
losses in the line (leak)Uncertainty of calibration gas
Measurement uncertainty (Concentration Measured)
Zero drift % full scale
<2 % / 3 kPa
% full scale <2 % rangeRepeatability at zero
-
-
<2 % range
<1 % range-
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10.2 m/s154491 m³/hr
Performance Characteristics & Source of Value Units Values Requirement CompliantUncertainty of Local Gas Velocity Determination
Uncertainty of pitot tube coefficient - 0.010
Uncertainty of mean local dynamic pressures - 0.35
Factor loading, function of the number of measurements. 3 readings 0.591 minimum 3 Yes
Range of measurment device pa 1000
Resolution pa 1.00
Calibration uncertainty pa 3.06<1% of Value or 20
Pa whichever is greater
Yes
Drift % range 0.10
Linearity % range 0.06 <2% of value Yes
Uncertainty of gas density determination
Uncertainty of molar mass determination kg/mol 0.00002Uncertainty of temperature measurement K 1.68 <1% of value Yes
Uncertainty of absolute pressure in the duct pa 520
Uncertainty associated with the estimate of density - 0.008
Uncertainty associated with the measurement of local velocity - 0.0001Uncertainty associated with the measurement of mean velocity - 0.0001
m/s0.120.24
%1.202.36
m³/hr40237886
%2.605.10
Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Note - The expanded uncertainty uses a coverage factor of k = 2.
APPENDIX 3 - Measurement Uncertainty Budget Calculations
MEASUREMENT UNCERTAINTY BUDGET - VELOCITY & VOLUMETRIC FLOW RATE
Expanded Measurement Uncertainty of Volumetric Flow Rate at a 95% Confidence IntervalExpressed as a % of the Measured Volumetric Flow RateExpanded uncertainty at a 95% Confidence Interval
Measured Velocity at Actual Conditions Measured Volumetric Flow rate at Actual Conditions
Measurement Uncertainty - VelocityCombined uncertaintyExpanded uncertainty at a 95% Confidence Interval
Note - The expanded uncertainty uses a coverage factor of k = 2.
Expanded Measurement Uncertainty of Velocity at a 95% Confidence IntervalExpressed as a % of the Measured VelocityExpanded uncertainty at a 95% Confidence Interval
Measurement Uncertainty Volumetric Flow Rate
Expanded uncertainty at a 95% Confidence Interval
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SOCOTEC UK LTD
www.socotec.co.uk
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Thank you for choosing SOCOTEC UK for your environmental monitoring needs. We hope our services have met your requirements and that you are fully satisfied with your experience of working with us, we really do value your custom and would welcome your feedback. We would appreciate it if you could take a
moment to complete a short online questionnaire so that we can improve our operations and address any areas that have not met with your expectations, by clicking on the following
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Masonite IrelandCarrick-on-ShannonSO2A
LEK 11283 / Version 123rd - 30th August
IPPC Licence: PO021-02
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