standardized automated co2/h2o flux systems for …€¦ · enclosed-path: tuscia open-path 1:...

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-3 0 3 6 0 12 24 36 48 Original LI-7500: average and range of 3 instruments LI-7500RS: average and range of 3 instruments Typical T drift in the reference for daily swing @ 10 mmol/mol LTF: contamination-related drifts in open-path H 2 O Rain Rain Drift in H 2 O, mmol mol -1 Measurement Days INTRODUCTION The LI-7500RS and LI-7200RS flux research systems include gas analyzers, but also have additional functionality significantly broader than just measuring CO 2 /H 2 O concentrations: increased stability under contamination and improved temperature controls automation and standardization of final flux calculations in real-time onsite seamless integration with online tools for flux tower network and data sharing AUTOMATED RS SYSTEMS STANDARDIZED AUTOMATED CO 2 /H 2 O FLUX SYSTEMS FOR INDIVIDUAL RESEARCH GROUPS & FLUX NETWORKS SUMMARY Field tests were conducted over six periods 5-14 months long, at 6 diverse sites, using 26 gas analyzers Instrument-to-instrument variability was reduced 3-9 fold in all new RS systems vs originals CO 2 and H 2 O drifts in open-path RS system were few-to-many-tens of times less than in the original models The unfiltered enclosed RS system performed substantially better than the original for H 2 O drifts, at times drifting few- to-tens of times less Improvements in enclosed-path CO 2 drifts were modest, being similar or just a bit better than the original CONCLUSIONS RS systems can significantly reduce site maintenance and improve flux data coverage vs originals models Automated standardized onsite flux processing, and settings and configuration files saved and provided with each processed file allow traceability and comparability between sites Seamless compatibility with on-line tools minimize day-to-day site management, and make the sharing of flux data very easy GAS ANALYZER FIELD RESULTS Drifts at Highly Contaminated Sites Fluxes at All Sites -0.26 ±0.85 -7.77 ±3.1 0.14 ±0.05 2.03 ±0.44 -2 0 2 4 0 12 24 36 48 Original unfiltered LI-7200: average and range of 3 instruments Unfiltered LI-7200RS: average and range of 3 instruments LTF: contamination-related drifts in enclosed H 2 O Measurement Days Drift in H 2 O, mmol mol -1 Rain Rain 0.83 ±0.09 2.81 ±0.33 Contamination-related drift Instrument-to-instrument variability -60 0 60 -60 0 60 CO 2 flux covariance Fc, mmol m -2 s -1 -7.5% +7.5% Original Model RS Model Enclosed-path: Howard Enclosed-path: LERS Enclosed-path: Tuscia Open-path: Howard Open-path 1: Landfill Open-path 2: Landfill 0 10 20 0 10 20 H 2 O flux covariance Fq, mmol m -2 s -1 -7.5% +7.5% 1:1 Original Model Open-path 1: Landfill Open-path 2: Landfill Open-path: Howard Enclosed-path:LERS Enclosed-path:LERS Enclosed-path: Tuscia Enclosed-path: Howard RS Model G. Burba 1* , I. Begashaw 1 , G. Fratini 1 , F. Griessbaum 1 , J. Kathilankal 1 , L. Xu 1 , D. Franz 2 , E. Joseph 3 , E. Larmanou 2 , S. Miller 3 , D. Papale 4 , S. Sabbatini 4 , T. Sachs 2 , R. Sakai 5 , and D. McDermitt 1 1 LI-COR Biosciences, Lincoln, Nebraska, United States, 2 GFZ German Research Centre for Geosciences, Potsdam, Germany, 3 State University of New York, Albany, New York, United States, 4 University of Tuscia, Viterbo, Italy, 5 NOAA-NCAS Howard University, Washington DC, United States; * Corresponding author: [email protected] New automated flux systems output real-time fully processed fluxes of CO 2 ,H 2 O, CH 4 , H, t, and auxiliary data Low-power weatherized microcomputer, SmartFlux2,runs EddyPro similar to a desktop Fully configurable processing includes Fourier Transform, spectra, co-spectra, planar fit, progressive RH corrections, etc. All configurations are saved for standardization and traceability All-digital integration includes gas analyzers, anemometers, multiple loggers, etc. Onsite clocks synchronized with PTP, clocks between stations are synchronized using GPS Flux network tool, FluxSuite, shows status, fluxes, weather, flags, etc., sends email alerts, and allows online data access and sharing LI-6251 Analyzer Closed-path CO 2 First of a kind LI-6252 Analyzer Closed-path CO 2 LI-6262 Analyzer Closed-path CO 2 /H 2 O First of a kind LI-7500 Analyzer Open-path CO 2 /H 2 O First of a kind LI-7000 Analyzer Closed-path CO 2 /H 2 O Cleanable cell LI-7500A Analyzer Open-path CO 2 /H 2 O Cold setting Fast logging LI-7200 Enclosed CO 2 /H 2 O Cold setting Fast logging First of a kind LI-7700 Analyzer Open-path CH 4 Low-power First of a kind EddyPro Flux processing Open-source Free Maintained Supported SmartFlux Microcomputer Runs EddyPro Onsite processing Full processing First of a kind LI-7500RS Open-path flux system CO 2 /H 2 O; accepts CH 4 Multiple anemometers Multiple slow loggers Standardized processing LI-7200RS Enclosed flux system CO 2 /H 2 O; accepts CH 4 Multiple anemometers Multiple slow loggers Standardized processing SmartFlux 2 Microcomputer Runs EddyPro Real-time processing Full complete processing Digital anemometer EC Station Digital flux station Time-synchronized Fully configurable Fully automated First of a kind FluxSuite Network tool for automated flux stations All stations are time-synchronized All stations viewed and managed remotely Global standardization and cross-sharing First of a kind HISTORICAL PERSPECTIVE ON THE NEW RS FLUX SYSTEMS AS KEY TOOLS FOR GLOBAL STANDARDIZATION OF FLUX NETWORKS 1987 2016 2000 1990 2011 2010 LI-COR is a registered trademark of LI-COR Inc. All other trademarks belong to their respective owners

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Page 1: STANDARDIZED AUTOMATED CO2/H2O FLUX SYSTEMS FOR …€¦ · Enclosed-path: Tuscia Open-path 1: Landfill Open-path 2: Landfill 0 10 20 0 10 20 H 2 O flux covariance Fq, mmol m-2 s-1-7.5%

-30

-20

-10

0

10

0 12 24 36 48

Original LI-7500: average and range of 3 instruments

LI-7500RS: average and range of 3 instruments

Typical T drift in the reference for daily swing @ 400 ppm

LTF: contamination-related drifts in open-path CO2

Dri

ft in

CO

2,p

pm

Measurement Days

Rain Rain

-3

0

3

6

0 12 24 36 48

Original LI-7500: average and range of 3 instruments

LI-7500RS: average and range of 3 instruments

Typical T drift in the reference for daily swing @ 10 mmol/mol

LTF: contamination-related drifts in open-path H2O

Rain Rain

Dri

ft in

H2O

,mm

ol m

ol-1

Measurement Days

INTRODUCTIONThe LI-7500RS and LI-7200RS flux researchsystems include gas analyzers, but also haveadditional functionality significantly broaderthan just measuring CO2/H2O concentrations:

increased stability under contamination andimproved temperature controls

automation and standardization of final fluxcalculations in real-time onsite

seamless integration with online tools forflux tower network and data sharing

AUTOMATED RS SYSTEMS

STANDARDIZED AUTOMATED CO2/H2O FLUX SYSTEMS FOR INDIVIDUAL RESEARCH GROUPS & FLUX NETWORKS

SUMMARY Field tests were conducted over six periods

5-14 months long, at 6 diverse sites, using26 gas analyzers

Instrument-to-instrument variability wasreduced 3-9 fold in all new RS systems vsoriginals

CO2 and H2O drifts in open-path RS systemwere few-to-many-tens of times less than inthe original models

The unfiltered enclosed RS systemperformed substantially better than theoriginal for H2O drifts, at times drifting few-to-tens of times less

Improvements in enclosed-path CO2 driftswere modest, being similar or just a bitbetter than the original

CONCLUSIONS

RS systems can significantly reduce sitemaintenance and improve flux datacoverage vs originals models

Automated standardized onsite fluxprocessing, and settings and configurationfiles saved and provided with eachprocessed file allow traceability andcomparability between sites

Seamless compatibility with on-line toolsminimize day-to-day site management, andmake the sharing of flux data very easy

GAS ANALYZER FIELD RESULTS

Drifts at Highly Contaminated Sites Fluxes at All Sites

-0.26 ±0.85

-7.77 ±3.1

0.14 ±0.05

2.03 ±0.44

-2

0

2

4

0 12 24 36 48

Original unfiltered LI-7200: average and range of 3 instruments

Unfiltered LI-7200RS: average and range of 3 instruments

LTF: contamination-related drifts in enclosed H2O

Measurement Days

Dri

ft in

H2O

,mm

ol m

ol-1

Rain Rain

0.83 ±0.09

2.81 ±0.33

Co

nta

min

atio

n-r

elat

ed d

rift

Inst

rum

ent-

to-i

nst

rum

ent

vari

abili

ty

-60

0

60

-60 0 60

CO2 flux covariance

Fc, mmol m-2 s-1

-7.5%

+7.5%

Original Model

RS M

odel

-60

0

60

-60 0 60

Open-path: Howard

Enclosed-path: Howard

Enclosed-path: LERS

Enclosed-path: Tuscia

Open-path 1: Landfill

Open-path 2: Landfill

-60

0

60

-60 0 60

Open-path: Howard

Enclosed-path: Howard

Enclosed-path: LERS

Enclosed-path: Tuscia

Open-path 1: Landfill

Open-path 2: Landfill

-60

0

60

-60 0 60

Open-path: Howard

Enclosed-path: Howard

Enclosed-path: LERS

Enclosed-path: Tuscia

Open-path 1: Landfill

Open-path 2: Landfill

-60

0

60

-60 0 60

Open-path: Howard

Enclosed-path: Howard

Enclosed-path: LERS

Enclosed-path: Tuscia

Open-path 1: Landfill

Open-path 2: Landfill

0

10

20

0 10 20

H2O flux covariance Fq, mmol m-2 s-1

-7.5%

+7.5% 1:1

Original Model

0

10

20

0 10 20

Open-path 1: Landfill

Open-path 2: Landfill

Open-path: Howard

Enclosed-path:LERS

Enclosed-path: Tuscia

Enclosed-path: Howard

H2O flux covariance, Fqmmol m-2 s-1

-7.5%

+7.5%1:1

Original Model

0

10

20

0 10 20

Open-path 1: Landfill

Open-path 2: Landfill

Open-path: Howard

Enclosed-path:LERS

Enclosed-path: Tuscia

Enclosed-path: Howard

H2O flux covariance, Fqmmol m-2 s-1

-7.5%

+7.5%1:1

Original Model-60

0

60

-60 0 60

CO2 flux covariance

Fc, mmol m-2 s-1

-7.5%

+7.5%

Original ModelRS

Mod

el

-60

0

60

-60 0 60

Open-path: Howard

Enclosed-path: Howard

Enclosed-path: LERS

Enclosed-path: Tuscia

Open-path 1: Landfill

Open-path 2: Landfill

-60

0

60

-60 0 60

Open-path: Howard

Enclosed-path: Howard

Enclosed-path: LERS

Enclosed-path: Tuscia

Open-path 1: Landfill

Open-path 2: Landfill

-60

0

60

-60 0 60

Open-path: Howard

Enclosed-path: Howard

Enclosed-path: LERS

Enclosed-path: Tuscia

Open-path 1: Landfill

Open-path 2: Landfill

-60

0

60

-60 0 60

Open-path: Howard

Enclosed-path: Howard

Enclosed-path: LERS

Enclosed-path: Tuscia

Open-path 1: Landfill

Open-path 2: Landfill

G. Burba1*, I. Begashaw1, G. Fratini1, F. Griessbaum1, J. Kathilankal1, L. Xu1, D. Franz2, E. Joseph3, E. Larmanou2, S. Miller3, D. Papale4, S. Sabbatini4, T. Sachs2, R. Sakai5, and D. McDermitt1

1LI-COR Biosciences, Lincoln, Nebraska, United States, 2GFZ German Research Centre for Geosciences, Potsdam, Germany, 3State University of New York, Albany, New York, United States, 4University of Tuscia, Viterbo, Italy, 5NOAA-NCAS Howard University, Washington DC, United States; *Corresponding author: [email protected]

New automated flux systems output real-timefully processed fluxes of CO2, H2O, CH4, H, t,and auxiliary data

Low-power weatherized microcomputer,SmartFlux 2, runs EddyPro similar to a desktop

Fully configurable processing includes FourierTransform, spectra, co-spectra, planar fit,progressiveRHcorrections, etc.

All configurations are saved for standardizationand traceability

All-digital integration includes gas analyzers,anemometers, multiple loggers, etc.

Onsite clocks synchronized with PTP, clocksbetween stations are synchronized usingGPS

Flux network tool, FluxSuite, shows status,fluxes, weather, flags, etc., sends email alerts,and allows online data access and sharing

LI-6251• Analyzer• Closed-path• CO2

• First of a kind

LI-6252• Analyzer• Closed-path• CO2

LI-6262• Analyzer• Closed-path• CO2/H2O• First of a kind

LI-7500• Analyzer• Open-path• CO2/H2O• First of a kind

LI-7000• Analyzer• Closed-path• CO2/H2O• Cleanable cell

LI-7500A• Analyzer• Open-path• CO2/H2O• Cold setting• Fast logging

LI-7200• Enclosed• CO2/H2O• Cold setting• Fast logging• First of a kind

LI-7700• Analyzer• Open-path• CH4

• Low-power• First of a kind

EddyPro• Flux processing• Open-source• Free• Maintained• Supported

SmartFlux• Microcomputer• Runs EddyPro• Onsite processing• Full processing• First of a kind

LI-7500RS• Open-path flux system• CO2/H2O; accepts CH4

• Multiple anemometers• Multiple slow loggers• Standardized processing

LI-7200RS• Enclosed flux system• CO2/H2O; accepts CH4

• Multiple anemometers• Multiple slow loggers• Standardized processing

SmartFlux 2• Microcomputer• Runs EddyPro• Real-time processing• Full complete processing• Digital anemometer

EC Station• Digital flux station• Time-synchronized• Fully configurable• Fully automated• First of a kind

FluxSuite• Network tool for automated flux stations • All stations are time-synchronized• All stations viewed and managed remotely• Global standardization and cross-sharing• First of a kind

HISTORICAL PERSPECTIVE ON THE NEW RS FLUX SYSTEMS AS KEY TOOLS FOR GLOBAL STANDARDIZATION OF FLUX NETWORKS

1987 201620001990 20112010

LI-COR is a registered trademark of LI-COR Inc.All other trademarks belong to their respective owners