supplementary information ratiometric selective ... · narinder kaur,a†jasminder singh,b†...

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Supplementary Information ZnO decorated with organic nanoparticles based sensor for ratiometric selective determination of mercury ions Narinder Kaur, a† Jasminder Singh, b† Pushap Raj b , Narinder Singh, b * Harpreet Singh, c Sanjeev K. Sharma, a * Deuk Young Kim, a Navneet Kaur d,e * a. Semiconductor Materials and Device Laboratory, Department of Semiconductor Science, Dongguk University-Seoul, Seoul 100715, Republic of Korea b. Department of Chemistry, Indian Institute of Technology (IIT) Ropar, Rupnagar, Panjab 140001, India. E-mail: [email protected] c. School of Mechanical, Materials & Energy Engineering, IIT Ropar, Rupnagar, Punjab 140001, India d. Centre for Nanoscience and Nanotechnology (UIEAST), Panjab University, Chandigarh, India, 160014. e. Department of Chemistry, Panjab University, Chandigarh, India, 160014; E-mail: [email protected] Both authors contributed equally Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015

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Page 1: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Supplementary Information

ZnO decorated with organic nanoparticles based sensor for ratiometric selective determination of mercury ions

Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K.

Sharma,a* Deuk Young Kim,a Navneet Kaurd,e*

a.Semiconductor Materials and Device Laboratory, Department of Semiconductor Science, Dongguk University-Seoul, Seoul 100715, Republic of Korea

b.Department of Chemistry, Indian Institute of Technology (IIT) Ropar, Rupnagar, Panjab 140001, India. E-mail: [email protected]

c.School of Mechanical, Materials & Energy Engineering, IIT Ropar, Rupnagar, Punjab 140001, India

d.Centre for Nanoscience and Nanotechnology (UIEAST), Panjab University, Chandigarh, India, 160014.

e.Department of Chemistry, Panjab University, Chandigarh, India, 160014; E-mail: [email protected]

†Both authors contributed equally

Electronic Supplementary Material (ESI) for New Journal of Chemistry.This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015

Page 2: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Figure S1: 1H NMR of R1

Page 3: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Figure S2: 13C NMR of R1

Page 4: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Figure S3: 1H NMR of R1 coated on surface of ZnO

Page 5: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Figure S4 a: IR spectrum of R1

Page 6: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Figure S4 b: IR spectrum of N1 i.e. R1 coated on the surface of ZnO

Page 7: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Figure S5: Comparison of absorption profile of prepared receptor (R1) and R1 coated on surface of ZnO (N1)

Page 8: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Figure S6: Comparison of fluorescence profile of prepared receptor (R1) and R1 coated on surface of ZnO (N1)

Page 9: Supplementary Information ratiometric selective ... · Narinder Kaur,a†Jasminder Singh,b† Pushap Rajb, Narinder Singh,b* Harpreet Singh,c Sanjeev K. Sharma,a* Deuk Young Kim,a

Figure S7: Bar diagram showing stability of N1 fluorescence response in due course of time