symmetry and point group theory 260912
TRANSCRIPT
![Page 1: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/1.jpg)
Symmetry and Introduction
to Group Theory
Disclaimer: Some lecture note slides are adopted from CHEM 59-
250 - Originally by Dr. Samuel Johnson
Power point slides from Inorganic Chemistry 4th edition by Gary
L. Miessler and Donald A. Tarr
![Page 2: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/2.jpg)
Symmetry and Point Groups
I. Introduction
A. Symmetry is present in nature and in human culture
![Page 3: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/3.jpg)
B. Using Symmetry in Chemistry
1. Understand what orbitals are used in bonding
2. Predict IR spectra or Interpret UV-Vis spectra
3. Predict optical activity of a molecule
II. Symmetry Elements and Operations
A. Definitions
1. Symmetry Element = geometrical entity such as a line, a plane, or a point,
with respect to which one or more symmetry operations can be carried out
2. Symmetry Operation = a movement of a body such that the appearance
after the operation is indistinguishable from the original appearance (if you
can tell the difference, it wasn’t a symmetry operation)
B. The Symmetry Operations
1. E (Identity Operation) = no change in the object
a. Needed for mathematical completeness
b. Every molecule has at least this symmetry operation
![Page 4: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/4.jpg)
2. Cn (Rotation Operation) = rotation of the object 360/n degrees about an axis
a. The symmetry element is a line
b. Counterclockwise rotation is taken as positive
c. Principle axis = axis with the largest possible n value
d. Examples:
C23 = two C3’s
C33 = E
C17 axis
![Page 5: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/5.jpg)
3. s (Reflection Operation) = exchange of points through a plane to an
opposite and equidistant point
a. Symmetry element is a plane
b. Human Body has an approximate s operation
c. Linear objects have infinite s‘s
d. s h = plane perpendicular to principle axis
e. s v = plane includes the principle axis
f. s d = plane includes the principle axis, but not the outer atoms
O C O OH H
sh sv
sd
![Page 6: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/6.jpg)
4. i (Inversion Operation) = each point moves through a common central
point to a position opposite and equidistant
a. Symmetry element is a point
b. Sometimes difficult to see, sometimes not present when you think
you see it
c. Ethane has i, methane does not
d. Tetrahedra, triangles, pentagons do not have i
e. Squares, parallelograms, rectangular solids, octahedra do
![Page 7: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/7.jpg)
5. Sn (Improper Rotation Operation) = rotation about 360/n axis followed by
reflection through a plane perpendicular to axis of rotation
a. Methane has 3 S4 operations (90 degree rotation, then reflection)
b. 2 Sn operations = Cn/2 (S24 = C2)
c. nSn = E, S2 = i, S1 = s
d. Snowflake has S2, S3, S6 axes
![Page 8: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/8.jpg)
C. Examples:
1. H2O: E, C2, 2s
2. p-dichlorobenzene: E, 3s, 3C2, i
3. Ethane (staggered): E, 3s, C3, 3C2, i, S6
4. Try Ex. 4-1, 4-2
OH H
sv
sdC2
Cl Cl
C C
H
H
H
H
H
H
![Page 9: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/9.jpg)
![Page 10: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/10.jpg)
![Page 11: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/11.jpg)
III. Point Groups
A. Definitions:
1. Point Group = the set of symmetry operations for a molecule
2. Group Theory = mathematical treatment of the properties of the group
which can be used to find properties of the molecule
B. Assigning the Point Group of a Molecule
1. Determine if the molecule is of high or low symmetry by inspection
a. Low Symmetry Groups
![Page 12: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/12.jpg)
b. High Symmetry Groups
![Page 13: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/13.jpg)
2. If not, find the principle axis
3. If there are C2 axes perpendicular
to Cn the molecule is in D
If not, the molecule will be in C or S
a. If sh perpendicular to Cn then Dnh or Cnh
If not, go to the next step
b. If s contains Cn then Cnv or Dnd
If not, Dn or Cn or S2n
c. If S2n along Cn then S2n
If not Cn
![Page 14: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/14.jpg)
C. Examples: Assign point groups of molecules in Fig 4.8
![Page 15: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/15.jpg)
Rotation axes of “normal” symmetry molecules
![Page 16: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/16.jpg)
Perpendicular C2 axes
Horizontal Mirror Planes
![Page 17: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/17.jpg)
Vertical or Dihedral Mirror Planes and S2n Axes
Examples: XeF4, SF4, IOF3, Table 4-4, Exercise 4-3
![Page 18: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/18.jpg)
D. Properties of Point Groups
1. Symmetry operation of NH3
a. Ammonia has E, 2C3
(C3 and C23) and 3sv
b. Point group = C3v
2. Properties of C3v (any group)
a. Must contain E
b. Each operation must
have an inverse; doing both
gives E (right to left)
c. Any product equals
another group member
d. Associative property
![Page 19: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/19.jpg)
No symmetry – CHFClBr
Some symmetry – CHFCl2
More symmetry – CH2Cl2
More symmetry ? – CHCl3
We need to be able to specify the symmetry of molecules clearly.
F
B rCl
H
F
Cl
Cl
H
Cl
H H
Cl Cl
Cl
H
Cl
What about ?
Point groups provide us with a way to
indicate the symmetry unambiguously.
![Page 20: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/20.jpg)
Symmetry and Point Groups
Symmetry elements are geometric entities about which a symmetry
operation can be performed. In a point group, all symmetry elements must
pass through the center of mass (the point). A symmetry operation is the
action that produces an object identical to the initial object.
Point groups have symmetry about a single point at the center of mass of
the system.
The symmetry elements and related operations that we will find in
molecules are:
Element Operation
Rotation axis, Cn n-fold rotation
Improper rotation axis, Sn n-fold improper rotation
Plane of symmetry, s Reflection
Center of symmetry, i Inversion
Identity, E
The Identity operation does nothing to the object – it is necessary for
mathematical completeness, as we will see later.
![Page 21: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/21.jpg)
n-fold rotation - a rotation of 360°/n about the Cn axis (n = 1 to )
H(2)
O(1)
H(3) H(3)
O(1)
H(2)
In water there is a C2 axis so we can perform a 2-fold (180°) rotation to get
the identical arrangement of atoms.
H(2)
H(3)H(4)
N(1)
H(2)
H(3)
H(4)
N(1)
In ammonia there is a C3 axis so we can perform 3-fold
(120°) rotations to get identical arrangement of atoms.
H(2)H(3)
H(4)
N(1)
120° 120°
180°
![Page 22: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/22.jpg)
H(2)
H(3)H(4)
N(1)
H(2)
H(3)
H(4)
N(1)
Notes about rotation operations:
- Rotations are considered positive in the counter-clockwise direction.
- Each possible rotation operation is assigned using a superscript integer m
of the form Cnm.
- The rotation Cnn is equivalent to the identity operation (nothing is moved).
H(2)H(3)
H(4)
N(1)
C31 C3
2
C33 = E
H(2)
H(3)H(4)
N(1)
![Page 23: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/23.jpg)
Cl (4)
Cl (3)
Ni (1)
Cl (2)
Cl (5)
C42 = C2
1 C41
C43
Cl (4)
Cl (2) Ni (1) Cl (3)
Cl (5)
Cl (4)
Cl (2)
Ni (1)
Cl (3)
Cl (5)
Cl (4)
Cl (3) Ni (1) Cl (2)
Cl (5)
Notes about rotation operations, Cnm:
- If n/m is an integer, then that rotation operation is equivalent to an n/m -
fold rotation.
e.g. C42 = C2
1, C62 = C3
1, C63 = C2
1, etc. (identical to simplifying fractions)
![Page 24: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/24.jpg)
Notes about rotation operations, Cnm:
- Linear molecules have an infinite number of rotation axes C because any
rotation on the molecular axis will give the same arrangement.
O(2)C(1)
C(1)O(2)
O(3) C(1) O(2)
N(2)N(1)N(1)N(2)
![Page 25: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/25.jpg)
The Principal axis in an object is the highest order rotation axis. It is
usually easy to identify the principle axis and this is typically assigned to
the z-axis if we are using Cartesian coordinates.
Ethane, C2H6 Benzene, C6H6
The principal axis is the three-fold axis
containing the C-C bond. The principal axis is the six-fold axis
through the center of the ring.
The principal axis in a tetrahedron is a
three-fold axis going through one vertex
and the center of the object.
![Page 26: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/26.jpg)
Reflection across a plane of symmetry, s (mirror plane)
H(2)
O(1)
H(3) H(3)
O(1)
H(2)
sv
H(2)
O(1)
H(3)
sv
H(2)
O(1)
H(3)
These mirror planes are
called “vertical” mirror
planes, sv, because they
contain the principal axis.
The reflection illustrated in
the top diagram is through a
mirror plane perpendicular
to the plane of the water
molecule. The plane shown
on the bottom is in the
same plane as the water
molecule.
Handedness is changed by reflection!
![Page 27: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/27.jpg)
A “horizontal” mirror plane, sh, is
perpendicular to the principal axis.
This must be the xy-plane if the z-
axis is the principal axis.
In benzene, the sh is in the plane
of the molecule – it “reflects” each
atom onto itself.
Notes about reflection operations:
- A reflection operation exchanges one half of the object with the reflection of
the other half.
- Reflection planes may be vertical, horizontal or dihedral (more on sd later).
- Two successive reflections are equivalent to the identity operation (nothing is
moved).
sh
sv sv
Vertical and dihedral mirror
planes of geometric shapes.
sd sd
sh
![Page 28: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/28.jpg)
Inversion and centers of symmetry, i (inversion centers)
In this operation, every part of the object is reflected through the inversion
center, which must be at the center of mass of the object.
i
Br
Cl
F
F
Cl
Br
Br
Cl
F
F
Cl
Br
1
1
1 1
1
1 2
2
2 2
2
2
2 2 1 1
[x, y, z]
i [-x, -y, -z]
We will not consider the matrix approach to each of the symmetry operations in this
course but it is particularly helpful for understanding what the inversion operation
does.
![Page 29: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/29.jpg)
n-fold improper rotation, Snm (associated with an improper rotation axis or
a rotation-reflection axis) This operation involves a rotation of 360°/n
followed by a reflection perpendicular to the axis. It is a single operation and
is labeled in the same manner as “proper” rotations. F1
F2
F3
F4 S41
90°
F4
F1
F2
F3
sh F1
F2
F3
F4
Note that: S1 = s, S2 = i, and sometimes S2n = Cn (e.g. in box) this makes
more sense if you examine the final result of each of the operations.
C
H1
H3
H2H4
C
H2
H4
H3H1
C
H1
H3
H2 H4
S41
S42
C21
![Page 30: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/30.jpg)
We can use a flow chart such as this
one to determine the point group of
any object. The steps in this process
are:
1. Determine the symmetry is special
(e.g. octahedral).
2. Determine if there is a principal
rotation axis.
3. Determine if there are rotation axes
perpendicular to the principal axis.
4. Determine if there are mirror planes.
5. Assign point group.
Identifying point groups
![Page 31: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/31.jpg)
Identifying point groups
![Page 32: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/32.jpg)
Identifying point groups
Perfect icosahedral (Ih) e.g. [B12H12]-2, C60
Special cases:
Perfect tetrahedral (Td) e.g. P4, CH4
Perfect octahedral (Oh) e.g. SF6, [B6H6]-2
![Page 33: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/33.jpg)
Identifying point groups Low symmetry groups:
F1
F2
F3
F4
Only* an improper axis (Sn)
e.g. 1,3,5,7-tetrafluoroCOT, S4
Only a mirror plane (Cs)
e.g. CHFCl2 F
Cl
Cl
H
![Page 34: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/34.jpg)
Identifying point groups Low symmetry groups:
Only an inversion center (Ci)
e.g. (conformation is important !)
No symmetry (C1)
e.g. CHFClBr
Br
Cl
F
F
Cl
Br
F
B rCl
H
![Page 35: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/35.jpg)
Identifying point groups Cn type groups:
A Cn axis and a sh (Cnh)
e.g. B(OH)3 (C3h, conformation is important !)
O
H
H
B
O
O
H
e.g. H2O2 (C2h, conformation is important !)
H
O O
H
Note: molecule does not have to be planar
e.g. B(NH2)3 (C3h, conformation is important !)
![Page 36: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/36.jpg)
Identifying point groups
Cn type groups:
Only a Cn axis (Cn)
e.g. B(NH2)3 (C3, conformation is important !)
e.g. H2O2 (C2, conformation is important !)
H
H
HN
B
N
N
H
H
H
H
H
O O
![Page 37: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/37.jpg)
Identifying point groups
Cn type groups:
A Cn axis and a sv (Cnv)
e.g. NH3 (C3v)
e.g. H2O2 (C2v, conformation is important !)
H
HH
N
HH
OO
![Page 38: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/38.jpg)
Identifying point groups
Cn type groups:
A Cn axis and a sv (Cnv)
e.g. NH3 (C3v, conformation is important !)
e.g. trans-[SbF4ClBr]- (C4v)
H
H
H
H
H
H
H
H
NH
F F
Br
Sb
Cl
FFBrF
F
Sb
F
FCl
OC
e.g. carbon monoxide, CO (Cv)
There are an infinite number of possible
Cn axes and sv mirror planes.
CO
![Page 39: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/39.jpg)
Identifying point groups
Dn type groups:
A Cn axis, n perpendicular C2 axes
and a sh (Dnh)
e.g. BH3 (D3h)
e.g. NiCl4 (D4h)
H
B
H
H
HH BH
Cl (4)
Cl (3)
Ni (1)
Cl (2)
Cl (5)
ClCl Ni ClCl
Cl ClNiCl Cl
![Page 40: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/40.jpg)
Identifying point groups
Dn type groups:
A Cn axis, n perpendicular C2 axes
and a sh (Dnh)
e.g. Mg(5-Cp)2 (D5h in the eclipsed conformation)
Mg
Mg
View down the C5 axis
e.g. carbon dioxide, CO2 or N2 (Dh)
There are an infinite number of possible Cn
axes and sv mirror planes in addition to the
sh.
COO O
e.g. square prism (D4h)
e.g. pentagonal prism (D5h)
![Page 41: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/41.jpg)
Identifying point groups Dn type groups:
A Cn axis, n perpendicular C2 axes
and no mirror planes (Dn)
-propellor shapes
e.g. Ni(CH2)4 (D4)
H
H
H
H
Ni
H
H
H
H
H
HH
H
Ni
H
H
H
H
H
H
H
H
Ni
H
H
H
H
![Page 42: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/42.jpg)
e.g. (SCH2CH2)3 (D3 conformation is important!)
e.g. Ni(en)3 (D3 conformation is important!) en = H2NCH2CH2NH2
e.g. propellor (D3)
![Page 43: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/43.jpg)
Identifying point groups
Dn type groups:
A Cn axis, n perpendicular C2 axes
and a sd (Dnd)
e.g. ethane, H3C-CH3
(D3d in the staggered conformation)
H H
H
H
H H
H
H
H
H
H
H
dihedral means between sides or planes –
this is where you find the C2 axes
![Page 44: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/44.jpg)
Mg AlFe M
e.g. Mg(5-Cp)2 and other metallocenes in the staggered conformation (D5d)
View down the C5 axis
These are pentagonal
antiprisms
e.g. triagular
antiprism (D3d)
e.g. square
antiprism (D4d) e.g. allene or a tennis ball (D2d)
![Page 45: Symmetry and point group theory 260912](https://reader034.vdocument.in/reader034/viewer/2022050620/558a4915d8b42a8e368b473f/html5/thumbnails/45.jpg)
1. Determine the symmetry is special
(e.g. octahedral).
2. Determine if there is a principal
rotation axis.
3. Determine if there are rotation axes
perpendicular to the principal axis.
4. Determine if there are mirror planes.
5. Assign point group.
Summary of point group identification