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synthesis of novel oxazolyl-indoles

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2007 Oxazole derivatives R 0220 Synthesis of Novel Oxazolyl-indoles. — The synthesis of several oxazolylindoles (VI) and (X), structurally related to pimprinaphine, is described. An interesting effect of the N-cyanoalkyl group on the DDQ-oxidation of the 3-aminoethyl side chain in compounds (I) is observed. — (ROY, S.; HAQUE, S.; GRIBBLE*, G. W.; Synthesis 2006, 23, 3948-3954; Dep. Chem., Dartmouth Coll., Hanover, NH 03755, USA; Eng.) — Mischke 15- 119

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Page 1: Synthesis of Novel Oxazolyl-indoles

2007

Oxazole derivativesR 0220 Synthesis of Novel Oxazolyl-indoles. — The synthesis of several oxazolylindoles

(VI) and (X), structurally related to pimprinaphine, is described. An interesting effect of the N-cyanoalkyl group on the DDQ-oxidation of the 3-aminoethyl side chain in compounds (I) is observed. — (ROY, S.; HAQUE, S.; GRIBBLE*, G. W.; Synthesis 2006, 23, 3948-3954; Dep. Chem., Dartmouth Coll., Hanover, NH 03755, USA; Eng.) — Mischke

15- 119

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