synthetic paraffinic jet fuel -3 q12
DESCRIPTION
Updated SPK Jet Fuel SlidesTRANSCRIPT
![Page 1: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/1.jpg)
SYNTHETIC PARAFFINICJET FUEL
Ramin Abhari, P.E.Senior Process EngineerSyntroleum Corporation
![Page 2: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/2.jpg)
A bright spot in recent alternative fuel news…
![Page 3: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/3.jpg)
A-10 Thunderbolt synthetic fuel flight; March 25, 2010
![Page 4: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/4.jpg)
F/A-18 synthetic fuel flight; April 28, 2010
![Page 5: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/5.jpg)
C-17 synthetic fuel flight;Oct. 22, 2007
![Page 6: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/6.jpg)
B-52 synthetic fuel flight; Sept. 26, 2006
![Page 7: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/7.jpg)
What’s up with all the synthetic fuel flight tests?
![Page 8: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/8.jpg)
DoD intends to catalyze commercial industry to produce clean fuels for the military from secure domestic resources using environmentally sensitive process as a bridge to the future
- Energy Independence and Security Act of 2007
![Page 9: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/9.jpg)
By 2016, 50% of all fuel for the continental U.S. fleet will be purchased domestically from alternate sources
- Air Force Policy Document 90-17
![Page 10: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/10.jpg)
What is synthetic jet fuel…and how is it made?
![Page 11: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/11.jpg)
Same components as petroleum jet fuel…
…except for the “bad” and the “ugly”
”The good,
the bad,
and theugly!”
Petro Synthetics
![Page 12: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/12.jpg)
Two ways tosynthetic paraffinic jet fuel
![Page 13: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/13.jpg)
1. Low Temperature Fischer-Tropsch
2 C + ½ O2 + H2O à CO + 2 H2 + CO2
CO + 2 H2 + CO2 à –[CH2]n– + H2O + CO2
Gasification:Carbon to syngas
Fischer-Tropsch:Syngas to n-paraffins
Carbon Feedstock:· Coal (~80% C)· Woody biomass (~50% C)
–[CH2]n– + H2 à +–[CH(CH2)]n-m–
+ –[CH2]m–
Hydrocracking:n-paraffins to shorter n- and iso-paraffins
Synthetic Jet Fuel to Distillation and Shipping
![Page 14: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/14.jpg)
2. Hydroprocessing of Fats and Oils
C17H33COOH + 4 H2 à C18H38 + H2O
C18H38 + H2 à n-C9H20 + i-C9H20
Liquid Biomass Feed:· Fats/Oils/Greases· Algae oils
Synthetic Jet Fuel to Distillation and Shipping
Hydrocracking:n-paraffins to shorter n- and iso-paraffins
Hydrodeoxygenation:Fatty acid/glycerides to n-paraffins
![Page 15: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/15.jpg)
5 10 15 20 25 30Time-->
5163 R-8
4909 S-8
Weight % n-Paraffins
C7-C9 C10-C13 C14-C16 C17-C19
5163 3.0 7.8 1.7 0.0634909 4.1 10.8 2.2 0.10
C11C12
C13
C14 C15 C16 C17 C18
C10C9
C8C7
C19
5 10 15 20 25 30Time-->
5163 R-8
4909 S-8
Weight % n-Paraffins
C7-C9 C10-C13 C14-C16 C17-C19
5163 3.0 7.8 1.7 0.0634909 4.1 10.8 2.2 0.10
Weight % n-Paraffins
C7-C9 C10-C13 C14-C16 C17-C19
5163 3.0 7.8 1.7 0.0634909 4.1 10.8 2.2 0.10
C11C12
C13
C14 C15 C16 C17 C18
C10C9
C8C7
C19
C11C12
C13
C14 C15 C16 C17 C18
C10C9
C8C7
C19
Same fuel from both processes
Hydro-processed Renewable Jet (HRJ
or Bio-SPK)
Fischer Tropsch (FT or SPK)
![Page 16: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/16.jpg)
Feedstock
Process
Synthetic Jet Fuel
How does synthetic jet fuel perform?
![Page 17: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/17.jpg)
Three key performance advantages
![Page 18: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/18.jpg)
2. Lower Emissions
JP-8 R-8 50/50 R-80
1
2
3
4
5
6
7
8
IdleCruise
Em
issio
n I
nd
ex (
1E1
5 p
ar-
ticle
s/k
g f
uel)
1. Lower Emissions
![Page 19: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/19.jpg)
2. Better Low Temperature Performance
Synthetic
![Page 20: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/20.jpg)
3. Less carbon deposit in fuel system
Fuel Description
15-Hr Mass Accumulation (μg/cm2)
R-8 (Syntroleum Bio-SPK)
0.3
S-8 (Syntroleum FT SPK)
0.4
JP-8 3.0
![Page 21: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/21.jpg)
Oct. 2010
Dynamic Fuels LLC, Geismar, LAStarts Up as First Supplier of Bio-SPK
![Page 22: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/22.jpg)
June 2011
Bio-SPK Certified for Commercial Aviation through ASTM D7566 Standard for Synthetic Jet Fuel
![Page 23: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/23.jpg)
June 2011
Paris-Amsterdam Flight Makes History as First Passenger Flight on Biofuel
![Page 24: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/24.jpg)
Nov. 2011
Alaska Airlines Flies First Set of Domestic Flights on Bio-SPK
![Page 25: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/25.jpg)
“Great Green Fleet” US Navy Exercises on Bio-SPK jet fuel and Renewable Diesel
July 2012USS Nimitz
![Page 26: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/26.jpg)
Summary
Strong interest by military and commercial purchasers
Superior fuel properties Two processes, abundant
feedstocks Domestic commercial
production capacity since 2010
![Page 27: Synthetic paraffinic jet fuel -3 q12](https://reader035.vdocument.in/reader035/viewer/2022081413/54754832b4af9f980a8b59b7/html5/thumbnails/27.jpg)
Some of the Contributors to the Success…