t/ (• .j 1-----~-.-···'· --···- · gray dated march 10, 1993 concerning biw arrhenius...

72
\ ltJJU \lllllll' \ X f \'II f"'l\ UJ (JOlcUIOII ' .t< . k-· ,.. / > •• ,-1 :J ? I 1.. ' .4-- ; I 4--' I I t ' \. r , . ! ( ' .. < { / (. ( ( / ') .., f / (' :'. 1 _, •. · ,. c.·)· r'r':· 1':193 U.S. Nuclear Regulatory Commission Office of Nuclear Reactor Regulation Washinqton, D.C. t/ ./ J ( f I 1 ; At tf·nt ion: Mr. Brian K. Grimes, Operating Reactor Support (• .J ( I 1 I \ I Di /• 1'") i .' ,' I ;!, !'") Division .. --···- .. ·--··· .. / I , . / J ') /I / : of .) ; - Potential Deficiency of B1W IE Instrumentatiori Control Cables Cr:nt J Pmen: United Energy Services Corporation {UESC) is an engineering services company, under contract to a number of utilities in the u.s. and Canada to address Environmental Qualification (EQ) for equipment which is important to safety. In the course of performing our analysis, we have identified additional information which relates to the issues raised in NRC Information Notice 93-33, "Potential Deficiency of Cf•rtain lE Jnstrumr:ntat.ion and Control Cables," for BIW caliles. Our analysis of various EQ test reports by BIW has caused us to question BlW's aging methodology in their reports, to the extent that W(' havf\ stopped using the activation energies derived from aqinq d;itil in those reports. We have also advised all of our utility ,·ustomers to reevaluate any of their EQ files which may have this data. Because of the age of these BIW test reports, and their lack of detail, we are unable to verify our concerns or further evaluate the potential of 10 Cfl< 21 implications. Therefore, we are forwarding the enclosed analysis for you to evaluate for possible invesUgation at BIW. If you have any questions or need further i nf ormation, plt!ase contact Mr. Jerry Henley in this off ice at 922-0700. JH: jh F.nr.losure 930805 POR PT21 EECQBAS 93 PDR .. r

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Page 1: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

\ ltJJU \lllllll' \ X f \'II f"'l\ UJ (JOlcUIOII ' .t< • . k-·

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U.S. Nuclear Regulatory Commission Office of Nuclear Reactor Regulation Washinqton, D.C. 20~;55

t/ ./ J ( f

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At tf·nt ion: Mr. Brian K. Grimes, Operating Reactor Support

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Potential Deficiency of B1W IE Instrumentatiori ~nd Control Cables

Cr:nt J Pmen:

United Energy Services Corporation {UESC) is an engineering services company, under contract to a number of utilities in the u.s. and Canada to address Environmental Qualification (EQ) for equipment which is important to safety.

In the course of performing our analysis, we have identified additional information which relates to the issues raised in NRC Information Notice 93-33, "Potential Deficiency of Cf•rtain lE Jnstrumr:ntat.ion and Control Cables," spE~cifically for BIW caliles. Our analysis of various EQ test reports by BIW has caused us to question BlW's aging methodology in their reports, to the extent that W(' havf\ stopped using the activation energies derived from aqinq d;itil in those reports. We have also advised all of our utility ,·ustomers to reevaluate any of their EQ files which may have u~ed this data.

Because of the age of these BIW test reports, and their lack of detail, we are unable to verify our concerns or further evaluate the potential of 10 Cfl< 21 implications. Therefore, we are forwarding the enclosed analysis for you to evaluate for possible invesUgation at BIW. If you have any questions or need further i nf ormation, plt!ase contact Mr. Jerry Henley in this off ice at (20~1) 922-0700.

JH: jh

F.nr.losure 93083001~ 930805 POR PT21 EECQBAS 93 PDR

.. r

Page 2: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

United Energy Serv J ces Corporation 6b8 Discovery Drive Hunts v i l l c , A L J 1) 8 o 6

Attn: Jerrell c. Henley

Ret: HlW Reports 8912, 891~, and B916 Aging Methodology

Dear Mr. Henley,

April 1:>, l<J'-Jl

1 have reviewed the Telephone contact Report attached to your Apr i 1 1 3 FAX, and should 1 ike to advise that I am in genera 1 agreement with the substance of that report. However, there are a couple ot m1nor points which should be clarified.

1. Para I.

Chang(~ the 4th sentence to read as fallows. "The elongation tests showed basically the same aging rate (slope) regardless of thP value of elongation selected." It should be clarified that this was true for a range of elongation values which varied with the particular compound being tested. The upper elongation values were ~00% for the EPR insulation of Report 8915, and 350% for the FH-XLPE of Reports 8912 and 8916. For both materials, aging lines were drawn for 50% and 0% elongation based on a regression analysis. However, in practice it is almost impossible to actually measure such small elongations, so they 1.:-an only be obtained from th(-"' regression lines.

2 Para 3.

Change the Jrd sentence to read as follows. "Mr. Jeanmonod admitted that he could not justify the conservatism of BlW's selection of a flame retardant material to represent a non­flame retardant material." The aging line in Report B912 was obtained from tests on FR-XLPE, but the coaxial and triaxial cables covered by this report are insulated with non-flame retardant XJ.PF.

9 Forge Pan,, Franklin, Massact1usetts 02038 • 5081520-1200 6001753-4237 FAX 5081526-9950 0

Page 3: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

<'h;Jnqe UH· ind !:;('ntf•n,·(· to rt•ild <j~; follows. "John had a J imitt·d amount of d<1L1 .:w;d lablf· to him in addition to tht• !t·:.t t••p(>t1, L1Jf lit' hiid d I.J'Hid l<·r·c,Jl£·<·tion cf tllf· t(·~;t:: .. '' J Wd~; not Pf~rsuna1Jy involvHd w.1th the tPstinq pr·ograms, but Wd~; ilWan· ot Uw ~;cope of t lw t f•st j IHJ in my capacity as assi f;tan1 to tt1e Vi cP Pn,s i dE~nt of Eng j neer i ng, who directed the rn·oqr·am.

Chanq1· the 1st sentencP to read d!; follow! .. ",John said they hiWl' had no siqnit icant qw•!-;t HJn!; 1 rom t IH· nuc](~<H .industry teqardinq their methodoloqy (c~v£•ryone Ge>(•ms to agn>.P with 1t), but Uwy haw,• had a qut.!stion a.i)out riH:> BSI12 report's usf• ot the flame retardant material test data for the non-flame rPtardant." 'J'here ha~; on] y been one other questj on on thj s subject, to my recollection.

J f you have any 1 ul-Uwr qu('st ions on this ~;ubj ect , pl f~ase do nut IH·!; i tat f' to ca 11 me.

I f ' I

I /. ( I ... ( ' l . \I . , ' ""~

,'

(

John \Jeanmonod

Manaqer, Applications Engineering

Page 4: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

TBLEPHOMB CONTAC~ REPORT OP J.C. HENLEY PHOMI NO.I 800•'6'-7180

WORK ORDIR MO. c M/ A

DATE OP COHTACTr April 12 an4 16, 1993

COKPAlfY COJ'TACTBD/ADDRI88: Draka Interoable (BIW Cable 8yat•a, Inc.), 9 Forq• Park, Franklin, Kl 02038

PBRSOM COMTACTED/TITLBJ John Jeanaonod, Application• Bn;ineer

SOBJBC'l'c a.qinq Kethodoloqi•• tor BIW Cable•

DISCOSSIOlf:

Mr. Jeanmonod was very helpful and provided the following information concerning 8IW cable tests in the mid to late 1970's:

There was disagreement among cable manufacturers at that time about which Arrhenius failure parameter was most applicable to natural aging of cables in service. As a result, BIW elected to perform two types of aging tests. First, they performed elongation tests on aged coupons of materials to draw the Arrhenius curve (standard IEEE method). The elongation tests showed basically the same aging rate (slope) regardless of the value of elongation selected up to lOOl. Second, they tested complete cables (conductor, insulation, shield, fillers, and jacket) by aging them at five different temperatures and periodically withdrawing them for subjection to a 2,200 VAC dielectric withstand test. This aging, removal from aging, and dielectric withstand test cycle was repeated for durations up to and beyond what the elongation curve predicted as a 40-Jear life and resulted in the data points shown on the plots. Since dielectric withstand is accepted as proof of a cable's integrity, this showed the cables had considerable useful life beyond a 40-year life predicted by the Arrhenius curve.

The Arrhenius curves in both 8IW Reports 8915 (EPR) and 8916 (CLPE­FR) were derived from testing on coupons of the exact material compc:.md as the cable insulation addressed in the report. However, Report 8912 (CLPE-NFR), on coaxial and triaxial cables, used a CLPE-FR material to draw the Arrhenius curve. Mr. Jeanmoncd admitted that he could not justify the conservatism of BIW' s selection of a non-flame retardant material to represent a flame retardant material.

Supporting data and notes from the period of testing are sketchy but may be available through a search of the company archives. John had a limited amount of data available to him in addition to the test report, but he had a good recollection of the tests since he was personally involved in the testing programs at that time. He said he was willing to ~onfirm these facts in writing.

Page 5: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

Contact Report of J. Henley to ,John Jeanaonod, BIW cable systems April 12, 1993 Paqe 2 of 2

John said they have had no significant questions from the nuclear industry regarding their methodology (everyone seems to agree with it), but they have had many questions about the B912 report's use of the flame retardant material test data for the non-flame retardant. They have no data for the non-flame retardant material. The decision was made years ago not to perform that testing.

Mr. Jeanmonod stated that he had mailed me a letter to clarity the above points. He stated that the clarifications were simply to put the facts into perspective and not contradictions.

Mr. Jeanmonod provided the following additional information as clarification on BIW Report No. B915, pages 5-8:

1. There is no significance to the fact that B915 is the only BIW Cable Test Report that includes Figures 2A and 2B. These figures present data that is from the same testing as stated on page 5 of the report.

2. The parameters in Figures 2A and 2B are differ~nt repr.esentations of the same elongation test data. The percent elongation in Figure 2B represents the ratio of length at break to or i gina 1 1 ength given as a percentage. The percent remaining elongation in Figure 2A represents a percentage of elongation remaining but normalized to 100% In fact, the actual length of unaged EPR at break would approach 700% of the unstretched length.

3. Draka probably would not have a problem with someone paying "a modest fee" to research their BIW Cable Systems archives to find any additional data. If the data can't be found in 2-3 days, it probably doesn't exist.

AC''I'JON: Henley: Finish evaluation.

COPY TO: T. Hancock, B. Craig, R. Martin, R. Morris, J. Smith, M. Kimbrell, G. Endicott

Page 6: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

-.. '~!

April 16, 1993

TO:

FROK:

SUBJ:

M. liabrell, Quality Assurance Manager

J. Henley ~~ !lfJ

Possible Reportable Event BIW Cable - Report Mo. UESC 21-01

1. I have reviewed the subject report and investigated the circumstances surrounding the source documents which are the object of the report. This memorandum will be attached to the report as support information for the determination in Part C that reportability of the event is D.Q.t.~stablished because there is a lack of data available from the manufacturer.

2. Stat.uept of the f[QI:»l!IIZ. Part A3 gives the description of the non-compliance or defect as, "In the System 1000, the Arrhenius data on BIW cable is unsubstantiated and, as indicated by attachment to the above reference, is non-existent."

Part A4 of the report describes the hazard created by this non­compliance as, "BIW cable lite cannot be predicted for any environment. Life cannot be calculated from BIW supplied data. Therefore cables may fail prematurely or in an accident environment."

3. Blhibita Identitie4 fertipent to tbe Investigation

a. Memorandum from Guy Endicott to M. Kimbrell Dated April 2, 1993, Subject: System 1000 QA Concerns, BIW Cable Entries

b. Memorandum from R.A. Gray to J.K. Smith Dated March 10, 1993, Subject: Unjustified Boston Insulated Wire (BIW) Arrhenius Data in the System 1000 Database

c. Memorandum from R.A. Gray to J.K. Smith Dated March 19, 1993, Subject: Additions for Memorandum to J.J<. Smith from R.A. Gray dated March 10, 1993 Concerning BIW Arrhenius Data

d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental Qualification of BIW Coaxial Cable.

e. System 1000 Library Code Number 060-838 Dated January 20, 1987, Arrhenius Plots for BIW Cables from Various BIW Reports

f. System 1000 Library Code Number 121-91 Dated March 23, 1991, BIW Cable System Arrhenius Plot for Silicone Rubber Insulation

g. BIW Test Report No. 8910, "BIW Bostrad 7E Cables Flame and Radiation Resistant Cables for Nuclear Power Plants," Dated

Page 7: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

M. .. oran4ua J. Henley to M. J.iawrell Apr:i.l 16, 1993 Paqe 2 of 1

May, 1975 h. 8IW 'J'est. Report No. B912, "BIW Coaxial and Triaxial

Cables Flame and Radiation Resistant Cables for Nuclear Power Plants Crosslinked Polyethylene lhsulation"

i. BIW Test Report No. 891!:>, Rev. 1, "Bostrad 7E Cables Flame and Radiation Resistant Cables for Nuclear Power Plants," Dated December 1984

j. BIW Test Report No. B916, "Bostrad XL Flame and Radiation Resistant Cables Crosslinked Polyethylene Insulated Cables for Use in Fossil and Nuclear Power stations," Dated April 1980

k. BIW Test Report No. 8917, Rev. 1, "BIW Coaxi.al and Triaxial Cables Flaae and Radiation Resistant Cables for Nuclear Power Plants crosslinked Polyethylene Insulation," Dated Deceaber 1984

1. BlW Test Report No. 8918, "BIW Bostrad CX Coaxial and 'I'riaxial Cables Flaae and Radiation Resistant Cables for Nuclear Power Plants," Dated December 1984

m. BIW Test Report No. 8921, "BIW Lo-Smoke• Cables Flaae and Radiati.on Resistant Cables for Nuclear Power Plants," Dated October 1977

n. Letter from BIW Cable Systems, lnc. (J.R. Learn, Applications Engineer) to Bechtel Power Corporation (E.A. Goldenberg), Dated June 27, 1983

o. Telephone Contact Report of J. c. Henley, UESC to John Jeanmonod, Draka Intercable (formerly BIW Cable Systems, Inc.), Dated April 12, 1993

p. Oigital Engineering System 1000 Program Revision 14 calculations for BIW Report 8915, Figure 2A for 25\, 50l, and 75l Loss of Elongation and BIW Report 8910 Figure 2

3. I11Ultl 9f thl lDYIItigatiODI

Exhibits a through d formed the basis for the report of the possib]@ reportable event. Exhibit b originally identified four BIW Cable Test Reports (Exhibits h, i, j, and a) which used unsubstantiated data as a part of the deteraination of a 40-year qualified life. Excerpts from these reports are used in the System 1000 Ljhrary Cod@ Number 060-838 (Exhibit e) to derive activation energies for use in predicting an end-of-life condition or for calculating demonstrated qualified life for these materials in safety-related applications. Exhibit c added another BIW Cable Test Report (Exhibit k) as also having unsubstantiated data of the same type.

During the course of the investigation, additional BIW Cable Test Reports (Exhibits q and 1) were located. Exhibit q uses the aaae aging methodology as Exhibits h, 1, j, and m. Exhibit 1, however,

Page 8: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

••or•adu.a J. Ben ley to .M. limb.t ell tt.pril 16, 19tJ Pa9• 3 of 7

uses Arrhenius data provided by DuPont tor Tefzel, and applies that data in the generally accepted manner to determine aqinq times for placing cables in an end-of~life condition.

Additional BIW cable aging data, in the form of an Arrhenius plot tor Silicone Rubber cables, was provided in a letter from BIW, which was used as an input to the System 1000 Library Code Nu.ber 121-91 (Exhibit f) to derive an activation energy. This plot also shows points along the Arrhenius line which represent a 50t loss of elongation and were used t.o derive the activation energy.

To summarize, there are eight documents from BIW (seven BIW Cable Teat Reports and one letter) which have been identified durin, this investigation as providing insiwht into BIW's aging aethodoloqy. Six of these documents (Exhibits g through k and II) present the same or similar methodology. The seventh document (Exhibit f) trans11ita actual data points tor an established failure paraaeter (50\ loss of elongation) and the eighth docuaent (Exhibit 1) presents aging data provided by a material supplier (DuPont Tefzel). Both of these latter two docuaents present data in a manner traditionally accepted by the i.ndustry and published IEEE standards such as IEEE 101.

The methodology for the six BIW Test Reports which are the same or similar was identified in an attachment to a letter from BIW (Exhibit n) and identifies a potentially unsafe application of the Arrhenius theory of aging. Although the derivation of the Arrhenius data does conform to accepted practice, Sections 2.5 and 2.6 describe the application of the line which apparently was used in the six BIW Test Reports identified above. The aethodoloqy allows tor the use of a line with the same slope as the Arrhenius line drawn through the point representinq a 40-year life at 90~. Then cables are thermally aged at various temperatures and periodically withdrawn for subjection to a dielectric withstand test at 2,200 VAC to demonstrate acceptabiljty. This methodology purportedly demonstrates the conservatism of aging to the line for a 40-year life.

All of the six BIW Ter.t Repr;rts apparently used this basic methodology, testlng Ln~ oasic insulation for elongation, shifting this line to pas• throu~n the •v-year at 90°C point, and then aging complete cables at several temperatures, withdrawing them periodically and testing for dielectric withstand at 2,200 VAC. In at least one BIW Cable Test Report (Exhibit h), however, a flame retardant crosslinked polyethylene was used to represent a non­flame retardant polyethylene material. Verbal confirmation of this difference was obtained in Exhibit o, but Draka Intercable

Page 9: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

••oraadua J. Henley to M. Jt.imbrell April 16, lttl Pat• • of 7

(formerly BJW Cable systems, Inc.) has not c:ontirmed this in writing to date.

The shifting of the Arrhenius line is justified in one of the BIW Cable Test Reports (f~xhibit. i), based on a stateaent that the resulting Arrhenius plots tor various values of retained elongation were •essentially straiqht and parallel." This saae justificati.on was also presented verbally in Exhibit o tor two other BIW Cable Test Reports (Exhibits i and j). Exhibit i is unique aaonCjJ the six BlW Cable Test Reports in that it presents elonqat ion curves as well as the resulti.nq Arrhenius plots (all of the other BlW Cable Test Reports only give the final Arrhenius line which passes throuqh the 40-year at 90°C point). This additional data may qive insight to the application of the BIW aqinq aethodology and the central issue for the possible reportable event.

Reduction of the data presented in Fiqure 2A ot Exhibit i apparently does not result in the plot shown in Fiqure 3, as BIW states that. it does on page 5 of Exhibit i. Calculations of the activation energy reading the data from Figure 2A and using the Systea 1000 for activation enerqy detenllination show the following results:

25\ 50t 75%

0.92 ev 0.96 ev 0.98 ev

'l'hese activation energies are significantly less than that shown by the Arrhenius plot in Fiqure 3 which is calculated by the System 1000 as E, • 1.14 ev. Thereto; , it does not appear that the data in Figure 2A can be used to generate the same activation energy as that shown on Figure 3.

The possibility exists that BIW used the elongation data from Figure ?.A to plot an initial Arrhenius line, then shifted this line manually to the left to pass throuqh the 40-years at 90°C point. If so, the resulting line represents something beyond the end-of­lite condition that the data in Fiqure 2A would support. For example, the data fro11 Figure 2A for 75l loss of elongation in fact only supports approximately a 4.9-year life at 90°C (Exhibit p).

By uainq the Arrhenius line derived fro• elongation tests and plotting the results of dielectr·:c withstand tests, BIW's aging methodology compares mechanical properties with electrical properties. Electrical properties typically do not correlate well

Page 10: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

••or and ua J. Ben 1. •Y to M. l i.liliJ: ell ~pril 16, 1tt3 Paqe s of 1

for cable performance in service. Re(.:ent.ly, this tact. was confirmed by SAND91-1766/2, which tested the same BlW Bostrad 7E EPR/CSPE cables, among other EPR cables, under aqinq and accident conditions. Page 2 ot this report concluded that "elon<Jation is the best condition monitoring method", and also that "electrical measurements were not effective for monitoring residual life ... Therefore, the data points from dielectric withstand testing above the shifted Arrhenius line does not indicate a siqnificant amount of conservatism in the cable design, if any.

In view of this difference between activation enerqies derived from electrical properties and activation energies derived for mechanical properties, it is significant to note that the data points indicating electrical failures for BIW EPR/CSPE cables in BIW Cable Test Report 8910, Figure 2 (Exhibit q) form a line with a much lower slope than the Arrhenius line which passes through the 40-years at 90°C point. The System 1000 calculates an activation energy of Ea • 0.63 eV for the three failure points, which are all above the drawn Arrhenius line (Exhibit p).

Therefore, this investiqation reveals that the six BIW Cable Test Reports which seem to support the same methodoloqy may have a fundamental misunderstanding between the meaning of an end-of-life condition and the accelerated aging rate. The application of this misunderstandinq, through usinq the acti vati.on energies derived from these reports, could result in an unsafe condition by the premature failure of safety related equipment.

Further investigation at Draka Intercable is required to retrieve backup data which can deteraine whether this is a reportable event under 10 CFR 21 and constitutes a substantial safety hazard. Since this issue has a large potential impact upon the qualification of BIW cables at a large number of u.s. nuclear plants, it is recommended that the NRC pursue the evaluation with Draka Intercable.

As a precaution pending further investigation, UESC will withdraw all BIW aqing data in the System 1000 (Library Code Numbers 060-838 and 121·91, Exhibits band c, respectively), notify all customers of the System 1000 of the withdrawal of this data, and ask them to assess the impact, if any, on their safety related equipment. UESC will also attempt to determine the use of the activation energies from these Library Code Numbers and contact the affected client(s), if any.

JCH: jh

Page 11: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

Meaorandua J. Hen 1 ey t<:. M r i n,r., e J l Apr j l 16, 1993 Page 6 of 7

u·(w/c): 'I. Harw,;··~, W. craiq, f;'. Martin, ~. Morr.is, B. Messitt, ,J. Smith, ,J. f:nt:;un, C" Lndlcott, F. Gtay

Page 12: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

UNITJJ) ENIJHiY SERVU'ES ('OPPOHATJO~

MEMORANDtJM

'l'O: M. K.imurell / lJA'l'J:<: 4/i/':JJ ' J/

Guy I;ndicolt1 f'ROM:

SUBJECT: SYSTEM 1000 QA Concerns, BIW Cable Entries

REf'F.~t~NCE: 1 ) Memorandum f'rom R.A. Gray to J.J<. Smith Dated 3/10/93, Subject: Unju~tified Boston Insulated Wire (BJW) Arrhenius Data in the System 1000 Database

2) Memorandum f'rom R.A. Gray to J.t<. Smith Dated 3/19/93, Subject: Additions for Memorandum to J.J<. Smith t'rom R.A. Gray dated March 10, 1993 Concerning BJW Arrhenius Data.

3) Note To R.A. Gray from M.D. Sterian Dated 31 March 1993, Subject: Environmental Qualification of BIW Coaxial Cable.

In further investigatjon of this concern with our customer, Ontario Hydro, we were notified that through a contact they had with BIW, they learned that the Arrhenius line presented in the BJW test reports does not show relevant data. The line drawn through the 40 year point is parallel to a line based on testing BlW performed on PE (Polyethylene) to a predetermined change in elongation. The "Arrhenius" testing that is presented in the BIW test report(s) is based on an electrical property of the material (in this case XLPE- crosslinked polyethylene).

This leads to the conclusion that the Arrhenius line presented by BIW is not only based on a totally different property than that on which the aaterial test data in the report is based, but it is based on a coapletely different 11aterial (PE Vs. XLPE). See the enclosed letter (Reference #3) with the appropriate paragraphs circled.

Based on this, it is recommended that all Arrhenius data presented by BIW in their test reports should be thoroughly questioned, if not totally eliminated, from System 1000.

Enclosure

cc: R. Martin J. Smith R. Gray W. Hight C. Harris

Page 13: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

--==::==:::::===-":=--=:::c::::..-=.:c=-· =========.=.=J~. ~===========~~~:~~~::::~:::=

f y},.LI K IN-SERVICE £0 PROJECT MEMORANDUM

Oat~: March 10, 1993

TO: J . K . Sm i t h

FROM: H. A. Gray (~/JJf~·

SUBJECT: Unjustified Boston Insulated Wire (BJW) Arrhenius Data in the System 1000 Database

'l'be assessment for BIW Xl.JlE insulated coax cable at OHIS NGS ( 5. ex. 01) uncovered certain System 1000 database errors and unsubstantiated data from the cable manufacturer. Due to the uncertainty of the data, it could not be used in the assessment process.

Arrhenius plots are developed by testing at va.ri.ous temperatures until a pre­defined failure criteria is reached. In other words, an Arrhenius plot is generated based on failure points. The system 1000 "Arrhenius Data Calculation Worksheet•• tor BIW XLPE insulated cable with Chloroprene uses four analytical points as the "time to tai Jure" points to generate the Arrhenius data (Attachment 1). These tour points (Yl through Y4) &r~ not failure points. These points are in fact random points in time where the test samples were removed from the oven, subjected t:o a dielectric proof test ot 2200 volts, then after successfully passing the test returned to the oven for continued aging (Attachment 2, third paragraph). Therefore, the System 1000 data entry points do not represent an Arrhenius relationship but appear to be a "backfit" to an arbitrary line. This is an unacceptable practi.ce and the System 1000 database entry is invalid.

The pre-existing Arrhenius line appearu in BIW Reports B9l2, B915 and 8916 (Attachments 3, 4 and 5 respectively). In each instance, there is a note stating "slope derived from prior aging test data". This prior data has not been provided to date (requested from BIW). Additionally, the lines in all three cases are parallel. This depicts the same slope and activation energy for each material which is highly improbable due to the differences between Flame Retardant Crosslinked Polyethylene Insulation with Neoprene/CSPE Jackets (Report B912), Ethylene Propylene Rubber Insulation with CSPE Jackets (Report 8915), and Flame Retardant Crosslinked Polyethylene Insulation with Neoprene Outer Jackets only (Report 8916). The validity of the sue Arrhenius line being applicable to all the different materials is highly questionable.

ATTACUM~ from system 1000

1) Material Aging and Radiation Effects Library Arrhenius Data Calculation Worksheet for library code 060-838

2) Library Code 060-838 page 86 (BIW Report W B916, 3) Library Code 060-838 page 68 (BIW Report ~ B912, 4) Library Code 060-838 page 40 (BIW Report W 8915 1

5) Library Code 060•838 page 87 (BIW Report W 8916,

cc: R.s. Martin G.W. Endicott M. Kimbrell

G.W. Hight D.O. Minor File

page 6) paqe 6, Fig. page 8, Fig. page 7, Fig.

2) 3) 3)

Page 14: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

A1TACIIMENTI

o:t•ateat. R.MII: anr ooUUL ~ .... ~~

Glllt&ldC: CLUBlnet.~·t~c <.."1108fiLDIUO POL~ tftftl CIIW)ItOPRDE

~~~~ l.f.W.

Mtlal U. ctASil,lCATIOI 1 CAllA/Will DIUIAft'*

2.0 ARRH~IU6 ~TlOHS

Tift' T8CPIM!'URI (C) TDII ft> PAIUJU (HilS) IlL I I r ••-

Xl: 110 Yl: 100 12: 150 Y2: 1000 Xl: 136 Yl: .310 X.t: 121 v•: 17520

F.UUIRE PARAICETER: E!.ZCTfUCAL ICATBRlAL tf'HICICN!SS: N,'A

SLDPJC: 1!5753. 0.5290379 IIITERCIPT: -30. 211.t2500299

ACTIVATION ~Y: 1.36 CORRElATION OOEPFICIENT: .9992119731B35J

ARRH1~lUS REFERENC£ PAGE NUM~ER: 086

3.0 RADIATION INFORMATION

RADINI'ION DAMAGE THRFSHOLO LEVf;L: 3. 8E5

RADII~TIOH REFERENCE LIBR..MY COPE NUMBER: 126-83

4 • 0 TEMPERATURE RATING lNFORMA'l'ION

TEMPERATURE RATING ASSIGNED: 90C SOURCf.; MFR.

5.0 LlUrtARY SOURCE INfORMATION

LIBRARY ('ODE NUMBER A~SIGNEO: 060-838 DATE: KARCH 29, 1984

E.NTEREO BY; . ..fAtJL .JOHNSON ( ' e-) . : ~"' ,.{_1 ( \ \,. ..•.

APPROVED BY: DAVID STINSON

/0~.Y1·~. tul'f

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----------------~-,------·······,·-----·-.. --·--------------------------------·······

Page 15: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

A1TAOIMENT 2 OOOOSG

IV. 411 YEAI< Lin

t•.IW f'LAMf: Rf'TAROAH'J' CROS6L!NI<f:D PULYFTHYLt-:tH:

t,onq· tere physkal a•.png tf'St.t> conducted on 806TRAIJ XL cablf'6 tndicah· life in f"H'f'8fl of 40 years at 90t. This ifl shown by th~ Arrht>nius plot in figurE' 3 for c·ablee 119ed at. 20HC, l80C, 150C, lH)( and 1/lC. Tt>sU; are st1ll 1n proqrf.'Bf!.

Acc••l•'rated aqinq w.,f, pf-dotmed us1ng the />. rhenius tt>chniqut> on f;labs of lru-;ulat 1011 at f ivf' tefit temperat.urf's. Tht· slopt> of ttw Arrhenius curve was found to be 1dentical for any end condition. Becauat> the slope ia constant, Arrheniue theory ie val !dated and a 1 inf' ustnq t.hh slope can be constructed throu9h the point reprf'senttnq 40 years and 90C. Any point CJn the constructed 1 ine will LJe equivalent to a •o yeu, 90C lite.

To himulate 40 year aging, BIW placed cable samples in air oven& at 200(', 180C, lSOC, J36C and 121C. These cables Wf're pE>riod·· ically removPd trom thf' ov~ns at u,., times shown in figure 3, and suhjN·ted to a d~f'lf>ctr ic proof tf>f.d of 2200 volts (twicf' rated volt<'H3f' 1000.) 'l'hf> dif'lf'ctnc tests JHf> in accordanc£> with IU.I. HlJ-1974, rJal /. Ll. Aft('[ 1HHTt•Asfully pas;dnq t.h£· tf3t I

ttw ,;amples wf•r(' ~f'turned to Hw oven tor continued aqing. A6 ttw data clf•arly tndHaH•, tl1f' cablP~ withbtand the proof tef>t voltayr· whPn aqt•d in t'~Cf:'f>~ of tt1at t(•ptP!,t•rH ing 40 year servlct• at 90C. SpP<im•·ns w~>r;• al!'.o subjP.ct•·d to twnd1nq aftf>r aqinq tn ('Jt(f•fiS of thf· •o y.-·ar .or1d1. •nn1nq.

A~ r1qurf' I l.nr:lH a!•·~ .. · ;.L.•· sarnplt·:, at ;ou(, !HOC, l')IV' and l3tJ< haw· alr.-•ady ~:lurpa~~!;(•rl ,·,~· •r· yf•ar t«'(jJlt(•mf·nt When bf'n~ around a 4lJX dlanwtt·r mandH'l, tr.(• flam'' u•tapjant no!ibllnkNI polyf'tily }f'rw Insula• IO'il ~o~lt t.~.l noel t hP vnlt ;,qp proof tf•f,t. T(JfiU; ar (' ('ont 1n111nq at l21C tn cornplf'tP tiH' data .:tt thf' fiVf' lf>St

t f'm pt> r .at u r f> s .

F 1 q I) r '· I d.- m •) n r. t r d t r· ~ t II a 1 H 1 ; T f< A I · X 1 ( •l L l • ;<. 1 i 11 v 1 · a qua 1 1 t H' d • '1

Yhll llff' ;st 90C.

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Page 16: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 17: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 18: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 19: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

tN SfRVICl. tO PROJEC 1 MEMORANDUM

I 'I I

'l ' 1 : '1 ' I :: t], I ' l:

!.:tJBJLl'T: AddiUons 1or M(•fllOldlldUrll to .J.F .. SnllUl from }<.IL <;ray t1att~d Marcil ](J, l9YJ Con< I'! lliliq hlW /\ITlit·TilUS !lata.

RIW Hf.:>fH.H"t N' B9l'l, Rev. 1 dated OPcernller 1984, was n:>v .i PWed and t ound to be in the same category as th£! Unee reports previously cited in the subject mf~mora ndum. 'I'he B 1 W Arrhenius J i ne remains unsubstantiated and .is ouspect to t·emain so. Considering the short amount o1 time available, it is recommended that OH Research Lab proceed with Arrhenius testing on the BIW Coax cable in ot·der to determine an activation (•nf.>rqy value tor the insulation and the jacket protecting the shield. Once these values are detPnnined, the aging and accident simulation data in t hP BlW report~ can bt: US(~d to quality the coax. 'J'his is judged to bP thf· mn!~t time and cost eJtect ivP approach to takr· with Uw ]~ast amount of ri~;k.

cc : l< • ~_; • Ma r·t 1 n G . W. End i cot 1 M . }<j mbn: J l c.w. ll)<cJht t i I r·

Page 20: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 21: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

'. ; ''

n 1DuJ1u;.iatltJ.l•It.~tlill w•:41ihlll tdc: Ba Dunnr, uw meetinr of 1993 Mardl 23 if wu pointed out th.at there is no need to qualify tht cable foe an QtX:fi\UJJl! lr..rnpt".rctturT. of t<JOC Sinoe this is • siena! cablt whic~ convt'y' 11 very low curre.nr (maximum l00ll04A) ttte.e k ao aelf~; the cable will not~· • tempentturt bl&hec than the amble4at tcmpurature, which ill that .,. i$ 48iC. It l& pmpoltld to try to qualify the cable Ulin,g ~~~ u c)(lMWn,c ~ (with lOme ,.....tn added).

Db. DuriA£ e tclcphot~e Qld~un wida IGha ,_.tiiOGOd, tpp1KIIdon qlncct wUh BIW, il wu leamed that BfW tau ...S u UUIUII way fcJr BQ ... f1l thek Clblet:

11Mty ha.,. tMted tome PB • ....,. .......... • .... ...-w. "'- 6ey be.ve cltn'lk • Plf'llel ~line'........., ........... 90'C..,... poh1l w......., dlffcnn amles, tf the c.t points Milt above rb.ia liM.. die Clble waa uaatnld tn bt. •6eQuate f01 a .O~year tif•. Vohqe WiNland, Plldimes after ""'in& lite GIIIJie 011 40I4ia ........,.., wu the..,.. Uled; BIW ~ dliJ u men Wialliw CJI lhc Cllhle ...,.._,. ._ .. 8oftplion teat.

,. lciAd of -.in& ..... fuDJ ,...,. the ...SIIied Ufe, ,..,.,...., ., dtftfnat matadalt. Uftfottun~Miy, .a.,.._. wlao .. w.....,....ln Chis • (,.,. ia Che lace NWftdet) •w eldllr ftlia.t CK IWl OM: WiiiJ8lJ ud lddl.._.. tftfOnnllian Ia • available.

.... ing the- report 8911, ........................... .., * xuaEeoaxial C:ablt ..,t•Bau"-1 npntms ..,....,. llilll-.. .... JCLPS iniUiafion iJ ·na ......... , tile XLPB iaulation on couial.., ia ..- 'fllnle ...,... •. 1laeonty docamentalion &YIIlable tor 81ial1Jf muial I«mabk.k iooltHIId Ia lrus 2 rllhc 101 _,...liD: .,.. • poiata for Ibis cEle are mattced with .....-.

Be. I& lt&ID'Il Chat the insulltiaa of BIW aoulal Oilble It • wry table material; oonsidlftna tile data fnam fit.l of 1e1t report 8917:

.. The aclivatiOrt tMtD (t\lt nlllld 10 dle (..Uu.Uiied) lane drawn by BIW rt1a&a to • value of0.66 eV, a WI}' low value(~) for XLPP... E~ UJiaa Chit low value, in 01'Ger to jUitify 40 )'01111 a.t ~the""-'...._ tbauld have'-" qed (or IS II houri at II~; it wu .,.. for 101Nl21000 houf1 chua J.J liiDianctJ:,

• '1\e towest AE listed far XLPE Ia fhe ~ 1000 data Mnk it 0.89. Looklft& at the fig. 2 in 8911 we oaly ...... the .,.... • •u• (wbida ildudel bending the Olbk aft« acil& ana N"'))t a to .;;sw v J, I.e Ilia& aone IJClUft! aua • UU.«J ttoun • t WC) Md tbe AB of0.89, would justify a QURIWed Ufcaf:ZU )'11(1 at 50\':.

Bd. H~t. none of this -a•nc wu pcr{onned in cmjunction with ~ radiation and ~Cddeftt exposure testing; that&Jifll wu only portonned for l681lou11 at 12~ (fi&.6 in 81W npon 8912). In Older 10 jusuf'y the qulllfled life or 410 yean, Ike inldlation ttCCds to ltawe an AE of 1.18 wbkh is noc jusbfted an)'Wbart.

For th&t RWM, d,erin& • lllOOtiq on 29 Mard\1993 b«Mil!lll P. V. Cas&aldo, R.S. MaRin lAd N.D. Sklrian it wat decided to Ilk Mr. A"*"'. Oatario H}ldro ~.to find by at.s Cbe IKlivation ~ n( lhia mh&c. 11tit Ia eapecliiBd to ld 6 • 12 moniN

It is er.~ that (for lhc ,..... lilted in Be) tile MtiYitioft GROI'£Y will prove to be lUper thaa 1.18 and in that cue, Chc LOCA testa petformod by BIW Qluld be: w.Jidali!d and no fw1hcr tests wifllx~ rcqui~ on this able.

I .t; ·

Page 22: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

'".. f' :f , , I j Jjl .)"},-•' . f 1i'

JV ()urwr C! tckpLntw omve..atiun with 1om Ti\llli2i on 29 Mwc.h 1993. he S~AU:!d that it " mlp(lrtan! lh.<~! thr JM~t"l t~lso ktqJ iu. insulatinr, JlfOPI!I'Jties otheJwi~ <:Urrt:"..tll liklps and a apurtou\ rcudor l!!JI 'nu!d l'.appeu

A'fl a •e~ult. Mr. Arumd Wa5 rcques-' co abo esuabbsh the AE of U~C cable Jacket.

Bf. Meanwhile, BIW w.u abo_.... to uk U. fwmlllaUoP nwabciJ of abe QOQlPCJUild UMd

In fMftUfac.turlnt: the: oabk, in the ltope ._by matdlin& chU compouu aumbtl with edacn IIV&ilable in dutn hanks, tht aoti.,...._, l'lld8f eould be establi.thld. Du.rins a ~ ~ w1Ch Mr. John JeanRIGI'IIJCl aa 29 Nan* 1991, he.._. CMl BIW UIC their own formulations; while he Mll.ftld 1m1t ....._. numbetl (i.e. Cl8 for lwadon ud 320-'JI009-402 f« tbt }tcbt) ~ do Rot matdlay bewn eompouad PutnlKn.

C. lldi&Uoo iQli.JJ!; <.a. 'l11ele coa•ial abies art oaly u.d for aonwsyiq lhc li&Mll from tbe ion dlanaberJ. 111ef laave llmUar rou~tngs tn aU , ... ..., -.dons, dlus IMIId aal tJc (lu.liflld tor tile "WOI'It ~· CXJndition1. Nick StowoiVTCNII Uolandlr WCR IWid tiOOIIP to uk for • CJIIcutdoe for the tpeoUic ama wha-t lhote ..,,... .,. ..,....., ud the.......,. wu:

- 66 Mrads entegrated ckMe duriJt& nomud ....., ewer 40 )'CIU'\, .. 15 Mradr. Rem and 0.~ Mradl <Jamma dua~na the fint 2~ houn uf ~ CORditions, - 3~ Mrads Beta and 2 Mfl.ds Gamma for 90 days of aocilbu + post l«ident eoaditioM. Since 1 pRrt of aheae cabl•, whea tt.y oon.neot to the icwl chambeR u UI1JliU(f.dDd t..

rovtin&, the Bell radia.tioo amnot be dilooua&ed.

(]J. ll follows that during UlciU opcntill& hfe tad main miaioa CirK, whiob was )II)' OOGICIVICivcly estimatod to be 16 taoura. the cables will be IUIJ.jccted tD 81.~ MJ~tk. thus a. than tbc Vlllut: vruvaf by (Qtl.

<A;. lf ~hart tli the ioaent tQ alto Ult the ablea for long-dme ~. chey will be IUbjeclod to 103 Meads. Since Che cable was provea by tests to widlstaftd 100 Mrads (radiltion ~ was stopped withoot Mtinc any clamac), it is •IUClltCd tD ea:llftd the wau1tl of the teata perionned CO 103 Mta<b .. If ~beE ....atJ CIRnot be e&tendod, the operan should be asbr.1 .., ,..,..; "''"' WUilUU Uk: iuu UIIIUeMN UNUUQAI W.iMt Ute: WM i.:i u.,, vi ..nc ;.u Oa.y poi(~ IGOidmt period.

J L ( ..... .JJ, (!+\\··<':, "(.A, ,of lL•L'\

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oc: P.V.Castaldo H09 A20 ItS. Manm H09 A24 W. Seidl H09 821 f) K Amuu1 feR f( c{ t'( t?.. ,.,,« ·~

biwinf

T0Tf4.. P.84

Page 23: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 24: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 25: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

&.1.1 110 Dl 150 Ail 13.6· xc, ,121

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4. 0 ~·!IIPEI<ATt.1RB RATING II(J'()RICATIOM

YIXPikA'J.'tJRI RATI1fG ASSIGHIDz tOC SOURC!: KFR.

5. 0 LIBRARY SOURCE INPOIUCATIOH

L!IRARY COD! MUM8ER ASSIGNEDt 060•838 DATE I MARCH 2i, 1984

mrrDID BY a ~A~ JOHNSON

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Page 26: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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RADIATION REr'PENCE LIBRAKI COD! NUIIBER: 126-83

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SOURCE: MJ'R.

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LIIIIARY CODI IIUICID AUIGNIDI 060•838 DATI: JULY 27, 1983

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Page 27: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

. , ~·- '·

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Page 28: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 29: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 30: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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the ~·-for eiti•ti• ..• , nu:Mnttr for tO ,.ar tftsta11at1on .,. Miftl carrttd ocat tn tM •• .,....,. • in NPOf't 8910.

llcHH of the exce11ent agtnt d\ancter\at1cs of to-S.U •tar1a1, perto...anc• equt1 tc or eJ.C.Hdtng that repot'ted ln rwport 1910 11 eJCPI(ted.

1M data potnu tndtcat1ve of thh and add1 t1ona1 data points will be reported as tM.y art obtJined.

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Page 31: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 32: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

7E ao&ftlAD CABLES

FLME A•O RADlATIOII RESIS1'ANT CUL!S FOil lWOCLEA~ POWER PLANTS

REPORT NO. B 91 ';

NOVEMRfJ.' l91l0

Page 33: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

I

tV. 40 Y!AI LIP!

Lont t.er• a9 inCJ t_eeta conducted on cabl•s tnd tcete 1 lt fe expectancy tn eaceaa of 40 ~sari at toe for IIW'a ethylene propylene rubber inaulation.

A9in9 waa ac~elerated uaing the Arrheniua technique deacribed below.

!be ag1n9 char act.er iat lei of BIW • a ethylene propylene rubber aa1d CSPE ~u.~u"~' were found by •onttocing the elongation of these cuapounda after eapoauae iu Jtfferent te•peraturea f~r varying tiaea. ~ia waa done by placin9 bundreda of aaaplea ot each coapound in ovens at 1;1c, ll6C, 150C, 180C and 20t'C, and after preacrib~d intervalet reaoving aeaplea troa each oven and aeaauring u1t111ete elongation. fbe reaulte of elonqet1on v•r•ua tiae at each teaperature ue ehown in Piqure 2A.

The data in Piqure 2A 11 tranaforaed into a te11perature versus t iae relet ionah ip by aelect in9 var ioua cond it tone of elongat 1on and plotting the locus of tiae "nd teaperature or. aeai-loqar ithllic paper (Pigure 28). It can ~ seen that for any selected value of elongation, tne curve• ar• eaaentially straiqht and parallel. Arrheniua theory in the teaperature range inveati9ated ie validated by the atrai9ht line, t.e. the straight linea deaonatrate a conatant rate of reaction in the region. Since a rate of a9ing haa been det~rained for the cable, then for any defined aervice condition, a line havinq the predeterained 191n9 rate (elope) can be conatructed through the poir:t representing the servtce condition, and all points on the line will be equivalent to the det1ned eervice condition.

Elonqat1on, how~ver, cannot be related directly to the ab1l1ty of a cable to function for a q1ven ti11e and temperature. HovPver, tf a cable can wlthatand dtelectnc proof testing after aqtng, lts llfe 16 verified. TheretorP, to df'lftonetr&te queldied lth, SIW ages cablf' samples to the destcf.'d serv1ce condlttons and, after th16 aqtnq and bend1n9 to 40X ceble OD, dtelPctrtcally proof tests th• cable.

BOSTRAD 7E cabl ee have bePn type tested to qual1 fy for a 40 year, 90C service llfe. Thte has bePn done by construct tnq a ltne wtth thf> slop• shown tn Ftgure 2B throuqh the de&ired 40 year, 90C p<nnt, as shown in P 1qure 3. To stmulatf th l8 end 11 fe, BIW placed cablf' aa111pleJ tn au ovens at 200C, 180C, 150C, 136C • .nd 1/lC. These cables were removed from the ovens per1odically and subjected to a dtelectrlc proof test of 2200 volts (hnce rated voltaqe + 1000 in accordencf' w1th IEEE 383-1974, para. 2.3.2.). After 6uccesafully w1thstand1nq the test, the eaaples were returned to the oven for cont1nued aq1nq •

- ~ -

Page 34: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

000038

IV. 40 YBAI LIPI (Cont.)

BOI!IAO 71 cable aaaplea ated in ••c••• cf the •o year equivalency requtr ... nt at 200C, liOC, lSOC, ll6C and 121C, were bent around a •ox diMeter undrel and witbatood tbe voltat• proof teat. !heae tyre teat• deaonatrate tbe capability of the cable to function after bein9 aged to the equivalent of •c yeara life at tOe.

- 6 -

Page 35: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

I I J

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Page 36: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 37: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

8!W CO-.liA! ANO TRIAJ!At CARl rc.

l1ilil Cdr,lr> SJstrm•,, ln f,J Hay Stref't

:1n-:. ton, '·'A<..!.ac"·lSP.t! '>

Page 38: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

·-J . ..........,,

1~. 40 YEAR LIF£

£vidence of 40 yetr 11ft 1t 90C 1s shown by the following 1nform.tion and figure 2 for RJ1t1conductor cc1bles with 1 fllllt retardant trade of eros•­linked polyethylene ir.sulet1on. Although tht crosslinked polyethylene on coa~ial and tr1ta111 clb1es 1s not • fl ... rttlrdant grtde, its lift ts c~arab le to that of the flafftf retardant 9rtdt. This 1S being conf1 rwd by aging tests now in pro9re~s o~ coa•1al cables.

The test progratlll conducted •or the flame retardant gra::te 1nd presently underway for the co1x1a1 and triu111 grade of crosslinlced polyet.,ylene in-

sulation is descr1be1 below.

8!W's cross11nked polyethylene 1nsulat1on has an indicated l1fe of over 40 yeari at 90C according to ag1ng tests currently in progress. Test dtta are being evtluated by the Arrhenius technique, using a slope determined by aging tests previously conducted by BIW. When thE' aging slope 1s dtter­m1ned for meterh1, a 40 year condition 11f'e can be established at t .. 1~ serv1ce ~rature, as shown on Ftgure 2.

Aging of BIW's flame retardant cross11nked polyethylene is betng conducted at f1ve temperatures: 200C, lBOC, 136C and 121C on 2/C and 7/C cable samples. The cables hove heavy-duty neoprene overall jackets. The data on Figure 2 show that the 1nsuiati'n is intact, and cables are operable up to and above tt.l:! ,·equi red aging times at 200C, 180C, 150C and 136C, since any point on the curve represer.ts the equivalent of 40 years life Dt 90(. Tests are made periodica1 1y lt twice raterl voltagE' plu~ l,COO volt~ cr 2,20G volts, between condu,·tors and be·ween conductors and shield for these nOO volt cables. When the agin9 reaches tht 40 year liff' curve, the cable~ are straightened out, given a 40x bend, straightened out aga1n and tested iit 2 ,2CO volts.

NOTE· l!St levf'l is tQOO v0lt~ on coaxial cables w1th rrosslinked polyethylene insulaUon.

With the indicated life of at least 40 ye•rs at 90C already proveu at lOO(. 180C, 150C and 13~C. 1t 1s to be e~pected that the aging data still 1n pro­gt~ss at 121C w11. further substantiate this performance. We might point out that since data on other insulations show that a test voltage ot 1,200 volts or less 1s suffic1e~t to detect cr!ck~ or flaws, passing at 2,200 volts shows excellent 1nsuiation integrity.

..,

Page 39: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

'

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Page 40: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

BOSTRAD IL

~!616TAMT CAaLES

fOF USE IN

t •• : '.·. I . A ! . : l' 'i y ~~ ·~ :~ !>t . . " ( ''; h<~v S•: P~·t

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Page 41: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

-~ ..

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OOOOSG @

IV. tO YEAR LifE

BI• rLAU R!TARDAWf CJ088LI.I£D POLYITHYLIM£

on BOSTR~D KL cables This 1~ shown by th~

at 200C, 180C, l'>OC,

Lonq · t~ r• phye ica 1 aq i nq tea te conduc t~d indicate life in ~•cess of 40 years at 90l. A rr h P n 1 u e p 1 o t i ,.. f' 1. q u n• 3 t o r c at, l e • aq e d l36C and l2lC. Tt>st~; cUP r,ttll in progress.

Arc«>lerated a<pnq Wf'IS perfouned us1ng the Arrhenius lf'chnlque on slab& of 1n!'iulat1nn at flvP U'>f>t tf'mperature6. Tht~ slopt' of thf• l'rther.tub c1nvr· wo!ls found to btP 1dPnt1cal for any E'nd coodltion. RecduSt· ttu !ilOpf· 1s cons~ ant, Arrhenlll!'i thf'Oty IS val idatf'd and a l~rH· us1nr.J ttHs slope can l1f' consttucterl throuqh t.he po1nt re-presPntlnq 40 yf'cHr; and ~OC. Any point on thE> constructt•d llnP

wlll l1f' t•qulval••nt to a 40 yf'ar, 90C llft>.

To s1mulat~ 40 yt•ar c.q1nq, BIW placE>d cablf' samples in au ovens at 200C, 180(, l'JOC, l36C and l21C. These cables wt>re pE>nod­lcally n'.'move<l from thP ovf'>nS at q,e times shown in figure 3, and sub-i· ·ted to a du·lt>ct r 1c proQf test of 2200 volts (twin~ rated vol + 1000.) Thf' di?lectnc test£> are 1n dc<·ordance with JEEt JID-1974, par 2.3.2. "ftf'r sucr.efHduliy pa:--;;nnq thr· tc;t, the 6amplf'S w•·rf:' rPturu·d tn thf' ovPn fnr <:<l:ltinut>:'i aq,nq. As th(• data clParly :ndtcdtt', t;,t· cablP~> w1d1~,tand thf' pro<d tf'!.t

voltl''I(JP when a·~'·d in PlH'f'·s~, nf tnal rt•prP',Pnt 1ny 40 year sPrVlCf

at 90C. SpP!lifif'fi~, "*' IP ll<;r; sub)PCtt·d tq t•~>nrllrl'l nftr•r a1.4inq 1n

e)(c~>c:;s nt th•• 40 yr•<Jr ·ondl' loninq.

A~i F1qurt> l H1rll' dtt·f,, <-.l •• f' sampl~·s at :2001, !HOC, j',tJ~: .wd l H.t. havf' alrPady surp~!·;~~H1 'tt-~·· 40 yt>ar rf'<.,JltPfTif•nt. Wlwn t'~nt aanuwi a 4CJ)( dlalll•'~*'r :nand!' t, lr,f• f~arr.'' P'tar'iant cror;sllnkH1 polyr,t:ly lf'n• rr,f,•,llo1'J(dl ..,ith•;!r•t•d tl;l' '-''llt .rp· P'""f IP'.I Tf'~-t·· ,)(t

,,,,·,tJntliL'1

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t ~·m p.-• r at 11 r .-. s .

f'lq<ll" I rlf'm•)nr.tr<~'•·:, that H(i'T\-!P,(j XL ··dhlP: 1\av• _,, qudl:IH•d 4t!

Y f' (I I } Jf f> .~ t If(: (' .

Page 42: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 43: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

..

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REVISIONS

UV. NO. DATE UUTIALS OESCRIPI'IOM OF CHANGE

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QA APPROVAL: ICUltV •IJCBRELV~ () . ~ Plt.D/DATI J,~, I l1'1~.

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Page 44: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

JIIOIIJ, t:.3.

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Page 45: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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PAILUU PAI.A.UTIR: KICIWIICAL

ILDPI: 12110.543753'5

IIATIIUAL ftiCDUI: • 0•1

INTERCEPT: ·17.15315135

CORRELATION COEFFICIENT: 0.18952631

AltllBDIUS R£Ya'3UDICI PAGE NO.: 2

3.0 RADIATION INFORMATION

IADD.nOII t'BR.BSIIOLD LEVEL: 1. 016 RADlAt'ION J.IFERENCE PAGE NO. : 36

a&DDnOI IZP'DDICI LlBURY COllie OJI-Il

•. 0 TIKPDATURI MTDIG ltfPOIIIATlOII

IOURCI: nm. 5.0 LIBRARY SOURCE IlfFORKATlON

LIIIARY COOl NONBII ASSIGHID: 121-11 DATI: 03/15/11

APPIIDVBO BYr ~~·it-1fi1J

- DIGITAL INGINEIRI»G, IBC. PORN NO. 3.3-J -

I I

Page 46: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 47: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

• IIW BOSTRAD

7r CABLES

FLAME AND RADIATION RESISTANT

CABLES FOR NUCLEAR POWER PLANTS

MAY, 1975

Report No. 8910

BOSTON INSULA TED WIRE & CABLE CO.

65 Bay Street Boston, Ma11achueetts 02125

Page 48: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

IV. 40 YEAR LJ FE

BIW's ethylene pr-opylene rubber insulation/ Bostrad 7 chlorosulfonated polyethylene jacket system has an indicated life of over 40 years at 90C according to ag1na tests curr~1tly in progress. Test data are being evaluated by the Arrhenius technique, using a slope determined by aging tests previously conducted by BIW. When the aging slope is determined for a matert.al, a 40 year condition line can be established at the service temperature, as shown on Figure 2.

Aging or BIW's ethylene propylene rubber/ Bostrad 7 chlorosulfonated polyethylene is being conducted at five temperatures: 200C, l80C, 150C, l36C and l21C on 2/C and 7/C shielded cable samples. The cables have heavy-duty Bostrad 7 chlorosultonated polyethylene overall jackets . The data on Figure 2 show that the insulation is intact, and cables are operable up to and above the required aging times at 200C, 180C, 150C and 136C, since any point on the curve represents the equivalent of 40 years life at 90C. Tests are made periodically at twice rated voltage plus 1,000 volts, or 2,200 volts, between conductors and between conductors and shield for these 6oo volt cables. When the aging reaches the 40 year life curve, the cables are straight­ened out, given a 40x bend, straightened out again and tested at 2,200 volts.

With the indicated lite of at least 40 years at 90C already proved at 200C, 180C, 150C and 136C, it 1s to be expected that the aging data still in progress at l21C will further substantiate this performance. We might point out that since data on other insulations show that a test voltage or 1,200 volts or less is sufficient to detect cracks or flaws, passing at 2,200 volts shows excellent insulation integrity •

- r::: --

Page 49: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

Ill s.... ::l 0 --

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t YR. 2/C and.f/C rlL AWGjCab~es I

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Page 50: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

BIW COAXIAL ANU THIAXIAL CA8LfS

FLAME AND RADIATION RESISTANT CABLES

FOR NUCU:AR POWER PLANTS

CROSSLINKED POLYETHYLENE INSULATION

REPORT NO. H917 1 HEV. 1

DECEMBER 1984

BIW CABLE SYSTEMS, INC. 65 BAY STREET

Boston, Massachusetts 02125

Page 51: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

\...,.... 'J

IV. 40 Yf:f..h f IF>

Lonq-term tny·,, L """'""'"on cables tndirat •. • ltl·• "' ''''"''" o[ 40 y e .:u ~~ a t ·; d' , · t t i· H'i ' :, c r c ~o s 1 i n ked po 1 y e t hy l en e i n !.l u LH 1 on .

~

At:cel•rated •·Jln•,l on •dabs ot crosslinked polyethylene was performed ooy the Arrhentus technique at five test temperatures. The slope of the Arrhenius curve wao tound to be Identical for any end cond!E1on. Because the slope is constant, a line using this slope can be constructed through the point representing 40 years an~ 90°C and any point on this line will be equivalent to a 40 year, 90 C life (Figure 2) •

Material tXpe tests gn multi-conductor cables aged at 200°c, 180°c, 1S0°c, 136 c and 121 c show a projected life on the Arrhenius plot in Fi9ure 2 of •o years at 90°C with considerable mar;in as represented by the passing points above the line. The cables were removed from the oven periodically and subjected to a dielectric proof test of 2200 volts (twice rated voltage • 1000 volts). After successfully passing the test, the samples were returned to the oven for continued aging. As the data In Figure 2 clearly indicate, the cables pass a bend test after aging to the equivalent of 40 years at 90°C and continue to pass upon additional aging.

Life of 40 years at 90°C tor the crosslinked polyethXlene Insulation A• additionally confirMed on coaxial cables aged at 150 C, l21°C and 110 C, Fi9ure 2. These cables were tested at 3500 volts (rated voltage + 1200 volts). Mechanical considerations preclude accelerated agtng of coaxial cables at higher temperatures.

Figure 2 is offered as evidence of 40 year life at 90°C. Figure 2A

SinCe a rate of aging has been doteralned for the Insulation (&lope of llnm In Figure 2), then for any defined service condition, e line having the predoterelned aging rate (slope) can be constructed through the point representing the service condition, and all points on the line will be equivalent to the defined servtee condition. In Figure 2A, Lines B and C have the saae slope (rate of aging) ~s Line A from Figure 2. Consequently, cables aged for 668 hours at 121 C as In Figure 3 have • projected Alfe of 40 years at 54 C (Line C) and cables aged for 168

0 hours at 150 c as In Figure 4 have a projected life of 40 years at 74 c (tine B).

)

..

Page 52: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 53: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 54: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

B IW BOS'I"RAD CX COOXIAL MID 1'RIAXlAL CABLES

I

' I I

FIA"\E AND AA.DIJ\TIOO RESISTANT CABU:S

REPORT NJ. B918, REV 1

oo:oorn 1984

BIW 0\BU: ~~ DC. 65 Bay Street

Boston, Massachusetts 02125

Page 55: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 56: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 57: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 58: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

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Page 59: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

,. • 1 ~ •)' ' , \1

B I W CABLE SYSTEMS, INC. 'j ~!i. • '.' I' , t' _ H>, 1! I I';~-~ Iii i ::

Junt>?/, l9f3

T01S77o Mr. [. A. Goldenberg Bechtel Power Corporotion P.O. Bo:>- 396~ San francisco, CA. 94119

Attention: Mr. Basant Oilodare

Subject: Job No. 11760. Pot~t1and General flectric Company ~ Trojan Nuclear Power Plant Environmental Qualification Program BIW Report 8915. Bostrad 7l Cables Doc. Control No. T015522

Gentlemen.

We are pleased to furnish the additional information that you requested ir. reft>nmce to BIW Report 8915 dated November 1900.

l terr. 1

Item 2

Item 3

Radiation Certification

Because the B915 Report 1s based upon many tests, the radiation certifications are voluminous and. as a practical matter, are retained at BJ W. We certify that the dose levels are as stated in the report and that the dose rates are in accordance with I£H 383~1974. All irradiation was conducted by Isomedi>:, Inc. Parsippany, New Jersey ~sing a Cobalt 60 source at a dose rate not greater than 1 ) 10 rads per hour.

Synergistic [ffects -

BIW has not identified, rtor is aware of any synergistic effects in our cable materials. We have, therefore, chosen to do sequential age conditioning.

Au toe 1 ave Equ i prnent

Appendix I (attached) provides:

a. The physical arrangement of the cable and test equipment description in accordance with IEEE 383-1974.

b. The type and location of all environmental and cable monitoring sensors of each variable per IEEE 383-1974.

Page 60: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

T01a770

Mr. l . A. Go ldenber9 BH:htel Power Corporation JunP ?7 ~ 1983 raqp lwc

A 11 pressures and temperatures a t'f monitored by gauges and thenno­mPters which are calibrated throughout the entire range of the test·-· r,arameters by using standards traceable to the NBS.

Pressure gauges penetrate the wall of the autoclave and arE at least 1 inch into the environment. The thenmometers penetrate the wall of the autoclave and are at least 1 inch into the environment.

Item 4

Item S

I tern 6

We are providing written procedures for qualification testing in accordance with 1£[[ Standard 383. These test. proceGires were used for ell test 1 ng 1 n Report 8915 and meet the requirements of both IEH Standard 383 and IH£ Standard 323. The foll~ing are enclosed.

a. Long Tenm Aging Procedure for IEEE Standard 383.

b. Thennal and Radiation lxposure lest Procedurf. for 1£[[ ~tandard 383.

(, LOCA Test Procedure for Il£[ Standard 383.

d. Vertical lray name Tpst Procedure for IHE Standard 383.

For the lOCA simulation tests in Report 8915, the excursions to maximum temperature and pressure are as follows.

Figure 5 - Cable environment raised to 340('F and 115 psi (both excursions) in 10 seconds maximum.

Figure 6 - Cable environment raised to 340°F and 105 psi (both excursions) in 10 seconds maximum.

figure 7 - Cable environment raised to 34ocr and 110 psi (both excursions) in 10 seconds maximum.

Figure 8 - Cable environment raised to 340°F and 110 psi in 10 seconds maximum.

Single Conductors Broken Out of Multiconductor Cables -Sacrificial Jackets

BIW has successfully conducted LOCA tests on both s1n~le conductor and multiconductor cables. The jacket on a multi conductor cable serves as mechanical protect1on during installation end we acknowledge that it may be damaged during thenmal conditioning or simultted OBE's. The cables w111 function electr1ce11y without the outer jackets.

Page 61: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

Mr. I . A. bt' 1 (1t•niH·I (i

Let:hte l Powt·' (Ofln'ltilt i 011

clunP ?J', ]G;< · fagf 1 t,tPt

T015770

fvidencr:· of single conductors successfully passing OBl qualifi<.ation tests is shown by figure 8, page 17 in Report B915 and by the attached Reports 76C009 for a 1/C 112 AWG (aL1e and 758025 for a 1/C 16 AWG cable. The jackets on 1/C cables also undergo damage during testing and are not r·equired for the electrical operation and the cables t~till function electrically without the jacket. This serves as t>vidence that the individual conductors of a multiconductor catle will also function electrically without jackets.

Item 7 Figures 15 and 16 ;n Report 891& show that unaged cables have excellent perfonmance properties after long term immersion for 48 weeks ( 336 days) in 90°C water by the e 1 ec troendosmos is nlf'thod and 52 weeks (364 days) in 75°C water by the lM-60 method. Long terni water ilflllersion tests are typically perfonned only on unaged cables.

As shown by Figure 7 in Report 8915, a cab 1 e aged to the equivalent of 40 years at 90°C (figure 3, Report B915) performed well throughout the period of 161 days in LOCA during which time the cable was continuously in contact with moisture. The boric acid spray was applied for the first 24 hours and mineral-free water was applied there­after through 161 days. Afaer aging to the equivalent to 40 years at 90°C, 2 x 10 rads gamma radiation, and 161 days in contact with moisture during LOCA, the cable had sufficient elongation, after a 40X bend, to pass a 2400 volt a-c dielectric test for 5 minutes while immersed in water. This shows the excellent water resistance of aged and irradiated cables.

figure 8 in Report 8915, and Reports 76B025 and 76C009 furnish additional evidence of the ability of aged and irradiated cables to withstand a wet environment under the severe LOCA environmental conditions of IEEE 323 (Figure Al cycle for Reports 768025 and 76C009 and Table A2 cycle for Figure 8).

We certify that all test data in Report 8915 applies to the cables in P.O. N-18988. Report 8915 presents prototype test data for cables with the same insulation and jacket materials in strict accordance with lEE£ 383-1974 and IEEE 323-1974.

Please contact us if you have any additional questions.

Very truly yours,

~~::H5,1NC.

a~~·~ Applications Engineer

Page 62: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

l. INTRODUCTION

LONG TERM AGING PROCEDURE FOR

1_EEE STANDARD_.]_§)

The method described in this procedure shows how accelerated aa1ng r ~~ ---

times and temperatures are determined for organic insulation systems. Thia method relates cable perfcrmance to actual service conditions and ia baaed upon the verification that the insulation material itself behaves in a manner Which pennita the uae of Arrhenius techniques.

2. VERIFICATION OF ARRHENIUS TECHNIQUE

Prior to the performance or any teats on cable apecimens, a lone term aging program is conducted to determine the behavior or the insulation material being considered. The details are given below.

2.1 Sample Preparation: A sufficient number of standard lSTM tensile bars are cut from molded sheets of the material in accordance with the procedures of ASTM ~12, Paragraph 12.

2.2 Sample Aging: The aaaplea are taken in aroupa of thrte and placed on wire hangers. The hangers are then placed in circulating air ovens at a minimum gr three temperature• at least 10 C apart, and including 136 C. The samples, again in groups of three. ere removed at suitable intervals. After a time period not to exceed 96 hours or leas than 16 hours, t~e tensile strength and elongation are measured and recorded. The teats at each temperature are carried out to zero elongation.

2.3 Sample Test1ns: Normal industry tensile teat methods for test1n& rubber and plaatic which employ crosshead apeeda of 20 lnchee per minute are only suitable for materials-having elongation• creater than 201. For this reaaon, a croashead speed or 2 inches per a1nute 11 uaed aa indicated in ASTH 0638 (Speed C) for eater1ala havtnc leas than 201 eloncetion. Results obtained using the lower speed ere represented by the broken line of Figure 1.

2.4 Plotttn& of Elonaation Curves: For each teat temperature the elongation of three samplea is plotted at each time interval until zero elongation is reached. Curves obtained for all temperatures are placed on 1 single greph, auch as that shown in Figure 2.

Page 63: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

2.5

2.6

2.7

Arrhenius Plot: from the data as presented ln­second fam1ly of curves is plotted for constan elongation. This is shown on the Arrhenius plo 3. If the resulting lines are straight this is an indication of a constant rate of aging. The parallelism of the lines representing the different end points (elongation) indicates that the aging rate is constant aod independent of the particular end points. The linea must be both atraight and parallel if this method of determining preaging is valid.

Aging Plot for Cable: A line having the elope determined from Figure 3 is drawn through a defined end point such as ~0 years at 90°C. The line shown in figure ~ represents the time and temperature relationship equivalent to the end of life condition.

Cable Sample Pr·eparation: Prior to undergoing air oven aging cable samples having the insulation for which the Arrhen1us plot was developed are prepared in the following manner:

{a) The samples approximately 18 inches in length have 2 inches of jacket removed from each end and the insulation removed from 1/2 inch of each conductor. The conductora are then splayed out and held in this position by packing with uncured silicone rubber. This is done to prevent electrical test failures at the cable ends due to handling.

2.8 ~able Aging: Three cable samples are placed in circulating air ovens at three or more suitable temperatures at least 10°C apart, and including 136°C. These samples are removed at designed intervals and subjected to a dielectric test of twice the rated voltage plus 1,000 volts for one minute. At that time which corr~aponds to the Arrhenius plot for the test temperature the cable sample is given a bend around a mandrel having a diameter of 40 times the cable 0.0. It is then subjected to a dielectric test in water of twice the rated voltage plus 1,000 volta for one minute. If the cables aucceaafully withstand this test voltace after the bend they are put back in the oven and tested periodically until failure. Teat points are shown in Figure 4. It ia the intent of this procedure to demonstrate that cables aged to the equivalent of the end of life condition still w11 hatand the electrical test requirements.

Page 64: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

350-4---

... ... .. -. ... 0 $000 15,000

TIM((Urtl IIG. I

,./ ,

106

'

,,; I

10 "---200~---1-00 __ ___

·c (.i •c:cale) FIG.3

z·~o~~r-~~~~--~

2 200...,_....._. _ __,.,__ __ _ .... c ~ l.SOIH--+-----+--------9 ... !0() ....... --41~--...,._ ______ _ ~

0 5000 10,000 U,OOC' 20,00

TIMECHrtl FIG,j

106

Yr,90'C Pt.

105

Ill

104 .. :: -... I -...

103 -Failure eTtit Paint

102

i Test Cont.

FIG.4

Page 65: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

'l'ELEPHONE CONTACT REPORT OF J. C. HENLEY 1 ,}//

PHONE NO.: 800-666-7580 t412 lfi WORI ORDER NO.: N/A

DATE OF CONTACT: April 12, 1993

COMPANY CONTACTED/ADDRESS: Draka Illtercable (BIW Cable Syatus, Ine.), 9 rorqe Park, Franklin, KA 02038

PERSON CONTACTED/TITLE:

SUBJECT: Aqinq Metho4oloqiea tor BII Cables

DISCUSSION:

Mr. Jeanmonod was very helpful and provided the following information concerning BIW cable tests in the mid to late 1970's:

There was disagreement among cable manufacturers at that time about which Arrhenius failure parameter was most applicable to natural aging of cables in service. As a result, BIW elected to perform two types of aging tests. First, they performed elongation tests on aged coupons of materials to draw the Arrhenius curve (standard IEEE method). The elongation tests showed basically the same aging rate (slope) regardless of the value of elongation selected up to 100%. Second, they tested complete cables (conductor, insulation, shield, fillers, and jacket) by aging them at five different temperatures and periodically withdrawing them for subjection to a 2,200 VAC dielectric withstand test. This aging, removal from aging, and dielectric withstand test cycle was repeated for durations up to and beyond what the elongation curve predicted as a 40-year life and resulted in the data points shown on the plots. Since dielectric withstand is accepted as proof of a cable's integrity, this showed the cables had considerable useful life beyond a 40-year life predicted by the Arrhenius curve.

The Arrhenius curves in both BIW Reports 8915 (EPR) and 8916 (CLPE­FR) were derived from testing on coupons of the exact material compound as the cable insulation addressed in the report. However, Report 8912 (CLPE-NFR), on coaxial and triaxi.al cables, used a CLPE-FR material to draw the Arrhenius curve. Mr. Jeanmonod admitted that he could not justify the conservatism of BIW' s selection of a non-flame retardant material to represent a flame retardant material.

Supporting data and notes from the period of testing are sketchy but may be available through a search of the company archives. John had a limited amount of data available to him in addition to the test report, but he had a qood recollection of the tests since he was personally involved in the testing programs at that time. He said he was willing to confirm these facts in writing.

John said they have had no siqnificant questions from the nuclear industry regarding their methodology (everyone seems to agree with

Page 66: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

contact Report of J. Henley to John Jeanaonod, BIW Cable systeas April 12, 1993 Paqe 2 of 2

it), but they have had many questions about the 8912 report's use of the flame retardant material test data for the non-flame retardant. They have no data for the non-flame retardant material. The decision was .aade years aqo not to perform that testing.

CONCURRED: ________ ----------·-------------

TITLE:----··---- ___ ---····---·-·-·-·--·-·------··---

Page 67: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

! )t I, J I f F I ~-~ ,.. I~ f 6 Digital Engineering SYSTEM 1000, Program Revision 14

Ethylene Propylene Rubber - BIW Report B915 Figure 2A

Purpose: Check Expected Life at 90oC - 75\ Elongation Performed by: J. Henley Date: 04/l~J/Y3 Time: 18:28

Verifjed By: Date:

lnput(s) SLOPE: INTERCEPT:

Tf.:MPt:RA'I'URF: UN l'I'S 90.00 c

Result(s): EXPECTED LifE;;:;

11413.0000000 -20.7650000

\ OF SERVICE LIFE 100.000

4.94220e0

Units

y

Page 68: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

L ~~~~~~ll; 1~_,~ ) (; f- ~)h

Digital :Engineering SYSTEM 1000, Program Revision 14

Ethylene Propylene Rubber - BIW Report B915 Figure 2A

Purpose: Check 060-838 Activation Energy -Performed Ly: J. Henley Date: 04/15/93 •rime: 13:21

Verified By: Date:

lnput(s)

TIME UNITS 112.00000 H 360.00000 H 840.00000 H

5720.00000 H

Result(s): SI...OPE = I NTERCEP'l' = ACTIVA'l'ION ENERGY -CORR. COEFFICIENT -

TEMPERATURE 180.00 150.00 136.00 121.00

UNITS c c c c

1. 14130e4 -2.07650el 9.83500e-l 9.65410e-l

ev

Page 69: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

? ' ,, . I' 1">~;1! ) rA /K; Piqital I:nqineerinq SYSTEM 1000, Program Revision 14

Ethylene Propylene Rubber - BIW Report 891~ Fjgure 2A

PlHJlOSE·: Check 060-B 3 B Activation Et1E'Y qy ' Performed by: .J. Henley Date : n 4 I J '; 1 !-J l 1' i nlt" : J n : 2 ',

Veri11ed By: Date:

Input (s)

'IJMI: UNITS 108.00000 H 297.00000 H 7f,9. 00000 H

496/.00000 H

Result(s): SLOPE "' JNTER.CEPT ~"

ACTJVATlON ENEHGY -CORR. COEfflCIENT -

'I'EMPERA'l'tJHE liN 1 'l'S 180.00 c J~Jo.oo c 136.00 c 121.00 c

l.ll680e4 -2.02980el 9.62320e-1 9.~J9440e-l

I :, ,. I)

I

eV

Page 70: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

Diqj1aJ Engineering SYSTt~M 1000, Program Revision 14

Ethylene Propylene Rubber - BIW Report 8915 Figure 2A

Purpose: Check 060-BJB Activation Energy - 75%.AElongation Performed by: J. Henley Date: 04 I 15 I 9 3 'I' i me: 13: :n ~I' n ,,.. .. ",

VPrified By: Date:

Input(s)

TIME UNI'l'S 104.00000 H 256.00000 H 800.00000 H

3840.00000 H

Result(s): SLOPE = INTEI<CEPT -· ACTIVATION ENERGY -· CORR. COEFFICIENT -

TEMPERATURE UNJT8 180.00 c 150.0(1 c 136.00 c 121.00 c

l.07260e4 -1.93400el 9.24300e-l 9.6~470e-l

ev

Page 71: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

, J , I ;·, I " ) II I .

I

Digital F:nginc::!ering SYS'J'I::.M 1000, Program Revision 14

BlW Report B91~, Page 8 - EPR Insulation

Purpose: A~.-t1vat;uL l.Ht1-J; D··tuJrjrh1t,~,r. Performed by: J. Henley Date: 041 J 219 3 Time: 1 .l : 4 t.

Vt'llf H'd By: Datf~:

1 npu t ( s)

TIME UNITS 230.00000 H

1800.00000 H 5833.00000 H

18001.00000 H

Result(s): Sl.A)PE ""· 1 NTt:RCEP'J' "­ACTIVATION ENERGY = CORR. COEFFICIENT -

TEMPERATURE UNITS 18 0. 00 c 1':.0.00 c 136.00 c 1:() .00 c

1.32890e4 -2.38930el

l.l4!>10eO 9.99640e-l

ev

f l' ./' ·d ..

(

Page 72: t/ (• .J 1-----~-.-···'· --···- · Gray dated March 10, 1993 Concerning BIW Arrhenius Data d. Note to R.A. Gray to M.D. Sterian Dated 31 March 1993, Subject: Environmental

; j · I , I , •I . !

Digital I·.rv:prwf·! lnq SYS'I'r:M 1000, l'rognun Revision 14

R.lh' U'f</('Sf•t: Dlf:LEC'J'RlC WJ'I'HS'l'AND FAiLURES Nl '2,)00 VAC

Puq;osp; ('Al.CULJ-.';L .t•''l ;·.,; IJ 1 )N Jt;Ef<;:, !HUM BJW l·ll J.l h'tJ(!

Pertormed by: J. IHNUY Date : o 4 jlt i '! ' T lllle: 1 4 : ;1?

Vet if ied B;r: Date:

lnput (s)

'lJMl llN.lTS t;r,). (!()000 11

1000. U\IOUU H 31:\Ht .. 00000 H

Resu H u.q : SlJWI:. INTERCEPT ACTIVATION f;NERGY CORR. COt FFI Cl ENT

TEMJ1 l::RATIJI-\f UN .I 'l'S ~·oo. oo c 1110.00 \. 1'10.00

I . l 0 J 1 Of' 3 ··Y. o~, J ~:~Of~O

f.:, • ') 9 J 4 Oe ~ 1 9 • 8 9 :> 1 Oe · J

.::V