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TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007: Automotive Advanced High-Strength and Other Specialty Sheet Steel Products for the Automotive Industry Processing and Properties of TRIP Steels Microstructural Evolution During Continuous Galvanizing and Final Mechanical Properties of High Al-Low Si TRIP Steels ..................................................................................................1 M. Gomez, C. Garcia, A. DeArdo, and D. Haezebrouck Applications of Niobium to Automotive Ultra High-Strength TRIP-Aided Steels with Bainitic Ferrite and/or Martensite Matrix ..................................................................................................15 K.-I. Sugimoto, and M. Murata Dynamic Behavior of TRIP and DP Steels in Tension at Different Temperatures ...................................27 S. Curtze, M. Hokka, V.-T. Kuokkala, and P. Peura Processing and Properties of Advanced High Strength Specialty Steels I Functional Improvement of Automotive High Strength Steel Grades by Niobium Microalloying.............................................................................................................................................37 H. Mohrbacher Effect of Overaging on the Properties of Dual Phase Steel during Continuous Annealing ......................49 X. Tao, S. Birosca, H.S. Kim, and B.C. De Cooman Microstructural Evolution in a Complex-Phase Steel ................................................................................61 S. Sarkar, M. Militzer, W.J. Poole, and F. Fazeli Dilatometric Study of the Quench and Partitioning (Q&P) Process..........................................................73 S.J. Kim, Han S. Kim, and B.C. De Cooman Effect of Aluminum Content on the Mechanical Properties of Dual Stabilized Ti-Nb Interstitial Free High Strength Steel (IF-HSS)...........................................................................................85 H. Kang, C.I. Garcia, K. Chin, and A.J DeArdo © 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

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TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Automotive

Advanced High-Strength and Other Specialty Sheet Steel Products for the Automotive Industry

Processing and Properties of TRIP Steels

Microstructural Evolution During Continuous Galvanizing and Final Mechanical Properties of High Al-Low Si TRIP Steels..................................................................................................1 M. Gomez, C. Garcia, A. DeArdo, and D. Haezebrouck Applications of Niobium to Automotive Ultra High-Strength TRIP-Aided Steels with Bainitic Ferrite and/or Martensite Matrix ..................................................................................................15 K.-I. Sugimoto, and M. Murata Dynamic Behavior of TRIP and DP Steels in Tension at Different Temperatures ...................................27 S. Curtze, M. Hokka, V.-T. Kuokkala, and P. Peura

Processing and Properties of Advanced High Strength Specialty Steels I

Functional Improvement of Automotive High Strength Steel Grades by Niobium Microalloying.............................................................................................................................................37 H. Mohrbacher Effect of Overaging on the Properties of Dual Phase Steel during Continuous Annealing ......................49 X. Tao, S. Birosca, H.S. Kim, and B.C. De Cooman Microstructural Evolution in a Complex-Phase Steel................................................................................61 S. Sarkar, M. Militzer, W.J. Poole, and F. Fazeli Dilatometric Study of the Quench and Partitioning (Q&P) Process..........................................................73 S.J. Kim, Han S. Kim, and B.C. De Cooman Effect of Aluminum Content on the Mechanical Properties of Dual Stabilized Ti-Nb Interstitial Free High Strength Steel (IF-HSS)...........................................................................................85 H. Kang, C.I. Garcia, K. Chin, and A.J DeArdo

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Processing and Properties of Other Advanced High Strength and Specialty Steels II Critical Review of Hot Stamping Technology for Automotive Steels ......................................................99 D.W. Fan, H.S. Kim, S. Birosca, and B.C. De Cooman High Strength Air-Hardening Steels for Automotive Applications.........................................................111 U. Diekmann, C.-M. Rogall, T. Saeuberlich, and A. Frehn Characterization of Nano-Sized Precipitates in Microalloyed Steels ......................................................123 J. Lu, H. Henein, and D.G. Ivey

Manufacturing with Advanced High Strength Steels I: Fracture in Bending and

Edge-Stretching Metallurgical Aspects Regarding the Stretching Edge of Advance High Strength Steel ........................135 C. Chiriac The Susceptiblity to Shear Fracture in Bending of Advanced High Strength Sheet Steels.....................145 A. Hudgins, D. Matlock, J. Speer, J. Fekete, and M. Walp Influence of the Edge Conditons on the Hole Expansion Property of Dual-Phase and Complex-Phase Steels..............................................................................................................................159 A. Karelova, C. Krempaszky, E. Werner, T. Hebesberger, and A. Pichler Influence of the Shear Cutting Process on Damage in Laboratory Dual Phase Steels Developed for automotive Application....................................................................................................171 A. Dalloz, A.-F. Gourgues, A. Pineau, J. Besson, and T. Sturel Some Aspects of Thermo-Mechanical Properties of High Mn TWIP Steels Investigated by In-Situ Infrared Thermography...........................................................................................................183 L. Chen, S. Birosca, Han S. Kim, S.K. Kim, and B.C. De Cooman

Manufacturing with Advanced High Strength Steels II: Simulation, Springback,

Joining, Tool Materials Modeling and Characterization of High Frequency Induction Welds in Advanced High Strength Steels .........................................................................................................................................195 Y. Adonyi, V. Jurko, and A. Lesko Sources of Variability in the Fatigue Strength of Spot Welded Specimens ............................................207 H. Kang, J.J.F. Bonnen, and R.M. Iyengar Multibody Joining: A New Method for Spot Joining of Sheet Materials................................................227 M.P. Miles, K. Kohkonen, B. Siemssen, R. Steel, S. Packer, and Y.S. Sato Tool Steel Selection for Cold Forming of High Strength Steels Based on the Stress Distribution in Tools ................................................................................................................................235 R. Hernandez, M.D. Riera, D. Casellas, I. Valls, B. Casas, and J.M. Prado

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Auto/Steel Partnership 20th Anniversary Symposium Formation of Ceramic Layer on Steel Strips by Combined Method of Cladding and PEO....................245 H.S. Dehghanian, M.H. Shariat, A. Deghan, and H. Daneshmanesh

Automotive and Ground Vehicles: Applications of Materials to Vehicle

Designs

Advanced Materials and Processes Development and Use of Polyamide 6 for Automotive Safety Restraint System Components .............................................................................................................................................253 M. Huisman, and N. Bokhari Optimization of Engergy Saving Materials and Compressed Insulating Layers in the Automotive Chemical Converters............................................................................................................261 E. Litovsky, V. Issoupov, J. Kleiman, R. Latham, F. Lacin, A. Kotrba, and K. Olivier Study of Intrusion Bending for Steel Tubes with Thin Wall Thickness..................................................273 H. Naoi, N. Kitakami, M. Mizumura, and Y. Kuriyama

Armor/Armored Vehicles

Function-Oriented Design of Inoovative Composite Materials for High Speed Impact .........................285 H. Wang, Y. Cui, Z.-D. Ma, and D. Rose

Automotive and Ground Vehicles: Materials and Processes for Vehicles

Aluminum: Alloy Development and Microstructure

Texture Variation in a Heat Treated Heavily Deformed Aluminum Alloy 6061 ....................................297 S. Adedokun, J. Schwartz, and H. Garmestani

Tribology, Surfaces, Lubricants and Coatings I

Review of Motor Vehicle Ap-lications for Functional Thermal Spray Coatings....................................303 R. Betts Development of Thin Film Coatings for Dies Used in Aluminum Pressure Die-Casting of Automotive Components .........................................................................................................................313 J. Lin, B. Mishra, S. Myers, S. Bhattacharyya, J.J. Moore, and P. Ried

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Cast Iron Effects of Refractory Coatings on the Performance of a Chemically Bonded Sand System at Elevated Temperatures.........................................................................................................................325 S. Ramrattan, and A. Abdelwahab

Automotive Light Metal Castings: Technology and Applications

Melt Treatment, Control and Casting Process Development

Effect of Applied Isostatic Pressure during Solidification on Static Mechanical Properties of Lost Foam Aluminum Castings...........................................................................................................333 P. Chitalapati, J. Griffin, R. Griffin, and H. Littleton Studies on the Surface Oxidation of Molten Aluminium – Silicon Alloys Using Laser as a Probe ........................................................................................................................................................345 K. R. Udupa, and S. Chatterjee Visualization of the Muliphase Flow in the Lost Foam Casting Process by Neutron Radiography and Image Processing.........................................................................................................359 X. Luo, and D. Penumadu

Integrated Computational Materials Engineering, Computational Materials Design

and Applications Establishment of Nucleation Model and Microstructure Simulation of Al-Si Alloy for Low Pressure Die Casting........................................................................................................................367 B. Li, Q.Y. Zu, and B.C. Liu

Casting Process Development, Simulation and Modeling

Simulation of Microporosity in Aluminum Castings by Coupling Hydrogen Diffusion with Interdendritic Feeding......................................................................................................................377 G.P. Backer, and Q. Wang Mold Filling Simulations for the Semi Solid Metal Manufacturing Process...........................................389 G.P. Backer

Casting Process Development, Simulation, Modeling and Optimization

Study of Microstructure and Mechanical Properties of Continuously Cast AA6111 Strips Following Horizontal Single Belt Casting (HSBC), Rolling and Heat Treatment ..................................399 D. Li, M. Isac, and R.I.L. Guthrie

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

The Role of High Pressure Die Casting in the Expanded Use of Aluminum and Magnesium for Automotive Applications ...............................................................................................409 J. Yurko

Alloy Development, Microstructure Evolution and Phase Transformation

Microstructural Examination of Directionally Solidified Mg Alloys Confirming Mg-Rich Phase Equilibria of Mg-Al-Ca .................................................................................................................423 H. Cao, C. Zhang, J. Zhu, G. Cao, S. Kou, and Y.A. Chang Characterization of Combinatorially Prepared Mixed-Phase Magnesium-Aluminum Thin Film Alloys ..............................................................................................................................................435 C.H. Olk, and D.B. Haddad

Casting Process Development, Material Properties and Performance

The Effect of Hydrogen Level, Sr Additions, and Grain Refinement on the Spatial Distribution of Porosity in 319-Type Alloy Castings ..............................................................................445 J. Zindel, and L. Godlewski Regarding Influences of Production Processes on Material Parameters in Fatigue Life Prediciton (Dendrite Arm Spacing, Boundary Layer Model)..................................................................457 M. Meise, W. Aichberger, H. Riener, and H. Dannbauer

Microstructure Evolution, Phase Transformation and Light Metal Composites

Refinement of Eutectic Grains/Cells in Near-Eutectic Al-Si Alloys.......................................................469 H. Liao, M. Zhang, H. Wang, G. Dong, and G. Sun Influence of In Situ TIB2 Particles on the Microstructural, Mechanical, and Abrasive Wear Behavior of A356 Alloy.................................................................................................................483 S. Kumar, V.S. Sarma, and B.S. Murty Development and Testing of Chilled Aluminum Alloy-Corundum Particulate Composite for Automotive Applications ...................................................................................................................491 K.S. Shekar, and J. Hemanth

High-Density Hydrogen Storage for Automotive Applications: Materials

and Methods

Tanks, Analysis, & Systems Engineering Effects of Metal Hydride Properties on the Performance of Hydrogen Storage Systems .......................503 T. Johnson, D. Dedrick, and S. Jorgensen

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Zinc Coated Steel Sheets

Zinc Coated Sheet Steels Session 1 Changes in the Mechanical Properties of Galvanized TRIP Steels .........................................................525 E.J. Petit, B. Bolle, M. Gilles, I. Sr.iti, J. Gilgert, and Z. Azari Processing of TRIP Steels in Continuous Galvanizing Lines: Surface and Subsurface Oxidation Study .......................................................................................................................................535 Y.F. Gong, S. Birosca, H.S. Kim, and B.C. De Cooman Effect of Continuous Galvanizing Heat Treatments on the Microstructure and Mechanical Properties of Al-Si TRIP Steels ...............................................................................................................547 E.M. Bellhouse, and J.R. McDermid Properties of Galvanized and Galvannealed High Strength Hot Rolled Steel.........................................557 R. Fourmentin, J.R. McDermid, V. Gertsman, S. Dionne, and F. Goodwin Characterizing Reactive Wetting Kinetics of High-Mn Dual-Phase Steels in Hot-Dip Galvanizing Baths....................................................................................................................................569 R.J. Meguerian, and J.R. McDermid

Zinc Coated Sheet Steels 2

ALEUTEC, a New Zinc Coating for Steel ..............................................................................................579 W. van Ooij, J. Zervoudis, and G. Poag Mechanism and Growth of Dross on the Submerged Pot Hardware in Galvalume (GL) Bath ..........................................................................................................................................................591 A. Varadarajan, and B.S.-J. Kang XRF as a Method for Measuring Coat Weight Thickness of Various Conversion Coatings on Steel or Aluminum..............................................................................................................................599 S. Fess Author Index ............................................................................................................................................613 Subject Index ...........................................................................................................................................617

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Electronic and Magnetic Properties

Ferroelectrics and Multiferroics

Magnetoelectric Composites Fabrication of Thick Hard Magnetic Coatings by thermal Spray Technologies .........................................1 B. Dzur, C. Zimmer, and G. Thomas

Multiferroics, Nanoscale Structures and Properties

Dielectric Studies on Ferroelectromagnetic SrBi5–xLaxFeTi4O18............................................................7 S.V. Suryanarayana, E. Venkata ramana, and T.B. Sankaram

Domain Switching, Phase Transition, and Thin Film Phenomenon

Integrated Technology of Decoupling BST Thin Film Capacitors............................................................17 N. Kamehara, and K. Kurihara

Ferroelectric Materials, Characterization, and Properties

Structural and Electrical Properties of 0.38Bi(GaxSc1–x)O3 - 0.62PBTiO3 Piezoelectric Ceramics ....................................................................................................................................................25 Y. Jiang, C. Du, B. Qin, Y. Chen, X. Yue, D. Xiao, and J. Zhu Lead-Free Sodium Potassium Niobate Piezoelectric Ceramics and Middle Frequency Resonator ...................................................................................................................................................35 Q. Chen, L. Chen, Q. Li, D. Xiao, and J. Zhu

Poster

Dielectric Properties of Sr2+ and Sn4+ Co-substitued BaTiO3-Based Solid Solution Ceramics ....................................................................................................................................................43 S.N Yun, X.L. Wang, D.L.Xu, and H. Li Pb(Zr0.52Ti0.48)O3 Films Grown on Nickel Substrate by Pulsed Laser Deposition...............................53 Y.H. Yu, M.O. Lai, and L. Lu

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

General Topics in Electroceramics

Electroceramic Materials Processing and Characterization Non-Lead Based Ceramic Film Processing by Laser Transfer for Improved Integration and System-in-Package..............................................................................................................................63 T. Chakraborty, R.E. Miles, and S.J. Milne Effect of Ca Substitution on the Microwave Properties and Lattice Vibration of Ba(Mg1/3Ta2/3)O3 Ceramics ...................................................................................................................73 T. Shimada

Sensor Materials and Performance

Metal-Oxide Nanoparticle Gas Sensor Arrays ..........................................................................................85 E. Beach, M. Andio, P.A. Morris, and S. Stewart

Sosman Symposium - Electroceramics II

Characterization of CeO2/Al2O3 Nano Composites for SOFC Applications...........................................97 R. Chockalingam, H. Giesche, and V.R.W. Amarakoon

International Symposium on Dielectric Materials: Design, Preparation

and Applications

Composition Processing, Micro-/Nanostructure, and Property Relationships Controlled Designing of Fine Particles at Molecular and Nano Levels ..................................................109 D. Uskokovic

Ferroelectric Relaxors, Single Crystals, and Novel Compositions

Novel Class of Capacitor Materials .........................................................................................................121 G.D. Singh Growth, Characterization and Transport Properties of PbxZn1-xS Mixed Crystals ...............................127 B. Rajam, E. Nagabushan, M. Nanabhushanam, and K. Yadaiah

Mechanism, Modeling and Designing Issues for Piezoelectric Materials

Effect of Acceptor (Mg) Concentration on the Electrical Resistance at Room and High (200°C) Temperatures of Acceptor (Mg)-Doped BaTiO3 Ceramics ......................................................143 S.-H. Yoon, M.-H. Hong, J.-O. Hong, Y.-T. Kim, and K.-H. Hur

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Temperature- and Stress-Dependent Scaling of Ferroelectric Hysteresis in Soft and Hard PZT Bulk Ceramics..................................................................................................................................155 R. Yimnirun, S. Wongsaenmai, R. Wongmaneerung, M. Un ruan, N. Wongdamnern, A. Ngamjarurojana, Y. Laosiritaworn, and S. Ananta Interfacial Polarization in Liquid Phase Sintered Ceramic/Glass Composites........................................167 E.P. Gorzkowski, M.-J. Pan, B.A. Bender, and C.C.M. Wu

Ferroic Materials Synthesis and Properties: A Joint Session with Electronics

Division's General Session Optimization of Dry Powder Deposition Parameters for the Production of Dielectric and Magneto-Dielectric Composites ..............................................................................................................175 S. Nergiz, and G. Kizilta Dielectric Characterization of M and W-Type Barium Hexaferrite Prepared by Multiple Sintering Techniques ...............................................................................................................................189 P. Shepherd, I. Harrison, and K.K. Mallick Fabrication of Photonic Assemblies for High-Gain Antennas ................................................................201 G. Mumcu, S. Yarga, K. Sertel, and J.L. Volakis Thermoelectric Power, Dielectric and Magnetic Properties of Sr-La M-Type Hexagonal Ferrites .....................................................................................................................................................209 A. Singh, K. Singh, S.B. Narang, D. Ravinder, and R.K. Kotnala

Synthesis and Properties of Thin Films, Thick Films, Laminated, and Multilayer

Materials and Devices BaTiO3 Thin Films on Metallic Substrates: Fabrication, Microstructure and Property..........................223 J.C. Jiang, Z. Yuan, J. Lie, J. Weaver, C.L. Chen, B. Lin, V. Giurgiutiu, R.Y. Guo, and A. Bhalla

Dielectric and Piezoelectric Materials and Composites: Applications and Processing Microstructure and Dielectric Properties of Barium Strontium Titanate Derived by Sol- Gel............................................................................................................................................................233 H. Manuspiya, G. Panomsuwan, H. Ishida, and A. Bhalla

Poster

A Two-Stage Solid-State Reaction to Lead Nickel Niobate Powders.....................................................249 O. Khamman, R. Yimnirun, and S. Ananta Synthesis and Characterization of Magneto-Dielectric Composites for Radio Frequency Applications .............................................................................................................................................261 S. Farhat, M. Hawley, L. Kempel, and S. Balasubramaniam

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Effect of Nb-Doping on Electrical Properties of Pb(Zr0.52Ti0.48)O3 Ceramics ...................................269 P. Ketsuwan, Y. Laosiritaworn, S. Ananta, R. Yimnirun, and D.P. Cann

Perovskite Material Engineering

Nano-scale Engineering B: Thin Films and Dielectric Response

A-Site Substitution Controlled Dielectric Dispersion in Lead Free Sodium Bismuth Titanate ....................................................................................................................................................279 S.V. Suryanarayana, M. Raghavender, G. Prasad, and T. Bhimasankaram

Spintronic Materials and Devices

Spintronic Materials II

Room Temperature Ferromagnetic Dilute Magnetic Semiconductor Zn-0.95Co0.05O .........................295 Q. Liu, C.L. Gan, and G.C. Han

Structure-Property Relationships of Multifunctional Oxide Thin Films

and Interfaces

Charaterization and Application of Metal-oxides Interface Engineering in the High-K Dielectrics Gate Stacks .................................................................305 S.J. Wang

Oxide Film Synthesis and Integration

Strain-Enhanced Dielectric and Ferroelectric Properties of Pb(Zr0.8Ti0.2)O3/Pb(Zr0.2Ti0.8)O3 Multilayer Thin Films Without Buffer Layers ............................315 H. Liu, X. Gong, J. Liang, X. Li, D. Ziao, J. Zhu, and Z. Pu

Poster

Porous Titania Films Prepared in Aqueous Solution...............................................................................325 Y. Masuda, T. Kimura, X. Hu, X. Meng, K. Kato, and T. Ohji Magnetic Energy Distribution in Polycrystalline Sputtered CoCr Magnetic Thin Films........................335 J. F. Al-Sharab, J.E. Wittig, G. Bertero, T. Yamashita, J. Bentley, and N. Evans Author Index ............................................................................................................................................343 Subject Index ...........................................................................................................................................345

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Energy

Degradation of Materials for Application in Nuclear Power and Waste Management Systems

Degradation of Materials for Application in Nuclear Waste Management Systems I

Repassivation of Alloy 22 Crevice Corrosion at 90°C ................................................................................1 A.K. Mishra, and G.S. Frankel

Degradation of Materials for Application in Nuclear Waste Management Systems II A Study of Corrosion and Stress Corrosion Cracking of Carbon Steel Nuclear Waste Stroage Tanks.............................................................................................................................................13 C. Scott, F. Gui, C.S. Brossia, J. Beavers, G. Edgemon, H. Berman, K. Boomer, and G. Frankel Electrochemical Formation of Passive Film on Carbon Steel and Its Interaction with Hydrogen Peroxide ....................................................................................................................................25 W. Xu, X. Zhang, and J.C. Wren

Degradation of Materials for Application in Nuclear Power Systems

Modelling of the Oxide Film Growth and Layer Restructuring on Stainless Steels in LWRs .........................................................................................................................................................39 I. Betova, M. Bojinov, P. Kinnunen, T. Saario, and K. Lundgren Behaviour of NiCr Coatings under Different Environments .....................................................................53 N. Bala, H. Singh, and S. Prakash

Poster

A Passive Film Formed on Alloy 600 as a Steam Generator Tubing Material .........................................67 D.-J. Kim, H.C. Kwon, S.S. Hwang, and H.P. Kim

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Encapsulation and Immobilization of Hazardous and Nuclear Wastes Using Ceramics, Glass and Other Materials

Use of Analytical Techniques in Nuclear Waste Disposal I

Key Elements of Characterizing Savannah River Site (SRS) High Level Waste (HLW) Sludge Insolubles through Sampling and Analysis ...................................................................................79 S. Reboul, B. Hamm, P. Hill, D. DiPrete, N. Bibler, and W. Wilmarth Physical and Chemical Measurements Nedded to Support Dispositon of Savannah River Site Radioactife High Level Wast Sludge .................................................................................................91 B. Hamm, S. Reboul, P. Hill, and N. Bibler

Use of Analytical Techniques in Nuclear Waste Disposal 2

Development of a New Zirconoloite-Base Glass-Ceramic for Immobilization of Radioactive Wastes....................................................................................................................................99 M. Mahmoudysepehr, V. Marghussian, J. Javadpour, and H. Kazemian Accelerated Weathering of Fluidized Bed Steam Reformation Material Under Hydraulically Unsaturated Conditions.....................................................................................................107 E.M. Pierce

Energy: Encapsulation and Immobilization of Hazardous and Nuclear Wastes Using

Ceramics, Glass and Other Materials Process Changes to DWPF to Increase Throughput and Incorporate Salt Streams.................................119 C. Herman, D. Peeler, T. Edwards, M. Stone, and M. Smith

Poster

Investigation of LTC SS 316 as Bipolar Plate material for PEMFC Application ...................................131 V. Nikam, and T. Johns

Energy Materials

Characterization Methods

A Micro-Indentation Method for Assessment of TBC Bond Coat Systems............................................141 C. Feng, M. Alvin, and B.S.-J. Kang

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Solar Energy Materials II Evaluation of Ionic Liquids as Heat Transfer Materials in Thermal Storage systems ............................151 M. Zhang, and R.G. Reddy

Energy Materials and Technologies I

A Study on the Synthesis of LiFePO4: A Potential Cathode Material for Lithium Ion Batteries ...................................................................................................................................................161 K.E. Howard, and E.J. Swedberg Growth of Hydrous Manganese Oxides Nanowall Arrays and Their Li-Ion Intercalation Property....................................................................................................................................................173 D.W. Liu, Q.F. Zhang, B.B. Garcia, Q. Guo, R. Champion, G.Z. Cao, and P. Ziao New Processes and Characterization of LiCoO2 Chemistries for Li-Ion Batteries.................................181 J.F. Al-Sharab, F. Cosandey, B. Yakshinskiy, N. Pereira, F. Badway, and G.G. Amatucci Laser Doping Fabrication of Energy Conversion Devices ......................................................................191 N.R. Quick, S. Bet, and A. Kar Effects of Thermal History on the Dielectric Properties of Nanostructured Titania ...............................203 S. Chao, V. Petrovsky, and F. Dogan

Energy Materials and Technologies II

Kinetics of Supercritical Water Reformation of Ethanol to Hydrogen....................................................213 J. Wenzel, J. Picou, M. Factor, and S. Lee Mineralogical Sequestration of Carbon Dioxide through Aqueous Processing of Steelmaking Slag .....................................................................................................................................225 C.H. Rawlins, S.N. Lekakh, V.L. Richards, and K.D. Peaslee

Poster

Processing, Characterization and Dielectric Properties of Hydrothermal BaTiO3 Films on Stainless Steel ..........................................................................................................................................239 S. Chao, V. Petrovsky, and F. Dogan Fabrication of NbC, ZrC and UC-Based Silicon Carbide Matrix Composites for Nucliear Applications Using Polymer Infiltration and Pyrolysis ...........................................................................253 A.K. Singh, and R.P. Singh

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Fuel Cells: Materials, Processing, Manufacturing and Power Management Technologies

Cell Materials, Performance, Degradation, Manufacturing of High Temperature

FCs I Thermodynamic Modeling and Testing of the H2/O2/Ni/NiO System...................................................263 I.D. Kellogg, U.O. Koylu, V. Petrovsky, and F. Dogan

Cell Materials, Performance, Degradation, Manufacturing of High Temperature

FCs II The Properties and Performance of Micro-Tubular (Less than 1mm OD) Anode Supported Solid Oxide Fuel Cells............................................................................................................271 N. Sammes, A. Smirnova, A. Mohammadi, F. Serincan, Z. Xiaoyu, J. Pusz, M. Awano, T. Suzuki, T. Yamaguchi, Y. Fujishiro, and Y. Funahashi

PEM Fuel Cells, Fuel Processing, and Catalysts

Effect of Fuel Conditions on Performance of Novel PEMFC Flow Field Design ..................................285 V.V. Nikam, and R.G. Reddy

Sealing, Contact, Stack Manufacturing, and Balance of Plants of SOFC

Candidate Alloys for Cost-Effective, High-Efficiency, High-Temperature Compact/Foul Heat-Exchangers ......................................................................................................................................295 N. Evans, P. Maziasz, J. Shingledecker, B. Pint, and Y. Yamamoto Development of Candidate Silver Cermet Contact Materials for Cathode Side in Solid Oxide Fuel Cell ........................................................................................................................................307 T.-B. Sheppard, and B.S.-J. Kang

Interconnects of High Temperature Fuel Cells I

Corrosion of Metallic SOFC Interconnects in Coal Syngas ....................................................................317 R.R. Dastane, X. Liu, C. Johnson, and S. Mao The Application of Protective Coatings on Crofer 22 APU ....................................................................331 M.R. Bateni, P. Wei, and A. Petric Electrodeposition of Mn-Co Alloys on Stainless Steels for SOFC Interconnect Application...............................................................................................................................................341 J. Wu, Y. Jiang, C. Johnson, M. Gong, and X. Liu

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Interconnects of HighTemperature Fuel Cells II The Formation of Alumina Coating on Ferritic Steels ............................................................................353 M. R. Bateni, L. Quintero, and A. Petric

Poster

La0.67Sr 0.33MnO3 Coating on SOFC Interconnect by Plasma-Sputtering ..........................................363 C.-L. Chu, Y.-N. Cheng, and S. Lee Glass-Ceramic Seal Stability Study for Solid Oxide Electrolyzer/Fuel Cells .........................................371 M.K. Mahapatra, C. Story, K. Lu, and W.T. Reynolds The Application of a Novel Ni-Cr-Si Coating on Fe-9Cr Steel for SOFC Interconnects .......................381 L.S. Quintero, D. Laverde, M.R. Bateni, and A. Petric Author Index ............................................................................................................................................391 Subject Index ...........................................................................................................................................393

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Fundamentals and Characterization

Characterization & Modeling of the Mechanical Performance of Advanced Alloys: Bridging the Data Gap

Automotive Materials: Keynote Session I

Advanced Simulation Techniques - Exceeding Reality?.............................................................................1 K. Roll

Formability of Advanced Automotive Alloys

Investigation of Temperature and Strain Rate Effects on Material Flow Curve and Microstructure of Aluminum Sheet Metal Alloys .....................................................................................15 S. Mahabunphachai, Y. Usta, and M. Koc Micromechanical Modelling of the Formability of Dual-Phase Steels .....................................................31 C. Krempaszky, J. Ocenasek, V. Espinoza, E. Werner, T. Hebesberger, and A. Pichler Prediction of Springback for a Channel Draw Process Using Different Hardening Models.....................45 A. Taherizadeh, A. Ghaei, and D.E. Green

Characterization of Automotive Aluminum Alloys

Microstructures for Large Elongations in Superplastic Aluminum Materials...........................................57 H. Hosokawa, and K. Higashi

Modeling the Mechanical Properties of Advanced Alloys

Modeling the Influence of Grain-Level Matrix Inhomogeneity on Strain Localization in the Presence of Hard Particles ...................................................................................................................69 X. Hu, D.S. Wilkinson, M. Jain, and R.K. Mishra Stress Response of Advanced High Strength Steels using Tapered Tensile Speciments and Digital Image Correlation Method ......................................................................................................85 J. Mullins, P. Hodgson, and T. Hilditch

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Characterization of Advanced Alloys-I Tensile Response of Titanium at Reasonable High Strain Rates and Temperatures.................................99 M.F. Quinlan, and P. Phelan A Simple Indentation Measurement Technique for Surface Mechanical Property Evaluation ................................................................................................................................................111 C. Feng, and B.S.-J. Kang A Study of Aging Effects on Hardness and Tensile Properties of 2219 Aluminum Alloy .....................119 I. Jabeen, and R. Ahmad

Poster

The Minimum Coefficient of Friction Obtained by MATROLL Software and the Effect of Improper Friction during the Cold Rolling of Steel ............................................................................129 H. Abdollahi, and K. Dehghani

Discovery and Optimization of Materials through Computational Design

Application of Atomistic Modeling for the Design of Materials I

Dislocation Absorption in an Asymmetric Tilt Boundary.......................................................................139 J. Askin, P. Anderson, and R. Hoagland

Continuum Theoretical and Numerical Analyses to Describe the Properties,

Equilibrium, and Kinetics of Materials I A New Method for Simulating Strongly Anisotropic Cahn-Hilliard Equations......................................149 S. Torabi, S. Wise, J. Lowengrub, A. Rätz, and A. Voigt

Poster

Wavelet-Based Local Region-of-Interest Reconstruction for Synchrotron Radiation X-ray Microtomography ....................................................................................................................................163 L. Li, H. Toda, T. Ohgaki, M. Kobayashi, K. Uesugi, and Y. Suzuki

Frontiers in Materials Science: Materials for Sports and Medicine

Implant Performance

Finite Element Analysis of PMJMA Reinforced Osteoporotic Femurs ..................................................175 M.N. Shaw, M.E. Bolander, K.E. Bennet, S. McEligot, M.J. Burke, J.T. Bronk, and D.M. Dragomir-Daescu

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Sports, Prosthetics and Biocompatibility Formation of Biomimetic Porous Calcium Phosphate Coatings on Surfaces of Polyethylene/Zinc Stearate Blends ..........................................................................................................187 J. Drelich, and K.G. Field Tensile Deformation Behavior of Epoxy Composites Reinforced With Three Different Woven Fabrics .........................................................................................................................................199 A.A. Mazen, M.A. Metwali, and N.A. El-Mahallawy

Fundamentals of Brittle Fracture

Environmental Effects

Bond Breaking and the Fracture Process .................................................................................................215 J.K. West

High Temperature Material Systems - Fatigue Mechanisms and

Prognosis

Role of Microstructure and Environment on Fatigue of Ti-Based Alloys and Other Structural Alloys

Mechanical Properties and Microstructure of AlFeSiV-SiC Particulate Composite...............................231 M. Arhami, F. Sarioglu, A. Kalkanli, and M. Hashemipour Thermo-Mechanical Fatigue Analysis of Cast Aluminum Cylinder Heads ............................................239 C.C. Engler-Pinto Jr., X. Su, J.V. Lasecki, X. Chen, and J.E. Allison

Role of Microstructure and Environment on Fatigue of Turbine Engine Materials II Impact of Additional γ' Strengthening on the Strength and Fatigue Behavior of Oxide Dispersion Strengthened Ni-Base Superalloys .............................................................................251 M. Nganbe, M. Heilmaier, and M. Schaper

International Symposium on Defects, Transport and Related Phenomena

Structure and Properties

A Quantized Crystal Plasticity Finite Element Model on Stress-Strain Response of Nanocrystalline Metals ............................................................................................................................263 L. Li, M.G. Lee, P.M. Anderson, E. Bitzek, P.M. Derlet, and H. Van Swygenhoven

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Transport III Quantitative Prediction of Void Formation in Growing Magnetite Scal Formed on Iron at 823 K........................................................................................................................................................277 M. Ueda, and T. Maruyama

Transport and Relaxation

Anomalous Diffusion in Superionic Solids .............................................................................................289 T. Ishii Modification of Crystal Lattice by Impurity Ordering in Gallium Phosphide ........................................303 S. Pyshkin, R. Zhitaru, and J. Ballato

Poster

Atomic Diffusion Behaviour of BF2+ and Boron Implant p+n Junction with Thermal Budget: A Simulation/Analytical Approach............................................................................................311 A.K. Sr.ivastava

Numerical, Mathematical and Physical Modeling Tools for Materials

Processes

Numerical, Mathematical, and Physical Modeling Tools for Materials Processes I FEM Analysis of Weld Distortion in HSLA-65 Steel for Naval Applications........................................319 J. Huang, and Y. Gooroochurn Heat Treatment of High Alloy Stainless Steel Castings ..........................................................................331 J.D. Farren, and J.N. DuPont Numerical Simulation of Kinetics of the Cobalt Gradient Change in WC-Co during Liquid Phase Sintering.............................................................................................................................343 P. Fan, Z. Fang, and P. Prichard

Numerical, Mathematical, and Physical Modeling Tools for Materials Processes II

Finite Element Simulation of the Joining Process of Glass Feedthroughs for Medical Devices.....................................................................................................................................................353 M. Reiterer, B. Tischendorf, and J. Taylor A Cellular Automaton Madel for Grain Growth......................................................................................365 S. Raghavan, and S.S. Sahay

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Studying Tunnel-Like Defect in Friction Stir Welding Process Using Computational Fluid Dynamics........................................................................................................................................375 H. Atharifar, D.C. Lin, and R. Kovacevic

Numerical, Mathematical, and Physical Modeling Tools for Materials Processes III

A Numerical Study of Plasma-Particle Energy Exchange Dynamics in Induction Thermal Plasmas for Glassification........................................................................................................................393 M.M. Hossain, Y. Yao, and T. Watanabe

Numerical, Mathematical, and Physical Modeling Tools for Materials Processes IV

Contribution to Digital Representation of Materials Subjected to Thermomechanical Processing ................................................................................................................................................403 L. Madej, J. Gawad, P.D. Hodgson, and M. Pietrzyk Effect of Nozzle Port Clogging on the Behavior of Liquid Steel, Slag, and Bubble in Slab Mold.........................................................................................................................................................415 G. Wen, P. Tang, Y. Wang, and Z. Chen Modeling of Quasicrystal Plastic Deformation of Anisotropic Metals by means of Their Macromechanical Properties....................................................................................................................423 S.A. Balogun, S.O. Adeosun, and D.E. Esezobor

Poster

An Energy Model for Friction Stir Welding............................................................................................435 A. El-Domiaty, and H.A. El-hafez

Phase Stability, Diffusion and Their Applications

Phase Transformations, Amorphization, and Diffusion in Oxides

Microstructural Simulation of Phase Decomposition in Isothermally Aged Cu-Ni Alloys ....................449 E. Avila-Davila, V. Lopez-Hirata, M. Saucedo-Munoz, and J. Gonzalez-Velazquez

Phase Transformations and Coarsening

Mechanism and Kinetics of Clustering in Naturally-Aged Al-Mg-Si Alloys .........................................461 H. Seyedrezai, and H.S. Zurob Effect of Silver on the Precipitation of Aluminum-Magnesium-Silicon Alloy.......................................471 K. Matsuda, J. Nakamura, T. Kawabata, and S. Ikeno

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Oxidation and Diffusion Effect of MnO2 Additions on the Hot Corrosion Behaviour of Some Fe-, Co-, and Ni- Base Superalloys......................................................................................................................................479 Gitanjaly, H. Singh, N. Bala, and S. Prakash

Interdiffusion Measurements and Modeling

Diffusion Analysis of Cu-Sn System.......................................................................................................493 S. Kumar, K. Kulkarni, C. Handwerker, and M. Dayananda

Poster

Studies on the Thermal Behavior of FePO4 in Air..................................................................................505 L. Zhang, M. Schlesinger, and R. Brow Growth Kinetics of Boride Layers on Iron-Chromium Alloys and their Dry Abrasive Wear Resistance.......................................................................................................................................513 V.I. Dybkov, L.V. Goncharuk, V.G. Khoruzha, K.A. Melesheivich, A.V. Samelyuk, and V. R. Sidorko Phase Formation and Diffusion in Binary Systems: Real Facts and Misleading Views .........................525 V.I. Dybkov Carbon Diffusion Coefficient in Complexly Alloyed Austenite .............................................................537 A. Vasilyev

Developments in Web-Based Materials Property Databases, Knowledge Management of Materials Information, and Materials Informatics for

Accelerated Materials Discovery

Cyber Infrastructure and Data Distribution Development of Information Platform for Data Exchange between Heterogeneous Material Data Resources ..........................................................................................................................553 T. Ashino, and N. Oka

What We Can Learn from Failure Analysis

Tools & Techniques

3D Surface MicroTexture/Wear Measurement and Analysis..................................................................565 D.K. Cohen

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Automotive Systems and Components Failure Analysis of Friction Weld (FRW) in Truck Axle Application....................................................583 Y. Huang, and Y. Zhu Use of Metallurgical Analysis to Pinpoint a Brake Problem and the Cause of a Bus Fire......................591 R. Hargis, and T. Jur Analysis of Transport Trailer Front End Structures ................................................................................607 R. Harris, and P. Young Failure Analysis of Automotive Suspension Coil Springs ......................................................................621 Y. Prawoto, M. Ideda, S.K. Manville, and A. Nishikawa

Corrosion, Wear and Coatings

Critical Influence Water Component for Copper Cooling Power Generation.........................................643 A. Reani Author Index ............................................................................................................................................649 Subject Index ...........................................................................................................................................653

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Materials and Systems

Coatings as an Enabler of System Performance

Environmental Barrier Coatings/Erosion II Corrosion/Erosion Resistance of Ceramic Oxide Coatings Against CF4 + O2 Plasma ..............................1 K.H. Baik, Y.R. Lee, and H.K. Seok Revolutionary UV-Cured Nanotchnology Thin Film Coatings with Superior Barrier Properties .....................................................................................................................................................9 T. Krotine, and S. Ramsey Oil-Production Equipment Component Hardening with the Help of the Thermochemical Treatment ...................................................................................................................................................17 V.P. Artemyev, A.G. Sokolov, E.G. Sokolov, and A.A. Chalov

Coatings Via Spray Processes II

Consolidation of Composite Materials by Kinetic Spray Process .............................................................29 S.B. Zhao, B.a. Gillispie, T.Y. Han, N. Patel, and S. Khalid Structure-Property Relationship in Particle Reinforced metal-Matrix composites Made by Low Pressure Gas Dynamic Spray ............................................................................................................45 R.Gr. Maev, V. Leshchynsky, and K.Y. Sastry

Coatings for Fatigue and Wear Applications

Thick Nano-Structured CVD Coating HARDIDE as Enabler for Engineering Systems in Extreme Wear and Erosion condtions........................................................................................................55 Y.N. Zhuk

Poster

Synthiesis and Characterization of Atmospheric Pressure Chemically Vapor Deposited Aluminum ..................................................................................................................................................67 S. Maeng, S. Gu, R. Levy, F. Gomez, S. Newberg, D. Deavenport, E. Brooman, E. Berman, and J. Beatty

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Commonality of Phenomena in Composite Materials

Particle Reinforced Composites Review of the Mechanical Behavior of Micrometric & Nanometric Particulate Reinforced Metal Matrix Composites ..........................................................................................................................79 A. Ahmed, A.J. Neely, and K.K. Shankar Mechanically Milled Al Base MMC Reinforced with Ti3Al Intermetallics .............................................91 M. Adamiak

Fiber Reinforced Composites II

A Study of the Deformability of Layered Solids under Plane Strain Condition .....................................103 M.H. Serror, J. Inoue, T. Koseki, and Y. Fujino

Coating Characterization

The Development of Photo-Stimulated Luminescence Spectroscopy for 3D Stress Measurements in the Thermally Grown Oxide Layer of Thermal Barrier Coatings...............................115 S. Raghavan, and P.K. Imbrie Indenter Shape Effects on Interface Adhesion Measurement in Thermal Barrier Coating Systems ....................................................................................................................................................127 Q. Ma, J.L. Beuth, G.H. Meier, and F.S. Pettit Influence of a Viscoelastic Surface Infiltrate on the Damping Properties of Plasma Sprayed Alumina Coatings Part I: Room Temperature ...........................................................................139 P. Torvik, R. Willson, and J. Hansel Influence of a Viscoelastic Surface Infiltrate on the Damping Properties of Plasma Sprayed Alumina Coatings Part II: Effects of Elevated Temperatures and Static Strain........................151 P. Torvik, R. Willson, J. Hansel, and J. Henderson

Poster

Microstructure and Mechanical Properties of In-Situ TiC Dispersed Steel Matrix Composite ................................................................................................................................................163 K.I. Parashivamurthy, P. Sampathkumaran, S. Seetharamu, and M.N. Chandrasekharaiah Kinetics of Radiation Alterations in Polymer Materials Irradiated by High-Energy Electrons ..................................................................................................................................................179 G.A. Ismailova Production and Mechanical Properties of an Epoxy Resin/Aluminum Composite.................................183 R. Gonzalez-Aguirre, A. Altamirano-Torres, E. Rocha-Rangel, and A.B. Soto-Guzman

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Copper and Copper Alloys for Emerging Technologies

Copper Alloy Technology I Bend Formability – Characterization and Performance...........................................................................193 L. Wojnicz, J. Stainbrook, P. Robinson, K. Funke, and S. Theobald Fundamental and Applied Aspects of Newly Developed Cu-Al-Mn-Based Shape Memory Alloys ........................................................................................................................................207 T. Omori, Y. Sutou, R. Kainuma, and K. Ishida

Copper Alloy Technology II

Advances in Coppery Alloy Mold Materials for Plastic Injection and Blow Molding ...........................217 J. Kuli, and R. Kusner

Poster

Surface Characteristics of Silver Coated Copper Composite Powder by Activation- Electroless Plating Method ......................................................................................................................225 J.G. Ahn, H.T. Hail, D.J. Kim, J.S. Sohn, and H.S. Chung

Glass and Optical Materials

Metallic Glasses

Bulk Metallic Glass Formation in Ni-Rich Ternary Ni-Nb-Zr Alloy System.........................................231 Z.W. Zhu, H.F. Zhang, B.Z. Ding, and Z.Q. Hu Bulk Metallic Glasses and Synthesis by Chill Block Casting .................................................................245 N. Patki, S. Pawak, P. Kulkarni Quasi-Static and High Strain-Rate Compression Behavior of an Fe-Based Bulk Metallic Glass.........................................................................................................................................................263 G. Sunny, V. Prakash, A.S. Nouri, and J. Lewandowski

Crystalline and Glass-Ceramic Systems

Dielectric and Resistivity of THz Materials: CdTe, CdZnTe and Tl3AsSe3 Crystals ............................269 N.B. Singh, R.N. Singh, A. Berghmans, D. Knuteson, D. Kahler, B. Wagner, and J. Hawkins

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

International Symposium on Ceramic Matrix Composites

Oxide CMCs/Coatings Studies on 20% Gadolinia Stabilized Zirconia Thermal Barrier Coatings ..............................................285 L. Chandrasagar, S. Vynatheya, S. Seetharamu, and P.M. Jebaraj Functional Intermediate Layers for the Improvement of Thermal Barrier Coatings Performance .............................................................................................................................................297 C.R.C. Lima, and J.M. Guilemany The Effect of Parameters on the Incorporation of Nano-Alumina in to Composite Nickel Electrodeposits.........................................................................................................................................305 L. O'Donoghue, and M.J. Pomeroy

Poster

In Situ Neutron Diffraction Study on the Effect of Aluminium Fluoride on Phase Transformation of Mullite from Alumina/Clay .......................................................................................317 N. Tezuka, I.-M. Low, I. Davies, I. Alecu, R. Stead, M. Avdeev, E. Mehrtens, and B. Latella Production and Characterization of Al2O3-Based Composites Reinforced with Different Metals.......................................................................................................................................................327 S. Moreno-Guerrero, L.N. Couvert, J. Miranda-Hernandez, and E. Rocha-Rangel Fracture Toughness of Silicon Nitrides with Various Microstructures Determined by Indentation Fracture (IF) Method ............................................................................................................339 H. Miyazaki, H. Hyuga, Y. Yoshizawa, K. Hirao, and T. Ohji

Iron-Based Amorphous Metals: An Important Family of High-

Performance, Corrosion-Resistant Materials

Introduction and Plenary I Formation, Properties and Applications of Bulk Glassy Alloys in Fe-(Cr, Mo)-Metalloid System......................................................................................................................................................349 A. Inoue, and K. Amiya

Synthesis, Characterization, Phase Stability & Neitronics I

Assessing the Thermal Stability of Bulk Metallic Glasses for Nuclear Waste Applications ..................361 K. Hildal, J.H. Perepezko, and L. Kaufman

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Corrosion Resistance I Iron-Based Metallic Glasses with Exceptional Localized Corrosion Resistance in Chloride-Based Solutions ........................................................................................................................371 R. Huang, D. Horton, F. Bocher, and J.R. Scully The Corrosion Resistance of Fe-Based Amorphous Metals: Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4 and other Compositions.............................................381 J. Farmer, J. Haslam, S. Day, T. Lian, C.-K. Saw, P. Hailey, J.-S. Choi, R. Rebak, J. Payer, C. Blue, W. Peters, and D. Branagan Industrial Salt Fog Testing of a SAM2X5 Coated Stainless Steel Cylinder............................................393 L.F. Aprigliano, S.D. Day, J.J. Haslam, J.C. Farmer, and R.B. Rebak Examination of Galvanic Action between Fe-Based Amorphous Metals and Commercial Alloys.......................................................................................................................................................403 H. Ha, and J. Payer

Mechanical Properties & Damage Tolerance I

Thermal Exposure Effects on Mechanical Behavior of Iron-Based Metallic Glass................................413 A.Shamimi, and J.J. Lewandowski Quasi-Static and High Strain-Rate Compression Behavior of an Fe-Based Bulk Metallic Glass.........................................................................................................................................................427 G. Sunny, V. Prakash, A. Shamimi Nouri, and J. Lewandowski

Synthesis, Characterization, Phase Stability & Neutronics II

Neutron-Absorbing Coatings for Safe Storage of Fissile Materials with Enhanced Shielding & Criticality Safety..................................................................................................................433 J.S. Choi, J. Farmer, C. Lee, L. Fischer, M. Boussoufi, B. Liu, and H. Egbert

Atomization, Thermal Spray & Applications I

Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings ...................................................................................................................................................445 J. Blink, J. Choi, and J. Farmer

Corrosion Resistance II

Cyclic and Linear Polarization of Yttrium Containing Iron-Based Amorphous Alloys .........................459 S.D. Day, T. Lian, J.C. Farmer, and R.B. Rebak

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Long-Term Corrosion Testing of Thermal Spray Coatings of Amorphous Metals: Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4 and Fe48Mo14Cr15Y2C15B6 ..................................471 J. Farmer, S. Day, T. Lian, C.-K. Saw, P. Hailey, J. Payer, L. Aprigliano, B. Beardsley, and D. Branagan Corrosion Resistance of High-Boron High-Molybdenum Iron-Based Amorphous Metal Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4 for Spent Nuclear Fuel Criticality Control Application .................................................................................................................................483 S. Day, J. Haslam, P. Hailey, C. Saw, J. Farmer, N. Yang, and D. Branagan Anodic Behavior of SAM2X5 Material Applied as Amorphous Coatings .............................................497 P.D. Hailey, J.C. Farmer, S.D. Day, and R.B. Rebak

Corrosion Resistance III

Dissolution Modes and Effect of High Temperature Aging on the Corrosion Resistance of Iron Based Amorphous Alloys.................................................................................................................511 S.D. Day, J.J. Haslam, J. Farmer, and R.B. Rebak Methods to Examine Corrosion damage Evolution for Fe-Base Amorphous Alloy ...............................525 P. Pharkya, X. Shan, J. Payer

Introduction and Plenary III

Iron-Based Amorphous Metals: The High Performance Corrosion Resistant Materials (HPCRM) Program ..................................................................................................................................537 J. Farmer

Atomization, Thermal Spray & Applications II

Comparison of Crevice Corrosion of Fe-Based Amorphous Metal and Crsyalline Ni-Cr- Mo Alloy..................................................................................................................................................569 X. Shan, H. Ha, and J. Payer

Synthesis, Characterization, Phase Stability & Neutronics III

XRD Technique: A Way to Discriminate Structural Changes in Iron-Based Amorphous Materials ..................................................................................................................................................581 C.K. Saw, T. Lian, S.D. Day, and J.C. Farmer

Mechanical Properties & Damage Tolerance II

Characterization of Corrosion Resistant Amorphous Metal Coatings Subsequent to Mechanical Deformation .........................................................................................................................591 J.J. Haslam, J.C. Farmer, S. Day, P. Hailey, T. Lian, and L.F. Aprigliano

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Poster Evaluation of the Wear Characteristics of Continuously Cast Ductile Iron and AISI 1144 Steel With and Without Q & T Heat Treatment ......................................................................................607 P. Gangasani

Next Generation Biomaterials: Advanced Processing, Characterization

and Modeling of Materials for Medical Devices

Biomaterial Surfaces and Imaging Application of Rare-Earth Doped Ceramic Nanophosphers for Bioimaging under NIR Excitation .................................................................................................................................................619 K. Soga, Y. Saito, K. Shimizu, Y. Okumura, and T. Konishi

Processing and Characterization of Metallic Implant Materials

Fabrication of ASTM F75 Powders for Surgical Implants by the Uniform-Droplet Spray Process .....................................................................................................................................................625 S. Roy, T. Ando, M. Ishida, and M. Nishida

Physical and Mechanical Properties Characterization of Biomaterials, Part I

Nanotechnology for Treating Organ Failure............................................................................................633 T.J. Webster

Thermal Shock Resistant Materials

Thermal Shock Resistant Materials I

Probe Method for Local Uniformity within Particulate Filters ...............................................................645 G. Crosbie

Thermal Shock Resistant Materials II

Analysis of Thermal Stress in a Honeycomb Structure ...........................................................................657 M. Miyazaki, Y. Kato, Y. Miyairi, M. Makino, and P. Busch Author Index ............................................................................................................................................671 Subject Index ...........................................................................................................................................675

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Nanotechnology

Innovative 3D Nanoparticulate Material Processing

3D Nanoparticulate Material Characterization Fabrication of ZnO Films Consisting of Clusters Aggregated by Nanocrystallites and Their Application on Dye-Sensitized Solar Cells ........................................................................................1 Q.F. Zhang, T.P. Chou, B. Russo, D.W. Liu, G.Z. Cao, and S.A. Jenekhe General and Simple Approach for Visual Detection of Chromium (VI) Ions using Three- Dimensional Nanoscale Structures ..............................................................................................................9 S.A. El-Safty, A.A. Ismail, H. Matsunaga, Y. Kiyozumi, and F. Mizukami

Materials Characterization at the Nanoscale: Instrumentation and

Applications

Particulate Materials The Characterization of Particle Size Distribution of Nano-Tungsten Powders and Ultra- Fine Tungsten Powders by Small Angle X-Ray Scattering Method .........................................................21 L.H. Zhu, G.J. Shao, D. Siddle, and Y.X. Lie Behavior of Ultra Fine Particles in Electric Field......................................................................................29 J. Shibata, N. Murayama, D. Yamashita, and R. Shibata

Thermoanalytical Methods

On the existence of Nanoclusters in a Thermally-Cycled Gallium Alloy of Complex Composition and their Effects on Phase Transitions .................................................................................39 M. Marya

Mechanical Characterization

Study of Damage Distribution Over Primary Shear Zone in Metal Cutting Process by Nanoindentation.........................................................................................................................................49 M. Saket Kashani, and V. Madhavan Formation of Nano-Grains during Biaxial High Frequency Fully Reversed Loading ..............................59 K. Johnson, R. Higginson, P. Dickens, G. West, A. Gupta, and D. White

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Experimental NanoMechanics: A Look at Edge Dislocations in 4HSiC Crystals ....................................71 F.M. Sciammarella, C.A. Sciammarella, and L. Lamberti

Mechanics of Nanomaterials and Micro/Nanodevices - Experimental and

Modeling

Mechanics of Nanomaterials and Micro/Nanodevices-III Influence of Initial Defect Size and Location on Crack Growth and Fracture Behavior of metal Foils..................................................................................................................................................83 D. Yang, Q. Ziao, F. Tsuchiya, and T. Wyrobek

Mechanics of Nanomaterials and Micro/Nanodevices-IV

Novel Issues in Modeling of Carbon Nanomaterials.................................................................................93 R. Scipioni

Mechanics of Nanomaterials and Micro/Nanodevices-VII

Mechanical and Impact Properties of Carbon-Nanotube-Reinforced Amorphous Silicon Carbide Composites via Atomistic Simulation Studies ...........................................................................103 M.A. Makeev, and D. Sr.ivastava

Nanomaterials for Electronic Applications

Recent Developments in Nanoelectronics

Recent Developments in Nanomaterials and Nanotechnology................................................................113 J. Narayan, G.R. Trichy, and A. Tiwari

Nanoscale Particles and Powders

Electronic Spectral Densities Characterization of Individual Dots .........................................................125 K. Kral Iron Oxide Nanoparticles Supported onto Sepiolite as Novel Humidity Sensors ...................................135 J.M. Tulliani, V. Naglier, A. Esteban-Cubillo, C. Pecharroman, and J.S. Moya Effect of Si Content and Heat Treatment on Microstructure and Magnetic Properties of Mechanically Alloyed Fe-Si Powders .....................................................................................................145 S. Miraghaei, P. Abachi, and H.R. Madaah Hosseini

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Nanocomposites, Devices and Applications Nano PbTiO3, Composited with Micron Powder and Its Microwave Absorbing Properties..................157 W. Zhihui, H. Dingyong, and Y. Aidi Application of a Nanoporous Material to Improve the Downhole Temperature Survival Time for Oil & Gas Logging Sensors ......................................................................................................163 S. Rafie, and B. Hughes

Nanotubes, Nanofibers and Nanowires

Fabrication of Patterned Metallic Nanowire Array Using Anodic Aluminum Oxide for Interconnection Applications ...................................................................................................................175 H. Cai, C.L. Gan, B.S. Ong, S.Z. Li, J. Ma, S.C. Chong, G. Sharma, and K. Vaidyanathan Electrospun Cellulose Nitrate Nanofibers for Biosensor Applications ...................................................185 S. Nartker, M. Misra, L. Drzal, S. Daugherty, and P. Satoh

Poster

Investigation of Electrodeposited Co-Based Films Used for MEMS Applications ................................195 C. Elbuken, M. Yavuz, M.B. Khamesee, S. Kambe, and O. Ishii

Nano-Processing - Property Enhancement by Quantum Confinement and

Other Effects in Reduced Dimensions

Property Enhancement in Reduced Dimensions I Quantum Dots and QED ..........................................................................................................................205 T. Prevenslik Photoluminescent Intensity Enhancement of ZnS Nanoparticles Prepared by Exploding Wire Technique........................................................................................................................................217 N. Goswami

Property Enhancement in Reduced Dimensions II

NSTT-NanoTech Surface Treatment Technology May Revolutionize the Steel Industry's Hot-Rolling Mill Operations....................................................................................................................227 S. Ghosh

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Nanostructured Ceramic Materials: Science and Technology

Biomaterials, Self-assembly, Arrayed, and Nanoporous Material Synthesis of Novel, Nanoporous, High Surface-Area, Amorphous MgO Aerogels ...............................237 W. Dong, C. Tang, A. Yao, J. Amsden, S. Yen, J. Paik, and J. Sakamoto Fabrication and Characterization of Micro/Nanochannels and Micro/Nanofluidics Devices for Single Molecule Trapping and Detection.............................................................................249 X. Li, and W. Hofmeister

Synthesis and Processing of Nanopowders, Nanostructures, and Nanocomposites II

Nanostructuring Processes during Cold Gas Dynamic Spry of Cu and Ni Based Composites...............................................................................................................................................259 E. Maeva, E. Leshchinsky, and M. Lubrick Semiconducting Ba1–xSrxTiO3 Synthesized at 1050 °C........................................................................269 W. Wu, W. Jones, and Y. Liu

Industrial Development and Applications

Surface Characterization of SiC Nano-Particles and Their Stability in Aqueous Solutions ...................279 A.K. Bakshi

Functional Behavior and Characterization of Nanomaterials

Synthesis and Characterization of Nanostructured Magnesia-Yttria Based Nanocomposites.......................................................................................................................................289 J.F. Al-Sharab, R. Sadangi, V. Shukla, and B.H. Kear

Nanotubes, Nanorods, Nanowires, and Other 1-D Structures

Fabrication Strategies and Electrical Characterization of Nanodevices Contacted Using Focused Ion Beam Techniques ................................................................................................................301 A. Romano-Rodríguez, F. Hernández-Ramírez, A. Tarancón, O. Casals, D. Prades, J.R. Morante, S. Barth, and S. Mathur Fabrication of Carbon Nanofiber (CNF)/SiAlON Composites by Pulsed Electric-Current Pressure Sintering and Their Mechanical and Electrical Properties ........................................................309 K. Hirota, T. Shibata, M. Kato, and T. Nishimura

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Simulations of Nanomaterials Study by Topological Methods for Estabilishing Dimensional Repartition of Nano- Ceramic Powders (Packing and Porosity in Real Geometric R3 Space) .................................................321 N. Popescu-Pogrion, I. Merioniu, and S. Constantinescu Author Index ............................................................................................................................................333 Subject Index ...........................................................................................................................................335

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Processing and Product Manufacturing

Advances in Cement-Based Materials: Manufacturing, Hydration, Admixture Interaction, Properties/Characterization, Modeling and

Degradation/Durability

Advanced and Novel Methods for Characterization of Cements and Cement Manufacturing

Stability and Elastic Properties of Tobermorite, a Model of Cement Hydrate at the Nano- Scale.............................................................................................................................................................1 R.J.-M. Pellenq, A. Gmira, and H. Van damme

Hydration and Related Phenomena in Cement-based Systems

Monitoring of Hydration Processes in Cement Materials by Broadband Time-Domain- Reflectometry Dielectric Spectroscopy .....................................................................................................13 N.E. Hager III, and R.C. Domszy Hydration Mechanism of Alkali-Activated Fine Slag Geopolymer ..........................................................25 Y.J. Zhang, Y.L. Zhao, and D.L. Xu

Environmental Issues in the Material Science and Technology Industries

Green Materials and Processes

Green Alternative for the Preparation of Transition Metal Molybdates....................................................33 M. Chehbouni, and A. Apblett Comparative Characterization of Cr3+- and Cr6+ -based Chromate Conversion Coatings on Al Substrates for Test and Measurement Instrumentation....................................................................43 M. Powers, S. Sen, C.N. Cao, M.R. Fukui, D. Hok, F. Kuo, A.A. Maich, J.F. Merckling, J.T. Pham, N.J. spada, E.G. Szkup, E.L. Vallejo, A.S. Williamson, F. Wu, and J.D. Wu

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Environmental Issues Robustness of Materials Selection Decisions Using Various Life-Cycle Assessment Methods......................................................................................................................................................55 A. Allen, S. Das, F. Field, J. Gregory, and R. Kirchain A Novel Mechanical Process for CRT Glass Recycling ...........................................................................67 F. La Marca, S. De Arcangelis, and N. Magliozzi

Poster

Preparation of Ceramic Faience from Tunisian Raw Materials.................................................................77 H. Baccour, M. Medhioub, F. Jamoussi, and T. Mhiri Development of On-Line Analysis System for the Monitoring of Multistage Mixer-Settler....................89 J.Y. Lee, J.S. Kim, J.S. Shon, and D.Y. Yang

Innovative Processing and Synthesis of Ceramics, Glasses and

Composites

Microwave & Plasma Processing and Electrophoresis Microwave Processing of Polymer Derived Ceramics from Actively Seeded Precursor..........................97 S.C. Zunjarrao, P. Dyjak, J.D. metzger, and R.P. Singh Plasma Facility for Basalt Filaments Production.....................................................................................109 T. Svintradze, Z. Batkhadze, M. Gelenidze, Z. Chankvetadze, D. Gelenidze, F. Marquis, J. Mostaghimi, and E. Bakuradze

Coatings and Films

High-Speed Preparation of Titania Films by Laser Chemical Vapor Deposition ...................................117 T. Goto, T. Kimura, and R. Tu Influence of Process Parameters on Surface Quality of Ni-Based Composite Coatings Deposited using Low Pressure Gas Dynamic Spray Process ..................................................................127 K.Y. Sastry, V. Leshchynsky, A. Kagan, E. Strumban, and R.Gr. Maev

Reaction Mechanisms and Kinetics of Processes

Glass Melts as Indicators for Liquid Phase Sintering in Alumina...........................................................141 T. Lam, K. DeCarlo, and W. Carty Preventing Solids Flow and Segregation Problems during Precision Material Manufacturing Operations .......................................................................................................................153 R.A. Barnum

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Sol-gel & Soft Chemistry Processing, Laminated Object Manufacturing, Functionaly Graded Materials

Optimum Process Parameters and Influencing Factors for Embedding SiC Fibres in Al 6061 O Matrix through Ultrasonic Consolidation ...................................................................................169 D. Li, and R. Soar

Spark Plasma Sintering, Reaction Forming and Mechanical Alloying

Introduction of an Emerging Compaction Technology - Spark Plasma Sintering (SPS) Method and Systems ................................................................................................................................187 M. Tokita, and R. Aalund

Poster

Effect of Poly-Acrylic-Acid (PAA) Binder System on Characteristics of Dry-Pressed Alumina....................................................................................................................................................199 M.I. Zainuddin, S. Tanaka, and K. Uematsu Effect of Pulsed DC Current on Atomic Diffusion of Mo-C Diffusion Couple......................................209 T. Kondo, M. Yasuhara, Y. Kodera, M. Ohyanagi, and Z.A. Munir

Joining of Advanced and Specialty Materials IX

Joining of Steels (especially HSLA and AHSS) I

Mechanical Performance of Resistance Spot Welds in Dissimilar AHSS Combinations .......................217 V.H. Baltazar, I. Khan, M.L. Kuntz, and N. Zhou Effect of Weld Microstructure on the Static and Impact Performance Spot Welded (RSW) Dual Phase Steels.....................................................................................................................................227 M.I. Khan, M.L. Kuntz, and Y. Zhou

Joining of Steels (especially HSLA and AHSS) II

Advanced High Strength Steel (AHSS) Weld Performance Study for Autobody Structural Components .............................................................................................................................................239 D.F. Maatz Jr. High Temperature Brazing of Monolithic 430 to Porous 430L Stainless Steel for Hydrogen Separation Applications ..........................................................................................................255 V. Malave, A. Meier, and K.S. Weil Influence of Laser Welding on the Formability of AHSS Steels.............................................................267 N. Sr.eenivasan, M. Kuntz, and Y. Zhou

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Effect of Titanium and Carbon on the Microstructure of Fe-Al-Cr Weld Overlays ...............................281 K. Adams, and J. DuPont

Repair and Manufacture of Industrial Gas Turbines and Aero-Engine Components

Laser Weld Repair of Single Crystal Ni-Base Superalloys .....................................................................293 T. Anderson, J. DuPont, and T. DebRoy Repair Welding of Nodular Iron Castings for Heavy Duty Gas Turbines...............................................303 S. Janssen, E. Maldfeld, and J. Braun Laser Powder Deposition for Making Functional Net-Shape Parts and Repairing Damaged Gas Turbine Componenets ......................................................................................................315 L. Xue, J. Chen, S.-H. Wang, and Y. Li

Welding Metallurgy and Failure Analysis

Mechanisms of Macrosegregation Formation Near Fusion Boundary in Welds Made with Dissimilar Filler Metals ...........................................................................................................................329 Y.K. Yang, and S. Kou Investigation of Metallurgical Features and Local Mechanical Properties in Laser Drilled Waspaloy..................................................................................................................................................341 R. Bright, J. Garofano, C. Weiss, M. Aindow, and H. Marcus Evidence of Macrosegregation near Fusion Boundary in Welds Made with Dissimilar Filler Metals .............................................................................................................................................349 Y.K. Yang, and S. Kou

Brazing and Other Joining Methods

The Use of Electrodeposited Coatings as Interlayers in Transient Liquid Phase Bonding .....................361 R.K. Saha, and T.I. Khan Maintaining Work Hardening in Resistance Brazed Aluminum Alloy Periodic Cellular Metals.......................................................................................................................................................373 E. Bele, B. Bouwhis, and G. Hibbard Brazing of Porous Aluminum Alloy 6101 to Monolithic Aluminum Alloy 6061 for Composite Sandwich Structures Used in Thermal Management Applications .......................................385 A. Bauer, A. Meier, M. Powell, and K.S. Weil Reactive Air Brazing of ZTA to Ni Alloys with Ag-CuO Braze Alloys.................................................397 E. Prevost, A.J. DeMarco, B. MacMichael, A. Meier, J. Hoffman, and W. Walker

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Joining of Ceramics Experimental Complex for Investigations of High-Temperature Behaviour of Molten Metals in Contact with Refractory Materials...........................................................................................409 N. Sobczak, R. Nowak, W. Radziwill, J. Budzioch, and A. Glenz Alloy Depletion and Martensite Formation during Glass-to-Metal Joining of Austenitic Stainless Steels.........................................................................................................................................417 D.F. Susan, M.J. Perricone, C.V. Robino, J.R. Michael, B.B. McKenzie, and M. Rodriguez

Solid-State Joining Processes

Application of Ultrasonic Peening in Manufacturing, Rehabilitation and Repair of Welded Elements and Structures .............................................................................................................429 Y. Kudryavtsev, and J. Kleiman Automatic Fault Detection in Friction Stir Welding................................................................................441 P.A. Fleming, K.A. Fleming, D. Lammlein, D.M. Wilkes, T. Bloodworth, G. Cook, A. Strauss, D. DeLapp, T. Prater, T. Lienert, and M. Bement

Poster

Dispersion and Joining of Carbon-Nano-Tubes ......................................................................................449 S. Sahin, M. Yavuz, E. Wang, R. Zhao, and N. Zhou Glass-Metal Joining in Nuclear Environment: The State of the Art........................................................459 M. Jacobs, B. Brichard, and G. Van Oost The Role of Ag Diffusion Control Layer in the Titanium Dissimilar Joining when using an Ag-Cu-Ti Filler ...................................................................................................................................471 M.K. Lee, J.G. Lee, j.K. Lee, G.H. Kim, J.J. Park, Y.R. Uhm, and C.K. Rhee Microstructural Evolution of Ti Dissimilar Joint Brazed Using a Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 Amorphous Filler.............................................................................481 J.G. Lee, M.K. Lee, J.K. Lee, S.M. Hong, G.H. Kim, and C.K. Rhee

Lead-Free Solders: Emerging Issues in Manufacturing, Performance and

Reliability

Pb-Free Solder Alloys: Microstructure Evolution The Nucleation Kinetics of Sn in Sn-Ag-Cu Solder Joints: Relation to Microstructure .........................493 B. Arfaei, M. Benedict, and E. Cotts

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

ACerS Arthur L. Friedberg Memorial Lecture Materials Science and Engineering: A Rewarding Career ......................................................................501 D. Richerson

Poster

Interfacial Reaction and Joint Strength of Sn-3.0Ag-0.5Cu/Cu Solder Bumping Made by Two Binary Electroplating.......................................................................................................................515 S.-H. Lee, Y.-S. Shin, C.-W. Lee, J.-G. Kim, and J.-H. Kim Interfacial Interaction of Nickel with Liquid Pb-Free Sn-Bi-In-Zn-Sb Soldering Alloys.......................525 K. Barmak, D.C. Berry, V.C. Sidorko, A.V. Samelyuk, and V.I. Dybkov

Surface Engineering Using Hybrid Plasma Assisted PVD and CVD

Technologies

Nanostructured Coatings Nanocrystalline Diamond Coated Cutting Tools.....................................................................................537 J. Hu, Y. Chou, and R. Thompson Combined Magnetron Sputtering and Ion Implantation - a High Energy Ion Assisted Deposition Method for Producing Nano-Structurated Coatings..............................................................549 C. Ruset, E. Grigore, H. Maier, and R. Neu

Emerging Technologies; CVD and Plasma Surface Treatments

Investigation of Plasma Enhanced Chemically Vapor Deposited Tantalum on High Strength Steels .........................................................................................................................................563 Y. Suh, W. Chen, S. Maeng, R. Levy, H. Thridandam, K. Cuthill, and T. Gaffney

Richard M. Fulrath Award Session

Novel CO2 Absorbents using Lithium-Containing Oxide.......................................................................573 M. Kato Author Index ............................................................................................................................................583 Subject Index ...........................................................................................................................................587

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Special Topics

Industry Track 2007

Industry Track III Strategies for Intellectual Property Protection.............................................................................................1 M. Harper, and R. Citkowski Patent Licenses and the Recent Supreme Court MedImmune Decision......................................................9 P. Fleischut, and T. McBride U.S. Patent Law Update – 2007.................................................................................................................15 P. Fleischut

Journal of Undergraduate Materials Research

Journal of Undergraduate Materials Research

Characterization of Electrolessly Plated Graphite Foams with Particle Additions ...................................21 M. Asaro, J. Mueller, P. Dykema, B. Poquette, S. Kampe, and G. Pickrell Author Index ..............................................................................................................................................27 Subject Index .............................................................................................................................................29

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

TABLE OF CONTENTS Materials Science and Technology (MS&T) 2007:

Steel

4th International Symposium on Railroad Tank Cars

4th International Symposium on Railroad Tank Cars I Tank Car Steels to Improve Performance....................................................................................................1 R.D. Sims An Inspection Tool for Tank Car Thermal Protection System....................................................................9 S. Wong

4th International Symposium on Railroad Tank Cars II

Effects of Niobium, Titanium and Nitrogen on Microstructure and Mechanical Properties of Normalized Tank Car Steel Plates.........................................................................................................17 M. Manohar, and W.E. Heitmann The Influence of Sulfur Concentration Below 0.006% Along With Sulfide Shape Control on the Charpy V-Notch Properties of Normalized and Stress Relieved TC128 Grade B Steel Plate...................................................................................................................................................27 W.E. Heitmann, F.C. Feher, C. Hybinette, and M. Manohar As-Rolled Plate Product with Improved Yield Strength, Toughness, and Weldability for Pressurized Railroad Tank Cars.................................................................................................................37 R.L. Bodnar, F. Hamad, C. Penniston, and S. Roysum Processing Alternatives for Optimized Strength and Toughness Balance of ASTM A709 HPS 70W Composition..............................................................................................................................53 A. De, M. Manohar, W. Heitmann, and F. Feher

Future of Alloying in Steel

Future of Alloying in Steel

Graphical Expressions of Alloying Effects in Fe and Their Analogical Applications ..............................67 Y. Mae The Effect of Aluminum on Isothermal Oxidation Resistance of Austenitic Heat Resistant Steels ..........................................................................................................................................................79 M.O. Aminian, J. Hedjazi, and Y. Kharazi

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

The Reception of Zinc Coverings in Conditions of Self-Propagating High-Temperature Synthesis ....................................................................................................................................................93 B. Sereda

Recent Developments in Steel Processing

Casting

Modelling of the Concentric Solidification Technique using DICTRATM................................................97 S. Aminorroaya, R. Dippenaar, and M. Reid In-situ Observation of the Delta-Ferrite to Austenite Phase Transition in Fe-C Alloys..........................109 S. Niknafs, and R. Dippenaar Embrittlement Mechanisms at High Temperatures for a C-Mn Steel with High Residuals Content.....................................................................................................................................................119 J. Calvo, J.M. Carbrera, A. Rezaeian, and S. Yue Effect of Mould Taper, Mn/S Ratio and Ems on Quality of Continuously Cast Bloom .........................133 B. Mukhopadhyay, S.K. Ray, A.K. Bandopadhyay, and K. Patwari Influence of the Casting Conditions on Slab Quality of Low Carbon Steel............................................141 G. Wen, P. Tang, G. Luo, H. Xu, and Z. Chen

Processing and Modeling

Skin-Pass Rolling of Steel Strip Using Liquid Nitrogen .........................................................................149 G. Plicht, H. Schillak, M. Lin, R. Edwards, T. Mebrahtu, H. Hofinghoff, and T. Demski Deformation Characteristics of Oxide Scale in Hot Rolling by Scale Transfer Method Using Vacuum Hot Rolling Mill..............................................................................................................159 A. Segawa, and T. Taguchi Validity of Heat Transfer Coefficient Based on Cooling Time, Cooling Rate, and Heat Flux on Jominy End quench Test.............................................................................................................171 A. Sugianto, M. Narazaki, M. Kogawara, and A. Shirayori Efficient Cyclic Thermal Processing of Materials...................................................................................181 S.S. Sahay Application of the Life Cycle Modeling to Forging of Connecting Parts ...............................................191 L. Madej, S. Weglarczyk, M. Packo, R. Kuziak, and M. Pietrzyk Standardized and Computer Controlled Packing Philosophy (DCPP) for Steel......................................201 J. Rajagopalan, and T. Aijo

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Thermomechanical Processing Heat Transfer during Run-Out Table Cooling - Effect of Jet Configuration...........................................221 M.A. Wells, M. Militzer, and V. Prodanovic Influence of the Chemical Composition on Transformation Behavior of Low Carbon Microalloyed Steels under Continuous Cooling ......................................................................................233 J. Calvo, A.M. Elwazri, S Bai Effects of Alloying Elements on Microstructure and mechanical Proeprties of Microalloyed Steels Undergoing Cool Deformation ...............................................................................243 A. Fatehi, J. Calvo, A.M. Elwazri, D.Q. Bai, and S. Yue Thermomechanical Processing Effects on the Elevated Temperature Behavior of Niobium Bearing Fire-Resistant Steel .....................................................................................................255 R.W. Regier, J.G. Speer, D.K. Matlock, A.J. Bailey, and S.G. Jansto Thermomechanical Treatment of Nb-Microalloyed Weather Resistant Steel .........................................267 S.N. Prasad

Surface Treatment and Corrosion

NanoTech Surface Treatment Technology - NSTT- Reveals Remarkable Enhancement of Heat & Corrosion Resistance...................................................................................................................283 Subrata Ghosh, and Shubhalok Ghosh Integrated Machining and Surface Modification of Steel Components...................................................299 M.A.A. Sadiq, P. Laxminarayana, and V.S.R. Murti Developments in Citric Acid Passivation of Stainless Steel....................................................................307 R. Kremer The Retrieving of Boronizing Coverings on Steel Received in Self-Propagating High- Temperature Synthesis Conditions ..........................................................................................................313 B. Sereda, and S. Sheyko Effect of Thermal Cycling on the Corrosion and Microstructure of Plain Carbon Steels.......................317 Elmaryami, and Abdlmanam

Poster

Microstructure Evolution of a V-N Steel during Seamless Tube Hot Rolling ........................................331 R.N. Carvalho, M.A.C. Ferreira, D.B. Santos, and R. Barbosa Continuous Annealing Technology of Cold Rolling Automotive Sheet .................................................341 H. Jianfeng

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Measurement of the Mechanical Properties of Austenite-\Martensite Mixtures at the Reaction Temperature..............................................................................................................................353 C. Zheng, and D. Watt

Steel Product Metallurgy and Applications

Thermomechanical Processing

Microstructure and Mechanical Properties of High Strength Linepipe Steels ........................................355 D. Bai, L. Collins, F. Hamad, X. Chen, and R. Klein

Microstructure and Heat Treatment

The Effect of Heating Rate and Prior Microstructure on Austenitization Kinetics of 5150 Hot-Rolled and Quenched and Tempered Steel.......................................................................................367 K.D. Clarke, and C.J. Van Tyne Effect of Tempering on the Microstructure and Properties of Copper and Boron Bearing Very Low Carbon Steels Treated with DQ/T ..........................................................................................383 S. Jiao, X. Liang, C. Wang, L. Jin, and Y. Gong Flash Bainite Nucleated in 80ms by Water Quenching ...........................................................................393 G. Cola Jr. Bainitic Transformation in Carburized 4317 M2.....................................................................................403 P. Nash, and S. Chupatanakul

Tool Steels

An Assessment of Material Properties on Bohler W360 Isobloc for Hot Work Tool Steel ....................423 F.T. Lee Choosing Vancron Grades for Cold Work Metal Forming Tools ...........................................................433 F.T. Lee Enhancing Plastic Mould Steel Tooling Performance with Nimax .........................................................439 F.T. Lee Investigation of the Influence of Deep Cryogenic Treatment on Residual Stresses in HCHC D2 Steels using X-Ray Diffraction..............................................................................................447 S.V. Lomte, and S.B. Chikalthankar

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Product Metallurgy I The Strengthening Behavior in V-N Steels .............................................................................................461 M.J. Hua, C.I. Garcia, A.J. DeArdo, M.K. Miller, and R.J. Glodowski Limited - Hardenability Steels and New Heat Treating Technologies ....................................................471 N. Kobasko Development of 780MPa Grade Steel Plates with Excellent Deformability by Microstructural Control through the On-Line Heating Process...............................................................481 K. Ueda, S. Endo, S. Mitao, N. Shikanai, and T. Ito Study of the Grain Size Effect on the Deformation Behavior of Microalloyed Steels............................493 K. Muszka, J. Majta, and P.D. Hodgson Cyclic Plasticity of Steel..........................................................................................................................505 C.K. Seal, M.A. Hodgson, and W.G. Ferguson

Product Metallurgy II

Microstructure and Properties of Cold-Rolled-and-Annealed Low-Carbon Manganese TRIP Steels ..............................................................................................................................................515 M.J. Merwin Mechanical Behavior and Microstructure Characteristics of TRIP Steel Plates under Various heat-Treating Conditions............................................................................................................537 Q. Tian, and X. Dong Strain Aging Behavior of Bake Hardening Steel for Automotive Application .......................................547 A. Vasilyev, N. Kuzmin, a Lee Influence of Normalizing Conditions on Electrical Steel Texture Development ....................................563 S.M. Shin, S. Birosca, S.K. Chang, and B.C. De Cooman Mechanical Properties of 3% Silicon Steels during Warm Deformation ................................................575 S. Lee, and S.K. Chang, B.C. De Cooman Morphology and Crystallography of Copper Sulfide Precipitated during Isothermal Heat Treatment in Iron Alloy ...........................................................................................................................587 Z. Liu, M. Kuwabara, and Y. Iwata A Study of the Relationships Between Inclusion Morphology and Reduction Ratio for Bar Products.............................................................................................................................................599 Y. Huang, and J. Yang Study of Hot Workability of Free-Cutting Steels by the SKIZ Technique..............................................609 C. Revilla-Gomez, B. Lopez, and J.M. Rodriguez-Ibabe

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

Stainless Steels Dispersion Strengthening of σ Phase in Ferritic and Austenitic Stainless Steels After Hot Rolled ......................................................................................................................................621 C.-C. Hsieh, D.-Y. Lin, and W. Wu Microstructural Investigation of Stainless Steel AM350 Pulsed Nd-YAG and Fibre Laser Welds .......................................................................................................................................................633 L. O'Donoghue, M. Quinlan, and P. Phelan Effect of Nitrogen Content and Strain Rate on the Deformation Behavior of High- Nitrogen Austenitic Steel (18Cr-14Mn-4Ni-3Mo-xN) with Various Nitrogen Contents........................645 S.M. Nam, Y.-S. Kim, and S.-J. Kim

Poster

Sliding Wear Mechanism of the Ultra-Fine Grained (UFG) Dual Phase Steel under Low and High Applied Load Conditons ..........................................................................................................655 H.S. Yu, Y.-S. Kim, and D.H. Shin Author Index ............................................................................................................................................667 Subject Index ...........................................................................................................................................669

© 2007 ASM International. All Rights Reserved. MS&T 2007 (#05222A) www.asminternational.org

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