techlab - matériaux de référence certifiés et equipements ... · astm d-5442 (reapproved 1998)...

ASTM D-5453 Total Sulfur in Light Hydrocarbons,Motor Fuels and Oils by Ultraviolet Fluorescence

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

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ASTM

TECHLAB Tél. 03 87 75 54 29 • Fax 03 87 36 23 90 • Web www.techlab.fr 31

ASTM Standards

D-5453

Meets

EPA Guidelines

for RFG

Analysis

Method 544254435453

ASTM D-5443 Paraffin, Naphthene, and Aromatic Hydrocarbon Type Analysis in (Reapproved 1998) Petroleum Distillates through 200°C by Multi-dimensional GC

HHyyddrrooccaarrbboonn TTeesstt MMiixxttuurreeDD--55444433--9933--HHTTMM $$ 110000 // 11 xx 11 mmLLAt stated Wt. % 28 comps.

ASTM D-5442 (Reapproved 1998) Analysis of Petroleum Waxes by GC

RReetteennttiioonn TTiimmee SSttaannddaarrdd MMiixx 11DD--55444422--RRTT11 $$ 5500 // 550000 mmggEqual parts by weight 12 comps.

RReetteennttiioonn TTiimmee SSttaannddaarrdd MMiixx 22DD--55444422--RRTT22 $$ 5555 // 550000 mmggEqual parts by weight 16 comps.

n-Hexadecane (c16)n-Octadecane (c18)n-Eicosane (c20)n-Docosane(c22)n-Tetracosane (c24)n-Hexacosane (c26)

CCoolluummnn RReessoolluuttiioonnSSttaannddaarrddDD--55444422--CCRR--PPAAKK $$ 4400 // 55 xx 11 mmLLAt stated Wt. % in Cyclohexane

2 comps.

WWtt..//WWtt.. %%n-Eicosane 0.05n-Tetracontane 0.05

n-Octacosane (c28)n-Triacontane (c30)n-Dotriacontane (c32)n-Hexatriacontane (c36)n-Tetracontane (c40)n-Tetratetracontane (c44)

QQuuaannttiittaattiivvee WWaaxx SSttaannddaarrddDD--55444422--PPAAKK $$ 9955 // 55 xx 11 mmLLAt stated Wt. % in Cyclohexane 16 comps.

n-Dodecane (c12)n-Tetradecane (c14)n-Hexadecane (c16)n-Octadecane (c18)n-Eicosane (c20)n-Docosane (c22)n-Tetracosane (c24)n-Hexacosane (c26)

n-Octacosane (c28)n-Triacontane (c30)n-Dotriacontane (c32)n-Hexatriacontane (c36)n-Tetracontane (c40)n-Tetratetracontane (c44)n-Pentacontane (c50)n-Hexacontane (c60)

NEW

WWtt..//WWtt.. %%Cyclopentane 1.00n-Pentane 1.00Cyclohexane 2.002,3-Dimethylbutane 2.00n-Hexane 2.00n-Hexene 1.50Methylcyclohexane 4.254-Methyl-1-hexene 1.50n-Heptane 3.50

WWtt..//WWtt.. %%1cis,2-Dimethylcyclohexane 5.00Isooctane 5.00n-Octane 5.001cis,2 cis,4-Trimethylcyclohexane 4.25n-Nonane 4.50n-Decane 4.25n-Undecane 3.50n-Dodecane 3.25Benzene 2.25Toluene 2.25

WWtt..//WWtt.. %%trans-Decahydronaphthelene 4.25n-Tetradecane 4.50Ethylbenzene 4.50o-Xylene 4.25n-Propylbenzene 5.001,2,4-Trimethylbenzene 4.501,2,3-Trimethylbenzene 5.001,2,4,5-Tetramethylbenzene 5.00Pentamethylbenzene 5.00

WWtt..//WWtt.. %%n-Tetracosane 0.10n-Hexacosane 0.12n-Octacosane 0.12n-Triacontane 0.10n-Dotriacontane 0.08

WWtt..//WWtt.. %%n-Dodecane 0.02n-Tetradecane 0.03n-Hexadecane 0.04n-Octadecane 0.05n-Eicosane 0.06n-Docosane 0.08

WWtt..//WWtt.. %%n-Hexatriacontane 0.06n-Tetracontane 0.05n-Tetratetracontane 0.04n-Pentacontane 0.03n-Hexacontane 0.02

HHiigghh LLeevveell SSuullffuurr SSeettDD--55445533--HHLL--SSEETT $$ 9900 // 55 xx 22 mmLLThe set contains the following 5 standards in Isooctane

MMiidd LLeevveell SSuullffuurr SSeettDD--55445533--MMLL--SSEETT $$ 9900 // 66 xx 22 mmLLThe set contains the following 5 standards in Isooctane

LLooww LLeevveell SSuullffuurr SSeettDD--55445533--LLLL--SSEETT $$ 9900 // 55 xx 22 mmLLThe set contains the following 5 standards in Isooctane RReeaall WWoorrlldd SSuullffuurr iinn VVaarriioouuss GGaassoolliinnee

&& FFuueellssQQCC SSaammpplleessSSBBPPTT--LLSSGGAASS $$ 2255 // 22 xx 1155 mmLLParameter Method Approx .Range

Sulfur D-5453-00 0 - 50 µg/g

CCaatt.. NNoo.. DDeessccrriippttiioonn UUnniitt

D-5453-HL-BL Sulfur Blank 2 mLD-5453-HL-01 Sulfur @ 100 ng/µL 2 mLD-5453-HL-02 Sulfur @ 250 ng/µL 2 mLD-5453-HL-03 Sulfur @ 500 ng/µL 2 mLD-5453-HL-04 Sulfur @ 1000 ng/µL 2 mL


D-5453-ML-BL Sulfur Blank 2 mLD-5453-ML-01 Sulfur @ 5.0 ng/µL 2 mLD-5453-ML-02 Sulfur @ 25 ng/µL 2 mLD-5453-ML-03 Sulfur @ 50 ng/µL 2 mLD-5453-ML-04 Sulfur @ 100 ng/µL 2 mLD-5453-ML-05 Sulfur @ 200 ng/µL 2 mL


D-5453-LL-BL Sulfur Blank 2 mLD-5453-LL-01 Sulfur @ 0.5 ng/µL 2 mLD-5453-LL-02 Sulfur @ 2.5 ng/µL 2 mLD-5453-LL-03 Sulfur @ 5.0 ng/µL 2 mLD-5453-LL-04 Sulfur @ 10.0 ng/µL 2 mL

Originally designed forD-5442-93



NEW

Technical NoteDue to the wide variety ofrecommended solvents andstarting materials mentioned inthe preparation of the sulfurstandards, please review thecurrent product offering listedfor certified sulfur standards.Should AccuStandard’s currentsulfur standard line be missingthe necessary standards foryour application, please use ourcustom quotation request formto indicate your requiredformulation. For ppb Sulfurmeasurements, see page 6-11.

Standards of InterestSee ASTM Methods D-3710,D-5307, D-6352 for additionalcalibration standards for hydro-carbon analysis or page 15 fornew proposed methods.

Standards of InterestSee pages 6-11 for acomprehensive line of CertifiedSulfur Calibration Standards,Petrocheck, & Petrotest qualitycontrol products, pages 1-2.

Techlab - Matériaux de référence certifiés et Equipements de laboratoire - www.techlab.fr

TECHLAB www.techlab.fr Tél. (33) 03 87 75 54 29

ASTM D-5482 & D-5191 Vapor Pressure Standards

ASTM D-5501 Ethanol Content of Denatured Fuel Ethanol by GC

MMeemmbbeerr

ASTM

TECHLAB 4C La Tannerie - BP 30055 - 57072 - METZ cedex 332

VVaappoorr PPrreessssuurree QQuuaalliittyy CCoonnttrrooll SSaammpplleess

AASSTTMM DD--55558800--0000 CCoonnttiinnuueeddoonn tthhee NNeexxtt PPaaggee

ASTM Standards

ASTM D-5580 Benzene, Toluene, Ethylbenzene, m/p-Xylene, o-Xylene, C9 and Heavier Aromatics, & Total Aromatics in Finished Gasoline by GC

AAnnaallyyttee SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 55AAnnaallyyttee CCaalliibbrraattiioonn rraannggee WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %%

Benzene 0.09 - 4.50 0.09 0.45 0.90 1.80 4.50Toluene 0.90 - 13.50 13.50 9.00 4.50 2.25 0.90Ethylbenzene 0.45 - 9.00 0.45 0.90 2.25 4.50 9.00o-Xylene 0.45 - 9.00 0.90 2.25 9.00 4.50 0.451,2,4-Trimethylbenzene 0.45 - 9.00 0.90 9.00 0.45 4.50 2.252-Hexanone (Internal Std.) 10.00 10.00 10.00 10.00 10.00Isooctane 74.16 68.40 72.90 72.45 72.90

AAnnaallyyttee SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 55AAnnaallyyttee CCaalliibbrraattiioonn rraannggee WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %%

Benzene 0.10 - 5.00 0.10 0.50 1.00 2.00 5.00Toluene 1.00 - 15.00 15.00 10.00 5.00 2.50 1.00Ethylbenzene 0.50 - 10.00 0.50 1.00 2.50 5.00 10.00o-Xylene 0.50 - 10.00 1.00 2.50 10.00 5.00 0.501,2,4-Trimethylbenzene 0.50 - 10.00 1.00 10.00 0.50 5.00 2.50Isooctane 82.40 76.00 81.00 80.50 81.00

DDeennaattuurreedd FFuueell EEtthhaannooll CCaalliibbrraattiioonn SSeettDD--55550011--9944--SSEETT $$ 7755 // sseett ooff 77 xx 11 mmLL

CCaatt.. NNoo.. CCoommpp..11 WWtt..// WWtt..%% CCoommpp..22 WWtt..// WWtt..%% CCoommpp..33 WWtt..// WWtt..%% UUnniitt

D-5501-94-01 Ethanol 92 Methanol 0.6 Heptane 7.4 1 x 1 mLD-5501-94-02 Ethanol 93 Methanol 0.5 Heptane 6.5 1 x 1 mLD-5501-94-03 Ethanol 94 Methanol 0.4 Heptane 5.6 1 x 1 mLD-5501-94-04 Ethanol 95 Methanol 0.3 Heptane 4.7 1 x 1 mLD-5501-94-05 Ethanol 96 Methanol 0.2 Heptane 3.8 1 x 1 mLD-5501-94-06 Ethanol 97 Methanol 0.1 Heptane 2.9 1 x 1 mLD-5501-94-07 Ethanol 98 Methanol 0.05 Heptane 1.95 1 x 1 mL

Method 5480548255015580

n-Dodecanen-Decanen-Undecane

ASTM D-5480 Engine Oil Volatility by GC

n-Octadecanen-Tetracosane

n-Decanen-Dodecanen-Hexadecane

AArroommaattiiccss QQuuaannttiittaattiivvee CCaalliibbrraattiioonn MMiixxeess ((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))DD--55558800--9955--CCAALL--SSEETT--1100MMLL $$ 330000 // sseett ooff 55 xx 1100 mmLL of 6 component mix

AArroommaattiiccss QQuuaannttiittaattiivvee CCaalliibbrraattiioonn MMiixxeess ((wwiitthh IInntteerrnnaall SSttaannddaarrdd))DD--55558800--9955--CCAALL--IISS--SSEETT $$ 110000 // sseett ooff 55 xx 11 mmLL of 7 component mix

TTeettrraaccoossaannee ((SSoolluuttiioonn AA))DD--55448800--CC4400--55MMLL $$ 1155 // 11 xx 55 mmLLDD--55448800--CC4400--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 6600 // 55 xx 55 mmLL500 µg/mL in CS2

n-Tetracosane

SSttoocckk CCoolluummnn RReessoolluuttiioonn SSttaannddaarrddDD--55448800--CCRR--PPAAKK $$ 4400 // 55 xx 11 mmLLEach comp. at 10 µg/mL in CS2 5 comps.

DD--55448800--CCRR--110000XX--PPAAKK $$ 5500 // 55 xx 11 mmLLEach comp. at 1000 µg/mL in CS2 5 comps.

IInntteerrnnaall SSttaannddaarrdd SSoolluuttiioonnDD--55448800--IISS--55MMLL $$ 3300 // 11 xx 55 mmLLDD--55448800--IISS--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 112200 // 55 xx 55 mmLLEach comp. at equal weights 3 comps.

CCaatt.. NNoo.. VVaappoorr PPrreessssuurree PPrriiccee // SSeett ooff 1100

ASTM-P-124-01 68.3kPa (9.91 psi) $ 65 / 10 x 10 mLASTM-P-124-02 68.0kPa (9.86 psi) 75 / 10 x 10 mLASTM-P-124-03 51.1kPa (7.41 psi) 70 / 10 x 10 mLASTM-P-124-04 46.7kPa (6.77 psi) 125 / 10 x 10 mLASTM-P-124-05 22.5kPa (3.26 psi) 50 / 10 x 10 mLASTM-P-124-06 7.1kPa (1.03 psi) 50 / 10 x 10 mL


Originally designed forD-5482-99 & D-5191-99



Technical NoteAdditional Oxygenate calibra-tion, check standards, andindependent referencestandards can be found inASTM method D-4815 (page24) or D-5622-94 (page 37).The required QA/QCprocedures in EPA methodsstipulate a calibration checkstandard be used once peranalytical batch or per 10sample set. AccuStandard hasbulk packaged check standardsto meet this increased usage.

Standards of InterestAlternative n-Paraffin stand-ards are available on page 15for further method developmentwork or more DetailedHydrocarbon Analysis (DHA).

Technical NoteConsists ofpure solventswith knownvapor pressure.



ASTM D-5580-00 Benzene, Toluene, Ethylbenzene, m/p-Xylene, o-Xylene, C9 &Continued Heavier Aromatics, and Total Aromatics in Finished Gasoline by GC

MMeemmbbeerr

ASTM


Exclusive Aromatic Chemical Reference MaterialBenefits from AccuStandard

EEvveerryy aannaallyyttee iinn eeaacchh ssoolluuttiioonn iiss iinnddiivviidduuaallllyy wweeiigghheedd

AAccttuuaall wweeiigghhttss aanndd wweeiigghhtt ppeerrcceennttss aarree aavvaaiillaabbllee wwiitthh aallllAASSTTMM//EEPPAA ssoolluuttiioonnss

ASTM Standards

VVaallvvee TTiimmiinngg CCaalliibbrraattiioonn MMiixx((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))MM--GGRRAA--VVTT--AASS--1100MMLL $$ 110000 // 11 xx 1100 mmLLMM--GGRRAA--VVTT--AASS--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 440000 // 55 xx 1100 mmLLEach at stated conc. 5 comps.

WWtt..//WWtt.. %%Benzene 5.0Toluene 5.0Ethylbenzene 10.0o-Xylene 10.0Isooctane 70.0

IInntteerrnnaall SSttaannddaarrddMM--GGRRAA--IISS--AASS--55MMLL $$ 1100 // 11 xx 55 mmLLMM--GGRRAA--IISS--AASS--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 55 mmLL

2-Hexanone (Neat)

SSeelleeccttiivviittyy CChheecckk SSttaannddaarrddMM--GGRRAA--SSCCSS--AASS $$ 1100 // 11 xx 11 mmLLMM--GGRRAA--SSCCSS--AASS--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 11 mmLLEach at stated conc. 2 comps.

WWtt..//WWtt.. %%n-Dodecane 1.5Isooctane 98.5

Method 5580

WWtt..//WWtt.. %%Toluene 9Ethylbenzene 2p-Xylene 3o-Xylene 21,2,4-Trimethylbenzene 31,2,4,5-Tetramethylbenzene 1Naphthalene 1

WWtt..//WWtt.. %%n-Hexane 12n-Heptane 20n-Octane 15n-Decane 10n-Triadecane 1Isooctane 20Benzene 1

WWtt..//WWtt.. %%Toluene 9Ethylbenzene 2p-Xylene 3o-Xylene 21,2,4-Trimethylbenzene 31,2,4,5-Tetramethylbenzene 1Naphthalene 1

WWtt..//WWtt.. %%n-Hexane 12n-Heptane 20n-Octane 15n-Decane 10n-Dodecane 1Isooctane 20Benzene 1

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrddwwiitthhoouutt IInntteerrnnaall SSttaannddaarrddDD--55558800--QQCC $$ 112255 // 11 xx 1100 mmLLDD--55558800--QQCC--PPAAKK $$ 550000 // 55 xx 1100 mmLL

14 comps.

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrddwwiitthhoouutt IInntteerrnnaall SSttaannddaarrddDD--55558800--QQCC--RR11 $$ 112255 // 11 xx 1100 mmLLDD--55558800--QQCC--RR11--PPAAKK SSAAVVEE 2200%% $$ 550000 // 55 xx 1100 mmLL

14 comps.

VVaallvvee TTiimmiinngg CCaalliibbrraattiioonn MMiixx((wwiitthh IInntteerrnnaall SSttaannddaarrdd))MM--GGRRAA--VVTT//IISS--AASS $$ 2255 // 11 xx 11 mmLLMM--GGRRAA--VVTT//IISS--AASS--PPAAKK SSAAVVEE 2200%% $$ 110000 // 55 xx 11 mmLLEach at stated conc. 6 comps.

WWtt..//WWtt.. %%Benzene 4.5Toluene 4.5Ethylbenzene 9.0o-Xylene 9.02-Hexanone (Internal Std.) 10.0Isooctane 63.0


Technical NoteAASSTTMM DD--55558800 GGaassoolliinneeRReeffiinneerryy QQuuaalliittyy CCoonnttrroollSSttaannddaarrddAccuStandard was requested bythe Petrochemical Industry tomanufacture the following QA/QCstandards for ASTM Method D-5580. The configuration of yourinstrument valve time switching andthe pre-column incorporateddetermines which QA/QC standardprovides optimum performancewhen analyzing gasolines samplesby Method D-5580. Use of the D-5580 standards in conjunctionwith the real world gasolineAAccccuuPPeettrrooTTeesstt & AAccccuuPPeettrrooCChheecckkConsensus Value ReferenceMaterial (see pages 1-2) canprovide added assurance that theanalytical results being generatedby the laboratory are reproducibleand the analytical system isperforming to methodspecifications.



ASTM Standards

ASTM D-5599 Oxygenates in Gas by GC & O-FID

AAnnaallyyttee SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 55 SSttdd.. 66 SSttdd.. 77 SSttdd.. 88CCaalliibbrraattiioonn rraannggee WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %%

Methanol 0.1 - 5.0 --- 0.1 2.5 --- 5 0.5 1 ---Ethanol 1.0 - 12.0 12 --- 3 --- 8 5 1 ---Isopropanol 0.1 - 2.0 2 1 --- 0.1 0.3 --- 0.5 ---t-Butanol 0.1 - 2.0 0.5 0.1 1 --- 2 0.3 --- ---Propanol 0.2 - 2.0 2 --- 0.7 0.2 1 --- 0.4 ---MtBE 1.0 - 17.0 5 17 --- --- 1 2.5 10 ---sec-Butanol 0.1 - 2.5 1 --- 0.5 0.1 --- 2.5 0.7 ---Diisopropyl ether 0.1 - 2.0 --- 0.5 0.3 0.1 2 1 --- ---iso-Butanol 0.1 - 2.0 2 0.5 --- 1 0.1 0.3 --- ---EtBE 1.0 - 18.0 --- 3.5 18 7.5 --- 1 12 ---t-Pentanol 0.1 - 2.0 0.3 1 --- 0.5 0.1 2 --- ---Butanol 0.1 - 2.0 1 --- 0.3 --- 0.5 0.1 2 ---TAME 1.0 - 18.0 --- 3.5 1 18 7.5 12 --- ---

RFA Gasoline 74.2 64.8 64.7 64.5 64.5 64.8 64.4 100

TToottaall ooxxyyggeennaatteess 2255..88 2277..22 2277..33 2277..55 2277..55 2277..22 2277..66 00

EEvveerryy aannaallyyttee iinn eeaacchh ssoolluuttiioonniiss iinnddiivviidduuaallllyy wweeiigghheedd

AAnnaallyyttee SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 55 SSttdd.. 66 SSttdd.. 77 SSttdd.. 88CCaalliibbrraattiioonn rraannggee WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %%

Methanol 0.1 - 5.0 --- 0.1 2.5 --- 5 0.5 1 ---Ethanol 1.0 - 12.0 12 --- 3 --- 8 5 1 ---Isopropanol 0.1 - 2.0 2 1 --- 0.1 0.3 --- 0.5 ---t-Butanol 0.1 - 2.0 0.5 0.1 1 --- 2 0.3 --- ---Propanol 0.2 - 2.0 2 --- 0.7 0.2 1 --- 0.4 ---MtBE 1.0 - 17.0 5 17 --- --- 1 2.5 10 ---sec-Butanol 0.1 - 2.5 1 --- 0.5 0.1 --- 2.5 0.7 ---Diisopropyl ether 0.1 - 2.0 --- 0.5 0.3 0.1 2 1 --- ---iso-Butanol 0.1 - 2.0 2 0.5 --- 1 0.1 0.3 --- ---EtBE 1.0 - 18.0 --- 3.5 18 7.5 --- 1 12 ---t-Pentanol 0.1 - 2.0 0.3 1 --- 0.5 0.1 2 --- ---Butanol 0.1 - 2.0 1 --- 0.3 --- 0.5 0.1 2 ---TAME 1.0 - 18.0 --- 3.5 1 18 7.5 12 --- ---

1,2- Dimethoxyethane (ISTD) 4 4 4 4 4 4 4 ---RFA Gasoline 70.2 68.8 68.7 68.5 68.5 68.8 68.4 100

TToottaall ooxxyyggeennaatteess && IISSTTDD 2299..88 3311..22 3311..33 3311..55 3311..55 3311..22 3311..66 00

ASTMMMeemmbbeerr

ASTM


OOxxyyggeennaatteess CCaalliibbrraattiioonn CCuurrvvee wwiitthh IInntteerrnnaall SSttaannddaarrddMM--GGRROO--CCAALL//IISS--SSEETT $$ 225500 // sseett ooff 88 xx 11 mmLLMM--GGRROO--CCAALL//IISS--SSEETT--PPAAKK $$ 11,,000000 // 55 xx ((88 xx 11)) mmLL

of 15 Comp. Mix

D-5599

Meets

EPA Guidelines

for RFG

Analysis

Method 5599

OOxxyyggeennaatteess CCaalliibbrraattiioonn CCuurrvvee wwiitthhoouutt IInntteerrnnaall SSttaannddaarrddMM--GGRROO--CCAALL--SSEETT $$ 885500 // sseett ooff 88 xx 1100 mmLL

of 14 Comp. Mix

FFeeaattuurreess:: BBeenneeffiittss::

AAnnaallyytteess cchheecckkeedd ffoorr cchheemmiiccaall ppuurriittyy && wwaatteerr ccoonntteenntt TThhee uussee && vvaalliiddaattiioonn ooff tthhee hhiigghheesstt ppuurriittyy nneeaattss eennhhaannccee tthhee iinntteeggrriittyy ooff tthhee ssttaannddaarrdd..

AAnnaallyyzzeedd bbyy IInnddeeppeennddeenntt LLaabboorraattoorriieess IInnddeeppeennddeenntt pprroodduucctt vvaalliiddaattiioonn ooff cceerrttiiffiieedd vvaalluueess..

CCeerrttiiffiieedd mmeetthhoodd ssppeecciiffiicc ccaalliibbrraattiioonn ssttaannddaarrddss IInnccrreeaasseedd ccoonnffiiddeennccee iinn aannaallyyttiiccaall rreessuullttss..

EElliimmiinnaattiioonn ooff ssttaannddaarrddss pprreeppaarraattiioonn TTiimmee iiss uuttiilliizzeedd qquuaannttiiffyyiinngg ssaammpplleess..

IInntteerrnnaall SSttaannddaarrddss iinnccoorrppoorraatteedd RReeaaddyy--ttoo--IInnjjeecctt SSttaannddaarrddss..

WWeeiigghhttss aanndd wweeiigghhtt ppeerrcceennttss pprroovviiddeedd EEaassee ooff uussee iinn ppeerrffoorrmmiinngg bbaacckk ccaallccuullaattiioonnss..

AAllll nneecceessssaarryy ssoolluuttiioonnss iinncclluuddeedd PPrroovviiddeess ssiinnggllee ssoouurrccee ffoorr ssaammppllee aannaallyyssiiss..

VVaarriiaattiioonnss iinn PPaacckkaaggiinngg ssiizzee MMeeeett llaabboorraattoorryy ssaammppllee vvoolluummeess..

EEccoonnoommiiccaall TTiimmee iiss ssppeenntt oonn aannaallyyssiiss rraatthheerr tthhaann pprreeppaarriinngg ssttddss..

77 ssttddss.. uusseedd ttoo ggeenneerraattee 55 ppooiinntt ccuurrvvee GGeenneerraattee aa 55 ppooiinntt ccuurrvvee iinn 3300%% lleessss ttiimmee tthhaann ccoommppeettiittoorrss'' 1100 ssttaannddaarrdd sseett..

Benefits from AccuStandard’s Oxygenates


AAccttuuaall wweeiigghhttss aanndd wweeiigghhtt ppeerrcceennttss aarreepprroovviiddeedd wwiitthh aallll AASSTTMM//EEPPAA SSoolluuttiioonnss

Technical NoteOOxxyyggeennaattee CCaalliibbrraattiioonn CCuurrvveessIISSTTDD--FFrreeee aanndd LLaarrggeerrPPaacckkaaggiinngg SSiizzeeAccuStandard has receivedrequests from the PetroleumIndustry to formulate our D-5599Oxygenate product without internalstandard (ISTD) and package it in alarger volume. We have met thoserequests by introducing the M-GRO-CAL-SET calibration curve.This curve is manufactured withoutincorporating an internal standardand is packaged in RReeaaddyy--ttoo--UUssee10 mL sample volume.

The certified oxygenate calibrationcurve can be used in combinationwith other aromatic standards forcombined oxygenate/aromaticanalysis, to change the amount ofinternal standard added, or toincorporate alternative internalstandard analytes.

Technical NoteAccuStandard’s M-GROoxygenate calibration curve hasbeen successfully used byPetroleum Refineries andsupporting laboratories for bothASTM Method D-5599 andASTM Method D-4815. Inaddition, AccuStandard’scertified oxygenate chemicalreference materials provide thefollowing features and benefitsfor superior performance andvalue.



ASTM D-5599 Oxygenates in Gasoline by GC & O-FIDContinued

CCoommppoouunndd TTaarrggeett OOxxyyggeennaattee WWtt.. %%

Methanol 1Ethanol 1Isopropanol 1t-Butanol 1Propanol 1MtBE 3sec-Butanol 1Di-isopropyl ether 1

ASTM Standards

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--QQCC--1100MMLL $$ 110000 // 11 xx 1100 mmLLMM--GGRROO--QQCC--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 440000 // 55 xx 1100 mmLL

RReevviisseedd DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--QQCC--RR--1100MMLL $$ 110000 // 11 xx 1100 mmLLMM--GGRROO--QQCC--RR--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 440000 // 55 xx 1100 mmLL

GGaassoolliinnee RReeffiinneerryy BBllaannkk((wwiitthh IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--BBLLNNKK//IISS--1100MMLL $$ 1155 // 11 xx 1100mmLLMM--GGRROO--BBLLNNKK//IISS--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 6600 // 55 xx 1100mmLL

2 comps.

WWtt.. %%1,2- Dimethoxyethane (ISTD) 4RFA Gasoline 96

MMeemmbbeerr

ASTM


D-5599

Meets

EPA Guidelines

for RFG

AnalysisAASSTTMM//EEPPAA OOxxyyggeennaattee QQuuaalliittyy CCoonnttrrooll SSttaannddaarrddss

Method 5599


iso-Butanol 1EtBE 3t-Pentanol 1Butanol 1TAME 3

RFA Gasoline 81

14 comps. 100


iso-Butanol 1EtBE 3t-Pentanol 1Butanol 1TAME 3

RFA Gasoline 79

14 comps. 100


Methanol 1Ethanol 1Isopropanol 1t-Butanol 1Propanol 1MtBE 3sec-Butanol 1Di-isopropyl ether 3


Di-isopropyl ether 3iso-Butanol 1EtBE 3t-Pentanol 1Butanol 1TAME 3

RFA Gasoline 79

100


Methanol 1Ethanol 1Isopropanol 1t-Butanol 1Propanol 1MtBE 3sec-Butanol 1

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--QQCC//IISS--55MMLL $$ 7755 // 11 xx 55 mmLLMM--GGRROO--QQCC//IISS--55MMLL--PPAAKK SSAAVVEE 2277%% $$ 227755 // 55 xx 55 mmLL

RReevviisseedd DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--QQCC--RR//IISS--55MMLL $$ 7755 // 11 xx 55 mmLLMM--GGRROO--QQCC--RR//IISS--55MMLL--PPAAKK SSAAVVEE 2277%% $$ 227755 // 55 xx 55 mmLL


Di-isopropyl ether 1iso-Butanol 1EtBE 3t-Pentanol 1Butanol 1TAME 3

RFA Gasoline 81

100


Methanol 1Ethanol 1Isopropanol 1t-Butanol 1Propanol 1MtBE 3sec-Butanol 1

1,2-Dimethoxyethane (ISTD) is combined withthe above 14 comps. in a 4 to 100 weight ratio

15 comps.

OO--FFIIDD GGaassoolliinnee RReeffiinneerryy BBllaannkkMM--GGRROO--BBLLNNKK--1100MMLL $$ 1100 // 11 xx 1100mmLLMM--GGRROO--BBLLNNKK--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 1100mmLL

RFA Gasoline (neat)

OO--FFIIDD//EEPPAA GGaassoolliinnee RReeffiinneerryyIInntteerrnnaall SSttaannddaarrddMM--GGRROO--IISS--55MMLL $$ 1100 // 11 xx 55 mmLLMM--GGRROO--IISS--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 55 mmLL

1,2- Dimethoxyethane (ISTD)

1,2-Dimethoxyethane (ISTD) is combined withthe above 14 comps. in a 4 to 100 weight ratio

15 comps.


Technical NoteThe Daily Quality ControlStandard M-GRO-QC-R wasdeveloped in response to yourrequests for a QC mixbracketed by the CalibrationCurve.

AccuStandard reduced thediisopropyl ether content from 3Wt. % to 1 Wt. % to meet themethod specifications.

Technical NoteAdditional Oxygenatecalibration, check standards,and independent referencestandards can be found inASTM method D-4815 (page24) or D-5622 (page 37). Therequired QA/QC procedures inEPA methods stipulate acalibration check standard beused once per analytical batchor per 10 sample set.AccuStandard has bulkpackaged check standards tomeet this increased usage.



ASTM D-5599 EPA Gasoline Refinery Oxygenates Calibration Curves

WWtt..//WWtt.. %%Methyl tert-butyl ether 11.40RFA gasoline 67.45DME (internal standard) 5.0

WWtt..//WWtt.. %%Methyl tert-butyl ether 12.0RFA gasoline 71.0

WWtt..//WWtt.. %%Methanol 3.80Ethanol 7.60tert-Butanol 4.75

WWtt..//WWtt.. %%Methanol 4.0Ethanol 8.0tert-Butanol 5.0

AAnnaallyyttee SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 55CCaalliibbrr.. rraannggee WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %%

Methanol 0.29 - 11.40 5.70 11.40 2.85 0.29 8.55Ethanol 0.29 - 11.40 0.29 2.85 5.70 8.55 11.40t-Butanol 0.29 - 11.40 0.29 5.70 8.55 11.40 2.85MtBE 0.29 - 14.29 14.25 7.13 10.69 3.56 0.291,2-Dimethoxyethane (ISTD) 5.00 5.00 5.00 5.00 5.00RFA Gasoline 74.48 67.93 67.31 71.20 71.92

EEPPAA OO--FFIIDD QQuuaannttiittaattiivvee CCaalliibbrraattiioonn MMiixxeess ((wwiitthh IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--CCAALL--IISS//EEPPAA--SSEETT $$ 117755 // sseett ooff 55 xx 11 mmLL

6 comps.

EEPPAA OO--FFIIDD QQuuaannttiittaattiivvee CCaalliibbrraattiioonn MMiixxeess ((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--CCAALL--EEPPAA--SSEETT--1100MMLL $$ 335500 // sseett ooff 55 xx 1100 mmLL

5 comps.

AAnnaallyyttee SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 55CCaalliibbrr.. rraannggee WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %%

Methanol 0.30 - 12.00 6.00 12.00 3.00 0.30 9.00Ethanol 0.30 - 12.00 0.30 3.00 6.00 9.00 12.00t-Butanol 0.30 - 12.00 0.30 6.00 9.00 12.00 3.00MtBE 0.30 - 15.00 15.00 7.50 11.25 3.75 0.30RFA Gasoline 78.40 71.50 70.75 74.95 75.70

EEPPAA OO--FFIIDD OOxxyyggeennaattee PPeettrroocchheemmiiccaall SSttaannddaarrddssAccuStandard has formulated this second oxygenate version to meet the specific analyte requirements set forth in the EPA methodology.

Oxygenates Using O-FIDASTMMMeemmbbeerr

ASTM


Cross Reference TableASTM IP ISO DIN JIS AFNOR sorted by

ASTM Method see beginning of Catalog

FFoorr oouurr ccoommpplleettee lliinnee ooff OOrrggaanniicc SSttaannddaarrddss,,rreeqquueesstt aa ccooppyy ooff oouurrCCaattaalloogg..

Method 5599

IInntteerrnnaall SSttaannddaarrddMM--GGRROO--IISS--55MMLL $$ 1100 // 11 xx 1100 mmLLMM--GGRROO--IISS--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 1100 mmLL

1,2-Dimethoxyethane (ISTD)

OOxxyyggeennaattee FFrreeee GGaassoolliinnee RReeffiinneerryyBBllaannkkMM--GGRROO--BBLLNNKK--1100MMLL $$ 1100 // 11 xx 1100 mmLLMM--GGRROO--BBLLNNKK--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 1100 mmLL

RFA Gasoline (neat)

EEPPAA OO--FFIIDD SSppiikkiinngg SSoolluuttiioonnMM--GGRROO--EEPPAA--SSPP--55MMLL $$ 5500 // 11 xx 55 mmLLMM--GGRROO--EEPPAA--SSPP--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 220000 // 55 xx 55 mmLL

4 comps.

EEPPAA OO--FFIIDD QQuuaannttiittaattiivvee CCaalliibbrraattiioonnCChheecckk SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--EEPPAA--CCCC//IISS--55MMLL $$ 3355 // 11 xx 55 mmLLMM--GGRROO--EEPPAA--CCCC//IISS--55MMLLPPAAKK SSAAVVEE 2200%% $$ 115500 // 55 xx 55 mmLL

6 comps.

EEPPAA OO--FFIIDD QQuuaannttiittaattiivvee CCaalliibbrraattiioonnCChheecckk SSttaannddaarrdd((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))MM--GGRROO--EEPPAA--CCCC--1100MMLL $$ 5500 // 11 xx 1100 mmLLMM--GGRROO--EEPPAA--CCCC--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 220000 // 55 xx 1100 mmLL

5 comps.

WWtt..//WWtt.. %%tert-Butanol 14.3Methyl tert-butyl ether 42.8

WWtt..//WWtt.. %%Methanol 14.3Ethanol 28.6


Technical NoteAdditional Oxygenatecalibration, check standards,and independent referencestandards can be found inASTM method D-4815 (page24) or D-5622 (page 37). Therequired QA/QC procedures inEPA methods stipulate acalibration check standard beused once per analytical batchor per 10 sample set.AccuStandard has bulkpackaged check standards tomeet this increased usage.



ASTM D-5622 Total Oxygen in Gasoline & MeOH Fuels by Reductive Pyrolysis

FFoorr oouurr ccoommpplleettee lliinnee ooff IInnoorrggaanniicc SSttaannddaarrddss,,rreeqquueesstt aa ccooppyy ooff oouurrIInnoorrggaanniiccss CCaattaalloogg..

ASTM Standards

ASTM D-5600 Trace Metals in Petroleum Coke by ICP-AES

MMeemmbbeerr

ASTM


Method 56005622

SodiumTitaniumVanadiumZinc

MagnesiumManganeseNickelSilicon

AluminumBariumCalciumIron LLiitthhiiuumm BBoorraattee DDiilluueenntt

DD--55660000--LLIIBB--11 $$ 112255 // 11 xx 110000 mmLLDD--55660000--LLIIBB--55 $$ 118800 // 11 xx 550000 mmLL

2.0% Lithium Borate in 10% HCl

HHyyddrroocchhlloorriicc AAcciidd DDiilluueennttDD--55660000--BBLLHH--55 $$ 5500 // 11 xx 550000 mmLLDD--55660000--BBLLHH--LL $$ 6655 // 11 xx 11 LL

20% HCl in ASTM Type II water

MMuullttii--EElleemmeenntt CCaalliibbrraattiioonn SSttaannddaarrddDD--55660000--0011--11 $$ 222255 // 11 xx 110000 mmLL500 µg/mL each in 2-5% HNO3 tr. HF 12 comps.

OOxxyyggeennaattee UUnniittCCaatt.. NNoo.. DDeessccrriippttiioonn ((22 xx 1100 mmLL,, pplluuss aann RRFFAA ggaassoolliinnee bbllaannkk)) WWtt.. %% PPrriiccee

ASTM-P-0061-SET * Ethanol in Oxygenate free RFA gasoline 5.0 3 x 10 mL $ 50ASTM-P-0062-SET * Ethanol in Oxygenate free RFA gasoline 10.0 3 x 10 mL 50ASTM-P-0063-SET * t-Amyl methyl ether in Oxygenate free RFA gasoline 10.0 3 x 10 mL 50ASTM-P-0064-SET * t-Amyl methyl ether in Oxygenate free RFA gasoline 15.0 3 x 10 mL 50ASTM-P-0065-SET * Ethyl t-butyl ether in Oxygenate free RFA gasoline 10.0 3 x 10 mL 50ASTM-P-0066-SET * Ethyl t-butyl ether in Oxygenate free RFA gasoline 15.0 3 x 10 mL 50ASTM-P-0067-SET * Methyl t-butyl ether in Oxygenate free RFA gasoline 10.0 3 x 10 mL 50ASTM-P-0068-SET * Methyl t-butyl ether in Oxygenate free RFA gasoline 15.0 3 x 10 mL 50ASTM-P-0069-SET * Methanol & t-Butanol in Oxygenate free RFA gasoline 10.0 & 5.0 3 x 10 mL 50

** EEaacchh SSeett iinncclluuddeess MM--GGRROO--BBLLNNKK--1100MMLL

OOxxyyggeennaattee FFrreeee GGaassoolliinnee RReeffiinneerryy BBllaannkkMM--GGRROO--BBLLNNKK--1100MMLL $$ 1100 // 11 xx 1100 mmLL

RFA Gasoline (neat)



Standards of InterestSee ASTM Methods D-4815 (page 24) and D-5599(pages 34-36) for additional oxygenate calibrationstandards.

Standards of InterestIndividual ICP Standards are on pages 67-72.

Technical NoteAccuStandard’s Oxygenatereference fuel line wasdesigned as a cost effectivealternative for PetrochemicalLaboratories. All oxygenateblends come with a certificateto maintain traceability links toNIST SRMs (when available).By packaging the standard in10 mL sealed ampules yourlaboratory will realize costsavings. The 10 mL size avoidshaving special packaging andhazardous material fees billedto your invoice.

Technical NoteDD--55660000 RReeaaddyy--ttoo--AAssppiirraatteeSSttaannddaarrddssAccuStandard has formulated thefollowing stock standards forASTM Method D-5600. We haveprepared numerous RReeaaddyy--ttoo--AAssppiirraattee ICP multi-elementsolutions. Should your companywant to eliminate the preparationprocess for Inorganic standardscontact our Technical Departmentfor a quote on a RReeaaddyy--ttoo--AAssppiirraattee working level Inorganicstandard.

Technical NoteUse M-GRO-BLNK-10ML as anoxygenate free RFA gasoline matrix tomake up your own oxygenatestandards or call our Technical Dept. tohave a Standard custom made for you.



ASTM D-5623 Sulfur Compounds in Light Petroleum Liquids by GC andSulfur Selective Detection

MMeemmbbeerr

ASTM


Custom Ampulling for Bulk Quantity Requirements

• FFiillll VVoolluummeess ffrroomm 00..22 mmLL ttoo 2200 mmLL• FFllaammmmaabblleess• QQCC SSeerrvviicceess aavvaaiillaabblleeAccuStandard has the resources and equipment to meet yourcustom packaging requirements. Our full automated filler-sealercan accommodate a fill range from 0.2 to 20 mL, and ampulesizes from 1 mL to 20 mL.

AccuStandard has extensive experience with Round Robinsamples for ASTM committees.

Call our Technical Department for a quotation.

WWee ccaann rreedduuccee yyoouurr ccoossttss bbyy uussiinngg tthhee CCoozzzzoollii AAuuttoo FFiilllliinngg//SSeeaalliinngg MMaacchhiinnee ttoo ppaacckkaaggeejjuusstt tthhee rriigghhtt ssiizzee pprroodduucctt ffoorr yyoouurr aapppplliiccaattiioonn..

ASTM Standards

AASSTTMM--PP--00009911--1100XX--SSEETT $$ 662255 // sseett ooff 2222 xx 11 mmLLApprox. 2.0 mg/mL each in Toluene

AAnnaallyyttee CCaatt.. NNoo.. UUnniitt PPrriiccee

Hydrogen sulfide ASTM-P-0091-01-10X 1 x 1 mL $ 35Carbonyl sulfide (Carbon oxysulfide) ASTM-P-0091-02-10X 1 x 1 mL 35Methyl mercaptan (Methanethiol) ASTM-P-0091-03-10X 1 x 1 mL 35Ethyl mercaptan (Ethanethiol) ASTM-P-0091-04-10X 1 x 1 mL 35Methyl sulfide (Dimethyl sulfide) ASTM-P-0091-05-10X 1 x 1 mL 35Carbon disulfide ASTM-P-0091-06-10X 1 x 1 mL 352-Propanethiol (Isopropyl mercaptan ASTM-P-0091-07-10X 1 x 1 mL 352-Methyl-2-propanethiol (t-butyl mercaptan) ASTM-P-0091-08-10X 1 x 1 mL 351-Propanethiol (Propyl mercaptan) ASTM-P-0091-09-10X 1 x 1 mL 35Ethyl methyl sulfide ASTM-P-0091-10-10X 1 x 1 mL 351-Methyl-1-propanethiol (2-butanethiol) ASTM-P-0091-11-10X 1 x 1 mL 35Thiophene ASTM-P-0091-12-10X 1 x 1 mL 352-Methyl-1-propanethiol (Isobutyl mercaptan) ASTM-P-0091-13-10X 1 x 1 mL 35Diethyl sulfide ASTM-P-0091-14-10X 1 x 1 mL 351-Butanethiol (Butyl mercaptan) ASTM-P-0091-15-10X 1 x 1 mL 35Methyl disulfide (Dimethyl disulfide) ASTM-P-0091-16-10X 1 x 1 mL 352-Methylthiophene ASTM-P-0091-17-10X 1 x 1 mL 353-Methylthiophene ASTM-P-0091-18-10X 1 x 1 mL 35Diethyl disulfide (Ethyl disulfide) ASTM-P-0091-19-10X 1 x 1 mL 353-Methylbenzo[b]thiophene ASTM-P-0091-20-10X 1 x 1 mL 355-Methylbenzo[b]thiophene ASTM-P-0091-21-10X 1 x 1 mL 75Diphenyl sulfide ASTM-P-0091-22-10X 1 x 1 mL 35

This set of qualitative Sulfur Standards are formulated for research evaluation of the presence of the sulfuranalytes or their breakdown products.

Method 5623




ASTM D-5708 Nickel, Vanadium, & Iron in Crude Oils & Residual Fuels by ICP-AES

MMeemmbbeerr

ASTM


ASTM Standards

SSuullffuurr aanndd MMeettaallss iinn RReessiidduuaall FFuueell OOiillAASSTTMM--PP--00110033--SSEETT $$ 22110000 // 110000 mmLL

SSuullffuurr IIrroonn NNiicckkeell VVaannaaddiiuummCCaatt.. NNoo.. CCoonncc.. CCoonncc.. CCoonncc.. CCoonncc.. PPrriiccee

((WWtt.. %%)) ((µµgg//gg)) ((µµgg//gg)) ((µµgg//gg)) 110000 mmLL

ASTM-P-0103-01 0.00 0 0 0 $ 200ASTM-P-0103-02 0.50 300 10 500 200ASTM-P-0103-03 1.00 500 100 25 200ASTM-P-0103-04 - 100 80 250 200ASTM-P-0103-05 2.00 200 40 100 200ASTM-P-0103-06 2.50 400 5 400 200ASTM-P-0103-07 3.00 0 60 300 200ASTM-P-0103-08 3.50 500 0 200 200ASTM-P-0103-09 - 100 100 0 200ASTM-P-0103-10 4.50 300 50 250 200ASTM-P-0103-11 5.00 200 20 500 200ASTM-P-0103-12 5.50 50 100 50 200

SSuullffuurr aanndd MMeettaallss iinn MMiinneerraall OOiillAASSTTMM--PP--00110022--SSEETT $$ 11885500 // 110000 mmLL

SSuullffuurr IIrroonn NNiicckkeell VVaannaaddiiuummCCaatt.. NNoo.. CCoonncc.. CCoonncc.. CCoonncc.. CCoonncc.. PPrriiccee

((WWtt.. %%)) ((µµgg//gg)) ((µµgg//gg)) ((µµgg//gg)) 110000 mmLL

ASTM-P-0102-01 0.00 0 0 0 $ 200ASTM-P-0102-02 0.50 300 10 500 200ASTM-P-0102-03 1.00 500 100 25 200ASTM-P-0102-04 - 100 80 250 200ASTM-P-0102-05 2.00 200 40 100 200ASTM-P-0102-06 2.50 400 5 400 200ASTM-P-0102-07 3.00 0 60 300 200ASTM-P-0102-08 3.50 500 0 200 200ASTM-P-0102-09 - 100 100 0 200ASTM-P-0102-10 4.50 300 50 250 200ASTM-P-0102-11 5.00 200 20 500 200ASTM-P-0102-12 5.50 50 100 50 200

VanadiumIronNickelVanadiumIron

Nickel

IronNickelVanadium

WWoorrkkiinngg LLeevveell MMuullttii--EElleemmeennttAAqquueeoouuss SSttaannddaarrddDD--55770088--BB--55 $$ 110055 // 550000 mmLLEach at 10 µg/mL in 2-5% HNO3 3 comps.

TTeesstt MMeetthhoodd BB -- IICCPP aafftteerr AAcciidd DDeeccoommppoossiittiioonn ooff SSaammppllee

SSttoocckk MMuullttii--EElleemmeenntt iinnMMiinneerraall OOiillDD--55770088--AA--1100XX $$ 115500 // 44 oozz..100 µg/g in 20 cSt mineral oil

3 comps.

NNiittrriicc AAcciidd BBllaannkkCCLLPP--BBLLNN--55 $$ 3300 // 550000 mmLLCCLLPP--BBLLNN--LL $$ 4455 // LL (2 x 500 mL)

5% HNO3 in ASTM Type I Water

SSttoocckk MMuullttii--EElleemmeenntt AAqquueeoouuss SSttaannddaarrddDD--55770088--BB--1100XX--11 $$ 6600 // 110000 mmLLDD--55770088--BB--1100XX--55 $$ 111155 // 550000 mmLLEach at 100 µg/mL in 2-5% HNO3 3 comps.

TTeesstt MMeetthhoodd AA -- IICCPP wwiitthh aann OOrrggaanniicc SSoollvveenntt SSppeecciimmeenn SSoolluuttiioonn

Method 5599

FFoorr oouurr ccoommpplleettee lliinnee ooff IInnoorrggaanniicc SSttaannddaarrddss,,rreeqquueesstt aa ccooppyy ooff oouurrIInnoorrggaanniiccss CCaattaalloogg

Originally designed forD-5708-95a

MMeemmbbeerr

AAccccuuSSttaannddaarrdd iiss aann aaccttiivvee mmeemmbbeerr iinn AASSTTMM aannddssttrriivveess ttoo kkeeeepp aabbrreeaasstt ooff AASSTTMM mmeetthhoodd rreevviissiioonnss.. IIffoouurr lliisstteedd ffoorrmmuullaattiioonn ddooeess nnoott mmeeeett tthhee mmoosstt rreecceennttmmeetthhoodd rreevviissiioonn,, pplleeaassee ccoonnttaacctt TTeecchhnniiccaall SSuuppppoorrtt,,eexxtt.. 111177 ffoorr aann uuppddaatteedd pprroodduucctt..

WEAR M

ETALS

Standards of InterestSee Table of Contents forthe Wear Metals Grouppages.



ASTM D-5762 Nitrogen in Petroleum & Petroleum Products by Boat-Inlet Chemiluminescence

QC Standards

MMeemmbbeerr

ASTM


AAccccuuPPeettrrooCChheecckk QQCC SSttaannddaarrddssTwo of the fuels are available as AccuPetroCheckConsensus Value QC Standards. TheAccuPetroCheck CARB and Conventionalgasoline reference materials have all parameterslisted on the certificate with the Consensus Valuesand the regression equations for reproducability.Use of these Reference Materials improve thequality of laboratory results. The ConsensusValues listed reflect initial statistical treatment ofthe data at the time the catalog was published.The actual certificate provided with theAccuPetroCheck QC standard will have theaccepted Consensus Value based on statisticaltreatment of the data.

CCoonnvveennttiioonnaall GGaassoolliinnee QQCCSSttaannddaarrddAASSTTMM--FFUUEELL--QQCCSS--0022--PPAAKK $$ 6600 // 55 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd VVaalluuee CCoonncc..Total Aromatics D-1319 34.6 Vol.%Total Olefins D-1319 12.4 Vol.%Total Saturates D-1319 62.8 Vol.%Sulfur D-2622 0.0338 Wt.%Sulfur D-4294 0.0368 Wt.%Sulfur D-5453 317.36 µg/gSulfur D-6344 338.78 µg/gBenzene D-5769 0.55 Vol.%Toluene D-5769 5.53 Vol.%Total Aromatics D-5769 32.51 Vol.%Benzene D-6227 0.52 Vol.%Total Olefins D-6550 12.4 Vol.%

CCAARRBB LLooww SSuullffuurr RRFFGG QQCCSSttaannddaarrddAASSTTMM--FFUUEELL--QQCCSS--0011--PPAAKK $$ 6600 // 55 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd VVaalluuee CCoonncc..Total Aromatics D-1319 24.5 Vol.%Total Olefins D-1319 5.3 Vol.%Total Saturates D-1319 58.3 Vol.%Sulfur D-2622 0.0057 Wt.%Sulfur D-4294 0.0078 Wt.%Sulfur D-5453 55.76 µg/gSulfur D-6344 59.31 µg/gBenzene D-5769 0.80 Vol.%Toluene D-5769 4.92 Vol.%Total Aromatics D-5769 23.42 Vol.%Benzene D-6227 0.78 Vol.%Total Olefins D-6550 5.3 Vol.%

AAccccuuPPeettrrooCChheecckk aanndd AAccccuuPPeettrrooTTeesstt RReeaall WWoorrlldd GGaassoolliinnee QQCC SSttaannddaarrddssIn cooperation with ASTM D-02 subcommittee 3 and 4, AccuStandard ampulled 21 Real World gasoline reference fuels. Consensus Values havebeen determined for these reference fuels by various ASTM Round Robins to provide Petrochemical Laboratories with a source of wellcharacterized gasoline standards for use in QA/QC applications and as Single Blind test samples over an extended period of time. As new ASTMD-02.03 and D-02.04 Test methods are promulgated they require mandatory Quality Control testing of real world samples. AccuStandard’sAccuPetroTest & AccuPetroCheck standards are being successfully used to achieve these new Quality Control requirements.

ASTM Standards

LLooww lleevveell NNiittrrooggeenn && SSuullffuurr CCaalliibbrraattiioonn SSeettAASSTTMM--PP--00007711--SSEETT $$ 5500 // 44 xx 11 mmLLCCaatt.. NNoo.. DDeessccrriippttiioonn UUnniittASTM-P-0071-BL Benzene Blank 1 x 1 mLASTM-P-0071-01 Nitrogen @ 0.25 µg/g & Sulfur @ 0.25 µg/g in Benzene 1 x 1 mLASTM-P-0071-02 Nitrogen @ 0.50 µg/g & Sulfur @ 0.50 µg/g in Benzene 1 x 1 mLASTM-P-0071-03 Nitrogen @ 1.00 µg/g & Sulfur @ 1.00 µg/g in Benzene 1 x 1 mL

LLooww lleevveell NNiittrrooggeenn CCaalliibbrraattiioonn SSeettAASSTTMM--PP--00007700--SSEETT $$ 7755 // 66 xx 11 mmLL

CCaatt.. NNoo.. DDeessccrriippttiioonn UUnniittASTM-P-0070-BL Isooctane Blank 1 x 1 mLASTM-P-0070-1X Nitrogen @ 0.5 µg/g in Isooctane 1 x 1 mLASTM-P-0070-2X Nitrogen @ 1.0 µg/g in Isooctane 1 x 1 mLASTM-P-0070-4X Nitrogen @ 2.0 µg/g in Isooctane 1 x 1 mLASTM-P-0070-10X Nitrogen @ 5.0 µg/g in Isooctane 1 x 1 mLASTM-P-0070-20X Nitrogen @ 10.0 µg/g in Isooctane 1 x 1 mL

NNiittrrooggeenn CCaalliibbrraattiioonn SSeettDD--55776622--9955--CCAALL--SSEETT $$ 7755 // 66 xx 11 mmLL

CCaatt.. NNoo.. DDeessccrriippttiioonn UUnniittD-5762-95-BL Xylene Blank 1 x 1 mLD-5762-95-1X Nitrogen @ 1.0 µg/mL in Xylene 1 x 1 mLD-5762-95-5X Nitrogen @ 5.0 µg/mL in Xylene 1 x 1 mLD-5762-95-10X Nitrogen @ 10 µg/mL in Xylene 1 x 1 mLD-5762-95-50X Nitrogen @ 50 µg/mL in Xylene 1 x 1 mLD-5762-95-100X Nitrogen @ 100 µg/mL in Xylene 1 x 1 mL

SSttoocckk NNiittrrooggeenn SSttaannddaarrddDD--55776622--9955--550000XX--PPAAKK $$ 4455 // 55 xx 11 mmLL

Nitrogen @ 500 µg/mL in Xylene (Acridine @ 6397 µg/mL)

Method 5762


Technical NoteNitrogen introduced usingAcridine.

Technical NoteNitrogen introduced usingAcridine.

Technical NoteThe Nitrogen isintroduced usingAniline and the Sulfuris introduced usingn-Butyl sulfide.



AccuPetroTest Gasoline

AccuPetroTest Gasoline QC

AccuPetroTest Gasoline

AccuPetroTest

MMeemmbbeerr

ASTM


CCoommpprreehheennssiivvee SSiinnggllee BBlliinndd GGaassoolliinnee QQCCSSaammpplleeSSBBPPTT--CCOOMMPP $$ 5500 // 22 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd AApppprrooxx.. RRaannggee CCoonncc..Total Aromatics D-1319 8 - 60 Vol.%Total Olefins D-1319 1 - 40 Vol.%Total Saturates D-1319 30 - 80 Vol.%Sulfur D-2622 0.0001 - 0.0930 Wt.%Sulfur D-4294 0.0016 - 0.0930 Wt.%Sulfur D-5453 0.5 -500 µg/gSulfur D-6344 1.0 - 1000 µg/gBenzene D-5769 0.1 - 2.0 Vol.%Toluene D-5769 1.0 - 15 Vol.%Total Aromatics D-5769 8 - 60 Vol.%Benzene D-6277 0.1 - 2.0 Vol.%Total Olefins D-6550 1 - 40 Vol.%

CCoonndduuccttiinngg aa PPeettrroocchheemmiiccaall RRoouunndd RRoobbiinn ffoorr aa nneeww AASSTTMM mmeetthhoodd??Select AccuStandard to prepare the necessary samples for the Round Robinstudy.

SSuullffuurr QQCC SSaammpplleeSSBBPPTT--SSGGAASS $$ 2255 // 22 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd AApppprrooxx.. RRaannggeeSulfur D-2622 0.0001 - 0.0930 Wt.%Sulfur D-4294 0.0016 - 0.0930 Wt.%Sulfur D-5453 4.0 - 500 µg/gSulfur D-XXXX 1.0 - 1000 µg/g

SSeeee AASSTTMM MMeetthhooddss DD--22662222,, DD--33112200,, DD--33224466--9922,, DD--44229944,, DD--55445533 ffoorr SSuullffuurr CCaalliibbrraattiioonn SSttaannddaarrddss

OOlleeffiinnss QQCC SSaammpplleeSSBBPPTT--OOLLEEFFIINN $$ 2255 // 22 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd AApppprrooxx.. RRaannggeeTotal Aromatics D-1319 8-60 Vol.%Total Olefins D-1319 1 - 40 Vol.%Total Saturates D-1319 30-80 Vol. %

SSeeee AASSTTMM MMeetthhoodd DD--11331199 ffoorr SSuullffuurr CCaalliibbrraattiioonnSSttaannddaarrddss

AAccccuuPPeettrrooTTeesstt SSiinnggllee BBlliinnddSSttaannddaarrddssPetrochemical Laboratories looking totest the performance of the laboratory fora specific parameter can order the SingleBlind AccuPetroTest sample for theparameter of interest. Two real worldgasoline samples will be sent for the testparameter requested and a separate sealedenvelope containing the determinedConsensus Value is also provided. Thesecond sample is for repeatability testingor as a future QA/QC reference.

AArroommaattiiccss QQCC SSaammpplleeSSBBPPTT--AARROOMM $$ 2255 // 22 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd AApppprrooxx.. RRaannggeeTotal Aromatics D-5769 8 - 60 Vol.%

SSeeee AASSTTMM MMeetthhooddss DD--33660066,, DD--55558800--9955,, DD--55776699--9955ffoorr BBeennzzeennee CCaalliibbrraattiioonn SSttaannddaarrddss

BBeennzzeennee//TToolluueennee QQCC SSaammpplleeSSBBPPTT--BBEENNZZ $$ 2255 // 22 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd AApppprrooxx.. RRaannggeeBenzene D-5769 0.1 - 2.0 Vol.%Toluene D-5769 1.0 - 15 Vol.%

SSeeee AASSTTMM MMeetthhooddss DD--33660066,, DD--55558800--9955,, DD--55776699--9955ffoorr BBeennzzeennee CCaalliibbrraattiioonn SSttaannddaarrddss

LLooww SSuullffuurr QQCC SSaammpplleeSSBBPPTT--LLSSGGAASS $$ 2255 // 22 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd AApppprrooxx.. RRaannggeeSulfur 5453 0 - 50 µg/g

SSuullffuurr SSiinnggllee BBlliinndd AAccccuuPPeettrrooTTeessttAAlltteerrnnaattiivvee MMaattrriicceess SSttaannddaarrddssAccuStandard has manufactured a number ofDiesel and White Mineral Oil quality controlproducts containing a gravimetrically preparedamount of Sulfur. Use of these alternativematrix materials can provide further evaluationof the QA/QC process in the laboratory. Twosamples will be sent for the test parameter anda separate sealed envelope containing thegravimetrically prepared sulfur values is alsoprovided. The second sample is forrepeatability testing or for use as a futureQA/QC reference.

SSuullffuurr iinn WWhhiittee MMiinneerraall OOiill QQCCSSttaannddaarrddSSBBPPTT--SSWWMMOO $$ 2255 // 22 xx 1155 mmLL

PPaarraammeetteerr AApppprrooxx.. RRaannggeeSulfur 20 - 11000 mg/kg

SSeeee AASSTTMM MMeetthhooddss DD--22662222,, DD--33112200,, DD--33224466--9922,, DD--44229944,, DD--55445533 ffoorr SSuullffuurrCCaalliibbrraattiioonn SSttaannddaarrddss

SSuullffuurr iinn DDiieesseell FFuueell QQCC SSttaannddaarrddSSBBPPTT--SSDDFF $$ 2255 // 22 xx 1155 mmLL

PPaarraammeetteerr AApppprrooxx.. RRaannggeeSulfur 20 - 11000 mg/kg

SSeeee AASSTTMM MMeetthhooddss DD--22662222,, DD--33112200,, DD--33224466--9922,, DD--44229944,, DD--55445533,, ffoorr SSuullffuurr CCaalliibbrraattiioonn SSttaannddaarrddss

Petrochemical Standards

OOlleeffiinn QQCC SSaammpplleeSSBBPPTT--OOLLEEFFIINNSSFFCC $$ 2255 // 22 xx 1155 mmLL

PPaarraammeetteerr MMeetthhoodd AApppprrooxx.. RRaannggeeOlefins 6550 1 - 40 Vol.%

Test toLow ppb

SulfurSee Pages 6-11

Technical NoteOur new comprehensive singleblind gasoline QC sample tests formore parameters from a singlesample. The actual gasolinesample will have consensusvalues listed on the datasheet thatfall within the range listed for eachparameter.



ASTM D-5769 Benzene, Toluene & Total Aromatics in Finished Gasoline by GC/MS

MMeemmbbeerr

ASTM


AASSTTMM MMeetthhoodd DD--55776699--9988BBeennzzeennee,, TToolluueennee,, aanndd TToottaall AArroommaattiiccss iinn FFiinniisshheedd GGaassoolliinnee bbyy GGCC//MMSS

ASTM Standards

All of your standards requirements for ASTM Method D-5769 have been put together in thefollowing 10 pages. These standards and methods are used in the monitoring of TotalAromatics according to the latest methods and amendments to the US Clean Air Act.

A set of Amendments, containing more stringent specifications became effective January 1,1995 limiting the volatility and composition of reformulated gasoline.

The D-02 Committee of the American Society of Testing Materials, developed a standard testmethod D-5769 for the determination of the analyte composition by GC/MS of reformulatedgasoline.

Method 5769


Aromatic Product Line yields the following important benefits

FFeeaattuurreess:: BBeenneeffiittss::Purity and Identity of all analytes verified .......... Impurity interferences in analyte retention time under identical operating conditions window are compensated.

Certified method specific calibration standards . Increased confidence in analytical results.

Eliminates preparation of calibration standards ..Time is utilized quantifying actual samples.

Internal Standards Incorporated ......................... Saves time.

Weights and weight percents provided .............. Ease of use in performing back calculations.

Includes all necessary solutions .........................Complete single source for reference materials.

Variations in packaging size .............................. Meet laboratory sample volumes and demands.

Low Cost ............................................................ More economical to purchase than to prepare standards.

Flexibility ............................................................ Meet your lab requirements/method changes.

Only 5 standards needed for a 5 Point Curve ... Generate a full calibration curve in 1/2 the time of the two set version composed of 10 standards.

No charge disk deliverable calibration curve .... Direct computer uploading eliminates the input of 135 weights (CALAMTS™) separate data points.



ASTM D-5769 Benzene, Toluene & Total Aromatics in Finished Gasoline by GC/MS

MMeemmbbeerr

ASTM


ASTM Standards

SSttaannddaarrddss DDeessiiggnneedd ffoorr AASSTTMM DD--55776699 aass ppuubblliisshheedd iinn tthhee 11999977 AAnnnnuuaall BBooookk ooff AASSTTMM SSttaannddaarrddss,, VVooll..0055..0033 PPeettrroolleeuumm PPrroodduuccttss aanndd LLuubbrriiccaannttss ((IIIIII)):: DD--44663366--llaatteesstt;; CCaattaallyyssttssThe following MM--GGRRAA catalog numbers contain the necessary calibration curves, daily quality control, andinternal standards designed to meet the promulgated GC/MS Aromatic method listed in the 1997 ASTMBook of Standards.AccuStandard offers two different versions of the MM--GGRRAA catalog numbers: MM--GGRRAA tthhrreeee ccoommppoonneennttiinntteerrnnaall ssttaannddaarrdd vveerrssiioonn,, and the MM--GGRRAA ffoouurr ccoommppoonneenntt iinntteerrnnaall ssttaannddaarrdd vveerrssiioonn.The tthhrreeee ccoommppoonneenntt iinntteerrnnaall ssttaannddaarrdd vveerrssiioonn contains the necessary deuterated analytes for fullqualitative and quantitative analysis of the 25 components listed in the published version. The ffoouurr ccoommppoonneenntt iinntteerrnnaall ssttaannddaarrdd vveerrssiioonn was designed at the request of the petroleum refinerylaboratories. This four internal standard version incorporates not only the Benzene-d6, Ethyl benzene-d10,Naphthalene-d8, but also Toluene-d8. Incorporating the Toluene-d8 as the internal standard for thequantification of gasolines with higher Toluene levels has improved analytical results for this analyte. IInnccoorrppoorraattiioonn ooff aa 66tthh CCaalliibbrraattiioonn SSttaannddaarrddAA 66tthh ccaalliibbrraattiioonn ssttaannddaarrdd has been formulated for the M-GRA product line to improve the linearity at thehigh end of the calibration curve see page 44. This sixth standard can be especially important in thequantification of gasoline samples containing high toluene levels. The formulation contains an analyteconcentration between the high level standard and the next level, which is standard two. Use of the sixthstandard provides an additional calibration point that is desirable when the calibration curve is developedusing a quadratic fit.

MM--GGRRAA--KK22 $$ 770000(Developed for improved high concentration linearity)

KKiitt iinncclluuddeess:: UUnniittss FFuunnccttiioonnM-GRA-CAL/IS-SET 5 x 1 mL 5 Pt. Curve w/ 3 ISTD'sM-GRA-ADD/IS 1 x 1 mL 6th Std. for revison 5 FM-GRA-QC/IS-5ML 1 x 5 mL Daily QC w/ 3 ISTD'sM-GRA-IS-5ML 1 x 5 mL Internal Std. 3 comps. M-GRA-ST 1 x 1 mL Sensitivity Test Solution

SSeeee ppaaggee 4444 ffoorr pprroodduucctt ddeessccrriippttiioonn wwiitthhaannaallyytteess && ccoonncc..

FFoorr yyoouurr aaddddeedd ccoonnvveenniieennccee wwee hhaavveepprroovviiddeedd tthhee ffoolllloowwiinngg AArroommaattiiccss KKiittss ttoommeeeett tthhee aannaallyyttiiccaall rreeqquuiirreemmeennttss ffoorr tthhiissmmeetthhoodd..

AArroommaattiiccss KKiittss ffoorr aannaallyyssiiss bbyy GGCC//MMSS

MM--GGRRAA--KK44 $$ 885500(Used to meet the Toluene-d8 internal standard versionrecommended by a network of major petroleum refineries)

KKiitt iinncclluuddeess:: UUnniittss FFuunnccttiioonnM-GRA-CAL-R/IS-R-SET5 x 1 mL 5 Pt. Curve w/ 4 ISTD'sM-GRA-ADD/IS-R 1 x 1 mL 6th Standard for rev. 5 FM-GRA-QC-R/IS-R-5ML 1 x 5 mL Daily QC w/ 4 ISTD'sM-GRA-IS-R-10ML 1 x 10 mL Internal Std. 4 comps.M-GRA-ST 1 x 1 mL Sensitivity Test Solution


MM--GGRRAA--KK11 $$ 660000(Original Formulations)

KKiitt iinncclluuddeess:: UUnniittss FFuunnccttiioonnM-GRA-CAL/IS-SET 5 x 1 mL 5 Pt. Curve w/ 3 ISTD'sM-GRA-QC/IS-5ML 1 x 5 mL Daily QC w/ 3 ISTD'sM-GRA-IS-5ML 1 x 5 mL Internal Std. 3 comps.M-GRA-ST 1 x 1 mL Sensitivity Test Solution




Method 5769




ASTM D-5769 Calibration Curve with 3 Component Deuterated Internal Standard Added

MMeemmbbeerr

ASTM


ASTM Standards

DDiisskk DDeelliivveerraabbllee((AAtt nnoo aaddddiittiioonnaall cchhaarrggee))

EElliimmiinnaatteess hhaanndd kkeeyyeedd--iinn ddaattaa..

CCAALLAAMMTTSS™™((DDiisskk ccoonnttaaiinniinngg ““CCaalliibbrraattiioonn

AAmmoouunnttss””))

EEaacchh aannaallyyttee iinn eeaacchh ssttaannddaarrddiiss iinnddiivviidduuaallllyy wweeiigghheedd.. AAccttuuaallwweeiigghhttss aanndd wweeiigghhtt ppeerrcceennttssaarree pprroovviiddeedd..

CCoommppoouunndd MMiixx RRaattiiooNaphthalene-d8 1 gm

CCoommppoouunndd MMiixx RRaattiiooBenzene-d6 2 mLEthylbenzene-d10 2 mL

WWtt.. CCoommppoouunndd RRaattiiooToluene 9Ethylbenzene 3m-Xylene 3o-Xylene 31,2,4-Trimethylbenzene 31,2,4,5-Tetramethylbenzene 3

13 Comp. Core Mix 100

Includes MM--GGRRAA--IISS (3 Comp. Internal Standards mix)combined with the above 13 Comp. Core QC Mix: MM--GGRRAA--QQCC in a 5 to 100 weight ratio. 16 comps.

WWtt.. CCoommppoouunndd RRaattiioon-Hexane 12n-Heptane 17n-Octane 17n-Decane 12n-Dodecane 5Isooctane 12Benzene 1




DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd))MM--GGRRAA--QQCC//IISS--55MMLL $$ 110000 // 11 xx 55 mmLLMM--GGRRAA--QQCC//IISS--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 440000 // 55 xx 55 mmLL

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))MM--GGRRAA--QQCC--1100MMLL $$ 112255 // 11 xx 1100 mmLLMM--GGRRAA--QQCC--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 550000 // 55 xx 1100 mmLL

33 CCoommpp.. DDeeuutteerraatteedd IInntteerrnnaall SSttdd.. MMiixxMM--GGRRAA--IISS--55MMLL $$ 115500 // 11 xx 55 mmLLMM--GGRRAA--IISS--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 660000 // 55 xx 55 mmLL

3 comps.

AASSTTMM//EEPPAA SSeennssiittiivviittyy TTeesstt SSoolluuttiioonnMM--GGRRAA--SSTT $$ 1100 // 11 xx 11 mmLLMM--GGRRAA--SSTT--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 11 mmLL100 µg/mL in Isooctane

1,4-Diethyl benzene

CCoorree CCaalliibbrr.. MMiixx OOppttiioonnaall SSttdd.. 662244 CCoommppss.. TTaarrggeett VVooll.. %%

Benzene 2.25Toluene 15Ethylbenzene 3.75m-Xylene 4.50p-Xylene 4.50o-Xylene 4.50Isopropylbenzene 2.25n-Proplylbenzene 2.253-Ethyltoluene 2.254-Ethyltoluene 2.251,3,5-Trimethylbenzene 2.252-Ethyltoluene 2.251,2,4-Trimethylbenzene 3.751,2,3-Trimethylbenzene 2.25Indan 2.251,4-Diethylbenzene 2.25n-Butylbenzene 2.251,2-Diethylbenzene 2.251,2,4,5-Tetramethylbenzene 4.01,2,3,5-Tetramethylbenzene 1.5Naphthalene 1.5Pentamethylbenzene 1.51-Methylnaphthalene 1.52-Methylnaphthalene 1.5Isooctane Bal

IInntteerrnnaall SSttaannddaarrdd ((MM--GGRRAA--IISS))Benzene-d6 2Ethylbenzene-d10 2Naphthalene-d8 1

CCoorree CCaalliibbrr.. MMiixx SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 552244 CCoommppss.. TTaarrggeett VVooll.. %%VVooll.. %% VVooll.. %% VVooll.. %% VVooll.. %%

Benzene 3 1.50 0.75 0.375 0.1875Toluene 19 9.50 4.75 2.375 1.1875Ethylbenzene 5 2.50 1.25 0.625 0.3125m-Xylene 6 3.00 1.50 0.750 0.3750p-Xylene 6 3.00 1.50 0.750 0.3750o-Xylene 6 3.00 1.50 0.750 0.3750Isopropylbenzene 3 1.50 0.75 0.375 0.1875n-Propylbenzene 3 1.50 0.75 0.375 0.18751-Methyl-3-ethylbenzene 3 1.50 0.75 0.375 0.18751-Methyl-4-ethylbenzene 3 1.50 0.75 0.375 0.18751,3,5-Trimethylbenzene 3 1.50 0.75 0.375 0.18751-Methyl-2-ethylbenzene 3 1.50 0.75 0.375 0.18751,2,4-Trimethylbenzene 5 2.50 1.25 0.625 0.31251,2,3-Trimethylbenzene 3 1.50 0.75 0.375 0.1875Indan 3 1.50 0.75 0.375 0.18751,4-Diethylbenzene 3 1.50 0.75 0.375 0.1875n-Butylbenzene 3 1.50 0.75 0.375 0.18751,2-Diethylbenzene 3 1.50 0.75 0.375 0.18751,2,4,5-Tetramethylbenzene 2 1.00 0.50 0.250 0.12501,2,3,5-Tetramethylbenzene 2 1.00 0.50 0.250 0.1250Naphthalene 2 1.00 0.50 0.250 0.1250Pentamethylbenzene 2 1.00 0.50 0.250 0.12501-Methylnaphthalene 2 1.00 0.50 0.250 0.12502-Methylnaphthalene 2 1.00 0.50 0.250 0.1250Isooctane -- Bal Bal Bal Bal

IInntteerrnnaall SSttaannddaarrdd ((MM--GGRRAA--IISS))Benzene-d6 2 2 2 2 2Ethylbenzene-d10 2 2 2 2 2Naphthalene-d8 1 1 1 1 1

OOppttiioonnaall SSiixxtthh SSttaannddaarrddwwiitthh 33 CCoommpp.. DDeeuutteerraatteeddIInntteerrnnaall SSttaannddaarrdd AAddddeeddMM--GGRRAA--AADDDD//IISS $$ 110000 // 11 xx 11 mmLL

AArroommaattiiccss CCaalliibbrraattiioonn SSttaannddaarrddss KKiitt((33 IInntteerrnnaall SSttaannddaarrdd VVeerrssiioonn))MM--GGRRAA--CCAALL//IISS--SSEETT $$ 337755 // sseett ooff 55 xx 11 mmLL

Method 5769


Technical NoteUse with any M-GRA Calibration Curve.



ASTM D-5769 Calibration Curve with 4 Component Deuterated Internal Standard Added

MMeemmbbeerr

ASTM


ASTM Standards

CCoommppoouunndd MMiixx RRaattiiooNaphthalene-d8 1 gmToluene-d8 7 mL





Includes MM--GGRRAA--IISS--RR (4 Comp. Internal StandardsMix) combined with the above 13 Comp. Core QC Mix:MM--GGRRAA--QQCC in a 12 to 100 weight ratio. 17 comps.




DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd MM--GGRRAA--IISS--RR))MM--GGRRAA--QQCC//IISS--RR--55MMLL $$ 112255 // 11 xx 55 mmLLMM--GGRRAA--QQCC//IISS--RR--55MMLL--PPAAKKSSAAVVEE 2200%% $$ 550000 // 55 xx 55mmLL

AASSTTMM//EEPPAA SSeennssiittiivviittyy TTeesstt SSoolluuttiioonnMM--GGRRAA--SSTT $$ 1100 // 11 xx 11 mmLLMM--GGRRAA--SSTT--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 11 mmLL100 µg/mL in Isooctane

1,4-Diethyl benzene


44 CCoommpp.. DDeeuutteerraatteedd IInntteerrnnaall SSttdd.. MMiixxMM--GGRRAA--IISS--RR--1100MMLL $$ 222255 // 11 xx 1100 mmLLMM--GGRRAA--IISS--RR--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 990000 // 55 xx 1100 mmLL

4 comps.

The 4 component internal standard mix (M-GRA-IS-R) is combined with the 25 component core calibrationcurve mixtures in a 12 to 100 weight ratio to formulate a complete calibration solution containing 29 comps.

OOppttiioonnaall SSiixxtthh SSttaannddaarrddwwiitthh 44 CCoommpp.. DDeeuutteerraatteeddIInntteerrnnaall SSttaannddaarrdd AAddddeeddMM--GGRRAA--AADDDD//IISS--RR $$ 110000 // 11 xx 11 mmLL

AArroommaattiiccss CCaalliibbrraattiioonn SSttaannddaarrddss KKiitt((44 IInntteerrnnaall SSttaannddaarrdd VVeerrssiioonn))MM--GGRRAA--CCAALL--RR//IISS--RR--SSEETT $$ 442255 // sseett ooff 55 xx 11 mmLL

Method 5769

CCoorree CCaalliibbrr.. MMiixx SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 552244 CCoommppss.. TTaarrggeett WWtt.. %%WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %%

Benzene 3.13 1.78 0.95 0.490 0.2490Toluene 19.65 11.11 5.90 3.058 1.5547Ethylbenzene 5.12 2.92 1.55 0.805 0.4090m-Xylene 6.27 3.50 1.86 0.962 0.4891p-Xylene 6.33 3.50 1.86 0.962 0.4891o-Xylene 6.51 3.56 1.89 0.980 0.4981Isopropylbenzene 3.06 1.74 0.93 0.480 0.2439n-Propylbenzene 3.04 1.74 0.93 0.480 0.24403-Ethyltoluene 3.08 1.75 0.93 0.481 0.24464-Ethyltoluene 3.05 1.74 0.93 0.479 0.24371,3,5-Trimethylbenzene 3.07 1.75 0.93 0.481 0.24482-Ethyltoluene 3.14 1.78 0.95 0.490 0.24921,2,4-Trimethylbenzene 5.18 2.95 1.57 0.812 0.41301,2,3-Trimethylbenzene 3.19 1.81 0.96 0.498 0.2530Indan 3.46 1.95 1.04 0.536 0.27261,4-Diethylbenzene 3.04 1.74 0.93 0.480 0.2439n-Butylbenzene 3.05 1.74 0.92 0.479 0.24341,2-Diethylbenzene 3.22 1.78 0.95 0.490 0.24891,2,4,5-Tetramethylbenzene 2.10 1.20 0.64 0.329 0.16741,2,3,5-Tetramethylbenzene 2.09 1.20 0.64 0.330 0.1679Naphthalene 2.35 1.34 0.71 0.369 0.1877Pentamethylbenzene 2.16 1.23 0.66 0.340 0.17271-Methylnaphthalene 2.32 1.34 0.71 0.369 0.18772-Methylnaphthalene 2.41 1.37 0.73 0.378 0.1922Isooctane ----- 43.47 69.96 84.441 92.0905

IInntteerrnnaall SSttaannddaarrdd((MM--GGRRAA--IISS--RR)) MMiixx RRaattiiooBenzene-d6 (2 mL) 16.57 16.57 16.57 16.57 16.57Ethylbenzene-d10 (2 mL) 16.76 16.76 16.76 16.76 16.76Naphthalene-d8 (1 gm) 8.78 8.78 8.78 8.78 8.78Toluene-d8 (7 mL) 57.88 57.88 57.88 57.88 57.88

CCoorree CCaalliibbrr.. MMiixx OOppttiioonnaall SSttdd.. 662244 CCoommppss.. TTaarrggeett WWtt.. %%

Benzene 2.48Toluene 16.29Ethylbenzene 4.07m-Xylene 4.87p-Xylene 4.87o-Xylene 4.96Isopropylbenzene 2.43n-Propylbenzene 2.433-Ethyltoluene 2.444-Ethyltoluene 2.431,3,5-Trimethylbenzene 2.442-Ethyltoluene 2.481,2,4-Trimethylbenzene 4.111,2,3-Trimethylbenzene 2.52Indan 2.711,4-Diethylbenzene 2.43n-Butylbenzene 2.421,2-Diethylbenzene 2.481,2,4,5-Tetramethylbenzene 4.441,2,3,5-Tetramethylbenzene 1.67Naphthalene 1.87Pentamethylbenzene 1.721-Methylnaphthalene 1.872-Methylnaphthalene 1.91Isooctane 17.67

IInntteerrnnaall SSttaannddaarrdd((MM--GGRRAA--IISS--RR)) MMiixx RRaattiiooBenzene-d6 (2 mL) 16.57Ethylbenzene-d10 (2 mL) 16.76Naphthalene-d8 (1 mL) 8.78Toluene-d8 (7 mL) 57.88


Technical NoteUse with any M-GRA Calibration Curve.

Technical NoteThis set of calibration solutionswas formulated to improvequantification for Toluene byusing Toluene-d8 as anadditional Internal Standard.

Standards of InterestFor the mandatory real worldQC samples stipulated in theMethod, see pages 1-2



ASTM D-5769 Version with No Internal Standard

MMeemmbbeerr

ASTM


ASTM Standards

WWtt..CCoommppoouunndd RRaattiiooToluene 9Ethylbenzene 3m-Xylene 3o-Xylene 31,2,4-Trimethylbenzene 31,2,4,5-Tetramethylbenzene 2Naphthalene 1


MMiixx CCoommppoouunndd RRaattiiooNaphthalene-d8 1 gmToluene-d8 7 mL

WWtt..CCoommppoouunndd RRaattiioon-Hexane 12n-Heptane 17n-Octane 17n-Decane 12n-Dodecane 5Isooctane 12Benzene 1

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))DD--55776699--QQCC--1100MMLL $$ 112255 // 11 xx 1100 mmLLDD--55776699--QQCC--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 550000 // 55 xx 1100 mmLL

MMiixx CCoommppoouunndd RRaattiiooBenzene-d6 2 mLEthylbenzene-d10 2 mL

CCoommppoouunndd MMiixx RRaattiiooBenzene-d6 2 mLEthylbenzene-d10 2 mLNaphthalene-d8 1 gm

CCaalliibbrraattiioonn CCuurrvvee wwiitthh NNoo IInntteerrnnaall SSttdd.. AAddddeeddDD--55776699--CCAALL--SSEETT--55MMLL $$ 11550000 // SSeett ooff 55 xx 55 mmLLDD--55776699--CCAALL--SSEETT--1100MMLL $$ 22775500 // SSeett ooff 55 xx 1100 mmLL

CCoorree CCaalliibbrraattiioonn MMiixx TTaarrggeett 2233 CCoommppss.. WWtt.. %%

Benzene 4.16Toluene 16.41Ethylbenzene 4.10m-Xylene 4.91p-Xylene 4.91o-Xylene 5.00Isopropylbenzene 2.45n-Propylbenzene 2.453-Ethyltoluene 2.454-Ethyltoluene 2.441,3,5-Trimethylbenzene 2.462-Ethyltoluene 2.501,2,4-Trimethylbenzene 4.141,2,3-Trimethylbenzene 2.54Indan 2.731,4-Diethylbenzene 2.45n-Butylbenzene 2.441,2-Diethylbenzene 2.501,2,4,5-Tetramethylbenzene 1.681,2,3,5-Tetramethylbenzene 1.68Naphthalene 1.881-Methylnaphthalene 1.882-Methylnaphthalene 1.93Isooctane 19.92

CCoorree CCaalliibbrr.. MMiixx SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44 SSttdd.. 552233 CCoommppss.. TTaarrggeett WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %% WWtt.. %%

Benzene 5.25 2.95 1.575 0.8144 0.4143Toluene 19.67 11.06 5.898 3.0505 1.5519Ethylbenzene 5.18 2.91 1.552 0.8026 0.4083m-Xylene 6.19 3.48 1.856 0.9598 0.4883p-Xylene 6.19 3.48 1.856 0.9598 0.4883o-Xylene 6.30 3.54 1.890 0.9776 0.4973Isopropylbenzene 3.09 1.74 0.925 0.4786 0.2435n-Propylbenzene 3.09 1.74 0.926 0.4787 0.24353-Ethyltoluene 3.10 1.74 0.928 0.4801 0.24424-Ethyltoluene 3.08 1.73 0.925 0.4782 0.24331,3,5-Trimethylbenzene 3.10 1.74 0.929 0.4804 0.24442-Ethyltoluene 3.15 1.77 0.945 0.4890 0.24881,2,4-Trimethylbenzene 5.23 2.94 1.567 0.8104 0.41231,2,3-Trimethylbenzene 3.20 1.80 0.960 0.4965 0.2526Indan 3.45 1.94 1.034 0.5350 0.27221,4-Diethylbenzene 3.09 1.74 0.925 0.4786 0.2435n-Butylbenzene 3.08 1.73 0.923 0.4776 0.24301,2-Diethylbenzene 3.15 1.77 0.945 0.4885 0.24851,2,4,5-Tetramethylbenzene 2.12 1.19 0.635 0.3284 0.16711,2,3,5-Tetramethylbenzene 2.12 1.19 0.637 0.3295 0.1676Naphthalene 2.37 1.34 0.712 0.3683 0.18741-Methylnaphthalene 2.37 1.34 0.712 0.3683 0.18742-Methylnaphthalene 2.43 1.37 0.730 0.3773 0.1919Isooctane ----- 43.77 70.015 84.4922 92.1105

OOppttiioonnaall SSiixxtthh SSttaannddaarrddDD--55776699--AADDDD--55MMLL $$ 115500 // 11 xx 55 mmLLDD--55776699--AADDDD--1100MMLL $$ 330000 // 11 xx 1100 mmLL


4 comps.


3 comps.

The following D-5769 and M-GRA Standards were formulated to address proposed and promulgatedchanges to ASTM Method D-5769-98 Aromatics by GC/MS. Many of these changes were evaluated and/or adopted due to the results generated from the 1997 Round Robin, which used a select group of 21gasolines ampulized by AccuStandard.

AccuStandard is committed to staying abreast of ASTM committee D-02 method developments. We askthat you contact us when your analytical group finds a beneficial procedure or modification.

MMooddiiffiiccaattiioonnss

A SSiixxtthh SSttaannddaarrdd was added to meet the latest D-5769 method requirements and provide improvedlinearity at the high end of the Calibration curve

The CCaalliibbrraattiioonn CCuurrvvee was packaged in two convenient sizes without the internal standard. Thispackaging scheme allows for the addition of any ISTD formulation or oxygenate components.

The QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd was reformulated in the latest D-5769 revision. The formulation changesinclude reducing the 1,2,4,5-Tetramethylbenzene weight ratio and adding Naphthalene.The BBeennzzeennee TTaarrggeett WWeeiigghhtt %% has been increased to meet the latest D-5769 method requirements.PPeennttaammeetthhyyllbbeennzzeennee has now been removed from the analyte list. DDiisskk DDeelliivveerraabbllee

((AAtt nnoo aaddddiittiioonnaall cchhaarrggee))


CCAALLAAMMTTSS®®

((DDiisskk ccoonnttaaiinniinngg ““CCaalliibbrraattiioonnAAmmoouunnttss””))


Method 5769




ASTM D-5769 Version with 3 Internal Standards

MMeemmbbeerr

ASTM


ASTM Standards


IInncclluuddeess MM--GGRRAA--IISS ((33 ccoommppoonneenntt mmiixx)) aaddddeedd iinn 55 ttoo 110000 wweeiigghhtt rraattiioo

WWtt..CCoommppoouunndd RRaattiiooToluene 9Ethylbenzene 3m-Xylene 3o-Xylene 31,2,4-Trimethylbenzene 31,2,4,5-Tetramethylbenzene 2Naphthalene 1

100

WWtt..CCoommppoouunndd RRaattiioon-Hexane 12n-Heptane 17n-Octane 17n-Decane 12n-Dodecane 5Isooctane 12Benzene 1

OOppttiioonnaall SSiixxtthh SSttaannddaarrddwwiitthh aa 33 CCoommpp.. DDeeuutteerraatteeddIInntteerrnnaall SSttaannddaarrdd aaddddeeddDD--55776699--AADDDD//IISS $$ 110000 // 11 xx 11 mmLL



CCoorree CCaalliibbrraattiioonn MMiixx TTaarrggeett 2244 CCoommppss.. WWtt.. %%


MMaassss SSccaann RRaannggee SSttaannddaarrddMM--GGRRAA--MMSSRR $$ 2200 // 11 xx 11 mmLLMM--GGRRAA--MMSSRR--PPAAKK SSAAVVEE 2200%% $$ 8800 // 55 xx 11 mmLL3.0% w/w in Isooctane

Toluene

RReessoolluuttiioonn SSttaannddaarrddMM--GGRRAA--RREESS $$ 3300 // 11 xx 11 mmLLMM--GGRRAA--RREESS--PPAAKK $$ 112200 // 55 xx 11 mmLL

WWtt.. %% 3 comps.1,3,5-Trimethylbenzene 3.01-Methyl-2-ethylbenzene 3.0Isooctane 94

CCoommppoouunndd MMiixx rraattiiooBenzene-d6 2 mLEthylbenzene-d10 2 mLNaphthalene-d8 1 gm

IInntteerrnnaall SSttaannddaarrddMM--GGRRAA--IISS

The 3 Comp. Internal Standard Mix (M-GRA-IS) iscombined with the 24 Comp. Core Calibration Curve Mixesabove in a 5 to 100 weight ratio to formulate these 27 Comp. calibration solutions.

FFrraaggmmeennttaattiioonn PPaatttteerrnn SSttaannddaarrddMM--GGRRAA--FFPP $$ 2200 // 11 xx 11 mmLLMM--GGRRAA--FFPP--PPAAKK SSAAVVEE 2200%% $$ 8800 // 55 xx 11 mmLL3.0% w/w in Isooctane

1,2,3-Trimethylbenzene

SSeennssiittiivviittyy TTeesstt SSoolluuttiioonnMM--GGRRAA--SSTT $$ 1100 // 11 xx 11 mmLLMM--GGRRAA--SSTT--PPAAKK SSAAVVEE 2200%% $$ 4400 // 55 xx 11 mmLL100 µg/mL in Isooctane

1,4-Diethyl benzene


3 comps.

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd))DD--55776699--QQCC//IISS--55MMLL $$ 110000 // 11 xx 55 mmLLDD--55776699--QQCC//IISS--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 440000 // 55 xx 55 mmLL

17 comps.

Method 5769

CCaalliibbrraattiioonn CCuurrvvee wwiitthh aa 33 CCoommpp.. DDeeuutteerraatteeddIInntteerrnnaall SSttaannddaarrdd aaddddeeddDD--55776699--CCAALL//IISS--SSEETT $$ 337755 // 55 xx 11 mmLL

Test toLow ppb

SulfurSee Pages 6-11




ASTM D-5769 4 Internal Standard Version (includes Toluene-d8)

MMeemmbbeerr

ASTM


ASTM Standards

CCoommppoouunndd WWtt.. %%1,3,5-Trimethylbenzene 3.01-Methyl-2-ethylbenzene 3.0Isooctane 94

CCoommppoouunndd MMiixx RRaattiiooNaphthalene-d8 1 gmToluene-d8 7 mL


WWtt.. CCoommppoouunndd RRaattiiooToluene 9Ethylbenzene 3m-Xylene 3o-Xylene 31,2,4-Trimethylbenzene 31,2,4,5-Tetramethylbenzene 2Naphthalene 1

100IInncclluuddeess MM--GGRRAA--IISS--RR ((44 ccoommppoonneenntt mmiixx)) aaddddeedd iinn 1122 ttoo 110000 wweeiigghhtt rraattiioo




CCoorree CCaalliibbrraattiioonn MMiixx TTaarrggeett 2244 CCoommpp.. WWtt.. %%


OOppttiioonnaall SSiixxtthh SSttaannddaarrddwwiitthh aa 44 CCoommpp.. DDeeuutteerraatteeddIInntteerrnnaall SSttaannddaarrdd aaddddeeddDD--55776699--AADDDD//IISS--RR $$ 110000 // 11 xx 11 mmLL

CCaalliibbrraattiioonn CCuurrvvee wwiitthh aa 44 CCoommpp.. DDeeuutteerraatteeddIInntteerrnnaall SSttaannddaarrdd aaddddeeddDD--55776699--CCAALL//IISS--RR--SSEETT $$ 442255 // 55 xx 11 mmLL

RReessoolluuttiioonn SSttaannddaarrddMM--GGRRAA--RREESS $$ 3300 // 11 xx 11 mmLLMM--GGRRAA--RREESS--PPAAKK SSAAVVEE 2200%% $$ 112200 // 55 xx 11 mmLL

3 comps.

CCoommppoouunndd MMiixx rraattiiooBenzene-d6 2 mLEthylbenzene-d10 2 mLNaphthalene-d8 1 gmToluene-d8 7 mL

IInntteerrnnaall SSttaannddaarrddMM--GGRRAA--IISS--RR

The 4 Comp. Internal Standard Mix (M-GRA-IS-R) iscombined with the 24 component core calibrationcurve mixtures above in a 12 to 100 weight ratio toformulate these 28 component calibration solutions.

FFrraaggmmeennttaattiioonn PPaatttteerrnn SSttaannddaarrddMM--GGRRAA--FFPP $$ 2200 // 11 xx 11 mmLLMM--GGRRAA--FFPP--PPAAKK SSAAVVEE 2200%% $$ 8800 // 55 xx 11 mmLL3.0 w/w in Isooctane



1,4-Diethyl benzene

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd))DD--55776699--QQCC//IISS--RR--55MMLL $$ 110000 // 11 xx 55 mmLLDD--55776699--QQCC//IISS--RR--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 440000//55 xx 55 mmLL

18 comps.

44 CCoommpp.. DDeeuutteerraatteedd IInntteerrnnaall SSttdd.. MMiixxMM--GGRRAA--IISS--RR--1100MMLL $$ 222255 // 11 xx 1100 mmLLMM--GGRRAA--IISS--RR--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 990000// 55 xx 1100 mmLL

Method 5769




ASTM D-5769 New Proposed / Promulgated Method Modifications

MMeemmbbeerr

ASTM


ASTM Standards

CCoommppoouunndd WWtt.. %%1,3,5-Trimethylbenzene 3.01-Methyl-2-ethylbenzene 3.0Isooctane 94

CCoommppoouunndd MMiixx RRaattiiooChlorobenzene 2 mL1,2-Dichlorobenzene 2 mL1,2,4-Trichlorobenzene 1 mL

WWtt.. CCoommppoouunndd RRaattiiooToluene 9Ethylbenzene 3m-Xylene 3o-Xylene 31,2,4-Trimethylbenzene 31,2,4,5-Tetramethylbenzene 2Naphthalene 1

100IInncclluuddeess MM--GGRRAA--IISS--RR22 ((33 ccoommppoonneenntt mmiixx)) aaddddeedd iinn 55 ttoo 110000 wweeiigghhtt rraattiioo


CCoorree CCaalliibbrraattiioonn MMiixx TTaarrggeett 2244 CCoommppoonneenntt WWtt..%%


CCaalliibbrraattiioonn CCuurrvvee wwiitthh aa 33 CCoommpp.. CChhlloorriinnaatteeddIInntteerrnnaall SSttaannddaarrdd aaddddeeddDD--55776699--CCAALL//IISS--RR22--SSEETT $$ 337755 // 55 xx 11 mmLL

OOppttiioonnaall SSiixxtthh SSttaannddaarrdd wwiitthhaa 33 CCoommpp.. CChhlloorriinnaatteeddIInntteerrnnaall SSttaannddaarrdd aaddddeeddDD--55776699--AADDDD//IISS--RR22 $$ 110000 // 11 xx 11 mmLL



RReessoolluuttiioonn SSttaannddaarrddMM--GGRRAA--RREESS $$ 3300 // 11 xx 11 mmLLMM--GGRRAA--RREESS--PPAAKK SSAAVVEE 2200%% $$ 112200 // 55 xx 11 mmLL

3 comps.

33 CCoommpp.. CChhlloorriinnaatteedd IInntteerrnnaall SSttdd.. MMiixxMM--GGRRAA--IISS--RR22--SSEETT $$112255 // sseett ooff 2255 xx 11 mmLLMM--GGRRAA--IISS--RR22--2255MMLL $$ 110000 // 11 xx 2255 mmLL

3 comps.

CCoommppoouunndd MMiixx rraattiiooChlorobenzene 2 mL1,2-Dichlorobenzene 2 mL1,2,4-Trichlorobenzene 1 mL

IInntteerrnnaall SSttaannddaarrddMM--GGRRAA--IISS--RR22

The 3 Comp. Internal Standard Mix (M-GRA-IS-R2)is combined with the 24 Comp. Core CalibrationCurve mixtures above in a 5 to 100 weight ratio toformulate these 27 Comp. calibration solutions.

FFrraaggmmeennttaattiioonn PPaatttteerrnn SSttaannddaarrddMM--GGRRAA--FFPP $$ 2200 // 11 xx 11 mmLLMM--GGRRAA--FFPP--PPAAKK SSAAVVEE 2200%% $$ 8800 // 55 xx 11 mmLL3.0 w/w in Isooctane



1,4-Diethyl benzene

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd))DD--55776699--QQCC//IISS--RR22--55MMLL $$ 110000 // 11 xx 55 mmLLDD--55776699--QQCC//IISS--RR22--55MMLL--PPAAKKSSAAVVEE 2200%% $$440000//55 xx 55 mmLL

17 comps.

DDiisskk DDeelliivveerraabbllee((AAtt nnoo aaddddiittiioonnaall cchhaarrggee))


CCAALLAAMMTTSS®®

((DDiisskk ccoonnttaaiinniinngg ““CCaalliibbrraattiioonnAAmmoouunnttss””))


Method 5769


Standards of InterestFor the mandatory real worldQC samples stipulated in theMethod, see pages 1-2



ASTM D-5769 Special QA/QC Formulations

MMeemmbbeerr

ASTM


ASTM Standards

Includes M-GRA-IS-R (4 Comp. Internal Standards mix) combined with the above 15 Comp.Core QC Mix: M-GRA-QC-R in a 12 to 100 Wt. ratio

WWtt.. CCoommppoouunndd RRaattiioon-Hexane 12n-Heptane 17n-Octane 17n-Decane 12n-Dodecane 5Isooctane 12Benzene 1Toluene 9

Includes M-GRA-IS (3 Comp. Internal StandardsMix) combined with the above 15 Comp. Core QCMix: M-GRA-QC-R in a 5 to 100 weight ratio

WWtt.. CCoommppoouunndd RRaattiiooEthylbenzene 3m-Xylene 3o-Xylene 31,2,4-Trimethylbenzene 31,2,4,5-Tetramethylbenzene 1Pentamethylbenzene 11-Methylnaphthalene 1



AccuPAK®

Reduce reordering frequency

Reduce data entry time forCalibration tables due toLot No. consistency

Economical

Save 20-40%Buy AccuPAKs

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttdd.. MM--GGRRAA--IISS--RR))MM--GGRRAA--QQCC--RR//IISS--RR--55MMLL $$ 112255 // 11 xx 55 mmLLMM--GGRRAA--QQCC--RR//IISS--RR--55MMLL--PPAAKK SSAAVVEE $$ 550000 // 55 xx 55 mmLL

19 comps.

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthh IInntteerrnnaall SSttaannddaarrdd MM--GGRRAA--IISS))MM--GGRRAA--QQCC--RR//IISS--55MMLL $$ 110000 // 11 xx 55 mmLLMM--GGRRAA--QQCC--RR//IISS--55MMLL--PPAAKK SSAAVVEE 2200%% $$ 440000 // 55 xx 55 mmLL

18 comps.

FFoorr uussee wwiitthh aannyy MM--GGRRAA CCaalliibbrraattiioonn CCuurrvvee

DDaaiillyy QQuuaalliittyy CCoonnttrrooll SSttaannddaarrdd((wwiitthhoouutt IInntteerrnnaall SSttaannddaarrdd))MM--GGRRAA--QQCC--RR--1100MMLL $$ 112255 // 11 xx 1100 mmLLMM--GGRRAA--QQCC--RR--1100MMLL--PPAAKK SSAAVVEE 2200%% $$ 550000 // 55 xx 1100 mmLL

Method 5769


100



100

CCoommppoouunndd MMiixx RRaattiiooBenzene-d6 2 mLEthylbenzene-d10 2 mLNaphthalene-d8 1 gmToluene-d8 7 mL



3 comps.


4 comps.


Custom Ampulling for Bulk Quantity Requirements• FFiillll VVoolluummeess ffrroomm 00..22 mmLL ttoo 2200 mmLL• FFllaammmmaabblleess• QQCC SSeerrvviicceess aavvaaiillaabblleeAccuStandard has the resources and equipment to meet your custom packagingrequirements. Our full automated filler-sealer can accommodate a fill range from0.5 to 20 mL, and ampule sizes from 1 mL to 20 mL.

AccuStandard has extensive experience with Round Robin samples for ASTMcommittees.

Call our Technical Department for a quotation.

Technical NoteSpecially formulated Daily Quality ControlStandards originally designed in response toclient requests for QC mixes that bracket thecurve and contain more C9+ analytes to verifythe instrument and QC solution integrity.



ASTM D-5769-XX Calibration Curve with No Internal Standard Added

MMeemmbbeerr

ASTM


ASTM Standards

CCoommppoossiittiioonn ooff DDaaiillyy QQCC SSttaannddaarrddAASSTTMM--PP--00114400--QQCC $$ 112255 // 11 xx 1100 mmLLAASSTTMM--PP--00114400--QQCC--PPAAKK $$ 550000 // 55 xx 1100 mmLL

9 comps.TTaarrggeett

CCoommppoouunndd MMaassss %%Benzene 1Toluene 10Ethylbenzene 31,3-Dimethylbenzene 61,2-Dimethylbenzene 31,2,4-Trimethylbenzene 31,2-Diethylbenzene 0.02Naphthalene 1Isooctane (solvent) * balance

PPeerrffoorrmmaannccee EEvvaalluuttaattiioonn SSttaannddaarrddAASSTTMM--PP--00114400--PPEESS $$ 5555 // 11 xx 11 mmLLAASSTTMM--PP--00114400--PPEESS--PPAAKK $$ 222200 // 55 xx 11 mmLL

11 comps.

CCoommppoouunndd MMaassss %%Naphthalene-d8 1Toluene-d8 7Isooctane * balance

44 CCoommpp.. DDeeuutteerraatteedd IInntteerrnnaall SSttdd.. MMiixxAASSTTMM--PP--00114400--IISS22 $$ 9955 // 11 xx 1100 mmLLAASSTTMM--PP--00114400--IISS22--PPAAKK $$ 338800 // 55 xx 1100 mmLL

5 comps.

AASSTTMM--PP--00114400--0055

AASSTTMM--PP--00114400--0044

AASSTTMM--PP--00114400--0033

AASSTTMM--PP--00114400--0022

AASSTTMM--PP--00114400--0011

A = This component is a solid at roomtemperature

AASSTTMM--PP--00114400--SSEETT $$ 11550000 // SSeett ooff 55 xx 55 mmLL

CCoorree CCaalliibbrr.. MMiixx LLeevveell 11 LLeevveell 22 LLeevveell 33 LLeevveell 44 LLeevveell 55CCoommppoouunndd TTaarrggeett MMaassss %% MMaassss %% MMaassss %% MMaassss %% MMaassss %%

Benzene 5 3 1 0.5 0.1Toluene 12 9 6 3 0.5Ethylbenzene 5 3.75 2.5 1.25 0.21,3-Dimethylbenzene 10 7.5 5 2.5 0.21,4-Dimethylbenezene 5 3.75 2.5 1.25 0.21,2-Dimethylbenezene 5 3.75 2.5 1.25 0.2(1-Methylethyl)-benzene 3 2.25 1.5 0.75 0.21-Methyl-3-ethylbenzene 3 2.25 1.5 0.75 0.21-Methyl-4-ethylbenzene 3 2.25 1.5 0.75 0.21,3,5-Trimethylbenzene 3 2.25 1.5 0.75 0.21-Methyl-2-ethylbenzene 3 2.25 1.5 0.75 0.21,2,4-Trimethylbenzene 6 4.5 3 1.5 0.21,2,3-Trimethylbenzene 3 2.25 1.5 0.75 0.2Indan 3 2.25 1.5 0.75 0.21,2-Diethylbenzene 2 1.5 1 0.5 0.2NaphthaleneA 2 1.5 1 0.5 0.12-MethylnaphthaleneA 2 1.5 1 0.5 0.11-MethylnaphthaleneA 2 1.5 1 0.5 0.1Isooctane (solvent) * balance balance balance balance balance

44 CCoommpp.. DDeeuutteerraatteedd IInntteerrnnaall SSttdd.. MMiixxAASSTTMM--PP--00114400--IISS $$ 7755 // 11 xx 1100 mmLLAASSTTMM--PP--00114400--IISS--PPAAKK $$ 330000 // 55 xx 1100 mmLL

4 comps.

Through a collaborative effort involving the instrument manufactures, Petrochemical end users, and Chemical Reference Standard manufacturers,the following proposed D-5769 method is under consideration. A number of end users would like to evaluate this proposed D-5769 method andhave asked AccuStandard to make the standards. We have formulated the following certified standards to meet those requests.

SSuummmmaarryy PPrrooppoosseedd MMooddiiffiiccaattiioonnss ffoorr DD--55776699• Calibration standards when combined with internal standards are diluted into significantly more isooctane.• The analytes in the Performance Standard have been expanded to better tune the GC/MS system for optimum performance.• The number of components in the QA/QC mix has been reduced with new QA/QC tolerances.• The number of analytes in the calibration mix has been reduced.• Samples that exceed the linear range are to be diluted, reducing the number of extra calibration points required.

Method 5769

CCoommppoouunndd MMaassss %%Benzene-d6 2Ethylbenzene-d10 2

CCoommppoouunndd MMaassss %%Naphthalene-d8 1Isooctane * balance

CCoommppoouunndd MMaassss %%Benzene-d6 2Ethylbenzene-d10 2

TTaarrggeettCCoommppoouunndd MMaassss %%Benzene 11,2-Diethylbenzene 0.0051,3,5-Trimethylbenzene 11-Methyl-2-ethylbenzene 1Styrene 0.1Indene 0.1Biphenyl 0.11,2,4,5-Tetramethylbenzene 11,2,3,5-Tetramethylbenzene 1Hexadecane 1Isooctane:Toluene(1:1) * balance

Technical Note* The isooctane balance is theamount of material to make upa 100 mL calibration standard.Certificate will reflect actualweight of each component inthe 100 mL batch including theisooctane.



ASTM D-5863 Nickel, Vanadium, Iron, & Sodium in Crude Oils & Residual Fuels byFlame AA Spectrometry

ASTM D-5773 Cloud Point of Petroleum Products (Constant Cooling Rate Method)

ASTM D-5772 Cloud Point of Petroleum Products (Linear Cooling Rate Method)

ASTM D-5771 Cloud Point of Petroleum Products

MMeemmbbeerr

ASTM


See page 5 for AccuStandard’s comprehensive line of certified Cloud Point Standards.



µµgg//ggVanadium 150

µµgg//mmLLVanadium 200

µµgg//mmLLIron 100 Nickel 200

µµgg//ggSodium 50 Nickel 200

TTeesstt MMeetthhoodd AA -- SSaammppllee DDeeccoommppoossiittiioonn wwiitthh AAcciidd ffoorr TToottaall NNii,, VV aanndd FFeeDDeetteerrmmiinnaattiioonn

ASTM Standards

IInnddiivviidduuaall HHiigghh CCoonncceennttrraattiioonn EElleemmeennttss iinn AAqquueeoouuss MMaattrriixx

SSttoocckk MMuullttii--EElleemmeenntt SSttaannddaarrdd iinn MMiinneerraallOOiill DD--55886633--9955BB--1100XX $$ 116600 // 11 xx 44 oozzAt stated conc. in 20 cst Mineral Oil 3 comps.

11,,000000 µµgg//mmLL CCoonncc..EElleemmeenntt MMaattrriixx UUnniitt CCaatt.. NNoo.. PPrriiccee

IIrroonn Fe 500 mL ICP-27N-5 $ 67in HNO3

NNiicckkeell Ni 500 mL ICP-37N-5 67in HNO3

VVaannaaddiiuumm V2O5 500 mL ICP-67N-5 67in HNO3

MMaattrriixx BBllaannkkNNiittrriicc AAcciidd BBllaannkkCCLLPP--BBLLNN--55 $$ 3300 // 550000 mmLLCCLLPP--BBLLNN--LL SSAAVVEE 3333%% $$ 4455 // LL (2 x 500 mL)

5% HNO3 in ASTM Type I Water

SSttoocckk MMuullttii--EElleemmeennttAAqquueeoouuss SSttaannddaarrddDD--55886633--9955AA--1100XX--11 $$ 7755 // 11 xx 110000 mmLL2-5% HNO3 3 comps.

TTeesstt MMeetthhoodd BB -- SSaammppllee DDiilluuttiioonn wwiitthh OOrrggaanniicc SSoollvveenntt ffoorr tthhee DDeetteerrmmiinnaattiioonn ooff NNii,, VVaanndd NNaa uussiinngg OOiill--SSoolluubbllee MMeettaallss aass CCaalliibbrraannttss..

Method 5771577257735863


WEA

R MET

ALS

Standards of InterestSee page 73-75 for additionalTrace Metal Standards by AA.

Standards of InterestSee pages 59-65 for AccuStandard’scomprehensive line of Certified Oil DissolvedWear Metal calibration standards designed forflame AA Applications.



ASTM D-5986 Oxygenates, Benzene, Toluene, C8-C12, Aromatics & Total Aromatics in Finished Gasolines by GC/FTIR

ASTM D-5972 Freezing Point Aviation Fuels (Automated Phase Transition Method)

ASTM D-5901 Freezing Point Aviation Fuels (Automated Optical Method)

MMeemmbbeerr

ASTM


ASTM Standards





See page 5 for AccuStandard’s comprehensive line of Certified Freezing Point Standards.

See page 5 for AccuStandard’s comprehensive line of Certified Freezing Point Standards.

Method 5901 -5986




Standards of InterestAlso see Cloud Pointstandards used for ASTMMethod D-2500 on page 5.

Standards of InterestSee page 34 for OxygenateCalibration Curve (Cat. No. M-GRO-CAL-SET) and page 46for AccuStandard’s AromaticCalibration Curve (Cat. No. D-5769-CAL-SET-5ML).

Technical NoteAccuStandard formulated this quality controlstandard to meet Section 11 of ASTM D-5986-96specifications stipulating to “analyze the qualitycontrol reference material before every batch ofsamples. Bracket the samples with the referencematerials”.

Oxygenate QC samples are available on pages 1-2 or can be custom formulated.



ASTM D-6277 Benzene in Spark - Ignition Engine Fuels using Mid Infrared Spectroscopy

ASTM D-6258 Solvent Red 164 Dye Concentration in Diesel Fuels

ASTM D-6160 Polychlorinated Biphenyls (PCBs in Waste Materials by GC)

MMeemmbbeerr

ASTM


ASTM Standards

See page 1 for AccuStandard’s QA/QC material reference in the method.

SSttoocckk SSoollvveenntt RReedd 2266 SSttaannddaarrddDD--66225588--CCOONNCC--55MMLL $$ 4455 // 11 xx 55 mmLL

Solvent Red 26 @ 300 µg/mL in Xylene

DD--66225588 CCaalliibbrraattiioonn CCuurrvveeDD--66225588--CCAALL--SSEETT--55MMLL $$ 112255 // sseett ooff 66 xx 55 mmLL

Set includes the following Cat. No.’s


D-6258-BL Xylene Blank 1 x 5 mLD-6258-01 Solvent Red 26 Dye @ 3 µg/mL in Xylene 1 x 5 mLD-6258-02 Solvent Red 26 Dye @ 6 µg/mL in Xylene 1 x 5 mLD-6258-03 Solvent Red 26 Dye @ 9 µg/mL in Xylene 1 x 5 mLD-6258-04 Solvent Red 26 Dye @ 12 µg/mL in Xylene 1 x 5 mLD-6258-05 Solvent Red 26 Dye @ 15 µg/mL in Xylene 1 x 5 mL

AAddddiittiioonnaall RReeaaddyy--ttoo--IInnjjeecctt PPCCBBAArroocclloorr CCaalliibbrraattiioonnCCuurrvveess aavvaaiillaabbllee iinn oouurr OOrrggaanniiccCCaattaalloogg

SSAAVVEE 2200%%iinn PPAAKK

((3355 µµgg//mmLL iinn ((3355 µµgg//mmLL iinn ((3355 µµgg//mmLL iinn IIssooooccttaannee)) MMeeOOHH)) HHeexxaannee)) 11 xx 11 mmLL 55 xx 11 mmLL

AArroocclloorr ## CCaatt.. NNoo.. CCaatt.. NNoo.. CCaatt.. NNoo.. PPrriiccee CCaatt.. NNoo.. PPrriiccee

Aroclor 1016 C-216S C-216S-M C-216S-H-10X $ 15 Cat. #-PAK $ 60Aroclor 1221 C-221S C-221S-M C-221S-H-10X 15 Cat. #-PAK 60Aroclor 1232 C-232S C-232S-M C-232S-H-10X 15 Cat. #-PAK 60Aroclor 1242 C-242S C-242S-M C-242S-H-10X 15 Cat. #-PAK 60Aroclor 1248 C-248S C-248S-M C-248S-H-10X 15 Cat. #-PAK 60Aroclor 1254 C-254S C-254S-M C-254S-H-10X 15 Cat. #-PAK 60Aroclor 1260 C-260S C-260S-M C-260S-H-10X 15 Cat. #-PAK 60Aroclor 1262 C-262S C-262S-M C-262S-H-10X 15 Cat. #-PAK 60Aroclor 1268 C-268S C-268S-M C-268S-H-10X 15 Cat. #-PAK 60

KKiitt ooff aallll 99 aabboovvee ZZ--000088SS ZZ--000088SS--MM ZZ--000088SS--HH--1100XX $$ 7788 // 99 xx 11 mmLL

AArroocclloorr SSoolluuttiioonnss ((IInnddiivviidduuaall aanndd KKiitt))

Method 616062586277



MMeemmbbeerr

AAccccuuSSttaannddaarrdd iiss aann aaccttiivvee mmeemmbbeerr iinn AASSTTMM aannddssttrriivveess ttoo kkeeeepp aabbrreeaasstt ooff AASSTTMM mmeetthhoodd rreevviissiioonnss.. IIffoouurr lliisstteedd ffoorrmmuullaattiioonn ddooeess nnoott mmeeeett tthhee mmoosstt rreecceennttmmeetthhoodd rreevviissiioonn,, pplleeaassee ccoonnttaacctt TTeecchhnniiccaall SSuuppppoorrtt,,eexxtt.. 111177 ffoorr aann uuppddaatteedd pprroodduucctt..

Technical NoteSolvent Red 26 is the azo dyestandard against which theconcentration of Solvent Red164 is measured. The visiblespectrum of Solvent Red 164 isvirtually identical to thespectrum of Solvent Red 26.



ASTM D-6296 Total Olefins in Spark-Ignition Engine Fuels by Multidimensional GC

ASTM D-6293 Oxygenates & Paraffin, Olefin, Naphthene, Aromatics (O-PONA) Hydrocarbontypes in Low-Olefin Spark-Ignition Engine Fuels by GC

MMeemmbbeerr

ASTM


ASTM Standards

WWtt..//WWtt.. %%n-Nonane 3.0n-Decane 3.0

OO--PPOONNAA PPaarraaffffiinn MMiixxAASSTTMM--PP--00008822--RR11 $$ 2255 // 11 xx 11 mmLLAASSTTMM--PP--00008822--RR11--PPAAKK $$ 110000 // 55 xx 11 mmLLAt stated conc. in Hexane : Heptane (1:1)

2 comps.

OO--PPOONNAA SSyysstteemm VVaalliiddaattiioonn MMiixxttuurreeAASSTTMM--PP--00008800 $$ 113355 // 11 xx 11 mmLLAASSTTMM--PP--00008800--PPAAKK SSAAVVEE 2266%% $$ 550000 // 55 xx 11 mmLL

33 comps.

WWtt..//WWtt.. %%Benzene 2.5Toluene 2.5trans-Decahydronaphthelene 3.5n-Tetradecane 2.0Ethylbenzene 3.5o-Xylene 3.0n-Propylbenzene 3.51,2,4-Trimethylbenzene 3.01,2,3-Trimethylbenzene 2.01,2,4,5-Tetramethylbenzene 2.0Pentamethylbenzene 2.5Ethanol 5.0t-Butanol 4.0MtBE 8.0ETBE 3.0TAME 5.0

WWtt..//WWtt.. %%n-Nonane 5.0n-Decane 2.0

OO--PPOONNAA PPaarraaffffiinn MMiixxAASSTTMM--PP--00008822 $$ 2255 // 11 xx 11 mmLLAASSTTMM--PP--00008822--PPAAKK $$ 110000 // 55 xx 11 mmLLAt stated conc. in Hexane : Heptane (1:1)

2 comps.

WWtt..//WWtt.. %%1-Pentene 5.01-Hexene 2.01-Heptene 2.01-Octene 2.01-Nonene 3.0

OO--PPOONNAA OOlleeffiinn MMiixxAASSTTMM--PP--00008811 $$ 4455 // 11 xx 11 mmLLAASSTTMM--PP--00008811--PPAAKK $$ 118800 // 55 xx 11 mmLLAt stated conc. in Hexane : Heptane (1:1)

5 comps.WWtt..//WWtt.. %%Cyclopentane 1.5n-Pentane 1.5Cyclohexane 2.02,3-Dimethylbutane 2.0n-Hexane 2.01-Hexene 1.5Methylcyclohexane 3.54-Methyl-1-hexene 1.5n-Heptane 3.0cis-1,2-Dimethylcyclohexane 4.5Isooctane 4.0n-Octane 4.01,2,4-Trimethylcyclohexane 3.5n-Nonane 3.0n-Decane 3.5n-Undecane 2.0n-Dodecane 2.0

IIssooooccttaannee BBllaannkk CCoommppeennssaattiioonn SSttaannddaarrddDD--66229966--BBLL $$ 1155 // 11 xx 55 mmLL

Isooctane (Neat)

WWtt.. %%Decane 1.0Undecane 1.0Dodecane 1.0Isooctane 86.0ETBE 5.0

WWtt.. %%Decene 1.0Undecane 1.0Dodecane 1.0Isooctane 87.0MTBE 5.0

WWtt.. %%Pentene 1.0Hexene 1.0Heptene 1.0Octene 1.0Nonene 1.0

SSyysstteemm SSeettuupp && VVeerriiffiiccaattiioonn SSttaannddaarrddssDD--66229966--VVEERR--SSEETT $$ 4400 // 22 xx 11 mmLLSSeett ccoonnttaaiinnss 11 aammppuullee ooff eeaacchh CCaatt.. NNoo.. lliisstteedd bbeellooww

DD--66229966--VVEERR--SSEETT--PPAAKK SSAAVVEE 2233%% $$ 115500 // 55 xx ((22 xx 11 mmLL))55 sseettss ccoonnttaaiinniinngg 11 aammppuullee ooff eeaacchh CCaatt.. NNoo.. lliisstteedd bbeellooww

WWtt.. %%ETBE 5%Isooctane 95%

SSyysstteemm SSeettuupp && VVeerriiffiiccaattiioonn SSttaannddaarrddssDD--66229966--VVEERR22 11 xx 11 mmLL

2 comps.WWtt.. %%MTBE 5%Isooctane 95%

SSyysstteemm SSeettuupp && VVeerriiffiiccaattiioonn SSttaannddaarrddssDD--66229966--VVEERR11 11 xx 11 mmLL

2 comps.

WWtt.. %%Pentene 1.0Hexene 1.0Heptene 1.0Octene 1.0Nonene 1.0Decene 1.0

CCaalliibbrraattiioonn SSttaannddaarrdd wwiitthh EETTBBEEDD--66229966--CCAALL22 $$ 6655 // 11 xx 11 mmLLDD--66229966--CCAALL22--PPAAKK SSAAVVEE 2233%% $$ 225500 // 55 xx 11 mmLL

11 comps.

CCaalliibbrraattiioonn SSttaannddaarrdd wwiitthh MMTTBBEEDD--66229966--CCAALL11 $$ 6655 // 11 xx 11 mmLLDD--66229966--CCAALL11--PPAAKK SSAAVVEE 2233%% $$ 225500 // 55 xx 11 mmLL

10 comps.

Method 62936296



Standards of InterestFor the mandatory real worldQC samples stipulated inQA/QC section 8.6 of themethod see pages 1-2.



ASTM D-6304 Determination of Water in Petroleum Products Lubricating oil, andadditives by Coulometric Karl Fischer Titration

ASTM D-6378 Vapor Pressure (VPx) of Petroleum Products, Hydrocarbons, & Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)

ASTM D-6352 Boiling Range Distribution of Petroleum Distillates from 174 to 700ºC by GC

ASTM D-6334 Sulfur in Gasoline by Wavelength Dispersive X-Ray Fluorescence

MMeemmbbeerr

ASTM


ASTM Standards

CCoolluummnn TTeesstt MMiixxttuurreeAASSTTMM--DD22888877 $$ 1100 // 11 xx 11 mmLL1% v/v in n-Octane 2 comps.

n-Hexadecane n-Octadecane

CCaalliibbrraattiioonn MMiixxDDRRHH--000022NN $$ 1100 // 110000 mmggDDRRHH--000022NN--1100XX $$ 4400 // 11 ggmm

17 comps.

WWtt.. %%n-Octadecane 5n-Eicosane 2n-Tetracosane 2n-Octacosane 1n-Dotriacontane 1n-Hexatriacontane 1n-Tetracontane 1n-Tetratetracontane 1

WWtt.. %%n-Hexane 6n-Heptane 6n-Octane 8n-Nonane 8n-Decane 12n-Undecane 12n-Dodecane 12n-Tetradecane 12n-Hexadecane 10

PPoollyywwaaxx 11000000®®AASSTTMM--PP--00113388NN--22GG $$ 2200 // 22 ggrraammss

Polywax 1000


Polywax 850


Polywax 655


Polywax 500

See Sulfur Standards Group listing in the Table of Contents for AccuStandard’s comprehensiveline of Certified Sulfur Calibration Standards.

See pages 29 & 32 for AccuStandard’s comprehensive line of Vapor Pressure Standards &Instrument Quality Control Samples.

Method 630463346352

See page 5 for AccuStandard’s comprehensive line of Certified Water Standards, forKarl Fischer Analysis.

Triacontanen-HentriacontaneDotriacontaneTritriacontaneTetratriacontanePentatriacontaneHexatriacontaneHeptatriacontaneOctatriacontaneNonatriacontaneTetracontane

NonadecanePhytaneEicosaneHeneicosaneDocosaneTricosaneTetracosanePentacosaneHexacosaneHeptacosaneOctacosaneNonacosane

OctaneNonaneDecaneUndecaneDodecaneTridecaneTetradecanePentadecaneHexadecaneHeptadecaneOctadecanePristane

HHyyddrrooccaarrbboonn WWiinnddoowwDDeeffiinniinngg SSttaannddaarrdd**DDRRHH--000088SS--RR22 $$ 6655 // 11 xx 11 mmLLDDRRHH--000088SS--RR22--PPAAKK SSAAVVEE 2200%% $$ 226600 // 55 xx 11 mmLL500 µg/mL each in Chloroform 35 comps.

** CCaann bbee sshhiippppeedd bbyy AAiirr aanndd SSeeaa


Standards of InterestContact AccuStandard’sTechnical Department regardingthe availability of a QA/QCReference Oil Sample underdevelopment in ASTM.



ASTM D-6428 Sulfur by Combustion and Electrochemical Detection

ASTM D-6417 Estimation of Engine Oil Volatility by Capillary GC

D-6591 Aromatic Hydrocarbon Types in Middle Distillates - IP 391 HPLC method with Refractive Index Detection

ASTM D-6379 Aromatic Hydrocarbon Types in Aviation Fuels & Petroleum Distillates - HPLC method with Refractive Index

MMeemmbbeerr

ASTM


ASTM Standards

DD--66337799 CCaalliibbrraattiioonn CCuurrvveeDD--66337799--SSEETT $$ 110000 // 44 xx 11 mmLLDD--66337799--SSEETT--PPAAKK SSAAVVEE 3300%% $$ 335500 // 55 xx ((44 xx 11 mmLL))At stated Conc. in n-Heptane

AAnnaallyyttee SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44(mg/mL) (mg/mL) (mg/mL) (mg/mL)

Cyclohexane 5 2 0.5 0.1o-Xylene 15 5 1.0 0.11-Methyl naphthalene 5 1.0 0.2 0.05

Cyclohexane 10 mg/mLo-Xylene 0.5 mg/mL1-Methyl naphthalene 0.05 mg/mL

Cyclohexane 10 mg/mLo-Xylene 5.0 mg/mLDibenzothiophene 0.5 mg/mL9-Methylanthracene 0.5 mg/mL

SSyysstteemm PPeerrffoorrmmaannccee SSttaannddaarrddAASSTTMM--PP--00113355 $$ 7755 // 11 xx 55 mmLLAASSTTMM--PP--00113355--PPAAKK SSAAVVEE 2200%% $$ 330000 // 55 xx 55 mmLLAt stated Conc. in n-Heptane 4 comps.

IIPP 339911--9955 CCaalliibbrraattiioonn CCuurrvveeAASSTTMM--PP--00113366--SSEETT $$ 114455 // 44 xx 11 mmLLAt stated Conc. in n-Heptane

AAnnaallyyttee SSttdd.. 11 SSttdd.. 22 SSttdd.. 33 SSttdd.. 44(mg/mL) (mg/mL) (mg/mL) (mg/mL)

Cyclohexane 50 20 5 1o-Xylene 40 10 2.5 0.51-Methyl naphthalene 40 10 2.5 0.2Phenanthrene 4 2 0.5 0.1

See page 15 for Alkane and Polywax standards suitable for D-6417.

SSyysstteemm RReessoolluuttiioonn SSttaannddaarrddDD--66337799--SSRRSS $$ 4400 // 11 xx 11 mmLLDD--66337799--SSRRSS--PPAAKK SSAAVVEE 3300%% $$ 114400 // 55 xx 11 mmLLAt stated Conc. in n-Heptane 3 comps.

DD--66442288--RR11--44--SSEETT $$ 330000 // 77 xx 44 oozzDD--66442288--RR11--SSEETT $$ 6655 // 77 xx 11 mmLLSulfur as Dibenzothiophene

NEW

DD--66442288--RR11--44--SSEETT DD--66442288--RR11--SSEETTDDeessccrriippttiioonn CCaatt.. NNoo.. UUnniitt CCaatt.. NNoo.. UUnniitt

Sulfur Blank D-6428-BL-4 4 oz D-6428-BL 1 mLSulfur @ 0.1 µg/g D-6428-0.1X-4 4 oz D-6428-0.1X 1 mLSulfur @ 0.5 µg/g D-6428-0.5X-4 4 oz D-6428-0.5X 1 mLSulfur @ 1.0 µg/g D-6428-1X-4 4 oz D-6428-1X 1 mLSulfur @ 2.5 µg/g D-6428-2.5X-4 4 oz D-6428-2.5X 1 mLSulfur @ 5.0 µg/g D-6428-5X-4 4 oz D-6428-5X 1 mLSulfur @ 10 µg/g D-6428-10X-4 4 oz D-6428-10X 1 mL

DD--66442288--RR22--44--SSEETT $$ 227755 // 66 xx 44 oozzDD--66442288--RR22--SSEETT $$ 6655 // 66 xx 11 mmLLSulfur as Dibenzothiophene

Method 6379IP 39164176428

DD--66442288--RR22--44--SSEETT DD--66442288--RR22--SSEETTDDeessccrriippttiioonn CCaatt.. NNoo.. UUnniitt CCaatt.. NNoo.. UUnniitt

Sulfur Blank D-6428-BL-4 4 oz D-6428-BL 1 mLSulfur @ 10 µg/g D-6428-10X-4 4 oz D-6428-10X 1 mLSulfur @ 25 µg/g D-6428-25X-4 4 oz D-6428-25X 1 mLSulfur @ 50 µg/g D-6428-50X-4 4 oz D-6428-50X 1 mLSulfur @ 75 µg/g D-6428-75X-4 4 oz D-6428-75X 1 mLSulfur @ 100 µg/g D-6428-100X-4 4 oz D-6428-100X 1 mL


Standards of InterestSee ASTM Methods D-3710,D-5307, D-5442, D-6352 foradditional calibration standardsfor hydrocarbon analysis.



ASTM D-6550 Olefin Content of Gasolines by SFC

ASTM D-6481 P, S, Ca and Zn in Lube Oils by ED-XRF

ASTM D-6445 Sulfur in Gasoline by ED - XRF

ASTM D-6443 Ca, Cl, Cu, Mg, P, S, Zn in Unused Lubricating Oils & Additives byWavelength Dispersive X-ray Fluorescence & Spectrometry

MMeemmbbeerr

ASTM


ASTM Standards

WWtt.. %%3-Methyl-1,3-pentadiene 22-Methyl-1-butene 252-Methyl-2-pentene 101-Heptene 102-Methyl-1-octene 2.52-Methyl-1-heptene 55-Methyl-1-hexene 10

WWtt.. %%1-Nonene 2.5Cyclohexene 51-Hexene 51-Octene 51-Decene 52-Methyl-1,3-butadiene 54-Methyl-1-pentene 51,5-Hexadiene 3

SSttoocckk OOlleeffiinn CCaalliibbrraattiioonn SSttaannddaarrddDD--66555500--CCOONNCC $$ 8800 // 11 xx 11 mmLLDD--66555500--CCOONNCC--55MMLL $$ 335500 // 11 xx 55 mmLLAt stated Conc. by Wt. % 15 comps.

Lubricating Oil, Elements, EDXRF ASTM Method(Nominal Value) Wt.% listed belowAASSTTMM--PP--00111144--SSEETT $$ 11990000 // 1177 xx 110000 mmLL

CCaa PP SS ZZnnCCaatt.. NNoo.. ((WWtt..%%)) ((WWtt..%%)) ((WWtt..%%)) ((WWtt..%%))

ASTM-P-0114-01 0.005 0.005 0.050 0.050ASTM-P-0114-02 0.600 0.000 0.000 0.000ASTM-P-0114-03 0.000 0.300 0.000 0.000ASTM-P-0114-04 1.000 0.000 1.000 0.000ASTM-P-0114-05 0.000 0.000 0.000 0.300ASTM-P-0114-06 0.005 0.250 0.800 0.300ASTM-P-0114-07 0.500 0.150 0.500 0.150ASTM-P-0114-08 0.010 0.200 0.100 0.250ASTM-P-0114-09 0.050 0.010 0.400 0.075ASTM-P-0114-10 0.100 0.150 0.200 0.200ASTM-P-0114-11 0.200 0.200 0.800 0.100ASTM-P-0114-12 0.400 0.005 0.800 0.300ASTM-P-0114-13 0.600 0.100 0.500 0.050ASTM-P-0114-14 0.800 0.010 0.050 0.100ASTM-P-0114-15 1.000 0.300 1.000 0.150ASTM-P-0114-16 0.400 0.050 0.600 0.250ASTM-P-0114-17 0.000 0.000 0.000 0.000

See the Sulfur Standards Group listing in the Table of Contents for AccuStandard’scomprehensive line of Certified Sulfur Calibration Standards.

Lubricating Oil, Elements, WLXRF ASTM Method (Nominal Value) Wt.% listed belowAASSTTMM--PP--00111177--SSEETT $$ 22110000 // 1100 xx 110000 mmLL

CCaa CCll CCuu MMgg PP SS ZZnnCCaatt.. NNoo.. ((WWtt..%%)) ((WWtt..%%)) ((WWtt..%%)) ((WWtt..%%)) ((WWtt..%%)) ((WWtt..%%)) ((WWtt..%%))

ASTM-P-0117-01 0.020 0.030 0.010 0.200 0.250 1.000 0.020ASTM-P-0117-02 0.020 0.020 0.050 0.200 0.020 0.020 0.250ASTM-P-0117-03 0.020 0.200 0.010 0.040 0.250 0.150 0.250ASTM-P-0117-04 0.020 0.200 0.050 0.040 0.020 1.000 0.020ASTM-P-0117-05 0.400 0.020 0.010 0.040 0.020 1.000 0.250ASTM-P-0117-06 0.400 0.020 0.050 0.040 0.250 0.020 0.020ASTM-P-0117-07 0.400 0.200 0.010 0.200 0.020 0.020 0.050ASTM-P-0117-08 0.400 0.200 0.050 0.200 0.250 1.000 0.250ASTM-P-0117-09 0.200 0.100 0.025 0.080 0.150 0.500 0.100ASTM-P-0117-10 0.000 0.000 0.000 0.000 0.000 0.000 0.000

Method 644364816550




WEA

R MET

ALS

Standards of InterestSee the Wear Metal Grouplisting in the Table of Contentsfor a comprehensive line ofCertified Oil Dissolved WearMetal Calibration Standards.

Standards of InterestSee page 2 for consensusvalue QA/QC material availablefor this method.

Technical NoteAccuStandard worked inconjunction with the D-02technical committee and ShellOil to develop this stock OlefinStandard proven useful increating the required calibrationcurve.



ASTM-FUEL-QCS-01-PAK:40ASTM-FUEL-QCS-02-PAK:40ASTM-P-0051N-2G:56ASTM-P-0053N-2G:56ASTM-P-0061-SET:37ASTM-P-0062-SET:37ASTM-P-0063-SET:37ASTM-P-0064-SET:37ASTM-P-0065-SET:37ASTM-P-0066-SET:37ASTM-P-0067-SET:37ASTM-P-0068-SET:37ASTM-P-0069-SET:37ASTM-P-0070-10X:40ASTM-P-0070-1X:40ASTM-P-0070-20X:40ASTM-P-0070-2X:40ASTM-P-0070-4X:40ASTM-P-0070-BL:40ASTM-P-0070-SET:40ASTM-P-0071-01:40ASTM-P-0071-02:40ASTM-P-0071-03:40ASTM-P-0071-BL:40ASTM-P-0071-SET:40ASTM-P-0080:55

ASTM-P-0080-PAK:55ASTM-P-0081:55ASTM-P-0081-PAK:55ASTM-P-0082:55ASTM-P-0082-PAK:55ASTM-P-0082-R1:55ASTM-P-0082-R1-PAK:55ASTM-P-0091-01-10X:38ASTM-P-0091-02-10X:38ASTM-P-0091-03-10X:38ASTM-P-0091-04-10X:38ASTM-P-0091-05-10X:38ASTM-P-0091-06-10X:38ASTM-P-0091-07-10X:38ASTM-P-0091-08-10X:38ASTM-P-0091-09-10X:38ASTM-P-0091-10-10X:38ASTM-P-0091-10X-SET:38ASTM-P-0091-11-10X:38ASTM-P-0091-12-10X:38ASTM-P-0091-13-10X:38ASTM-P-0091-14-10X:38ASTM-P-0091-15-10X:38ASTM-P-0091-16-10X:38ASTM-P-0091-17-10X:38ASTM-P-0091-18-10X:38ASTM-P-0091-19-

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