technical data sheet · 2019. 2. 7. · rhino armafloor® 500 au technical data sheet a-side, resin...

Rhino ArmaFloor® 500 AU Technical Data Sheet

A-side, Resin - ArmaFloor® 500 AUB-side, Hardener - ArmaFloor® 500 AU Date Revised: 20-September 2017

Issue Date: 09-February-2016

DESCRIPTION: ArmaFloor® 500 AU (AF500 AU) is a two- component, rapid curing, hybrid polyurea coating system designed as a Decorative Finish yet durable coating for floors and other applications. Formulated with aliphatic chemistry, ArmaFloor® 500 AU is colour stable allowing it take UV exposure without colour shifts seen with other coating systems such as epoxies. ArmaFloor® 500 AU is a 1:1 mix ratio system with sufficient pot life to be rolled with common Rhino Linings® application equipment.

FEATURES & BENEFITS: • Fast cure allowing rapid turnaround time; under normal conditions, light foot traffic within 3-5 Hours,

return to service within 24 hours.

• Robust application window with ability to apply at low temperatures and high humidity.

• Achieve variety of colours, patterns, logos, using decorative flakes, particles, or signs.

• Excellent abrasion and impact resistance.

• Excellent chemical resistance.

• Excellent UV resistance and high gloss characteristics.

• Bonds to virtually all substrates, including metals, woods, concrete, and fibreglass.

• Low VOC’s; environmentally friendly.

APPLICATIONS: • Excellent durability and aesthetics for floor, equipment and other coatings including:

- Garage floors- Laboratories- Restaurant floors- Airplane hangars- Entry and lobby areas- Industrial

• Creates a durable, seamless lining which conforms to any shape and size.

PHYSICAL PROPERTIES: Hardness

- Pencil 2H - Pendulum 160

Tensile Strength (psi)* 6,500 ASTM D-412 Elongation (%)* 6-8 ASTM D-412 Impact Resistance, lbs (kg) 100 (45.4)Taber Abrasion Resistance 50-60 ASTM D-4060 - (mg of loss/1000 cycles) CS17 Wheel; 1000 grams weightSpecific Gravity (grams/cc) 1.0 ASTM D-792 Water Absorption (%) 0.5 ASTM D-570 Water Vapour Transmission ASTM E-96

- Rate of Transmission, grains/h ft2 0.58 - Permeance (perm, in – lb) 1.39

Theoretical VOC 0.82 QUV Weatherometer, 4,000 hours

- Oxidation No effect - Loss of gloss No effect

- Blistering No effect - Yellowing No effect

* Properties were checked on dry films at 0.127 to 0.152 mm thick, air dried for 7 days.

CHEMICAL RESISTANCE: Excellent resistance to many chemicals. For a 7 day immersion in:

- Gasoline No effect - Brake Fluid No effect

- Skydrol No effect - Coolant or Anti-Freeze No effect - Ammonium hydroxide No effect R

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SURFACE PREPARATION: Substrate should be clean, dry and free of oils and other contaminants. Rhino recommends diamond grinding or shot-blasting for creating surface profile. Concrete Profile to be ICRI Standard CSP 2 to 3. Acid or wet etching is not recommended.

MIXING & RECOAT WINDOW: • Mix ratio 1:1 by volume

• Pigment ratio 10% by volume of mixed product (use only Rhino ArmaFloor pigments)

• Maximum thinning 10% by volume of mixed product (use only Rhino ArmaFloor Thinners)

• Recoat Time 3-6 hours between coats

• Recoat Time After 6 hours mechanically abrade (polyvac or sand) wipe withacetone to increase recoat time to up to 24 hours

THICKNESS & COVERAGE RATE:

If used as a solid colour coating, 2 x pigmented coats may be required. Total thickness for a flake floor finish (3 coats) is typically 300 – 500 microns. Coverage is 5-6 sqm per litre – possibly slightly less on the base coat to gain coverage on some substrates.

STORAGE & SHELF LIFE: ArmaFloor® AF500 AU components should be stored in sealed containers at 160C -320C in a dry area and on pallet racks.

A-side - Resin: Twelve months, unopened, stored properlyB-side - Hardener (Isocyanate): Six months, unopened, stored properly

COLOUR OPTIONS: Natural Colour - Clear Standard pigments, tint or colours available are: grey, beige, terracotta, black and white. Decorative Flake (paint chips – small & large): see Rhino Colour Flake Selection Chart for more details. Custom pigments, tints or colours are also available by special order (extra time) & extra cost.

SAFETY PRECAUTIONS: Health Considerations: Consult the Rhino Linings Material Safety Data Sheets. Read and follow warning labels on all components. For professional use only. The uncured components of ArmaFloor® 500 AU can cause irritation to the eyes, skin, and mucous membranes and are harmful if swallowed. When handling, avoid contact with eyes and skin (especially open cuts). In case of contact, immediately wash off with plenty of water for at least fifteen (15) minutes. For eyes, obtain medical attention. Always wash hands before eating. Obtain immediate medical attention in case of ingestion.

ArmaFloor® 500 AU contains isocyanates and may cause allergic skin and respiratory reactions. Do not use if you have chronic breathing problems (asthma) or if you have ever had reactions to isocyanates. When applying ArmaFloor® 500 AU, avoid breathing harmful vapours. Introduce fresh air flow into the application area. It is recommended that fresh air-supplied standard painter’s hood and full face respirator be worn by all personnel entering the area where ArmaFloor® 500 AU is being applied until vapours have been exhausted. In case of extreme exposure or adverse reaction, remove affected personnel to fresh air immediately and obtain medial help.

For Your Protection: The information and recommendations in this publication are, to the best of our knowledge, reliable. Suggestions made concerning the products and their uses, applications, storage and handling are only the opinion of Rhino Linings Corporation. Users should conduct their own tests to determine the suitability of these products for their own particular purpose and of the storage and handling methods herein suggested. The toxicity and risk characteristics of products made by Rhino Linings Corporation will necessarily differ from the toxicity and risk characteristics developed when such products are used with other materials during a manufacturing process. The resulting risk characteristics should be determined and made known to ultimate end-users and processors. Because of numerous factors affecting the potential application results, Rhino Linings Corporation makes no warranty of any kind, express or implied, other than that the material conforms to its applicable current Standard Specifications. Rhino Linings Corporation hereby disclaims any, and all other warranties, including but not limited to those of merchantability or fitness for a particular purpose. No statements made herein may be construed as a representation or warranty. The liability of Rhino Linings Corporation for any claims arising from or sounding in breach of warranty, negligence, strict liability, or otherwise shall be limited to the purchase price of the material.

©2018 Rhino Linings Australasia Pty Ltd. All rights reserved.

Rhino Linings Australasia Pty Ltd 39 Activity Crescent, Molendinar Qld, 4214, Australia

Ph: +61 7 5585 700

Rhino Linings USA, Inc. ˚ Rhino Linings of Canada, Inc. ˚ Rhino Linings Latin America, ˚ Rhino Linings Europe

Rhino Linings (Rhino Linings Australasia) Chemwatch Hazard Alert Code: 2

Rhino ArmaFloor 500 AU A-Side

Chemwatch: 42-2706Version No: 2.1.1.1Safety Data Sheet according to WHS and ADG requirements

Issue Date: 17/07/2014Print Date: 03/07/2018

S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name Rhino ArmaFloor 500 AU A-Side

Chemical Name aspartic acid, N,N'-(methylenedicyclohexanediyl)bis-,ester

Synonyms Not Available

Other means of identification Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Part A of a polyurea/polyurethane coating.

Details of the supplier of the safety data sheet

Registered company name Rhino Linings (Rhino Linings Australasia)

Address 39 Activity Crescent Molendinar QLD 4214 Australia

Telephone +61 7 5585 7000

Fax Not Available

Website www.rhinolinings.com.au

Email [email protected]

Emergency telephone number

Association / Organisation Chemwatch Emergency Line 24/7

Emergency telephone numbers 1800 039 008 (24hrs)

Other emergency telephonenumbers

Not Available

CHEMWATCH EMERGENCY RESPONSE

Primary Number Alternative Number 1 Alternative Number 2

1800 039 008 1800 039 008 +612 9186 1132

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

CHEMWATCH HAZARD RATINGS

MaxMinFlammability 1 Toxicity 0Body Contact 1 Reactivity 1 Chronic 2

0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme

Poisons Schedule Not Applicable

Classification [1] Skin Sensitizer Category 1, Acute Aquatic Hazard Category 3, Chronic Aquatic Hazard Category 3

Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

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Label elements

Hazard pictogram(s)

SIGNAL WORD WARNING

Hazard statement(s)

H317 May cause an allergic skin reaction.

H412 Harmful to aquatic life with long lasting effects.

Precautionary statement(s) Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P261 Avoid breathing mist/vapours/spray.

P273 Avoid release to the environment.

P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary statement(s) Response

P363 Wash contaminated clothing before reuse.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances

See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

136210-30-5 >95

not spec contains

623-91-6 3

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

InhalationIf fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.

Ingestion

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

Foam. Dry chemical powder. BCF (where regulations permit).

aspartic acid, N,N'-(methylenedicyclohexanediyl)bis-,ester

diethyl fumarate

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Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area.

Fire/Explosion Hazard

Combustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO).

Combustion products include:,carbon dioxide (CO2),nitrogen oxides (NOx),other pyrolysis products typical of burning organic material.May emit poisonous fumes.May emit corrosive fumes.

HAZCHEM Not Applicable

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions

See section 12

Methods and material for containment and cleaning up

Minor Spills

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.

Major Spills

Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

DO NOT allow clothing wet with material to stay in contact with skinAvoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.

Other information

Store in original containers. Keep containers securely sealed. No smoking, naked lights or ignition sources. Store in a cool, dry, well-ventilated area.

Conditions for safe storage, including any incompatibilities

Suitable containerMetal can or drum Packaging as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Storage incompatibilitySegregate from alcohol, water. Avoid reaction with oxidising agents

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Not Available

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

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Rhino ArmaFloor 500 AU A-Side Not Available Not Available Not Available Not Available

Ingredient Original IDLH Revised IDLH

aspartic acid,N,N'-(methylenedicyclohexanediyl)bis-,ester

Not Available Not Available

diethyl fumarate Not Available Not Available

Exposure controls

Appropriate engineeringcontrols

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can behighly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and"removes" air in the work environment.

Personal protection

Eye and face protection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearingof lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below

Hands/feet protection

Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber

NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, toavoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer.Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to bechecked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a finalchoice.Personal hygiene is a key element of effective hand care.

Body protection See Other protection below

Other protectionOveralls. P.V.C. apron. Barrier cream.

Respiratory protection

Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio ofcontaminant outside and inside the mask) may also be important.

Required minimum protection factor Maximum gas/vapour concentration present in air p.p.m. (by volume) Half-face Respirator Full-Face Respirator

up to 10 1000 A-AUS / Class1 P2 -

up to 50 1000 - A-AUS / Class 1 P2

up to 50 5000 Airline * -

up to 100 5000 - A-2 P2

up to 100 10000 - A-3 P2

100+ Airline**

* - Continuous Flow ** - Continuous-flow or positive pressure demandA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agriculturalchemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content. The wearer must be warned to leave the contaminated areaimmediately on detecting any odours through the respirator. The odour may indicate that the mask is not functioning properly, that the vapour concentration is too high, or that the mask is notproperly fitted. Because of these limitations, only restricted use of cartridge respirators is considered appropriate.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Colourless liquid with slight inherent odour; does not mix with water.

Physical state Liquid Relative density (Water = 1) Not Available

Odour Not AvailablePartition coefficient n-octanol /

waterNot Available

Odour threshold Not Available Auto-ignition temperature (°C) 375 ca. (ignition temp.)

pH (as supplied) Not Available Decomposition temperature 234 ca.

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Melting point / freezing point(°C)

-2 ca. Viscosity (cSt) 2.030 @ 20C

Initial boiling point and boilingrange (°C)

100 ca. Molecular weight (g/mol) Not Applicable

Flash point (°C) 100 ca. Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Upper Explosive Limit (%) Not AvailableSurface Tension (dyn/cm or

mN/m)Not Available

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) 0.3 @ 20C Gas group Not Available

Solubility in water (g/L) Immiscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L 31.56

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility of hazardousreactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decompositionproducts

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

InhaledThere is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to such irritation can causefurther lung damage.

IngestionAlthough ingestion is not thought to produce harmful effects (as classified under EC Directives), the material may still be damaging to the health of theindividual, following ingestion, especially where pre-existing organ (e.g. liver, kidney) damage is evident.

Skin Contact

There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to theuse of the material and ensure that any external damage is suitably protected.

EyeAlthough the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfortcharacterised by tearing or conjunctival redness (as with windburn).

ChronicSkin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population.


TOXICITY IRRITATION

Dermal (Rat) LD50: >2000 mg/kg*[2] Skin : Mild

Inhalation (Rat) LC50: >4.224 mg/m3/4h*[2]

Oral (Rat) LD50: >2000 mg/kg*[2]


TOXICITY IRRITATION

dermal (rat) LD50: >2000 mg/kg[2] Eye : Mild

Oral (rat) LD50: >2000 mg/kg[2] Skin : Moderate

diethyl fumarateTOXICITY IRRITATION

Oral (rat) LD50: 1780 mg/kg[2] Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specifieddata extracted from RTECS - Register of Toxic Effect of chemical Substances

ASPARTIC ACID,N,N'-(METHYLENEDICYCLOHEXANEDIYL)BIS-,ESTER

The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. Thepathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergicskin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions.Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens and occurrapidly. Allergic potential of the allergen and period of exposure often determine the severity of symptoms. Some people may begenetically more prone than others, and exposure to other irritants may aggravate symptoms. Allergy causing activity is due tointeractions with proteins.Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma and eczema.Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated

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Legend: – Data available but does not fill the criteria for classification – Data available to make classification

– Data Not Available to make classification

reactions (T lymphocytes) may be involved. Such allergy is of the delayed type with onset up to four hours following exposure.for similar substance CAS 136210-10-32-7: Evidence of sensitisation (adjuvant test) * After the first challenge very mild to clearlyvisible skin reddening was observed in 85% of the test substance animals. After the second challenge, very mild to clearly visibleskin reddening was observed in 50% and 35% of the test substance animals challenged with 25% and 12% test substancerespectively. A scaly administration site was observed in some animals. Rat repeat dose oral toxicity - 29 days NOAEL 1000mg/kg/day * Genotoxicity ? bacterial reverse mutation non mutagenic * Genotoxicity ? in vitro not determined * Genotoxicity ? invivo erythrocyte micronucleus test non clastogenic * The notified chemical is considered to be of low acute toxicity via the oral,dermal and inhalation routes. Irritation and Sensitisation. The material is considered to be a slight skin and eye irritant and mildrespiratory irritant and a skin sensitiser. As skin reactions were observed in 85% of animals at a concentration of 50%, thesubstance is considered to be a strong sensitiser. The potential for respiratory sensitisation cannot be ruled out. Repeated DoseToxicity. In a 28 day study in rats, the No Observed Adverse Effect Level (NOAEL) was established as 1000 mg/kg bw/day basedon the absence of adverse treatment related effects. Mutagenicity. The material was negative in an Ames test and an in vivoerythrocyte micronucleus test. The substance is not considered to be mutagenic. Neurotoxicity: In the in vivo mouse erythrocytemicronucleus test, following intraperitoneal administration of a fairly high dose (5345 mg/kg bw) some evidence of non-specificneurological impairment was seen. However, this was not observed in any of the tests conducted on any other species and couldeither be species-specific or an expression of generalised toxicity induced at high doses, as opposed to specific neurotoxicity. *NICNAS Report

DIETHYL FUMARATE

for diethyl fumarateRepeat dose toxicity: In an oral combined repeated dose and reproductive/developmental toxicity test at doses of 0, 11, 30 and100 mg/kg/day [OECD TG 422], no effects were observed on clinical signs, body weight, food consumption, urinalysis,haematology or blood chemistry examinations. Histopathological examination of the forestomach revealed thickening of themucosal layer in both sexes of all treated groups, hyperkeratosis in males of all treated groups and in females of the 30 and 100mg/kg groups. These changes were dose-dependent. In addition, oedema in the submucosal tissue as well as ulcer and focaledema in lamina propria mucosae were noted in males and females of the 30 mg/kg groups, and vesiculation in the superficialzone of the mucosal layer was apparent in males of the 30 and 100 mg/kg groups.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye Damage/Irritation STOT - Single Exposure

Respiratory or Skinsensitisation

STOT - Repeated Exposure

Mutagenicity Aspiration Hazard

SECTION 12 ECOLOGICAL INFORMATION

Toxicity


ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

NotAvailable

Not Available Not AvailableNotAvailable

NotAvailable



NOEC 504 Crustacea 0.013mg/L 2

diethyl fumarateENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 4.5mg/L 4

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12(QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE(Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

diethyl fumarate LOW LOW

Bioaccumulative potential

Ingredient Bioaccumulation

diethyl fumarate LOW (LogKOW = 2.1955)

Mobility in soil

Ingredient Mobility

diethyl fumarate LOW (KOC = 10.9)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

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Product / Packaging disposal

Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Authority for disposal. Bury or incinerate residue at an approved site. Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO


Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

ASPARTIC ACID, N,N'-(METHYLENEDICYCLOHEXANEDIYL)BIS-,ESTER(136210-30-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals Australia Inventory of Chemical Substances (AICS)

DIETHYL FUMARATE(623-91-6) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Inventory of Chemical Substances (AICS)

National Inventory Status


Australia - AICS Y

Canada - DSL N (diethyl fumarate)

Canada - NDSL N (aspartic acid, N,N'-(methylenedicyclohexanediyl)bis-,ester)

China - IECSC Y

Europe - EINEC / ELINCS / NLP N (aspartic acid, N,N'-(methylenedicyclohexanediyl)bis-,ester)

Japan - ENCS N (aspartic acid, N,N'-(methylenedicyclohexanediyl)bis-,ester)

Korea - KECI Y

New Zealand - NZIoC Y

Philippines - PICCS N (aspartic acid, N,N'-(methylenedicyclohexanediyl)bis-,ester)

USA - TSCA Y

Legend:Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Revision Date 17/07/2014

Initial Date Not Available

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee usingavailable literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or othersettings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index

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Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH.TEL (+61 3) 9572 4700.

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end of SDS

Rhino Linings (Rhino Linings Australasia) Chemwatch Hazard Alert Code: 2

Rhino ArmaFloor 500 AU B-Side

Chemwatch: 42-2707Version No: 2.1.1.1Safety Data Sheet according to WHS and ADG requirements

Issue Date: 17/07/2014Print Date: 03/07/2018

S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name Rhino ArmaFloor 500 AU B-Side

Synonyms Not Available

Other means of identification Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Hardener or Part B of a 2 packurethane coating systemRequires that the two parts be mixed by hand or mixer before use, in accordance with manufacturers directions. Mix only as much as is required. Donot return the mixed material to the original containers

Details of the supplier of the safety data sheet

Registered company name Rhino Linings (Rhino Linings Australasia)

Address 39 Activity Crescent Molendinar QLD 4214 Australia

Telephone +61 7 5585 7000

Fax Not Available

Website www.rhinolinings.com.au

Email [email protected]

Emergency telephone number

Association / Organisation Chemwatch Emergency Line 24/7

Emergency telephone numbers 1800 039 008 (24hrs)

Other emergency telephonenumbers

Not Available

CHEMWATCH EMERGENCY RESPONSE

Primary Number Alternative Number 1 Alternative Number 2

1800 039 008 1800 039 008 +612 9186 1132

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

COMBUSTIBLE LIQUID, regulated for storage purposes only

CHEMWATCH HAZARD RATINGS

MaxMinFlammability 1 Toxicity 2 Body Contact 1 Reactivity 1 Chronic 2

0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme

Poisons Schedule S6

Continued...

Classification [1] Flammable Liquid Category 4, Acute Toxicity (Inhalation) Category 4, Skin Sensitizer Category 1, Respiratory Sensitizer Category 1

Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

Label elements

Hazard pictogram(s)

SIGNAL WORD DANGER

Hazard statement(s)

H227 Combustible liquid.

H332 Harmful if inhaled.

H317 May cause an allergic skin reaction.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary statement(s) Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P261 Avoid breathing mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam for extinction.

Precautionary statement(s) Storage

P403+P235 Store in a well-ventilated place. Keep cool.

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances

See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

28182-81-2 >95

not spec contains

822-06-0 <0.2

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR ifnecessary. Transport to hospital, or doctor.

Following uptake by inhalation, move person to an area free from risk of further exposure. Oxygen or artificial respiration should be administered as needed.Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Treatment is essentially symptomatic. A physician should beconsulted.

hexamethylene diisocyanate polymer

hexamethylene diisocyanate

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Ingestion

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.

Indication of any immediate medical attention and special treatment needed

For sub-chronic and chronic exposures to isocyanates:This material may be a potent pulmonary sensitiser which causes bronchospasm even in patients without prior airway hyperreactivity. Clinical symptoms of exposure involve mucosal irritation of respiratory and gastrointestinal tracts. Conjunctival irritation, skin inflammation (erythema, pain vesiculation) and gastrointestinal disturbances occur soon after exposure. Pulmonary symptoms include cough, burning, substernal pain and dyspnoea. Some cross-sensitivity occurs between different isocyanates. Noncardiogenic pulmonary oedema and bronchospasm are the most serious consequences of exposure. Markedly symptomatic patients should receive oxygen, ventilatory support and anintravenous line. Treatment for asthma includes inhaled sympathomimetics (epinephrine [adrenalin], terbutaline) and steroids. Activated charcoal (1 g/kg) and a cathartic (sorbitol, magnesium citrate) may be useful for ingestion. Mydriatics, systemic analgesics and topical antibiotics (Sulamyd) may be used for corneal abrasions. There is no effective therapy for sensitised workers.

[Ellenhorn and Barceloux; Medical Toxicology]NOTE: Isocyanates cause airway restriction in naive individuals with the degree of response dependant on the concentration and duration of exposure. They induce smooth muscle contractionwhich leads to bronchoconstrictive episodes. Acute changes in lung function, such as decreased FEV1, may not represent sensitivity.[Karol & Jin, Frontiers in Molecular Toxicology, pp 56-61, 1992]Personnel who work with isocyanates, isocyanate prepolymers or polyisocyanates should have a pre-placement medical examination and periodic examinations thereafter, including a pulmonaryfunction test. Anyone with a medical history of chronic respiratory disease, asthmatic or bronchial attacks, indications of allergic responses, recurrent eczema or sensitisation conditions of the skinshould not handle or work with isocyanates. Anyone who develops chronic respiratory distress when working with isocyanates should be removed from exposure and examined by a physician.Further exposure must be avoided if a sensitivity to isocyanates or polyisocyanates has developed.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

Small quantities of water in contact with hot liquid may react violently with generation of a large volume of rapidly expanding hot sticky semi-solid foam. Presents additional hazard when fire fighting in a confined space. Cooling with flooding quantities of water reduces this risk. Water spray or fog may cause frothing and should be used in large quantities. Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area.

Fire/Explosion Hazard

Moderate fire hazard when exposed to heat or flame.When heated to high temperatures decomposes rapidly generating vapour which pressures and may then rupture containers with release of flammable andhighly toxic isocyanate vapour.Burns with acrid black smoke and poisonous fumes.Combustion products include:,carbon dioxide (CO2),isocyanates,and minor amounts of,hydrogen cyanide,nitrogen oxides (NOx),other pyrolysis products typical of burning organic material.May emit corrosive fumes.When heated at high temperatures many isocyanates decompose rapidly generating a vapour which pressurises containers, possibly to the point of rupture.Release of toxic and/or flammable isocyanate vapours may then occur


SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions

See section 12

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Methods and material for containment and cleaning up

Minor Spills

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.

Major Spills

Liquid Isocyanates and high isocyanate vapour concentrations will penetrate seals on self contained breathing apparatus - SCBA should be used insideencapsulating suit where this exposure may occur.

For isocyanate spills of less than 40 litres (2 m2):Evacuate area from everybody not dealing with the emergency, keep them upwind and prevent further access, remove ignition sources and, if insidebuilding, ventilate area as well as possible. Notify supervision and others as necessary. Put on personal protective equipment (suitable respiratory protection, face and eye protection, protective suit, gloves and impermeable boots). Control source of leakage (where applicable). Avoid contamination with water, alkalies and detergent solutions. Material reacts with water and generates gas, pressurises containers with even drum rupture resulting. DO NOT reseal container if contamination is suspected. Open all containers with care.

Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

DO NOT allow clothing wet with material to stay in contact with skinAvoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.

Other information

for commercial quantities of isocyanates:Isocyanates should be stored in adequately bunded areas. Nothing else should be kept within the same bunding. Pre-polymers need not be segregated.Drums of isocyanates should be stored under cover, out of direct sunlight, protected from rain, protected from physical damage and well away frommoisture, acids and alkalis. Store in original containers. Keep containers securely sealed. No smoking, naked lights or ignition sources. Store in a cool, dry, well-ventilated area.

Conditions for safe storage, including any incompatibilities

Suitable containerMetal can or drum Packaging as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Storage incompatibility

Avoid cross contamination between the two liquid parts of product (kit). If two part products are mixed or allowed to mix in proportions other than manufacturer's recommendation, polymerisation with gelation and evolution ofheat (exotherm) may occur. This excess heat may generate toxic vapour Avoid reaction with water, alcohols and detergent solutions. Isocyanates and thioisocyanates are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions withamines, strong bases, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidisers, hydrides, phenols, and peroxides can cause vigorousreleases of heat. Acids and bases initiate polymerisation reactions in these materials. A range of exothermic decomposition energies for isocyanates is given as 20-30 kJ/mol. The relationship between energy of decomposition and processing hazards has been the subject of discussion; it is suggested that values of energyreleased per unit of mass, rather than on a molar basis (J/g) be used in the assessment. For example, in "open vessel processes" (with man-hole size openings, in an industrial setting), substances with exothermic decomposition energiesbelow 500 J/g are unlikely to present a danger, whilst those in "closed vessel processes" (opening is a safety valve or bursting disk) present somedanger where the decomposition energy exceeds 150 J/g.

BRETHERICK: Handbook of Reactive Chemical Hazards, 4th Edition

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Australia Exposure Standards hexamethylene diisocyanate polymer Isocyanates, all (as-NCO) 0.02 mg/m3 0.07 mg/m3 Not Available Not Available

Australia Exposure Standards hexamethylene diisocyanate Hexamethylene diisocyanate Not Available Not Available Not Available Not Available

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

hexamethylene diisocyanatepolymer

Hexamethylene diisocyanate polymer 7.8 mg/m3 86 mg/m3 510 mg/m3

hexamethylene diisocyanate Hexamethylene diisocyanate; (1,6-Diisocyanatohexane) 0.018 ppm 0.2 ppm 3 ppm

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Ingredient Original IDLH Revised IDLH



hexamethylene diisocyanate Not Available Not Available

Exposure controls

Appropriate engineeringcontrols

All processes in which isocyanates are used should be enclosed wherever possible. Total enclosure, accompanied by good general ventilation, should be used to keep atmospheric concentrations below the relevant exposure standards. If total enclosure of the process is not feasible, local exhaust ventilation may be necessary. Local exhaust ventilation is essential where lower molecularweight isocyanates (such as TDI or HDI) is used or where isocyanate or polyurethane is sprayed.

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can behighly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and"removes" air in the work environment.

Personal protection

Eye and face protection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearingof lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below

Hands/feet protection

NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, toavoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer.Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to bechecked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a finalchoice.Personal hygiene is a key element of effective hand care.

Do NOT wear natural rubber (latex gloves). Isocyanate resistant materials include Teflon, Viton, nitrile rubber and some PVA gloves. Protective gloves and overalls should be worn as specified in the appropriate national standard. Contaminated garments should be removed promptly and should not be re-used until they have been decontaminated. NOTE: Natural rubber, neoprene, PVC can be affected by isocyanates DO NOT use skin cream unless necessary and then use only minimum amount. Isocyanate vapour may be absorbed into skin cream and this increases hazard.

Body protection See Other protection below

Other protection

All employees working with isocyanates must be informed of the hazards from exposure to the contaminant and the precautions necessary to preventdamage to their health. They should be made aware of the need to carry out their work so that as little contamination as possible is produced, and of theimportance of the proper use of all safeguards against exposure to themselves and their fellow workers. Adequate training, both in the proper execution ofthe task and in the use of all associated engineering controls, as well as of any personal protective equipment, is essential.Employees exposed to contamination hazards should be educated in the need for, and proper use of, facilities, clothing and equipment and thereby maintaina high standard of personal cleanliness.

Overalls. P.V.C. apron. Barrier cream.

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: Rhino ArmaFloor 500 AU B-Side

Material CPI

SARANEX-23 C

* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors such as"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwisebe unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

Respiratory protection

Full face respirator with supplied air.

Cartridge respirators should never be used for emergency ingress or in areas of unknownvapour concentrations or oxygen content. The wearer must be warned to leave the contaminatedarea immediately on detecting any odours through the respirator. The odour may indicate thatthe mask is not functioning properly, that the vapour concentration is too high, or that the maskis not properly fitted. Because of these limitations, only restricted use of cartridge respirators isconsidered appropriate.

In certain circumstances, personal protection of the individual employee is necessary.Personal protective devices should be regarded as being supplementary to substitution andengineering control and should not be used in preference to them as they do nothing toeliminate the hazard. However, in some situations, minimising exposure to isocyanates by enclosure and ventilationis not possible, and occupational exposure standards may be exceeded, particularly duringon-site mixing of paints, spray-painting, foaming and maintenance of machine and ventilationsystems. In these situations, air-line respirators or self-contained breathing apparatuscomplying with the appropriate nationals standard must be used. Organic vapour respirators with particulate pre- filters and powered, air-purifying respiratorsare NOT suitable. Personal protective equipment must be appropriately selected, individually fitted and workerstrained in their correct use and maintenance. Personal protective equipment must beregularly checked and maintained to ensure that the worker is being protected. Air- line respirators or self-contained breathing apparatus complying with the appropriatenational standard should be used during the clean-up of spills and the repair or clean-up ofcontaminated equipment and similar situations which cause emergency exposures tohazardous atmospheric concentrations of isocyanate.

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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Straw coloured liquid with aromatic odour; does not mix with water.

Physical state Liquid Relative density (Water = 1) 1.08

Odour Not AvailablePartition coefficient n-octanol /

waterNot Available

Odour threshold Not Available Auto-ignition temperature (°C) 375 ca. (ignition temp.)

pH (as supplied) Not Available Decomposition temperature Not Available

Melting point / freezing point(°C)

Not Available Viscosity (cSt) Not Available

Initial boiling point and boilingrange (°C)

Not Available Molecular weight (g/mol) Not Applicable

Flash point (°C) >65 Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Combustible. Oxidising properties Not Available

Upper Explosive Limit (%) Not AvailableSurface Tension (dyn/cm or

mN/m)Not Available

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water (g/L) Immiscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L 1085.28

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility of hazardousreactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decompositionproducts

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful.There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to such irritation can causefurther lung damage.The vapour/mist may be highly irritating to the upper respiratory tract and lungs; the response may be severe enough to produce bronchitis and pulmonaryoedema. Possible neurological symptoms arising from isocyanate exposure include headache, insomnia, euphoria, ataxia, anxiety neurosis, depression andparanoia. Gastrointestinal disturbances are characterised by nausea and vomiting. Pulmonary sensitisation may produce asthmatic reactions ranging fromminor breathing difficulties to severe allergic attacks; this may occur following a single acute exposure or may develop without warning for several hoursafter exposure.

IngestionAccidental ingestion of the material may be damaging to the health of the individual.Ingestion may result in nausea, abdominal irritation, pain and vomiting

Skin Contact

Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to theuse of the material and ensure that any external damage is suitably protected.There is some evidence to suggest that the material may cause moderate inflammation of the skin either following direct contact or after a delay of sometime. Repeated exposure can cause contact dermatitis which is characterised by redness, swelling and blistering.

EyeThere is some evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation. Moderateinflammation may be expected with redness; conjunctivitis may occur with prolonged exposure.

Chronic

Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population.Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.

Persons with a history of asthma or other respiratory problems or are known to be sensitised, should not be engaged in any work involving the handling ofisocyanates. [CCTRADE-Bayer, APMF]Animal testing shows that polymeric MDI can damage the nasal cavities and lungs, causing inflammation.and increased cell growth.This product contains a polymer with a functional group considered to be of high concern. Isothiocyanates may cause hypersensitivity of the skin andairways.

CONTAINS free organic isocyanate. Mixing and application requires special precautions and use of personal protective gear [APMF]Isocyanate vapours are irritating to the airways and can cause their inflammation, with wheezing, gasping, severe distress, even loss of consciousness andfluid in the lungs. Nervous system symptoms that may occur include headache, sleep disturbance, euphoria, inco-ordination, anxiety, depression andparanoia.

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Legend: – Data available but does not fill the criteria for classification – Data available to make classification

– Data Not Available to make classification

Rhino ArmaFloor 500 AUB-Side

TOXICITY IRRITATION



TOXICITY IRRITATION

Dermal (rabbit) LD50: >5000 mg/kg[2] Skin (rabbit): 500 mg - moderate

Inhalation (rat) LC50: 4.625 mg/l/1he[2]

Oral (rat) LD50: >10000 mg/kg[2]

hexamethylene diisocyanate

TOXICITY IRRITATION

Dermal (rabbit) LD50: 570 mg/kg[1] Not Available

Inhalation (rat) LC50: 0.06 mg/l/4h[2]

Oral (rat) LD50: 738 mg/kg[2]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specifieddata extracted from RTECS - Register of Toxic Effect of chemical Substances

HEXAMETHYLENEDIISOCYANATE POLYMER

The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.* Bayer SDS ** Ardex SDS

HEXAMETHYLENEDIISOCYANATE

Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition known asreactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main criteria for diagnosingRADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes tohours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate tosevere bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without eosinophilia.No significant acute toxicological data identified in literature search. For 1,6-hexamethylene diisocyanate (HDI):Exposures to HDI are often associated with exposures to its prepolymers, one of which is widely used as a hardener in automobile and airplane paints. Boththe prepolymers and the native substance may cause asthma. HDI is corrosive to the skin and eye, and will sensitise the skin and airway. Most of the toxicityis in the upper airway (nose), although animal testing did not show that HDI caused cancer.Aromatic and aliphatic diisocyanates may cause airway toxicity and skin sensitization. Monomers and prepolymers exhibit similar respiratory effect. Of theseveral members of diisocyanates tested on experimental animals by inhalation and oral exposure, some caused cancer while others produced a harmlessoutcome. This group of compounds has therefore been classified as cancer-causing.

HEXAMETHYLENEDIISOCYANATE POLYMER &

HEXAMETHYLENEDIISOCYANATE

The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contact eczemainvolves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediatedimmune reactions.Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens and occur rapidly. Allergic potential ofthe allergen and period of exposure often determine the severity of symptoms. Some people may be genetically more prone than others, and exposure toother irritants may aggravate symptoms. Allergy causing activity is due to interactions with proteins.Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma and eczema.Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated reactions (T lymphocytes) maybe involved. Such allergy is of the delayed type with onset up to four hours following exposure.Isocyanate vapours are irritating to the airways and can cause their inflammation, with wheezing, gasping, severe distress, even loss of consciousness andfluid in the lungs. Nervous system symptoms that may occur include headache, sleep disturbance, euphoria, inco-ordination, anxiety, depression andparanoia.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye Damage/Irritation STOT - Single Exposure

Respiratory or Skinsensitisation

STOT - Repeated Exposure

Mutagenicity Aspiration Hazard

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

Rhino ArmaFloor 500 AUB-Side


NotAvailable


NotAvailable



NotAvailable


NotAvailable

hexamethylene diisocyanateENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 22mg/L 1

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EC50 72 Algae or other aquatic plants >77.4mg/L 2

EC0 24 Crustacea <0.33mg/L 1

NOEC 72 Algae or other aquatic plants 11.7mg/L 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12(QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE(Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air


HIGH HIGH

hexamethylene diisocyanate LOW LOW

Bioaccumulative potential

Ingredient Bioaccumulation


LOW (LogKOW = 7.5795)

hexamethylene diisocyanate LOW (LogKOW = 3.1956)

Mobility in soil

Ingredient Mobility


LOW (KOC = 18560000)

hexamethylene diisocyanate LOW (KOC = 5864)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging disposal

DO NOT recycle spilled material. Consult State Land Waste Management Authority for disposal. Neutralise spill material carefully and decontaminate empty containers and spill residues with 10% ammonia solution plus detergent or a proprietarydecontaminant prior to disposal. DO NOT seal or stopper drums being decontaminated as CO2 gas is generated and may pressurise containers.

SECTION 14 TRANSPORT INFORMATION

Labels Required

COMBUSTIBLE LIQUID COMBUSTIBLE LIQUID, regulated for storage purposes only

Marine Pollutant NO


Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

HEXAMETHYLENE DIISOCYANATE POLYMER(28182-81-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Exposure Standards


Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - AppendixE (Part 2)

Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - AppendixF (Part 3)

Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule6

Australia Work Health and Safety Regulations 2016 - Hazardous chemicals (other than lead)requiring health monitoring

HEXAMETHYLENE DIISOCYANATE(822-06-0) IS FOUND ON THE FOLLOWING REGULATORY LISTS

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Australia Exposure Standards

Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals


Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - AppendixE (Part 2)

Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - AppendixF (Part 3)

Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule6

Australia Work Health and Safety Regulations 2016 - Hazardous chemicals (other than lead)requiring health monitoring



Australia - AICS Y

Canada - DSL Y

Canada - NDSL N (hexamethylene diisocyanate)

China - IECSC Y

Europe - EINEC / ELINCS / NLP Y

Japan - ENCS N (hexamethylene diisocyanate polymer)

Korea - KECI Y

New Zealand - NZIoC Y

Philippines - PICCS Y

USA - TSCA Y

Legend:Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Revision Date 17/07/2014

Initial Date Not Available

Other information

Ingredients with multiple cas numbers

Name CAS No


28182-81-2, 53200-31-0, 1192214-73-5

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee usingavailable literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or othersettings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index

Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH.TEL (+61 3) 9572 4700.

Chemwatch: 42-2707

Version No: 2.1.1.1

Page 9 of 9




end of SDS

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