technical memorandum no. 3a for remedial … · "standard methods for the examination of water...

94

«: TECHNICAL MEMORANDUM NO. 3AFOR

REMEDIAL INVESTIGATION/FEASIBILITY STUDYCITY DISPOSAL CORPORATION LANDFILL

(DUNN LANDFILL)

(PELA Reference No. 495207)

Appendix G

Results of AnalysesSoil and Ground-Water Samples

Volume 16 of 16

Technical Report

SAMPLES: CA4376-CA4377

April 1991

-RE.LaMoreaux& Associates—

OHM Corporation

Environmental Testingand Certification Corp.

Technical Report

for

WASTE MANAGEMENT, INC.

:iS^

ETCStmp/tNO..l:[:M^ii^\l!X:W^

.$liHW

Richard P. AlbertVice President. Oenertt Manager

This Technical -Report is an INSITE1" service generated by LOOESTflR*" Data Management Software.

-284 Raritan Cenler Parkwav CN 7808 Edison, New Jersey 08818-7 201-225-5600-

ETC

TAJBIL,:E

Case Narrative 1Methodology 3

Volatile Data 6QC Summary Data 7Sample Data 14Standard Data • 37Raw QC Data 62

t

Semivolatile Data 90QC Summary Data 91Sample Data 98Standard Data 140Raw QC Data 181

Pesticide/PCB Data 210QC Summary Data 211Sample Data 215Standard Data 222Raw QC Data 264

Chain of Custody 274

ETC

CASE NARJRATIVE

———ETC———————————————SDG NARRATIVE

This technical report submitted by ETC Corporation contains theanalytical results and required deliverables for WASTE MANAGEMENT,INC. Site 405 samples as identified below:

ETC ID CLIENT ID ETC ID CLIENT IDCA4376 1SLPZ11I CA4377 1SLPZ11I

During the preparation and analysis of these samples, the followingwas observed:

VOLATILES: COV70337);The intact sample or extract required dilution resulting inelevated method detection limits (MDL's).

SEMIVOIATILES; (QC70246);The internal standard area counts for the blank outside QC controllimits was confirmed by the results of a replicate analysis. Datafrom both analyses has been included in this report.

The internal standard area counts for sample CA4377 outside QCcontrol limits was confirmed by the results of a replicateanalysis. Data from both analyses has been included in thisreport.

PESTICIDES/PCBS; (067024$.).;Problems were not observed during the preparation and analysis ofthis batch.

Release of the data contained in this hardcopy data package hasbeen authorized by the following signature.

Gregory G. Morrison / /' DateLaboratory Manager

ETC

METHODOLOGY

——ETC———————————-_______INTRODUCTION

Environmental Testing and Certification Corp.284 Raritan Center Parkway, CN 7808

Edison, New Jersey 08818-7808(201) 225-6700

This report contains analytical results in tabular form for your sample. It includescomprehensive data for each analytical process. Associated quality control data is alsopresented, including OC batch results for the laboratory blank, spiked blank, matrix spikeand a replicated sample spike, as well as results from surrogate compound analyses.Quality control data for instrument performance is also included. Other appendices mayinclude data system printouts and chain of custody records.

Analytical Methodology

ETC utilizes a wide variety of methodologies and ERA approved procedures which arelisted below. Analytical results and Quality Assurance protocols are based upon theapproriate guideline dependent upon the level of deliverable requested.

"Methods of Organic Chemical Analysis of Municipal and IndustrialWastewater", Federal Register Vol. 49, No. 209, October 26, 1984;

Test Methods for Evaluating Solid Waste", SW-846 Third Edition, September1986, USEPA;

"Standard Methods for the Examination of Water and Wastewater" 1985,14th, 15th and 16th Edition;

"Methods for Chemical Analysis of Water and Wastes" March 1983, EMSL,ERA 600 4-79-020;

Organic Analysis: Multi-media, Multi-Concentration-IFB-CLP, SOW February1988;

Inorganic Analysis: Multi-media, Multi-Concentration IFB-CLP, SOW July1987;

Dioxin Analysis: Soil/Sediment/Water Matrix; Multi-Concentration, SelectedIon Monitoring with Jar Extraction Procedure; IFB WA86-K357.

"Methods for the Determination of Organic Compounds in Drinking Water"December 1988, EPA-600/4-88/039;

"Handbook for Analytical Quality Control in Water and WastewaterLaboratories", EPA-600/4-79-019, March 1979;

"National Enforcement Investigation Center Policies and ProceduresManual,EPA-330/9/78/001-R, Revised May 1986.

4

——ETC ———————————————————————ETC Network Laboratories are certified to perform analytical analyses upon samplescollected throughout the United States. It may be required that this environmental databe reported with reference to a certified laboratory. The Laboratory IdentificationNumbers for ETC Corp., Edison NJ Laboratory are summarized below for yourinformation and reference. Please contact your Program Manager should you requirecertification verification for an ETC Network Laboratory.

Certification Summary. January 1990

State Agency

Alabama Department of Environmental Management

Arizona Department of Environmental Quality

California Department of Health Services

Connecticut Department of Health Services

Florida Department of Healthand Rehabilitative Services

Illinois Environmental Protection Agency

Kansas Department of Health and Environment

New Hampshire Department of Environmental Services

New Jersey Department of Environmental Protection

New York Department of Public Health

Oklahoma Water Resources Board

Pennsylvania Department of Environmental Regulation

South Carolina Department of Healthand Environmental Control

Tennessee Department of Health and EnvironmentalLaboratory Services

Utah Department of Health

Virginia Department of General Services

Wisconsin Department of Natural Resources

40280

322

162

0511

E87074& 87262

100224

E-148&E1122

198948-B

12257

10586

8703

68-323

94002

02915

E-91

00113

999464070

ETC

VOLATILE DATA

ETC

QC SUMMARY

26SOIL UOLATILE SURROGATE RECOUERY

Lab Name: ETCNJ I Laboratory Contract:

Lab Code: Case No.: SAS No.:

Leve 1 : CLOU/MED >LOUI

SDG No -

010203040506070809101112131415161718192021222324252627282930

1 EPA1 SAMPLE NO.

1 UBLK011 A43761 A43771 A4377MS1 A4377MSD1 UBLK021 A4377111

1

SI( TOL ) *

9910310110110310099

S2(BFB)#

10299999898

10198

S3(DCE)#

94939594929998

OTHER ITOTOUT-- =0000000

page 1 of

51 (TOD = Toluene-d852 (BFB) = Bromofluorobenzene53 (DCE) = l,2-Dichloroethane-d4

QC LIMITS(81-117)(74-121)(70-121)

# Column to be used to flag* Values outside QC l i m i t sD Surrogates d i l u t e d out

recovery values

FORM I I UOA -2 1/87 Rev.

3BSOIL UOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOUERY

Lab Name: ETCNJ I Laboratory Contract:

Lab Code: Case No.: SAS No.: SDG No.:

M a t r i x Spike - EPA Sample No.: A4377 Le ve 1 : (LOUJ/MED) LOU)

111 COMPOUND

1 1 , 1-Dich loroethene1 Tr i ch 1 o roe t hene1 Benzene1 To 1 uene1 Ch 1 orobenzene1

1 SPIKE1 ADDED1 lug/Kg)

= = = 1 = = = = = = = = =15000. 00015000. 00015000. 00015000. 00015000. 0001

SAMPLECONCENTRATION

(ug/Kg )

0. 0000. 0000. 000o. uoo0. 000

MS 1CONCENTRATION!

tug/Kg) 1= = = = = = = = = = = = = | =5389.504 15509.875 15350.920 15423.779 15630.871 1

1

MS%REC #

108110107108113

1 QC 1ILIMITSI1 REC. 11 = = = = = = |159-172 1162-1371166-142 1159-139 1160-13311 1

111 COMPOUND

1 1 f 1-D i ch 1 o roe t hene

1 Benzene1 To 1 uene1 Ch lorobenzene

SPIKEADDEDCug/Kg )

5000. 0005000. 0005000. 0005000.0005000. 000

MSDCONCENTRATION

(.ug/Kg )

5358. 0245486.3725345.6155440 . 4445658.587

MSD*

REC #

107110107109113

HRPD #

10000

QC LIMITSRPD 1 k'EC .

= = = = = = | = = = = = =22 159-172O A \ £. *~} 1 "^ "7

21 166-14221 159-13921 160-133

1

# Column to be used to flag recovery and RPD values with an asterisk

* Ualues outside of l i m i t s

°PD: 0 out of 5 outside l i m i t sSpike Recovery: 0 out of 10 outside limits

Commen t s:

FORM I I I UOA -2 1/87 Rev.

4AUOLATILE METHOD BLANK SUMMARY

Lab Name: ETCNJ

Lab Code: Case No.:

Lab F i l e ID: >D1138

Date Analyzed 08/31/90

Matrix: (soil/water) SOIL

Instrument ID: GC/MS D

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:

Con t rac t :

SAS No.: SDG No.:

Lab Sample ID: UBLK01

Time Analyzed: 2100

Le^e1:tlow/med) LOW

1 EPA1 SAMPLE NO.!=,===„«===«=

Oil A4376021 A4377031 A4377MS041 A4377MSD05 106 107108 109110111 112 113 114115 116 117118 119 120121 122 123 124125 126 127128129 1301

LABSAMPLE ID

CA4376UCA4377UCA4377USCA4377UR

LABFILE ID

>D1140>D1141>D1142>D1143

TIMEANALYZED

2240233000200111

-ommen t s :

page 1 ofFORM IU UOA 1/87

10

4AVOLATILE METHOD BLANK SUMMARY

Lab Name: ETCNJ

Lab Code: Case No.:



Mat r i x : (soil/water) SOIL

Instrument ID: EC/MS D


Con t rac t :

SAS No.: SDG No.:

Lab Sample ID: U8LK02

Time Analyzed: 2249

Leve1:(low/med) LOW

I EPAI SAMPLE NO.

Oil A437702!03 I04!05 I06 I07!08!09 I10 111 112 113 114115 116117118 119 120 121 122 123 124125 126127128 129 1301

LABSAMPLE ID

CA4377U2

LABFILE ID

>D1152

TIMEANALYZED

0119

Commen t s:

page 1 ofFORM IU UOA 1/87 Rev.

11

5AUOLATILE ORGANIC GC/MS TUNING AND MASSCALIBRATION - BROMOFLUORObENZLNE CBFB)

Lab Name:ETCNJ I Laboratory

Lab Code: Case No.:

Lab F i l e ID: :D1132


Con t rac t :

SAS No.: SDb No.:

BFB Injection Date:08/31/90

BFB Injection Time:15 >1

Matrix:CsoiI/water) SOIL Leve 1 : ( 1 ow/med ) LOU) Co 1 umn : C pack/cap J PACK

m/e

50759596173174175176177

I1 ION ABUNDANCE CRITERIA

1 15.0 - 40.0* of mass 951 30.0 - 60 . 05< of mass 951 Base peak, 10054 r e l a t i v e abundance1 5.0 - 9 . 0% of mass 951 Less than 2 . 0* of mass 1741 Greater than 50.056 of mass 951 5.0 - 9.0% of mass 1741 Greater than 95. OS, but less than 101. OS of mass 1741 5.0 - 9. 054 of mass 1761

5i RELATIVEABUNDANCE

19.57.

100.7.0.

90.6 .88.6 .

52080 t64 (2 C4 I

0.0)1

7.1)197.3)17.3)2

1-Oalue is 54 mass 174 2-Ualue is H mass

THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

0102U304050607080910111213141516171819202122

EPASAMPLE NO.

USTD50USTD200USTD150USTD100USTD20UBLKOlA4376A4377M4377MSA4377MSD

LABSAMPLE ID

QC70337USQC70337USQC70337USQC70337USQC70337USQC70337UCA4376UCA4377UCA4377USCA4377UR

LABFILE ID

>D1133>D1134>D1135>D1136>D1137>D1138>D1140>D1141>D1142>D1143

DATEANALYZED

08/31/9008/31/90U8/31/9008/31/9008/31/9008/31/9008/31/9008/31/9009/01/9009/01/90

TIMEANALYSED

1600173818281919201021 UO2240233000200111

page of FORM U UOA I/, Rev.

5AUOLATILE ORGANIC GC/MS TUNING AND nASSCALIBRATION - BROMOFLUOROBENZLNE (6FBJ

Lab Name : ETCNJ

Lab Code:

Lab F i l e ID: ^


I Laboratory

Case No. :

Cont rac t :

SAS No . : SDG No . :

BFB Injection Date: O^/

BFB Injection Time: / °) :

M a t r i x : (soi I/water) SOIL Leve1: C1ow/medJ LOW Co 1umn: Ipack/cap)PACK

m/e

50759596173174175176

ION ABUNDANCE

15.030.0Base5.0-LessGreat5.0-Gr ea t

177 1 5.0 -1

- 40. OX

CRITERIA

of mass 95- 60 . OX of mass 95peak, 19. OX o

than 2.e r than9 . OX o

er than9. OX o

OOX ref massOX of50. OX

f mass95. OX

f mass

lative abundance95

mass 174of mass 95174, but less than 101176

1 X RELATIUE1 ABUNDANCE

1 20.1 56.1 100.1 7.1 0.1 94.1 6.

OX of mass 174 1 91 .1 6.1

10030 (19 (7 t7 (

0.

7.97.7.

0)1

3)14)14)2

1-Ualue is X mass 174 2-Ualue is X mass 176

THIS TUNt APPLIES TO THE FOLLOWING SAMPLES, MS, hSD, BLANKS, AND STANDARDS:

1 ERA1 SAMPLE NO.|. »«. = »».„.„

Oil USTD5002 1 UBLK0203 1 A437704105 106 107108 109 110 111 112 113 114115 116 117118 119 120 121 122 1

LABSAMPLE ID

QC70337USQC70337U2CA4377U2

LABFILE ID

>D1147>D1149>D1152

DATEANALYZED

09/01/9009/01/9009/02/90

TIMEANALYSED

210722490119

page of FORM U UOA Rev.

ETC

SAMPLE DATA

14

1AUOLATILE ORGAN ICS ANALYSIS DATA SHEET

Lab Name: ETCNJ

Lab Code : Case No . :

M a t r i x : (soil/water) SOIL

Sample wt/vol: .0 (g/mL) G

Level: (low/med) LOW

% Moisture: not dec. *K ( 8~

Column: (pack/cap) PACK

Cont ract:

SAS No.:

ERA SAMPLE NC

IIA4376I_____

**

SDG No.:

Lab Sample ID: CA4376U

Lab File ID: >D1140

Dat e Recei ved :

CAS NO. COMPOUND

Date Analyzed: 08/31/90

Dilution Factor: 100

CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG U

74-87-3---------CH lorome thane______________I 100074-8 3-9------- --Bromome thane________________I 1UOO75-01-4-- —— — — Uinyl Chloride______________I 100075-00-3--—— -- — Chlo roe thane_______________I 100075-09-2----- —— -Methylene Chloride_________15006 7-64-1---------Ace tone_____________________1420075-15-0- —— - — --Carbon Disulf ide___________150075-35-4---------l,l-Dich loroethene_________I 50075-34-3————————1,1-Di chlo roe thane_________1500540-59-0——----1,2-Dichlorethene (total)__150067-66-3-- — -----Chloroform_________________1500107-06-2 — — ——— 1,2-Di chlo roe thane_________150078-93-3- ——— ——— 2-Butanone_________________12000071-55-6-- ————— -1,1,1-Tr i chlo roe thane______150056-23-5- —— - ——— Carbon Tet rach 1 or ide_______I500108-05-4- —————— Uinyl Acetate______________I 100075-27-4--------~Bromodichloromethane________I 50078-87-5---------l,2-Dich loropropane_________150010061-01-5-- — --cis-1,3-Dichloropropene_____I 50079-01-6-- — - — --Trich loroethene____________1500124-48-l--------Dibromoch lorome thane_______I 50079-00-5 ——— - ——— 1,1,2-Tr i chlo roe thane______150071-43-2 ———————— Benzene________________________150010061-02-6------trans-l,3-Dichloropropene__150075-25-2 ———————— Bromoform__________________1500108-10-1--------4-Me thy 1-2-Pentanone________I 1000591-78-6 ——————— 2-Hexanone__________________11000127-18-4----- —— Tet rach loroethene__________150079-34-5- ——————— 1,1,2,2-Tetrachloroethane__1500108-88-3 ————— --Toluene____________________1500108-90-7--------Ch lorobenzene______________I 500100-41-4———————Ethyl benzene__________________1500100-42-5 —— — — -Styrene_____________________15001330-20-7——————Xylene (total )___________1500____________________________________________ I_____

IUIUIUIUIUIIUIUIUIUIUIUIIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

FORM I UOA I/87] §e

1AVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: ETC

Lab Code: Case No.:

Contract:

SAS No.:

EPA SAy?L.I NO.

ASDG No.:

Matrix: (soil/water) SOIL.

Sample vt/vol:.*? &> _____(g/mL)_§;_

Level: (low/ned)

% Moisture: not dec.

Column: (pack/cap)

Lab Sample ID:

Lab File ID: 7orf

Date Received: _j£

Date Analyzed: P

CAS NO. COMPOUND

Dilution Factor:

CONCENTRATION UNITS:(ug/L or ug/Kg) MStluG

Tetrahydrofuran_

FORM I VOA 1/87 Rev.

16

IEVOLATILE ORGAN ICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

Lab Name:ETCNJ I Laboratory

Lab Code: Case No.:


Sample wt/vol: .1 (g/mLJ G

Le^el: (low/med) LOU

% Moisture: not dec. 18


Number TICs found: 2

Lon tract:

SAS No.:

EPA SAMPLE NO.

IIA4376I ____

SDG No.:

Lab Sample ID: Crt4376V

Lab Fi \e ID: >D1140Cy/23,/9

Date Received: 09/OS/1'?


D i l u t i o n Factor: 82.0

CONCENTRATION UNITS:lug/L or ug/Kg) UG/Kb

CAS NUMBER

01.02.

COMPOUND NAME

UnknownUnknown

RT

21.2015.^8

EST . CONL

60U600

Q

JJ

FOKIM I UOA-T 1C 1/87

M

TOTAL ION CHROMPTOGRflMFi le >D1

78000-

60000-

50000-

48888-

30000-

30000-

10000-

0-

140 35.0-360.0 amu

. i . .

. B4376,, CR4376V ,QV70337,Sir

400 t 600 | 800 ; 1000

i §I j !•? I

ji:

7 9

4 e :

s § H 1i | 12) 1

l iI :i

15

1 ' I12

5 ^

S|

<4

1

iv ^Jl.

t ^ 2g «n

|I I

3

IWl8

16 Z9 34 38 33 36 40

Data File: >D1140::SSName: A4376,,Misc: CA4376U ,QU70337,S:M4,0.05,, 1:100 DL

Id File: ID0259::U1Title: XUOA13, IFB, PP/UOALast Calibration: 900901 17:25

Operator ID: EK1710Quant Time: 900901 17:27Injected at: 900831 22:40

Quant Output File: ~D1140::AQ

18

Operator ID:Output File:Data Fi le:Name : A4376 , ,Nisc: CA4376U

EK1710~D1140::AQ>D1140::SS

,QU70337,S:M4,

QUANT REPORT

Quant Rev: 7 Quan t TimeInjected at

D i l u t i o n Factor

1:100 DL

Page 1

900901 17:27900831 22:40

1. 00000

ID File: ID0259::U1T i t l e : XUOA13, IFB, PP/UOALast Calibration: 900901 17:25

Compound R.T. Scan* Area Cone Units

1)7)9)15)18)20)21)36)41)43)45)46)48)

*Bromoch lorome thaneMe-t- h v \ erre — L!I lui iUi -*- .y • • • ~t ~ ' T • ~ • * w ^Acetone I/ .Te t rahyd ro fu ran */1 ,2-Dichloroethane-D4 (SURR)

*1 ,4-Di f luorobenzeneMethyl ethyl ketone^/

*Ch Iorobenzene-d5Toluene-DS CSURR)

p-Bromof 1 uorobenzene (SURR)

mto Xmlenng —

11.

9.12.14.22.14.27.25.27.32.34.36.

62093367532061219333684714

266175207293341539343668635671809Q r- c

B9B

3875637121028371757788915960812205

117999174658

983342324•550*

250.20.211.276.231.250.1017.250.256.6.

248.4.

i n .

00

47766000040052121609R<r,

NGklf~"

NGNGNGNGNGNGNGNGNGklf"*

Nr;

97939510093979482957690O JL

91

* Compound is ISTD

19

REFERENCE STRNDORO SPECTRUMFile >C4697Bpk Rb 9999

10000-

j"-1— i—

Targat Reference SpectraNRM NOH

43s-

44 46 48 58 52

Scan 1667. 48 tain.

[-100

. . . . . . . . . I54 56 56

SOMPLE SPECTRUM <BRCKSROUND SUBTRRCTED)File >D1140 R4376, ,Bpk Rb 746

43I

506-•.

Q

X

42/s[

44

44 46

CR4376V .QV78337, 3:04,8. 8 Scan 297SUB 9-33 Kin.

58-

1

-100.•-PI

48 ' 50 ' 52 ' 54 ' 56 ' 58

SRMPLE SPECTRUM (UNRLTERED)File >D1140 04376, ,Bpk Ob 746

43:

500

^

42/

'

44

144 46

CR4376V ,QV70337,S:M4,0.0 Scan 2079.33 Min.

58

|

-100

-Pi48 ' 50 ' 52 ' '54 ' 56 ' 58

Data File: >D1140::SS Quant Output File: ~D1140::AQName: A4376,,Misc: CA4376U ,QU70337,S:M4,0.05,, 1:100 DLQuant Time: 900901 17:27 Quant ID File: ID0259::U1Injected at: 900831 22:40 Last Calibration: 900901 17:25

Compound No: 9Compound Name: AcetoneScan Number: 207Retention Time: 9.33 min.Quant Ion: 43.0Area: 10283Concentration: 211.47 NGq-value: 95

20

REFERENCE STftNDflRD SPECTRUMFile >CS010Bpk Rb 9999

10000-j i'

^ . i40

Tarset Reference SpectraNRFt NOn

43

72

1 \50 ' 60 ' 70 ' 80

Scan13.06

90 100

309tun .

-109

LSflMPLE SPECTRUM (BRCKGROUND SUBTRRCTED)File >D1140 R4376, ,Bpk Rb 4503

43

4000-•

gt

42 51

. . \ ,40 S0

CR4376V ,aV70337,S:M4,0.0 Scan 343SUB 14.61 Bin.

65

1 7357 63 / 10£Mf,.....',),!...,)...,,.,,.,,.,.,.,,,,,,,,,,,,,.'',,-

-100

69 70 80 90 100

SflMPLE SPECTRUM CUNRLTERED)File >01140 R4376, ,Bpk Rb 4503

43

4000-

-42

""

51

, , 1 ,40 50

CR4376V ,QV70337,SiM4,0.0

65

= 7 «J , 7\ -M" 1 160 70 80 90

Scan 34314.61 min.

161

-1B0

100


Compound No: 21Compound Name: Methyl ethyl ketoneScan Number: 343Retention Time: 14.61 mm.Quant Ion: 72.0Area: 12205Concentration: 1017.04 NGq-value: 94

REFERENCE STPNORRO SPECTRUMFil« >DBMS T«rs«t R«f«r«nc« Sp«c tr* Scan 251Bpk Ob 9999 CLP NRM NOM 251.00 Min.

4210008-

;& , r , ,-r^-, , , . ,- r-r . , . , -.--, . , . r-r- ,.,,-,-

43 78

48 44 46 52 56 68 64 68

-100

-072

SPMPLE SPECTRUM (BPCK6ROUND SUBTRPCTED)FileBpk

>D1140 P4376, , CP4376V .QV70337 ,S :M4 ,0 .0 Sc*n 293Pb 597 SUB 12.67 min.

42

J '460H 39{-"

J)

43

1 .

[-100

4e ' ' ' 44 ' ' '4e' ' '52' ' ' ?6 ' ' 's'e' ' '$V ' 'e'e' ' ' izSPMPLE SPECTRUM CUNPLTERED)Fi l* >01140 P4376, ,Bpk Pb 597

42

400^9

(3 i43

1 148 ' 44 ' 48

CR4376V ,QV70337,SiM4,0.0 Scan 29312.67 m i n .

Fee

52 ' 56 ' 60 ' 64 ' 68 ' 72

Data File: >D1140::SS Quant Output File: ~D1140::«QName: A4376,,Misc: CA4376U ,QU70337,S:M4,0.05,, 1:100 DLQuant Time: 900901 17:27 Quant ID File: ID0259::U1Injected at: 900831 22:40 Last Calibration: 900901 17:25

Compound No: 15Compound Name: TetrahydrofuranScan Number: 293Retention Time: 12.67 min.Quant Ion: 42.0Area: 7175Concentration: 276.76 NGq-^alue: 100

22

File >D1140 S4376,Epk Sb 9999

10000-

800*-

600£-

400CV-

''RPi CV-

'"J.,.,,File Ht:49KBpk Rb 9999

leeee-seeo-iea*-4000-

2000-

27\

cJ ____ 1

, CS437c.',' .QV73337 ,3 :M4 ,0 .05 . , icir, 51oSUE NPM 21 .20 mm.

41 rr

!

57""

-100

-80

-60

.i j i' £1 7 (-? i"i

• I ^tl "40 SS 126 ID£' 200

1-Bute-ne * c in 800.00 mm.

41

U)

i

56.--'

llrt

C" ™*

-i oeUo-by

-40

-2(<

,- - "~ L40 S3 120 lt-0 200

Data File: >D1140::S3Name: £43 76,,Misc. Date: LM4376U , C" .'"0777 , S : (14 , 0 . 05 , , 1:100 DLPT ( m i n i : 21 . 20Scan: ?13Area: 47979 Rank: 4Sem i -qi.an t i t a t i ve Cone ', unco r r ec t ed -1 : 30.06 NGSern i-quan t i t a t i'./e Cone ( c o r r e c t e d ): 601.22 ug/l- gC a l c u l a t e d usinq Istd: 1 , 4-D i f 1 uo r obenrene (51 22.24 min u t e s

1. i-Butene 56 C4HS

Sample f i l e : >D1140 Spectrum #:" e a r c h speed: 2 T i l t i n g option: S

5 17No. of ion ranqes searched:

P r o b . CAS # CDt-i $ ROOT K DK tt-LG TILT

11* 106°8':' °9S NBS49k' 25 54 2 0 65

23

Ti l * 51)1140Bpk flb 9999

1 IC00-

isoao-

90.*-

rea^

eaee-

seo*

4600-

3000-

2000-

10 FiFt

'",

fl4376

4

39

i

40

* »

1

4 2

13

4 4

C04276V , Q V 7 C 3 3 7 ,: :M4 ,0SUE MPM

c

46 43 E0 52 S4

65

5

, , ; c

E7

i

i 58

in 3fci, m i n . |

:"*^100

_QIJ

-70

-r 0

L-,

|ao

he

-3a

r

^

Data F i l e : >D1140::SSN^me: A4376 , ,Misc. Data: CH47-76O , Q'.i^O??"7 , $ : M4 , 0 . O1? , , 1:100 DI-PT ' mm) : 15 .53bear: ?6bHrea: 70156 Rank: 5Sem i-quant i t at ive Cone ( unco r rec t ed ): 2'5.96 NGSem i -quan t i t a t i >.>e Cone C corrected ) : 599.27 uq.--'l qC a l c u l a t e d using Istd: Er ornoch 1 o rome thane |9 11.66 mi nut'

t-io PBtl h i t s for t h i s scan.

24

1AVOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

IIA4377

Lab Name: ETCNJ Con t rac t :


Matri x : (soil/water) SOIL Lab Sample ID: CA4377U

Sample wt/vol: .0 Cg/mL) 6 Lab File ID: >D1141

Level: (low/med) LOUI Date Received:

?i Moisture: not dec. "frit? <c\


CAS NO. COMPOUND


Di lut ion Factor: 1UU

CONCENTRATION UNITS:lug/L or ug/Kg ) LJG/KG

I74-87-3---------Ch lorome thane______________I 100074-83-9---------Bromome thane________________I 100075-01-4- — - ———— Uinyl Chloride______________I 100075-00-3---------Ch lo roe thane________________I 100075-09-2- ————— --Methylene Chloride_________15006 7-64-1---------Ace tone_____________________I 580075-15-0---------Carbon Disulf ide___________I 50075-35-4- — ------1,1-Dich loroethene_________150075-34-3---------l,l-Dich lo roe thane__________I 500540-59-0----- — -1,2-Dichlorethene (total)__I 50067-66-3- ——— -- — Chloroform__________________1500107-06-2--------l,2-Dich lo roe thane_________I 50078-93-3- — -- — --2-Butanone_________________13100071-55-6--- — ----1,1,1-Trichloroe thane_______150056-23-5- — -- — --Carbon Te t rach 1 or ide________1500108-05-4- — - — --Uinyl Acetate_______________I 100075-27-4---------Bromodichloromethane________I 50078-87-5---------l,2-Dich loropropane________150010061-01-5---—-cis-l,3-Dichloropropene____150079-01-6---------Trich loroethene____________I 500124-48-l--------Dibromochloromethane_______I 50079-00-5- — —— ——1,1,2-Tr ich loroethane______150071-43-2- —————— -Benzene____________________150010061-02-6------trans-l,3-Dichloropropene___I 50075-25-2---------Bromof orm___________________I 500108-10-1 ——————— 4-Methyl-2-Pentanone________I 1000591-78-6 —— —— --2-Hexanone__________________I 1000127-18-4- — ———— Tet rach loroethene__________150079-34-5- — —— — -1,1,2,2-Tetrachloroe thane___1500106-88-3 ——————— Toluene____________________1500108-90-7----- — -Chlorobenzene______________1500100-41-4--------Ethyl benzene_______________1500100-42-5 — — ——— Styrene____________________15001330-20-7- ——— — Xylene (total )____________1500

Q

IUIUIU!UIUIIUIUIUIUIUIUIIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI LIIUIUIUIUIUI

FORM I OOA ev.

Lab Name:

Lab Code:


___________ Contract:____

Case No.: _____ SAS No.:

EPA SAXFLI NO.

,44377

Matrix: ( soil/water )

Sample wt/vol : ~O

Level: (low/med)

% Moisture: not dec. •' 6

Column: (pack/cap)

(9/aL).

CAS NO. COMPOUND

Tetrahydrofuran

SDG No. :

Lab Sample ID:

Lab File ID:

Date Received:

Date Analyzed:

Dilution Factor: /

CONCENTRATION TWITS.:(ug/L or uo/Kcr)

FORM X VOX 1/87 Rev.

26

IEUOLAT1LE ORGAN1CS ANALYSIS DATA SHEET

TENTATIUELY IDENTIFIED COMPOUNDS

Lab NamerETCNJ I Laboratory

Lab Code: Case No. :

natrix: (soil/water) SOIL

Sample wt/vol: .1 (g/mL) G

Level: Clow/med) LOW




Con t rac t :

SAB No.:

ERA SAMPLE NO.

IIA4377I_____

SDG. No. :

Lab Sample ID: CA4377U

Lab File ID: >D1141o?/t3/<?*

Date Received: • OSMUOV9U


D i l u t i o n Factor: 84.U

CONCENTRATION UNITS:tug/L or ug/Kg) UG/Kb

CAS NUMBER

01. 110-54-302.

COMPOUND NAME

HexaneUnknown

RT

21. 1915.53

EST. CONC

560890

-

Q

JJ

FORM I UOA-TIC 1/87 K'ev.

27

TOTPL ION CHROHPTOBRPMFile >D1141 35.0-860.0 »mu. B43". ,

TIC

70000-

60000-

peeee-

40008-

30000-

20000-

10000-

CP4377V ,QV70337,S:r

600

7 9

' 1

15JL. ^Ji

16 88 3£ 36 40

Data File: >D1141::SSName: A4377,,Misc: CA4377U ,QU70?37,S:M4,0.05,, 1:100 DL




28

QUANT REPORT Page

Quant Rev: 7Operator ID: EK1710Output File: ~D1141::AQData File: >D1141::SSName: A4377,,Misc: CA4377U ,QU70337,S: M4/frr* -, , 1:100 DL

ID File: ID0259::UlTitle: XYOA13, IFB, PP/UOALast Calibration: 900901 17:25

Quant Time:In jected at:

Dilution Factor:

900901 17:28900831 23:30

1.00000

Compound R.T. Scan# Area Cone Units

1)7)9)15)18)20)21)36)41)42)43)45)46)48)

•Bromoch loro me thaneMethylene .ihloi ideAcetone \/Tet rahydrof urarn/l,2-Dichloroethane-D4 (SURR)

*1 ,4-Di f luorobenzeneMethyl ethyl ketone /

*Chlorobenzene-d5Toluene-DB (SURR)

Ghlui uUeii^mil!-p-Bromof luorobenzene (SURR)

11.618. 089.33

12.7014.4822.2414.6027.2125.9626.1227.3232.6734.5036.17

267176208295341541344669637641672810857900

388523484140399548798321638011901412144817715424412856

10140228583534

250.00 NG18.98 NG288.00 NG367.39 NG236.79 NG250.00 NGHMJ.OO MG//'250.00 NG252.80 NG6.64 NG5.91 NG

248.63 NG4.89 NG

10.62 NG

9497931009299

25" 9585969779917493

* Compound is ISTD

29

-DO3 C TJ— an9 3 1n <f ar+ r+(1 H 0a - - -i

3an —r* •• £J.. ••

NO ^O 3o o <no o ;o\o ^o uo o into 10O I-1h«* \5l• • ••

»-* *>-o 10

r™ 'j ( tft .-• aw <f

IT •-•n •• —a n•~* x •*— ctr o -~J T> Oa i-> of \tl 10»-•- v VJ10 •<)3 »— « ••» -n ••

ro c>€>. l->Oo TJ• 3 "0(=> \ro c

Ovji

is

301n

i"}T>V>l

SJ

^ro^JOCoWkw

\J

waooro\ji

V

"

h-»

toOC3

Dr

Z 0a OP3 <+n a

T|X^ *-'^ —^ (I\J ••\J- D

!-•\j!ro

C(->

ocart-

Oc/*TJC<f

"1^^n• •

O . S S S 3 3 3 S 3 3 3 S S 2 - VA n f f l m ' ^ f f i A A i S A A O A m V

< f . 9 ( p < p < p i B ( y < J ) < y ^ ) ( p ( p < p < p ( p 0

-Jf

•G0~

~

Hru

"•

"*"

~

ro19

roj

a>~-

bjro"

^-

"^ '<9"

_

' l>

______ ^^^^^ -i^• ^ ^™"" " 1~ HrDfTTOcW-ort'mwnorM

* OI

•~z- •» —— —— 1f3-Oi«Noro*thon«-D4 (5URR)

** i Dtl

I " —— — Chtarobcnzcne-dS4fI1

^======^^<™«^<*™«* CSUMO

M(KTO

b)01

Q>ro m-<o o-.<9 (9

•ii3C

* -ID-3) «».o oa

^

<D

_

Ox>00 *to ua> >j

ro-

O

-® 2* w<9 ^

OT

>o

KJ

D

CMCD

QUANT REPORT

Operator ID: MGRMS QuantOutput File: /SD1152::AQData File: >D1152::U1Name: A4377,,Misc: CA4377U2 ,QU70337,S:M4,0 . 025,,

ID File: ID0259::UlTitle: XYOA13, IFB, PP/UOALast Calibration: 900902 15:34

Compound

7 Quant Time:In jected at:

Di lut ion Factor:

Page 1

900902 15:42900902 01:19

1.00000

1:200 DL

R.T. Scan* Area Cone Units

1)9)15)18)20)21)36)41)45)

*Bro mo chlorome thaneAcetoneTe t rahydrof uranl,2-Dichloroethane-D4 CSURR)

*1 ,4-Di f luorobenzeneMethyl ethyl ketone

*Ch Iorobenzene-d5Toluene-08 (SURR)p-Bromof luorobenzene (SURR)

11.9.12.14.22.14.27.25.32.

621459492453219772

266202291340540341668636810

41796803856038610217095211351127870184532106517

250.146.191.244.250.847.250.247.245.

008772210068002539

NGNGNGNGNG .NG NGNGNG

9594100949893849489

» Compound is ISTD

31

REFERENCE STflNDflRD SPECTRUMFile >C4697 T»rs«t R«f«r«nc« Sp«c tr*Bpk flb 9999 NRH NOD

43leeee-

e- , . i . i . i . i . i • i . i . i • i . i . i •

^

44 46 48 60 52 54

Scan 1667.48 Kiln.

kiee

L56 ' 58

SRMPLE SPECTRUM <BPCK6ROUND SUBTRPCTED)Fila >D1141 P4377, ,Bpk Pb 993

431000-

•42

i

y

44

' '4V "46

CP4377V ,aV70337,S 1(14,0.0 Scan £98SUB 9.33 Bin.

58

' 48 ' 60 ' 68 ' 64 ' 66 ' 5(

-100

-0J

SPMPLE SPECTRUI1 <UNPLTERED>Fil« >D1141 P4377,,Bpk Pb 993

431000-

.

e-4a'

441

i i " i i '44 46

CP4377V ,QV70337,S iM4,0.0 Scan 2089.33 Bin.

58|

-100

-fi48 50 5£ 54 56 58


Compound No: 9Compound Name: AcetoneScan Number: 208Retention Time: 9.33 min.Quant Ion: 43.0Area: 14039Concentration: 288.00 NGq-value: 93

32

REFERENCE STANDARD SPECTRUMFile >C£010 T«ra«t Reference Spectra Scan 309Bpk fib 9999 NRM MOM 13.06 Kin.

4310000-

•

0-

*~^

72

i. ......................... A.. ................................

-106

•

-048 58 60 76 80 90 108

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)File >D1152 A4377, , CA4377V2 ,QV70337,SsM4 ,0. Scan 341Bpk Ab 6646 SUB 14.53 «in.

65•,

4000-

f^ '

43^~

42\40

51

I I I' 50 60

67i"" 72 102

1-100•

70 ' 80 ' 90 ' 100SAMPLE SPECTRUM (UNALTERED)File >D1152 A4377..Bpk Ab 6648

•.

4800;

0.

CA4377V3 ,QV78337,S :M4 ,0 . Scan 34114.53 Bin.

6543

42\

40 '

5157

... , . ' !_ Jj

67^ 7£ 182

. . , 1 1 i .

j-100

-a,, 1.^4 W i-|-i-|. ir,-r, T- r- ,,T „,,,-,„, ,,,,.,,,,, j- r y, , , ,_r, j , „

50 60 70 80 90 100

Data File: >D1152::U1 Quant Output File: "D1152::AQName: A4377,,Misc: CA4377U2 ,QV70337,S: (14, 0 . 025 ,, 1:200 DLQuant Time: 900902 15:42 Quant ID File: ID0259::U1Injected at: 900902 01:19 Last Calibration: 900902 15:34

Compound No: 21Compound Name: Methyl ethyl ketoneScan Number: 341Retention Time: 14.53 min.Quant Ion: 72.0Area: 11351Concentration: 847.68 NG

93

33

REFERENCE STANDARD SPECTRUMFile >DBMS Target Reference SpectraBpk Rb 9999 CLP NRM NOM

4£10000-

•

e-

4:'

f^

148 44 48 52 56 60 64 68

Scan 251251.00 (tin.

72

J |

-100

;-0

iz 76 88

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)Tile >D1141Bpk Ab 763

500-

:39V

A4377,, CA4377V .OV70337 ,S :H4 ,0 .0 Scan 295SUB 18.70 (tin.

4841/ 78

/ 831 \

hi 00;•

1 46 4V ' 4'e1 ' 'rfe ' '5V ' '6V ' «V ' 'e' ' ii ' >V ' 'eV ' "SAMPLE SPECTRUM (UNALTERED)File >D1141Bpk Ab 783

500-

^

39v

04377,, CA4377V .QV78337 ,S :M4 ,0 .0 Scan 295

4843/ff

18.70 «in.

72

1, 1

i »j

\

hl00

•

48 44 48 58 56 60 64 68 78 76 60

Data File: >D1141::SS Quant Output File: "D1141::AQName: A4377,,Misc: CA4377U ,QU70337,S:M4,0.05,, 1:100 DLQuant Time: 900901 17:28 Quant ID File: ID0259::U1Injected at: 900831 23:30 Last Calibration: 900901 17:25

Compound No: 15Compound Name: TetrahydrofuranScan Number: 295Retention Time: 12.70 min.Quant Ion: 42.0Area: 9548Concentration: 367.39 NGq-value: 100

34

! File Mil 141 84377, ,Epk fib 9999

41

3000-4000-

6-

/ 5?

I Ii' J!l, ill:

40

C04377V ,G>V7e337,Sil>l4,C.05, , Scan 514SUE HRM 21 .19 n.iti .

86 2P7y "v.li

-se-4 Pi

-0ee lie lee see

F i l e N!-:-49tBpk fib 999?

Sc«r, 6810 . 0C" »in.

80ee-

0- , , , , ,

27

J .,

File HBI49KEpk fib 9999

seoe-430<d~l

0-

27"-w, ^

, ,,, J

574? '"""n''

Ju Sf. £:7

-60

-fi40 se 120 166 see

Pen tine. 2-m*thy 1- Sc»n 6780.00 mill.

43

iI, II

71/ . . 87

....„!. J y^--^^

-ee••40

-e4e ee ise 160 see

Data File: 5D1141::SSName: A4377,,Misc Data: CA4377U ,Q"703?7 ,S : M4 , 0 . 05 , , 1:100 DI-RT Cm in >: 21 . 19Scan: 514Area: 46474 Rank: 4Bern i - q u a n t i t a t i v e Cone Cuncorrected 1 : 28.04 NGSemi-quantitative Cone ( corrected ): 560.76 ug-'kgCalculated using Istd: 1,4-Dif1uorobenzene @ 22.24 minutes

1. Hexane2. Pentane, 2-me thy 1-

86 C6H1486 C6H14

Sample file: >D1141 Spectrum #:= a r c h speed: 2 T i l t i n g option: S

514No. of ion ranges searched: 46

Prob. CAS # CON ^ ROOT

52* 110543 6971 NBS49K20* 10"7S35 4260 NBS49K

K DK #FLG TILT

7826

CON C ! P I"

5860

22 71

1854

0

35

VDK)

CO •

',$, £ C. 03g »-* Q C,: £i '3? 'i' 'j' C< d' '':. i«j

'^ _ T, i , i7M , ,T, ,,,'?,, , i'Y, . i /fi . i ,'i'ii, ,7i , i ,'i'i i i.'i'i , i ,Ti 1 1 i'i|JU>

Ul<~

r-Ul

Ul£> u» .

ui "v ——0

2

i-

CDr-b

•:. E

>•) .

d 0 •

u>/TJ-

'*

^ ITKr-

S " \jg' A A A A A A A A & A A ,j•"• U1 ,-« is Q-, tyj i ..£j ift ^ CO fsj ^-«

.^a " "a

- a.L.a

t

..''-0iii

•oUl

.J.w

"LI_

13)U)

."»

~

..'i'

~V

i\j"*

^

"*

j

_JQoo<-*""

«-H

-•

O

O•*-

x^

*.tor-KiK,OI V

-•i'0

D-i r.--T r- K,-H K. If". ' -T •LJ - a U--". • U i

f\ CO•• r-, •• -o0) f-i iO •• K.

— xT *-• •--• <I iP C

Lu LJ -e ..iO ID U - C-tJ £ u) iDiD iD " 1— OLJ z r a: i/j

OJ

DC

en --i; t\

CD CTiLf"Z D -0

.o KI *~^'*-T Ci ^ — '.

--T ra ej'J ijj

CO OJc

XT• • .. •*-•

4) T3 0-t-j lj_i i_ •O 4-' 0

ill tj "~*i- a> -ci- i. UD i_ O

IT- 0 0 £C (J OD >-

.. _ „ QQ_ C o U •••C £. C T3

Qt O u <-U U a!

<U 0);• : tji' - • ' -* C

C-l ^ ^' -<-i iu m uili. •*-' *^ D-3- - ~•? -U 4-. T)

C C 0)

n 3 IDcr cr —

ID " - O11 e £ —t- iD lU "0;I 1/1 i.O u

.CIDOu)

u)

Si•#-•

^O

'14-

10+-'

•*"

ma.o

~?

ETC

STANDARDS DATA

37

6hUOLATILE ORGAN1CS INITIAL CALIBRATION DATA

Lab Name:ETCNJ I Laboratory Contract:


Instrument ID:GC/MS D Calibration Date(s ) 08/31/90 08/31/9U

Matrix:(soiI/water) SOIL Leve1: (Iow/med) LOW Co 1umn: (pack/cap) PACK

Mm RRF for SPCC ( #) - 0.300 10.250 for Bromoform) Max JiRSD for CCC(») = 30.0*

ILAB FILE ID: RRF20 =>D1137IRRF100=>D1136 RRF15 0= >D1 1351

RRF50 =>D1133RRF200«>D1134

1 1 1 1 1 1 11 COMPOUND IRRF20 IRRF50 1 RRF100 1 RRF150 1 RRF2U 0 1

1 Ch 1 o rome t hane ••\ Bromome t hane

t .35511 .3121

lUinvl Chloride * .69611 Ch 1 o roe t haneiMethvlene Chloride1 Ace t oneICarbon Disulfide

.490 11.316 1.355 1

3.430 11 1 . 1-Dich loroethene * 1.11911 1 ,1-Dichloroethane # 2.32711 1,2-Dichlorethene (total) __ 1 1.2261IChlorofo-rm * 2.68311 1 ,2-Dichloroethane1 2-Bu t anone1 1 ,1 ,1-TrichloroethaneICarbon Te t rach lor i deI'Jmvl AcetateIBromodlchlo rome thane1 1 ,2-Dich loropropane *1 c is-1 ,3-Dich lorop ropene ___1 Tr ich loroethene1 D i bromoch 1 o rome thane1 I ,1 ,2-Trichloroethane1 Benzene1 trans-l,3-Dichl oropropene __1 Bromo form :!4-Methvl-2-Pentanone1 2 - He x a n o n e1 Tet rach loroethene

2.1671. 019 1.7881.665 1.399 1.6171.310 1.409 1.3941.440 1.3041.8981.3841.289 1.383 1.318 1.588 1

11,1 /2, 2-Tetrachl oroe thane _ * .508 1IToluene * .8211IChlorobenzene * 1.06811 Et hulbenzene * .56911 S t v r e n e1 Xvlene (total )

1 To 1 uene-d8iBromofluorobenzene1 1 ,2-Dichloroethane-d41

1.2671.725 1

1.4541.8471

2. 095 11

FORM

.418 1

.3671

.818 1

.555 11.2641 1.356 1

3.8121 31. 116 1 12.2881 21.2661 12.6201 21.9621 2. 0191.7471.662 1.450 1.576 1.286 1.3841.3671.389 1.262 1.8271.3541.255 1.3171.2541.562 1.449 1.7571

1. 008 1.556 1

1.203 1 1.696 1

1.401 1 1.8371

2. 062 1 2\

UI UOA

.3571

.3051

.732 1

.4941

.0931

.316 1

.430 1

. 071 1

. 1671

. 193 1

.5201

. 0291

. 019 1

.7241

.659 1

.379 1

.6041

.289 I

.398 1

.3591

.445 1

.2791

.799 1

.381 1

.322 1

.3271

.246 1

.5471

.473 1

.739 1

.979 1

.536 1

.2071

.675 1

.455 1

.8541

. 199 11

.3701

.273 1

.762 1

.503 11. 131 1.278 1

3.726 11. 076 12.208 11.21012.54212. 021 1. 019 1.7141.659 1.436 1.5941.2821.401 1.351 1.4341.263 1.7801.381 1.319 1.3101.245 1. 545 1.458 1.742 1.978.542

1.203.681

1.451.842

2.259

.371 1;257I.731 1.498 1

1. 100 1.263 1

3.66411. 066 12. 132 11.20412.453 11.870 1. 0171.6841.6471.418 1.562 1.2641.380 1.343 1.3941.2321.7561.3471.281 1.2741.2041.536 1.409 1.723 1.939 1.515 1

1. 133 1.648 1

l.:452 1. is i

2.i32 11

1111

RRF 1

.3741

.303 1

.748 1

.508 11. 181 1.3141

3.613 11. 090 12. 22411/220 12.563 12. 010 1. 019 1.731 1.658 1.416 1.590 1.286 1.3941.363 1.421 1.268 1.812 1.370 1.293 1.322 1.253 1.555 1.459 1.756 1.995 1.5441

1.2031.685 1

1.443 1.840 1

2. 16911

RS

61465e13423235451635356964912163754344

114

1D 1= = 1.8*. 1 1. 1*.3 1.71.6 1.6 1.4*./•#.3 1.5*. 4 1.3 1.3 1. 1 1.81.8 1.7*. 0 1.41.41. 71.71.71.5*.21.2 1.71.e#. 0*

.8*

. 0

. 1

.6

.6

. 0

1/87 Rev.

38

6AVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Naa«:.Lab Cod«:

In»truB«nt 10:

Contract:,SAS No. :Ca>« No.:

p Calibration Dat«(s):SZX« No. :

Matrix: (»oil/watar) s*>>i~ Level: (iow/m«d) Le><^ Column: (pacJc/cap)Min RR? for SPCC(I) • 0.300 (0.250 for Broaofon) Max tRSO for CCC(*) »LAB FILE ID:RRF100- >

RRT20 •RRT130-"

RRF50 •RW200-"

COMPOUKD

Tetrahydrofuran.

2-Dichloro«than«-d4

RRF20•mmmm*.n i

RRT50 IRRT100IRRT150

FORM vt VGA'

RRT200mm^mm. <5-5t

RRF"?W

RSS

6 . ;

1/87 Rev.

39

TOTAL ION CHROrtPTOGROflFile >D1137 35.6-260.e amu. VSTD20

zee

70006-

60886-

50C00-

48888-

38006-

aeeee-

10000-

GlC7e337VS,O.V7e337, Si

16 20 84 ' 26' ' 38 ' "36 '

Data File: >D1137::SS Quant Output File: ~D1137::AQName: USTD20Misc: QC70337US,QU70337;S:M4,5,, 2UL CAL I * I I+XUOA



40

QUANT REPORT Page

Operator ID: EK1710Output File: ~D1137::AQData File: >D1137::SSName: VSTD20Misc: QC70337US,QU70337,S:M4,5,,

ID File: ID0259::UlTitle: XUOA13, IFB, PP/YOALast Calibration: 900830 08:26

Compound

Quant Rev: 7 Quant Time:In jected at:

Di lu t i on Factor ',

900831 20:53900831 20:10

1.00000

2UL CAL I+II+XUOA

R.T. Scan* Area Cone Uni ts

1)2)3)5)6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)22)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)42)43)44)

•Bromoch loro me thaneMe t hy 1 ch 1 or ideMethyl bromideVinyl ch lor ideCh loroethaneMethylene chlorideAero 1 e inAcetoneAery Ion i t r i leCarbon disulfideTrichlorof luorome thane1,1-Dichloroethylene1,1-DichloroethaneTetrahydrofuran1 ,2-Trans-dichloroethyleneCh lorof orml,2-Dichloroethane-D4 (SURR)1,2-Dich loroethane

*1 ,4-Dif luorobenzene1,1,1-TrichloroethaneCarbon t e t rach lor ideCarbon tet rach lor ideUinyl acetateDich 1 o rob romome thane1 ,2-Dichloropropanec is-1 ,3-DichloropropyleneTrichloroethyleneCh lorod ib romome thanebisCChloro methyl )etherBenzene1,1, 2- Trich loroethanetrans-l,3-Dichloropropylene2-Ch loroethyl vinyl etherBromof orm»Chlorobenzene-d5Me t hy 1- iso-bu ty 1 ketone2-Hexanone1 , 1 ,2 ,2-Tet rach loroethaneTet rach loroethyleneToluene-08 (SURR)To lueneCh lorobenzeneEthylbenzene

11234588899101112121313141422151516161618181919191919192022272224242425262729

.54

.24

.40

.29

.57

.01

.83

.83

.64

.72

.34

.08

.43

.51

.21

.83

.49

.57

.20

.92

.92

.31

.47

.85

.25

.52

.10

.72

.72

.61

.84

.84

.92

.48

. 18

.94

.49

.76

.80

.93

.13

.29

.58

264245477110173194194215217233252287289307323340342539377377387391401437444459475475472478478506546667558598605606635640670729

3931255754903109467703

207012643855805447

5393239953175893658626871928642190823403406916318751468647343431260414027320222266672573828729925558592198192507928351885212370018937157342513229076179857406265284828172

2504228434866

25672392971284981

258761732056625010114966992777185882407287642010125089827570

228427521

.00

. 14

.62

.64

.58

.18

.92

.49

.33

.34

.54

. 15

.79

.06

.30

.93

.21

.22

.00

.15

.34

.19

.60

.89

.73

.72

.91

.90

.23

.43

.93

.46

.13

.87

. 00

.69

.49

.05

.53

.66

.90

.64

.60

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

97979999969994949999999797100989894959895969897959595949810095929410097849491989896999779

41

QUANT REPORT Page 2

Operator ID: EK1710 Quant Rev: 7 Quant Time: 900831 20:53Output File: ~D1137::AQ Injected at: 900831 20:10Data File: >D1137::SS Dilution Factor: 1.00000Name: USTD20Misc: QC70337US,QU70337,S:M4,5,, 2UL CAL I + I I+XUOA

ID File: ID0259::U1Title: XUOA13, IFB, PP/UOALast Calibration: 900830 08:26


45)46)47)48)

p-Bromofluorobenzene (SURR)St yrenem-Xy leneo+p-Xy lenes

32.34.34.36.

64478610

808855865897

104759627063536371774

207.61.28.29.

42190381

NGNGNGNG

92959790

* Compound is ISTD

42

TOTBL ION CHROMPTOSRPMfile >D1133 35.e-266.e MU.

eeeeen

70000-

60006-

50000-

40000-

seeee-1

80000-

10000-

QC7e337VS,QV7e337,Sl

6B0 , B00 ,

i • i • i • i • i * i • i • i • i • i • i • i * i • i • i • j • i • i6 IS 16 80 84 28 38 36 40

Quant Output File: ~D1133::AQData File: >D1133::UOName: USTD50Misc: QC70337US,QU70337,S:M4,5,, 5UL CAL I+II+XVOA



43

QUANT REPORT Page

Operator ID: EK1710Output File: ">D1133::AQData File: >D1133::UOName: YSTD50Misc: QC70337US,QU70337,S:M4,5, ,

ID File: ID0259::U1Ti t l e : XUOA13, IFB, PP/UOALast Calibration: 900830 08:26

Compound

Quant Rev: 7 Quant TimeIn ject ed a t

Di lut ion Fac tor

900831 16:43900831 16:00

1.00000

5UL CAL I+II+XUOA


1 )2)3)4)5)6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)21)?2)23)23)24)25)26)27)28)29)30)31 )32)33)34)35)36)37)38)39)40)41)42)

*BromochloromethaneMe t hy 1 ch 1 o r i deMe t hy 1 bromi deDichlorodifluoromethaneUi ny 1 ch 1 or i deCh 1 oroe thaneMethylene chlorideAc ro 1 e inAcetoneAc ry 1 on i t r i leCarbon d isu 1 f ideTr ichlorof luoro me thane1,1-Dichloroethylene1,1-DichloroethaneTe t rahydrof uran1,2-Trans-dichloroethyleneCh 1 orof orml,2-Dic'hloroethane-D4 (SURR)1,2-Dichl oroe thane

*1 ,4-Di f luorobenzeneMethyl ethyl ketone1,1,1-TrichloroethaneCarbon t e t rach lor i deCarbon t et rach lor ideU i ny 1 acetateDichlorobromo me thane1,2-Dichloropropanecis-1 ,3-DichloropropyleneTrichloroethyleneChlorodibromomethanebis(Chloromethyl )etherBenzene1,1,2-Trichloroethanetrans-l,3-Dichloropropylene2-Ch 1 oroe thy 1 vi nyl etherBr omo f o rm*Ch Iorobenzene-d5Me t hy 1 - i so-bu t y 1 ketone2-Hexanone1 , 1 ,2 ,2-Tet rach loroethaneTe t rach lo roe thyleneToluene-08 (SURR)To 1 uene

11.2.3.4.4.5.8.8.8.9.9.

10.11.12.12.13.13.14.14.22.14.15.15.16.16.16.18.18.19.19.19.19.19.19.20.22.27.22.24.24.24.25.26.

60263820315900818958703210455727855163235998983753913158167875679090955021965283839516

26625547578

111173194196214217233253288291309324341344540343379379389393403439446461477476474480480507547668559599607607636641

40389168751484016121133049224255105377160143721385815398010982845166923946543

5111910580183298792631717903303

1282431556911372377259988794910265985630186678422207142152449436087824978438741287464085732747578307236818035197431

250.124.84.9.

128.137.158.

7294.58.

228.270.343.122.201.

6131.158.180.202.149.250.25.

239.32.

239.196.216.179.168.199.196.547.166.189.148.168.225.250.185.164.TL65.-&68 .220.98.

00153348256587718965509385056616450696004941752514652957803155934163512200929593663085


959397

979599939491999597971009798949696929697999797999694981009689931009788979495989596

44

QUANT REPORT

Operator ID: EK1710Output File: ~D1133:: AQData FiIB: >D1133::UOName: USTD50Misc: QC70337US,QU70337,S:M4,5,,

Quant Rev: 7 Quant TimeIn jected a t:

Di lut ion Fact or'

Page 2

900831 16:43900831 16:00

1. 00000

5UL CAL I + I I+XUOA



43)44)45)46)47)48)

ChlorobenzeneEthy Ibenzenep-Bromof luorobenzene (SURR)St yrenem-Xy leneo +p-Xy lenes

272932343436

.33

.62

.72

.54

.86

.14

671730810857865898

1298267158310769915494087894179104

178.52.

204.145.66.71.

537489279448

NGNGNGNGNGNG

927988969790

Compound is ISTD

45

TOTAL ION CHROMRTOBRPnFile >D1136 35.0-260.0 anu. VSTD100

800 400

QC70337VS,QV70337,S i

3eee

88 38 36 404 8 18 16 80 84

Data File: >D1136::SS Quant Output File: /SD1136::AQName: USTDIOOMisc: QC70337US,Q«J70337,S:M4,5,, 10UL CAL I + IJ+XUOA

Id File: ID0259::UlTitle: XUOA13, IFB, PP/UOALast Calibration: 900830 08:26


46

QUANT REPORT Page

Operator ID: EK1710Output File: ~D1136::AQData File: >D1136::SSName: USTD100Misc: QC70337US,QU70337,S:M4,5,,


Compound


Dilution Factor:

900831 20:02900831 19:19

1.00000

10UL CAL I+II+XUOA


1)2)3)5)6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)32)33)35)36)37)38)39)40)41)42)43)44)

•Bromoch loro me thaneMethyl ch lor ideMethyl bromideUiny 1 ch lor i deCh 1 oroe thaneMethylene chlorideAero le inAcetoneAery 1 on i t r i leCarbon disulf ideTrichlorofluoro me thane1,1-Dichloroethylene1,1-DichloroethaneTe t rahydrof uran1,2-Trans-dichloroethyleneCh lorof orml,2-Dichloroethane-D4 (SURR)1,2-Dichl oroe thane

*l,4-DifluorobenzeneMethyl ethyl ketone1,1,1-TrichloroethaneCarbon tet rach lor ideCarbon tet rach lor ideUinyl acetateDichlorobromomethane1,2-Dichloropropanecis-l,3-DichloropropyleneTrichloroethyleneCh lorodibromomethanebis (Ch loro methyl )etherBenzene1,1,2-Trichloroethanetrans-l,3-DichloropropyleneBromof orm*Ch Iorobenzene-d5Methyl- iso-butyl ketone2-Hexanone1, 1, 2, 2- Tet rach lor oe thaneTet rachloroethyleneToluene-08 CSURR)To lueneChlorobenzeneEthy Ibenzene

11234588899101112121313141422141515161616IB1819191919191922272224242425262729

.58

.24

.40

.29

.61

.01

.79

.87

.60

.72

.34

.11

.47

.55

.25

.83

.49

.61

.21

.53

.96

.92

.35

.51

.89

.29

.56

.10

.76

.73

.65

.84

.84

.48

.18

.94

.50

.77

.81

.93

.13

.34

.62

265245477111173193195214217233253288290308323340343539341378377388392402438445459476475473478478546667558598605606635640671730

4038928830246105910239919882981521912552127408277073203446864891750271447296382203524888221638731709966573

247747300162253061295322067279888413627912291015235147851273090954901304111099561294148473163787122374141611188284191167253318138668

250212139229245274

14388104452486637235380

1356229834721531025050464634763304553623493914491185322404319567250383319349328228192346101

.00

.10

.85

.35

.04

.76

.13

.57

.22

.73

.10

.24

.86

.19

.19

.13

.46

.04

.00

.96

.65

.44

.20

.37

.06

.74

.76

.51

.92

.33

.19

.32

.87

.05

.00

.58

.65

.31

.34

.81

.95

.56

.65


9697979997969295959997949710098979398978996979996979696939610096909496869692979794969580

47

QUANT REPORT

Operator ID: EK1710Output File: ~D1136::AQData File: >D1136::S3Name: USTD100Misc:


Di lut ion Factor;USTD100QC70337US,QU70337,S:M4,5,, 10UL CAL I+II+XVOA

Page 2

900831 20:02900831 19:19

1.00000

ID File: ID0259::UlTitle: XUOA13, IFB, PP/UOALast Calibration: 900830 08:26


45)46)47)48)

p-Bromof luorobenzene (SURR)St yrenem-Xy 1 eneo+p-Xy 1 enes

32.34.34.36.

69478207

809855864896

110473312474171450349503

209291129138

.08

.46

.90

.77

NGNGNGNG

91949691

* Compound is ISTD

48

TOTAL ION CHROHflT06RPttFile >D1135 35.8-260.0 amu. U.C70337VS ,O.V7e337 ,S

1000

Quant Output File: ~D1135:: AQData File: >D1135::SSName: USTD150Misc: QC70337US,QU70337,S:M4,5,, 15UL CAL I+II+XUOA

Id File: ID0259::U1Title: XUOA13, IFB, PP/UOALast Calibration: 900B30 08:26


49

QUANT REPORT Page

Operator ID: EK1710Output File: ~D1135:: AQData File: >D1135::SSName: USTD150disc: QC70337US,QU70337,S:M4,5,,


Compound

Quant Rev: 7 Quant Time:In jected at :

Di lut ion Fac tori

900831 19:11900831 18:28

1.00000

15UL CAL I+I1+XUOA


1)2)3)4)5)6.X7)8)9)10)11)12)13)14)15)16)17)IB)19)20)°1 ),2)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)36)39)40)41)42)

*BromochloromethaneMe t hy 1 ch lor i deMethyl bromideDich lorod i f luoro me thaneUiny 1 ch lor ideO?i l.Q*1? Q>t*i.*riVPi'fcMethylene chlorideAero 1 e i nAcetoneAc ry Ion i t r i leCarbon disulfideTrichlorofluorome thane1,1-Dichloroethylene1,1-DichloroethaneTetrahydrofuran1,2-Trans-dichloroethyleneCh lorof orml,2-Dichloroethane-D4 (SURR)1,2-Dich lor oe thane

*l,4-DifluorobenzeneMethyl ethyl ketone1,1,1-TrichloroethaneCarbon tet rach lor ideCarbon tet rach lor ideUinyl acetateDich lo rob romome thane1 ,2-Dich loropropanec is-1 ,3-Dich loropropyleneTrichloroethyleneCh lorodibromomethaneb is ( Ch 1 orome thy 1 )e t herBenzene1 ,1 ,2-Tr ichloroethanetrans-1 ,3-Dich loropropylene2-Ch loroe t hy 1 viny 1 etherBromof orm*Ch Iorobenzene-d5Me t hy 1 - iso-bu t y 1 ketone2-Hexanone1,1,2,2-TetrachloroethaneTet rach loroethyleneToluene-08 (SURR)To luene

11.582.243.404.174.29"5 ."*y~/8.058.838.879.569.72

10.3411.1212.4712.5113.2513.8714.4914.6122.2514.5315.9615.9616.3516.5116.8918.2918.5619.1419.7619.7619.6519.8819.8820.9722.5227.2222.9824.5424.8124.8525.9826.17

26524547477

lit)174194195213217 '233253288289308324340343540341378378388392402438445460476476473479479507547668559599606607636641

406674511533290421092910614191380142282833395342182454569315745131237269420210171476123101379186124652717949810425

38450346723354730234615319821151804215783188997233780743434198161418762051998420717183813425012487598636184649219477194798298951

250.00 NG329.63 NG187.88 NG24.59 NG

358. 08 NG374.43 NG426.53 NG

21434.34 NG138. 16 NG691.22 NG793.08 NG982.00 NG354.51 NG582.25 NG

19561.08 NG453.57 NG525.35 NG221.31 NG463.22 NG250.00 NG77.00 NG686.98 NG94.07 NG714.23 NG570.04 NG670.67 NG530.49 NG527.58 NG573.50 NG657.69 NG1754.35 NG471.84 NG572.27 NG479.47 NG543.70 NG844.21 NG250.00 NG544.94 NG.476.47 NG~_508.08 NG90.55 NG~^2B.19 NG290.86 NG

96939893979799929993999395961009997969897959697999899959694951009790941009885969496979297

50

QUANT REPORT

Operator ID: EK1710Output File: ~D1135::AQData File: >D1135::SSName: USTD150disc: QC70337US,QU70337,S:I14,5, ,


Compound


Dilut ion Factor:

Page 2

900831 19:11900831 18:28

1.00000

15UL CAL I+II+XUOA


43)44)45)46)47)46)

Ch lorobenzeneEthyl benzenep-Bromof luorobenzene (SURR)Styrenem-Xy leneo+p-Xy lenes

272932343436

.38

.66

.73

.51

.94

.11

672731810856867897

39403121B107113077484450266464548513

519.154.206.435.194.209.

641230596294

NGNGNGNGNGNG

958089939790

Compound is ISTD

51

TOTRL ION CHROMPT08RPMFile >D1134 35.0-260.0 sum. VSTP200

800 400

aC7fl337VS , QV70337 , S i

e0e ,

48

IS 16 80 84 88 38 36 40

Data File: >D1134::SS Quant Output File: ~D1134::AQName: USTD200Misc: QC70337«JS,QU70337,S:M4,5, , 20UL CAL 1 + II+XUOA

Id F i Je : I D 0 2 5 9 : : U 1Title: XUOA13, IFB, PP/UOALast Calibration: 900B30 08:26


52

QUANT REPORT Page

Operator ID: EK1710Output File: "D1134::AQData File: >D1134::SSName: USTD200Misc: QC70337US,QU70337,S:M4,5,,

ID File: ID0259::U1Title: XUOA13, IFB, PP/VOALast Calibration: 900830 08:26

Compound

Quant Re<*>: 7 Quan t Time:In jec ted at

Di1ut ion Factor:

900831 18:20900831 17:38

1.00000

20UL CAL I+II+XUOA

R.T. Scan* Area Cone Un i ts

1)2)3 )4)5)6)7)8)9)10)11)12)13)14)15)15)16)17)18)19)20)>1 )-2)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)

"BromochloromethaneMethyl chlorideMe t hy 1 brom i deDi-chlorodifl uorome thaneUi ny 1 ch 1 o r ideCh loroe t haneMethylene chlorideAero le i nAcetoneAery 1 on i t r i leCarbon disulfideTr ich lorof luoromethane1,1-Dichloroethylene1,1-DichloroethaneTet rahydrof uranTet rahydrofuran1 ,2-Trans-dichloroethyleneCh lorof orml,2-Dichloroethane-D4 (SLJRR)1,2-Dichloroethane

*l,4-DifluorobenzeneMethyl ethyl ketone1,1,1-TrichloroetheneCarbon t et rach lor i deCarbon t e t rach 1 or ideUi ny 1 acetateDichlorobromomethane1,2-Dichloropropanec is- 1,3-Dich loropropyleneTrichloroethyleneChlorodibromome thanebisCChloromethyl )etherBenzene1,1,2-Trichloroethanet rans-1 , 3-D ich loropropylene2-Ch 1 oroe t hy 1 vi ny 1 etherBromof orm

*Ch Iorobenzene-d5Me t hy 1- i so-bu t y 1 ketone2-Hexanone1,1,2,2-TetrachloroethaneTet rach loroethyleneToluene-D8 CSURR)

11.2.3.4.4.5.8.6.8.9.9.10.11.12.12.13.13.13.14.14.22,14.15.15.16.16.16.18.18.19.19.19.19.19.19.20.22.27.22.24.24.24.26.

64305028396712899763744014505823278955672759999942539235591779796791919955259752838701

26726577780113176196198215218235254289291308309325342345541343379379390393403440446461477477474480480508548669559599607608637

4098560820421466174

119839816271803452900764318150446600734416550174809349501248943702

1974144021459148430660317911212463489865581284632722992854022861892532725072458822823939155754154216642224880197032201236129084141331105153211235276545187418

25044023635458493553

27024174820

10391285468749

22989341860167521857125092877117934728845662667747796

2165609672582627990250641-52804

-*42228

.00

.94

.01

.78

.28

.77

.03

.99

.35

.22

.96

.47

.55

.46

.73

.82

.89

.92

.69

.64

.00

.25

.11

.29

.78

.74

.42

.78

.71

.72

.17

.22

.96

.72

.61

.86

.77

.00

.44

.28

.49

.84

.34


959698969794969294979895969710010097989898969096999896999795939910097899310098839693979994

53

QUANT REPORT

Operator ID: EK1710Output File: ~D1134:: AQData File: >D1134::SSName: USTD200Misc: QC70337US,QU70337,S:M4,5,,

ID File: ID0259::U1Title: XUOA13, IFB, PP/UQALast Calibration: 900830 08:26

Compound

Quant Rev: 7 Quant Time'Injected at:

Dilution Factor:

Page 2

900831 18:20900831 17:38

1.00000

20UL CAL I+II+XUOA

R.T. Scan# Area Cone Uni ts

42)43)44)45)46)47)48)

To 1 ueneCh 1 orobenzeneEthylbenzenep-Bromo f 1 uorobenzene (SURR)St yrenem-Xy 1 eneo+p-Xy 1 enes

26.27.29.32.34.34.36.

16366576589721

641672731811858868900

373158484885265874105635585U15325561669319

377.665.195.200.547.247.266.

59053943073043

NGNGNGNGNGNGNG

97958090959791

* Compound is ISTD

54

7AUOLATILE CONTINUING CALIBRATION CHECK

Lab Name:ETCNJ I Laboratory Contract:


Instrument ID:GC/MS D Calibration Date: 09/01/90

SDG. No,

Time: 2107

Lab File ID: >D1147 I n i t Ca1ib. Dates(s): OB/31/90 OB/31/90

Hatrix: (soiI/water) SOIL Leve1: ( 1 ow/med) LOW Co 1umn: (pack/cap) PACK

Mm RRF50 for SPCC(#) - 0.300 (0.250 for Bromoform) Max SRSD for CCCC*) = 25.OS

11 COMPOUND

1 1KRF 1

1 Ch 1 orome thane # .37411 Bromome thane 1 .3031lUmul Chloride * .74811 Ch 1 oroe t haneIMetnulene Chloride1 Ace t one1 Carbon Disu 1 f ide

1 .50811. 181 1

1 .31413.613 1

1 1 . 1-Dichloroethene * 1.09011 1 ,1-Dichloroethane # 2.22411 1 ,2-Dichlorethene (total) __ 1 1.2201IChloroform * 2.56311 1 ,2-DichloroethaneI 2-Bu t anone1 1 ,1 ,1-TrichloroethaneICarbon Te t rach lor idelUmvl Acetate1 Bromod i chl orome t hane1 1 . 2-Di ch 1 oropropane *lcis-1,, 3-Dichl oropropene ___1 Tr ich loroetheneIDibromochloromethane11 rl .2-Trichloroethane1 Benzene1 trans-l,3-Dich 1 oropropene __IBromoform . =!4-Methvl-2-Pentanone1 2-Hexanone1 Tet rach loroethene

2. 0101. 019 1.731 1.658 1.416 1.590 1.286 1.3941.363 1.421 1.268 !.8121.370 1

I .2931.3221.2531.5551

1 1, 1,2,2- Tetrachlo roe thane _ # . 459 1IToluene * .75611 Ch lorobenzene * .9951lEthvlbenzene * .544'!1 St vrene1 Xvlene (total )

1 To 1 uene-dBIBromofluorobenzene1 1 ,2-Di chl oroe thane-d41

1.203 1.685 1

1.443 i.840 1

2. 169 11

1RRF50 1

.362 1

.3341

.722 1

.50711. 085 1.3271

3.413 11. 061 12. 190 11. 15712.48011.9851.0^01.6921.599 1.448 !.5551.281 1.3801.351 1.3H5 1.269 1.795 1.357!.2541.3321.266 1.5371. 464 1. 744 1.982 1.539 1

1. 182 1.660 1

1.459 1.849 1

2. 109 11

XD= = « = =3. H10.43.4*. 1

8. 14.45.52.6*1.5}5.23.2*1.24.25.49. 07.66. 11.6*3.63.38.4.5

2.03.4

13.5}2.94.83.3.9

1.7*1.2fl.9*

1.73.7

1.21:. 12

-i

FORM UII UOA 1/87

Lab Naa«:.Lab Cod«:

7AVOLATILE CONTINUING CALIBRATION CHECK

_ Contract:_____ SAS NO.:Case No.:

Instrun«nt ID:

Lab Fil« ID:

CalibrationSDG No.:

Tia«: =

it. Calib. Dat«(«);

Matrix: (»oil/wat«r) S ? L«v«l: (low/««d) c u.- Coluan: (pack/ cap)Min RRT50 for SPCC(I) • 0.300 (0.250 for Broaofon) Max ID for CCC(*j 2 5 . C \

CORPOUND

; Tetrahydrofuran.

I 55?•I 1

I

._

f:

J.I"*

l,2-Dichloro^thana^dT

rom vii VGA

ID

.1*

1/87 Re-.

56

TOTAL ION CHROMOT06RPM

48808-

30888-

20080-

ieee&-

File >D1147 35.0-260.0 *mu. VSTD5B

80000-

70000

60000

QC78337VS,QV703377sI

T I 1 ) I * I I ' I • I I • i • I " ) " I r I I8 IS 16 26 24 ZB 32 36 40

Quant Output File: "D1147::AQData File: >D1147::U1Name: USTD50flisc: QC70337US,QU70337,S:M4,5, , 5UL CAL I + II+XUOA

Id File: ID0259::UlTitle: XUOA13, IFB, PP/UOALast Calibration: 900901 17:25

Operator ID: MGRMSQuant Time: 900901 21:50Injected at: 900901 21:07

57

Operator ID: MGRMSOutput File: ~D1147::AQData File: >D1147::U1Name: USTD50Misc: QC70337US,QU70337,S:M4,5,,

ID File: ID0259::U1T i t l e : XVOA13, IFB, PP/UOALast Calibration: 900901 17:25

QUANT REPORT

Quant Rev: 7 Quant TimeInjected at

D i l u t i o n Factor:

Page 1

900901 21:50900901 21:07

1. 000005UL CAL I+II+XUOA

12;3;5)6)7)6)9)10)11)12)13)14)15)16)17)18)19)0)

21)22)23)23)24)25)26)27)26)29)30)31)32)33)34)35)36 ) «37)38)39)40)*,\\42)43)

Compound

) *Bromoch loromethane1 Methyl chloride1 Methyl bromide

Uinyl chlorideCh loroethaneMethylene chlorideAero le inAcetoneAcrylon i t r i leCarbon disulfideTnchlorof luoromethane1,1-Dichloroethylene1,1-Dich loroethaneTet rahydrof uran1,2-Trans-dichloroethyleneChloroforml,2-Dichloroethane-D4 (SURRi1 O r» • L * ^ OLJfTK J1,2-Dichloroethane

*l,4-Dif luorobenzeneMethyl ethyl ketone1,1,1-Trich loroethaneCarbon t e t rach 1 o r i deCarbon t e t rach 1 o r i deYinyl acetateDichlorobromome thane1,2-Dichloropropanecis-1 3-Dichloropropylene1 nchloroethyleneChlorodibromome thanebisCChloromethyl )etherBenzene1 ,1,2-Tr ichloroethanetrans-l,3-D,chloropropylene2-Chloroethylwnyl etherBromo formChlorobenzene-d5Methyl- l s o_ b u t y l ketone^-nexanone1, 1, 2, 2-Tet rach loroethanelet rachloroethylene""J-fYuene-TJB (SURR)To 1 ueneCh 1 orobenzene

R.T.

11.622 O s. 243.364.295.578 nc. Up8.798.839.609.76

10.3811.1512.5112.5513.2913.8714.5314.6422.2514.5716.0016.0016.4316.5416.9318.3318.6019.1419.8019.7619.6919.8819.8820.9722.5227.2222.9824.5324.812A.<3A25.9726.1327.37

Scan*

266245377110174193194214218234254289290309324341344540342379379390393403439446460477476474479479507547668559599606-bTT?636640672

Area

451981638215110326402293249062859751479615021

154259110960479589900379015227211210495316897381944093807

134581162331164458704310780854718739486826274873240751546505234569428306134928614357347629381506659477UB:?209496106780141019

Cone Uni

250.00 NG-242.27 NG276.04 NG241.45 NG249.63 NG999 "?o kir-*-£-T . sy (sik4173.13 NG260.91 NG395.11 NG236.19 NG237.75 NG243.38 NG246.20 NG261.33 NG237.01 NGOX1 QQ i.|f^ *+ 1. . oy Nla243.02 NG246.98 NG250.00 NG260.45 NG236.61 NG31.71 NG227.47 NG268.96 NG234.78 NG245.89 NG241.08 NG241.86 NG228.96 NG228.71 NG244.97 NG251.13 NG241.53 NG408. 17 NG216.21 NG250. 00 NG7.37 NG

2fc2.08 NG252.36 NG241.63 NGOCO QQ klf^£7^ . OO Nb

245.85 NG58246.91 NG

ts q

Q r-77

9299gof DO<is O

9895959099989598100999996969887979699979693959494

100959295

100978496919<tT 96979795

QUANT REPORT

Operator ID: MGRMSOutput File: 01147:. 'AQData Fi le: >D1147: :U1Name: USTD50Misc: QC70337US,QU70337,S:ri4,5,

ID Fi le: ID0259: : UlTit l e : XUOA13, IFB, PP/UOALast Calibration: 900901 17:25

Quant Rev: 7 Quant TimeInjected a t i

Di lut i on Factor

Page 2

900901 21:50900901, 21:07

1.00000

5UL CAL I+II+XUOA


44;45)46;47;48;

Ethylbenzene 29.66 731 77353 247.82 NGp-Bromofluorobenzene (SURR) 32.73 810 121844 252.72 NGStyrene 34.55 857 169775 245.79 NGm-Xylene 34.94 867 94391 245.17 NGo+p-Xylenes 36.22 900 189412 481.47 NG

Compound is ISTD

8090959691

59

8AUOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: ETCNJ Contract:


Lab File ID (Standard): >D1133 Data Analyzed: Q8/31/9U

Instrument ID: GC/MS D Time Analyzed: 160U

Hatr ix : (soiI/water) SOIL Leve1:(1ow/med) LOW Co 1umn: (pack/cap ) ____

01020304050607OB0910111213141516171819202122

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

..*»»...»UBLK01A4376A4377A4377MSA4377MSD

IS1CBCMJAREA #

40389

80778...«.es.»

20194

4022338756386523872239137

RT

11.60

11.5711.6211.6111.6711.66

IS2(DFB)AREA #

171790

343580

85895

166162159608163S01160645163573

RT

22.23

22.2322.2022.2422.2622.20

I S3 ( CBZ )AREA #

128746

257492

64373

126268117999121448119629120366

RT

27.21

27.2127.2127.2127.2327. 17

Bromoch lorome thane1,4-Dif luorobenzeneChlorobenzene-d5

151 CBCM)152 (DFB)153 (CB2)

# Column used to fla_q, i-oAt,1; •?.

page __ of __—— ——

UPPER LIMIT - + 1UOMof internal standard area.LOWER LIMIT - - 50%of internal standard area.

area va'lues with an asterisk

FORM Oil I UOA 1/87

60

8AUOLATILE INTERNAL STANDARD AREA SUMMARY



Lab F i l e ID (Standard): >D1147 Data Analyzed: 09/01/91)

Instrument ID: GC/MS D Time Analyzed: 2107

Mat r i x : (so i 1 /wa t er ) SOIL Leve1:(1ow/med) LGU) Co 1 umn :( pack/cap ) ____

01020304050607080910111213141516171819202122

12 HOUR STD

UPPER LIMIT

LOUER LIMIT

EPA SAMPLENO.

UBLK02A4377

ISKBCM)ARE.A #

45198

90396

22599

4103941796

RT

11.62

11.6211.62

IS2CDFB)AREA #

194409

388818

97205

173451170952

RT

22.25

22.2422.24

IS3(CBZ)AREA #

143573

287146

71786

==========130884127870

RT

27.22

27.2127.21

151 (8CM) = Bromochloromethane152 (DFB) = 1,4-Difluorobenzene153 (CBZ) = ChIorobenzene-d5

UPPER LIMIT - + 100%of internal standard area.LOWER LIMIT = - bO*of internal standard area.

# Column used to flag internal standard area values with an asterisk,

page __ of __

FORM U I I 1 UOA 1/87 Rev.

61

ETC

RAW QC DATA

62

MS Data File: >D1132::UO

Name: .................... Operator: EK1710Misc: p-BFB

Date/Time: 8/31/90 15:31

File >D1Bpk Ob 4

4800--

4400^

4000^

360EK

3200:

880fr-

-_

-1600^

-1200^

J800-«i

132363

50

\ ,,

1 68 -

N|ii 1.1

I * " 1 * '

40

c

'5

1

1.1 ll 180

p-BFB

>5t

174

133 147

I ' ' ' 1 ' ' ' 1 ' ' ' 1 " '

1S0 160

Sc»n10.51

X ,! V8,300

189nin .

rl!0

-100

•90

80

-76

-60

•50

40

30

20

f-10

63


Date/Time: 8/31/90 15:31Mi sc : p-BFB

>D1132189 NRM

Fi le: >D1132 Scan #:

m/z

37.1038. 0539. 0541. 0543. 0544. 0545. 0549.0550.0551. 0555. 0556. 0557. 05

I

54224855195237

nt .

.868

.492

.590

.957

.882

.870

.134

.088

.551

.776

.452

.461

. 105

m/z

58.0559. 0559.9561.0562.0563.0567.0568. 0569.0570. 0571. 0573.0574. 05

189

Int .

3.3231.6271.2385.7305.7533.5981. 031

11.82712.7891.9711.74214.37119.299

p-BFB

Re t n . t ime :

m/z

75.0576.0578.9579.9580.9581.9587.0588.0592.0593.0594.0595.0596. 05

Int .

57.2084.6764. 1711.3524.6761. 1923.2785.6153.0484.60711. 116

100. 0007.816

10.51

m/z

97.05102.95105.05105.95117. 00119. 00133.00141.00143. 00147.00149. 00155.00

Int .

.8021. 1461.008.871

1.3291.9251.8341.2611. 0542.292.711.825

m/z

173.175.176.177.179.190.192.194.207.208.209.222.

900000000095950505050595

Int .

90.6266.41888. 1966.395.802

1.8573.896.665

8.5722.1091.4443.392

64


Name: .................... Operator: EK1710flisc: p-BFB

Date /T ime: B/31/90 15:31

File >D113£TIC

p-BFB

40 80 120 160 200 240 880i i , i • i . , , i , . . i . i , i . • i i i . . i • . . i. i • i . . . i . . . i . . i i i i • i i . . i .-100

:90

-80

-70

-68

-30

-40

-30

-20

4.0 5.0 6.6 7.0 8.8 9.6 16.611.612.613.014.015.6

65

:ARINI

MS Data File: >D1145::Ul

Name: .................... Operator: MGRMSMisc: p-BFB

Date/Time: 9/01/90 19:52

File >D1145 p-BFBBpk Ob 5004

5200-

4800-

4400-

4000-

3600-

3200-

£800-

2400-

2000-

1600-

1800-

800-

400-

75

50

)5f 174

\

1 68

• I f I I 133 147

IlilJI JJl IJlLMlJ ./ . ,/„ S .

177X

40 ' 80 ' 180 ' 160

Sc*n 19316.56 min.

-110

807\ 80 6

K 1' ' ! • ' ' • • I1"

-i0e

-96

'-ez

-70

-60

-50

r40

38

-80

-10

800

66

MS Data File: >D1145::Ul

Date/Time: 9/01x90 19:52h i sc : p

>D1145193

File: >

m/z

37. 1038. 0538.9539.9541. 0543. 0544. 0545. 0546.9549. 0550. 0551. 05

-BFB

NRH

D1145 Scan #:

Irvt .

5.6554.9962.6981.7192.8384.4769. 0735.456.779

4.45620. 1045.975

m/z

55.0556. 0557. 0558.0559.0559.9561. 0562.0563.0568.0569.0570. 05

—r~

193

Int .

2.2.6.2.1.1.5.4.3.11.12.1.

398658675678319159556996857651450239

p-BFB

Re tr» . t ime :

m/z

73. 0574. 0575. 0576.0576.9578.9579.9580.9585. 0587. 0588. 0591.05

Int .

12.95017.36656.0154.796.979

3.5971. 1593.9771. 0393.3575.256.879

10.56

m/z

92. 0593. 0594. 0595. 0596. 05114.90117. 00119. 00127.90133. 00135.00140.90

Int.

3.4.

15 .100.7.,

1.1..

1.,

1.

217217671000294620119399819559779399

m/z

142.90147.00162.90173.90175.00175.90176.90192.95194.85206.95208. 05222.95

Int .

1. 0191.799.560

94. 1056.89491.6676.7353.857.600

5.4161.2993.477

67

MS Data F i l e : >D1145: :U1

M i s c : p-BFB

Film >D1145 35.6-866.6 *nu. p-BFB

46000^-

36066-

38000^

£8000^

84000-

20660-

16030^

12000-

6-

40 80 180 160 800 £40 880

11 i/

]/ 1

/ \

J V^vJ l^ __ Y4'.e c'.e 6 '.9 ?'.e e'.e $le le.e n'.e le'.e is'.e 14.0 is.

-166

-90

-86

-70

*e

-50

-46

-36

-26

0

68

1AUOLATILE ORGANJCS ANALYSIS DATA SHEET

ERA SAMPLE NO.

I IIUBLK01

Lab Name: ETCNJ



Con tract:

SAS No.:

Sample wt/vol: 5.0

Level: (low/med) LGUJ

% rioisture: not dec. 0


(g/mL) G

SDG No. :

Lab Sample ID: QC70337U

Lab File ID: >D1138os-/s>3/?0

Date Received: 09 'OBS**


D i l u t i o n Factor: 1

CAS NO. - COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

74-87-3---- — —— Chl orome thane______________I 1074-83-9---------Bromomethane_______________I 1075-01-4- ——————— Uinyl Chloride______________I 1075-00-3--- ———— -Chloroe thane_______________I 1075-09-2---------Methylene Chloride_________1467-64-l---------Acetone____________________I 1075-15-0---------Carbon Disulf ide___________I 575-35-4- — -- ——— 1,1-Dichloroethene_________1575-34-3- ——— --—1,1-Di chloroe thane_________15540-59-0--------l,2-Dichlorethene (total)__1567-66-3---------Ch lorof orm_________________I 5107-06-2--------l,2-Dich loroe thane_________I 578-93-3 — --- —— -2-Butanone_________________I 1071-55-6- ———— -—1,1,1-Tri ch loroe thane______1556-23-5- — - ———— Carbon Te t rach 1 o r i de_______15108-05-4——— — — Uinyl Acetate______________I 1075-27-4---------Bromodichloromet hane_______ I 578-87-5-- ——— ---1,2-Dichloropropane________1510061-01-5 ———— -cis-l,3-Dichloropropene____1579-01-6--- —— ---Trichloroethene____________15124-48-l--------Dibromoch 1 orome t hane_______ I 579-00-5 ——— -———1,1,2-Tr i ch 1 oroe t hane_______1571-43-2- ——— - —— Benzene____________________1210061-02-6------trans-l,3-Dichloropropene__1575-25-2---------Bromof orm__________________I 5108-10-1--------4-Me thy 1-2-Pent a none_______ I 10591-78-6 — - ———— 2-Hexanone_________________I 10127-18-4--------Tetrachloroethene___________1579-34-5------- —1,1,2,2-Tetrachloroethane__15108-88-3 ——— — — Toluene____________________12108-90-7--------Ch lorobenzene______________I 5100-41-4- —— ----Ethyl benzene_______________15100-42-5--------Styrene_____________________ I 51330-20-7——————Xylene (total )_____________15___________________________________________I

U

IUIUI LIIUI JIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIJIUIUIUIUIUIUIJIUIUIUIUI

FORri I UGA 1/87 Rev.

69


EPA SAXFLE NO.

Lab Nana;

Lab Coda: Casa No.:

Contract:,

SAS No.: SDG No. :

Matrix: (»oil/vatcr) .got u

Sainpla vt/vol : 5,0 (q/aL)

Laval: (low/B«d)

\ Moistur*: not d«c. O

Column: (pack/cap)

Lab Sanpl* ID:

Lab Fil« ID: >J> 1

Data R«ctiv«d: *9/

Data Anaiyzad:

CAS NO. COMPOUND

Dilution Factor:

CONCENTRATION UNITS:(ug/L or ug/Kg)

Tetrahydrofuran_

FORM I VOA

i

1/87 Rev.

70

IEVOLATILE ORGAN ICS ANALYSIS DATA SHEET


EPA SAMPLE NO.

IOBLK01Lab Name:ETCNJ I Laboratory

Lab Code: Case No.:


Sample wt/vol: 5.0 (g/mL) G

Level: Uow/med) LOW

?i Moisture: not dec. 0



Con tract:

SAb No.: SDG No.:

Lab Sample ID: QC70337U

Lab File ID: >D1138

Date Received: f&*4l-& HJ "/


D i l u t i o n Factor : 1. U

CONCENTRATION UNITS:(ug/L or ug/K'j ) UG/KG

CAS NUMBER

111

COMPOUND NAME

FORM I UOA-TIC

RT EST. CONC

.

—— > —————————-i1/87

7

Q

ke^.

1

TOTfiL ION CHROMflTOGRfiMPile >D1138 35.0-S60.8 amu. VBLK01 QC70337V ,QV70337,Sl

88000-

70000-

60000

50000-

30000--

20000-

10000-

0-

S00 f 400 i 600 ( 800 ( 1000

i ! *P* c S .j-. p1 I il !1 ic

7

5 I5 Qcr

4 8 IS

N

, 22 281J1

5 h

•r_^

40

1 11 1s

3

S.

4648

1 6 ' 2 0 24 ' 28 ' 32 ' 36 ' 40

Data File: >D1138::SSName: UBLK01Misc: QC70337U ;QU70337,S:M4,5,,

Id Fi le: ID0259: :U1T i t l e : XUOA13, IFB, PP/UOALast Calibration: 900901 17:25



BLANK

72

, QUANT REPORT

Opera tor ID:Output File:Data File:Name: UBLK01nisc: QC70337U

EK1710"-D1138:>D1138:

Quant Rev: 7:AQ:SS

Quant Time'In jec ted at

Dilution Factor.'

Page 1

900901 17:30900831 21:00

1.00000

,QV70337,S:ri4,5, , BLANK


Compound R.T. Scan* Area Cone Uni ts

1 )7)18)20)22)28)31)36)40)41)42)43)45)46)48)

*Bromoch loro me thaneMethylene chloride L/l,2-Dichloroethane-D4 (SURR)

*l,4-Difluorobenzene1-, 1 , 1- Ti nil lui ue Uitine

Benzene i/*Ch Iorobenzene-d5Tm t . - nh i TnrtJiy lege—Toluene-08 (SURR)To 1 uene \X

p-Bromo f 1 uorobenzene (SURR)

11814221519192724252627323436

.57

. 01

.48

.23

.91

. 09

.68

.21

.83

.96

.12

.32

.71

.57

.13

265173340540377459474668607636640671810858898

40223363581881166162240522255098

1262682075

18109234423398

10833432764181

250.. 19.234.250.4.9.9.

250.7.

248.9.6.

255.5.12.

0013590095224500405601764939

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

989593989590948596929882898791

* Compound is ISTD

73

REFERENCE STfiNDQRD SPCCTRUtlFile >C4697Bpk fib 9999

49. s

•

0-

47t

51

f48 5c

Tarset Reference Spectra Scan 143HRH NOn 6.59 fnin.

84 [-100-^ t

t56 60 64 6e 7£ 76 66 84

SfiMPLE SPECTRUM <BflCKGROUND SUBTRACTED)File >D1138 VBLK01 QC70337V ,QV70337 ,S :M4 ,5 , Scan 173Bpk Pb 367 SUB 8.01 min.

49400-

-

gK

47

i l

' 34 h10051S

JL48 ' 5S ' 56 ' 60 ' 64 ' 68 ' 7£ ' 76 ' 80 ' 84

SBMPLE SPECTRUM <UNBLTERED>FileBpk

>D1138fib 367

400n

01

44

VBLK01 QC70337V .UV70337 ,S :M4 ,5 , Scan 1738.01 min.

49

47

1 ,

' 54f51 in

Ve' ' 1B

I2

1 | 1 5 I 6 1 1 '6'0' "6V 'e'e' ' V8' ' '?6 ' 'e'e' "84 ' '

-100

•e

Data File: >D1138::SS Quant Output File:Name: YBLK01Misc: QC70337U ,QU70337,S:M4,5,, BLANKQuant Time: 900901 17:30 Quant ID File: ID0259::LJ1Injected at: 900631 21:00 Last Calibration: 900901 17:25

Compound No: 7Compound Name: M e t h y l e n e c h l o r i d eScan Number: 173Retention Time: 8.01 min.Quant Ion: 84.0Area: 3635Concentration: 19.13 NGq-value: 95

74

REFERENCE STflNOflRD SPECTRUMTile >C4697 Taraet Reference SpectraBpk fib 9999 SUB

7810000-

.

0-| . ! . | . | . I i I . I .

52

II 146 60 60 180

NRrt MOM

128 140 168

Scan 43617.95 min.

-100

-n188 288

SfiMPLE SPECTRUM (BRCK6POUND SUBTRRCTED)Tile >D1138 VBLK01Bpk Hb 259

78

200-• 5S (.1

rv |H ' " '40 69 80

QC70337V ,aV70337,S:M4,5,SUB

S3*•"

160 120 140 160 180

Scan 47419.68 min.

[-100

267 L|L0

200

SRMPLE SPECTRUM <UN«LTERED>File >D1138Bpk fib 859

289-•

Ck_

52

40

VBLK01 QC70337V .QV70337 ,S :H4 .5 , Scan19.68

78^

61* / 1fi 1 1

83 207^ ~*-.\

60 ' 80 ' 100 ' 120 ' 140 ' 160 ' 180 ' 200

474mm .

f-100

LB

Data File: >D1138::SS Quant Output File:Name: UBLK01Misc: QC70337U , QU70337 , S: (14,5 , , BLANKQuant Time: 900901 17:30 Quant ID File: ID0259::U1Injected at: 900831 21:00 Last Calibration: 900901 17:25

Compound No: 31Compound Name: BenzeneScan Number: 474Retention Time: 19.68 min.Quant Ion: 78.0Area: 5098Concentration: 9.45 NGq-value: 94

75

REFERENCE STBNDRRP SPECTRUMFile >C4697Bpk fib 9999

10000-

! 39

a-C i40

Target Reference SpectraNRH NOft

91\ 92

- I1 II's'e' ' 'e'e' ' '100' ' '120 ' '140' ' 'lie '

Scan 66224.39 A. in.

-iee

_o

180 200SOUPLE SPECTRUM (BRCKGROUND SUBTRACTED)File >D1138 VBLK01 QC78337V .QV70337 ,S :M4 ,5 ,Bpk Pb 502 SUB

91

400-

0-

1

39 65 1

40 60 80 100 120 140 168 180

Scan 64026.18 min.

207

200

-180

"SfiMPLE SPECTRUM CUNOLTERED)File >D1138Bpk fib 1957

2000-

_-

0J , .

42/

n 1 1 if40

VBLK01

•54 78

.1 1 .. «l i .68 80

aC70337V ,aV70337,S:M4,5, Scan 64026.12 min.

98

91

I,• II . .1

'

\ 807\

i i..

-100

-e180 ' 120 ' 140 ' 168 ' 180 ' 888

Data File: >D1138::SS Quant Output File: ^01138::AQName: UBLK01Misc: QC70337U ,QU70337,S:M4,5,, BLANKOuant Time: 900901 17:30 Quant ID File: ID0259::U1Injected at: 900831 21:00 Last Calibration: 900901 17:25

Compound No: 42Compound Name: TolueneScan Number: 640Retention Time: 26.12 min.Quant Ion: 92.0Area: 3442Concentration: 9.01 NG

98

76

1AUOLATILE ORGAN 1CS ANALYSIS DATA SHEET

ERA SAMPLE NO.

IIUBLK02

Lab Name: ETCNJ

Lab Code:

Cont ract:

Case No.:


Sample wt/vol: 5.0 Ig/mL) G

Level: (low/med) LOU)



CAS NO. COMPOUND

SAS No.: SDG No.:

Lab Sample ID: QC70337U2


Date Received: Q9-1'00-'"?U



CONCENTRATION UNITS:lug/L or ug/Kg) UG/KG U

I74-87-3-- — - ——— Chl or ome thane_______________I 1074-83-9----- — --Bromo me thane________________I 1075-01-4- — —— ---Uinyl Chloride______________I 1075-00-3---------Ch loroe thane________________I 1075-09-2- — - — —— Methylene Chloride__________1567-64-l---------Acetone_____________________I 1075-15-0---------Carbon Disulf ide___________I 575-35-4———-———1,1-Dichloroethene__________1575-34-3---- ——— -1,1-Dich loroe thane__________15540-59-0————---1,2-Dichlorethene (total)___1567-66-3- — ------Ch lorof orm__________________I 5107-06-2------—1/2-Dich loroe thane__________1578-93-3- — — ——— 2-Butanone__________________I 1071-55-6- —— ---—1,1,1-Trich loroe thane_______1556-23-5---------Carbon Tetrachlor ide________15108-05-4--- — - — Uinyl Acetate_______________I 1075-27-4---------Bromodichl or ome thane_______ I 578-87-5---------l,2-Dich loropropane________I 510061-01-5------cis-l,3-Dichloropropene_____1579-01-6--- — ----Trich loroethene_____________I 5124-48- l--------Dibromoch 1 orome thane________ I 579-00-5 —— — ——— 1,1,2-Tr ich loroe thane______1571-43-2- ———— ---Benzene_________________1510061-02-6---—-trans-l,3-Dichloropropene___1575-25-2---------Bromo form__________________15108-10-1- ————— -4-Methyl-2-Pentanone________I 10591-78-6- — — ---2-Hexanone__________________I 1012 7- 18-4- ------- Tetrach loroethene__________I 579-34-5---—----i,1,2,2-Tetrachloroethane__15108-88-3 ——————— Toluene____________________15108-90-7--------Ch lorobenzene_______________I 5100-41-4--------Ethyl benzene______________15100-42-5- —— —— -Styrene_____________________151330-20-7— ——— -Xylene (.total )_____________15

_____ _______ ___________I __

IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

FORM I UOA 1/8

1AUOLATILE ORGAN1CS ANALYSIS DATA SHEET

ERA SAMPLE NO.

IIUBLK02

Lab Name: ETCNJ


M a t r i x : Isoil/water) SOIL

Sample wt/vol: 5.0 Ig/mL) G

Le^e1: (low/med) LOW

H Moisture: not dec. 0

Column: Cpack/cap) PACK

Con tract:

SAS No.:

I

LAS NO. COMPOUND

SDG 'No. :

Lab Sample ID: QC7U337<J^


Date Received: 09;fDO;"?U


Dilution Factor: 1

CONCENTRATION UNITS:Cug/L or ug/Kg) UG/kG LJ

I74-8 7-3---------Ch lorome thane______________I 1074-83-9---- — ---Bromome thane_______________I 1075-01-4——————--Uinyl Chloride____________I 1075-00-3 — —— - —— Ch lor oe thane_____________I 1075-09-2- ———— ---Methylene Chloride_________1567-64-l---------Acetone__________________I 1075-15-0-- —— - — -Carbon Disulf ide___________1575-35-4———————1 ,1-Dich loroethene_________1575-34-3————————1,1-Dichlo roe thane_________15540-59-0 —— ————1,2-Dichlorethene C tota l )__1567-66-3- —— - ——— Chloroform_________________15107-06-2--------l,2-Dich loroe thane_________1578-93-3---------2-Butanone_________________I 1071-55-6- —————— -1,1,1-Tr ich loroe thane______1556-23-5---------Carbon Tetrachlor ide_______I 5108-05-4—- ——— -Umyl Acetate_____________\ 10•75-27-4---------Bromod ich lorome thane_______ I 578-87-5---------l,2-Dich loropropane________I 510061-01-5------C1S-1,3-Dichloropropene_____I 579-01-6---------Trich loroethene____________I 5124-48-l--------Dibromoch 1 oromethane_______ I 579-00-5————————1,1,2-Tr ich loroe thane______1571-43-2- ——— ——— Benzene____________________1510061-02-6-- — --trans-l,3-Dichloropropene___I 575-25-2- — - ——— -Bromoform__________________15108-10-l--------4-Methy 1-2-Pen t anone_______ I 10591-78-6 ——————— 2-Hexanone_________________I 10127-18-4- ——— — -Tetrach loroethene__________1579-34-5---------l,l,2,2-Tetrachloroethane__15108-88-3 ——————— Toluene____________________15108-90-7--------Ch lorobenzene______________I 5100-41-4————- — Ethyl benzene_______________15100-42-5---- —— -Styrene__________________151330-20-7—— — --Xylene t total )____________15

IIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

FORM I UOA 1/8

Lab Nana:

Lab Cod*:


_ Contract:____

___ SAS No.:

EPA SAXrLE NO.

Ca»a No.: SDC No. :

Matrix: (soil/water) _S£Sainpl* wt/vol: S~O ___

L«v«l: (low/m«d)

\ Moistur*: not d«c.

Column: (pack/cap)

(g/nL) %"Lab Sampla ID:

Lab Fil« ID:

Data Rccaivad:

Data Analyzad: ^f/olDilution Factor: /

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg)

Tetrahydrofuran_ UL

FORM I VOA 1/8? Rev.

78

IEVOLATILE ORGAN 1CS ANALYSIS DATA SHEET


Lab Name:ETC Corp. I Laboratory

Lab Code: Case No.:

Matrix: I soi1/water) WATER

Sample wt/vol: 5.0 Cg/mL) ML

Level: Clow/med) LOLJ



Con t rac t :

SAS No.:

EPA SAMPLE NO.

IIUBLK02I______

SDG No.:

Lab Sample ID: QC7033702

Lab Fi l e ID: >D11490?/2 >/?°

Date Received: 9-9.•'01••fl'C



Number TICs found: 0CONCENTRATION UNITS:Cug/L or ug/Kg) UG/L

CAS NUMBER COMPOUND NAME

FORM I UOA-T1C

RT EST. CONC

1/87

7

Q

Kev.

9

TOTflL ION CHROMRT06RPMFi le >D1149 35.0-860.6 amu. VBLK0S OC70337VS .QV70337 ,S i

800 , 4T60 A 600 i 600 , 1606

70000-

65006-

60006-

55800-

56000-

45006-

40006-"

35008-

30908-

85006--

86006--

15666-

10600-

tt.

J*»

I B - 5 -g S _f 1 if I

. § | II I

I ? ?c ?5 S-- ^V ®

I 1a o

\

C«l^|

I4 8 18 16 £0

f §g

I" 1i

JTj|[j

3 J

IL84 88 38 36 40

Data File: >D1149::U1Name: UBLK02rHsc: QC70?37U2,QU70337,S:M4,5,, BLANK


Operator ID: (1GRMSQuant Time: 900902 15:36Injected at: 900901 22:49


80

QUANT REPORT Page 1

Operator ID: MGRMS Quant Rev: 7 Quant Time: 900902 15:36Output File: ~D1149::AQ Injected at: 900901 22:49Data File: >D1149::(J1 Dilution Factor: 1.00000Name: UBLK02Misc: QC70337U2,QU70337,S:M4,5,, BLANK



1 )18)20)36)41)43)45)

*Bromochloro me thane1 ,2-Dichloroethane-D4 (SURR)

*1 ,4-Di f luorobenzene*Ch Iorobenrene-d5Toluene-08 (SURR)CMaPeb«na»no -p-Bromofluorobenzene (SURR)

11142227252732

.62

.53

.24

.21

.96

.33

.68

266341540668636"71O / 1809

41039860231734511308841900762721

111869

2502482502502485

251

. 00

.49

. 00

. 00

.82

.29

.79

NGNGNGNGNGNGNG

94959883957789

* Compound is ISTD

81

Lab Name: ETCNJ

1AUOLATILE ORGAN 1CS ANALYSIS DATA SHEET

Cont rac t:

ERA SAMPLE NO.

IIA4377MSI_______

Lab Code: Case No.: SAS No.: SDb No.:

Matrix: (soil/water) SOIL Lab Sample ID: CA4377Ub

Sample wt/vol: .0 (g/mL) 6 Lab File ID:

Level: (low/med) LOU) Date Recei*




D i l u t i o n Factor: 10U

CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or ug/Kg) US/KG

I74-87-3-- — -----Chlorome thane______________I 100074-83- 9- --------Bromome thane_____________I 100075-01-4---- — ---Uinyl Chloride___________I 100075-00-3--- —— — -Chloroe thane_______________I 10UO75-09-2 — -- ———— Methylene Chloride_________150067-64-1 — - —— — -Acetone_____________________1610075-15-0 —— - — — -Carbon Disulf ide___________150075-35-4——— — ——1,1-Dichloroethene_________1540075-34-3————————1,1-Di chloroe thane_________1500540-59-0—————1,2-Dichlorethene (total)___150067-66-3- ———— —— Chloroform_________________1500107-06-2 — —————1,2-Di chloroe thane_________150078-93-3 ———————— 2-Butanone_________________13200071-55-6 —— —————1,1,1-Tr i chloroe thane______150056-23-5---------Carbon Tetrachlor ide_______I 500108-05-4———————Uinyl Acetate______________I 1000•75-27-4------ —— Bromodich loromethane_______150078-87-5---- — ---1,2-Dich loropropane________150010061-01-5------cis-l,3-Dichloropropene____150079-01-6--- — —— -Tr ichloroethene__________15500124-48-1---- — --Dibromoch lorome thane_______I 50079-00-5--- ——— —1,1,2-Tn chloroe thane_____150071-43-2- —— — - — Benzene________________1540010061-02-6----—trans-1,3-Dichloropropene__150075-25-2---------Bromof orm__________________I 500108-10-1 —— - — — 4-Methyl-2-Pentanone_______I 10UO591-78-6---- ——— 2-Hexanone_______________I 1000127-18-4---- — --Tetrech loroethene__________I 50079-34-5- — -————1,1,2,2-Tetrachloroe thane__1500108-88-3-- —— —— Toluene____________________I54UO108-90-7- — — — -Chlorobenzene______________15600100-41-4——- —— -Ethyl benzene________________1500100-42-5- — - — --Styrene_____________________15001330-20-7——- —— Xylene (total )_____________1500

U

IUIUIUIUIUIIUIIUIUIUIUIIUIUIUIUIUIUIIUIUIIUIUIUIUIUIUIIIUIUIUI

FORM I UOA 1/8:8 6e

Lab Name:.

Lab Code:

VOLATILE ORGANIC ANALYSIS DATA SHEET

_ Contract:____

___ SAS No.:

EPA SAXPLE NO.

Case No.: SDC No. :

Matrix: (soil/water)

Sample wt/vol: .o

Level: (lov/ned)


Column: (pack/cap)

CAS NO.

.(g/mL)

Sample ID: C- AV37 7^

Lab File ID: ?& / /4-S

Date Received: _

Date Analyzed: _

Dilution Factor:

COMPOUNDCONCENTRATION UKITS:(ug/L or ug/Kg)

iTetrahydrofuran^ 5co

FORM I VGA 1/87 Rev.

TOTflL ION CHROMflTOSRPMTile >D1142 35.0-260.0 amu. 0437705,, C04377VS ,QV70337 ,S »r

80000^

70008^

HID30888;

20080-

10000-

J

. . . . . . . .&...:...*•...,. .. W. ... 8P» ...,...W.

2"

8"1 | s

1 I. 1| s —

If illIf 1 1v_%_ii i8 L I *(

i

\

3 J

m

"

\ 46

4 ' 8 ' 12 ' 16 20 ' 24 ' 28 ' 32 ' 36 ' 40

Data File: >D1142::SS Quant Output File: ~D1142::.AQName: A4377MS,,Misc: CA4377US,QU70337,S:M4,0.05,, 1:100 DL 10UL IFB SPIKE



84

Operator ID: EK1710Output File: ~D1142Data File: >D1142Name: A4377MS,,Misc :

: AQ:SS

QUANT REPORT


fry Dilution Factor:

1:100 DL 10UL IFB SPIKE

Page 1

900901 17:37900901 00:20

1.00000

ID File: ID0259: : UlTitle: XUOA13, IFB, PP/UOALast Calibration: 900901 17:25

Compound R.T. Scan# Area Cone Un i ts

1791315182021283031364142434546

)))))))))•))))))))

*Bromoch loromethaneH«thyl«ne eh+o-r d«-Acet one V1,1-DichloroethyleneTe t rahydrof uranl,2-Dichloroethane-D4 (SURR)

*1, 4- Dif luorobenzeneMethyl ethyl ketoneTrichloroethyleneh i f Th 1 rrnmnthy 1 1« thnrBenzene

*Chlorobenzene-d5Toluene-08 (SURR)To lueneCh lorobenzenep-Bromof luorobenzene (SURR)

11.•

9.11.12.14.22.14.19.19.19.27.25.26.27.32.-•,6..

6714421372542662157070239814347354

266175208252293340539342459473473667635639670809R54

38722•T D O O

14828454919985785831606451950864250C7OXo /DO

13956811962917505498141133985985889995

250.20.

305.269.385.233.250.

1615.275.101.267.250.253.271.281.245.

•?

00932148498700114901550060195441P7

NGki^*NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNIC

95O PTO

939310095979492100958495969689•74.

Compound is ISTD

85

Lab Name: ETCNJ

1AVOLATILE ORGAN1CS ANALYSIS DATA SHEET

Cont ract:

ERA SAMPLE NO.

IA4377MSD II____________ I

Lab Code: Case No.: SAS No.: SDb No.:

M a t r i x : (soiI/water) SOIL Lab Sample ID: CA4377UK

Sample wt/vol: .0 Cg/mL) G Lab F i l e ID: >Dl'i43

Level: (low/med) LOU) Date Received: 09/06/90


Column: (pack/cap) PRCK

CAS NO. COMPOUND


Di lut ion Factor : 1UU

CONCENTRATION UNITS:(ug/L or ug/Kg^ UG/KG

I74-8 7-3---------Ch lo rome thane______________I 100074-83-9---------Bromome thane_______________I 100075-01-4---------Uinyl Chloride______________I 100075-00-3---------Ch lo roe thane_______________I 100075-09-2--- — ----Methylene Chloride__________I50067-64-l---------ttcetone____________________I 590075-15-0- — ——— --Carbon Disulf ide__________150075-35-4—— — ----I , 1-Dichloroethene_________1540075-34-3------——1,1-Dichlo roe thane_________1500540-59-0--------l,2-Dichlorethene (total)__I 50067-66-3- ———— — -Chloroform__________________1500107-06-2 — ———— -1,2-Dichlo roe thane_________150078-93-3-- — - — --2-Butanone_________________13100071-55-6-- — ——— -1,1,1-Tr i ch 1 oroe t hane______150056-23-5--- —— ---Carbon Te t rach 1 or i de_______1500108-05-4— — ——— Uinyl Acetate_______________I 10UO75-27-4- — -- —— -Bromodichlorome thane_______150078-87-5---------l,2-Dich loropropane________I 50010061-01-5--——cis-1, 3-Dichloropropene____1500"7^-'tTi-b---------~l r ich'loroethene____________15500124-48-l--------Dibromoch loromethane_______150079-00-5- ———— - — 1,1,2-Tr ich lo roe t hane______150071-43-2-- —— - — -Benzene____________________153001006l-02-6------trans-l,3-Dichloropropene___150075-25-2---------Bromo form__________________I 500108-10-1-- — - —— 4-Methyl-2-Pentanone_______I 1000591-78-6 — -- — --2-Hexanone_________________I 1000127-18-4--------Tetrach loroethene__________I 50079-34-5-———----1,1,2,2-Tetrach1oroethane__1500108-88-3------ — Toluene____________________15400108-90-7- — --- — Chlorobenzene______________15700100-41-4----- — -Ethyl benzene________________I 500100-42-5--------St yrene_____________________15001330-20-7- —— — -Xylene (total )_____________1500

LI

IUIUIUIUIUIIUIIUIUIUIUIIUIUIUIUIUIUIIUIUIIUIUIUIUIUIUIIIUIUIUI

FORM I UOA 1/8$ ge

Lab Name:

Lab Cod*:


-&TCCase No.:

Contract:

SAS No . :

EPA SAKPLE NO.

A

SDG No. :

Matrix: (soil/water)

Sample wt/vol: .0

Level: (lov/ned)


Column: (pack/cap)

CAS NO.

Lab Sample ID:-

Lab Fil« ID:

Data R«c«ivad:

Data Analyzed:

COMPOUND

Dilution Factor:

CONCENTRATION UNITS:(ug/L or ug/Kg)

Tetrahydrofuran_

FORM X VGA 1/87 Rev.

87

TOTfiL ION CHROMOT06RPMFile >D1143 35.8-860.8 «mu.

200

76666-

60000-

seeee-

40086-

30000-

28800-

18000-

TIC400

CR4377VR,OV70337,S«t

600 800 . 10.00

Data File: >D1143::SS Quant Output File: ~D1143::AQName: A4377MSD,,Misc: CA4377UR,QU70337,S:M4,0.05,, 1:100 DL 10UL IFB SPIKE

Id File: ID0259::U1T i t l e : XUOA13, IFB, PP/UOALast Calibration: 900901 17:25


88

QUANT REPORT

Quant Re<*>: 7I Quant Time:In jected at:

Di lut ion Fac tor:

Operator ID: EK1710Output File: ~D1143::AQData File: >D1143::SSName: A4377MSD,,Misc: CA4377UR,QU70337,S:M4,er«*-?, 1:100 DL 10UL IFB SPIKE

ID File: ID0259::U1T i t l e : XUOA13, IFB, PP/UOALast Calibration: 900901 17:25

Page 1

900901 17:39900901 01:11

1.00000


1 )7)9)13)15)18)20)21)28)30)31)36)41 )42)43)45)

*Bromoch loro me thaneM fc h 1

Acetone v*hl e i - ide

1,1-DichloroethyleneTetrahydrofuran1 ,2-Dichloroethane-D4 (SURR)

*1 ,4-Di f luorobenzeneMethyl ethyl ketoneTrichloroethylene

Benzene*Ch Iorobenzene-d5To luene-D8To luene

(SURR)

Ch lorobenzenep-Bromof luorobenzene (SURR)

119

11121422141919192725262732

.66

.13

.37

.08

.70

.49

.20

.60

. 10

.64

.64

.17

.92

.13

.33

.68

267176208252294340539343459473473667635640671809

39137355414363457109511779741635731883365142

1419711203661785209904913547499004

250.19.

292.267.363.229 .250.

1531.274.101.267.250.257.272.282.244.

00225090305900313206280004029393

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

9595939410091979592100958599999586

Compound is ISTD

89

ETC

SEMIVOLATILE DATA

90

ETC

QC SUMMARY

91

2DSOIL SEMIUOLATILE SURROGATE RECOVERY

Lab Name: ETCNJ Contract: __

Lab Code: Case No.: ____ SAS No.:

Level : (LOU/MED ) LOU)

SDG No,

ERASAMPLE NO.

SBLK01A4376A4377A4377ttSA4377MSD

51( NBZ ) #

6972687071

52(FBP)*

6366656562

S3(TPH)*

6065656872

54(PHL)#

7464646468

55C2FP)#

6558536343

56(TBP)#

9356476364

OTHER TOTOUT

00000

01020304050607080910111213141516171819.2021222324252627282930

51 (NBZ) - Nitrobenzene-d552 (FBP) - 2-Fluorobiphenyl53 (TPH) - Terphenyl-dl454 (PHD - Phenol-d555 (2FP) - 2-Fluorophenol56 (TBP) - 2,4,6-Tribromopheno1

QC LIMITS(23-120)(30-115)(18-137)(24-113)(25-121)(19-122)

Column to be used to flagUalues outside QC limitsSurrogates di l u t e d out

recovery values-?

oaae 1 of

3DSOIL SENIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOUERY

Lab Name: ETCNJ Contract: __________

Lab Code: Case No.: ____ SAS No.: SDG No.:

Matrix Spike - EPA Sample No.: A4377 Leve 1 : (LOUJ/MED) LOW

11

COMPOUND 1

Phenol 12-Ch loropheno 1 11 .4-Dich lorobenzene ,.,,, 1N-Nitroso-di-n-prop. (l)_l1 ,2 , 4-Tr ich lorobenzene __ 14-Chloro-3-methylphenol_lAcenaphthene 14-Ni t ropheno 1 12 ,4-Din i t rot o luene 1Pen tach loropheno 1 1Purene 1

1

SPIKEADDED(ug/Kg)

7927.0707927.0703963.5353963.5353963.5357927.0703963.5357927.0703963.5357927.0703963.535

SAMPLECONCENTRATION

(ug/Kg)

0.0000.0000.0000.0000.0000. 0000. 0000.0000.0000. 0000.000

MSCONCENTRATION

(ug/Kg)

5377.9234612.1942710.5132552.5543106.7596135.9032754.79616571.4023129.4807019.5883300.994

MS\REC

68586864787770209798983

1 QC1 LIMITS

#1 REC.

126- 90125-102128-104141-126138-107126-103131-137

* 1 11-114128- 89117-109135-1421

1 SPIKE1 ADDED

COMPOUND 1 (ug/Kg)

Phenol 17927.0702-Chlorophenol 17927.0701 ,4- D ich lorobenzene ____ 13963.535N-Nitroso-di-n-prop. ( 1 )_l 3963 . 5351,2 , 4-Tr ich lorobenzene __ 13963 .5354-Chloro-3-methylphenol_l 7927. 070Acenaphthene 13963.5354-Nitroohenol 17927.0702 .4-Dinitrotoluene 13963.535Pentach loropheno 1 17927.070Purene 13963.535

1

MSDCONCENTRATION

(ug/Kg)

5229.3084795.7992817.6562778.6643035.4666127.4842672.5607985.8643650.3677036.2193226.100

MSD\REC *

6660717077776710192 «8961

\RPD ft

3448203

70 «1502

QC LIMITSRPD 1 REC.

35 126- 9050 125-10227 128-10438 141-12623 138-10733 126-10319 131-13750 111-11447 128- 8947 117-10936 135-142

1

(1) N-Ni t roso-d i -n-propy lamine



RPD: 1 out of 11 outside l i m i t sSpike Recovery: 2 out of 22 outside limi t s

Comments: - 7U

FORM III SU -2 1/87 Rev.

93

4BSEMIUOLATILE METHOD BLANK SUMMARY

Lab Name: ETCNJ

Lab Code: Case No.

Lab File ID: >P9853

Date Extracted: 08/30/90



Instrument ID: GC/MS P

Contract: __________

SAS No.: SDG No.:

Lab Sample ID: SBLK01

Extraction:CSepF/Cont/Sonc) SONC

Time Analyzed: 1718

Leve1:(low/med) LOU

THIS METHOD BLANK APPLIES TO THE FOLLOUING SAMPLES, MS AND MSD:

010203040506070809101112131415161718192021222324252627282930

EPA -SAMPLE NO.

A4376A4377A4377MSA4377MSD •

LABSAMPLE ID

CA4376CCA4377CCA4377CSCA4377CR

LABFILE ID

>P9854>P9855>P9856>P9B75

'

DATEANALYZED

09/04/9009/04/9009/04/9009/05/90

Comments:

page 1 of (FORM IU SU 1/87 Rev.

94

9BSEMI VOLATILE ORGANIC GCxMS TUNING AND MASS

CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)

Lab NameJETCNJ

Lab Code: Case No.:

Lab Fi la ID: >P9711

Instrument ID: EC/MS P

Contract:

SAS No . : SDG No. :

DFTPP Injaction Data:08^25x90

DFTPP Injaction Time:1418

11 mxe

1 511 681 691 701 127197

. 1981 1991 2751 3651 4411 4421 4431 ____

ION ABUNDANCE CRITERIA

30.0 - 60. OS of mass 198Less than 2.0 S of mass 69Mass 69 relative abundanceLess than 2 . OS of mass 6940.0 - 60. OS of mass 198Less than 1 . OS of mass 198Base peak, 100S relative abundance5.0 to 9. OS of mass 19810.0 - 30. OS of mass 198Greater than l.OOS of mass 198Present, but less than mass 443Greater than 40. OS of mass 19817.0 - 23. OS of mass 442

S RELATIUEABUNDANCE

45.10.0 C 0. )1

51.8.3 C . )1

44.80.0

100.06.9

19.21.5

10.266.312.6 C 19. )2

1-Ualue is S mass 69 2-Ualua is S mass 442

THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSO, BLANKS, AND STANDARDS:

1 EPA1 SAMPLE NO.

Oil SSTD160021 SSTD120031 SSTD80041 SSTD50051 SSTD2006 107 1oai091101111121131141151141171iai191201211221

LABSAMPLE ID

IFBXBNA160PPIFBXBNA120PPIFBXBNA80PPMIFBXBNA50PPMIFBXBNA20PPM

I

LABFILE ID

>P9712>P9713>P9714>P9715>P9716

DATEANALYZED

08X25X9008X25X9008X25X9008X25X9008X25X90

;

TIMEANALYZED

14351534163317321830

iI

paga of FORM U SU 1X87 Rev.

95

5BSEMIVOLATILE ORGANIC GC/MS TUNING AND MASS

CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)

Lab Name: ETC CORP Cont ract:

Lab Code: Case No.: SAS No.: SDG No. :.

Lab File ID:>P98513>

Instrument ID.: '

DFTPP Injection Date: 09x04/90

DFTPP Injection time: 16:04

m/e

51iCQXQ

701271971 OQ

199\ 275\ 365\ 441\ 4421 4431


30-60* of mass 198 —————— ————————— —— ————————Less than 2* of mass 69 — ———— - ——— ————— —————— — —Mass 69 relative abundance- —— --- —————— ————— ———Less than 2* of mass 69 ——————— - ——————— ___________40-60* of mass 198 — —— ——— —— —— —— —— —————— ———Less than 1* of mass 198 —————— —— —————— -T- —— -----Base peak, 100* relative abundance- — —————————— - —5-9* of mass 198 — ————— —— ——— ———— ————— — —— ————10-30* of mass 198 ————— ————— ——— ————— ———————Greater than 1* of mass 198- — ———— —— ______________Present, but less than mass 443 —————— ——————— - ———— -Greater than 40* of mass 198- ————— — - — —————— _____17-23* of mass 442 —————————————————————————

* RELATIVEABUNDANCE

47 9O.OC 0.0)154.6

,3( .6)141.40.0

100.06.4

19.71.38 JL

&r> 4.11. 6( 18.5)2

1-Ualue is * mass 69 2-Ualue is * mass 442


1 EPA1 SAMPLE NO.

Oil SS7KSO02 1 Sit-f/r/03 1 /3?G041 y^S.??

05 | x4v3?Â<J061071081091101111121131141151161171181

LABSAMPLE ID

$>(. 1l3^\f £-C/4t/H<e£,C/9V.1?3-Ô?t/3?^t^

191 1201 1211 1221 1

LAB 1 DATE 1 TIMEFILE ID (ANALYZED I ANALYZED

?P*.Pi»"2f">^3.3" c -Si V" O rfSii

~?fjS*5Tc

o4/0i//6o/11

J/'

-u_-J

fotf/ 3- ji-s

f f fv^

ff/^t>IÔ(f

<2oo /

page ( of ( _FORM U SU 1/87 V

5BSEMIUOLATILE ORGANIC EC/MS TUNING AND MASS

CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP

Lab Name: ETC CORP Con t r ac t :


Lab F i l e ID:>P9871

. rI nst rument ID.:

DFTPP Injection Date: 09/05x90

DFTPP Injection time: 18:14

1m/e

511 A Q

A Q

1 701271971 Q D

199<-\ -~}tr

365441442443


30-60* of mass 198------------------ ----------------Less than 2* of mass 69-----------------------------

Less than 2* of mass 69-----------------------------40-60* of mass 198----------------------------------Less than 1* of mass 198----------------------------

5-9* of mass 198------ — —— -- — --- —— - — —— ---- — — -10-30* of mass 198----------------------------------Greater than 1* of mass 198-------------------------Present,but less than mass 443----------------------Greater than 40* of mass 198---- — ------ — _ _ _ _ _ _ _ _ _ _17-23* of mass 442--- — - — — -- — ---- —— — — _ _ _ _ _ _ _ _ _

* RELATIUEABUNDANCE

47.60 . 0 ( 0.0)1

55.3.3C .6)1

41.80.0

100. 06 . 6

22.7i o

11 .3"70 i

IX. ~7 t 1O ClD

1-Ualue is, * mass 69 2-Ualue is * mass 442


01• 02

030405060708091011121314151617181921)2122

page /

EPASAMPLE NO.

-SO

LAB ISAMPLE ID t

LABFILE ID

S0|

- so

CA <

DATEANALYZED

TIMEANALYZED

/ ofFORM U SU

—— 971/87 REU

ETC

DATA

98

IBSEMI VOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

IA4376Lab Name: ETCNJ Contract:





54 Moisture: not dec. 18 dec.

Extraction: (SepF/Cont/Sonc) SONC

GPC Cleanup: (Y/N) Y- pH: 7.0

SDG No.:

Lab Sample ID: CA4376C

Lab File ID: >P9854

Date Received: 08/23/90


Date Analyzed: 09/D4/90

Dilution Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

108-95-2 ——————— Phenol _____________________ 1111-44-4 ——————— bis(2-Chloroethyl )ether ____ 195-57-8 ———————— 2-Chlorophenol _____________ 1541-73-1 ——————— 1,3-Dichlorobenzene ________ 1106-46-7 ——————— 1,4-Dichlorobenzene ________ 1100-51-6 ——————— Benzyl alcohol _____________ 195-50-1 ———————— 1,2-Dichlorobenzene ________ 195-48-7 ———————— 2-Methyl phenol _____________ 1108-60-1 — ------bis(2-Chloroisopropyl)ether_!106-44-5 ——————— 4-Methyl phenol _____________ 1621-64-7--------N-Ni t roso-d i-n-propy lamine __ I67-72-1 —————— — Hexachloroe thane ___________ 198-95-3----- — --Nitrobenzene _______________ 178-59-1- ——— -- — Isophorone _________________ 188-75-5 ———————— 2-Nitrophenol ______________ 1105-67-9 ——————— 2, 4-Di methyl phenol _________ 165-85-0 — -------Benzo ic acid _______________ 1111-91-1 — ——— — b is (2-Chloroethoxy)me thane __ 1120-83-2 ——————— 2,4-Dichlorophenol _________ 1120-82-1- —— - — -1,2,4-Tr ich lorobenzene _____ I9 1-2 0-3- - — — —— Naphthalene ________________ 1106-47-8 ——————— 4-Chloroani 1 ine ____________ 187-68-3------ — -Hexachlorobutad icne ________ I59-50-7 ———————— 4-Chloro-3-methyl phenol ____ 191-57-6 ———— —— -2-Methyl naphthalene ________ 177-47-4------- — Hexach lorocyc 1 open tad iene __ I88-06-2 ———————— 2,4,6-Tr ich loropheno 1 ______ 195-95-4 ——— ——— -2,4,5-Tr ich loropheno 1 _______ 191-58-7 — -------2-Ch loronaphtha Iene ________ I88-74-4 ———————— 2-Nitroani 1 ine _____________ 113 1-11- 3-- ——— --Dimethylph thai ate __________ 12 08-96 -B--- —— — Acenaph thy Iene _____________ 1606-20-2--------2,6-Dinitroto luene _________ I

4104104104104104104104104104104104104104104104109541041041041041041041041041041020004102000410410'

Q

IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIJIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU

FORM I SU -1 7 Rev.

1CSEMIUOLATILE ORSANICS ANALYSIS DATA SHEET

Lab Name: ETCNJ

Lab Code: Case No.:




Cont rac t:

SAS No.:

ERA SAMPLE NO.

IA4376I_____

Moisture: not dec. 18 dec .


GPC Cleanup: (Y/N) Y pH: 7.0

CAS NO. COMPOUND

SDG No.:


Lab File ID: >P9854




Dilution Factor: 1

CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

99-09-2 ———— -83-32-9 ———— -51-28-5 ———— -100-02-7 ——— -132-64-9 ——— -121-14-2 ——— -84-66-2 ———— -7005-72-3 —— -86-73-7 ———— -100-01-6 ——— -534-52-1 ——— -86-30-6 ———— -101-55-3 ——— -118-74-1 ——— -87-86-5 ———— -85-01-8 ———— •120-12-7 ——— -84-74-2 ———— -206-44-0 ——— -129-00-0 ——— -85-68-7 ———— -91-94-1 ———— -56-55-3 ———— -218-01-9 ——— -117-81-7 ——— -117-84-0 ——— -205-99-2 ——— -207-08-9 ——— -50-32-8 ———— -193-39-5 ——— -53-70-3 ———— -191-24-2 ——— -

----3-Nitroani 1 ine----Acenaphthene----2,4-Dinitrophenol----4-Ni trophenol----Dibenzofuran----2r4-Dinitrotoluene----Diet hvlphtha late----4-Ch lorophenyl-phenylethe r __----F luorene----4-Nitroani 1 ine----4,6-Dinitro-2-methylpheno 1 __----N-Ni t rosod ipheny lami ne (1) __._ — 4-Bromopheny 1-pheny let her __----Hexachlorobenzene----Pent ach lorophenol-- — Phe nan throne- - - - An thracene----Di-n-butylphtha late----Fluoranthene----Pyrene- - - - Bu t y 1 b e n z y 1 p h t h a 1 a t e----3.3'-Dichlorobenzidine---- Be nzo (a )an thracene----Chrysene-- — bis(2-Ethylhexyl )phthalate _— --Di-n-octylphthalate----Benzo(b)f luoranthene----Benzo(k)fluoranthene----Benzo(a)pyrene----Indeno(1.2.3-cd)p<jrene----DibenzC a, h) an thracene----Benzo(g,hr i )pervlene

112000141012000120001410141014101410141012000120001410141014101200014101410165141014101410181014101410134014101410141014101410141014101

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1 JIUIUIUIUIUIU1 JIUIUIUIUIUIUIU1

(1) - Cannot be separated from Diphenylamine

FORM I SU -2 1/87 Rev,

100

IFSEMIUOLATILE ORGANICS ANALYSIS DATA SHEET


EPA SAMPLE NO.

IA4376Lab Name:ETCNJ

Lab Code: Case No.: ____



Level: (low/med) LOUI

\ Moisture: not dec. 18 dec. 0


GPC Cleanup: (Y/N) Y PH: 7.0


Con t rac t:

SAS No.: SDG No.:


Lab File ID: >P9854


Date Extracted:08/30/90


Dilution Factor: 1.0


CAS NUMBER

01. 123-79-502.03.04.05.06.07. 116-02-908. 873-94-909.10.11.12. 52195-40-1

COMPOUND NAME

Hexanedioic acid, dioctyl esUnknownUnknownUnknownUnknownUnknownCyc lohexano 1 , 3 ,3 ,5- t r i methyCyc 1 ohexanone , 3 ,3 ,5- t r ime t hUnknownUnknownUnknown1-Propene, 1- (me thy 1 1 h io >- ,

RT

33.337.779.0314.916. 0411.9213.0012.677.0210.5210.7214.63

H

EST. CONC

1600064003200450440340300260240230220170

Q

JBJBJJJJJJJJJJ

FORM I SU-TIC 7 Rev.

TOTAL ION CHROHATOCRRHFile >P9854 35.8-588.8 mmu. 04376, 7, 18

TIC...... 4ee. ..... .88e. ....

2888888-

1888888-

1688888-

Meeeee-

1288888-

1888888-

888888

eeeeee-

488888-

288888-

*•* dpi

** w

2

i1

u

1 1 t!! f! '! 8 :4"f75 ,

J

i •i »

2 S

i t

1 I * ^• T ?E •L * *! i ;

ii-i!

E ( ^

. »w .

1sl} ••

CR4376C ,OC78246,Sl

. ... .«e ..... ?e.e?

I

;

\ \r

B.

8 12 16 28 24

62

28 '

[

1P 6D Fid f5 Nr,2 !

32 ' 36 ' 48 ' 44 '

Data File: >P9854::U2Name: A4376,7,18Misc: CA4376C ,QC70246,S:M4,24.63,1

Id File: IP0085::PFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900904 17:29

Operator ID: KU0786Quant Time: 900904 18:99Injected at: 900904 18:12

Quant Output File: "P9854::UL

BTL* 4

102

QUANT REPORT Page 1

Operator ID: KU07B6Output File: •*P9854::YLData File: >P9854::U2Name: A4376,7,18Misc: CA4376C ,QC70246,S:M4,24.63,1

ID File: IP0085::PFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900904 17:29

Quant Rev: 7 Quant Time: 900904 16:59Injected at: 900904 18:12

Dilution Factor: 1.00000

BTL* 4


1)2)3)5)12)14)15)17)18)26)32)36)50)52)54)62)65)66)67)72)73)

•d4-l,4-Dichlorobenzene 11.98 383 167718N-Nitrosodimethylamine 4.96 38 722012-Fluorophenol (SURR) 8.89 231 625356Phenol-05 (SURR) 11.37 353 900841N-Nitro&odi-n-propylamine 13.73 469 653002-Methylphenol 13.49 457 30224-Methylphenol 13.49 457 3022

•d8-Naphthalene 15.81 571 596875Nitrobenzene-05 (SURR) 13.73 469 426607Benzoic acid 15.40 551 6467

•dlO-Acenaphthalene 21.36 844 2680532-Fluorobiphenyl (SURR) 19.35 745 677857Fluorene 23.89 968 77912,4,6-Tribromophenol (SURR) 23.89 968 141081

•dlO-Phenanthrene 25.96 1070 350361Di-n-butyl phthalate 28.22 1181 18655•d!2-Chrysene 34.36 1483 182673Benzidine 25.96 1070 42703Terphenyl-014 (SURR) 31.17 1326 442331bis(2-Ethylhexyl)phthalate 34.87 1508 33620

«dl2-Perylene 38.68 1695 125295

40.00• 19.01-116.21128.5414.06

UG/MLUB/T1LUG/ML—UG/ML--OG ML

.6?0 US-^ML ~

.-530 UC.'ML40.0072.252.3340.0065.68,999

UG/MLUG/ML-UG/ML-UG/MLUG/ML-UC-'rH-

112.8040.001.6140.00

UG/ML-UG/MLUG/ML-UG/ML4JCXML

65.088.4940.00

UGXML-UG/hL-UG/ML

89100849038879494918692989293989895100929186

* Compound is ISTD

103

REFERENCE STANDARD SPECTRUMFil» >J1646Bpk Ab 9999.

10000-

*.,....,..

60 ,-"

1140 58

TARGET REFERENCE SPECTRP Scan 389SUB NRM NOM 9.99 min.

77 l?E 19*

' ~\,KX •188

«40 78 88 98 108 118 128

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)nit >P9854 A4376.7.18 CA4376C .QC70246 .SiH4.24 Scan 551Bpk Rb 1436.

ieee-0J

El39 ^

il .

SUB 15.40 *in.

77"***•

T 52 /6Ir". ,/40 50 60 70

105

78r .

/ 122"-».

i

hi 80

•a88 98 108 118 128

SAMPLE SPECTRUM (UNALTERED)File >P9854 A4376,7,18 CA4376C ,QC70246 ,S iM4 ,24 Scan 551Bpk Ab 1436.

1088-

^

43 51

,1 1 III

77"^^

1B^ 581, i Ir-" , ii ,

48 58 60 70

15.48 «in.iee

78f .

/ 122•

i

hi 00

ft68 98 100 lie lie

Data File: >P9854::U2 Quant Output File: AP9854::ULName: A4376,7,1Bhisc: CA4376C ,QC70246,S:M4,24.63,1 BTL* 4Quant Time: 900904 18:59 Quant ID File: IP0085::PFInjected at: 900904 18:12 Last Calibration: 900904 17:29

Compound No: 26Compound Name: Benzoic acidScan Number: 951Retention Time: 15.40 min.Quant Ion: 105.0Area: 6467Concentration: 2.33 UG/MLq-value: 86

104

REFERENCE STANDARD SPECTRUMFil« >EBpk Rb

18888-

8-i

4169 TARGET REFERENCE SPE9999. SUB NRH NOM

149

»e ee 128

CTRA Scan 128. 8B •

' 166 268

614in.

•188

9

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)File >P96S4Bpk Rb 7327

5888-'• 41. f**

48

A4376,7,16

/' « '\f * >

86 "

CA4376C ,OC78246,S:M4,24 Scan 1161SUB 26.22 Bin.

149

1§4"\/ \285f

hi 66

126 ' 166 ' 2^8

SAMPLE SPECTRUM (UNALTERED)Fil» >P9854Bpk Rb 7327

seee-41

46

A4376,7,16 CA4376C .QC76246 ,S |H4 ,24 Scan 116128.22 «in.

149V.

67 76 " 16412xl/ , T i , \ . / Y 265

hi 86

A

88 ' 128 ' lie ' 280 '

Data File: >P9854::U2 Quant Output File: /"P9854::ULName: A4376,7,1BMisc: CA4376C ,QC70246,S:M4,24.63,1 BTL* 4Quant Time: 900904 18:59 Quant ID File: IP0085::PFInjected at: 900904 18:12 Last Calibration: 900904 17:29

Compound No: 62Compound Name: Di-n-butyl phthaleteScan Number: 1181Retention Time: 28.22 min.Quant Ion: 149.0Area: 18655Concentration: 1.61 UG/MLq-value: 98

105

REFERENCE STAHPARP SPECTRUMFile >J7992Bpk Ab 9999.

18888-• 67

" .

B- '48

71/

T+rr^86

TARGET REFERENCE SPECTRASUB NRM MOM149**"*

167**

1128 168 288

Scan 284833.28 Bin.

-188

.Q246 288

SAMPLE SPECTRUM (BACKCROUND SUBTRACTED)File >P9854Bpk flb 1487

leeee- B7•*•>

6~ j jL.y48

A4376.7.18

. 7/ 83 113 »«

i ,-rrX T •88 ' 128

CA4376CSUB

149^•j

167

- , "I' 168

,QC78246>S:M4,24 Sc«n 158834.87 Bin.

W 88

279L -A

268 ' 248 ' 286

SAMPLE SPECTRUM (UNALTERED)FilBpk

» >P9864 A4376Ab 14999.

16686-

tU

57•*

46

71

,7,18

83 113^

88

132

i ,N128

CA4376C149">

i "i' ' ' 168

,QC78246,SiM4,24 Sc«n34.87

287 279

288 ' 248 ' 2

1668Bin.

hi 68

-aT -B8

Data File: >P9854::U2 Quant Output File: AP9B54::dLName: A4376,7,18Misc: CA4376C ,QC70246,S:M4,24.63,1 BTL* 4Quant Time: 900904 16:59 Quant ID File: IP006?::PFInjected at: 900904 18:12 Last Cal i b r a t i o n : 900904 17:29

Compound No: 72Compound Name: bis(2-EthyIhexyl)phthalateScan Number: 1908Retention Time: 34.87 min.Quant Ion: 149.0Area: 33620Concentration: 8.49 UG/MLq-value: 91

106

File >P9864 04376,7,18Bpk fib 9999.

1 67 78 „«J 3^i i r^ n

CA4376C ,OC78246,SiH4,24 Scan 1432SUB NRM 33.33 mir, .

l/ 172 199 223 241 372 313 f--J y .. j r f :*~ s . -^ .L

1 'lie' ' iie' ' '24e' ' '28V 'File >BICDB H«xan»dioic acid, BODO <2-» thy lh»xy 1 ) •* t»r (9CBpk Bb 9999.

J 66 78 112 f 14,29 If -^ \ l/ 172 199 ^241 268

' 48 88 1^8 ' 168 ' 2de ' s4e ' 2^8File >B!CDB Nonan*, 3-Btthyl- (8CI9CI)Bpk fib 9999.

| 2/'j I I ll^ 127 142 143

48 ' 88 128 ' 168 ' 28*8 ' 24*8 ' 2^8 '

File >BICDB Cycloh«xan», (••thyl-ac i-ni tro) - (9CI)Bpk Rb 9999.

A { 83Pt^ | J ^ 138^144^49

' 48 88 126 168 ' 28*8 ' a4e ' 2^8

'328'Scan 138BBe.ee Bin.

328

Scan 11159e.ee *in.

328

Scan 11852e.ee Bin.

I328' '

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 33.33Scan: 1432Area: 4692173 Rank: 2Semi-quantitative Cone (unconnected): 403.09 KG/MLSemi-quantitative Cone ( corrected ): 16365.60 ug/kgCalculated using Istd: d!2-Chrysene § 34.36 minutes

BTL* 4

*ru,PRE ,,PBR181,,,1,31. Hexanedioic acid, mono(2-ethylhexyl)ester (9CI)2. Nonane, 3-methyl- (8CI9CI)3. Cyclohexane, (methyl-aci-nitro)- (9CI)

296 C14H2604142 C10H22143 C7H13N02

Sample file: >P9854 Spectrum f:Search speed: 1 Tilting option: S


Prob. CAS * CON * ROOT

1. 65 4337659 13850 "BIGDB2. 30» 5911046 11159 "BIGDB3. 25« 55937976 11052 "BIGDB

K

754740

DK *FLG TILT \ CON C_I R_I

703752

022

0it,

513031

314442

24126

552113

107

File >P9854 R4376.7.16 CR4376C .QC70246 ,S iM4 ,24 Scan 176Bpk

FileBpk

FileBpk

FileBpk

Ab 9999. SUB NRH 7.77 Bin.

J 39

................. . n~f20 40

E9 L.56 ' 69 72 03 !?l,*.| ,.v .,. /r-*' ;. , ft.E«

60 80 ' 100

>BICDB 2-Propanone (9CI) Scan 1231Ab 9999.

1 « f| 2 / 25 27 39n*f~' ,,|| " ifp'. **"),. ll,.

20' " 40

>BI6DB CuanidineAb 9999.

43J ie /17 f 28 40> .f. . »!,......... l^. ....... .^. ...

0.00 Bin.

H53 ™ 59 f/ . . 1 - •-' _ t«

60 ' 80 ' 100

(8CI9CI) Scan 15810.00 Bin.

/

Jr e ^60 ' ' " ' ' " ' '00 ' 100

>BICIB Hydroperoxide, 1 , l-diB»thylethyl (9CI) Scan 1591Ob 9999. 0.00 nin.

13 15 25 31 39J — ,,./;. ,... ,< , ,:r.,t. t20 40

59/ ,

56 73 89 [

60 ' 80 ' 100

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 7.77Scan: 176Area: 3636347 Rank: 3Semi-quantitative Cone (uncorrected): 157.17 UG/MLSemi-quantitative Cone ( corrected ): 6381.36 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 11.98 minutes

BTL* 4

*ru,PRE ,,PBR181,,,1,31. 2-Propanone C9CI)2. Guanidine (8CI9CI)3. Hydroperoxide, 1,1-dimethylethyl (9CI

58 C3H6059 CH5N390 C4H1002

Sample file: >P9854 Spectrum *:Search speed: 1 Tilting option: S


1.2.3.

Prob.

30«25«20

CAS * CON *

6764111300875912

123115811591

ROOT

"BIGDB"BIGDB"BIGDB

K

252036

DK #FLG TILT X CON C_I R_I<J

46 047 244 1

g6 73

6150

444955

8 187 135 13

108

Fil« >P9864 84376,7,18 CA4376C ,QC78246,S |H4 ,24Bpk

FileBpk

FileBpk

Ob 9999. SUB

1 ^ ? t* 1 I'l'l' T - l - l - l 1

28 ' 46

HI9.- 62

' ? f *i,i .,.,.,, ,l|i,[|.s ..i^iji,., ,7,68 86

>BJCDB Cyclop»ntan«, ••thyl*n»- (8CI9CI)Ab 9999.

1^18 26 29 4' 49 ^

28 48

67

8263 77 / 84

66 ' 88

>BICDB l-Penttn-3-ol . 4-a«thyl- (8CI9CI)Rb 9999.

1 27 29 4^ 43 66

28 46

Fil* >BI6DB 2-H«x»n-l-ol.Bpk ftb 9999.

j V 'tr •"26 ' 46

67

6/ 71 82 85

68 ' 86

(Z)- (8CI9CI)67

" 71 8/2

68 86

Scan 2389.83 min.

98 tee f.-. ..L168

Scan 31468.66 Bin.

I' 186 ' '

Scan 53846.88 *in.

96 188 [* _t«

Scan 53218.88 ain.

98 188 t.r^..^ L''"I'j • • »^188

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 9.03Scan: 238Area: 182818? Rank: 6Semi-quantitative Cone (uncorrected): 79.02 UG/MLSemi-quantitative Cone C corrected ): 3208.29 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 11.98 minutes

BTL* 4

*ru,PRE ,,PBR181,,,1,31. Cyclopentane, methylene- (8CI9CI)2. l-Penten-3-ol, 4-methyl- (8CI9CI)3. 2-Hexen-l-ol, (2)- (8CI9C1)

82 C6H10100 C6H120100 C6H120

Sample file: >P9854 Spectrum *: 238Search speed: 1 Tilting option: S No. of ion ranges searched:

1.2.3.

Prob.

29»28«25*

CAS * CON f

15283094798452928949

314653045321

ROOT

"BIGDB"BIGDB"BIGDB

422428

DK *FLG TILT \ CON C_I R_IU

316070

120

2t)

2710060

423B48

8 1710 147 19

109

Pil* >P9864 A4376,7,18Bpk fib 9999.

11680-3

18868-

9688-

8860-

7888-

6080-

5888:

4868-

3880-

2886-

1668-

63j

57

36

,]

/83

UkJ.J48 68 86

CR4376C ,QC78246,SiH4,24 Scan 627SUB NRH 14.91 min.

142\

\ie6 ?l

III Jill \ III J,, , JLI. .

rue196""

172146 163 if

/ I/ 11188 128 146 168 188

•188

•98

«e

•78

«.68

48

•38

•26

•16

e

Data File: >P9854::U2Name: A4376,7,18Miac Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 14.91Scan: 527Area: 330480 Rank: 10Semi-quantitative Cone (uncorrected): 10.99 US/MLSemi-quantitative Cone ( corrected ): 446.28 ug/kgCalculated using Istd: dB-Naphthalene § 15.81 minutes

BTL* 4

No PBM hits for this scan.

110

Fil* >P9864 R4376,7,Bpk fib 9999.

18888-

8888-

6888-

4090-

2888-

8-

18 C04376C ,0078246, SiM4, 24 Scan 91SUB NRM 6.84 «ln.

4

36 39

\%\\

13/ 47

7349 56 57 7j// 88

•188

«8

<e•48

•28

-a"''"j'e" *' ""38 48 ^ 58 ' 68* ' 78 T 88

Fil* >BICDBBpk fib 9999 .

10888-

8880-

6880-

4080-

2888-

8-

6

ie 24 28

Propanoic acid, 2-oxo- (9CI) Scan 118.88 Bin.

*•*

y? 36 48

45

/ 62 66 68 68 69 77 88

" 2'e""'""3e •'•"4le"T ""ee""1" ee" ' ""?e '""e'e""1"

•188

-88

-68

-48

-28

-8

Data File: >P9854::U2Name: A4376,7,1BMisc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 6.04Scan: 91Area: 291420 Rank: 11Semi-quantitative Cone (uncorrected)! 10.87 DC/MLSemi-quantitative Cone ( corrected ): 441.21 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene @ 11.98 minutes

BTL* 4

*ru,PRE ,,PBR181, ,,1,31. Propanoic acid, 2-oxo- (9CI) 88 C3H403



1.

Prob. CAS * CON * ROOT K DK *FLG TILT S CON C_I R_IU

20« 127173 11 "BIGDB 26 51 1 0 80 51 5 14

111

F1U >PBpk fib

11880-

18888-

9888-

8888-

7888-

6888-

5888-

4888-

3880-

2060-

1080-j

98649995

A

4-48

\ 04376,7,18 (>. SU

3

C

65 73I / ?8/

k. 4..... ....68 88

:04376C ,QC78246,SlH4,24 ScanB HRH 11.92 •

»7

97 JIB 158, V ' \ v' 188 ' 1^8 ' 148 '

388in.•118

•188

•98

•88

•79

«•

50

48

•38

28

•18

e

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 11.92Scan: 380Area: 190983 Rank: 12Semi-quantitative Cone (uncorrected): 8.2? UG/MLSemi-quantitative Cone ( corrected ): 335.15 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 11.98 minutes

BTL* 4


112

File >P9854 R4376.7.18 CR4376CBpk Bb 9999.

14,,,,,,i,l,i48

SUB HRh,QC7e246,SiM4,24

109

44 ** *?™ "3 9S 97 f|7 .(1|l|l(, vlji.l, - .ii|,l, . ..r" .1, f." ' " "ee" " ' " "e'e" " 'iee ""iie'

File >BICDB Cyc lohexanol , 3 ,3 ,5-t r i»» thy 1- (8CI9CI)Bpk Rb 9999.

1 « Vj f I Iej. .'i'ni.i.il|lill40

File >BICDBBpk fib 9999.

. 41

JiT7 if.^^i ^ ° * * i *48

File >B1CDBBpk Rb 9999.

1 r«Lj . .'

189

t7 83^4 SS 67^ , 9

' ' ' 60" ' ' 80 '

BicycloCB.l .03 octane67

64 I 82"^ 79 ' 9

. . 1 . l.^.\ | . . . Ma . . . ,

3,4-Pyridinediaaine

V|l|l|f|rii|i|i|l|iee

(8CI9CI)

5••i'l iee•C9CI)

' 'Vl|n.|.|.mfr|t126

'"ill

'"'lie'

Scan 43313.ee Bin.

12« 127 F

148

Scan 183876.86 min.

-4i4^L"""""IVScan E369e.ee *in.

, i1 " lieScan 103450 .ee Bin .

109

52 B4 6B 82

' V0 ' 80 iee__ne' 128

, i1 lie

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246 ,S: 114,24. 63 ,1RT (min): 13.00Scan: 433Area: 168621 Rank: 13Semi-quantitative Cone (unconnected): 7.29 UG/MLSemi-quantitative Cone ( corrected >: 299.91 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 11.98 minutes

BTL* 4

*ru,PRE ,,PBR181,,,1,31. Cyclohexanol, 3,3,5-trimethy1- (8CI9CI)2. BicycloC5.1.03octane (8CI9CI)3. 3,4-Pyridinediamine (9CI)

142 C9H180110 C8H14109 C5H7N3



1.2.3.

Prob.

8931*

CAS * CON *

11602928643154966

10387536910345

ROOT

'BIGDB•BIGDB'BIGDB

K

974827

DK *FLG TILT \ CON C_I R_I«J

153655

122

0"2

781889

54461

66 6312 222 14

113

Film >P9864 04376,7,18Bpk Ab 9999.

J 41 66^s. 43 /.l.lii.. — ..Hi..

C04376C ,0078246, S i M 4 ,24 Scan 417SUB NRH 12.67 Bin .

8369 r^ t-( 74 97 167 126 14^ E

28 46 68 86 166 128 148

F i l e >BICDB Cyc lohcxanon* ,Bpk Ob 9999.

1 16 « ^ 43 B/B4,-:-,- A, .Mvrrnil-,

3,3,6-tr i«»thyl- (8C19CI) Scan 663583 e'8e •*"•

6/9 f \82 97 112 122 125 146 \

....... I. 7TB ... . . ...<. ^. ^> f.. ^..L28 48 68 86 188 128 148

Fi l e >BICD£ Cyclohexane, bu ty l - ( 8 C I 9 C I ) Scan 16789Bpk Ob 9999. 6.86 K i n .

83H B6 62 f L.

28 4 , L « 3 { 67 ^| 97 ln »«M

28 ' 48 ' 68 ' e'e ' iee ' i2e ' lieFile >BI6DB Cycloh»x*nt,Bpk Ob 9999.

66-j 41 /3 27 *^ 43

pj /.I. JiCi-j'lta

(2-«»thylpropyl ) - (9CI) Scan 56366 .88 «in .

83.. 8i r 97 t^/ ^ f n2 n3 12S '\ [28 46 66 88 166 126 146

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 12.67Scan: 417Area: 149323 Rank: 14Semi-quantitative Cone (uncorrected): 6.45 UG/MLSemi-quantitative Cone ( corrected ): 262.04 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene @ 11.98 minutes

BTL* 4

*ru,PRE ,,PBR181,,,1,31. Cyclohexanone, 3,3,5-trimethy1- (8CI9CI)2. Cyclohexane, butyl- (8CI9CI)3. Cyclohexane, (2-methyIpropy1)- (9CI)

140 C9H160140 C10H20140 C10H20

Sample file: >P9854 Spectrum *:Search speed: 1 Tilting optionion: S

417No . of ion ranges searched: 47

1.2.3.

Prob.

79«67»60»

CAS * CON *

87394916789391678984

5635157895636

ROOT

"BIGDB"BIGDB"BIGDB

K

664639

DK #FLG TILT S CON C_I R_IU

365264

123

00

8175100

111511

433430

662113

114

File >P98S4 P4376,7,10Bpk Ab 9999.iieee-.

18000-

9088-

8800-

7008-

6000-

5800-

4000-

3000-

2000-

1000-

CB4376C ,QC70246,StH4,24 Scan 139SUB HUH 7.82 «in.

riie43

42NS

^

60

I40

E49

s'e

866

\\( 1.

'1f 84

i \ 87 7 ie\1 1 i ( ^

•100

•90

«0

•70

•60

€0

•40

•30

•20

•10

«60 1 ' 70 80 ' 90 ' 188 '

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 7.02Scan: 139Area: 136410 Rank: 16Semi-quantitative Cone (uncorrected): 5.96 UG/MLSemi-quantitative Cone ( corrected ): 242.89 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene g 11.96 minutes

BTL* 4


115

Fil* >P98C4 R4376,7,18Bpk fib 9999.

41 4S

J ^ v . /

,, i..Mi.n-1'iMiU ivi'l20 40

CR4376C ,0078246, SiH4 ,24 Scan 311SUB NRM 18.62 Bin.

>7

60 73 84 98 183 112 117 131 fjlr-''. i .jlj / . / . .71 "^ / " tfl60 ' 89 ' 180 ' 120

Fil* >B!CDB 1 ,3-Butan*diol (8CI9CI) Scan 333Bpk Rb 9999. 0.00 Bin.

4S

] 27 41 1 67 72 90 f*J,,l,,lM1.,,,>l|l,l,,.|<r >f» < t*

20 40 68 "80 ' lie ' l 2 0

Fil* >BICDB 4-P*nt*n-2-ol (8CI9C1) Scan 328Bpk Ab 9999. 8.00 Bin.

j 27 «j| 53 67 71 72 |

20 40 60 ' 88 ' 180 ' 120

Fil* >BI6DB 2-But*non*, 3-hydroxy- (8CI9CI) Scan'353Bpk flb 9999. 0.80 Bin.

j i5 ZJ 41 |j 55 60 72 86 88 99 114 115 f

20 ' ' 40 ' ' ' "60 ' 80 ' 188 ' 120

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 10.52Scan: 311Area: 131121 Rank: 17Semi-quantitative Cone (unconnected): 5.67 LJG/fILSemi-quantitative Cone ( corrected ): 230.10 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 11.98 minutes

BTL* 4

tru,PRE ,,PBR181,,,1,31. 1,3-Butanediol (8CI9CI)2. 4-Penten-2-ol (8CI9CI)7. 2-Butanone, 3-hydroxy- (8CI9CI)

90 C4H100286 C5H10088 C4H802

Sample file: >P9854 Spectrum #:Search speed: 1 Tilting option: S


Prob. CAS * CON * ROOT K

1. 20« 107880 333 "BIGDB 322. 15 625310 328 "BIGDB 353. 15 513860 353 "BIGDB 35

DK #FLG TILT

433850

111

688382

CON C_I R_IU

556058

5 173 133 13

116

Ft l* >P9664 R4376.7.18Bpk

F i l eBpk

Fi l eBpk

Fi leBpk

CA4376C ,QC78246,SiH4,24 Scan 321SUB NRM 16.72 B in ."" ""' « s,

J,,,,,,,,,iL26 46

~->

£9 " 77 98 ^«3¥^ ^ i i i - i ' i I't iC^ i- i ' l i \\ i i ii i 'Vi i |

66 66 166

> B I C D B 1 ,3-Butanediol ( 8 C I 9 C I )fib 9999.

J '? ^ 'e j.. , , , i i | i , i , , .Tpiiin^-26 46

7 72 96> •(•• (

68 88 186

> B I C D B 2-Butanone, 3-hydroxy- ( 8 C I 9 C I )fib 9999. ^

if ?: %lf26 46

55 59 72 83 88 99• I ' l ' i - i - . i • i ' | ' l ' i ' . • i ••• i - l - i . . . .'| • . . . |68 86 tee

>BICDB Diaz«n«, b i s C l , l -diB»thyl«thyl > - (9CI )Rb 9999.

V7 L126

Scan 3338.66 B in .

IScan 353

6.86 Bin.

114 115 [

Scan 11766. 66 Bin .

57

J 29 41

,,,Q£,26 46

59 71 83 85 97 185

66 86 166 '

Ill 127 fr-~ ^.L»

Data F i l e : >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 10.72Scan: 321Area: 122916 Rank: IBSemi-quantitative Cone (uncorrected): 5.31 UG/MLSemi-quantitative Cone ( corrected ): 215.70 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene @ 11.98 minutes

BTL* 4

*ru,PRE ,,PBR181,,,1,31. 1 ,3 -Butaned io l ( 8 C I 9 C I )2. 2-Butanone, 3-hydroxy- (8CI9CI)3. Diazene, bis(1,1-dimethylethyl)- (9CI)

90 C4H100288 C4H802142 C8H18N2



1.2.3.

Prob.

20»1511

CAS 4

107880513860927833

CON 4

3333531176

ROOT

'BIGDB'BIGDB'BIGDB

243535

DK *FLG TILT \ CON C_I R_W

515036

212

00

9884100

525864

5 143 132 12

1 1 7

FileBpk

FileBpk

FileBpk

FileBpk

>P9664Rb 9999

1_j

28

>BICDBFib 9999

JU628

>BISDBRb 9999

1 1B• (Jr""28

>BICDBRb 9999

£J ~X

28

R4376,7,18 CR4376CSUB NRH

/

- 43 67 67

1 Lff . . I I *>:>......

' 48 68 88

1-Propene, l-(*ethyl thio)46 73

39 f (28 / 63 61 a

48 ' 68 88

,aC78246,SlH4,24 Scan14.63

88^f

83 181 118116 12'

' lee lie-, CZ>- (9CI) Scane.ee

88

5 98

{e'e ' i2eBut«noic acid, 2-ftethyl-, nethyl ester, (.+-. Scan

6729 41 (' I 43 61 74 '

.III.., i.l .iTT . ill.l..- ' i (48 68 88

e.ee88

^ iei n61, . { f

iee tieButane, 2-»ethoxy-2,3,3-tri«ethyl- (9CI) Scan

73

29 41 43 66 65

48 68 e'e

83 91 99 11B 117

"'''"i^e"'1 "'iie'"

613• in.

rfte

6997• in*

I7885• in.

f

tfl

4481

I

Data File: >P9854::U2Name: A4376,7,18Misc Data: CA4376C ,QC70246,S:M4,24.63,1RT (min): 14.63Scan: 513Area: 122753 Rank: 19Semi-quantitative Cone (uncorrected): 4.08 UG/MLSemi-quantitative Cone ( corrected ): 165.77 ug/kgCalculated using Istd: d8-Naphthalene § 15.81 minutes

BTL* 4

*ru,PRE ,,PBR181,,,1,31. 1-Propene, 1-(methylthio)-, (Z>- (9C1) 88 C4H8S2. Butanoic acid, 2-methyl-, methyl ester, (.+-.)- (9CI 116 C6H12023. Butane, 2-methoxy-2,3,3-trimethyl- (9C1) 130 C8H180

Sample file: >P9854 Spectrum *: 513Search speed: 1 Tilting option: S No. of ion ranges searched: 47

Prob. CAS * CON

1. 41» 52195401 69972. 20« 53955810 70053. 15 27705211 4401

ROOT

'BIGDB'BIGDB'BIGDB

232533

DK #FLG TILT \ CON C_I R_I

927841

331

0TO

828395

215160

1753

121312

118

IBSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET





Level: (lou/med) LOU

>S Moisture: not dec. 16 dec.

Extraction: CSepF/Cont/Sonc) SONC

GPC Cleanup: (Y/N) Y. pH: 7.0

EPA SAMPLE NO.

IA4377I_____

SDG No.:


Lab Fi l e ID: >P9855




Dilution Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG Q

108-95-2 ———111-44-4- ——95-57-8-- ——541-73-1 ———106-46-7 ———100-51-6 ———95-50-1- ———95-48-7 ————108-60-1 ———106-44-5 ———621-64-7 ———67-72-1 ————98-95-3 ————78-59-1 ————DO ~7C K

105-67-9 ———65-85-0- ———111-91-1 ———120-83-2 ———120-82-1 ———91-20-3 ——— -106-47-8 ———87-68 3 —— -59-50-7 ————91-57-6 ————77-47-4- — _88-06 295-95-4 ————91-58-7----88-74-4 ————

1 131-11-3 ———1 208-96-8 ———1 606-20-2----1

1----Phenol 1----b is (2-Ch loroethvl )ether 1----2-Ch 1 oropheno 1 1---- 1 ,3-Dich lorobenzene 1---- 1 .4-Di ch 1 orobenzene 1----Benzol alcohol 1---- 1 j,2-Dich 1 orobenzene 1- — -2-Methvlphenol 1----bis(2-Chloroisopropyl)ether_l----4-Me t hvlpheno 1 1----N-Nitroso-di -n-propy lamine __ 1----Hexach 1 oroe thane 1----Nitrobenzene 1---- I sophorone 1----2-Ni t ropheno 1 1----2 .4-Dimethvlpheno 1 1----Benzoic acid 1----b is (2-Ch loroethoxy) me thane _ 1----2 ,4-D i ch loropheno 1 1----1 .2 .4-Tr ich lorobenzene 1----Naphthalene 1----4-Ch loroan i 1 ine 1

----4-Ch loro-3-methylpheno 1 ____ 1

----Hexach lorocvc lopent ad i ene 1----2 .4 .6-Tr i ch loropheno 1 1----2 ,4 .5-Tr ich loropheno 1 1

----2-Ni t roan i 1 me 1----D ime thvlph t ha la te 1----Acenaph t hv lene 1----2 ,6-D in i t ro t o 1 uene 1

1

4004004004004004004004004004004004004004004004009640040040040040040040040040040020004002000400400-'400

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1 JIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1

FORM I SU -1 7 Rev.

1CSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET

Lab Name: ETCNJ

Lab Code: Case No.:




Con t rac t :

SAS No.:

EPA SAMPLE NO.

IA4377I_____

Moisture: not dec. 16 dec.



CAS NO. COMPOUND

SDG No.:


Lab Fi l e ID: >P9855




Dilution Factor: 1


I99-09-2- — ------3-Nitroanil me_____________12000B3-32-9---------Acenaphthene_______________ I 40051-26-5- —— -----2,4-Dini t rophenol__________12000100-02-7——--——4-N it rophenol______________12000132-64-9 ——————— Dibenzofuran_______________1400121-14-2 ——— - — -2,4-Dini trotoluene_________140084-66-2 — - —— — -Diethylphthalate___________14007005-72-3-------4-Ch1oropheny1-phenylether__I 40086-73-7—- — - —— Fluorene___________________1400100-01-6 ———— -- -4-N it roan i 1 me_____________12000534-52-l--------4,6-Dinitro-2-methylphenol_1200086-30-6-- — -----N-Nitrosodiphenylamme (1)_1400101-55-3--------4-Bromopheny1-phenylether__I 400118-74-1-- — ----Hexach lorobenzene___________140087-86-5---------Pentachloropheno 1__________I 200085-01-8-- — -----Phenanthrene_______________140012 0-12-7-- —— — -Anthracene_________________140084-74-2---------Di-n-butylphtha late________167206-44-0--------Fluoranthene_______________I 400129-00-0- — - — --Pyrene_____________________140085-68-7---------Butylbenzylphthalate_______I 40091-94-1 ———————— 3,3 '-Dichlorobenzidme_____179056-55-3--------- Be nzo ( a )anthracene_________I 400218-01-9 —— —— --Chrysene___________________1400117-81-7—--- — -bis(2-Ethylhexyl)phthe late__I 120117-84-0- —— - — -Di-n-octylphthalate________1400205-99-2--------Benzo(b)fluoranthene______1400207-08-9- —— ----Benzo(k ) f luoranthene_______140050-32-8---------Benzo (a )pyrene_____________I 400193-39-5———————Indeno(l,2,3-cd)pyrene______140053-70-3----- — --Dibenz(a,h)anthracene_______I 400191-24-2-- — ----Benzo(g,h, i )perylene_______I 400

___________________________________________I(1) - Cannot be separated from Dipheny1 am me

FORM I SU -2

IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIJIUIUIUIUIUIUIJIUIUIUIUIUIUIUI

1/87 Rev.

120

IFSEMI VOLATILE ORGAN ICS ANALYSIS DATA SHEET


ERA SAMPLE NO.

IA4377Lab Name:ETCNJ





\ Moisture: not dec. 16 dec. 0




Cont rac t :

SAS No.:

I

SDG No.:


Lab File ID: >P9855




Di lut ion Factor: 1.0


CAS NUMBER

01. 123-79-502.03. 928-94-904.05.06.07.08.09. 503-74-210. 149-57-511. 116-02-9

COMPOUND NAME

Hexaned 10 i c acid, dioctyl esUnknown2-Hexen-l-ol , (2)- (8CI9CI)UnknownUnknownUnknownUnknownUnknownButanoic acid, 3-methyl- (9CHexanoic acid, 2-ethyl- (8CICyc lohexano 1 , 3 ,3 ,5- t r imet hy

'

RT

33.347.769.00

14.916.03

11.9114.5617.738.58

14.6412.99

m

EST. CONC

2500054005300540360300230170210170200

Q

JEJBJJJJJJJJJ

FORM I SU-T1C 1/87 Rev.

121

TOTRL ION CHROMRTOCRRHFll* >P9856 35.0-508.8 MHJ . R4377,7,16 CR4377C ,OC7B24fc,Si

40e , l\l , 1200 , itee , 2000

2088088-

1680088-

1608880-

1400000^

1200080-;

1888888-

680888--

688000^

480080-

28B080-

* Ig &

|(A

t

I]

^

»^4

i® I \\ is s 1 :ii•j .; i

A

' 12

• i i '1 *. ri

i * " '

b' ' 1

i*E ' •16 ' 20

1' [i *

*• 'N Ii ' °; s Ti l: J&U 1

62

24 ' 26 ' 32

A

! ?•o £!

h T36 40 44

Data File: >P9855::U2Namo: A4377,7,16Misc: CA4377C ,QC70246,S:M4,25.22,1

Id File: IP0085::PFTitle: IFB/BNA, PPxBNA, TCLBN1Last Calibration: 900904 17:29


Quant Output File: ~P9855

BTL* 5

122

QUANT REPORT Page

Operator ID:Output File:Data Fi le:

KU07B6~P9855::UL>P9855::U2

Name: A4377,7,16hisc: CA4377C ,QC70246,S:M4,25.22,1

Quant Rev: 7 Quant Time:In jected at

Di lut ion Factor:

900904 19:53900904 19:06

1.00000

BTL* 5



1)3)5)12)14)15)17)18)26)32)36)50)52)54)62)65)66)67)72)73)

*d4-l,4-Dichlorobenzene2-Fluorophenol (SURR)Phenol-D5 (SURR)N-Nitrosod i-n-propylamine2-Methylphenol4-MethyIpheno1

*d8-NaphthaleneNitrobenzene-05 (SURR)Benzoic acid

*dlO-Acenaphthaione2-Fluorobiphenyl (SURR)Fluorene2 ,4,6-Tribromopheno1 (SURR)

*dlO-PhenanthreneDi-n-butyl phthalate*d!2-ChryseneBenz idineTerphenyl-D14 (SURR)bis(2-Ethylhexyl)phthalate*d!2-Perylene

12.00 383 175259 40.00 UG/ML 908.72 222 117415 20.88 UG/ML- 8511.36 352 943691 128.86 UG/ML- 9013.73 468 64208 '1J.23 UG/ML 3813.48 456 2160 .431 UG/ML 8913.48 456 2160 - .J6J UO/ML 9615.82 571 628868 40.00 UG/ML 9413.73 468 421478 67.75 UG/Mtr 9215.42 551 7076 2.42 UG/ML- 9421.36 843 281694 40.00 UG/ML 9619.34 744 706683 65.15 UG/MIr 9723.88 967 6893 .041 UG^ML 9123.88 967 124183 94.48 UG/ML~ 9725.98 1070 369837 40.00 UG/ML 9928.24 1181 20748 1.69 UG/ML- 9634.36 1482 182568 40.00 UG/ML 9825.98 1070 45671 K2.B9 UC 'ML 10031.17 1325 444760 65.47 UG/ML- 9134.87 1507 11747 2.97 UG/ML~ 8838.68 1694 131870 40.00 UG/ML 83

* Compound is ISTD

123

REFERENCE STANDARD SPECTRUMFil« >J1646Bpk Ab 9999.

18000-j

0^ . , . . , . , . .

60 J-1

1148 68

TARGET REFERENCE SPECTRA Scan 389SUB

68 70

NRH NOM 9.99 Bin.185

77 / 122r [-100

•Ae'e 90 tee 110 120

SAMPLE SPECTRUM (BACK6ROUND SUBTRACTED)File >P9855 A4377.7.16 CA4377C .QC78246 ,S sM4 ,25 Scan 551Bpk Ab 1595. SUB 16.42 Bin.

1888- 60 B1

39 £ r" 67 6' 741 1 1 1 i ill , . i i i 1 1 148 60 60 70

10677

85i i f

/ 122

, 1.•100

«80 90 ' 100 ' 110 120

SAMPLE SPECTRUM (UNALTERED)Fi l» >PBpk Ab

0-

9065 04377,7,16 CA4377C ,QC70246,SlM1696.

177

~~^i ^ r' ^ 69 7A es. i l | i | l | i /ll i|l 1 i i f . i l i i !

4,25 Scan15.42 •

?5 I»

I

40 60 66 70 66 90 1^6 110 120

.561in.

•100

•0

Data File: >P9855::U2 Quant Output File: ~P9855::ULName: A4377,7,16Misc: CA4377C ,QC70246,5:M4,25.22,1 BTL* 5Quant Time: 900904 19:53 Quant ID File: IP0085::PFInjected at: 900904 19:06 Last Calibration: 900904 17:29

Compound No: 26Compound Name: Benzoic acidScan Number: 551Retention Time: 15.42 min.Quant Ion: 105.0Area: 7076Concentration: 2.42 UG/MLq-value: 94

124

REFERENCE STRHPRRP SPECTRUMFil* >E4169Bpk Rb 9999.

leeee-

B- ii i i%'e' • • ' •

TRRCET REFERENCE SPECTRR Sc«n 1SUB NRM NOM 26.65 •

149•«v

e'e ' 126 160 266

ei4in.

•166

•6

SRMPLE SPECTRUM (BRCK6ROUND SUBTRRCTED)File >PBpk Rb

seee-6

t

98SS R4377.7.167926.

41 B6 93

fr . r r i i . .h ., .,'.,(.16 66

CR4377C ,SUB

149•v.

121V

\'126 ' ' '

QC76246,SiH4,25 Scan 126.24 •

265h f166 ' 266

181in.

hi 06

^

SAMPLE SPECTRUM (UNRLTERED)Fil» >P98SB 04377,7,16Bpk Rb 7926.

5606-;*» 67 76 "jT.-' ... . .\46 88

CR4377C ,QC76246,SiM4,25 Scan 118128.24 Din.

149^

164 h • —

265L f i

-166

-a126 ' 166 ' 266

Data File: >P9B55::U2 Quant Output File: AP9B55::ULName: A4377,7,16Misc: CA4377C ,QC70246 ,S: (14,25 . 22 ,1 BTL* 5Quant Time: 900904 19:53 Quant ID File: IP0085::PFInjected at: 900904 19:06 Last Calibration: 900904 17:29

Compound No: 62Compound Name: Di-n-butyl phthaleteScan Number: 1181Retention Time: 28.24 min.Quant Ion: 149.0Area: 20748Concentration: 1.69 UG/MLq-value: 96

125

REFERENCE STANDARD SPECTRUMFil» >J7992Bpk Ab 9999.

10000-1

0-1

57 7j

»e 80

TARCET REFERENCE SPECTRASUB NRM NOM

149^v-

167

"1' 120 ' 160 ' 200

Scan 204833.28 Bin.

240 ' 28

-100

•0e

SAMPLE SPECTRUM (BPCKCROUND SUBTRACTED)File >P9855Bpk Ab 4623

4080-' 57

•

48

A4377.7.16

.. y 83 113^ 13*

80 ' 120

CA4377CSUB

149

167

' 160

,flC70246,S!M4,2S Scan 150734.87 »in.

-100

*** 279

200 ' 240 ' 280

SAMPLE SPECTRUM (UNALTERED)Fil* >P9855Bpk Ab 4623

4080-

A-

67SK

P4377,?,.

71 „_1 ' ?J jL. /

1 e'0 '

16 CA4377C

149-h** .

..'?, N .167,n

' ' ' ' 120 " ' " 160 '

,OC70246,S|H4,25 Scan 150734.87 Bin.

«? 279k j»

-100

fi200 ' 240 ' 280

Data File: >P9855::U2 Quant Output File: ~P9855::ULName: A4377,7,16Misc: CA4377C ,QC70246,S:M4,25.22,1 BTL* 5Quant Time: 900904 19:53 Quant ID File: IP0085::PFInjected at: 900904 19:06 Last Calibration: 900904 17:29

Compound No: 72Compound Name: bis(2-Ethylhexyl)phthalateScan Number: 1507Retention Time: 34.87 min.Quant Ion: 149.0Area: 11747Concentration: 2.97 UG/MLq-value: 88

126

File >P98E6 «4377,7,16Bpk Ob 9999.

~40 ' 60 ' ' 'l20

C04377C ,8078246, SiH4, 26 Scan 1432SUB NRH 33.34 Bin.

129

1B7 199212 241 284 313 341 378 fJ --*" J ff L ~ ~^ ~^. ~~-^ ~^~k*'l6e' ' 268 ' 246' 286 326 ' see'

File >BICDB Hexanedioic acid, dioctyl ester (9CI) Scan 13849Bpk Ob 9999. 0.88 Bin.

j ^-| j f"^ / 166 199212 24! 279313 341 376 [

40 80 120 160 ' 246 ' 246 ' 266

File >BICDB Hexanedioic acid, »ono (2-ethylhexyl)esterBpk Rb 9999.K 129

j 4-L. { r"~ ' \ 157 199212 241 268

*40 88 1 28 lie ' 280 ' 24*e ' 268

File >BI6DB Octane, l,l'-oxybi«- (9CI)Bpk Rb 9999.

57 71

j ^ j J 1 1/2 127.153 182 218242

48 ' 86 128 ' 166 ' 28*8 ' 24e ' 286 '

326 ' 368

(9C Scan 13856e.ee Bin.

, . ,t328 ' 368'

Scan 166228.88 Bin.

I326 ' 366

Data File: >P9855::U2Name: A4377,7,16Misc Data: CA4377C ,QC70246,S:M4,25.22,1RT (min): 33.34Scan: 1432Area: 7808578 Rank: 1Semi-quantitative Cone (uncorrected): 631.33 UG/MLSemi-quantitative Cone ( corrected ): 25033.02 ug/kgCalculated using Istd: d!2-Chrysene § 34.38 minutes

BTL* 5

*ru,PRE ,,PBR181,,,1,31. Hexanedioic acid, dioctyl ester (9CI)2. Hexanedioic acid, mono(2-ethyIhexyl)ester (9CI)3. Octane, l,l'-oxybis- C9CI)

370 C22H4204258 C14H2604242 C16H340

Sample file: >P9855 Spectrum f:Search speed: 1 Tilting option: S


1.2.3.

Prob.

87"6829*

CAS * CON #

1237954337659629823

138491385010822

ROOT K

"BIGDB 123"BIGDB 97"BIGDB 40

DK *FLG TILT * CON C_I R_IU

414879

001

1-1L

697626

132338

553010

865915

127

File >P9866 P.4377,7,16 COBpk Pb 9999. SUB

1 ^ ''20 40

Fil» >BICDB 2-PropancBpk Pb 9999.

| 2 / 26 27 39

Fil.Bpk

FileBpk

........ .^ ....... __ .

>BICBB 6u»nldin<Pb 9999.

43H 18 /] ^r" /e 4e

26 40

>BI6DB Hydropcroxid*. 1,1Pb 9999.

1] 15 25 31 39*^ \ v \ ** i'i / ri'i'l i-i i i f j . ....... . l . . . . l . . .

20 40

4377C ,QC70246.StH4,26 Sc«n 176NRM 7.76 Bin.

B9 L.66 ' 69 72 83 lft

'''' V0' ''''''' V0' ' '''''' 100

n» (9CI) Sc*n 12310.00 Bin.

63 ™ 69 t

60 ' 80 ' 100

t (8C19CI) Scan 168169 e'ee 'in-

( " f

60 ' 80 ' 100

-diMthylethyl (9CI) Scan 15910.00 Bin.

69

56 73 89 f->]t\ ^ ,- If

' 60 ' 80 ' 106

Data File: >P9855::U2Name: A4377,7,16Misc Data: CA4377C ,QC70246,S:M4,25.22,1RT Cmin): 7.76Scan: 175Area: 3391432 Rank: 3Semi-quantitative Cone (uncorrected): 135.13 UG/MLSemi-quantitative Cone ( corrected ): 5357.96 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 12.00 minutes

BTL* 5

*ru,PRE ,,PBR1B1,,,1,31. 2-Propanone (9CI)2. Guanidine (8CI9CI)3. Hydroperoxide, 1,1-dimethylethy1 C9CI)

58 C3H6059 CH5N390 C4H1002

Sample file: >P9855 Spectrum #:Search speed: 1 T i l t i n g option: S


1.2.3.

Prob.

30«25»20

CAS * CON * ROOT

67641 1231 "BIGDB113008 1581 "BIGDB75912 1591 "BIGDB

K

252036

DK #FLG TILT CON C_I R_IU

464744

021

0fli)

736254

444955

8 187 135 13

128

File >P985E H4377.7.16Bpk Rb 9999.

1 41 44

-' "'/•, vrnr

CR4377C ,eC78246,SiM4,2E ScanSUB HRH 9.88

67 82

B8 ^ 79 --" 108 181

48 68 ee iee izeFile >BICDB 2-Hexen-l-ol, (Z>- (8CI9CI) ScanBpk Rb 9999.

j 41 ""•*>8.88

67 8258 S" 79 -- 96 98 188

48 68 ' 88 ' iee ' 128

File >PIGDB Hexane, 2Bpk Rb 9999.

Or

1 29 4-L i3 ilJ...f,...:j.ir: ,.JIfr40 6

,2,3-tri«*thyl- (8CI9CI) Scan8.88

B8 71 77 8E 91 97 1J2 113 128

8 88 ' 188 ' 128

File >BI6BB Cyc 1 open tanol , 2-«ethyl-, ci«- (8CI9CI) ScanBpk Ob 9999. 8.88

67

j \" r.."r" ,." r r

236• in.

I6321• in.

I978• in.

i§361• in.

I4*e ' 68 ' e'e ' tee ' 128

Data File: >P9855::U2Name: A4377,7,16Misc Data: CA4377C ,QC70246,S:M4,25.22,1RT (min): 9.00Scan: 236Area: 3384249 Rank: 4Semi-quantitative Cone (unconnected): 134.84 UG/MLSemi-quantitative Cone ( corrected ): 9346.61 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 12.00 minutes

BTL* 5

*ru,PRE ,,PBR181,,,1,31. 2-Hexen-l-ol, (Z)- (8CI9CI)2. Hexane, 2,2,3-trimethy1- (8CI9CI)3. Cyclopentano1, 2-methyl-, cis- C8CI9CI)

100 C6H120128 C9H20100 C6H120



Prob. CAS * CON *

1. 60* 928949 53212. 20 16747254 9703. 11 25144052 5361

ROOT

'BIGDB•BIGDB'BIGDB

453535

DK *FLG TILT * CON C_I R_IU

534551

221

00

687932

155363

3052

191213

129

File >P9855 R4377.7.16Bpk fib 9999.

10080-

8880-

6880-

4888-

2888-

A.

63

|

38 68 I I

e-1— , — . t , , . , . , .48 68

File >BICDB Benzene,Bpk fib 9999.

18888-

8888-

6888-

4888-

2888-

8-

CB4377C ,0078246, SiH4, 26 Sc*n 526SUB NRH 14.91 Bin.

83

4i JB .!$V r 188' l

198/

142 144

11 119 \/ 163 /'

[._/ ,. IJ, L^ [L L

•188

•ee•68

-48

•28

•A

128 ' 148 ' 168 ' 180

l-bro»o-4-chloro- (8CI9CI) Sc«f> 23168

1

7568

36 \ 55

48 68

f

96

.r*/-|1t, „„,88 ' 188 F

8.88 Bin.192.

11

1 138 131 165 157

1 \x \x

t

I'lie' ' 'i4e ' lie' ' 'lie' 1

•188

•ee•69

•48

-28

Data File: >P9855::U2Name: A4377,7,16Misc Data: CA4377C ,QC70246,S:h4,25.22,1RT (min): 14.91Scan: 526Area: 427907 Rank: 10Semi-quantitative Cone (uncorrected):Semi-quantitative Cone ( corrected )

13.54 UG/ML537.04 ug/kg

Calculated using Istd: dB-Naphthalene § 15.82 minutes

BTL* 5

*ru,PRE ,,PBR181,,,1,31. Benzene, l-bromo-4-chloro- (8CI9CI) 190 C6H4BrCl

Sample file: >P9855 Spectrum *: 526Search speed: 1 Tilting option: S No. of ion ranges searched: 45

1.

Prob. CAS * CON * ROOT K

30* 106398 23150 "BIGDB 32

DK *FLG TILT X CON C_I R_IU

94 3 0 96 32 12 13

130

Fil* >P9866 04377,7,16 C04377C .OC78246.SiM4.25 Scan 98Bpk flb 9999. SUB NRM ' 6.83 Bin.

18888-

8888-

6888-

4888-

2888-

8-

t

39/||i ' ii' 1 1

28 "' 38 ' 48

47y

_7 7349 56 B7 72 / 88y \ / \ \

•tee«e•68

•48

28

AT- ..,,...,....,,...,....,.. .,,....,.. ,.,... -

58 68 78 88

Fll* >BICPB Propanoic acid, 2-oxo- (9CI) Scan 11Bpk Rb 9999.

18888-

8088-

6888-•

4888-

2888-

8-

43

16

.I

(

18 24 28 /' 36 48

.,(.. \',..l\... \.\,\

e.ee Bin.

46/ 62 66 68 68 69 77 88

•28 38 48

\ \ \ \/ / \ll..,llll lll..l....l..lfll...l.f..l....,..l

•188

«e68

48

28

-8

Data File: >P9855::U2Name: A4377,7,16Misc Data: CA4377C ,QC70246,S:M4,25.22,1RT (min): 6.03Scan: 90Area: 225330 Rank: 12Semi-quantitative Cone (uncorrected):Semi-quantitative Cone ( corrected ):

8.9B UG/ML355.99 ug/kg

BTLf 5

Calculated using Istd: d4-l,4-Dichlorobenzene g 12.00 minutes

*ru,PRE ,,PBR181,,,1,31. Propanoic acid, 2-oxo- (9CI) 86 C3H403



1.

Prob. CAS * CON * ROOT K DK #FLG TILT \ CON C_I R_IU

20« 127173 11 "BIGDB 26 51 1 0 81 51 5 14

131

File >P98SE R4377,7,16 CA4377C ,QC70246 ,S iH4 ,2E Se*n 379Bpk Rb 9999. SUB NRM 11.91 »in.

11000-

10000-

9080-

8000-

7880-

6080-

6800-

4000-

3000-

2000-

1000-

e-

43

42\

"**

~

87

63 *? 61 70 7? 831, .\L,l/ .,(,{ V.

40 ' 60 ' 60 ' 78 ' 88

97 183J,,,,,,,/,,,,,.',,,,,,,,.90 100 110

•lie

•188

•90

•08

•78

•68

€8

«"

•30

•20

•18

Data File: >P9B55::U2Name: A4377,7,16Mi»c Data: CA4377C ,QC70246,S:H4,25.22,1RT (min): 11.91Scan: 379Area: 190450 Rank: 13Semi-quantitative Cone (uncorrected): 7.59 UG/MLSemi-quantitative Cone ( corrected ): 300.88 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 12.00 minutes

BTL* 5


132

Fil» >P9865 04377,7,16 C04377CBpk Ob 9999.

10080-

8008-

6888-

4888-

2080-

0-

39

\

t 1

SUB HRH73

65k.~^^

41/

|.^ . . . . . .^.

Fil* >BICDB

J I'')

67

/ 68

III III,

s^

,QC78246,SiH4l25 Scan 68914.66 Bin.

88/

83

Mill' ' ' • ' - Ve • " • • • e'e'

Propane, 1-ethoxy-Bpk flb 9999.

*d

99 ' '"

, li Y,tf6lNiee ' 128

•188

•ee•68

•48

e

(9CI) Scan 69538. t8 Bin.

31 r

10088-

8888-

6000-

4000-

2000-

8-

•>x,

1.39\

69

43/

' ' " • V e 1

55

,', \-,

88

73 87 S 91

( .. . . . ^ ... . . _ ..f^^

•100

•88

«e•48

•ee-a

188 ' 128

Data File: >P9855::U2Name: A4377,7,16Miac Data: CA4377C ,QC70246,S:M4,25.22,1RT (min): 14.56Scan: 509Area: 180891 Rank: 14Semi-quantitative Cone (uncorrected ):Semi-quantitative Cone ( corrected

5.73 UG/ML227.03 ug/kg

Calculated using Istd: dB-Naphthalene § 15.62 minutes

BTL* 5

*ru,PRE ,,PBR181,,,1,31. Propane, 1-ethoxy- (9CI) 88 C5H120

Sample file: >P9855 Spectrum #: 509Search speed: 1 Tilting option: S No. of ion ranges searched: 47

1.

Prob. CAS * CON # ROOT K DK *FLG TILT * CON C_I R_IU

11" 628320 6953 "BIGDB 28 60 2 0 172 64 2 14

133

File >P98S6 «4377,7,16 CB4377CBpk fib 9999.

18800-

8880-

6808-

4060-

2800-

39\

t 1

SUB HRM

65•w_~ k

41/

I48

File >B!C£BBpk flb 9999.

3118000-

8000-

6800-

4000-

2000-

e-

^

1. \

,1 nil

67

73

/ 66

III ll66

*^

,QC78246,SlH4,

88/

83

M i l lr- ^86

Propane, 1-ethoxy-

/'.

43/

.48

65

,i, N,.

(|

r

7 "\100

(9CI)

88/

73 67

, *,V. N66 86

91

188

25 Sc*n 68914.66 Bin.

11612J.

HI! M

•188

«0

•60

•46

•26

«126

SCAD 69636.80 »ln.

•188

-88

•60

-40

•20

-a126

Data File: >P9855::U2Name: A4377,7,16hiac Data: CA4377C ,QC70246,S:M4,25.22,1RT Cmin): 14.56Scan: 509Area: 180891 Rank: 14Semi-quantitative Cone (unconnected) : 5.73 UG/tILSemi-quantitative Cone ( corrected ): 227.03 ug/kgCalculated using Istd: d8-Naphthalene § 15.82 minutes

BTL* 5

*ru,PRE ,,PBR181,,,1,31. Propane, 1-ethoxy- (9CI) 88 C5H120



1.

Prob. CAS * CON # ROOT K DK *FLG TILT * CON C_I R_HJ

11» 628320 6953 "BIGDB 28 60 2 0 172 64 2 14

133

F i l * >P985E P4377.7.16Bpk Pb 9999.

eeee-4fl 41

4eee- \X /P. Jl i ^ .^ ^Li

26 46 66

CA4377C ,QC78246,SiH4,2E Scan 665SUB NRH 17.73 B i n .

178

.9

9786 / 165 119... \ .1 / / !/

•66

•46

•e' 86 ' 166 ' 126 ' 146 166

Fi l* > B I C D B 1 ,3-Cyclop»ntan»dion», 2-broBO- ( B C I 9 C I ) Scan 21166Bpk flb 9999. 6. 66 Bin .

176, 69 ^

eeee-41 "

4AAA— S \4BB8- X

„: \\ fJ 1 ,i26 46 66

1/ 166 . oB .40 L1 / / 1J3 f |,, L ' v ** iJr r

•ee•46

A

86 166 126 146 166

F i l « > B I C D B I» id*zoC5, l - fKl ,2 ,43 tr i*zin»-2 ,7-di*«in» , 4, Scan 21391Bpk Rb 9999.

8898-<Mr \ VrV26 ' 46 66

6.66 Bin.178

X 81 9E 197 J2l 137

1 ' f" 1"^ 1 - ' ' I 1 • /• 1 '"'I • 1 • 1 • 1 •'86 166 126 146 166

•86

•46

•e

Data File: >P9855::U2Name: A4377,7,16Misc Data: CA4377C ,QC70246,S:M4,25.22,1RT (min): 17.73Scan: 66?Area: 137219 Rank: 15Semi-quantitative Cone (uncorrected): 4.34 UG/MLSemi-quantitative Cone ( corrected ): 172.22 ug/kgCalculated using Istd: dB-Naphthalene § 15.62 minutes

BTL* 5

*ru,PRE ,,PBR181,,,1,31. 1,3-Cyclopentanedione, 2-bromo- (8CI9CI) 176 C5H5Br022. Imidazo[5,l-f]tl,2,4]triazine-2,7-diamine, 4,5-dimet 178 C7H10N6

hyl- (9CI)

Sample file: >P9855 Spectrum #: 665Search speed: 1 Tilting option: S No. of ion ranges searched: 47

1.2.

Prob.

60»20»

CAS * CON *

1420324850473864

2116021391

ROOT

"BIGDB"BIGDB

3538

DK *FLG TILT J« CON C_I R_IU

8764

33

06

77100

1353

305

1313

134

Fil« >PBpk Ob

8888-

4888-

8-

Fil* >BBpk Ob

8888-

4888-

8-

Fil. >BBpk Ob

eeee-4880-

8-

9BBE 04377,7,16 C04379999. SUB HRM

(

41 43^1 /

S3

7C ,0078246, SiM4,2S Scan8.68 •

>0

69 67

, N ? J28' 48 68' ' 68 ' 188 '

ICDB Butanoic acid, 3-«9999.

t

41 43

2^ 2.9 [ 65

vE. ,1,1.. .1.1 1. ....>,,!.

•thyl- (9CI) Scan 18. 88 •

>8

'X ?8\ ??,. >!..,!. N ..1. /28 48 68 88 188

[CDB Pvntanoic ac i9999.

6

27 ^ \43 g6

!• !• ni . .'I1!')'! . i.|l| J» i...|ni|i|'ii . , , . , . . . , , , . . , , . . . . . . ,

d (9CI) Scan 18. 88 •

8

69 74 63 8/ 92 lel

20 48 68 88 188

215in.

ee•48

668in .

«e

-48

-8

866in.

ee-48

-8

Data File: >P9855::U2Name: A4377,7,16Misc Date: CA4377C ,QC70246,S:M4,25.22,1RT (mm): 6.58Scan: 215Area: 133095 Rank: 16Semi-quantitative Cone (uncorrected ) :Semi-quantitative Cone ( corrected ):

5.30 UG/ML210.27 ug/kg

BTL* 5

Calculated using Istd: d4-l,4-Dichlorobenzene § 12.00 minutes

#ru,PRE ,,PBR181,,,1,31. Butanoic acid, 3-methyl- (9CI)2. Pentanoic acid (9CI)

102 C5H1002102 C5H1002



1.2.

Prob.

7060

CAS * CON

503742109524

18681866

ROOT

'BIGDB'BIGDB

K

5443

DK *FLG TILT \ CON C_I R_IU

4345

22

8792

613

4230

1514

135

FiU >P9855 04377,7,16Bpk Pb 9999.

1 V .5

26 46

File >BICDB HexanoiBpk Rb 9999.

J 41

Lr•if j .I26 46

File >BICBB UrBpk Rb 9999.

38 44, / -^^

j 18 45

26 46 '

File >BICDB HydrazinBpk flb 9999.

H 29 44 *5

e ,..,...i|i|., ...ynjlTr,..'26 46

CP4377C ,QC78246,SiH4,26SUB HRh7i. 86

J* 83^ f 181 118^16 i

66 88 168 126

c acid, 2-»thyl- (BCI9CI)73 88

57 ^ (f 63 181 116

66 ' 88 ' 188 ' 128

»a, ethyl- C8CI9CI)

73 go

^56 1 77 f 89

68 ' 86 ' 188 ' 126

e, 1-butyl-l-ethyl- (9CI)73>

66 181 llfe

66 86 188 126

Scan14.64

28 129

'''"•i4eScan8.86

129 145

146

Scan6.66

146

Scan 1e.ee

•P— •

146

513• in.

I7626• in.

I6952• in.,

t

1721• in.

I

Data File: >P9855::U2Name: A4377,7,16Misc Data: CA4377C ,QC70246,S:M4,25.22,1RT Cmin): 14.64Scan: 513Area: 131563 Rank: 17Semi-quan t i ta t i we Cone (uncorrected): 4.16 UG/tILSemi-quantitative Cone C corrected ): 165.12 ug/kgCalculated using Istd: dB-Naphthalene § 15.82 minutes

BTL* 5

*ru,PRE ,,PBR1B1,,,1,31. Hexanoic acid, 2-ethyl- C8CI9CI)2. Urea, ethyl- (8CI9CI)3. Hydrarine, 1-buty1-1-ethy1- C9CI)

144 C8H160288 C3H8N20116 C6H16N2



Prob. CAS *

1. 83 1495752. 42« 6255253. 20» 52728560

CON *

70266952

11721

ROOT

"BIGDB"BIGDB"BIGDB

K

662238

DK

337944

*FLG

222

TILT

0J]0

*

7112889

CON

32555

c_i57175

R_IU

231319

136

Fil.Bpk

Fil*Bpk

Fil*Bpk

FileBpk

>P985S 04377,7,16 CP4377C .QC78246 ,S |H4 ,25 Scan 432Pb 9999. SUB HRM

-j 41 63

40 60 80

12.99 Bin.109

t97 123 I24 127 t

100 ' 120 ' 140

>BICDB Cyclohvxanol , 3 ,3 ,5-tri«»thyl- (8CI9CI) Scan 18387fib 9999.

1 29 4^ 43 55 67 7l *?

40 60 80

109 <»•<"> »in.

IM r97 123 I?4 146 Ist(rjr') ,, j.,. irr, r i-Mf100 120 140

>BICDB BicycloCE.l .83oct*ne (8CI9CI) Scan 5369fib 9999.

j 41 54 / 82

40 60 80

0.80 Bin..

l£m [180 ' 120 ' 140

>BICIB Cyclop»ntan», (2-»ethylpropyl )- (9CI) Scan 5415Rb 9999. 8.80 «in.

, \ 56 6' 831 27 1 43 ( | ,„ /\f K 1 i |U^ 1 91

Jj^ —— l,llL.,....lll.,M....ll ——— rW40 60 88

98 HI 126 128 [

180 120 ' 140

Data File: >P9855::U2Name: A4377,7,16tlisc Data: CA4377C ,QC70246,S:M4,25.22,1RT (min): 12.99Scan: 432Area: 127466 Rank: 18Semi-quantitative Cone (uncorrected): 5.08 DC/MLSemi-quantitative Cone ( corrected ): 201.38 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene @ 12.00 minutes

BTL* 5

*ru,PRE ,,PBR181,,,1,31. Cyclohexanol, 3,3,5-trimethyl- (8CI9CI)2. Bicyclo[5.1.0]octene (8CI9CI)3. Cyclopentane, (2-methyIpropy1)- (9CI)

142 C9H180110 C8H14126 C9H18



1.2.3.

Prob.

8931«27»

CAS *

1160292864313788327

CON *

1038753695415

ROOT

"BIGDB"BIGDB"BIGDB

K

1034843

DK

93645

*FLG

122

TILT

0:2^

*

741816

CON

54443

C_I R_IU

66128

762215

137

#~lia

61:02 S06006 : ** pa*oatu i<iS:60 906006 :

:QI

906006 :

PI

0003

a.i3

29

Q T ^ T Q

?

!

ii

0091 003T 888Oil

08*

•n«w 8'88S-9'Se

:9

-eee00a

000009

-0000081

-08080ZI

-8888891

-0800881

HOI

QUANT REPORT

Operator ID: KU0786Output File: /"P9874::ULData File: >P9874::U3Name; A4377,7,16Misc: CA4377C ,QC70246,S:M4,25.22,1

Quant Rev: 7 Quan t Time:Injected at

Di1ution Fac tor:

Page 1

900906 09:57900905 20:19

1. 00000

BTL# 4

ID Fjle:T i t l e : IFB/BNA,Last Calibration:

IPOOB5::PFPP/BNA, TCLBN1900906 09:54

Compound R.T. Scan* Area Cone Un i ts

1 )2)3)5)6)12)14)15)17)18)26)32)36)49)50)52)54)62)65)66)67)72)73)

*d4- 1 ,4-Dich lorobenzeneN-Ni t rosod imethylamine2-Fluorophenol (SURR)Phenol-05 (SURR)Pheno 1N-Nitrosodi-n-propylamine2-Me t hy Ipheno 14-flethylpheno 1

»d8-Naphtha leneNitrobenzene-05 (SURR)Benzo i c acid

*dlO-Acenaphthalene2-Fluorobiphenyl (SURR)Diethyl phthalateF 1 uo rene2 ,4, 6-Tr ibromopheno 1 (SURR)*dlO-PhenanthreneDi-n-butyl phthalate

»dl2-Chrys>eneBenz id ineTerphenyl-D14 (SURR)bis(2-Ethylhexyl)phthalate*d!2-Perylene

11.4.8.

11.11.13.13.13.15.13.15.21.19.22.23.23.25.28.34.25.31.34.38.

9282853335674343776740302999838191172991128059

379302283503514654534535684655508407419239649631066117714781066132215031689

21481640843691638M1088170

140518274121522152

77174153507112077

375518866257

24819526

181350584262320163151717345470913416368230034

40-7

96119

*

••J. -4

.-

.-

40673

4063

9240240

1 O f.

62240

.00CO

• -f *.

.75

.79

. 61-• L> 4.

* 8-OTJ-7•"• ' '

. 00

.71

.34

.00

.662-H-U X U.51. 00. 17.00D ni B U

.65

.61

. 00

UG/MLi ir* ^MILJI_ i IL_

UG/ML—UG/ML—-BG^ML-WS/ML-yG/ML1 If"1 '"MlLJLJ 1 IL_

UG/MLUG/ML-UG^hL—UG/fILUGXMI^

-W6-/MLUG/MC'UG^MLUG/ML-UG^MLI If^ r^M!

UG/Mt-UG/ML —UG/T1L

871008692713689999492929997978696989797100899184

* Compound is ISTD

139

ETC

STANDARDS DATA

140

6BSEMIUOLATILE ORGAN ICS INITIAL CALIBRATION DATA

Lab Name:ETCNJ Contract:__________

Lab Code: Case No.:____ SAS No.: SDG No.:

Instrument ID:GC/MS P Ca l i b r a t i o n Date(s) 08/25/90' 08/25/90

Mm RRF for SPCC(#) - 0.050 Max XRSD for CCC(«) « 30.0

LAB FILE ID:RRF80 ->P9714

RRF20 'RRF120'

= >P9716= >P9713

RRF50 ->P9715RRF160=>P9712

I1 11 COMPOUND IRRF20

IPhenol * 1.375Ibis(2-Chloroethyl )ether 1 1.31112-Chlorophenol 1 1.4331 1 .3-Dichlorobenzene 1 1.4851 1 .4-Dich lorobenzene * 1.516IBenzvl alcohol 1 1.0241 1 ,2-Dich lorobenzene 1 1.55812-Methvlohenol 1 1.065Ibis(2-Chloroisopropyl ) e t her 1 .33114-Methvlphenol 1 1.275IN-Nitroso-di-n-propylami ne_# .9211 Hexach 1 oroe thane 1 .6591 Ni t robenzene 1 .3511 Isoohorone 1 . 7281 2-Ni t ropheno 1 * .19112 ,4-Dimeth<jlpheno 1 1 .3491 Benzo ic ac id 1 . 130Ib is (2-Ch loroe thoxy ) me t hane_l .3591 2 .4-Dich loropheno 1 « .2991 1 ,2 ,4-Tr ich lorobenzene 1 .363(Naphthalene 1 1.02014-Ch loroan i 1 me 1 .360IHexach lorobutad iene « .2331 4-Ch loro-3-methylpheno 1 ____ * .27912-Methvlnaphthalene 1 .5501 Hexach lorocyc lopentad iene _ # .31812 .4.6-Tr ichlorophenol » .37112 .4.5-Tr ichlorophenol 1 .3881 2-Ch loronaphtha lene 1 1.20412-Nitroani 1 me 1 .2851 Dimethvlphtha late 1 1.4841 Acenaphthvlene 1 1.8321 2 .6-Din i t roto luene 1 .28413-Nitroani 1 me 1 .2421 Acenaph thene * 1.2041 2 .4-Dm 1 1 ropheno 1 * .08314-Nitrophenol * .0881 1

RRF50

1.3531.2621.3751.3821.4341.0241.3901.201.413

1.201.884.554.334.690. 193.329.153.341.280.324.907.352.194.259.511.376.381.392

1.170.285

1.3261.746.286.226

1.125. 092. 080

RRFBO

1.3581.2401.3801.3401.3921. 0401.2951. 098.394

1. 098.866.507.330.637.197.316.165.320.288.324.772.345. 190.260.495.410.399.408

1.208.315

1.3531.633.308.248

1. 131.137.086

1RRF120 IRRF160= = = ««=«= )..====1.2571 1.2091.2021 1.0101.3061 1.3351.311 1 1.3101.3621 1.2281.0341 .9461.3071 1.2761.1721 1.142

.3161 .3751.1721 1.142.8791 .852.5291 .538.3211 .328.5541 .480.1981 .209.3101 .317.1521 .153.3251 .322.2601 .264.3141 .321.6741 .587.3341 .345.1821 .175.2551 .270.4641 .452.4231 .404.4091 .406.4161 .407

1.2001 1.147.333! .351

1.3511 1.2541.4291 1.269.3341 .333.2691 .281

1.1161 1.049.1561 .167.0891 .090

1

RRF

1.3111.2051.3661.3661.3861.0141.3651.136.366

1. 178.880.557.333.618.197.324.150.333.278.329.792.347.195.265.494.386.393.40?

1. 186.314

1.3541.582.309.253

1.125. 127.087

\ 1RSD !

= = = = = |5.6*9.613.5 15.417.6*3.818.514.8 1

11.315.613.0*

10.613.41

16.3 13.5*4.718.514.9 16. 0*5.9 1

22. 0 12.8 111.6*3.6*7.91

10.9*4.2*2.912.219.3 16. 1114.6 17.9 18.614.9*29.8*4.6*

1FORM UI SU -1 1/87 Rev.

141

6CSEMIUOLATILE ORGAN ICS INITIAL CALIBRATION DATA



Instrument ID:GC/MS P Cali b r a t i o n DateCs) OB/25/90 08/25/90

Min RRF for SPCC(#) - 0.050 Max HRSD for CCC(«) 30. (

I LAB FILE ID:IRRF60 ->P9714

RRF20 =>P9716RRF120=>P9713

RRF50 ->P9715RRF160=>P9712

I

!I COMPOUND

I D i benzo f uran1 2 .4-Din i t roto luene1 Diet hvlphtha latel4-Chlorophenyl-phenylether_1 F 1 uorene14-Nitroani 1 mel4,6-Dinitro-2-methylphenol_1 N-N i t rosod ipheny 1 am i ne ( 1 )_*1 4-Bro mo pheny 1 -pheny let her __1 Hexach lorobenzene1 Pen t ach loropheno 1 *1 Phenan t h rene1 An t hraceneIDi-n-butvlphthalate1 F 1 uo r an t hene *1 PvreneIButvlbenzvlphthalate13 ,3 '-DichlorobenzidineIBenzo(a)anthracene1 Ch r vseneIbis(2-Ethylhexyl )phthalate_1 Di-n-ocfolphtha late *1 Benzo (b ) f luoranthene1 Benzo (k ) f luorantheneIBenzo(a)pvrene *1 Indeno ( 1 ,2 ,3-cd )pyrene _____IDibenzCa th)anthracene1 Benzo (q ,h f i Jperylene

1 Ni t robenzene-d51 2-F luorob iphenul! Te rphenv 1 -d!4IPhenol-d512-Fluorophenol12 ? 4 F 6-Tr i br o mop he no 11

RRF20

1.529.369

1.352.556

1.139. 171. 116

* .544.231.288

* . 115.993

1.0051.345

* .876.884.751. 180

1. Ill.972.920

1.6891.3251. 129

• .969.807.568.700

.3411.3381.2371.4791.300. 171

RRF50

1.427.362

1.231.511

1. 026. 191. 130.540.225.277. 116.971.961

1.280.791.779.773.273

1. 074.971.896

1.7411.2231.3081. 036.828.590.703

.3331.2721.3011.4341.164. 156

1RRF80 IRRF120

1.5101 1.390.4161 .441

1.2391 1.211.5301 .531

1.0591 1.054.2361 .263.1441 .153.5161 .504.2201 .207.2631 .256.1201 .117.9471 .907.9711 .886

1.1091 .942.7951 .768.7691 .736.7901 .799.3171 .330

1.1241 1.100.9731 .940.9581 .950

1.7671 1.6931.2761 1.3491.1661 1.0571.0711 1.058.9631 1.013.6891 .731.8241 .862

.3381 .3381.2671 1.1981.3231 1.3331.4481 1.4451.1341 1.140.1711 .182

1

RRF160

1.268.461.991.495

1. 046.284. 154.449.213.253. 121.849.783.791.728.720.896.338

1. 1971. 0021.0391.7501.4421. 1531.111.980.707.846

.3441. 1131.5061.3191. 174.185

RRF

1.425.410

1.205.524

1. 065.229.139.511.219.267. 118.933.921

1. 093.792.777.802.288

1. 121.972.953

1.7261.3231. 1621. 049.918.657.787

.3391.2381.3401.4251. 182.173

\ 1RSD 1

»«» 17.4110.7!10.914.414. 1 1

20.7111.7!7.5*4.315.5 !2. 1*6.119.6 1

21.1 16.8»8.3 17.01

22.714. 1 12.2 15.712.0-6.217.9 15. 0*10.2 111. 1 110.1 1

1.2 16.917.5 14.3 15.716.61

1

(1) Cannot be separated from Dipheny1 amineFORM UI SU -2 1/87 Rev.

142

TOTflL ION CHKOnflTOeRBH

58888-

File >P?716 35.0-900.8 aau.

688888- -"

688888-

088888-

588888-

408888-

488888-

308888-

388888-

858888-

888888-

158888-

1888IFB-'BNH 28 PPtl

1688 8888

6? i -

" itlil r.24 88 38 36 48 44 48

Data File: >P9716::U5Name: SSTD20Miac: IFB/BNA 20 PPM

Id File: IP0085::PFT i t l e : IFB/BNA. PP/BNA, TCLBN1Last C a l i b r a t i o n : 900823 17:10

Operator ID: KU0796Quant Time: 900825 19:21I n jec ted at: 90082? 18:30

Quant Output File: AP9716::UL

BTL* 6

143

QUANT REPORT Page 1

Operator 10: KU0786Output File: ~P9716:»ULOata File: >P9716::U5Name: SSTD20rtisc: IFB/BNA 20 PPM


Compound

Quant Rev/: 7 Quant Time:In jected at:

Di lut ion Factor:

900825 19:2190082? 18:30

1.00000

BTL* 6


1)2)2)3)4)5)6)7)8)8)8)9)9)9)10)10)10)11)12)13)14)15)16)16)17)18)19)19)20)21)21)22)23)24)25)26)27)27)28)29)30)31 )31 )

•d 4-1, 4-Dich lorobenzeneN-Nitrosodi methyl am meN-Ni trosodimethylamine2-Fluorophenol (SURR)b is (2-Ch loroe t hyl ) etherPhenol -05 (SURR)Pheno 12-Chlorophenol1.3-Dich lorobenzene1,3-Dich lorobenzene1 . 3-Dieh lorobenzene1 , 4-Dich lorobenzene1 .4-Dich lorobenzene1 , 4-Dich lorobenzene1.2-Dich lorobenzene1 ,2-Dich lorobenzene1 ,2-Dich lorobenzeneBenzyl alcoholN-Nitrosodi-n-propylamineHexach 1 o roe thane2-Me t hylpheno 14-Me thy Ipheno 1b is (2-Ch lore isopropyl )etherbis(2-Chloro isopropyl )ether

*d8-NaphthaleneNitrobenzene-05 (SURR)Nit robenzen*Ni t robenzena- i .Isophorone SSte"-2-Ni t rophenaJHHT2-Ni t ropheno^R^^2 ,4-Di methyl phenolb is (2-Ch lo roe thoxy)aie thane1 ,2 ,4-Tr ich lorobenzene2 . 4-Dich loropheno 1Benzoic acidNaphtha laneNaphtha lene4-Ch loroan i 1 ineHexach lorobutadiene2 -Methyl naphtha lenep-Ch loro-m-creso 1p-Ch loro-m-creso 1

12.345.185.228.9211.7711.6111.6511.8312.2212.3812.9112.2212.3812.9112.2212.3812.9112.8913.8013.8413.3613.8013.4013.8416.2014.0713.4414.1114.8614.8615.1115.3915.6716.1015.8615.8215.8616.2516.5316.9218.4219.4419.54

3732123205345337339348367375401367375401367375401400445447423445425447563458427460497497509523537558546544546565579598672722727

14000153895391290998M9177510351896260100292103970106100109084103970106100109084103970106100109084716966 4476 M46106745 74M8928 OM2315314634476352812189969836041735073417454628304085431864997130330859113205

24285885839M5557013107327192894

40.00 UG/ML42.45 UG/ML3.08 UG/ML20.25 UG/ML20.12 UG/ML19.08 UG/ML17.30 UG/ML19.51 UG/ML20.45 UG/flL20.87 UG/ML21.46 UG/ML19.69 UG/ML20.09 UG/ML20.66 UG/ML18.90 UG/ML19.29 UG/ML19.83 UG/ML33.56 UG/ML15.84 UG/ML19.11 UG/ML19.67 UG/ML27.18 UG/ML15.64 UG/ML9.89 UG/ML40.00 UG/ML16.71 UG/ML1.96 UG/ML16.42 UG/ML19.15 UG/ML1.25 UG/ML16.67 UG/ML18.43 UG/ML16.37 UG/ML19.61 UG/ML18.67 UG/ML17.31 UG/ML.273 UG/ML

20.66 UG/ML- 18.86 UG/ML18.86 UG/ML

>20.05 UG/ML.921 UG/ML.980 UGJKML

90100100

8494869891868799969798969785

92

1001009594737593618794879495

8790

9885100100

144

QUANT REPORT Page

Operator ID: KU0786Output File:Data File:Name: SSTD20Misc: IFB/BNA 20 PPM

Quant Rev: 7

>P9716::U5

Quant Time:In jected at:

Di lut ion Factor:

900825 19:2190082? 18:30

1.00000

5TL* 6

ID Fila: IP0085::PFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900823 17:10

Comoound R.T. Scan# Area Cone Un»ts

31)32)33)34)34)35)35)36)37)37)38)39)40)41)41 )42)43)44)45 )46)'<7 )"' ix t47)48)49 )50)51)51)52)53)54)55)56)56)57)58)59)60)£,0)61)61)62)63)

p-Chloro-m-cresol*dlO-Acenaphtha leneHexach lorocyclopentadiene2,4,6-Trichlorophenol2,4,6-Trichlorophenol2,4,5-Trichlorophenol2.4,5-Trichlorophenol2-Fluorobiphenyl (SURR)2-Chloronaphthalene2-Chloronaphthalene2-Ni t roan i 1 ineDimethyl phthalateAcenaphthy lene2.6-Oinitrotoluene2,6-Dinitroto luene3-Ni t roan i 1 ineAcenaph t hene2,4-DinitrophenolDibenzof uran2,4-Dinitrotoluene4-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 14-Ni t roan i 1 ineDiethyl phthalateF 1 uorene4-Ch lorophenyl phenyl ether4-Ch lorophenj*^ phenyl ether2,4,6-Tribroipfkhanol (SURR)1 . 2-DiphenymBgiraz ine

•d!0-Phenanth«*SRe4,6-Dini t ro-o-creso 1N-Ni trosodiphenylanvineN-Nitrosod ipheny lamina4-Bromopheny 1 phenyl etherHexach lorobenzenePentachlorophenolPhenanthrenePhenanthreneAnthraceneAnthraceneDi-n-butyl phthalateFluorant hene

18. 1621.7619. 1919.4419.5419.4419.5419.7019.4419.9320.4021. 1721.2521.3322.5321.7021.8622.0222.3522.5323.4523.5323.9423.6323.4523.4523.2423.5324.2624.0226.3823.8123.5323.9425.0325.4426.0326.4626.5326.4626.5828.6330.22

659836710722727722727735722746769807811815874833841849865874919923943928919919909923959947106393792394399710171046106710731067107311741252

66355M24318638647450974721245097472121626895090

146347346301804332227913451444868294171463661005418595444868107154329318720823M1643841384885289675652075412937333632619452723291459389154840719262167010168964167010168964226149147332

22.47 UG/ML40.00 UG/ML10.90 UG/ML16.61 UG/ML17.39 UG/ML18.66 UG/ML19.54 UG/ML17.43 UG/ML.604 UG/ML

17.38 UG/ML16.61 UG/ML23.03 UG/ML19.24 UG/ML19.38 UG/ML25.20 UG/ML22.31 UG/ML19.18 UG/ML21.25 UG/ML19.06 UG/ML24.40 UG/ML20. 19 UG/ML8.16 UG/ML6.01 UG/ML29.88 UG/ML25.33 UG/ML20.05 UG/ML1.58 UG/ML20.24 UG/ML19.42 UG/ML17.41 UG/ML40.00 UG/ML17.81 UG/ML1.53 UG/ML

19.36 UG/ML15.21 UG/ML15.08 UG/ML27.23 UG/ML18.71 UG/ML18.93 UG/ML19.07 UG/MLJ.9.29 UG/ML27.04 UG/ML26.04 UGf'ML

1009697959893999956968895987979100971008992100100100

939697889782988178969299929.y^'97969696

145

QUANT REPORT

Operator ID: KU0786Output File: ~P9716::ULData File: >P9716»:U5Name: SSTD20Misc: IFB/BNA 20 PPM


Di lut ion Factori

Page 3

900825 19:21900825 18:30

1.00000

BTL* 6

ID Fi le: IP0085::PFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900823 17:10


63)64),5)66)67)66)69)69)70)70)71)72)73)74)75)75)75)76)76)76)"•7)/7)78)79)80)

FluoranthenePyrene•d!2-ChryseneBenz id ineTerphenyl-D14 CSURR)Butyl benzyl phthalateBe nzo (a) anthraceneBenzo(a)anthraceneChryseneChrysene3 .3 '-Dlchlorobenzidinebis (2-Ethylhexyl ) phthalate

•d!2-PeryleneDi-n-octyl phthalateBenzo (b ) f luorantheneBenzo (b)f luorantheneBenzo (b)f luorantheneBenzo(k)fluorantheneBenzo (k ) f luorantheneBe nzo (k ) f luorantheneBenzo (a)pyreneBenzo (a)pyreneIndeno (1,2 ,3-c ,d )pyrenebibenzo(a,h)anthraceneBenzoCghi )perylene

30.30.34.26.31.33.34.34.34.34.34.35.39.37.37.38.38.37.38.38.38.38.43.43.44.

91918003563174887488762719109907999907990799284046

1286128614771046131814041474148114741481147515001693159016341638168316341638168316381683189419001952

1486711486711719533626

106337645879555383575955538357515475790771013848563BM6714857209491226714857209491225720949122409102878735501

26.27.40.2.14.20.20.17.20.18.25.23.40.19.22.19.16.23.19.17.20.17.17.17.16.

27980004487342869835014400668244693791107683041831

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

9797981009397100100100100869082998889899192929191100100100

* Compound is ISTD

146

TOTAL ION>PO?15 35.B-900.0 «*u. |fJD8i

«M

Data File: >P9715::U5Name: SSTD50Misc: IFB/BNA 50 PPM

Id File: IP0085::PFT t t l e : IFB/BNA, PP^BNA, TCLBN1Last Calibration: 900623 17:10

Operator ID: KU0786Quant Time: 900827 09:31Iniected at: 900829 17:32


BTL* 5

147

QUANT REPORT Page

Operator ID:Output File:Data File:Name: SSTD50Misc: IFB/BNA 50

KU0786

>P9715::U5

PPM

Quant Rev: 7 Quant Time:In iected at:

Dilut ion Factor:

900827 09:31900825 17:32

1.00000

BTL* 5



1)2)2)3)4)5)6)7)8)8)8)

. 9)9)9)10)10)11)12)12)13)14)15)15)16)16)17)18)19)19)19)19)20)21)21)22)22)23)24)25)26)27)27)28)

*d 4-1 ,4- Dich lorobenzeneN-Ni t rosod i me thy lamineN-Ni t rosod i me thy lamine2-Fluorophenol (SURR)b is(2-Ch loroethvl ) etherPhenol -05 ' (SURR)Pheno 12-Ch loropheno 11 ,3-Dich lorobenzene1 ,3-Dich lorobenzene1.3-Dich lorobenrene1 ,4- Dich lorobenzene1 ,4- Dich lorobenzene1 ,4-Dich lorobenzene1 .2 -Dich lorobenzene1 ,2-D ich lorobenzeneBenzyl alcoholN-Nitrosod i-n-propy lamineN-Ni t rosod i-n-propy lamineHexach 1 or oe thane2-Methy Ipheno 14-Methy Ipheno 14-Me thy Ipheno 1bis(2-Chloro i sop ropy 1 )etherbis(2-Chloro i sop ropy 1 )ether•dB-NaphthaleneNitrobenzene-05 (SURR)Ni t robenzenaNi t robenzenaNi t robenzenaNi t robenzenaIsophorone2-Ni t ropheno 1 f2-Ni t ropheno 12 ,4-Dime thy Ipheno 12 ,4-Dime thy Ipheno 1b is (2-Ch loroethoxy) me thane1 ,2 ,4-Tr ich lorubenzene2 .4-0 ich loropheno 1Benzoic acidNaphtha laneNaphtha lane4-Ch loroani 1 ina

12558111111111212121212121212121314131313131313161413131314141415151615161516151615

.35

.19

.25

.93

.80

.63

.68

.84

.23

.41

.94

.23

.41

.94

.41

.94

.92

.85

.10

.85

.83

.39

.83

.41

.85

.21

.10

.39

.47

.83

.16

.91

.91

.11

.42

.11

.70

.11

.89

.01

.89

.28

.89

3742225206347339341349368377403368377403377403402448460448447425447426448564460425429447463500500510525559539559548554548567548

1440991319013861

2095982272432583392437702476162489062583712503122489062583712503122583712503121843661593123465599787216268172221216268743143060353208322141010427625033651532222314587228936

1282162191282714

2268262153571864331014898908

6030502961

401002

4548464246474947454746454483388405550634820404018411394524243.

384343

. 50.

3* 45.

.00

.94

.95

.31

.40

.26

.57

.81

.57

.37

.83

.80

.54

.05

.63

.21

.83

.02

.27

.19

.43

.94

.97

.77

.08

.00

.79

.34

.40

.46

.08

.34

.93

.10

.54539.90.71.71.96678.92583

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUGVML

911001007385918496878888979897999788823889876097100100949361695184975881946884939991888961

148

QUANT REPORT Pag*

Operator ID: KU0786Jut put File: "-P9715JData File: >P9715:Name: SSTD50Misc: IFB/BNA 50 PPM

ID Fi le: IP0085::PFT i t l e : IFB/BNA, PP/BNA. TCLBN1Last Calibration: 900823 17:10

Compound

Quant Rev: 7 Quant Time:In jected at'

Di lut ion Factor

900827 09:31900825 17:32

1.00000

BTL* 5


2B)28)?9)30)31)32)33)34)34)35)35)36)37)37)37)38)39)39)40)41)U)42)42)43)44)45)46)47)47)47)47)47)48)49)50)50)51)51)52)53)54)55)56)

4-Ch loroan i 1 ine4-Ch loroan i 1 ineHexachlorobutadiene2-Methylnaphthalenep-Ch loro-m-creso 1

•dlO-AcenaphthaleneHexachlorocyc 1 open tad iene2,4,6-Trichlorophenol2,4,6-Trich loropheno 12,4,5-Tnchlorophenol2,4,5-Trichlorophenol2-Fluorobiphenyl (SURR)2-Chloronaphthalene2-Chloronaphthalene2-Chloronaphthalene2-Ni t roan i 1 ineDimethyl phthalateDimethyl phthalateAcenaph thy lene2,6-Dinitrotoluene.2 ,6-Din i t roto luene3-Ni t roan i 1 ine3-Ni t roan i 1 ineAcenaph thane2 ,4-Dini t ropheno 1Dibenzof uran2 ,4-Dini t rotoluvne4-N 1 1 rophano bt*.4-N i t rophenalfe :4-Nitrophenatjr^p4-Ni t ropheno IT •"4-Ni t ropheno 14-Ni t roan i 1 ine (Diethyl phthalateFluoreneFluorene4-Ch lorophenyl phenyl ether4-Ch lorophany 1 ph-jnyl ether2 ,4,6-Tr ibromophenol (SURR)1 ,2-Dipheny Ihydraz ine

•dlO-Phenanthrene4,6 -Din i t ro-o-cresolN-Ni t rosod ipheny lamina

16.2816.5616.9318.4318.1721.7719.2119.4519.5519.4519.5519.7419.4519.5519.9620.4121.2022.4021.2621.3622.5621.7322.3821.8722.0422.3822.5623.2623.4623.5423.6823.9523.6823.4823.4624.2823.2623.5424.2824.0326.3923.8523.54

5675815996736608377117237287237287377237287487708098688128178768358678428508678769109209249319449319219209609109249609481064939924

78152234294129323339735172399252476118609120243123815120243123815401510131324228

3692578998641841511322

55112990140114122712853718

35513929160450422114122209925258105384587667360261M388570323786285913965161321493563614753216545216417820

15.38 UG/ML46.10 UG/ML39.30 UG/ML46.53 UG/ML52.27 UG/ML40.00 UG/ML32.23 UG/ML42.67 UG/ML43.93 UG/ML47.93 UG/ML49.36 UG/ML41.44 UG/ML1.50 UG/ML.484 UG/ML

42.23 UG/ML41.58 UG/ML51.45 UG/ML1.39 UG/ML45.85 UG/ML48.76 KG/ML61.73 UG/ML52.08 UG/ML2.72 UG/ML44.83 UG/ML59.35 UG/ML44.46 UG/ML59.78 UG/ML3,81 UG/ML45.85 UG/ML19.13 UG/ML8.33 UG/ML12.11 UG/ML83.28 UG/ML57.68 UG/ML45 . 16 UG/ML.399 UG/ML4.03 UG/ML46.54 UG/ML44.48 UG/ML

. 46.86 UG/ML40.00 UG/ML

> 49.94 UG/ML3.94 UG^ML

7262958210096989796969599576097809897977979100100961009291100100100100100

92987599909584987277

49

QUANT REPORT Paga 3

Operator ID: KU0786Output File:Data File:Name: SSTD50Misc: IFB/BNA 50 PPM

Quant

>P9715»:U5

7 Quant Time:In iactad at:

Dilution Factor:

900827 09:31900825 17:32

1.00000

BTL* 5



56)57)58)59)60)60)61)61)62)63)63)64)65)66)67)66)69)69)70)70)71)72)73)74)75)75)75)76)76)76)77)77)77)78)79)80)

N-Ni trosodiphenylamine4-Bromopheny 1 phenyl etherHexach lorobenzenePentach loropheno 1PhenanthrenePhenan t hreneAnthraceneAnthraceneDi-n-butyl phthalateFluorantheneF 1 uorant henePyrene•d!2-ChryseneBenz id ineTerphenyl-D14 (SURR)Butyl benzyl phthalateBenzo (a ) anthraceneBenzo (a ) anthraceneChryseneChrysene3 ,3 ' -Dich lorobenz id inebis(2-Ethylhexyl ) phthalate•d!2-PeryleneDi-n-octyl phthalateBenzo (b )f luoran thaneBenzo (b ) f luoran thaneBenzo (b ) f luoran thaneBenzo (k ) f luorawthaneBenzo (k ) f luoi |i|heneBenzo (k ) f luo«*£itheneBenzo (a )pyraiwFrBenzo (a)pyrenaBenzo (a )pyrene fIndeno(l,2,3-c,d )pyrenaDibenzoCa.h ) anthraceneBenzoCghi )perylene

23.25.25.26.26.26.26.26.28.30.30.30.34.26.31.33.34.34.34.34.34.35.39.37.38.38.39.38.38.39.38.38.39.43.43.44.

950546054760476063249393790558337587758777281911010700010700010700293947

944998

1018104710681074106810741174125312871287147710471319140514751481147514811476150116931591163516381684163516381684163516381684189519001953

2172979046511137746808390452386361390452386361514481318031313065313065135054

84912196541304981812491639771812491639774614815120169242150675M105861113174896601058611131748966010586111317489660716665105860808

48363669454546466458576140638534944504594574050525644535745566047434440

.10

.98

.27

.19

.74

.26

.61

.12

.31

.77

.85

.62

.00

.08

.09

.32

.33

.63

.68

.85

.94

.07

.00

.64

.67

.31

.61

.95

.68

.69

.26

.15

.65

.72

.60

.90

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

96909897979896999596969898100929010010010010085958198909190949493929392100100100

* Compound is ISTD

150

TOTflL ION CH*OHBT00*fln>P9714 33.0-300.0 MU

400 . 000 1200

iFB'BNn1600 3000

32 36 40 44 40

Data File: >P9714::U5Name: SSTD80disc: IFB/BNA 80 PPM

Id File: IP0085::PFTitle: IFB/"BNA, PP/BNA, TCLBN1Last Calibration: 90082? 17:10

Operator ID: KU0786Quant Time: 900827 09:28Injected at: 90082? 16:33


BTL* 4

151

QUANT REPORT Page

Operator ID: KU0786Output File: "P9714::ULData Fila: >P9714::U5Name: SSTD80Misc: IFB/BNA 80 PPM

ID Fila: IP0085::PFTitle: IFB/BNA. PP/BNA, TCLBN1Last Calibration: 900823 17:10

Compound

Quant Rev: 7 Quant TimeiIn iected ati

Dilut ion Factor:

900827 09:28900825 16:33

1.00000

BTL* 4


1223456788a999

10101112121213141515151616171819191920212122222 >2324252626

)))))))))))))))))))))))))))))))))))))))))))

*d4-l ,4-Dich lorobenzeneN-NitrosodimethylamineN-Ni trosodi me thy lamina2-Fluoroohenol (SURR)bis(2-Chloroethvl ) etherPhenol-05 ' (SURR)Pheno 12-Ch loropheno 11, 3-D ich lorobenzene1,3-0 ich lorobenzene1,3-Dich lorobenzene1 .4-0 ich lorobenzene1 , 4- D ich lorobenzene1 ,4-Dich lorobenzene1 ,2-Dich lorobenzene1 ,2-Dich lorobenzeneBenzyl alcoholN-Nitrosod i-n-p ropy laminaN-Ni trosodi-n-propylamineN-Ni trosodi-n-propy laminaHexachloroethane2-Me thy Ipheno 14-Me t hy Ipheno 14-Me thy Ipheno 14-Me thylpheno 1b is (2-Ch loro i sop ropy 1 )etherb is (2-Ch loro i»opropyl Jet her*d8 -Naphtha !•!»*.£.Ni t robenzene-B|Sf (SURR)Ni t robenzen«.-j s,5gi*Ni t robenzeneNi t robenzeneIsophorone f

2-Ni t ropheno 12-Ni t ropheno 12 , 4-Dimethy Ipheno 12 , 4-Dimethy Ipheno 1o is (2-Ch 1 o roe thoxy)me thanebis (2-Ch loroe t hoxy) me thane1 ,2 , 4- Tr ich lorobenzene2 ,4-Dich loropheno 1Benzoic acidBenzoic acid

12558111111111212121212121212121313141313131313131316141313141414151515151516151516

.36

.25

.31

.95

.81

.67

.71

.88

.24

.40

.93

.24

.40

.93

.40

.93

.97

.79

.91

.11

.85

.87

.40

.79

.87

.42

.85

.23

.11

.40

.87

.18

.95

.95

.13

.36

.46

.64

.72

.13

.91

.66

.17

3752528207348341343351369377403369377403377403405445451461448449426445449427448565461426449464502502511522527536540560549537562

1545762139361213635070638338244767341992042653941436343043540027241436343043540027243043540027232148111864267631594581565983395502843894335

33955012182447663570248385421173834103772376702726782129512241841623036079921717364501369535 -328245 _" 4350 >187819M"

40.152.8.70.76.74.68.75.73.76.71.71.73.68.70.65.136.2.59.13.58.81.78.1.

93.74.29.40.66.28.17.61.67.3.68.3.66.3.58.69.71.2.87.

00636667127436178268310783658690276455237913422063531600265203810297680190483398810499

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

891001007379918297888689989597969882777738938662909610010095956151799659828994838095948696

152

QUANT REPORT Page 2

Operator ID: KU0786Output File: ~P9714J:ULData File: >P9714::U5Name: SSTD80Misc: IFB/BNA 80 PPM

Quant Raw: 7 Quant Time:In jected at:

Dilution Factor:

900827 09:28900825 16:33

1.00000

BTL* 4

ID Fi

Last

26)27)27)28)28)28)29)29)30)30)31)32)33)34)34)35)35)36)37)37)37)38)39)39)40)41)41)42)42)43)44)45)45)46)47)47)47)47),47)48)49)50)50)

la: IP0085::PF: IFB/BNA, PP/BNA , TCLBN1Calibration: 900823 17:10

Compound

Benzoic acidNaphtha leneNaph t ha lene4-Ch loroan i 1 ine4-Ch loroani 1 ine4-Ch loroan i 1 ineHexach lorobutadieneHexachlorobutad lene2-Methylnaphthalene2-Methylnaphthalenep-Chloro-m-cresol

•dlO-AcenaphthaleneHexach lorocyclopentadiene2,4,6-Trichlorophenol2,4,6-Trich loropheno 12,4,5-Trichlorophenol2 ,4,5-Trichlorophenol2-Fluorobiphenyl (SURR)2-Chloronaphthalene2-Chloronaphthalene2-Chloronaphthalene2-Ni t roani 1 ineDimethyl phthalateDimethyl phthalateAce naph thy lene2,6-Dinitroto luene2,6-Dinit roto luene3-Ni t roani 1 in*3-Ni t roani 1 in*'Acenaphthene> -S2 ,4-0 in i t rophinolDibenzofuranDibenzofuran *2 ,4-Din i t roto luene4-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 1^-Ni t ropheno 14-Ni t ropheno 14-Ni t roan i 1 ineDiethyl phthalataFluoreneFluorene

R

16151615161616161818182119191919191919191920212221212221222122222222232323232323232324

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.•

B

•

,

.

•

•

.

,

.

.

•

.•

•

.•

,

k

*

T.

17932993295842924576197720475747577547579645224028405977368908084059284856759975504830

Scan*

562550568550568582574599674689661837711724729724729738724729748772810868813819877837866843852852868877911921925

1-934-946934922921961

Area

2717215435

8803075032

1288803937013020

2171095649352880

296659264729217269211164216247211164216247670578232546970

639487166634716093321358645681629622204271311062130

599009727132540

799498220427395545363171079650128041250966561425605125339

Cone

121

62.

2372,

6172,

83405671738082662.

69738336884113911

72141

.73

.10

.54924.66.28856.57.20368.92.00.31.46.18.28.21.00.54760.76.44.97.77.59.07.72.35.48.12.15.239

7511067829162216492

.74

.27

.12

.85

.54

.62

.71

.17

.88

.89

.55^ .710

Units

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUGXML

q88869858756297988373100979697969697975658938398979482781001009810053808510010010010010091929683

153

QUANT REPORT Page

Operator ID: KU0786Dutput File: "P9714HULData File: >P9714itU5Name: SSTD80Misc: IFB/BNA 60 PPM

ID File: IP0085::PFT i t l e : IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900823 17:10

Compound

Quant Rev: 7 Quant TimeIn iected at:

Dilut ion Factor

900827 09:28900825 16:33

1.00000

BTL* 4

R.T. Scant Area Cone Units*

51)51)~2)53)54)55)56)56)57)56)59)60)60)61)61 )62)63)63)64)65)S6 )67)68)69)69)70)70)71)72)73)74)75)75)75)76)76)76)77)77)78)79)80)

4-Ch lorophenyl phenyl ether4-Ch loropheny 1 phenyl ether2 ,4, 6-Tr ibromopheno 1 (SURR)1 ,2-Diphenylhydrazine

•dlO-Phenanthrene4,6-Dinitro-o-creaolN-Nitrosod ipheny lam ineN-Nitrosodiphenylamine4-Bromopheny 1 phenyl etherHexach lorobenzenePentachlorophenolPhenanthrenePhenan t hreneAnthraceneAnthraceneOi-n-butyl phthalateFluorantheneF luoran thenePyrene«dl2-ChryseneBenz id meTerphenyl-D14 (SURR)Butyl benzyl phthalateBenzo (a ) anthraceneBenzo(a)anthraceneChryseneChrysene3,3'-Dichlore**nzidinebis (2-Ethylhejaj&^)phtha late•d!2-P«ryl •nipper.Di-n-octyl phfh*l«taBenzo (b ) f luoran theneBenzo (b) f luoran then*Benzo (b ) f luoran thaneBenzo (k ) f luoran theneBenzo (k ) f luoran theneBenzo (k) f luoran theneBenz-.j x« )pyraneBenzo (a )pyreneIndenod ,2 , 3-c,d )pyrenaDibenzo (a ,h) anthraceneBenzoCghi )perylene

232324242623232325252626262626283030303426313334343434343539373838393838393839434344

.28

.56

.30

.05

.39

.91

.56

.99

.07

.48

.07

.50

.64

.50

.64

.65

.26

.95

.95

.81

.05

.58

.33

.75

.90

.75

.90

.77

.28

.21

.11

.01

.09

.03

.01

.09

.03

.09

.03

.34

.42

.52

9119259619491064942925946999101910481069107610691076117512541288128814781047131914051475148214751482147615011694159116351639168516351639168516391685189719011955

25646280379907096704223772291085863072338901416605619847390193714232732608714232732608836328600123580195580195154291163244083592436543468783001423468783001429784629573394187332860M240451219586201759240451219586201759

+1 219586-201759181347129832155135 ^

~?

7,77.77.82.40.88.5.73.57.55.

113.71.73.72.74.89.94.91.97.40.10.61.87.82.71.84.73.176.97.40.82.87.80.73.90.82.75.85.78.81.83.

. 76.

061596890063804388116835186956145642370023991563509046207100249532800927597983333872

* Compound is ISTD

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

t

154

96919385978078989197959796969597969799971009297100100100100849382988890899293929191100100100

TOTHL ION CHROnflTOBRflnMl* >P9713 33.0-300.8 M

4«* . ••• 12M

wrnaaae

Data File: >P9713::U5Name: SSTD120M i s c : IFB/BN6 120 PPM


Operator ID: KU07B6Quant Time: 900827 09:27In,ectad at: 900825 15:34

Quant Output File: ~P9713::UL

BTL* 3

155

QUANT REPORT Paga

Operator ID: KU0786Output File: AP9713::WLData Fila: >P9713::U5Mama: SSTD120Misc: IFB/BNA 120 PPM

ID Fi la: IP0085::PFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900823 17:10

Compound

Quant Rev: 7 Quant Time:In jacted at:

Dilution Factor:

900827 09:27900829 19:34

1.00000

BTL* 3


1 )2)2)3)4)5)6 )7)8)8)8)9)9)9)10)10)10)11)12)12)2)

j.3)14)15)15 )15)16)16)17)18)19)19)20)20)20)21)21)22)22)23)23)24)2S)

•d4-l ,4-Dich lorobenzeneN-Ni trosodimethylamineN-Ni t rosod i me thy lamine2-Fluorophenol (SURR)b is (2-Ch loroethvl ) etherPheno 1-D5 ' (SURR)Pheno 12-Ch loropheno 11 ,3-Dich lorobenzene1 ,3-Dich lorobenzene1 ,3- Dich lorobenzene1,4- Dich lorobenzene1 ,4-Dich lorobenzene1,4-Dich lorobenzene1 ,2-Dich lorobenzene1 ,2-Dich lorobenzene1 ,2-Dich lorobenzeneBenzyl alcoholN-Ni t rosod i-n-propy lamineN-Ni t rosod i-n-propy laminaN-Ni t rosod i-n-propy lamineHexach loroe thane2-Methylpheno 14-Methy Ipheno 14-Methy Ipheno 14-Methy Ipheno 1b is (2-Ch loro isopropy 1 )etherb is (2-Ch loro iftppropyl )ather

•d8-Naohthalana),.Nitrobanzan»»C4t (SURR)Ni t robenzanaNit robanzenaIsophorone fIsophoroneIsophorona2-Ni t rophano 12-Nitrophanol2 ,4-Dime thy Ipheno 12 , 4-D i me t hy 1 pheno 1bis (2-Ch loroethoxy ) me thanebis (2-Ch loroethoxy )me thane1 ,2 ,4-Tr ichlorobanzana2 ,4-Dich loropheno 1

12.5.5.8.11.11.11.11.12.12.12.12.12.12.12.12.12.13.13.13.14.13.13.13.13.13.13.13.16.14.13.14.14.14.15.14.15.15.15.15.15.16.15.

36283296857175892642952642952642950180991587914280914487231544219098199817374964741384

3752729208350343345352370378404370378404370378404407446455463449451427446451428449565463428466500504514504513523529536541560546

1534913547731555752472155331266517857898060155660353862715060184360353862715060184360353862715060184347625614210404725863482435225396674191261497553966714550774128553959562283251597533049457899204251304949249

328792360485159352587853948852202425719

4025411

10611011194106108112107104108103100103992033

9019921291164

149894540994290487122

103698488

1101" 5

.00

.89

.18

.49

.64

.83

.92

.76

.28

.52

.98

.25

.33

.96

.06

.98

.78

.31

.18

.68

.35

.07

.86

.39

.16

.86

.65

.67

.00

.51

.50

.04

.35

.37

.39

.92

.69

.ta

.47

.26

.88

.77

.79

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUGJ'ML

891001007392908198868587969496979597857876389687589299100100949364799296976187939379809595

156

QUANT REPORT Paga 2

Operator ID: KU0786Output File: ~P9713::ULData Fila: >P9713::U5Name: SSTD120Misc: IFB/BNfl 120 PPM

ID File: IPOOB5::PFT i t l e : IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900823 17:10

Compound

Quant Rev: 7 Quant TimeIn lac ted at

Dilut ion Factor

900827 09:2790082? 19:34

1.00000

BTL* 3

R.T. Scan* Area Cone Dm ts

25)26)26)26)27)27)28)28)28)29)29)30)30)31)32)33)34)34)35)35)36)57)37)37)38)39)39)40)41)41)42)42)42)43)44)45)45)45)45)46)47)47)47)

2,4-DichlorophenolBenzoic acidBenzoic acidBenzo i c acidNaphtha leneNaphtha 1 ene4-Ch loroani 1 ine4-Ch loroan i 1 ine4-Ch loroani 1 ineHexachlorobutadieneHexachlorobutadiene2- Methyl naphtha lene2-Methylnaohthalenep-Ch loro-m-creao 1

•dlO-AcenaphthaleneHexach lorocyc lopentadiena2,4,6-Trichlorophenol2 ,4,6-Tr ich loropheno 12 ,4,5-Tr ich loropheno 12, 4, 5-Tr ich loropheno 12-Fluorobiphenyl (SURR)2-Ch loronaohthalene2-Ch loronaphtha lene2-Ch loronaphtha lene2-Ni t roam 1 ineDimethyl phthalataDimethyl phthalataAcenaph thy len*2 .6-0 in i t rotoluane2 ,6-Dini t ro toluene3-Ni t roan i 1 in*3-Ni t roani 1 ine3-Ni t roan i 1 ine /Acenaphthene2,4-DinitrophenolDibenzof uranDibenzof uranD ibenzof uranDibenzof uran2,4-Dinitroto luana4-Ni t rophano 14-Ni t ropheno 14-Ni t ropheno 1

15.9415.6816.2316.2715.9416.3115.9416.3116.6016.4316.9418.4718.7518.2021.7919.2219.4919.6119.4919.6119.7719.4919.6119.9820.4621.2422.4221.3021.4222.6221.8122.1122.4021.9122.1122.1122.4222.9523.2722.6223.3023.5023.58

551538565567551569551569583575600675689662838712725731725731739725731749773811869814820879839854868844854854869895911879912922926

4316083609

252723M10157820441

11200066668

1832355558744598

3023947714074451

424459247924314875304073309567304073309567891316331179790

892204247730100509549708

1062506248332328017199862291310047

8302751159343912

103354420977265

32801758126613820848

97.20 UG/ML1.74 UG/ML

121.88 UG/ML48.99 UG/ML1.49 UG/ML

81.91 UG/ML1.26 UG/ML

34.63 UG/ML105.05 UG/ML1.34 UG/ML88.27 UG/ML101.48 UG/ML.586 UG/ML

123.61 UG/ML40.00 UG/ML87.14 UG/ML109.88 UG/ML111.86 UG/ML123.43 UG/ML125.66 UG/ML93.67 UG/ML3.86 UG/ML1. 14 UG/ML

103.92 UG/ML116.58 UG/ML125.85 UG/ML6.22 UG/ML90.01 UG/ML136.80 UG/ML180.70 UG/ML148.70 UG/ML2.17 UG/ML7.47 UG/ML

106.74 UG/ML240.30 UG/ML

.393 UG/ML103.90 UG/ML

.211 L":/ML

.730 Ub/ML174.98 UG/ML10.74 UG/ML

:3»122.27 UG/ML^ 38.54 UGH1L

95389583S9926474629696798310095989495959693566191809796857777100100100981005270513387100100100

157

QUANT REPORT Page

Operator ID: KU0786Output File: ~P9713i:ULData File: >P9713::U5Name: SSTD120Misc: IFB/BNA 120 PPM

ID File: IP0085::PFT i t l e : IFB/BNA, PP/BNA, TCLBN1_a»t Calibration: 900823 17:10

Compound

Quant Rev: 7 Quant TimeIn iactad at

Di lut ion Factor

900827 09:27900825 15:34

1.00000

BTL* 3


47)47)48)49 )50)50)51)51)52)53)53)54)5'?)5'5)56)56)57)58)59)60)60)M)ol)62)63)63)64)65)66)67)68)69)69)69)70)70)70)71)72)72)73)74)75)

4-Ni t ropheno 14-Ni t ropheno 14-Ni t roan i 1 ineDiethyl phthalate .FluoreneFluorene4-Ch loropheny 1 phenyl ether4-Ch lorooheny 1 phenyl ether2 ,4 ,6-Tr ibromophenol (SURR)1 .2-0 ipheny Ihydraz me .1 ,2-Di phenyl hydraz ine

•dlO-Phenanthrene4.6-Dinitro-o-cresol4,6-Dinitro-o-cresolN-Ni t rosod ipheny lam ineN-Ni t rosod ipheny lamina4-Bromooheny 1 phenyl etherHexach lorobenzenePentach lorophenolPhenan thronePhenanthreneAnthraceneAnthraceneDi-n-butyl phthalateFluoranthaneF luoranthenePyrene•dl2-ChrysenaBenz id ineTerphenyl-D14>« " (SURR)Butyl benzyl plithalateBenzo (a ) anthraceneBenzo (a )anthracene ,Benzo (a ) anthraceneChryseneChrysanaChrysene3,3 '-Dichlorobenzidinabis (2-Ethy Ihexyl ) phthalateb is (2-Ethy Ihexyl )phthalata•dl2-PeryleneDi-n-octyl phthalateBenzo (b)fluoranthana

23.24.23.23.23.24.23.23.24.24.25.26.23.23.23.24.25.25.26.26.26.26.26.28.30.30.30.34.26.31.33.34.34.34.34.34.34.34.35.36.39.37.38.

81038152503427583207094178955803095009496649666526959582056033759298759298792820211103

937'94893792392296391192696295010001065936944926948100010201049106910771069107711751254128812881478104713201405147514831486147514831486147715011546169415911636

1549920023195456900571783681

8143374993952461352999931751288383692652476

16929542182558191229704283536129463100464898159610046489815961043509850761815127815127146546245615859053511114834204132716360

4834204132716360

144968417728

359195397484513(1385973

28.37.

275.136.111.

1.11.

116.124.131.17.40.2.

141.8.

107.81.80.166.102.100.104.102.113.136.131.139.40.16.93.132.121.103.

1.124.106.

1.274.145.1.

. 40.118.139 .

65020813301602131613010006171364784369521746066294207500206422256560575064863125001838

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/M"UG/hi_UG/MLUG/MLUG/MLUG/ML

10010097949786929297853997807378968293999897999892969798961009196100100100100100100919459839690

158

QUANT REPORT

Operator ID: KU0786Output File: ~P9713»:ULData File: >P9713::U5Name: S5T0120Misc: IFB/BNA 120 PPM

ID File: IP0085::PFT i t l e : IFB/BNA. PP/BNA, TCLBN1Last Calibration: 900823 17:10

Compound

Quant Rev: 7 Quant Time:In iected at:

Di lution Factor:

Page 4

900827 09:2790082? 15:34

1.00000

BTL* 3

R.T. Scant Area Cone Un i ts

75)75)76)'6)76)77)77)77)78)79)80)

Benzo (b)f luorantheneBenzo (b)f luorantheneBenzo (k)f luorantheneBenzo (k)f luorantheneBenzo (k)f luorantheneBenzo Ca )pyreneBenzo (a )pyreneBenzo (a )pyreneIndeno(l,2,3-c,d )pyreneDibenzoCa ,h)anthraceneBenzo (gh i )perylene

38.39.38.38.39.38.38.39.43.43.44.

1103031103031103364654

16401685163616401685163616401685189819031956

302623302832385973302623302832385973302623302832290044209148246607

109109142111112148116116128132120

.29

.36

.77

.94

.02

.89

.73

.82

.43

.61

.41

UG/MLUG/MLDC/MLUG/MLUG/MLUG/MLUG/MLKG/MLUG/MLUG/MLUG/ML

9089939392919191100100100

• Compound is ISTD

159

TOTflL ION CHEOHftTOaHflH

Data Fila: >P9712::U5Name: SSTD160Misc: IFB/BNA 160 PPM

Id File: IP0085::PFTitle: IFB/BNft, PP/BNA. TCLBN1Last Calibration: 900831 12:04

Ooerator ID: KU0786Quant Time: 900831 14:16Injected at: 900829 14:39

Quant Output File: ~P9712::i

BTL* 2

160

QUANT REPORT Page

Operator ID: KU0786Output File: ~P9712::U1-Data Fila: >P9712::U5Name: SSTD160Misc: IFB/BNA 160 PPM

ID Fila: IP0085::PFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900831 12:04

Compound


Oilut ion Factor:

900831 14:16900825 14:35

1.00000

BTL* 2

R.T. Scant Area Cone Un i ts

1)212)3)4)5)6 )7)8)9)9)9)9)9)10)10)10)11)11)12)12)12)13)14)14)14)15)15)15)16)16)17)18)19)19)19)19)19)20)20)20)21)21)

*d4-l , 4- Dich lorobenzeneN-NitrosodimethylamineN-Nitrosodimethylamine2-Fluorophenol ' (SURR)b is(2-Ch loroethvl ) etherPhenol-05 " (SURR)Pheno 12-Ch loropheno 11, 3-D ich lorobenzene1,3-Dich lorobenzene1, 3-D ich lorobenzene1 ,4- Dich lorobenzene1,4-Dich lorobenzene1 ,4-0 ich lorobenzene1 ,2-Dich lorobenzene1,2-D ich lorobenzene1 ,2-Dich lorobenzeneBenzyl alcoholBenzyl alcoholN-Ni trosodi-n-propy laminaN-Ni trosodi-n-propylamineN-Ni t rosod i-n-propy laminaHexach loroethane.2-Methy Ipheno 12-Methy Ipheno 12-Methy Iphenol4- Me thy I phenol4-Methylpheno44-Methylpha r>» V -.;b is (2-Ch loroiujpropy 1 )etherb is (2-Ch loroi*ojaropyl )ether

•d8-NaphthaleneNitrobenzene-05 (BURR)Ni t robenzeneNi t robenzeneNi t robenzeneNi t robenzeneV t robenzeneIsophoroneIsophoroneIsophorone2-Ni t ropheno 12-Ni t ropheno 1

12558111111111212121212121212121213131414131313131313131313161413131314141415151515

.38

.30

.34

.98

.87

.75

.79

.91

.28

.44

.97

.28

.44

.97

.28

.44

.97

.89

.05

.82

.03

.17

.87

.46

.85

.95

.46

.85

.95

.46

.87

.25

.17

.46

.50

.85

.23

.92

.92

.05

.25

.17

.25

3762830

209351345347353371379405371379405371379405401409447457464449429448453429448453429449566464429431448467Wl5Di507517513517

154400455348191297250786236278145877469128242088087797583947879668087797583947879668087797583947879668002358444118488

52601110587333244455424565064705151554245650647051512317821031085518857583303420156458819837724264286580545

10601443542604603704473

40.144.6.

152.116.132.128.144.140.131.136.136.128.133.138.129.134.19.141.4.

134.27.155.128.15.162.107.12.136.138.61.40.144.64.12.3.

135..57.

101.- 34.154.

3* i.

00900981706907523258716816160141463207748815730103862459442148001007107269377482023350

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUGVML

901001007594918996889290979798989699918882863894698486629396100100949264758775689597958073

161

QUANT REPORT Page

Operator ID:Output File:Data File:Name: SSTD160M i sc

KU0786~P9712::UL>P9712::U5


Dilution Factor:S3 I UJ.O U

IFB/BNA 160 PPM

900831 14:16900825 14:35

1.00000

BTL* 2

ID File: IP0085::PFT i t l e : IFB/BNA, PP/BNA, TCLBN1i_ast Calibration: 900831 12:04


22)22)22)22)23)23)24)24)25)25)26)26)26)27)27)27)28)28)28)29)29)JO)30)31)31 )31)31)32)33)34)34)35)35)36)37)37)37)38)39)40)41)42)42)

2,4-Dimethylphenol2 ,4-Dimethylphenol2 ,4-Dime thy Ipheno 12 ,4-Dimethylphenolbis(2-Chloroethoxy)methanebis(2-Chloroethoxy)methane1,2,4-Trichlorobenzene1 ,2 ,4-Trichlorobenzene2.4-Dichlorophenol2,4-DichlorophenolBenzo ic ac idBenzoic acidBenzoic acidNaphtha leneNaphtha leneNaphtha lene4-Ch loroan i 1 ine4-Ch loroani 1 ine4-Ch loroani 1 ineHexachlorobutadleneHexachlorobutadlene2- Methyl naphtha lene2-Methylnaphthalenep-Chloro-m-cresolp-Ch loro-m-creso 1p-Ch loro-m-creso 1p-Ch 1 oro-m-creso 1

*dlO-Acenaphth«leneHexach lorocy«lopentad lene2 ,4 ,6-Tr ichioropheno 12 ,4 ,6-Tr ich loropheno 12,4,5-Trich loropheno 12 ,4,5-Trich lorophen* 12-Fluorobiphenyl (SURR)2-Ch loronaphtha lene2-Ch loronaphtha lene2-Ch loronaphtha lene2-Ni t n in i 1 ineDimethyl phthalateAcenaph thy lene2,6-Dinitrotoluene3— Nitroani 1 ine3-Ni t roan i 1 ine

14.5615.3915.5416.0715.6615.7616. 1516.8415.8415.9815.7216.0516.3915.9816.3116.3915.9816.3316.6216.4316.9418.4918.7518.2218.2918.8619.2221.7919.2219.5119.6319.5119.6319.7919.5119.6320.0020.5121.2621.3021.4721.6921.85

483524531557537542561595546553540556573553569573553570584575600676689663666694712838712726732726732740726732750775812814822833841

319950592699177302952278711895708308268048171582028422784037338636M26931

129551856889179

2386077606676451

3873579967745450

595129242424482476

25976642009342179442329342179442329311564204505913436

1191604Jo503913031251318512345911 '3914 ^

291798 J

.652 UG/ML10.31 UG/ML142.44 UG/ML

.617 UG/ML9.73 UG/ML

132.53 UG/ML140.56 UG/ML

.532 UG/ML11.55 UG/ML

139.50 UG/ML2.19 UG/ML43.63 UG/ML175.82 UG/ML

1.87 UG/ML89.87 UG/ML.395 UG/ML1.63 UG/ML42.45 UG/ML135.34 UG/ML2.12 UG/ML

127.25 UG/ML134.25 UG/ML

.734 UG/ML169.15 UG/ML

.689 UG/ML

.696 UG/ML

.704 UG/ML40.00 UG/ML232.85 UG/ML150.61 UG/ML151.14 UG/ML145.51 UG/ML146.03 UG/ML112.38 UG/ML4.84 UG/ML1.44 UG/ML

127.91 UG/ML145.03 UG/ML133.82 UG/ML103.30 UG/ML163.90 UG/ML, 2.06 UG/ML153.28 UGKML

82949469817995969796809392909488637361969766831001001001009497969797978854619786948278100100

162

QUANT REPORT Page

Operator ID: KU0786Output File: ~P9712:Data File: >P9712::U5Name: SSTD160Misc: IFB/BNA 160 PPM

ID File: IP0085::PFTitle: IFB/BNA, PP/BNA, TCLBN1_aat Calibration: 900831 12:04

Compound

Quant Rev: 7 Quant Time:In lected at:

Dilution Factor:

900831 14:16900825 14:35

1.00000

BTL* 2


42 )42)43)*4)44)45)45)46)47)47)47 )47)47)48)49)49)50)50)51)51)52)3)

54)55)55)56)57)58)59)60)60)61)61)62)62)62)63)63)64)64)64)65)66)

3-Ni t roan i 1 ine3-Ni t roan i 1 ineAcenaoht hene2 ,4-D in i t ropheno 12 ,4-DinitrophenolDibenzof uranD i benzof uran2 ,4-Din itrotoluene4-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 14-Ni t roan i 1 ineDiethyl phthalateDiethyl phthalateF 1 uoreneF 1 uorene4-Ch lorophenyl phenyl ether4-Ch loropheny 1 phenyl ether2 ,4,6-Tr ibromophenol CSURR)1 , 2 -Di phenyl hydraz ine

•dlO-Phenanthrene4,6-Dinitro-o-cresol4,6-Dinitro-o-cresolN-Nitrosod i phenyl am me4-Bromophenyl phenyl etherHexach loroben««nePentachloroph«nolPhenanthren* ^PhenanthreneAnthraceneAnthracene fDi-n-butyl phthalateDi-n-butyl phthalateDi-n-butyl phthalateFluorant heneFluoranth* aPyrenePyrenePyrene•dl2-ChryseneBenz i d ine

22.22.21.22.22.22.22.22.23.23.23.23.24.23.22.23.23.24.23.23.24.24.26.23.23.24.25.25.26.26.26.26.26.28.28.28.30.30.30.30.31.34.26.

16449304144497673052598905896756523630593410428199050952095268526801688628982898618205

856870845850855870896881912923926941949941881925923964912926963951106593794694910001021104910701078107010781143117611851255128912551289132014781047

469224574

10894662368

1738541317390

30004789428725935472373724914302472949816341

10300981086449112715333351392119270812756263904503941

2397747017973325903947451885481326626122364213266261223642

53011235878

33551137133112417:113713.*1124120

239213129335222

2.4612.91133.707.24

531.44120.31.274

187.8916.34175.1944.4546.6656.64193.67.760

123.43144.291.5014.24137.26182.90170.7240.003.55

216.23114.94121.00126.56172.23125.27115.55124.99115.29.434

101.26.275

139.53137.93139.97138.37.294

_ 40.00V* 49.85

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG'/ML

100100951001005952841001001001001009573969790998497929888739688979888879088978280979693934797100

163

QUANT REPORT

Ocerator ID: KU0786Output File: AP9712::ULOata File: >P9712::U5Name: SSTD160ttisc: IFB/BNA 160 PPM

ID Fi le: IP0085::PFT i t l e : IFB/BNA, PP/BNA, TCLBN1-ast Calibration: 900831 12:04

Compound

Quant Rev: 7 Quant Time:In iacted at:

Di lut ion Factor:

Page 4

900831 14:16900825 14:35

1.00000

BTL* 2


66)67)68)69)69)69)70)70)70)71)72)72)72)73)74)74)75)75)75)76)76)76)77)77)77)78)79)BO)80)

Benz id meTerphenyl-D14 ( SURR )Butyl benzyl phthalateBe nzo (a) anthraceneBenzo(a)enthraceneBenzo (a ) anthraceneChryseneChryseneChrysene3 ,3 '-Dichlorobenzidinebis(2-Ethylhexyl) phthalatebis(2-Ethylhexyl ) phthalatebis(2-Ethylhexyl ) phthalate»d!2-PeryleneDi-n-octyl phthalateDi-n-octyl phthalateBenzo (b)f luorantheneBenzo (b ) f luorantheneBenzo (b ) f luorantheneBenzo (k ) f luorantheneBenzo (k)fluoranthenaBenzo (k ) f luoranthenaBenzo (a)pyreneBenzo (a )pyreneBenzo (a )pyreneIndeno(l,2,3-c,d )pyreneDibenzo(a,h ) anthraceneBenzo (gh i )peryl«neBenzo (gh i )peryl«n«

26.31.33.34.34.34.34.34.34.34.34.35.36.39.36.37.38.38.39.38.38.39.38.38.39.43.43.43.44.

4261347892997892998080292122211204120404120404120437473757

10651320140514761483148614761483I48614771477150115461694154615911636164016851636164016851636164016851898190318981957

502387907174705626288575259945061

6288575259945061

1776993974

5457195545797745545

676590460161367899354622460161367899354622460161367899354622312828225643312828270082

71.190.183.165.138.

1.179.150.

1.127.

1.170.

1.40.1.

182.192.153.148.191.153.147.214.171.165.138.136.158.136.

1052001312336123459724317300492348893456156353513248311352

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

100929510010010010010010084999357839998888790929193908992100100100100

Compound is ISTO

164

7BSEM1UOLATILE CONTINUING CALIBRATION CHECK

Lab Name:ETCNJ Contract:_________

Lab Code: Case No.:____ SAS No.:

Instrument ID:GC/MS P Calibration Date: 09/04X90

SDG No.:

Time: 1619

Lab F i l e ID: >P9B52

Min RRF50 for SPCC(#)

I n i t Calib. Dates(s): 08/25/90 OB/25/90

0. 050 Max SRSD for CCC(») 25. C

11 COMPOUND!„., = .,„ = = «« = __ = « = = _„ = = = = =1 PhenolIbis(2-Chloroethyl )e ther ____1 2-Ch loropheno 11 1 ,3-Dichlorobenzene1 1,4-Dichlorobenzene1 Benzu 1 a Icoho 11 1,2-Dichlorobenzene1 2-Methvlpheno 1Ibis(2-Chloroisopropyl ) e t her14-Methvlohenol

11

*

111*11111

IN-Nitroso-d i-n-propy lamine_#1 Hexach 1 oroe thane 11 Ni t robenzene1 I sophorone1 2-Ni t ropheno 112 r 4- Dime thy Ip he no 11 Benzo ic acidI b i s (2-Ch loroethoxy)methane_12 ,4-Dichlorophenol1 1 ,2 ,4-Tr ich 1 orobenzene1 Naph t ha lene14-Chloroani 1 me1 Hexachlorobutadiene1 4-Ch loro-3-methvlpheno 11 2- Me t hy 1 naphtha lene1 Hexach lorocyc lopentad lene _12 ,4,6-Trichlorophenol12,4,5-Trichlorophenol12-Chloronaphthalene1 2-Ni t roan i 1 meIDimethulphthalatelAcenaphthulene12.6-Dinitrotoluene1 3-Ni t roan i 1 ine1 Acenaph t hene12 r4-Dinitrophenol1 4-Ni t ropheno 11

11*111*111

1**

*

*

1

RRF IRRF50

1.3111.2051.3661.3661.3861. 0141.3651. 136.366

1. 178.880.557.333.618.197.324. 150.333.278.329.792.347.195.265.494.386.393.403

1. 186.314

1.3541.582.309.253

1. 125. 127. 087

1.6051 .4891.5421.5281.547.867

1.5281. 144.449

1.3591. 107.589.390.855.225.374. 186.410.293.358.982.390.204,262

.'431

.417

.4421.394.391

1.5171.992.339.262

1.294.112.081

1XD 1

22.5*23.6 112.9 111.9 111.6*14.5 112.0 1

.8 122.9 115.4125.8*5.8 117.2 138.4114. 1*15.4123.6123. 1 15.4*8.71

24. 1112.2 14.4*1.0*

11.6*6. 0*9.9117.5 124.7112. 1 126.0 19.713.5115. 0*11.9*6.6*

1

FORM UII SU -1 1/87 Rev.

165

7CSEMIVOLATILE CONTINUING CALIBRATION CHECK


Lab Code: Case No.:_____ SAS No.:

Instrument ID:GC/MS P Calibration Date: 09/04X90

SDG No.:

Time: 1619

Lab File ID: >P9852

Min RRF50 for SPCC(#)

Init Calib. Dates(s): 08/25/90 08/25/90

0.050 Max %RSD for CCC(») -25.0

11 COMPOUND!«...«.«...«.....«........«.1 Dibenzof uran12 ,4-Dinitrotoluene1 Diethvlphtha late14-Ch lorophenyl-phenylether_1 F 1 uo rene14-Nitroani 1 me!4,6-Dinitro-2-methylphenol_IN-Nitrosodiphenylamine (1)_*1 4-Bromophenyl -pheny let her __IHexachlorobenzene1 Pen t ach 1 oropheno 1 *1 Phenanthrene1 An t hraceneIDi-n-butulphthalate1 Fluoran t hene «1 PvreneIButvlbenz«jlphthalate13 ,3 '-Dichlorobenzidine1 Benzo (a )anthracene1 ChrvseneIbis(2-Ethylhexyl)phthalate_1 Di-n-octulphtha late «IBenzoCbJfluorantheneIBenzo(k)fluoranthene1 Benzo (a )p<jrene *1 Indeno(l,2,3-cd)pyrene1 Di benz ( a .h)anthraceneIBenzo(g,h , i )perylene

INitrobenzene-d512-Fluorobiphenyl1 Terphenul-dl4IPhenol-d512-Fluoropheno 11 2 ,4 ,6-Tr ibromophenol1

RRF

1.425.410

1.205.524

1. 065.229.139.511.219.267

* .118.933.921

1.093.792.777.802.288

1. 121.972.953

1.7281.3231. 162

* 1.049.918.657.787

.3391.2381.3401.4251. 182.173

RRF50

1.713.392

1.295.586

1.164.218.156.624.268.328. 145

1.0991.1401.325.861.850.773.252

1. 1691.040.867

1.7581.2601.3821.104.914.667.791

.3961.5401.4881.6711.283.187

XD

20.24.37.5

11.89.44.712.422.1«22.222.823. 1*17.723.721.28.8*9.33.612.44.37.09. 01.7*4.818.95.3*.5

1.5.5

16.824.411.117.38.67.8

(1) Cannot be separated from Dipheny1amine

FORM UII SU -2 1/87 Rev.

166

TOTRL ION CHROMflTOCRPMFile >P9B52 35.8-588.8 MU . SST558 50 PPH

1288 1688 2888

16 26 24 26 32 36 40 44e1 '' '12





BTL* 2

167

QUANT REPORT Page

Operator ID: KU0786Output File: "P9B52 : : Ul_Data File: >P9852::U2Name: SSTD50Misc: IFB/BNA 50 PPM


Compound

Quant Rev: 7 Quant TimeIn jected at

Di lut ion Factor;

900904 17:06900904 16:19

1 .00000

BTL* 2


1)2)2)3)4)5)6)7)8)8)8)9)9)9)10)10)10)11)12)12)13)14)14)15)15)16)16)17)18)19)19)19)20)20)21)21)22)23)24)25)26)27)27)

*d4- 1 , 4- Dich lorobenzeneN-Nitrosod i me thy lamineN-Nitrosodimethylamine2-Fluorophenol • (SURR)bis(2-Ch loroethyl ) etherPhenol -D5 (SURR)Pheno 12-Ch lorophenol1, 3-D ich lorobenzene1,3-Dich lorobenzene1,3-Dich lorobenzene1 ,4- Dich lorobenzene1 ,4- Dich lorobenzene1,4- Dich lorobenzene1 ,2-Dich lorobenzene1 ,2-Dich lorobenzene1,2-Dich lorobenzeneBenzyl alcoholN-Ni trosodi-n-propylamineN-Nitrosodi-n-propylamineHexach loroe thane2-Methylpheno 12-Methylpheno 14-Methy Ipheno 14-Methylpheno 1bis (2-Ch loroisopropyl )etherbis(2-Chloro i sop ropy 1 )ether

•de-NaphthaleneNitrobenzene-D5 (SURR)Ni t robenzeneNit robenzeneNit robenzeneI sophoroneIsophorone2-Ni t ropheno 12-Ni t ropheno 12 ,4- Dime thy Ipheno 1bis (2-Ch loroethoxy) me thane1,2, 4- Tr ich lorobenzene2,4-DichlorophenolBenzo ic ac idNaphtha leneNaphtha lene

11.4.4.6.11.11.11.11.11.12.12.11.12.12.11.12.12.12.13.13.13.13.13.13.13.13.13.15.13.13.13.14.14.15.14.14.15.15.15.15.15.15.15.

99899563463638508905588905588905586052744707520752054784740780555555557610357555715590

3813235216355350351357376384410376384410376384410411456467454434456434456433454570467434470507507556507517534546566556564556573

159147180161

51032553182962243325113193263068193040673078303040403040673078303040403040673078303040401725062202904601611723722764027041222764027041269399367266012062973561619362930921784464260252421144416916528123530842426902722039013974C10604 .73616F

40541

50565556545454545354535657564467145759715161562340522852367.3545858525048.

54

.00

.71

.55

.42

.97

.33

.28

.94

.28

.95

.27

.79

.46

.79

.43

.13

.42

.43

.85

.17

.96

.92

.17

.74

.46

.58

.24

.00

.28

.77

. 08

.17

.18548.66. 15.28.36.02. 09.09785.64


901001006687928195908790989796989796797738956787579810010093896382569582598093869695668691

168

QUANT REPORT Page 2

Operator ID: KV0786Output File:Data File:Name: SSTD50Misc: IFB/BNA 50 PPM

Quant Rev: 7

>P9852::U2

Quant TimeIn jected at:

Dilut ion Factor:

900904 17:06900904 16:19

1.00000

BTL# 2



28)28)28)29)29)30)30)31)32)33)34)34)35)35)36)37)37)37)38)39)40)41)42)42)43)44)45)45)46)47)47)47)47)47)48)49)50)50)51)51)52)53)54)

4-Ch loroan i 1 ine4-Ch loroani 1 ine4-Chloroani 1 ineHexach lorobutadieneHexachlorobutadiene2-Methylnaphtha lene2-Methylnaphtha lenep-Chloro-m-creso 1

*dlO-AcenaphthaleneHexachlorocyclopentadiene2 ,4,6-Tr ich loropheno 12,4,6-Trichlorophenol2, 4, 5-Tr ich loropheno 12, 4, 5-Tr ich loropheno 12-Fluorobiphenyl (SURR)2-Ch loronaphtha lene2- Ch lor on aphtha lene2- Ch loronaphtha lene2-Ni t roan i 1 ineDimethyl phthalateAce naph thy lene2,6-Dinitrotoluene3-Ni t roan i 1 ine3-Ni t roan i 1 meAcenaphthene2 ,4-Din i t ropheno 1D ibenzof uranDibenzof uran2 ,4-Dinitrotoluene4-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 14-Ni t ropheno 14-Ni t roan i 1 ineDiethyl phthalateF luoreneF 1 uorene4-Ch lorophenyl phenyl ether4-Ch loropheny 1 phenyl ether2 ,4,6-Tr ibromopheno 1 (SURR)1,2-Diphenylhydrazine

•dlO-Phenanthrene

15151616161818172118191919191919191920202020212121212122222223232323232323232223232325

.55

.90

.20

.04

.55

.07

.36

.85

.37

.81

. 09

.19

.09

.19

.36

.09

.19

.56

.05

.82

.86

.99

.35

.98

.47

.68

.98

.86

.19

.86

.06

.14

.31

.57

.31

.10

.06

.88

.86

. 14

.88

.63

.97

5565735885806056806946698427167307357307357437307357537778158178238418728478578729158829159259299379509379279259659159299659531068

342998428292854

20711530904011482077

196858250822135127130614138656130614138656482876141274682

436913122684475524624644106249820977907

405706350975370622840

122997226225349113045098706168457405968365053339215733.18379056517J1441429"*303873

.66619.1256.88.652

48.1658.40.302

53.3740.0049. 1949.0052.0246.9949.8855.601.75.581

54.2053.9258.4254.4954.8949.324.7556.7447.5754.98.291

51.594.4549.8422.2210.0213.8848.2458.8252.49.4884.5953.6249.6956.7740. 00

1

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML69

61696095988490100939598969796995658928698987710010098100923285100100100100100959495908983948698

Operator ID: KU0786Output File: "SP9852::U|_Data File: >P9852:: U2Name: SSTD50Miac: IFB/BNA 50 PPM


QUANT REPORT

Quant Rev: 7 Quant Time:In jected at :

Dilut ion Factor:

Page 3

900904 17:06900904 16:19

1.00000

BTL* 2

Compound55)56)56)57)58)59)60)60)61)61)62)63)63)64)64)65)66)66)67)68)69)69)70)70)71)72)73)74)75)75)75)76)76)76)77)77)77)78)79)80)

4,6-Dinitro-o-cresolN-NitrosodiphenylamineN-Ni trosod iphenylamine4-Bromopheny1 pnenyl etherHexachlorobenzenePentachloropheno1PhenanthrenePhenanthreneAn thraceneAnthraceneDi-n-butyl phthalateFluorantheneFluoranthenePyrenePyrene•d!2-ChryseneBenzidineBenz id ineTerphenyl-D14 (SURR)Butyl benzyl phthalateBenzo(a)anthraceneBenzo(a)anthraceneChryseneChrysene3,3'-Dichlorobenz idinebis(2-EthyIhexyl)phthalate

*d!2-PeryleneDi-n-octyl phthalateBenzoCb)fluorantheneBenzo(b)fluorantheneBenzo(b)fluorantheneBenzo(k)fluorantheneBenzo(k)fluorantheneBenzo(k)fluorantheneBenzo(a )pyreneBenzo(a)pyreneBenzo(a)pyreneIndeno(l,2,3-c,d)pyreneDibenzo(a,h)anthraceneBenzoCghi)perylene

R.T. Scan* Area Cone Units q

* Compound is ISTD

23.47 94523.14 92923.57 95024.65 100325.06 102325.65 105226.06 107226.20 107926.06 107226.20 107928.25 118029.82 125730.51 129129.82 125730.51 129134.37 1481

•X25.63 105125.97 1068

1 31.16 132332.91 140934.31 147834.46 148534.31 147834.46 148534.35 148034.88 150638.67 169236.69 159537.55 163737.61 164038.48 168337.55 163737.61 164038.48 168337.55 163737.61 164038.48 1683-42.55 188342.66 1888«3.65 1937

5940819775

236918•1018261246836103641734643285041734643285050345932717332285932717332285912211793773905222718111793117842815872017842815872038455132351651071430951025121125048987510251211250489875102512112504898757439354260"64370 .

54.54 UG/ML4.47 UG/ML53.52 UG/ML54.84 UG/ML55.78 UG/ML58.49 UG/ML57.57 UG/ML59.71 UG/ML55.53 UG/ML57.59 UG/ML63.20 UG/ML56.37 UG/ML55.62 UG/ML58.49 UG/ML57.71 UG/ML40.00 UG/ML52.06 UG/ML216.80 UG/ML57.20 UG/ML53.91 UG/ML53.66 UG/ML47.74 UG/ML58.56 UG/ML52 . 09 UG/ML38.12 UG/ML52.26 UG/ML40.00 UG/ML44.03 UG/ML49.71 UG/ML54.55 UG/ML43.58 UG/ML46.08 UG/ML50.57 UG/ML40.40 UG/ML57.44 UG/ML63.04 UG/ML50.36 UG/ML52.67 UG/ML51.84 UG/ML54.34 UG/ML

68819988979697969695959797989997100100959810010010010092918498918889949192929090100100100

170

7BSEMI VOLATILE CONTINUING CALIBRATION CHECK

Lab NameiETCNJ Contract:__________


Instrument ID:GC/MS P Calibration Date: 09/05/90 , Time: 1630

Lab F i l e ID: >P9872 I n i t Calib. Dates(s): 08/25/90 08/25/90

Mm RRF50 for SPCC(#) 0. 050 Max HRSD for CCCC*) 25. 0

COMPOUND

Pheno 1bis(2-Chloroethyl )ether ___2-Ch 1 oropheno 11 T 3-D i ch lorobenzene1 ,4-Dich lorobenzeneBenzvl alcohollT2-Dichlorobenzene2-Methvlpheno 1bis(2-Chloroisopropyl )et her4-Me t hvl pheno 1N-Nitroso-di-n-propylamine_Hexach loroe thaneNit robenzeneIsophor one2-Ni t ropheno 12 . 4-Dimethulpheno 1Benzoic acidb is (2-Ch loroe t hoxy ) me t hane_2 r 4-Dichlo ropheno 11,2,4-Trich lorobenzene ____Naph t ha 1 ene4-Chloroani 1 meHexach lorobutad iene4-Chloro-3- me thy 1 phenol2- he thyl naphtha leneHexach lorocyc lopentad iene _2 ,4,6-Trichlorophenol2 ,4,5-Trichlorophenol2-Ch loronaphtha lene2-N itroani 1 i neDimethvjlphtha lateAcenaph thy 1 ene2 .6-Din 1 1 roto luene3-Ni t roan i 1 i neAcenaph thene2 .4-Dinitrophenol4-Ni t ropheno 1

11

«111*

11111*111*111*

111**1**1I11111*##1

RRF

1.3111.2051.3661.3661.3861. 0141.3651. 136.366

1. 178.880.557.333.618. 197.324. 150.333.278.329.792.347.195.265.494.386.393.403

1.186.314

1.3541.582.309.253

1. 125. 127. 087

RRF50

1.6281.4651.5521.5161.5311. 1081.5031. 146.339

1.4471. 054.594.403.889.233.387. 187.414.323.365

1.030.454.208.321.574.426.471.471

1.346.452

1.5102.026.351.293

1.301. 132. 088

1\D 1

= ««=,,= |24.2*21.6 113.6 111.0110.4*9.31

10.11.9 1

7.4122.9 119.7*6.5 1

21.2143.9 118.3*19.5 124.4124.3 116.3*10.7130.1130.816.5*21.4*16.1110.4*19.9*17.1 113.5 144. 1 111.5128.1 113.7116. 0 115.6*3.6#1.6*

1

FORM UII SU -1 1/87 Rev,

171

TIo3c

IDC

Ito

to

"Vv

\ro\l73ac

na33O

cra

aTJa

aa

o3O

TJ

n3

a33(t

toK

ro TJi 3rT| 0)

-1n to1

z c o o — ' c o c o c o o c r n c o x f t•- a •- 3 o a a •- • M. 3- a ^

-1 -H rt 3 C r a 3 3 3 l « l T 3 ' j 4>. ~ 3 TJ —CN1H

c oo •—•

ITa

T 1 3r» *t wr w u. x,

f TJ Ml •—cr-jo30TJ•Jn3o»_~

MNJ

toONO

roo

CN

3"n3o*-

i

C0

ocr**.

O.TJ

»-• >-•I- XXco roto MI

M >-»

x>l CNxd NOI-1 (->

M (-»to ODCN xj

t_»Xs

^

"-1

WXN0

M

^xWNJ

NJ

to

3-a3cr_ •

t-4

toX>J

CO

_*,NO

MNJ

T N o n N N N 3 --NX: N -O O 3 3 O O O I N J O I Ocr ^ H o ~ ^ /-N o i a ~a u 3 ^ ~ » * - c r o m 3 o iN 3~- - TJ -t) rt,x; 3-n •. 3- tos3 ~ v^- -

c - - — <T C C TJ «

n ^ - f t x » J ( I O O 3 " 3 "1 TJ 3 1 3 T T rt na n r t n a o i f t T xxn T 3" av: T ^

- ft TJn n -<:3 0) Tn 3 n

a 3n

3 3 ft •<:rt- rt- »— • »— •3" 3- ft ~n a rt TJ3 3 n 3"n a rt

3-a*an1

a3rt-3"-Jftna3a

M (-• M (-• (->

V*l X j O \ N O O t - * x W \ j N O N O | - »

x»J CD sJI »-»NO NJ NJ CD

t> CN to to xii NJ rovO M s»J PDO v»l tO t-»

I-* I-1 I-1 M M t-»

ioo3->— *o

DO ~D ~Hc *< —rt T C<: a oi— 3 Tcr n oa3N•C

~l TJOcra3N•aM-3a

ro00CD

JX NJCNNOoOisNjooo, . .^(-« NJ ON !-•0 NJ tO NJ

toO l-»

NO ON Xs NO NO xH \J--* CO N£) xH (A3 J\ CN

ts CO NO V»l CN CD Xs

roJS

to•— * ^ **>< 00 >V"* O l~* Sfl "^ ^v STl SH

A r t

3"rt3"ft^^arta

3rt3">a

O D- 3

1 rt3 3-1 -I

cr OPc ort n<: 3•- a

3 TJa

CO NJ NJ0 NJ NONJ NJ ro

NJ NJ \J

"-" xTI ^

CO xH NJ

NO JS xd— — *

3-rt3"ft^-ftrtn

TJ3-n3a3rt-3-

n3

TJn3rtftO3"

O-3O

n TJ

*-•O NO

NO tO

xd l->

I-1 »-»0 l-»o £\ND O

toNJ xW

NJ NJ

NO

N>l

N>(

M

0NONJ4

NJ

-

3-n3Of-~

Ml-»CO

^_,^•Jl

totoNO*

I Xx Z Xx XN T| fxn> i i ^ i — ix co z ON z c nft -I •- 1 - O 3"O O rt O rt T H-

onrt•y

INJ

is1o3 ^ 3 - j M - j n o N C . -

— O O 3 O 3 TDTJ w ^ft ™ ""T 3- O rt 3o n Q- ~i **•cr 3 - o —a \c TJ i -3 •- -J NJ 3N i n i nn TJ 3 33 J" *C On n — rt

3 ft 3"•<: 3 XT

n 3 TJrt n 3-3~ nn — 3T t-1 O

( NW -

1,1

IV w

3"n3y;^~1

TJ3-(113

N£1 — •nrt3"(K-J

1

H»

to to xn M ro o MIO-. M (-» IjJ hJ CN tONJ NO t-1 NO NO <J1 XX

M

N>< NJ CN (-• NJ to CNxd oo xiJ >ji M xn (-*X\ ro xn o xj v/j jx

to to to i-» MX\ 00 Xx NJ xJI \j NJ

CO 00 xW Ml I-1 XJ M

3

rt-3"ft*^ftrt-n

>-•tooMl

,_.toMlto

N>4

NO

3

^-Jorto»--cn3(V

XN

o

^h-»•-*

v^

? "T i nn » o3 n 3N II TJO 1 O-n II cc n z~i B Oft n3 1

IIIIIIIIIIH1IfnHnHitH1H

l-> II

Xs « 3)to n TIMl H

•-• « ;oCO MlM OO

to ir\J 0

o

3*-•3

;o70T|vjjo"*>0-5

inTJnns-^*W

rio

oMlo

HPJQlX

X73U~)0

-nOT

nnn*•nto

r -- r r» 3 a »cr w cr cr

rt1

•n -> n z-• C O ft- 3 a 3a n n a

3— •••• mO H- n

0 ZV (_,

TJ <T)NO nCD \ enM 3 mro in 3»_•TJ Cn oft r

Oi J>n H

»— t

z ro m~ n3 ft n- — ort- Z NJ

cr -inn -i -ft Oi Z— rt c

cr O z3 n <nin oo o a> 3 n01 ft tO rt J>« r» T rn n> z OP —o> o n tu~ • rt ^j(d o •• •• J>~ NO H

\ .-.o aMl z

0 \CD NO n\ 0 Iro nMI n\ xNO mO H O

(D3n Zo

o00 »-»\ CO(0 N*l

Ml o\NO

o

TOTflL ION CHROHRTOSRPMF i l e >P987235.6-580.8 a»u. SSTIBe

1800000-

1600800-

1400800-

1200000-

1000009-

800000-

400000-

200000-

1200

IFB'BMfl

1600

PPM

2000

44




Quant Output F i l e : "-P9872: : UL

BTL# 2

173

QUANT REPORT Page

Operator ID:Output File:Data File:Name: SSTD50disc: IFB/BNA 50 PPM

KU0786"•P9872: :UL>P9B72::U3

Quant 7 Quant Ti me:In jec ted at:

Dilution Factor:

900905 19:17900905 18:30

1.00000

BTL* 2



1)2)2)3)4)5)6)7)8)8)8)9)9 )9)10)10)10)11)12)12)13)14)14)15)15)16)16)17)18)19)19)19)20)21)21)22)23)24)25)26)26)27)27)

*d4-l, 4- Dich lorobenzeneN-Ni t rosod imethylamineN-Nitrosodimethylamine2-Fluorophenol (SURR)b is (2-Ch loroe thy 1 ) etherPhenol-05 (SURR)Pheno 12-Ch 1 o ropheno 11 ,3-Dich lorobenzene1,3-Dichlorobenzene1 ,3-Dich lo robenzene1,4-Dichlorobenzene1,4-Dichlorobenzene1,4-Dichlorobenzene1 ,2-Dich lo robenzene1,2-Dichlorobenzene1 ,2-Dich lorobenzeneBenzy 1 a 1 coho 1N-Ni t rosod i-n-propylamineN-Nitrosodi-n-propylamineHexach loroe thane2-Methylphenol2-Me thy Ipheno 14-Methylphenol4-Methylpheno 1bis(2-Chloroisopropyl )etherbis(2-Chloroisopropyl )ether

*d8-Naphtha leneNitrobenzene-05 (SURR)Ni t robenzeneNi t robenzeneN i t robenzeneI sopho rone2-Ni t ropheno 12-Ni t ropheno 12 ,4-Dimethylpheno 1b is (2-Ch loroethoxy)methane1,2, 4- Trich lorobenzene2 ,4-Dich lo ropheno 1Benzo i c acidBenzo i c acidNaph t ha 1 eneNaphtha lene

11448111111111112121112121112121213131313131313131315131313141414141515151515151515

.96

.86

.90

.58

.41

.30

.34

.47

.83

.00

.53

.83

. 00

.53

.83

. 00

.53

.55

.46

.69

.42

. 01

.48

.01

.48

. 01

.42

.78

.69

. 01

.75

.52

.52

.52

.70

. 05

.29

.70

.50

.46

.72

.50

..a4

3813234

215354349351357375383409375383409375383409410455466453433456433456433453569466433469507507507516533545565555554566555?1

1584852003423687

263718290198335063322487M30739430038530320829767430038530320829767430038530320829767421940620874746968117586227062286693227062286693670753701959481930453516453829996918414

6610091199517355228806930790427102124050850491139189;11789^

7-bSttVo j'

40551

51495050504950494649484950496347105050634253372040512851351351515050551850.

V2

. 00

.83

. 03

.86

. 19

.60

.71

.30

.60

.07

. 15

.99

.45

.55

.61

. 07

. 16

.86

.58

.71

.36

.08

.23

. 16

.23

.67

.79

. 00

.76

.37

.72

. 18

.98

.58

.85

.77

.45

.91

. 15

.26

.34807!.42


911001008286918288886589979595969596857838957086609510010094916381639755799486959892898991

174

QUANT REPORT Page

Operator ID: KU0786Output File: "P9672::ULData File: >P9872::U3Name: SSTD50Misc: IFB/BNA 50 PPM

ID File: IP0085::PFTi t l e : IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900904 17:29

Compound

Quant Rev: 7 Quant T i meIn jected at:

Dilut ion Factor

900905 19:17900905 16:30

1.00000

BTL* 2


28)28)28)29)29)30)30)31)31)32)33)34)34)35)35)36)37)37)37)38)39)40)41)42)42)43)44)45)46)47)47)47)47)47)48)49)50)50)51)51)52)53)54)

4-Chloroani 1 ine4-Ch loroanilme4-Chloroani 1 meHexach lorobutad leneHexachlorobutadiene2-Methylnaphthalene2-Methylnaphtha lenep-Chloro-m-cresolp-Chloro-m-creso 1

*dlO-AcenaphthaleneHexachlorocyclopentadiene2 ,4 ,6-Tr ich loropheno 12,4,6-Trichlorophenol2,4,5-Trichlorophenol2,4,5-Trichlorophenol2-Fluorob ipheny 1 (SURR)2-Chloronaphthalene2-Chloronaphthalene2-Ch loronaphtha lene2-N 1 1 roan i 1 i neDimethyl phthalateAcenaphthylene2,6-Dmitrotoluene3-Ni t roan i 1 me3-Ni t roan i 1 meAcenaph t hene2,4-DinitrophenolDibenzof uran2,4-Dmitrotoluene4-N i t ropheno 14-N 1 1 ropheno 14-Ni t ropheno 14-Ni t ropheno 14-N i t ropheno 14-Nitroani 1 ineDie thy 1 phtha lateF 1 uo r eneF 1 uorene4-Ch 1 oropheny 1 phenyl ether4-Ch loropheny 1 phenyl ether2 ,4,6-Tr ibromopheno 1 (SURR)1 ,2-Diphenylhydraz me

*dlO-Phenanthrene

15151615161818171721181919191919191919202020202121212121222223232323232323232223232325

.50

.84

. 15

.99

.50

.02

.33

.80

.86

.32

.77

. 04

. 16

. 04

.16

.30

. 04

. 16

.51

. 00

.79

.83

.95

.32

.93

.44

.65

.93

. 14

.83

.01

. 11

.28

.52

.28

.05

.01

.85

.83

.09

.83

.60

.92

5555725875796046796946686718417167297357297357427297357527768158178238418718478578718819159249299379499379269249659159289649531067

3670974673377612039

154463426655

2203238754

2056294005156687173165173271173165173271532678183346054

4947261662265547687446881289931078459948

47807348406665199151093264832318136996098834579897460277460648424719044

22565876744

553160 ,,355075-'

1658.

5053.

61.

404956565353471.

4857495051565

50585252454231014494853.

452555340

633.82.29673.99.75278.29528.00.46.55.59.27.31. 06.79591.30.80.76.85.79.03.17.26.83.83.40.46.38.05.26. 04.78.36.83496.42.37.94.45. 00


68656389988177

10010096939896989697555992849998801001009610091831001001001001009293968595819875•99

175

QUANT REPORTOperator ID:Output File:Data File:Name: SSTD50Misc: IFB/BNA 50 PPM

KU0786~P9872::UL>P9872::U3

Quant Rev: 7 Quant TimeInjected at:

D i l u t i o n Factor;

Page 3

900905 19:17900905 18:30

1. 00000

ID File: IP0085::PFT i t l e : IFB/BNA, PP/BNA, TCLBN1

Calibration: 900904 17:29

Compound

Last

R.T. Scan*55) 4 ,6-D in i t ro-o-creso 156) N-N i t rosod ipheny 1 am me56) N-N i t rosod i pheny lam i ne57) 4-Bromopheny 1 phenyl ether58) Hexach lo robenzene59) Pen t ach 1 oropheno 160) Phenanthrene60) Phenanthrene61 ) Anthracene61) Anthracene62) Di-n-butyl phthalate63) Fluoranthene63) Fluoranthene64 ) Pyrene64) Pyrene65) *d!2-Chrysene66 ) Benz id ine66 ) Benz id ine67) Terphenyl-D14 (SURR)68) Butyl benzyl phthalate69) Benzo (a )an t hracene69) Benzo (a )an t h racene70) Chrysene70) Chrysene71) 3 ,3 ' -D ich 1 orobenz id ine72) b is (2-Ethy Ihexyl )phtha late73) «d!2-Perylene74) Di-n-octyl phthalate75) Benzo (b ) f luo ran thene75) Benzo (b ) f 1 uoran t hene75) Benzo (b ) f 1 uo ran t hene76) Benzo (k ) f 1 uo ran thene76) Benzo (k ) f 1 uoran thene76) Benzo C k ) f 1 uoran thene77) Benzo (a )pyrene77) Benzo C a )pyrene77) Benzo ( a )py r ene78) 1 ndeno ( 1 ,2 , 3-c , d )pyrene79) Dibenzo ( a , h )an t hracene79) D ibenzo ( a ,h )an t h racene80) Benzo ( gh i ) pe ry 1 ene

, , , , , _j>_. a i t v-

23.44 94523.11 92923.52 94924.60 100225.01 102225.60 105126.00 107126.15 107826.00 107126.15 107828.18 117829.75 125530.44 128929.75 125530.44 128934.30 147925.58 105025.92 106731.09 132132.84 140734.24 147634.38 148334.24 147634.38 148334.28 147834.81 150438.58 168936.64 159437.46 163437.54 163838.39 168037.46 163437.54 163838.39 168037.46 163437.54 163838.39 168042.40 187742.50 188243.48 193043.50 1931

Hrea

663902321028179812535514813464178M485303505851485303505B514478673255963263203255963263201177231081945552211403107498173019155125173019155125476441312187323116431713260297797998691326029779799869132602977979986983944606352057:71115;,

Cone Lln i t ;

47.82 UG/ML4.19 UG/ML50.90 UG/ML52.68 UG/ML50.84 UG/ML49.93 UG/ML49.76 UG/ML51.86 UG/ML47.98 UG/ML50.01 UG/ML38. 07 UG/ML42.58 UG/ML42.68 UG/ML43. 15 UG/ML43.25 UG/ML40.00 UG/ML59.84 UG/ML251.96 UG/ML48.26 UG/ML47.28 UG/ML50.29 UG/ML45. 09 UG/ML56.54 UG/ML50.69 UG/ML64.26 UG/ML51.42 UG/ML40.00 UG/ML51.05 UG/ML57.50 UG/ML42.41 UG/ML43.31 UG/ML52.39 UG/ML38.64 UG/ML39.46 UG/ML65.59 UG/ML48.37 UG/ML49.40 UG/ML50.16 UG/ML49.68 UG/ML1.69 UG/ML

49.11 UG/ML

s q

7576989097Q j£7 O

9797O -ty O

96o /7t>Q 7 6o .7*6O P7 t?

99O £.7 O

100100959210010010010085878497918989949292939091100100100100

176

BBSEMIUOLATILE INTERNAL STANDARD AREA SUMMARY



Lab File ID (Standard): >P9852 Data Analyzed: 09/04/90

Instrument ID: GC/MS P Time Analyzed: 1619

0102030405060708091011121314151617IB1920211221

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

SBLK01A4376A4377A4377MSf\ s, -T -p-purarN

ISKDCB)AREA *

159147

316294

7957?

1846631677181752591696461 JO "p.<O

RT

11.99

11.9711.9812. 0012. 00•f^^i y j

IS2CNPT)AREA #

601208

1202416

300604

706682596875628868609666d1" 1 Q QfT ~^

RT

15.84

15.8215.8115.8215.631 c riii

I S3 CANT)AREA *

250822

501644

125411

354881268053281694275078AC f /, r" i

RT

21.37

21.3821.3621.3621.37

151 (DCB) • l,4-Dichlorobenzene-d4152 (NPT) - Naphthalene-d8153 (ANT) - Acenaphthene-dlO

UPPER LIMIT - + 10OXof internal standard area.LOUER LIMIT - - 50*of internal standard area.

page

Column used to flag internal standard area values with an asterisk.

' of /

FORM UII I SU -1 1/87 Rev.

177

8CSEMIUOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: ETCNJ Contract: ___________

Lab Code: Case No.: ____ SAS No.: SDE No.:



01020304050607080910111213141516171819202122

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

SBLK01A4376A4377A4377MS043771 ISO

IS4CPHN)AREA #

303873

607746

151936

5.93908350361369837343488TT O 1-1 ~r n •>

RT

25.97

25.9825.9625.9825.99O C AO

IS5CCRY)AREA #

122117

244234

61059

346705*182673182568172147O *"! A i A 3 1

RT

34.37

34.3934.3634.3634.371/i T 4

1 56 (PRY)AREA #

65107

130214

32554

268737*125295131870*119193i r"iX~ ** ••— ™* —

RT

38.67

38.6938.6838.6838.6738.68'

154 (PHN) - Phenanthrene-dlO155 (CRY) - Naphthalene-d8156 (PRY) - Perylene-dl2

UPPER LIMIT - + 100*of internal standard area.LOWER LIMIT - - 50*of internal standard area.

# Column used to flag internal standard area values with an asterisk,

page ' of _j__

FORM UII I SU -2 1/87 Rev.

178

BBSEMIUOLATILE INTERNAL STANDARD AREA SUMMARY





01020304050607080910111213141516171819202122

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

SBLK01A4377A4377MSD

ISKDCB)AREA #

158485

316970

79243

182387214816194160

RT

11.96

..»..

11.9311.9211.94

IS2(NPT)AREA #

594819

1189638

297409

692666771741745793

RT

15.78

15.7615.7715.77

I S3 (ANT)AREA #

294005

588010

147002

363277375518390503

RT

21.32

21.3221.3021.31

151 (DCB) - l,4-Dichlorobenzene-d4152 (NPT) - Naphthalene-d8153 (ANT) - Acenaphthene-dlO

UPPER LIMIT - + 100\of internal standard area.LOWER LIMIT - - 5OXof internal standard area.

# Column used to flag internal standard area values with an asterisk.

Pa9e / of /

FORM U I I I SU -1 ^ 1/87 Rev.

179

8CSEMIUOLATILE INTERNAL STANDARD AREA SUMMARY





01020304050607080910111213141516171819202122

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

SBLK01A4377A4377MSD

I 54 (PHN)AREA #

355075

710150

177538

S'tea fO584262562635

RT

25.92

O&-VLJ25.9125.92

IS5(CRY)AREA #

117723

235446

58861

3?)SJf *315171*218938

RT

34.30

3</.3/

34.2934.28

1 56 (PRY)AREA #

73231

146462

36615

^^/fc*230034*138885

RT

38.58

3S.&P38.593 8 . 5 8

154 (PHN) - Phenanthrene-dlO155 (CRY) - Naphthalene-d8156 (PRY) - Perylene-dl2

UPPER LIMIT - + 100*of internal standard area.LOWER LIMIT - - 50*of internal standard area

page

Column used to flag internal standard area values with an asterisk

' of /

FORM UII I SU -2 1/87

180

ETC

RAW QC DATA.

S Data Fil«: >P9711::U5

ii»c: OFTPPOperator: KU0786 D«t«/Tim«: 8x25/90 14:18

BTL* 1

Fil« >P9711Bpk Ob 1M.

110-

ie»

' 99-

99.

78-

6fr

5»-

46-

3»

ae-

i»

»• i

51/

1 ,

X

,5»

69

NRtl

187\

-Jiee(|

lt«

141 ^.(^ j^Lise a

19t*r

255X

Ili 1

a

1be as*

DFTPP Se»n 5446.6B Bin.

»

44S\

78/

T T r TI3*t 361 4«*

•ii«

•!••

9«

•••

•79

•«•

•9B

•4t

•36

•ze

•is

<

182

IS Data Film: >P9711::U5

•lama: . . . . . . . . . . . . . . . . . . . . Operator: KU0786 DataxTim*: 8x25x90 14:18i i»cs DFTPP BTL* 1

•P9711544 NRM

DFTPP

- i l a : >P9711 Scan #:

Int. mxz

544 Ratn. t ima: 6.65

Int . mXz Int . Int . mXz Int.

37. .00?8.003 9 . 0 0•*4. 005 0 . 0 051.005 2 . 0 05 5 . 0 055 .905 7 . 0 057.9061 .006 2 . 0 06 3 . 0 06 4 . 0 064.9067.0068.90-o. oo73. 1074.0075 .0076. 1077 . 0 078.007 9 . 0 09 0 . 0 080.9082. 00P ' . O O85. 0086. 0036.9087.9039. 0093.9091.909 3 . 0 093.8595 e«>97.0597.9598.8599.95

.00.95102.95

.231

.7463.595

.92412.52045. 052

2.144.323

1.4933.509

.140.504.679

1.647.244.777.108

51.855.295.541

4.2046.9892.287

42.3033.1003.2662.4923.283

.786

.798

.598

.873

.349

.155

.140

.850

.8374.761

.347

.161

.1633.6652.737

.2941.647

.671

103.85104.95106.95107.95109.95110.95111.95115.15116.95117.95121.95122.95123.85124.95126.95127.95128.95129.95130.95131.95132.75133.85134.95135.95137.05137.85138.85140.05140.95141.9*142. tf143. Mr-145. 9mA14*.f*v147. 99148.95149.85151.05151.95152.95153.85154.90155.90156.90157.80158.90

.9991.080

12.4691.794

28.8853.895

.542

.0728.785

.733

.8271.345

.634

.62844.811

3.44620.327

1.690.274.119.099.597

1.510.568.622.179.125.234

2.259.824.529.138

. .4431.2122.S42

.506

.157

.299

.205

.739

.6191.2571.479

.378

.359

.285

159.90160.90161.90163.90164.80166.00166.90168.00168.90169.90170.90171.90172.90173.90175.00175.90176.90178.00178.90179.90180.90182.00183.00184.00185.00185.90186.90188.10188.90189.90190.90192.00193.00194.00195.90197.90198.90199.90201.40203.00204.00204.90206.00207.00207.90

1

31

1

22

1102

1

2100

6

24

192

.722

.067

.307

.146

.862

.606

.800

.669

.273

.166

.192

.345

.449

.873

.507

.508

.909

.303

.986

.014

.994

.193

.161

.295

.475

.849

.960

.311

.652

."99

.304

.894

.002

.192

.880

.000

.914

.444

.627

.630

.760

.543

.848

.590

.605

208.90211.60214.90215.90216.85217.85220.85222.85223.95224.95226.95227. 85228.85230.95233.05233.95234.95235.85236.95238.85240.85241.95242.95243.95244.95245.95246.85248 . 85251.95252.95254.95255.95256.95257.95258.95264.95265.95271.95272.95•i ) 952x4.95275 . 95276.95277.75282.90

5

61

1023

811

415

2

13

1921

.172

.862

.208

.419

.033

.605

.023

.045

.364

.370

.886

.640

.900

.389

.073

.227

.297

.201

.316

.145

.244

.525

.762

.129

.198

.339

.299

.325

.128

.205

.478

.898

.413

.263

.315

.671

.114

.097

.169

.450

.145

.619

.263

.169

.137

284.00254.90293.00295.80296.90298.00302.90314.00314.90315.90320 .90321.80322.90324 .00326.90327.90331.80333.00333.90335.00340.95345.95351.95352.95353.95364.85365.85370.95371.95372.75382.95389.95390.95401.95402.90403.80420.90422.00422.90423.90438.70440.90441.90442.90443.90

.102

.253

.3163.975

.609

.089

.568

.159

.486

.324

. 144

.1291.723

.317

.252

.167

. 101

. 169

.860

.280

.163

.302

.409

.338

.5451.551

.230

.138

.869

.193

.240

.125

.107

.372

.418

.129

.372

.5473.756

.651

.06510.22366.24512.650

1.219

183

1S Data Pilau >P9711::U5

>lam«: .................... Operator: KU0786ls»c: DFTPP

D«t»XTin»: 8x25x90 14:18BTL* 1

686666-

866886-saaeea-488666-

448888-

368688-

32B686-386868-

348888-

286888-168888-

120888-

86888-

48888-

a-

9711 30.6-468.8 MU. TJCifa eaa afa 4fa saa

4.4 4.8 9.8 S.t 6.6 6.4 '

«66 766 6f6

•

6.8 7.Z 7.6 8.1

•iaa

•99

•99

•79

•69

•56

•48

38

-ee

la

•91

184

MS Data File: >P9851::U2

Name: .................... Operator: KU0786disc: DFTPP

Date/Time: 9/04/90 16:04BTL* 1

T i l * >P9851Bpk fib 60088.

65000-

60080-

65008-

50000-

45000-

40080-

35000-

30000-

25000-

28000-

15000-

10000-

6000-

cu.

X51

1 L

69S

198

127

160

\ lJ100

\

186\

141 1h i t i 1 Aj l

255\

ii 1

DFTPP Sc»n 5016.45 B in .

442X

27S

i j160 200 260

f

*? /3 3« 403L I / » x / J

•110

•100

•90

*0

•70

<0

•60

•48

-30

•20

•10

A300 360 400

185


Name: .................... Operator: KY0786Misc: DFTPP

Date/Time: 9/04/90 16:04BTL* 1

>P9851501 NRM

DFTPP

"ilc: >

m/z

37.0037.9039.0040.0040.9043.0043.8048.9050.0051.0052. 0055.1055.9057. 0057.9060.9061.9063. 0065. 0067. 0068.9070. 0073. 0074.0074.9076.0077.0078.0079. 0080.0080.9081.9083. 0085.0085.9086.9091. 0092.0092.9093.9596.0597.8598.9599.95

P985

In

,

4.,

.

•

,

.

12.47.2.•

1.3..

a

•

1..

.

54.,

B

4.6.2.40.2.3.2.3.,

B

.

,

B

,

,

4.f

.

3.2.

B

1 £

t .

251762690201379185328473385916215428456678143654729531887186587318356146672170873894368303202800902584799341757789194371238502580270

Scan *:

m/z

100.95101.95102.85103.95104.95106.95107.95109.95110.95111.85115.95116.95117.85119.95121.95122.95123.95124.95126.95127.95128.95129.95131.05133.95134.95135.95136.95137.65138.85139.95140.95141.95142.95143.95144.25145.75146.95147.95148.85150.95151.55152.95153.95

503

Int.

1.508.120.528

1. 123.977

11.3352.02730. 0363.774.416.767

6.892.601.148.637

1.296.508.538

41.3793.36817.1171.516.320.526

1.291.499.651.216.150.218

1.751.885.506.136.128.348

1.0501.623.401.310.200.536.434

L Re t n .

m/z

154.90156.00157.10157.90159.00159.90161. 00161.80164.90166.00166.90167.90168.90169.90170.20170.80171.90172.90173.90174.90175.70176.90178.00178.90179.90180.90183.80184.90185.90186.90187.90188.90190.90191.90192.90193.90195.00195.90197.90198.90199.90201.30202.90

, t ime :

Int .

.9591.736.378.388.288.574.799.270.707.729

3.3901.408.310.125.098.210.300.451.744

1.090.486.742.306

2.2251.586.914.243

1.3089.5682.596.256.572.343.809.962.186.230

2.724100.0006.386.428.657.506

6.

m

203204206207208209210214215216217220222223224225226227228230233234236238240241242243244245246248252254255256257258264265272273274

45

/z

.90

.90

.00

.00

.00

.00

.90

.90

.90

.85

.85

.85

.95

.95

.95

.95

.85

.85

.95

.95

.85

.95

.85

.95

.85

.85

.95

.95

.95

.85

.85

.75

.95

.95

.95

.85

.95

.95

.95

.95

.95

.95

.95

Int .

2.2254. 12617.5442.388.506.245.797.173.411

4.460.592

6.3691.1359.7162.433.255

3.210.506.884.341.176.190.346.196.185.453.596

8.2431.0071.163.285.359.136

34.9494.969.388

1.658.258.586.1161.1273.27919.679

m/z

275.95276.95277.95281.00283. 00284.90292.90295.90296.90302.90314.00314.80316.00320.80322.90324.10326.90327.90331.90334.00334.90340.95345.95351.95352.85353.95354.85355.05364.85365.85371.95372.75382.95401.95402.90403.80420.90422.90423.90440.90441.90442.90443.90

Int .

2.6841.082.158.120.160.198.341

3.398.563.446.228.354.266.151

1.649.251.281.150.131.774.258. 168.311.424.293.523.121.115

1.325.161.719.163.261.271.396. 123.373

3.227.639

8.60962.64111.5661. 045

186


Name: .................... Operator: KU0786Misc: DFTPP

Date/Time: 9/04/90 16:04BTLt 1

Fil* >P

520000-460800-

440000-

406000-

360600-

320000-

2B0000-

240000-

260000-1

160000-

126000-

80000-

40006-

0-

96E1 36.0-450.0 »»u .100 206 306 400 S

DFTPP

0 600 700 80,6

Ji4.'4 ' 4.'6 ' S'.2 ' E.'6 ' 6.'e ' fcU ' 6ls ' ?'.£ ' 7\f> ' el

•tee

•30

•60

•70

•68

•66

r40

•36

•2e

•IB

-ee

187


N=ime: .................... Operator: KU0786M i s c : DFTPP

Date/Time: 9/05/9G 18:14BTLlt 1

File >P9671Epk Ob 77888.

•e00ee-

70060;

bWKK*-

50000-

40000-

:3o0eo:

20*0*-

leooo-

*:

C

L

i

ii.

x

ise

69'

1

L.1Jlee

.

2?

L

186\

148

156U

198

255N^

j lit»i .1 .ftlb> 4 ..

DFTPP Scan 5046.40 m i n .

[-110

442

\

275

' • -260 250

. , , . , . . , . . . . , . . . .306 356 460

-ie0

0

-S0

•e,*

-40

-30

-20

-10

188

MS Data F i l e : >P9871: :

n i sc :

>P9B71504

DFTPP

NRM

^ i la: >P9871 Scan #:

m/z

35.9037.0038.0059. 0060. 0040.9043. 004.} .9044 . 9050. 0051.0052. 0055. 0056. 0057.0057.9060.9062. 0063.0063.9065. 0067. 0068.9069 . 9070.90?3. 0074. 0075 . 0 076. 1077. 0078 . 0 079 . 0 0HO. 00H 1 . 0 1181.9083. 0084. 0085. 00H5.90H6 . 90SB. 0090.9092. 00^2.9093. 85V4.95

Int. m/z

.104 95.85

.229 97.95

.824 98.954.316 99.85.248 100.95.291 102.95.148 103.95.657 104.95.141 105.95

12.030 106.9547.566 107.952.483 109.95.371 110.95

1.583 111.853.256 115.95.172 116.95.496 117.95.616 118.95

1.638 121.85.302 122.95.704 123.95.139 124.95

55.310 126.95.342 127.95.103 128.95.478 129.95

4.170 130.956.626 131.852.077 133.8541. 054 134.952.763 135.953.156 137.052.297 139.953.093 140.95.750 141.95.749 142.85.214 143.85.628 145.95

1.005 146.95.437 147.95.135 148.85.799 151.15.736 151.35

4.433 151.95.300 152.95.09U 153.95

:U3

KV0786 Date/Tim«i 9/05/90BTL* 1

18: 14

DFTPP

504 Retn

In t . m/z

.245 154.903.160 156.002.484 156.80.271 157.80

1.562 158.90.524 159.90.936 160.90.967 161.80.381 164.00

11.504 164.901.627 166. 00

29.622 166.903.839 167.90.425 168.90.723 170.10

7.096 171.00.539 171.90.125 172.90.671 174.00

1.285 175.00.624 175.80.534 177.00

41.793 178.003.324 178.9016.522 179.901.579 180.90.309 183.90.167 184.90.460 185.90

1.312 186.90.497 187.80.588 188.90.230 190.90

1 .837 191 .90.687 192.90.406 193.90.143 195.90.315 197.90.887 198.90

1.860 199.90.398 201.40.298 202.90.297 203.90. 164 204.90.588 206.00.517 207. 00

. t ime : 6.40

Int. m/z

1. 114 207.901.584 208.90.389 210.90.351 215. 10.281 216.85.544 217.85.835 219. 05.268 220.85. 130 222.95.636 223.95.624 224.95

3.364 225.951.588 226.85.334 227.85.132 228.95. 175 230.95.285 233.95.392 234.95.715 235.851.394 236.85.467 240.85.718 241.95.325 242.95

2.464 243.951.764 244.95.903 245.95.262 246.85

1.500 248.8510.256 252.852.949 254.95.295 255.95.643 256.95. 368 257.95.815 259.05.926 259.95.211 264.85

3.021 265.95100. 000 270.756.586 272.05.546 272.95.517 273.95. 399 274.95

2.540 275.954. 184 276.9518.627 277.952.418 282.90

In t . m/z

.611 284.90

.182 292.90

.801 295.90

.175 296.904.198 302.10.612 302.90.083 303.90

6.906 314.00.967 314.90

9.855 315.902.511 321. 00

x .351 321.903.219 323.00.494 323.90.864 326.90.411 327.90.243 333.00.236 334.00.190 334.90.284 340.85.232 345.85.404 351.95.702 352.95

9.461 353.951.087 354.951.156 364.85.316 365.85.321 371.05.137 371.95

40.160 372.955.643 382.95.380 389.95

2.063 390.85.307 391 .95.089 401.85.660 402.90.125 403.80.108 420.90.136 421.90

1.417 422.903.770 423.9022.679 440.902.682 441.901.372 443.00.231 443.90. 154 444.80

Int.

.253

.2933.972.598.126.460.146.217.452.267.158. 089

1.700.300.273.135.185.971.279.200.276.394.344.573.108

1.840.239.145.901.196.217. 121.109. 100.312.494.195.484.440

4.075.751

11.31679.61214.7021.403.069

89

M-3 Data F i l e : >P9871::U?

Name: .................... Operator: KU0786 Date/Time: 9/05/90 18:14M i s c : DFTPP BTLtt 1

File --P9871 35.0-4E0.0 amu . DFTPP

£68808-

520000-

480808-1

400880-

360800-

320806-

248000-

200060-

i20eee-80000-

40000--

e-

180 zee 380 400 see 6ee ree see

111 .

.0 4.4 4.6 5.2 5.6 6.B 6.4 6.6 7.2 7.6 6.

-100

-90

•ee

-7 if

-te

€0

+•

-30

20

-10

-fle

190


Lab Name: ETCNJ Contract: _______

ERA SAMPLE NO.

ISBLK01I

Lab Code: Case No.: ____ SAS No.: 'SDG No.:

Matrix: (soil/water) SOIL Lab Sample ID: QC70246C

Sample wt/vol: 30.0 (g/mL) G Lab File ID: >P9853

Level: (low/med) LOUI Date Received: 08/23/90

Moisture: not dec. 0 dec.


GPC Cleanup: (Y/N) Y

CAS NO.

pH: 7.0

COMPOUND



Dilution Fac tor

CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG Q

l*DB-9^-2 ——111-44-4 ——95-57-8 ———541-73-1 ——106-46-7 — -100-51-6 ——Q f- cr n 1

95-48-7 ———i n o ^ n 1

106-44-5 ——621-64-7- —i —} "70 i98-95-3- --78-59-1 ——B8-75-5 ———105-67-9 ——65-85-0 ———111-91-1 ——120-63-2 ——120-82-1 ——91-20-3 ———106-47-8 ——87-68-3 ———59-50-7 ———91-57-6 ———77_47_4_ ——88-06-295-95-4----91 58-7 ——88-74-4 ———131-11-3 ——208-96-8 — -606-20-2 ——

-----Pheno 1_____bis(2-Chloroethul )ether-----2-Chlorophenol-----1,3-Dichlorobenzene-----1,4-Dichlorobenzene_____Benzyl alcohol-----1 .2-Dichlorobenzene-----2-Methylphenol

-----4-Methylphenol_ _ _ _ _ N _ N it roso-d i-n-p ropy 1 a mine _

-----Nitrobenzene----- Isophorone— ---2-Nitrophenol-----2, 4- Dime thy 1 phono 1-----Benzoic acid__ — -bis(2-Ch loroethoxy) me thane _-----2,4-Dichlorophenol-----1 .2 .4-Trichlorobenzene-----Naphthalene_____4_Cnloroani i jne

-----Hexach lorobutadiene-----4-Chloro-3-methylpheno 1 ______-----2-Methylnaphtha lene-----Hexachlorocyclopentad iene __-----2 .4.6-Trichlorophenol-----2 .4.5-Trichloroohenol

-----2-Ni t roani 1 ine-----Dimethylphthalate

-----2,6-Dinitrotoluene

113301330133013301330133013301330133013301330133013301330133013301 170013301330133013301330133013301330133013301 17001330117001330 -13301330 3*1

i.IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU1

FORM I SU -1 87 Rev.

1CSEMI VOLATILE ORGAN ICS ANALYSIS DATA SHEET

Lab Name: ETCNJ

Lab Code: Case No.:




% Moisture: not dec. 0 dec.



Con t rac t:

SAS No.:

EPA SAMPLE NO.

I1SBLK01I______________

SDG No.:

Lab Sample ID: QC70246C

Lab File ID: >P9B53





CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

99-09-2---- — — -3-Nitroanil me______________t 170083-32-9---------Acenaphthene_______________I 33051-2B-5---------2,4-Dmitropheno 1___________I 1700100-02-7----- —— 4-Nitrophenol_______________I 1700132-64-9 — - — - — Dibenzofuran________________1330121-14-2--------2,4-Dinitroto luene__________I 33084-66-2 —— - — - — Die thylph thai ate____________13307005-72-3-------4-Chlorophenyl-phenylether_I 33086-73-7————————Fluorene____________________1330100-01-6 ——————— 4-Nitroani 1 me_____________I 1700534-52-l--------4,6-Dinitro-2-methylphenol__I 170086-30-6---------N-Nitrosodiphenylamine (1)_I 330101-55-3--------4-Bromopheny1-phenylether___I 330118-74-1---- — --Hexach lorobenzene___________I 330S7-86-5---------Pentachloropheno 1___________| 170085-01-8---------Phenanthrene________________ I 330120-12-7———————Anthracene__________________133084-74-2---------Di-n-butylphtha late_________I 702 06-44-0--------Fluor an thene________________I 330129-00-0--- —— --Pyrene______________________133085-68-7----- —— -Butylbenzylphthalate________133091-94-1- —— -----3,3 '-Dichlorobenzidme_____167056-55-3---------Benzo (a ) anthracene__________I 330

I 218-01-9 ——————— Chrysene____________________1330I 117-81-7———————bis(2-Ethylhexyl )phthalate__150I 117-84-0--------Di-n-octylpht ha late_________1330205-99-2--------BenzoCb ) fluoranthene________I 330207-08-9--------Benzo(k)fluoranthene_______133050-32-8---------Benzo (a )pyrene______________I 330193-39-5——————— IndenoCl,2,3-cd)pyrene______133053-70-3---------Dibenz(a,h)anthracene_______I 330191-24-2 —— — ---Benzo(g,h,i )perylene________1330

(1) - Cannot be separated from Dipheny1 amine

FORM I SU -2

Q

IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIJIUIUIUIUIUIUIJIUIUIUIUIUIUIU

1/37

192Rev.

IFSEMIUOLATILE ORGAN ICS ANALYSIS DATA SHEET


ERA SAMPLE NO.

ISBLK01Lab Name:ETCNJ

'Lab "Lode : tase No . : ____



Level: (low/med) LOUI

\ Moisture: not dec. 0 dec.


GPC Cleanup: CY/N) Y PH: 7.0


Cont ract:

SAS No.: SDG No.:

Lab Sample ID: QC70246C

Lab File ID: >P9853

Date Received: 08/23x90





ICAS NUMBER

01. 123-79-502.

COMPOUND NAME

Hexanedioic acid, dioctyl esUnknown

RT

33.337.72

EST. CONC

92004200

Q

3J

FORM I Sv-TIC Rev.

TOTAL ION CHROMPTOCRPMFile >P9653 35.0-506.0 *»u.

4

2880000-

2600000-

2400000-

2200000-

2080000-

1800000-

1600000-

1480080-

1280000-

1000000-

880000-

600080-

480000-

280000-A-

I~ I•51 11 Jw 3It"

,1

Be

f *Mijr* •i.

a 12

j

8§^

1 i*

! ;i> s^ i

t i

ji C: '!

J

SBLK01TICeae ( 1200

I I !i

E-| •[• !

i iI \

•

j[

1 B.gJ :

A 2

5 :\ c

I 1! 14 . 9V • i<> ** I JI7

1 " 1

<j

62

16 28 24 26

OC70246C ,0078246, Si

( 1600 ( 2000

t-••«is.

6

im 3

CM £

V N

^5

2 1

32 ' 36" ' "40" ' "44 '

Data File: >P9B53::U2Name: SBLK01Misc: QC70246C ,QC70246,S:M4,30.00,1




BTL* 3

194

QUANT REPORT Page

Operator ID: KU0786Output File: -P9853::ULData File: >P9853:: U2Name: SBLK01Misc: QC70246C ,QC70246,S:M4,30.00,1


Quant Rev:" 7 Quant Time:Injected at

Di lut ion Factor:

900904 18:135900904 17:18

1.00000

BTL* 3


1)3)5)12)17)18)32)36)49)50)52)54)62)65)66)67)68)68)72)73)

•d4-l,4-Dichlorobenzene 11.97 382 1846632-Fluorophenol (SURR) 8.72 222 765027Phenol-05 (SURR) 11.36 352 1136970N-Nitrosodi-n-propylamine 13.72 468 .75322

•d8-Naphthalene 15.82 571 706682Nitrobenzene-D5 (SURR) 13.72 468 484303

•dlO-Acenaphthalene 21.38 844 3548812-Fluorobiphenyl (SURR) 19.34 744 860460Diethyl phthalate 23.07 927 3241Fluorene 23.90 968 161402,4,6-Tribromophenol (SURR) 23.90 968 306500

•dlO-Phenanthrene 25.98 1070 593908Di-n-butyl phthalate 28.22 1180 41554»d!2-Chrysene 34.39 1483 346705Benzidine 25.98 1070 72155Terphenyl-D14 (SURR) 31.19 1326 779357Butyl benzyl phthalate 32.90 1410 3353Butyl benzyl phthalate 33.33 1431 2890bis(2-Ethylhexyl)phthalate 34.88 1507 11277•d!2-Perylene 38.69 1694 268737

40.00129.12147.34

UG/MLUG/MLTUG/Mlr--UG-41L

40. 0069.2840.0062.97

.282

UG/MLUG/Mlr-UG/MLUG/Mb

Sii UG>t1L185.10

40 .002.11

40 .00

UG/MlrUG/MLUG/ML—UG/ML

60.42 UG/ML.501 UC/ML.432 UG^ML1.50 UG/ML"

40.00 UG/ML

8883903893919499928394999697

1009490489182

* Compound is ISTD

195

REFERENCE STRNPPRP SPECTRUMFil* >EBpk Pb

teeee-

e-4

41699999.

ie ee

TflRCET REFERSUB MR

149

ENCE SPECTRfl Sc«n 1tM NOM 26.85 •

' 128 T 1^8 ' 288 ' 24*8 '

814In.

•188

<

SAHPLE SPECTRUM (BACKGROUND SUBTRACTED)File >P9653 SBLK81Bpk Pb 14271.

18e9e" « « «*V OO -X

46 ' ' e'0

QC78246CSUB

149

~]' 184 121 MSB

128 ' 168 i '

,QC78246,SlM4,3e

286 223^ /

' 288 ' ' ' ' ' 24e

Sc«n 118828.22 Bin.

[-166

278

, . , . .T' -8

SAMPLE SPECTRUM (UNPLTERED)File >P9863 SBLK81 QC78246CBpk Ab 14271.

149.

18886-^

*> 71.6 184 121 156r: ,46 86 128 168

,0076246,5 IM4.36

286X

' 288 '

223X

240

Sc»n 118028.22 Bin.

278

hi 88

A

Data File: >P9853::U2 Quant Output File: ~P9853::ULName: SBLK01Misc: QC70246C ,QC70246,S:M4,30.00,1 BTL* 3Quant Time: 900904 18:05 Quant ID File: IP0085::PFInjected at: 900904 17:18 Last Calibration: 900904 17:29

Compound No: 62Compound Name: Di-n-butyl phthalateScan Number: 1180Retention Time: 28.22 mm.Quant Ion: 149.0Area: 41554Concentration: 2.11 DC/MLq-value: 96

196

REFERENCE STANDARD SPECTRUMFil» >JBpk Ab

teeee-

4

7992 TARGET REFER9999. SUB N

149•.

57^ 7j

ENCE SPECTRA Scan 2?M NOM 33.26 •

167

i

848in.

•186

«16 ' 86 ' 126 166 ' 288 ' 246 ' 288

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)File >P9853 SBLK81Bpk Ab 4327.

4666-

- 5^ 7/ 83 IK.fL } ,-/./. 74e' ' ' e'e

QC78246CSUB

149""*"

167' 122 ^•^ .' . \ 1' 126 ' 166

,QC7e246,S:M4,3e

248\

286 ' 248

Scan 156734.66 Bin.

-188

279b J*

288

SAMPLE SPECTRUM (UNALTERED)Fil» >P98E3Bpk Ab 4327

A Oft ft-4866- B?•*-,

46

SBLK61n

"^ i 83 11:il i,^ ^r\ ( i i . , i . r^ i88

QC78246C149">

' 122~? X

167

128 ' 166

,QC78246tSiM4,38

267 246/ \

286 246

Scan 156734.88 «in.

-188

279

' 268

Data File: >P9853::U2 Quant Output File: "SP9B53::ULName: SBLK01Misc: QC70246C ,QC70246,S:M4,30.00,1 BTL* 7Quant Time: 900904 16:05 Quant ID File: IPOOB5::PFInjected at: 900904 17:18 Last Calibration: 900904 17:29

Compound No: 72Compound Name: bis(2-Ethylhexy1)phthalateScan Number: 1507Retention Time: 34.86 min.Quant Ion: 149.0Area: 11277Concentrat ion: 1.50 LJG/flL.q-value: 91

197

QUANT REPORT Page

Operator ID: KY0786 Quant Re-j:Output File: ~P9873::ULData File: >P9873: : U3Name: SBLK01Misc: QC70246C,QC70246,S:M4,3Q. 00,1

ID Fi le: IP0085: : PFTitle: IFB/BNA, PP/BNA, TCLBN1Last

1)3)5)6)12)17)18)32)36)49)50)52)54)62)65)66)67)68)72)73)

Calibration: 900906 09:54

Compound

*d4-l ,4-Dichlorobenzene2-Fluorophenol (SURR)Phenol -D5 (SURR)PhenolN-Ni t rosodi-n-propylamine

«d8-Naphtha leneNitrobenzene-05 (SURR)

*dlO-Acenaphthalene2-Fluorobiphenyl (SURR)Diethyl phthalateF 1 uorene2 ,4,6-Tr ibromophenol (SURR)•dlO-PhenanthreneDi-n- butyl phthalate*d!2-ChryseneBenzidineTerphenyl-D14 (SURR)Butyl benzyl phthalatebis£2-£thylhexyl )phthalate

*d!2-Perylene

R.

11.8.11.11.13.15.13.21.19.23.23.23.25.28.34.*? G

31.32.34.38.

T.

93663234667666323001RAD*»849216319211848058

7 Quant T ime :Injected at

Di 1 ut ion Fac tor:

Scan*

3802193503514655684658417429249f 596510671177147910671322140715031689

Area

1823877545921097796

5654767496926664910353632778503673436

1 O C C16777

3253775952103704433383174205772292295310013

269916

: 900906 09:55: 900905 19:2?: 1.00000

BTL4 3

Cone

40.124.142.' '

•L J ,

40.69.40.64.

•»• 'i171.40.2.40.

^ 11 n

64.s.

1.40.

003234

nn' '00230060n °— ~XQ

57004700C "T

41O X

3500

Units

UG/MLUG/ML-"UG/ML—-tte/MLt_H_l' ' 'I—

UG/MLUG/MLTUG/MLUG/Mbr-UG/ML-UG/MLUG/MCUG/MLUG/ML-^UG/MLUGj'MLUG/ML-1 IO xMI

UG/ML—UG/ML

q89829390389391979892B £\9497969610093879480

* Compound is ISTD

201

Til*Bpk

Bpk*

>P98S3 SBLK81flb 9999.

J 41 / 78 112

"liH...L.-' 48

>BICDBPb 9999.

' se ' ' 'i 2*e

QC70246C ,eC70246.SiN4,30 Scan 1431SUB NRM 33.33 Bin.

157 199212 241 284 313 341 |

T i1er ' 288 ' 248H*x*n*dioic *c id. dice tyl **t*r

* OO

r^irirFileBpk

FileBpk

' '48 88 128r !68

A /

168

199212 2*1

288 248

288' ' 328

(9CJ)

' 368

Scan 138498.08 Bin.

279313 341 378 [

288 ' 328

>BIGHB Hexanedioic acid, »ono(2-ethylhexyl )ester (9CAb 9999.

j 'S' 48

>BICDBHb 9999.

-K40

55

A-78 112

^•^ . /

80 120

129

157,T1 fT 'lie '

199212 241

200 ' 248

268^288 ' 328

Hexanedioic acid, dicyclohexvl ester (9CI)

55 83 »U

88 128

129s*

169

T lie1 '

184 211 229

288 ' 248 '288 ' 328

' 368 '

Scan 138588.88 Bin.

-L368Scan 138838.08 Bin.

I.368

Data File: >P9853::U2Name: 5BLK01Misc Data: QC70246C ,QC70246,S:M4,30 . 00 ,1RT (min): 33.33Scan: 1431Area: 6312340 Rank: 1Semi-quantitative Cone (uncorrected): 275.48 UG/MLSemi-quantitative Cone ( corrected ): 9182.63 ug/kgCalculated using Istd: d!2-Chrysene § 34.39 minutes

BTL* 3

*ru,PRE ,,PBR181,,,1,31. Hexanedioic acid, dioctyl ester (9CI)2. Hexanedioic acid, mono(2-ethyIhexy1)ester C9CI)3. Hexanedioic acid, dicyclohexyl ester (9C1 )

370 C22H4204258 C14H2604310 C18H3004



1.2.~> .

Prob.

82«7627

CAS *

1237954337659849990

CON *

13849138.50.13803

ROOT

"BIGDB" (3,T.rcC'E)"BIGDB

K

125*yy63

DK #FLG

394"ti75

002

TILT \

1-10

62•70" 89

CON

381537

C_I R_IU

374010

L5913

198

Film >P9863 SBLK81 OC78246C ,BC78246 ,S iH4 ,38 Scan 173Bpk Ab 9999. SUB NRM 7.72 Bin.

43

8888-

4888-

8-

69

44 66 69 71 83 10:

'20 38 48 68 68 78 88 98 188

-ee-48

-8

Film >BICDB Cuanidin* (8CI9CI) Scan 1681Bpk Ob 9999. 8.88 Bin.

69J 43 / (.

8888-

4888-

8-

v.18r «/j, t\. / ,,-28 38 48

44 68

VB' ' 68 ' '7'*' ' ' 'e'e' ' ' Ve' ' ' lee

•88

•48

Fil* >BICDB Ac»taBid» (8CI9CI) Scan 1677Bpk Ob 9999. 8.88 Bin.

59

8888-

4888-

8-

43*«s.

28 31

f / ,i rl'f'i ii|'28 38 48

r

61 61

68 68 78 88 98 188

«8

•48

•8

Data File: >P9853::U2Name: SBLK01Misc Data: QC70246C ,QC70246,S:M4,30.00,1RT (min): 7.72Scan: 173Area: 3238740 Rank: 2Semi-quantitative Cone (uncorrected): 124.84 UG/MLSemi-quantitative Cone ( corrected ): 4161.43 ug/kgCalculated using Istd: d4-l,4-Dichlorobenzene § 11.97 minutes

BTL* 3

*ru,PRE ,,PBR181,,,1,31. Guanidine (6CI9CI)2. Acetamide (8CI9CI)

59 CH5N359 C2H5NO



1.2.

Prob. CAS *

25* 11300815« 60355

CON *

15811577

ROOT

"BIGDB"BIGDB

K

2020

DK

4755

*FLG

12

TILT

00

K

5454

CON

4660

C_I R_IU

73

1413

199


Lab Name: ETCNJ Cont ract: _______

ERA SAMPLE NO.

A4377MS


Matrix: (soil/water) SOIL Lab Sample ID: CA4377CS

Sample wt/vol: J5^Z 3O Cg/mL) G Lab File ID: >P9856

Level: (low/med) LOU ,, . Date Received: 08/23/90

* Moisture: not dec. *-«*/<* dec. Date Extracted: 08/30/90


Dilution Factor: 1

Extract ion: CSepF/Cont/Sonc) SONC

GPC-Cleanup: (Y/N) Y pH: 7.0

CAS NO. COMPOUNDCONCENTRATION UN-ITS:(ug/L or ug/Kg) UG/KG

108-95-2 ——————— Phenol_____________________15400111-44-4———————b is C2-Chloroethy l)ether____140095-57-8 ———————— 2-Chlorophenol_____________14600541-73-1 ——————— 1,3-Dichlorobenzene________1400106-46-7———————1,4-Dichlorobenzene________12700100-51-6 ——————— Benzyl alcohol_____________140095-50-1 — ——————1,2-Dichlorobenzene________140095-48-7————————2-Methyl phenol_____________1400108-60-1 ———— —-bisC2-Chloroisopropy 1)ether_|400106-44-5 ——————— 4-Methylphenol_____________1400621-64-7- —————— N-Ni troso-di-n-p ropy lam ine__1260067-72-1 ———————— Hexachloroe thane___________140098-95-3-- —————— Nitrobenzene_______________140078-59-1———— — —Isophorone_________________140088-75-5- — — — — 2-Nitrophenol______________1400105-67-9———————2,4-Dimethylphenol_________140065-85-0———————Benzoic acid_______________1120111-91-1 — —————b is (2-Chloroethoxyimethane__1400120-83-2———————2,4-Dichlorophenol_________1400120-82-1 ——— ——— 1,2,4-Trichlorobenzene_____1310091-20-3 ———————— Naphthalene________________1400106-47-8 ——————— 4-Chloroani 1 ine____________140087-68-3 —————— --Hexachlorobutad iene________140059-50-7———— ——— 4-Chloro-3-methyl phenol____1610091-57-6 ———————— 2-Methyl naphtha Iene________140077-47-4-- — -----Hexachlorocyc1 open tadiene__140088-06-2 —— —— —— 2,4,6-Tr ich loropheno 1______140095-95-4————————2,4,5-Trichlorophenol______1200091-58-7——- ———— 2-Chloronaphthe Iene________140088-74-4———————2-Ni t roan i line____________12000131-11-3 ——————— Dimethylphtha late__________1400 -*2 08-96-8-- ———— Acenaph thy Iene____________1400606-20-2 —— ——— -2,6-Dinitrotoluene_________1400 -__________________________________________I

Q

IUtIUIIUtuIUIUIUIIUIUIUIUIUuIUIUIIUIUIUIIUIUIUIUIUIUIUIUIUI

FORM I S"J -1 Rev.

TOTOL ION CHROMOTOCRRMFile >P

2688888-

2400000-

2288800-

2008880-

1888080-

1688880-

1400000-

1280000-

1808080-

888888-

688000-

400000-

280880-

Ck-

9973 ss.e-see.e *«u. SBLKBI488 888

- 1 I f| i f i j

J til l|i1 | f Y » «;

lil:' s

' 49

8 ' 12 16 ' 28 ' 2

1288

?•

i ^

! ! ,; f ?i •>

62 6

4 ' 28 ' 32

9C78246C ,QC78246 ,S if

1680 2888

i1 I1 "°f2 i36 48 44

Data File: >P9873::U3Name: SBLK01Misc: QC70246C,QC70246,S:M4,30.00,1



Quant Output File: ~P9873::IJL

BTL* 3

200

1CSEMI VOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

IA4377MSLab Name: ETCNJ

Lab Code: Case No.:

Metrix: (soil /water) SOIL

Sample wt/vol: ^5^2 ?O (g/mL) G

Level: Clow/med) LOUJ &T *}/&}&

\ Moisture: not dec. --0" /fa dec .

Extraction: (SepF/Cont /Sonc ) SONC

GPC Cleanup: <Y/N) Y pH: 7.0

Contract:

SAS No.:

CAS NO. COMPOUND

SDG No.:

Lab Sample ID: CA4377CS

Lab File ID: >P9B56




Di lut ion Factor: 1

CONCENTRATION UNITS:Cug/L or ug/Kg) UG/KG

99-09-2 ———— -83-32-9 ————51-2B-5 ———— -100-02-7 ———132-64-9 ——— -121-14-2 ——— -84-66-2 ———— -7005-72-3 —— -86-73-7 ———— -100-01-6 ——— -534 52- 1- _ --B6-30-6 ———— -101-55-3 ——— -118-74-1 ——— -87-B6-5 ———— -85-01-8 ———— -120-12-7 ——— -84-74-2 ———— -206-44-0 ——— -129-00-0 ——— -85-68-7 ———— -91.94-1 ———— .56-55-3 ———— -218-01-9 ——— -117-81-7 ——— -117-B4-0 ——— -205-99-2 ——— -207-08-9 ——— -50-32-8 ———— -193-39-5 ——— -53-70-3 ———— -191-24-2 ——— -

-___3-Ni t roan i 1 ine, . —----Acenaphthene----2 ,4-Dinitrophenol----4-Ni t ropheno 1----Dibenzofuran----2,4-Dinitrotoluene----Diet h-jloht ha late'---4-Chlorophenyl-pheny 1 ether _----Fluorene----4-Ni t roan i 1 ine_ _ ,•---4,6-Dinitro-2~methylpheno 1 _----N-Nitrosodiphenylamine (1 )___•---4-Bromopheny 1-pheny let her __----Hexach lorobenzene•---Pentachlorophanol•---Phenanthrane• ---Anthracene^,----Di-n-but-jlphthelate•---Fluoranthene----Pgrene ,• ---But ulbenzsjlphtha late----3 .3 '-Dichlorobenzidine•---Benzo (a) anthracene----Chrysene.- —— bi»(2-Ethylhexyl )phthalate _----Di-n-octvlphthalate•---Benzo(b)fluoranthene----Benzo Ck ) f luoranthene• ---Benzo(a)pyreneg,---- Indeno C 1 .2 .3-cd )purene---Dibenz Ca .hlanthracene----Benzo Cg .h r i )oer«jlene

11200012800120001170001400131001400140014001200012000140014001400170001400140018114001330014001790140014001811400140014001400140014001400 -1

1IU1IU1IU1IUIUIUIUIUIUIUIU1IUIUIJIU1IUIUIUIUIJIUIUIUIUIUIUIU1


FORM I SU -2 1/87 Rev

203

TOTAL ION CHKOHflTOCROMFiU >P9656

2200000-

2000000-

1000000-

1600000-

1400000-

1200000-

1 000000-

000000-

600000-

400000-

200000-.

A.2

35.0-690.0 «*U. B4377H5 CR*t^77CS .iC70246i5lTIC

t 400 t 0f 0 f 1 2,00 , 1 600 ( 2000

:;

g

i £&

* 1j-. 5 aI

i

( i

II ]s j

9

1

; ;1

i!2

«

i **L

[ !

31T •t

*L.

r

l

••<

1

^

J

f

i

\\ iE

11 ';' t« I•IT 1

p

!L; 1 j

v < F2

& 12 ' 16 ' 20 24 ' 26 ' 32 ' 36 ' 40 ' 4*4 '

Data File: >P9856::U2Nam«: A4377MSMi»c: CA4377CS ,QC70246,S:M4,25.23,1

Id File: IP0085::PFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibrationi 900904 17:29


Quant Output File: /SP9656::UL

BTL* 6

204

QUANT REPORT Page

Operator ID: KV0786Output File: ~P9856::OLData File: >P9856::U2Name: A4377MS

CA4377CS ,QC70246 ,S:M4,25. 23 ,1

Quant Rev: 7 QuantInjected at

Di lut ion Factor

900904 20:48900904 20:01

1.00000

BTLt 6

ID File: IP0085: :PFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900904 17:29

Compound R.T. Scant Area Cone Unite

1)2)3)5)6)7)8)9)10)12)12)14)15)17)18)24)26)31)31)32)36)43)46)47)90)52)54)59)59)62)63)64)65)66)67)72)73)

*d4-l,4-DichlorobenzeneN-Ni trocodimethylamine2-Fluoropheno1 C5URR)Phenol-D5 CSURR)Phenol2-Chloropheno11.3-Dichlorobanzana1.4-Dichlorobenzene1,2-DichlorobenzeneN-Nit rosodi-n-propylamineN-Nitrosodi-n-propylamine2-Methylphenol4-Methylphenol

*de-NaphthalaneNitrobenzene-05 (SURR)1,2,4-TrichlorobenzeneBanzoic acidp-Chloro-m-crasolp-Chloro-m-cresol

*dlO-Acenaphthalene2-Fluorobiphenyl (SURR)Acanaphthane2,4-Dinitrotoluene4-Nitrophenoli/Fluorana2,4,6-Tribromophenol (SURR)

*dlO-PhenanthrenePentachloropheno 1Pentachloropheno1Di-n-butyl phthaiateFluoranthenaPyrane»d!2-ChryseneBanzidinaTerphenyl-D14 (SURR)bi*(2-Ethylhexyl)phthalate*d!2-Perylene

12.00 383 169646 40.00 UG/ML 894.84 31 40377 -10.PI UB>'ML 1008.70 221 127897 23.50 UG/MLr 83

11.41 354 904007 127.52 US/Mb- 9311.45 356 -923722 135.68 UG/ML— 8811.53 360 761171 116.37 UG/ML- 9412.04 385 448802 <P,B? UG/ML 8612.04 385 448802 68.39 UG/ML~ 9512.04 385 448802 69.84 UG/ML 9613.51 457 302456 64.40 UG/ML 7413.73 468 64713 13.79 UC/ML 3813.49 456 4775 r e4-WG/nU 8513.49 456 4775 .828 USxtlL 9615.83 571 609666 40.00 UG/ML 9313.73 468 423903 70.29 UGxMlT 9415.75 567 427679 78.38 UG/ML~ 9615.44 552 8832 3.12 UGXML- 9517.86 671 618082 154.81 UG/ML- 10017.93 674 3797 .9P1 UB;'ML 10021.37 843 275078 40.00 UG/ML 9519.35 744 692227 65.36 UG/(1lr- 9821.49 849 618498 69.50 UG/ML— 9922.20 884 213012 78.96 UG/ML- 9022.08 878 232465 418.10 UG/MLr- 10023.89 967 8767 1.09 UBvML 9123.87 966 161440 125.78 UG/ML— 9225.99 1070 343488 40.00 UG/ML 9925.66 1054 220216 177.10 UG/ML- 9926.44 1092 2687 ~2_1&-U£/ML 9328.23 1180 23201 2.04 UG/Mt—— 9530.50 1292 607889 -02.19 UQ;11L 9830.50 1292 607889 83.28 UG/ML- 9734.37 1482 172147 40.00 UG/ML 9625.99 1070 43113 ItJ.OB UC/ML 10031.18 1325 436719 68.18 UG/ML- 9334.88 1507 7605 2.04 UG/ML"~ 9038.67 1693 119193 40.00 UG/ML 80

* Compound is 1STD

205


ERA SAMPLE NO.

IA4377MSDLab Name: ETCNJ



Sample wt/vol: 2%~2 -*° Cg/mL) G

Level: Clow/mod) LOU

% Moisture: not dec. Jfr* /fa dec.*T 7/Wf o

Extract ion: (SepF/Cont/Sonc> SONC

Cont ract:

SAS No.:

GPC Cleanup: CY/N) Y

CAS NO.

pH: 7.0

COMPOUND

SDG No.:

Lab Sample ID: CA4377CR

Lab File ID: >P9875




Dilution Factor: 1


I108-95-2 ——————— Phenol._____________________15200111-44-4———————bia(2-Chloroethyl)ether____140095-57-8 ———————— 2-Chlorophenol_____________14800541-73-1 ——————— 1,3-Dichlorobenzene________1400106-46-7——————1,4-Dichlorobenzene________12800100-51-6 ——————— Benzyl alcohol_____________140095-50-1 —— ————— 1,2-Dichlorobenzene________140095-48-7————————2-Methylphenol_____________1400108-60-1 ——————— bi5(2-Chloroisopropyl >ether_l400106-44-5———————4-Methylphenol_____________1400621-64-7———————N-Ni t roeo-d i-n-p ropy lam me_1280067-72-1 ——————— Hexachlo roe thane__________140098-95-3 ———————— Nitrobenzene_______________140078-59-1———————— Isophorone_________________140088-75-5———————2-Nitrophenol_____________1400105-67-9 ——————— 2,4-Diro»thyl phenol_________140065-85-0——-————Benzole acid_______________1150111-91-1——————-bia(2-Chloroethoxy)methane__1400120-83-2 ——————— 2,4-Dichlorophenol_________1400120-82-1 ———— —— 1,2,4-Tr ichlorobenzene_____1300091-20-3————————Naphthalene________________1400106-47-8 ——————— 4-Chloroani 1 ine____________140087-68-3 — —————— Hexachlorobutad iene________140059-50-7————————4-Chloro-3-methyl phenol____1610091-57-6 ———————— 2-Methylnaphthe Iene________140077-47-4----- — --Hexachlorocyc1 opentad iene__140088-06-2 ———————— 2,4,6-Trichlorophenol______140095-95-4————————2,4,5-Trichlorophenol______1200091-58-7——— ———— 2-Chloronaphthalene________140088-74-4———————2-N i t roan i line____________12000131-11-3———————Dimethylphthalete__________1400208-96-8———————Acenaphthy Iene_____________I400-*606-20-2 ——————— 2,6-Dinitrotoluene_________I 40OX,

IUIIUIIUIUIUIUIUItuIUIUIUIU13tuIUIIUIUIUIIUIUIUIUIUIUIUIUIU

FORM I SO -1 Rev.

1CSEMI VOLATILE ORGAN ICS ANALYSIS DATA SHEET

ERA SAMPLE NO,

A4377MSDLab Name: ETCNJ

Lab Code:

Cont rac t:

Case No.:


Sample wt/vol: _2Ji*-2 $o Cg/mL) G

Level: (lou/med) LOU

S Moisture: not dec. *& k> dec.<*T 4/tf/fe

Extract ion: (SepF/Cont/Sonc) SONC

GPC Cleanup: CY/N) Y pH: 7.0

SAS No.: SDG No.:

Lab Sample ID: CA4377CR

Lab File ID: >P9875





CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg). UG/KG

99-09-2— ——— —— 3-Nitroani 1 ine___83-32-9 — -- ———— Acenaphthene____51-28-5- ———— —— 2,4-Dinitropheno 1,100-02-7———————4-Nitrophenol___132-64-9 —————— -Dibenzofuran____121-14-2 —————— -2,4-Dinitrotoluene.84-66-2- ——————— Diethylphthalate.

I__12000__12700__12000__18000__1400___13700__1400

7005-72-3——————4-Chlorophenyl-phenylether_140086-73-7———————Fluorene_________________1400100-01-6——————4-Ni t roan i line____________12000534-52-1——————4,6-Dinitro-2-methylphenol_1200086-30-6————————N-Nitrosodiphenylamine (1)_1400101-55-3———————4-Bromophenyl-phenylether__1400118-74-1 — — ——— Hexachlorobenzene_________140087-86-5 ———————— Pentachlorophenol__________1700085-01-8—— ————— Phenanthrene_______________1400120-12-7—— ———— Anthracene______________ 1400

__184__1400__13200__1400__1790__1400__1400

84-74-2————————Di-n-butylphthalate.206-44-0———————Fluoranthene_______129-00-0————85-68-7—————

•Pyrene.------Butylbenzylphtha late

91-94-1 ——— ———— 3,3'-Dichlorobenzidine.56-55-3---------Benzo<a) anthracene____218-01-9————-----Chrysene_________________117-81-7———————bisC2-Ethylhexyl )phthalate__I 100117-84-0———————Di-n-octylph thai ate________1400205-99-2 ————— — Benzo(b)f luo rant none_______1400207-08-9 ——————— BenzoCk)f luoranthene_______140050-32-8 —— ———— -BenzoCa)pyrene_____________1400193-39-5———————Indenod,2,3-cd)pyrene_____140053-70-3 —— — -- — D i benz C a, h) anthracene______1400191-24-2 —— —— — BenzoCg,h,i )perylene_______1400 ;


FORM I SU -2

Q

IUItu1IUIIUtuIUIUIUIUIUIUIIUIUIJIUIIUIUIUIUIJIUIUIUIUIUIUIUI

1/87 Rev,

207

TOTPL ION CHROHflTOCRflMFile >P9075

2608000-

2480090-

99Aaaaa^C£OWW

2999000-

1808888-

1688880-

1488088-

1 288880-

1000000-

800009-

600088-

400880-

200000-.

A-2

3S.8-SOO.O *»u.

. . . W . . . . .

§ I iI ~ '

if12«

•ii

j

' 2

[«.

.Jl

1118al ;• « '% <iIEJ-tf2

|«1! H1

»

7 ^ 1

B4377MSDTICsee t 1200

; ,

f :i ;i ,

4•

4

' ! t

r

[: :

gp 1

476

49

6•

;9 62

6 12 ' 16 ' 20 ' 24 ' 28 '

CR4377CR , BC70246 ,5 If

( 1600 , 2888

s£-

ai£

j"

,V nC ftf Jn F

1 iPry y5 J!

I 2 . .132 ' 3*6 ' 48 ' 44 '

Date File: >P9875::U3Name: A4377MSDMi»c: CA4377CR,QC70246,S:M4,25.23,1

Id File: IP0085:iPFTitle: IFB/BNA, PP/BNA, TCLBN1Last Calibration: 900906 09:94

Operator 10: KU07B6Quant Time: 900906 10:02Injected at: 90090? 21:14

Quant Output File: ^P9B75::«JL

BTL# 5

208

QUANT REPORT Page

Operator ID: KU07B6Output File: ^P9875::ULData File: >P9875::U3Name: A4377MSDM i sc: CA4377CR,QC70246,S:M4,25.23,



Oilut ion Factor

900906 10:02900905 21:14

1.00000

BTL* 5

Compound R.T. Scant Area Cone Units

1)2)3)5)6)7)6)9)10)12)12)12)14)15)17)18)24)25)26)27)3D31)32)36)41)43)46)47)49)50)52)54)59)59)62)63)64)65)66)67)72)73)

»d4-l,4-Dichlorobenzene 11.94 380 194160N-Nitrosodime thylamine 5.37 57 198552-Fluorophenol (SURR) 8.85 228 555297Phenol-05 (SURR) 11.37 352 1119238Pheno1 11.41 354 10424982-Chlorophenol 11.50 35B 9113291.3-Dichlorobenzene 11.99 382 5281381.4-Dichlorobenzene 11.99 362 5281381,2-Dichlorobenzene 11.99 382 52B13BN-Nitrosodi-n-propylamine 13.37 450 62336N-Nitrosodi-n-propylamine 13.47 455 358571N-Ni trosodi-n-propylamine 13.70 466 834032-Methylphenol 13.45 454 52544-Methylphenol 13.45 454 5254*d8-Naphthalene 15.77 568 745793Nitrobenzene-05 CSURR) 13.70 466 5424151,2,4-Trichlorobenzene 15.69 564 5204862,4-Dichlorophenol 15.45 552 3330Benzoic acid 15.43 551 13379Naphthalene 16.00 579 2548p-Chloro-m-cresol 17.85 670 925579p-Chloro-m-cresol 17.89 672 6504

*dlO-Acenaphthalene 21.31 840 3905032-Fluorobiphenyl (SURR) 19.30 741 BB05072,6-Dinitrotoluene 20.90 820 3132Acenephthene 21.43 846 8563252,4-Dinitrotoluene 22.15 881 3696564-Nitrophenol 22.07 877 172975Diethyl phthalate 23.02 924 2524Fluorene 23.84 964 135702,4,6-Tribromophenol (SURR) 23.84 964 260755

*dlO-Phenanthrene 25.92 1066 562635Pentachlorophenol 25.61 1051 361060Pentach loropheno1 26.36 1088 3882Di-n-butyl phthalate 28.15 1176 30182Fluoranthene 30.45 1289 841735Pyrene 30.45 1289 841735

*d!2-Chrysene 34.28 1477 218938Benzidine 25.94 1067 70328Terphenyl-D14 (SURR) 31.11 1321 562601bis(2-Ethylhexyl)phthalate 34.79 1502 12913

*d!2-Perylene 38.58 1688 138889*'

40.00 UG/ML 86•wi.Q'i UC.rEIL 10085.94 UG/ML 87136.32 UG/ML 93131.94 UG/ML 90121.00 UG/ML 92?1. 7*6 UG/ML 8671.09 UG/ML 957?2,4l UC/ML 961IB.19 UG/ML 7870.11 UG/ML 7416.31 tJG/ML ' 38'.944 OG/ML 86..7 0 U&^ML 9440.00 UG/ML 9471.03 UG/ML 9276.58 UG/ML 94.SSS> UC TIL 923.83 UG/ML 87i1JJ UG/ML 83

154.60 UG/ML 1001.09 US/ML 10040.00 UG/ML 9562.23 UG/ML 94•.Plrt UCfML 7567.43 UG/ML 9992.10 UG/ML 82201.48 UG/ML 100T206 U6*'ML 951.11 UC/ML 82

127.91 UG/ML 9540.00 UG/ML 99

177.52 UG/ML 97•4~&L-LLG/ML 962.13 UG/ML 98

01.56 UB/'ML 9781.39 UG/ML 9740.00 UG/ML 96

i74.?6 UB^IIL 10071.55 UG/ML 92

2.65 UG/ML 8840 .00 UG/ML 84

* Compound is ISTD

ETC

r>ESTXOXDE/E»GB DATA

210

ETC

QC

211

2FSOIL PESTICIDE SURROGATE RECOVERY



Level : (LOIO/MED)LQW

SDG No

EPASAMPLE NO.

PBLK01A4376A4377A4377SA4377R

SIf DBC ) #

9290619286

OTHER TOTOUT

00000

1I

010203040506070809101112131415161718192021222324252627282930

SI lDBC) " Dibutylchlorendate

ADUISORYOC LIMITS(20-150)

page 1 of

# Column to be used to flag recovery values* Ualues outside OC l i m i t sD S u r r o g a t e s d i l u t e d o u t

FORM II PEST-2 Rev

3FSOIL PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOUERY



Ma t r i x Spike - EPA Sample No.: A4377 Leva1:(LOW/MED) LOU

COMPOUND

qamma -BHCCLindane 3Hep t ach lorAldr inDie Idr inEndr in4.4--DDT

SPIKEADDED(ug/Kg)

63.41763.41763.417158.541158.541158.541

SAMPLECONCENTRATION

tug/Kg)

.142

.4500. 0001.542

"*1C

1.076

MSCONCENTRATION

(ug/Kg )

59.68849.97648.955139. 172ICO 4. Q 1

MS t OCS ILIMITS

REC *l REC.

94 146-12778 135-13077 134-13287 131-13496 142-139101 123-134

1

111 COMPOUND

i aamma-BHCCLi ndane )1 Hept ach lor1 A l d r i n1 Die Idr int Endrin1 4.4--DDT1

SPIKEADDED(ug/Kg)

63.36663.36663.366158.416158.416158.416

MSD 1CONCENTRATION!

(ug/Kg) 1

57.679 148.201 147.645 1144.921 1150.354 1147.751 1

1

MSDsREC *

91757591

\RPD *

3434

95 1 193 1 8

QCRPD

503143384550

1LIMITS 1

1 REC. 1

146-1271135-1301134-132 1131-1341142-139 1123-13411 1



RPD: 0 out of 6 outside limitsSpike Recovery: 0 out of 12 outside limits

Commen t s : ____________________________________________________ _..

FORM III PEST-2 1/87 Rev.

213

4CPESTICIDE METHOD BLANK SUMMARY

Lab Name: ETCNJ

Lab Code: Case No.

Lab Sample ID: PBLK01



Date Analyzed CU: 09/05/90

Time Analyzed CD: 1239

Inst rument ID CD: QA

GC Column ID (1): DB608

Cont rac t :

SAS No.: SDG No.:

Lab Fil e ID: >QA191

Leve1:(low/med) LOW

Extract ion: CSepF/Cont/Sonc) SONC

Date Analyzed C2):

Time Analyzed (2):

Instrument ID (2):

GC Column ID (2):


0102030405D60708091011121314151617181920212223242526

EPASAMPLE NO.

A4376A4377A4377SA4377R

LABSAMPLE ID

CA4376GCA4377GCA4377GSCA4377GR

DATEANALYZED 1

09/05/9009/05/9009/05/9009/05/90

DATEANALYZED 2

Commen t

page 1 ofFORM IU PEST 1/87 Re<

214

ETC

DATA

215

IDPESTICIDE ORGAN ICS ANALYSIS DATA SHEET

Lab Name: ETCNJ Cont ract:

ERA SAMPLE NO

IA4376


Matrix: (soil/water) SOIL Lab Sample ID: CA4376G

Sample wt/vol: 30.0 Ig/mL) G Lab File ID: >QA193

Leve1: (low/med) LOU Date Received:

Moisture: not dec. 18 dec

Extract ion: (SepF/Cont/Sonc) SONC

GPC Cleanup: (Y/N) N pH: 7.0




CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/kg) UG/KG

319-64-6--- ———— alpha-BHC________319-65-7- —————— beta-BHC_________319-86-8 —— - ——— delta-BHC________58-89-9----——--gamma-BHCCLxndane).76-44-8---------Heptach1 or________309-00-2 ——————— Aldnn___________1024-57-3---—--Heptachlor epoxide959-98-8——————Endosulfan I______60-57-l---~-----Dieldrin_________72-55-9 ———————— 4,4'-DDE_________72-2G-8---------Endrin___________33213-65-9 ————— Endosulfan II_____72-54-8 ———————— 4,4'-DDD_________1031-07-8——--—Endosulfan sulfate50-29-3 ———————— 4,4'-DDT__________72-43-5——--——Methoxychlor______53494-70-5--—--Endrin ketone_____5103-71-9 —————— alpha-Chlordane___5103-74-2-------gamma-Ch1o rdane___8Q01-35-2-------Toxaphene________12674-11-2*-———Aroclor-1016______11104-28-2*- ——— Ar o c I or-1221______11141-16-5 ————— Aroclor-1232______53469-21-9 ————— Aroc lor-1242______12672-29-6--——-Aroclor-1248______11097-69-1 ————— Aroc lor-1254______11096-82-5 ————— Aroc lor-1260______

9.8009.8009.800

800800800800soo

19.4019.4019.4019.4019.4019.4019.409819.4019,4019.401909896989898194194

Q

IIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI UIUIUIUIUI UIUIUIUIUIU

FORM I PEST 1/87 Re-

216

rile >QR193 l.B uu.48B

H4376 ,7 ,18

neeee*

leeBBBfr

eeeeee

seeeee

aeeee*

iseeCR43766 ,0678246 ,S 16

eeee

84 86 38

Data File: >QA193::U6 Quant Output FileName: A4376,7,19 Instrument IDdisc: CA43 76G , QG70 2 46 , S : G3 , 24 . 6 3 , 2 0

QA

Id File: I223QA::USTit le: IFBXPSTXPCB QA DB6 08Leet Cal ibrat ion: 900906 15:13

Operator ID: RLJ8206Quant Time: 900906 16:90Injected at: 900905 14:00

2ul INJ.

217

QUANT REPORT

Operator ID: RUJB206Output File: *QA193::AQData File: >QA193::U6Name: A4376,7,18flisc: CA4376G,QG70246, S:G3,24.63,20

Quant Rev: 7

ID File: I223QA::USTitle: IFB/PST/PCB QALast Calibration: 900906

Compound

DB608

Quant Time!In jected at:

Dilution Factor:Inst rument ID

2ul INJ.

Page 1

900906 16:90900909 14:00

1.00000

R.T. Scant Height Cone Units

19) #Dibutylchlorendate

t Compound uaes ESTD

30.55 1833 322434 .180 UG/ML 100

218

IDPESTICIDE ORGANICS ANALYSIS DATA SHEET

ERA SAMPLE NO.

Lab Name: ETCNJ

Lab Code: Case No.:


Samplewt/vol: 30.0 C g/mL) G

Level: (low/med) LOUJ

^Moisture: not dec. 16 dec.

Extraction: CSepF/Cont/SoncJ SONC

GPC Cleanup: (Y/N) N pH: 7.0

Con t rac t:

SAS No.:

. IA4377I

SDG No.:

Lab Sample ID: CA4377G

Lab File ID: >QA194

Date Received:




CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or ug/Kg) UG/KG

FORM I PEST

Q

319-64-6 -----319-65-7 ————319-86-8 ————58-89-9 ----- -76-44-8 -----309-00-2 -----1024-57-3 ———959-98-8 ————60-57-1 —————72-55-9 ------72-20-8-- ----33213-65-9 ——72-54-8 —————1031-07-8 ———50-29-3 —————72-43-5 ------53494-70-5 - —5103-71-9 -- —5103-74-2 ———8001-35-2 ———12674-11-2 ——11104-28-2 ——11141-16-5 - —53469-21-9 ——12672-29-6 ——11097-69-1---11096-82-5 ——

—— alpha-BHC—— beta-BHC—— delta-BHC---qamma-BHC CL indane )---Hept ach lor— -Aldr in---Heptachlor epoxide---Endosulfan I---Die Idr in—— 4.4'-DDE---Endr in---Endosulfan II—— 4.4'-DDD---Endosulfan sulfate—— 4.4--DDT---Methoxvchlor---Endr in ketone---alpha-Chlordane---oamma-Ch lordane---Toxaphene— -Aroclor-1016— -Aroclor-1221—— Aroclor-1232— -Aroclor-1242---Aroc lor-1248---Aroc lor-1254- — Aroc lor-1260

I19.60019.600(9.60019.60019.60019.60019.60019.6001 19. 00119.001 19. 001 19. 001 19. 00119. 001 19. 001961 19. 0019.60019.6001 1901961961961 Orf.

1961 1901 1901

1IU1LJIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUtuIUIUIUIUIU1

1/87 Rev

219

CHROMfiTOeRflMFile >Qfll94 1.0 «mu. B4377,7,16 CR43776,067^46,

400 800 ieee ieee 2000

1300000-

1100000-

1000004

900090!

700004

600004

D00004

380000:

**4*ee

Data File: >QA194::U6 Quant Output File: "QA194::AQName: £4377,7,16 Instrument ID: QAMisc: CA4377G,QG70246,S:G3,25.22,20

Id File: I223QA::USTi t le : IFB/PST/PCB QA DB606Last Calibration: 900906 19:13

Operator ID: RUI8206Quant Time: 900906 16:92Injected at: 900906 14:40

2ul INJ.

220

QUANT REPORT

Operator ID: RUJ8206Output File: ~QA194::AQData File: >QA194: :U6Name: A4377,7,16Misc: CA4377G,QG70246,S:G3,25.22,20

Quant Rev: 7

ID F i l e : I223QA::USTitle: IFB/PST/PCB QA DB608Last C a l i b r a t i o n : 900906 15:13

Compound

Quant TimeInjected at

Di l u t i o n FactorInstrument ID

2ul INJ.

Page 1

900906 16:52900905 14:40

1.00000QA

R.T. Scan* Height Cone Units

19) *DibutyIchlorendate

# Compound uses ESTD

30.55 1633 289921 .162 UG/ML 100

221

ETC

S TAN D ARD S D AT A.

222

8DPESTICIDE EUALUATION STANDARDS SUMMARY

Lab Name:ETCNJ Contract:


Instrument ID: QA GC Column ID: DB608

Dates of Analyses: 09/04/90 to 09/05/90

Evaluation Check for Linearity

PESTICIDE

ALDRINENDRIN4.4'-DDTDEC

1 CALIBRATION1 FACTORt EUAL MIX A

1 3500800.51 2115200.5

_l 1782400.21 1506150.21

CALIBRATIONFACTOR

EUAL MIX B

3409940.52093450.01754250.01417600.0

CALIBRATIONFACTOR

EvAL MIX C*

3299860.01951690.01616010.01238405.0

% RSD( </-10. OS)

3.04.35.29.B

(1) If > 10.OS RSD, plot a standard curve and determine the ngfor each sample in that set from the curve.

Evaluation Check for 4,4'-DDT/Endrin Breakdown(percent breakdown expressed as total degradation)

0102030405060708091011121314

INITIALEvAL MIX B•EUAL MIX BEUAL MIX B'EUAL MIX BEvAL MIX BEUAL MIX BEUAL MIX BEv-AL MIX BEvAL MIX BEUAL MIX BEvAL MIX BEUAL MIX BEUAL MIX BEUAL MIX B

DATEANALYZED

09/04/9009/05/9009/05/90

TIMEANALYZED

174605151320

ENDRIN

6.08.76.8

4,4'-DDT'

8.411.99.7

COMBINED(2)

(2) See form instructions.

FORM v I I I PEST-1

I ll)

1/67 Rev,

223

BEPESTICIDE EVALUATION FOR STANDARDS SUMMARY

Evaluation of Retention Time Shift for Dibutylchlorendate

Lab NameiETCNJ

Lab Code : Case No.:

Inst rument ID: QA

Cant ract:

SAS No.: SDG No

GC Column ID:DB6Q8

Dates of Analyses: 09/04/90 to 09/05/90

1 EPA 1 LAB SAMPLE1 SAMPLE NO. 1 ID1. ......... | ............

OllEVALA IEUALAQ2IE'JALB IEVALB03IE'JALC IEVALC041 INDA 1 INDA051 INDB 1 INDB06ITOXAPHENE 1 TOXAPHENE07IAR1016 IAR101608IAR1221 IAR122109IAR1232 IAR123210IAR1242 IAR124211IAR1248 IAR124B12 IAR1254 1AR125413IAR1260 IAR126014IPBLK01 IQC7Q223G151 A4639 ICA4639G16IA4459 ICA4459G17IA4460 ICA4460G181A4460S ICA4460GS19IEUALB IEUALB201A4460R ICA4460GR21IA4477 1CA4477G22IA4528 ICA4528G23IPBLK01 IQC7023424IA4714 ICA4714G251 INDA 1 INDA26IA4717 1CA4717G27IA4674 ICA4674G28 1 A4674S 1 CA4674GS29 1 A4674R 1 CA4674GR3QIPBLKQ1 IQC70246G31 IEUALB IEUALB32IA4376 ICA4376G33IA4377 1 CA4/77G34 1 A4377S 1 CA4377GS351A4377R ICA4377GR361 INDA 1 INDA371 INDB 1 INDB38 1 1

DATEANALYZED

09/04/9009/04/9009/04/9009/04/9009/04/9009/04/9009/04/9009/04/9009/04/9009/04/9009/04/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/9009/05/90

TIMEANALYZED*

1706174618261907194720272108214822292309235000300111015102320312035304340515055506360716075608370917095710381118115912391320140014401520160116411722

*D

0. 00.00.00. 00.0.1

0.00.00. 00.00.0.1

1.00.00.00.00.00.00.00. 00.00.00.00.00.00.00.00.00.00.00.0.1.1.1.1.1.1

*

Ua lues outside of QC l i m i t s0.3S for capillary columns)

(2.OK fcr packed columns,

page 1 ofFORM <JI!I PEST-2 1/87 Re224

PESTICIDE/PCS STANDARDS SUMMARY

Lab Name: ETCNJ

Lab Code:

Inst rument ID: QA

Case No.:

Cont ract:

SAS No.: SDG No.:

GC Column ID: DB608

11 COMPOUNDII----""------*lalpha-BHCIbeta-BHC1 de Ita-BHC1 g a mma - BHC ___1 Hept ach 1 or __lAldnn1 Hep t . epox ide1 Endosu 1 fan I_1 Die Id r in _____14. 4 '-DDE1 Endr in1 Endosu 1 fan I II4T4'-DDD1 Endo . su 1 f ate_I4,4'-DDT ____Itlethoxych 1 or__lEndrin ketonela. Ch lordaneIg. Chlordane_1 Toxaphene1 Aroclor-10161 Aroclor-1221_1 Aroclor-1232_1 Aroclor-1242_1 Aroclor-12481 Aroclor-1254I Aroclor-126Q_1

DATECS) OF FROM: 09/04/90ANALYSIS TO: 09/05/90TIMECS) OF FROM: 19 07ANALYSIS TO: 01 11

RT

6.478.5210.408.179.7211.4815.0217.3219.5519.4022.2323.7323.7327.4726.0333.6733.5517.2316.0823.959.856.328.079.8515.6820.4334.00

RTUIINDOU

FROM 1 TO

6.461 6.488.501 8.5310.381 10.428.151 8.189.701 9.73

11.451 11.5114.991 15.0517.291 17.3519.521 19.5819.361 19.4422.201 22.2723.701 23.7623.701 23.7727.431 27.5025.981 26. OB33.641 33.7033.501 33.6017.211 17.2616.061 16.1123.911 23.999.841 9.866.311 6.338.051 8.089.841 9.8615.661 15.7120.401 20.4633.951 34.05

1

*

CALIBRATIONFACTOR

404610121457602539340353974030221002411520203136017318401726090160577013498201687050117184011878401095680704132134016023334402319360313922374401372169248420697610828815449768994

DATE OF ANALYSIS 09/05/90TIME OF ANALYSIS 0917EPA SAMPLE NO.(STANDARD) INDA

RT CALIBRATIONFACTOR

8.179.7211.4815.0217.3219.55

23.73

26.0533.67

397314133408202650041221440019392011877130

1826570

1166080744762

1QNTY/N

YYYYYY

Y

YY

\D

12.210.59.99.012.08.8

3.3

6.45.8

Under QNT Y/N:HD must be lessor equal to 20.

enter Y i.f quantitation was performed, N if not performed.than c/r equal to 15. OS for quantitation, and less than

OX for confirmation.

Determining that no compounds were found above the CRQLquantitation, and therefore at least one column must meet theNote: is a form of

15.OS criteria

For mu,Licomponent analytes, the single largest peak that is characteristicof the component should be used to establish <~e^ention time and SD.Identification of such analytes is based prim^-ily on pattern recognition.

page 1 of FORM IX PEST 1/87 Rev

225

PESTICIDE/PCB STANDARDS SUMMARY

Lab Name: ETCNJ

Lab Code:

Instrument ID: QA

Case No.:

Cont ract

SAS No. SDG No

GC Column ID: DB608

11 COMPOUND1

1 alpha-BHC!h«ta-BHCIdel ta-BHC1 gamma-BHC ____1 Heptach lor __1 A l d r i n1 Hep t . epox idelEndosulfan I_I Die Idr in ____14. 4 '-DDE1 Endr i n1 Endosu 1 fan II1 4r4'-DDDlEndo. aul fate1 4, 4 '-DOT ____1 Me t hoxych lor_lEndrin ketonela. Chlordane1 q t Ch lordaneI Toxaphene1 Aroclor-1016Ifcroc lor-12211 Aroclor-1232IAroclor-12421 Aroclor-1248I Aroclor-12541 Aroclor-12601

DATECSJ OF FROM: 09/.Q4/90ANALYSIS TO: 09/05/90TIME(S) OF FROM: 1907ANALYSIS TO: 0111

RT

6.478.5210.408.179.72

11.4815.0217.3219.5519.4022.2323.7323.7327.4726.0333.6733.5517.2316. 0823.959.856.328. 079.8515.6820.4334. 00

RTU1INDOUI

FROM TO

'6. 468.5010.388.159.7011.4514.9917.2919.5219.3622.2023.7023.7027.4325.9833.6433.5017.2116.0623.919.846.318.059.8415.6620.4033.95

6.488.5310.428.189.73

11.5115.0517.35

1 19.5819.4422.2723.7623.7727.5026. 0833.7033.6017.2616.1123.999.866.338.089.8615.7120.4634.05

*

CALIBRATIONFACTOR

40461012145760253934035397403022100241152020313601731840172609016057701349820168705011718401187840109568070413213401602333440231936031392237440137216924842069761082881544976B994

DATE OF ANALYSIS 09/05/90TIME OF ANALYSIS 1641EPA SAMPLE NO.(STANDARD) INDA

RT

8.179.72

11.4715. 0017.3019.53

23.75

26.0233.65

CALIBRATIONFACTOR

391632131667402608640227840015244801870730

QNTY/N

YYYYYY

1672970 1 Y1

1245940800852

YY

1

SD

10.64.88.212.212. 08.4

.6

13.713.7

Under QNT Y/N: enter Y if quantitation uiasSD must be less than rfr equal to 15.OH foror equal to 20.OS for confirmation.

performed, N if not performed,quantitation, and less than

Note: Determining that no compounds were found above the CRQL is a form ofquant itation, and therefore at least one column must meet the 15.OX criteria

For mu 11 i-umponent analytes, the single largest p<iak that is characteristicof the component should be used to establish retention tame and SfiD.I d e n t i f i c a t i o n of such analytes is based primani • on pelt tern recognition.


226

PESTICIDE/PCS STANDARDS SUMMARY

Lab Name: ETCNJ

Lab Code:

Instrument ID: QA

Case No.:

Cont ract:

SA5 No.: SDG No.:

GC Column ID: DB6G8

11 COMPOUND1!»»....«....»«lalpha-BHC ___Ibeta-BHC ____Idelta-BHC ___1 gamma-BHC ___IMeptachlorlAldrin1 Hept . epox i de1 Endosu 1 fan I1 Die Id pin ____14, 4 '-DDE ____lEndnn1 Endosu 1 fan I I14, 4 '-ODD ____1 Endo , su 1 f at e_I4.4--DDT1 Methoxych lor—lEndrin ketonela. Chlordane_Ig. Chlordane—1 Toxaphene1 Aroclor-1016lAroc lor-12211 Arodor-1232IAroclop-1242IAroclor-1248IAroclor-12541 Aroclor-1260_1

DATECS) OF FROM: 09x04/90ANALYSIS TO: 09x05/90TIME(S) OF FROM:1907ANALYSIS TO: 01 11

RT

6.478.5210.408.179.72

11.4815.0217.3219.5519.4022.2323.7323.7327.4726.0333.6733.5517.2316.0823.959.856.328.079.8515.6820.4334.00

RTLJ I NDOU

FROM 1 TO........ I......

6.46! 6.488.501 8.5310.381 10.428.151 8.189.701 9.7311.451 11.5114.991 15. 0517.291 17.3519.521 19.5819,361 19.4422.201 22.2723.701 23.7623.701 23.7727.431 27.5025.981 26.0833.641 33.7033.501 33.6017.211 17.2616.061 16. 1123.911 23,999.841 9.866.311 6.338.051 8.089.841 9.8615.661 15.7120.401 20.4633.951 34.05

1

CALIBRATIONFACTOR

404610121457602539340353974030221002411520203136017318401726090160577013498201687050117184011878401095680704132134016023334402319360313922374401372169248420697610828315449768994

DATE OF ANALYSIS 09/05/90TIME OF ANALYSIS 1722EPA SAMPLE NO.(STANDARD) INDB

RT

6.478.5210.40

19.3822.22

23.7227.45

33.5517.2316.08

CALIBRATIONFACTOR

392834120787202479201

15705701258880

11705601155840

13521102252800 .2234881

QNTY/N

YYY

YY

YY__

YYY

___

_. _ _

*D

2.93.12.4

2.26.7

.12.7

T?~3.53.6

_

Undep QNT Y/N: enter Y, if quantitation was performed, N if not performed.5fiD must be less than or equal to 15.Of for quantitation, and less thanor equal to 20.OS for confirmation.

Note: Determining that no compounds were found above the CRQL is a form ofquant i taf ' -••" , and therefore at least one co lumjL rr» •.•«*• meet the 15.OX criteria

For mu1ticomponent analytes, the single largest peak that is characteristicof the component should be used to establish retention time and 960.Identification of such analytes is based primarily on pat tern recognition.


227

CMROriPTOeRflttPile >QA16a l.e uu. EVRLR

.,..*?• ... •?• ,,EVBLR

232886-

228008-

224000-

220000.

aeeeee-

209099-

196000-

108000-

104000-

180006-

•••

LjJAj ——— -i • i • r • i • i0 IE 1«

i i • i • i • i •20 £4 B0 32

Data File: >QA162::U6Name: EUALAnisei EUALA

Id File: I223QA::USTitle: IFB/PST/PCB QA DB6 08Lest Calibration: 900906 19:13

Operator ID: RW8206Quant Time: 900906 16:06Injected at: 900904 17:06

Quant Output File: *QA162::AQInstrument ID: QA

2ul INJ

228

QUANT REPORT

Operator ID:Output Fi!•Data File:Name: EUALAnisc: EUALA

RU8206-QA162>QA162

QuantAQU6

7 Quent Time,Injected at

Di lut ton FactorInstrument ID

Page 1

900906 16:06900904 17:06

1.00000QA

ID File: I223QA::USTitle: IFB'PST/PCB QA DB608Last Calibration: 900906 19:13

Compound

2ul INJ.


6) #Aldrin13) tEndrin16) #4,4'-DOT19) tDibutylchlorendete


11.90 690 3900622.25 1335 4230426.0? 1563 3564830.57 1834 30123

.00726 UG/ML 100.0157 UG/ML 100.0163 UGxnt 100.0168 UG/riL 100

KW)

229

Flit >QR163 1.6 MU. EVRLB EVRLB480 , 868 , 1500 t 1600 , 2000

420008-

400000-

380080-•

360*08-•

340600-

320066-

300000-

288066-

260088-

240000-

220000-•

200088-

188888-_l

&\

9v-

ML*.,M

___^AvJ——

j

ss

p£J

JU

58

.-gnnLJ^-

' 4 ' 8" ' 12 ' l'6 ' 86" ' 84 ' 88 ' 3'2 '

Date File: >Q«163::U6Name: EUAL8Misc: EUALB

Id File: I223QA::USTitle: IFB/PST/PCB QA DB6 08Last Calibration: 900906 19:13

Operator ID: RU8206Quant Time: 900906 16:08Injected at: 900904 17:46

Quant Output FileInstrument ID

2ul INJ

QA

2SO

QUANT REPORT

Operator ID: RUI8206Output File: "QA16?nAQData File: >QA163::U6Name: EUALBtlisc: EUALB

ID File: I223QA::USTitle: IFB/PST/PCB QALast Calibration! 900906

Compound

Quant Rev: 7 Quant TimeInjected et

Di lution FactorInstrument ID

Page 1

900906 16:06900904 17:46

1. 00000QA

DB608 2ul INJ.


6)11)13)14)16)19)20)

•Aldrin*4,4'-DOE#Endr in#4, 4 '-ODD#4, 4 '-DOT#Dibutylch lorendate#Endrin ketone

11192223263033

.48

.42

.23

.77

.09

.57

.57

689116513341426156318342014

1704973008

2093451305617542514176013440

.0354.000937.0775.00557.0801.0792.00501

UG/MLUG/P1LUGxtILUG/MLUG/riLUG/MLUG/ML

10010U100100100100100

Compound uses ESTD

£>^ 111)96

231

CHROnPTOSRPMme >OP

680889-

66080*

SE0000-

400088;

360000-

32000fr

2B0000-

—*

164 1.8 UU. EVRLC EVRLC

400 088 1800 1688 2000.. . i ... T ... i - - T . .. i ... i ... i . . ~ i . . . i . . . i . .

_l

I

rw

<L ,.

•i

?

_ j ——

\i*r

J

ijr

->

5

_7L_' 4 ' 0" ' "l'2" ' l'6 ' 80 ' 84 ' 88 ' 38 '

Data File: >QA164::U6Name: EUALCnisc: EOALC

Id File: I225QA::USTitle: IFB/PSTxPCB QA OB606La»t Celibration: 900906 19:13

Operator ID: RU8206Quant Time: 900906 16:10Injected ati 900904 16:26

Quant Output File: AQA164::AQInstrument ID: QA

2ul INJ

232

QUANT REPORT

Operator ID: RUB206Output File: ~QA164::AQData File: >QA164::U6Name: EUALCMisc: EUALC

ID File: I223QA::USTitle: IFB/PST/PCB QA DB6QBLast Calibration: 900906 19:13

Compound

Quant Rev: 7 Quant Time:Injected at

Di lut ion Factor:Instrument ID

Page 1

900906 16:10900904 16:26

1.00000QA

2ul INJ


6) *Aldrin13) #Endrin16) #4,4'-DDT19) tDibutylchlorendate

* Compound uses ESTD

11.48 68922.23 133426.09 196230.57 1834

329986 .0684 UG/ML 100390338 .145 UG/fIL 100323202 .147 UG/ML 100247681 .138 UG/ML 100

233

CHROHPT09BPMFii« >oniee i.e uu. EVHLB EVHLB

4«e , eee , i ee , it.ee t eeeeaeeeee-aieeee-3e0ve»£90888-

aeeeee-

8se0ee-

eaeeee-seeeee-•eieeee-seeeee-iveeee-

H3»

L *O)

9S r

"

e

Lu

t

u

6

8^U-

1 i ' e ' i'2 ' i'6 ' e'e ' 84~ ' "g'e" ' "a'a" '

Data File: >QA18Q::U6Name: EUALBnisc: EUALB

Id File: I227QA::USTitle! IFBxPSTxPCB QA DB606Last Calibration: 900906 19:13

Operator ID: RLJ8206Quant Time: 900906 16:22.Injected ati 900909 09:15


2ul INJ

234

T REPORT

Operator ID:Output File:Data File:Name: EUALBriisc: EUALB

RU8206 Quant Rev: 7

>QA180: :U6

QUAN

Quant TimeInjected at


Page 1

900906 16:22900905 05:15

1.00000QA

ID File: I223QA: : USTitle: IFB/PST/PCB QALast Calibration: 900906

Compound

DB60B 2ul INJ


6)11)13)14)16)19)20)

*Aldrin#4, 4 '-DDE#Endr in*4,4'-DDD#4)4 '-DOT*DifeutylchlorendatetEndrin ketone

11192223263033

.48

.45

.23

.75

.03

.57

.58

689116713341425156218342015

1075842496

12006410816986248979211402

.0223.000777.0445.00461.0450.0501.00425

UG/MLUC/HLUG/MLUG/T1LUG/MLUG/MLUG/ML

10010U100100100100100

Compound uses ESTD

235

CHROMPTOSRRnFlla >Qfll9a 1.6 MU.

.. «f ..

EVRLB EVflLB

E80000-

£60000-

246009-

seeeee-

Teeee

UA-

ee 24 ' £8

Data File: >QA192: :U6Nama: EUALB

EUALB

Id Fi la: I223QA: :UST 1 1 1 a : I FB/PST/PCB QALast Calibration: 900906


DB6 08

Quant Output File: ~QA192::AQInstrument ID: QA

2ul INJ.

236

QUANT REPORT

Operator ID:Output File:Da t a File:Name: EUALBtlisc: EUALB

RU8206^nAioo * • A OU|nX7& » * rlW

>QA192::U6


Di lut ion Factor:Inst rument ID

Page 1

900906 16:4b900909 13:20

1.00000QA

ID File: I223QA::USTitle: IFB/PST/PCB QA D86 08Last Calibration: 900906 19:13

Compound

2ul INJ


6)13)14)16)19)20)

•Aldnn#Endr in*4,4'-DDD#4, 4 '-DOTtDibuty Ich lorendate*Endr in ketone

112223263033

.47

.23

.80

.03

.57

.57

68813341426156218342014

114176130752

11712109100896009600

.0237

.0484.00500.0498.0500.00358

UG/MLUG/HLUG/MLUG/MLUG/MLUG/ML

1001QU10010U100iou

Compound uses ESTD

237

>OA165 1.8 a»u.

*C_INDR INDR

uaaaa*

leeeaee

eaaaea

saaea»

4eeea»

388889

aeaeefr' "i'6 ' s'a ea ss

Data File: >QA165::U6Name: INDAMisc: INDA

Id File: I223QA::USTi t le : IFB/PST/PCB QA DB6 06Lest Calibration! 900827 07:36

Operator ID: RU8206Quant Time: 900906 09:01Injected et: 900904 19:07

Quant Output File: ^QA165::AQInstrument ID: QA

2ul INJ

238

QUANT REPORT

Operator ID: RUJ6206Output File: ^QA165::AQData File: >QA165: : U6

Quant Rev: 7

Name: I NO AINDA

Quant Time!Injected at:

Di lution Factor:Instrument ID:

Page 1

900906 09:01900904 19:07

1.00000QA

ID File: I223QA::USTitle: IFB/PST/PCB QA DB60SLast Calibration: 900827 07:36

Compound

2ul INJ.


2)4)6)7)10)12)15)16)17)19)21)

#Gamma-BHCtHeptach lor*Aldrinfrleptachlor epoxidetEndosulfan I*D i e 1 d r i ntEndosulfan 1 1#4, 4 '-DOTtEndrin aldehydetDibutylchlorendatetflethoxych lor

8.9.11.15.17.

•- 19.23.26.26.30.33.

1772480232557303455767

490583689901

1039117314241562158718342020

1769871511051205761015688659217260916870510956811559089536352066

.0243

.0217

.0207

.0198

.0188

.0398

.0457

.0606

.0498

.0481.404

UG/MLUG/MLUG/rlLUGXMLuG/ni_UG/MLUG/MLUG/HLUG/MLUG/MLUG/ML

100100100100100100100100100100100

Compound uses ESTD

239

File >0fl

400000;

30000*

360000;

34000*

33000*

300000;

80000*

86000*

84000*

88000*

80000*

166 1.0 UU. INDB INDB

....«?• .....«.., ...W. . . . ."-•?. . . . .W.5«

.1. . i .

>

S

$o

id53

~

•5a Si

,

S r^

J —

•*8

1*

-

' 4 ' 0 ' 18 ' 16 ' a'0 84 ' 80 ' 38

Data Tile: >QA166: : U6Name: INDBMi»c: INDB

Id File: I223QA: :USTitle: IFBXPST/PCB QA DB60BLast Celibration: 900827 07:36

Quant Output FileInstrument ID

2ul INJ

QA

Operator ID:Quant Time:Injected at:

RU6206900906 09:03900904 19:47

240

Operator ID:Output File:Data Fi la:Name: INDBdisc: I NOB

RU8206

QUANT REPORT

Quant Rev: 7

>QA166: : U6

Quant Time!Injected at'

Di lut ion Factor:Instrument ID'

Page 1

900906 09:03900904 19:47

1.00000QA

itle: IFB/PST/PCB QA DB608 2u 1 INJ..aet Calibration: 900827 07:36

1)3)5)8)9)11)13)14)18)19)20)

Compound

tAlpha-BHCtBata-BHCtDelte-BHCtgamma-Ch lordanete. 1 pha-Ch^l o rdane#4,4' -DDE*#Endr in#4,4 '-DDD#Endoaulfan sulfatetDibuty Ich lorendate#Endr in ketone

R.

6.e.10.16.17.19.22.23.27.30.33.

T.

4752400623402373475755

Scant

3385116249651034116413341424164818342013

Height

20230510728812696711596811667216057713498211718411878499584134016

Cone

.0301

.0265

.0255

.0207

.0207

.0395

.0383

.0496

.0486

.0535

.0698

Units

UG/tlLUG/MLUG/MLUG/MLUGxntUG/MLUG/MLUG/MLUG/ni_UG/MLUG/HL

q

100100100100100100100100100100100

Compound uses ESTD

241

FH« > Oft 166 1.0 WU. INDR INDH

400 , 000 , 18,00 , 1*00 , £000

120888*

1100006

1000000

800000

70000*

««e.e»

B0000*

_ _ '40000*

30000*

1 ,

t>h

3

"i? 2 S ii J * 3 * * ~ ~ w $ r * .1 i £ S 3 | 1 v ° I

_ UillAJJI ' l ' i ' i ' i ' i " i • i • i ' i • i - i - i - i •

4 * 0 It 16 " 80 * £4 " 80 " 38

IDate File: >QA186:iU6Name: INOArii»c: INDA

Id Fila: I223QA::USTitle: IFB/PST/PCB QA DB6 08Last Calibration: 900906 19:13

Operator ID: RU8206Quant Timai 900906 16:33Injected at: 900909 09:17

Quant Output File: ~QA186::AQInstrument ID; QA

2ul INJ

242

QUANT REPORT

Operator ID:Output File:Da t e File:Name: INDAMisc: INDA

RU8206 Quant Rev: 7

>QA186: :U6

Quant Time!Injected at

Di lut ion FactoriInstrument ID:

Page 1

900906 16:77900905 09:17

1.00000QA

ID File: I223QA::USit liast

2)4)6)7)10)12)15)16)17)19)21)

9 : I FB/PSTxPCB QA DB6 08Calibration: 900906 15:13

Compound

#Gamma-BHCfHeptach lor*Aldrin•Hep tech lor epox ide#Endoaulfan ItDie Idr intEndosulfan II#4, 4 '-DOTtEndrin aldehyde•Dibuty Ich lorendatetrlethoxych lor

2ul IH

R.

e.9.11.15.17.19.23.26.26.30.33.

IJ.

T.

1772460232557305455767

Scan*

4905836899011039117314241563158718342020

Height

1986571670411325021107209696018771318265711660812158594336372381

Cone

.0281

.0276

.0275

.0273

.0280

.0544

.0541

.0532

.0526

.0527.264

Units

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/nLUG/MLUG/MLUG/rlL

q10010010010010010010010U100100100

Compound uses ESTD

243

File >0fll97 1.0 aau.

1100»0»

IHDR

999999

999999

78098*

699999

999999

499999

399999

S9999+

£•00

4' ' ' t ' 18

Data File: >QA197::U6Name: INOAhiac: INDA

Id File: I223QA::USTitle: IFB/PST/PCB QA DB606Last Calibration: 900906 19:13


Quant Output File: "QA197::AQInstrument ID: QA

2ul INJ

244

Operator ID:Output FilaiData File:Name: INDAMisci INDA

RU8206

QUANT REPORT

Quant Rev: 7

>QA197::U6

Quant Tima:Injectad at:

Di lut ion FactoriInstrument ID:

Page 1

900906 16:59900909 16:41

1.00000QA

'itl«.ast

2)4)6)7)10)12)15)16)17)19)21)

»: IFB/PST/PCB QA DB608Calibration: 900906 19:13

Compound

*Gamma-BHC#Heptach lorvAldrinftHeptachlor epoxidetEndosulfan ItDieldrintEndosulfan I I#4, 4 '-DOTtEndrin aldehydefDibuty Ich lorendeteftlethoxychlor

2ul IK

R.

6.9.11.15.17.19.23.26.26.30.33.

10.

T.

1772470030537502455565

Scan*

4905836889001038117214251561158718332019

Height

1958161583371304321139207622418707316729712459412537396448400426

Cone

.0277

.0262

.0270

.0280

.0220

.0542

.0496

.0569

.0542

.0539.284

Units

ue/ntUG/ntUG/MLUG/MLUG/MLUG/flLUG/rlLUG/MLUG/MLUG/MLUG/T1L

q100100100100100100100100100100100

* Compound uses E5TD

01/11/90

245

CHROtlRTOORfltlFill >QP

400906;

366696;

36090*

34990*

320090.

30099*

89099*

£6006*

84996*

88069*

20000*

196 1.0 UU. INDB INDB

i 4f° _i *f* i 13M i 16.*e i Miee

«••

&«

_ ^

$

IItj*

- gng £C

». * ,i

^

.,

?1

N •"*

*i 1? 9irt rv

- _A

|i\/ j *«**L1 4 ' B ' I'B ' 16 ' 89 ' 84 ' a'e ' a'e '

Data File: >QA19B::U6Name: INDBdisc: INDB

Id Fila; I223QA::USTitle: IFB/PST/PCB QA DB608Last Calibration: 900906 19:13



2ul INJ

246

Operator ID: RUI8206Output File: AQA198::AQData File: >QA198::U6Name: INDBMisc: INDB

QUANT REPORT

Quant Rev: 7 Quant Time;Injected at:

Oi lut ion Factor:Instrument ID:

Page 1

900906 17:02900905 17:22

1.00000QA

'it 1..ast

1)3)5)8)9)11)13)14)16)19)20)

B : I FB/PST/PCB QA DB6 08Calibration: 900906 15:13

Compound

*Alpha-BHC*Beta-BHC*Delta-BHC#gamma-Ch lordane*a Ipha-Ch lordane»4,4'-DDE#Endr in*4,4'-DDD#Endosu Ifan sulfatetDibuty Ich lorendatetEndrin ketone

2ul IN

R.

6.8.10.16.17.19.22.23.27.30.33.

Iw •

T.

4752400823382272455555

Scant

3B85116249651034116313331423164718332013

Height

19641710393612396011174411264015705712588811705611558495232135211

Cone

.0243

.0242

.0244

.0241

.0241

.0489

.0466

.0499

.0487

.0532

.0504

Units

UG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/MLUG/ML

q

10010010010010010010010010010U100

Compound uses ESTD

247

-DOD C -O*-- ft •

O ^ ft

• HOa «- Tft • «

O o 00

o o ofa ^k

tooo>O

toNJ

ft i- a

ft •-•O » —ft •- *n(T (D >-•-> \ Mft TJ M•» tf) W*•• -HOO S 3>3 -0 «" ODC>0 tf)oo(DOIO ^M

MO» Q)W (^OK o

O)

3 Z O~ a ft• 3 n 9 ft

O O —X X «

TJ-0I I vromozz »m m H»

M

i,-/

oC

• or* C-» •*C -D3 C

O«

DO

(KM

n> nt n» re M wm B» * »• w «• « CB * « a« o a a> a •» o o a> « •T.i.9.i.9.i.T.i.?.i.?,

ro^^oo

QUANT REPORT

Operator ID: RUI8206Output Fila: ^QA167::AQData Fila: >QA167::U6Name: TOXAPHENEtliac: TOXAPHENE

ID Fila: I223QA::USTitle: IFB/PST/PCB QA DB6 08Last Calibration: 900627 07:36

Compound

Quant 7 Quant Time:In jected ati

D i l u t ion Factor:Inst rument ID

Page 1

900906 09:06900904 20:27

1.00000QA

2ul INJ.


19) tDibutylchlorendate22) tToxaphene23) #Toxaphene-224) #Toxaphene-3


30.53 1832 13126523.95 1437 6278425.85 1551 3555127.47 1648 32704

.0706 UG/ML 100.796 UG/ML 100.696 UG/ML 100.779 UG/tlL 100

249

Flit >OR16B 1.0 aau.

. . . . 4**

aeeeee-

aeeeee-

S49999-

aeeeee-

RK1B16 RR1016

12 i t ee sa

Date Fi le= >QA166::U6Name: AR1016Misc: AR1016

Id File: I223QA::USTi t le : IFB/PST/PCB QA DB606Lest Calibration: 900827 07:36



2ul INJ

250

QUANT REPORT

Operator ID:Output File:Da t a File:Name: AR1016nisc: AR1016

RU8206~QA168t:AQ>QA168i:U6

Quant 7 Quant Time;Injected at•

Di lut ion Factor:Instrument ID:

Page 1

900906 09:06900904 21:08

1.00000QA

ID File: I223QA: : USTitle: IFB/PST/PCB QA DB60BLast Calibration: 900827 07:36

2ul INJ.

Compound R.T. Scan* Height Cone Units

19)29)26)27)

ftDibutylchlorandate*Aroclor 1016*AR 1016-2*AR 1016-3

30.57 1834 1418B9 .0763 UG/ML 1009.85 591 118720 .265 UG/ML 1008.08 485 92711 .510 UG/ML 10013.60 816 39424 .204 UG/HL 100

Compound uses E5TD

251

CHROHflTOSRPn

KM*File >QH169 l.B «BU.

Data File: >QA169::U6Name: AR1221tlisc: AR1221

Id File: I223QA:lUSTitle: IFB/PST/PCB QA DB608La»t Calibrationi 900627 07:76

Op*rator ID: RU8206Quant Tima: 900906 09:10Injacted at: 900904 21:48

Quant Output File: ~QA169:iAQInstrument ID: QA

2ul 1NJ

252

QUANT REPORT

Operator ID:Output File:Da t a File:Name: AR1221rtisc: AR1221

RU8206AQA169::AQ>QA169::U6

Quant Raw: 7 Quant Time:In jected ati

Oi lut ion Factor:Instrument ID:

Page 1

900906 09:10900904 21:48

1.00000QA

ID File: I223QA::USTitle: IFB/PST/PCB QA DB608Last Calibration: 900827 07:36

Compound

2ul INJ


19) tDibutylchlorendate28) #Aroclor 122129) *AR 1221-230) *AR 1221-3


50.57 1834 801926.32 379 686083.48 209 490565.52 331 31441

.0431 UG/ML 100.282 UG/HL 100.353 UG/ML 100.299 UG/ML 100

253

CHROnPTOORftttFi l* ><W170

270000

860000;

230000-

220000;

210000;

200000-

190000

MU. RR1232

S 9£

lil

AR1E32

1«00 B000

32

Data File: >QA170::U6Nam«: AR1232rii&c: AR1232

Id File: I223QA::USTitle: IFB/PST/PCB Qft DB6 06Last Calibration: 900627 07:36


Quant Output File: AQA17Q::AQInstrument ID: QA

2ul INJ

254

QUANT REPORT

Operator ID: RUI8206Output File: AQA170uAQData Ftle: >QA170i:U6Name: AR1232Misc: AR1232


Compound

Quant Rev: 7 Quant TimeInjactad at


Page 1

900906 09:11900904 22:29

1.00000QA

2ul INJ.


19) fDibutylchlorandate31) *Aroclor 123232) #AR 1232-233) *AR 1232-3

* Compound uses ESTD

30.57 1634 766088.07 484 462426.32 379 542239.85 591 53184

.0412 UG/'tlL 100.284 UG/tlL 100.278 UG/ML 100.281 UG/riL 100

255

CHROt1PT00RftHFilm >QA171 1.0 ABU.

£90000-

_ _ _ _ _ _RR1R48

870000;868000-zsaaae

eaaeee-

£08000-

19080^

T

£000

16 ee 84 eT 3E

Data File: >QA171::U6Natn«: AR1242flisc: AR1242

Id Fil.: I223QA::USTitle: IFB/PST/PCB QA DB608Leet Calibration: 900827 07136

Operator ID: RU6206Quant Time: 900906 09:13Injected ati 900904 23:09


2ul INJ

256

Operator ID: RU8206Output File:Data File:Name: AR1242Miec: AR1242

QUANT REPORT

Quant Rev: 7

>QA171i:U6

Quant Time:Injected at:

Dilut ion Factor:Instrument ID:

Page 1

900906 09:13900904 23:09

1.00000QA

ID File: I223QA::USTitle: IFB/PST/PCB QA DB608Laat Calibration: 900627 07:36

Compound

2ul INJ.


19) #Dibutylchlorendate34) *Aroclor 124235) *AR 1242-236) «AR 1242-3


30.57 1834 772489.85 591 1034888.08 465 619626.32 379 43506

.0415 UG/ML 100.673 UG/ML 100.583 UG/ML 100.153 UG/ML 100

257

CHROMPTOBRPnHR1E4B HR1E4B

live £000

Tilt >Qfll72 1.0 UU.

; • 0 - IE £4 38

Data Fi!•: >Qftl72::U6Name: AR124BMisc: AR1248

Id File: I223QA::USTitle: IFB/PST/PCB QA DB606.Last Calibration: 900827 07:36

;Operator ID: RU8206Quant Time: 900906 09:14Injected et: 900904 23:90


2ul INJ

258

QUANT REPORT

Operator ID:Output Fi1«:Da t a File!Name: AR1246hi»c: AR1246

RU8206^QA172tlAQ>QA172:JU6


Dilution Factor:Instrument ID:

Page 1

900906 09:14900904 23:50

1.00000QA


2ul INJ.

Compound R.T. Scan* Height Cone Units

19)37)38)39)

*Dibutylchlorendate*Aroclor 1248*AR 1246-2*AR 1246-3

30.57 1834 7718415.68 941 541449.65 591 61024

13.62 817 49024

.0415 UG/ML 100.300 UG/ML 100.368 UG/ML 100.160 UG/ML 100

Compound uses E5TD

tiw

259

CHRQMPTOORftnnit >OAi73 i.o

360600

seoee*

seoeeoj

280000;

£60080;

84000*

aeoooo

38

Data Fila: >QA173::U6Name: AR1254Misc: AR1254

Id File: I223QA::USTi t le : IFB/PST/PCB QA DB608Lest Celibration: 900627 07:36

Operetor ID: RU6206Quant Time: 900906 09:16Injected at: 900909 00:30

Quant Output File: AQA17?::AQInstrument ID: QA

2ul INJ

260

QUANT REPORT

Operetor ID: RU6206Output File:Data File:Name: AR12v4Misc: AR1254

Quant Rev: 7

>QA173;:U6

Quant Time:Injected at

Di lution Factor!Instrument ID:

Page 1

90U?06 09:1690,0905 00:30

1.00000QA


Compound

2ul INJ


19) *Dibutylchlorendate40) tAroclor 129441) *AR 1254-242) *AR 1254-3

* Compound uses ESTO

30.55 1833 7910420.43 1226 15449725.85 1551 9913616.72 1003 135872

.0425 UG/ML 100.434 UG/ni_ 100.479 UG/ML 100.887 UG/ML 100

261

&80000;

£00880-

180000

Fll* >M174 1.0 uu.

366080;

340000-

32098*

30000*

RR1E6B

888 iqee 1«00 8008

r T12 16

Data Fi le:Name: AR1260Miftc: AR1260

: : U6

Id File: I223QA: :USTitle: I FB/PSTxPCB QA DB6 06Last Calibration: 900B27 07:36



2ul INJ

262

QUANT REPORT

Operator ID:Output File:Deta File:Name: AR1260disc: AR1260

RLJ8206~QA174:!AQ>QA174::U6

Quant Rev: 7 Quant Time!In jected at:

Di lut ion Factor iInst rument ID

Page 1

900906 09:18900905 01:11

1.00000QA

ID File: I223QA::USTitle: IFB/PST/PCB QA DB6 08Last Calibration: 900827 07:36

Compound

2ul INJ

R.T. Scan* Height Cone Un its

19) tDibutyIchlorendote43) *Aroclor 126044) #AR 1260-245) #AR 1260-3

$ Compound uses ESTD

30.25 1815 15264134.00 2040 6899422.50 1350 12659221.80 1308 114432

.0821 UG/ML 100. 184 UGXflL 100.541 UG/hL 100.413 UG/ML 10Q

263

ETC

RAW QC DATA

264


ERA SAMPLE NO-

PBLK01Lab Name: ETCNJ

Lab Code: Case No.:

flat r i x : (soil /water ) SOIL


Level: I low/mod) LOUI

Ktloisture: not dec. 0 dec.


GPC Cleanup: (Y/N) N pH:

Cont ract :

SAS No.:

I

SDG No.:

Lab Sample ID: QC7Q246G,

Lab File ID: >QA191

Date Rece ived:




CAS NO. COMPOUNDCONCENTRATION UNITS:Cug/L or ug/Kg ) UG/KG

319-64-6 ——————— a Ipha-BHC________319-65-7———————beta-BHC_________319-66-8 —————— delta-BHC________56-89-9 ———— ——— gamma-BHC(Lindane).76-44-6 ——————— -Heptachlor_______309-00-2———————Aldrin___________1024-57-3 —————— Heptachlor epoxide.959-98-6 ——————— Endoaulfan I_____60-57-1 ———————— Dieldrin_________72-55-9 ———————— 4,4'-DDE_________72-20-8————————Endrin___________33213-65-9 ————— Endoaulfan II_____72-54-6 ———————— 4,4'-ODD_________1031-07-8-————EndosuIfan sulfate50-29-3————————4,4'-DOT__________72-43-5 ———————— Methoxychlor_____53494-70-5—————Endrin ketone_____5103-71-9 —————— alpha-Chlordane___5103-74-2-------gamma-Chlordane___B 001-35-2- ————— Toxapnene________12674-11-2—————Aroc lor-1016_____11104-26-2 ————— Aroc lor-1221_____11141-16-5—————Aroc lor-1232______53469-21-9 ————— Aroc lor-1242______12672-29-6 ————— Aroc lor-1246______11097-69-1 ————— Aroc lor-1254______11096-82-5 ————— Aroc lor-1260______

I1816161818161618I 16,116I 16116116I 161161801161816116016018018018018011601160I___

Q

IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

FORM I PEST 1/87 Rev.

265

CHROrtflTOSPflMTile >Qfll91 l.e *nu. FBLK81 QC79£466 ,Q67ee46,Sif

laeeeee-leeeOOe-

iieeeeo-1800000-

980000-

888008-

700000-

600600-

560000-

400800-

380000-

eoeoee-

4ee , eee t i^ee ( isee , geee

L.1

I ift 1Jl II

i i • i • i i ' r ' r ' i ' p • i • i • P ' i ' r • r • i • 1 '4 e is 16 ae 24 es 32

Data File: >Qftl91::U6Name: PBLKQ1

Quant Output FileInstrument ID QA

hisc: QC70246G,QG70246,S:G3,30,20

Id File: I223QA::USTitle: IFB/PST/PCB QA DB608Last Calibration: 900906 15:13


2ul INJ.

266

QUANT REPORT

Operator ID: RUB206Output Fi le: ~QA191: : AQData File: >QA191::U6Name: PBLK01Misc: QC70246G,QG70246,S:G3,30,20

ID File: I223QA::USTit le: IFB/PST/PCB QA D66Q6Last Calibration: 900906 15:13

Compound

Quant Rev: 7

2ul INJ

Quant Time:In jected at

Di lut ion Factor:Inst rument ID:

Page 1

900906 16:45900905 12:39

1 .00000

R.T. Scan* Height Cone Uni ts

19) *Dibutylchlorendete


30.57 1834 329602 .164 UG/ttL 100

267


Lab Name: ETCNJ

LabCode: Case No.:

Mat r i x : (soil/water) SO IL

Samp 1 e wt /vo 1 : 30.0 C g--"mL) G

Le^e 1 : C low/mcd ) LDLJ

^ M o i s t u r e : not dec. 16 dec.

Ext ract ion: (SepF/Cont/Sonc) SQNC

GPC Cleanup: (Y-'H) N pH: 7.0

Lont ract:

SAS No.:

ERA SAMPLE NO

IIA4377SI______________

5DG. No.:

Lab Sample ID: CA4377GS

Lab F i l e ID: >QA195

Date Received:

Date Extracted: Q8--"3Q-'90


Di1 u t ion Fac tor: 0

CAS NO. COMPOUNDCONCENTRATION UNITS:vug-''L or ug/Kg,1 UG/'KG

1 319-64-6--------alpha-BHC_________I 319-65-7-——----beta-BHC__________I 319-86-6-——----deIta-BHC_________I 58-39-9---------gamma-BHCCLindane).I 76-44-6---------Heptachlor________I 3 09-00-2-- ————— Aldr in____________I 1024-97-3-------Heptachlor epoxide.I 959-98-8-—— ——— Endosulfan I______I 60-57~l---------Dieldrin___________I 72-55-9-- ———— --4 ,4'-DDE__________I 72-20-6---------Endrin____________I 33213-65-9--——-Endosulfan II_____i 72-54-&---------4,4'-DDD__________I 1031-07-6-----—Endosulfan sulfate.I 50-29-3---------4,4'-DOT__________I 72-43-5---------tie thoxychlo r______I 53494-70-5----—Endrin ketone_____I 5103-71-9-------alpha-Chlordane___I 5103-74-2-------gamma-Chlo rdane___I 8001-35-2-------foxaphene_________I 12fc74-ll-2------Aroclor-1016______I 11104-2S-2------Aroclor-1221______1 11141-16-5------Aroclor-1232______I 5?469-21-9------«roclor-1242______i 12672-29-6------Aroclor-1246_______I 11097-69-1--——-Aroclor-1254_______I 11096-82-5------Aroclor-1260

9.6009.6009.6006050499.6009.60014019 . 0015319. 0019 . 0019. 01619619 . 009.600* . 6 0 01909696969696190190

Q

IUIUIU

IUIUIIUIIUIUIUIIUIUIUIUIUIUIUIUtut uIUIU

FORM 1 PEST 1/87 Re-

268

File >OR1?5 1.0 aau. fl4377S,7,l* CB43776S,oe7ee46,Sie

7800008;

aeeeeee-

,30000.

40e see i2ee i&ee aeee

*,JI

4

I 3 R -II ^s_IL/U_L A /I A . ^ A A• ( l l l ' I ' l • ! • ( • ! ' 1 ' I ' l ' ! ' I

B 12 16 80 24 26 32

Data File: >QA195::U6 Quant Output File: ~QA195::AQName: A4377S,7,16 Instrument ID: QAMisc: CA4377GS,QG70246,S:G3,25.23,20

Id File: I223QA::USTitle: IFB/PST/PCB QA DB6 OBLaat Calibration: 900906 15:13


2ul INJ.

269

QUflNT REPORT

Operator ID: RUB2Q6Output File: *QA195::AQData File: >QA195::U6Name: A4377S,7,16nisc: CA4377GS,QG70246,S:G3,25.23,2Q

Quant Rev: 7 Quant Time!In jected at:

Di lut ion Fac tor:Inst rument ID:

Page 1

900906 16:54900905 15:20

1.OOOOUQA

ID File: I223QA::USTitle: IFB/PST/PCB QA DB60SLast Calibrat ion: 900906 15:13

Compound

2ul IN3

R.T. Scan* Height Cone Un i ts

2)4)6)12)13)16)19)

#Gamma-BHCfc.Heptach lor*Aldr in#Die Idr in#Endr i n#4, 4 '-DOT$Dibutylchlorendate

8.9.11.19.22.26.30.

17724853230355

490583669

1172133415621833

533059381056297857606083520003444750328514

.0753

.0630

. 0616. 176. 193.203. 183

UG/MLUG/MLUG/ttLUG/MLUG/ttLUG/HLUG/ML

10010G100100100100100

Compound uses ESTD

270

IDPESTICIDE ORGANICS ANALYSIS DATA SHEET


EPA SAMPLE NO

Lab Code: Case No.: SDG No.:

M a t r i x : I s o i l /water) SOIL

Samp le wt /vo 1 : 30.1 Ig/mL)

Leve 1 : t low/med J LOW

Lab Sample ID: CA4377GR

Lab Fi le ID: >QA196

Date Received:

^Moisture: not dec. 16 dec.

E x t r a c t i o n : (SepF/Cont /Sonc ) SONC

GPC Cleanup: CY/N) N pH: 7.0



D i 1 u t ion Fac tor: 0

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kq) UG/KG

319-64-6--------alpha-BHC_________319-65-7- —————— bcta-BHC__________319-86-8———————delta-BHC_________58-89-9------—-gamma-BHCCLindane).76-44-8—----—-Heptachlor________309-00-2 ——————— A l d r in____________1024-57-3-------Heptachlor epoxide.959-98-8- —————— Endosu 1 fan I______60-57-l---------Dieldnn__________72-55-9———— ——— 4 ,4'-DDE__________72-2G-8—-------Endrin____________33213-65-9------Endosulfan I I_____72-54-e---------4,4'-ODD___________1031-07-8---——EndoauIfan sulfate.50-29-3 ——— ————4, 4'-DOT_________72-43-5---------Met hoxych1 or_______53494-70-5------Endrin ketone_____5103-71-9-------alpha-Chlordane___5103-74-2-------gamma-Ch1o rdene___8ClGl-35-2-------Toxaphene_________12674-ll-2------ttroclor-1016______11104-28-2------Aroclor-12 21______11141-16-5------Aroclor-1232______53469-2 1-9------Aroclor-1242______12672-29-6------Aroclor-1246______11097-69-1 —————— Aroc lor-1254_______11096-82-5------Aroclor-1260 ____

9 . 6009.6009.6005875759.6009.6009119. 009519.19.19.939619.19.19.1909696969696190190

000000

000000

Q

IUIUIIUIIUIUIUIIUIUIUIUIUIUIUIUIUIUIUIU

FORM I PEST 1/87 Rev

271

CHROHRTO&RfltlFi l e >QR156 1.6 MU. ft4377R,7,i6 CR43776R ,0678245,575

400 , see , 15*0 1600 goee

7888008;

6886000-

9000000|

4000000J

3000000-

eeeeeee-

1000000-

A16 | - !ae 1 • 1as

Data File: >QA196::U6 Quant Output File: ~QA196::AQName: A4377R,7,16 Instrument ID: QAMisc: CA4377GR,QG70246,S:G3,25.25,20

Id File: I223QA::USTitle: IFB/PST/PCB Qft DB60BLast Calibration: 900906 15:13


2ul INJ.

272

QUANT REPORT

Operator ID: RUS206Output File: ~QA196::AQData File: >QA196::U6Name: A4377R,7,16Misc: CA4377GR,QG70246,S:G3,25.25,2Q

Quant Rev: 7 Quant Time:Injected at

Di lut ion Factor:Inst rumen t ID

Page 1

900906 16:57900905 16:01

1. 00000QA

ID File: I223QA::USTitle: IFB/PST/PCB QA DB6 08Last Calibration: 900906 15:13

Compound

2ul INJ

R.T. Scan* Height Cone Uni ts

2)4)6)12)13)16)19)

£Gamma-BHC#Hept ach lor*Aldrin#D ie Idr in#Endr in#4,4'-DDT$Dibut ylchlorendate

891119222630

.17

.72

.46

.53

.23

.03

.55

490583689

1172133415621833

51552336781029011363.1619512451408766308738

.0728

. 0609

. 0602. 183.190.187.172

UG/tlLUG/MLUG/MLUG/tlLUG/tILUG/flLUG/ML

100100100100100100100

Compound uses ESTD

273

ETC

CHAIN OF CUSTODY

274

¥T"T'y~' F-niironmrnlul Trilinti Seal NO /JL-j A V> imci < frtifii-«1nm<.nTp

CHAIN OF CUSTODY FORM <CC1) ORIGINAL DateSeaied_^.

TCJob* r*~\7*

.By:

Company u~ = IE nftMftEti.nb.NT . INI. Attn, P*" GR£EN

Faciiily/Sne '• J^ ' F UUNN Phone:

Address. . L^ iJE COiJNTV. Ull

SAMPLE IDENTIFICATION

F a c i l i t y

Sample Pomi

Ociiorn Simple Poini C»»«cnpiiOi») j

/ i /i/iSl l i i lSti'i Dtif

ivviMMiDDSI*M Tim«

12*00 m ciociEi«PMO Hour*

H (0 Bot'on-i SeOimeni . (Bi Su't»ct impounOmtnt (I) L«acti»le Collection $yi (C) Ott>t'Si'eg'" '**• Ge"e'»!iO" Point iGl lr««lmen) Ficiftly (Tl L*M'Octan (LI Specify

SHUTTLE CONTENTSBOTTLE

No ' Type Size

i t T : JO

t '

Vi 40

. Tb • ' -ii

Pr«»«rv.

W :• '-

K .4E

I, 'T^'

t . ; JE

li....Jb

HL'L

GL Hi .

l r t--UOM

iF&,-bNA

lFb--P£I.-PLb

1FB TIET^LS

IFb- 'CYttNlDE

,)LJW bCfi.£EN

TR i *-• BL-HNK

Flit (Y(N)

N/

rJ

N/

A/

/S/

A/

SAMPLERObttrvations •

^

^

/

^

^

S

S <,,UL 7~

LABObMrvatlont

/

/

/

_/

/

/

CHAIN OF CUSTODY CHRONICLESnunie Opened

Signature /— -fti nave receivedName *-

Dale f - o ?

B/y(pnnt)/

J^/A.these

^4

"Vzla —materials

7)>W 6^a^ Dale: fc-r-T*Seal*. ^ /T^ / f j ' i

in good condition from the above person. .^ <4*^- Signature: L

fTl;,-•> (jTime: '> >° Remarks: v

Time. /y:Jtf

i^intact: ^-^

/M—^

i nave received these materials in good condition from the above person.Name Signature:

Date Time: Remarks:

Shuttle Sealed By. (print)

<^ETC FIELD PARAMETER FORM (CC2)* ' 12/89

1 1PURGE DA(VY MM D

SAMPLING METh

SamplerType

Sampler Material

Sample Composit

Well Elevation (ft

Depth to Ground

Groundwater Ele*

i,, i//ix),„„*/ It" '

3rrtJV/|*"

llh|V,^

,A/ nn

FIELD

i t i l

PTr.inR* CnV3 ?£•Sample Po'nt Li) l-rt«-I 1' 1

Soufct Coo^ Scm

PROCEDURES ^ 1 S *- P

1 1 1 1 I 1 1 1

fi- t i i i !!H* Coml I D

i i 1 ^l*!*TE STAP.T PURGE ELAPSED MRS WATER VOL IN CAKNG VOLUME PURGEDDi 12400 HI Clocfc) IGillonil , , lOallonti

/ ^- I , L L //. <.LOD* ?/^ / - "f 'if9*1 lr*"- x*^ r" /*• r"fc-7 . *s-* ' ( * *-* ?" •" **• U-t/

X A-Subm«r»ioie Pump D-DipD«f'Botlle — / .J -^.—^B-ISCO E-Balhir X-Of*f' ?J*ftT~ >/ *^-

——— C-B ladder Pump F-Scoop/Shov«l * aHcirt OTMERI

O A-Teflon C-PVC^ B-Metai D-Plastic X-Otrwr ————————————————————————————

1 A-T«flon C-Polyair1 B-Tygon - D-S licon

ed I Y/N | A^=>

FIELD M

\//\m iwater (ftl IV|>T 1 i

nation ff tmft l) ^1^ i

«TD> ,.t 1•p*c. e«M

(STO) O.j

tPK C«M

(STD| 4th

,rci \SM~\ I

IMEOFV OTMERI

Y.ntK.,WPECirr OTHER]

P.oe«u.«/P.opon,Dn,

EASUREMENTS

Well Depth (ft) r*^l

Sample Depth (non-well) (ft) 1^1

"*'Jy'"" M""

•I25'C

—MM.M'MWWn n

* i Ift i

>/•/

IhM uMti

1 1

Iv* VfMti

1 1hM unlit

S»mp)» T«mp TilffeMlty

Sample AppeararWeather ConditioOther JV^-V

FIELD COMMENTSce- S"»-K^X ***"? • /*••''" *i *•*•- P*~^T

ns *+~.H-^ t (*"*{']«»*- rV«^ 'j*-*^ 7^-

£* " '

^__ .. J / tVYl r ^*t» n-r i*/)

_SeL~,pl,

e-NB/Ot- <*r

t>,^K -?,Z Fc^r

rrvft^t t>^n^ 3-1 fCE

7f i itiiT - I rlvP•' y '

FILTERING: Use Chain of Custody (CC1) to indicate which bottles were filtered

Sarrm.er T* 7 3 * -^ Fmpinypr ft L** *' ———— */?"---

I certify that sampling procedures were in accordance with applicable EPA state and corporate protocols.

<cuit / /is>9 ,.,/y

ORIGINAL

276

T?TC^ ^-'»""'""«••"-'T«imt SeaINo, OV /Lf.g>^?tCJQb* L.^3.J_^ Jl Vj' unri ( rrlifiratmn ( <irp "

CHAIN OF CUSTODY FORM (CC1) ORIGINAL Date Sealed LU I I By: rt

Company. ui^STE _ nftNa£En£_NT f INC. Attn - DAN liREEN

Facil i ty/Site '^ :"- l> PL"-"; Phone: t )

AOdresS' t ^'";-" Ul

SAMPLE IDENTIFICATION

t»:'. ' iv'Sii» Coat

Sample Pomi I I I

S B-v*'Snea' r

lOoiionr S*moit Po»ni Dtierioifcni,

J I nz-i / Ift l I i I 1Slifi Tim* Et*pt*0 Hou'i

l)*00 ni ciocki (Ctuneot'tti

BollomSeOimem (Bi Surlace impounOmem (li L«»cn»1* Colltction Syl ,[C) Otr**rGen*'«no"Poini iGl Tf«ilm«Tii Facility |T| L««'Oc«n (LI Swci'

^

SHUTTLE CONTENTSBOTTLE

No ' Type i Size

. L . « -.0

- t : f •

it ' • J U

. f-i - !'•

i C .NU ji'5

. Ub • 4!j

. I

Pro«rv.

N,.::4E

N'..i:,t

K,,:JE

N._::-t

ML-4E

Hbi_i_

———————

i FB^'UDft

IFB-'BNA

1FB/PST/PC&

IPBx'METftLS

iFB/CYrtNlDE

U0« SCftttN

Fill (Y(N)

A>A/

V

V

A///

SAMPLEROb»trv«tions

y

/

/

/

/

/

LABOb«*nritlons

/ ——————LZ ______^ _____XX ____S

• •

CHAIN OF CUSTODY CHRONICLESnume Opened B*.

Signature ___JJ^

S^material

Date:

Seal*:

i have received tnese materials in good condition from the above person.Name -TV _ -<"o *«-v ST*v\- Signature:

Date Time: Remarks:

i nave received ihese materials in good condition from the above person.Name Signature:

Dale Time: Remarks:

Snytne Sealea By: (print)

Signature

277

OETC FIELD PARAMETER FORM (CC2)Form 0002

Sample Management12/B9

I l l 1 1 1

FTn.inR* CffyZ?/ft^mpLPninf g | I »lS|LlP|

Sou ret COM &*<n

FIELD PROCEDURES

1 1 I 1 1 1

1\t \ l \ t \ I 1pl« Point 1.0

1 1 1PURGE DATE ETAOT *U*GE ELAPSED MRS WATER VOL IN CASING VOLUME PURGED[vr MM DDl 11400 H< Clock) ld»lpntl lOilionii

SAMPLING METHOD: S/>i»T p.,. . /•Ht~*-'— } ^- A-»/[r~ fTi*, * *-.y—U * / '

XA-Submers lb l e Pump D-Dipper/Bottle /— ...„.-. .,,.- B-ISCO E-Baller *.n,*., r^ /• f T**~*-

——— C-B ladder Pump

^> A-TellonSampler Material p B-Metai_ ,_ . . . . . 1 1 A-TellonTubing Material | ___ | B.Ty00n

Sample Composited Y/N »*_*.

Well Elevation (ft/msl} [£lJ

Depth to Ground water (ft) VL_L. /

Groundwater Elevation (ft msl) ^y~_

1st J/ 1^1 (8TD> !-,P"

2ndrA/l^l «T» 2ndP"

3rd !>*/! (STD' 3rriP"

4th I Vl ^ «TD> 4thP*

Af^l i*c> IA-ftampi* T»mp

Sample Appearance T^^ , «^1*

Weather ConditionR- f~^+ll 'Other 5^"—v' ^Tl r^< ^

F-Scoop/Shovel 'V dPtcirv OTMEWI

C-PVCn.puatic X-O*^'

C- Polyethylene01 MM)

OTHERl

P.€K*0U™*rqoon,o«.

FIELD MEASUREMENTS

* i , uu*nn«pth(ft) |A/ 1/^l i Ramplfi Depth (non-well) (ft) K^l

^ 1 1 ^ P t t> XU_- 'V-» , ,*—

' . A^-f C^C ' .v— £

1 .tM'C I I

iMifcm

•P*C. MM WWW pMIHWMn *

umlcmf.»«-r

imtfcm.1 9fc-r

1/Tl 1 IHTUTyrMdlty

FIELD COMMENTS

<--A") / ^TCJS* -K -f-r-^r^U -K irr*f(*a

*l 1 1*l i 1^ .V- It ff^

\ \*tv* untlt

1 1•MM HMt»

1 1ltd* vnlti

I 1•hi* HIM*

^ ———— A-/V" — .//;S*m?u6- 1>J?TU Sir

tki^fci/^. <n^yL^ T)e.3Tvt ^fit CT 1 ^, *^

)

FILTERING: Use Chain ol Custody (CC1) to indicate which bottles were filtered-T- -C/L,r-fSamnlPr J *" *0 . ) fl ^" '

I certify that sampling procedures wei

F-^-T. ^ LBf

7— -^ /C^" £* /^Irf^Fmplnypr / ^

-..^x Al^-t

e in accordance with applicable ERA state and corporate protocols.

~>~—.0... .t-B^.-r^/ ^ ^J

ORIGINAL

278

• • M» AMI ••*•• - »T •»** mi^«

VT *•*«• • 1

SAMPLENUMBER

e A 1/3 7*flW

Cftl/37?-£

jH IMA^MA

•• • MM

IM

LOGLINK

p*as

MtlMMM

ETC CORP.

PERCENT MOISTURE WORKSHEET

QC BATCH: 7(>J V^

CRUCIBLE CRUCIBLE& WET &

CRUCIBLE WET SOIL SOIL DRY SOILWEIGHT WEIGHT WEIGHT WEIGHT

(g) (g) (g) (g)

/7 fon 1 v

^.^ ^^ : 2/.^/3 ft/ 5-*7. ^2./7

tl V'/ -?4 aJ^ i ^y' ' *• * ** ' T>

/71/1 '

. f

DRYSOIL PERCENT

WEIGHT MOISTURE( g ) ( % j

*.« l£

i!4.ir £?/ 23.2^\

S.J2. /£

COMMENTS

PERCENT MOISTURE SET-UP: _

PERCENT MOISTURE COMPLETION:

SUPERVISOR SIGNATURE: _

DATE:

\ldjrJct DATE:

279

ETC Corp. LABORATORY CHRONICLE : CC-MS Department 97 P«T« ' of *

Date In»tr.

A-Type___iTune fileSeq. filelMethod fil _^ID f i le iDQggqCB fileAnalyst t*-?*-Reviewed by/Date.

Batch

I_ Standards Updated.Dete___ Bw

Tape * Inj.__ul

Standard

•p-ltPG5.5. A*JT> 4**.*.C4(-T

04. 2-

OWVT-fS SottC

Coneppm

So2S?o5050

(/ 2S

LotNo.

SI* I•tf7Ji?MS<rm^505

16^3

LotUol.

\QJLSo « »,5 T

H^—WM

NAME

c A

DATAFile

> PH39

P i rt 5

0.05

c-os

ALS* O i l

IdPVI BI

••••••

tl.••••••

a••••••

••••••

i••••••

t••••••

3

t:\oo

Inj.Time

IS. "31

^'1 I

Comments

n:ts .*' i

23.' Ho -

00:20

Of.

C *

If?

i

R : redo , P t Aroclor search / * : Plus

* IPt

ETC Corp

Date

LABORATORY CHRONICLE : GC-flS Department 98 P«?« 7. of *•

Inatr.

A-TuiSeiheIDCBAnaRe*

Bei

JVoe 2 if %/ VPAie f i le /flf i-iW.a. f i le 3>»t> ,thod film vo*of i le -aooPSnf i le £»o2ST

ilu»t tlLXi*. «c/i>TrfcATjviewed by/Dati

ch *'s f?Vs

^o-n^

1 Standards Updated_ 1(Date Bu 1

Taoe # Inj. ul

Q

-

-

ur

NAHE

5C?o?3TV^

CA*1*7V1

tAHUl^T-

\"\

•

/*

S

S

DATAFile

> -PH5*

>pn5 \

> DllSZ

s.

\

\J

J

,/

in 1 1 .ml/g

^^

tf.o^S

o.o J 5

^*

ALS*

5"^•j.

^

x

Standard

*CC

?Afef-

O*J(L

Coneppm

>^ ———————

LotNo.

LotWo I .

Dil

r.-ioo

1:200

\^xT*XS

/

Inj.Time

ZVH

w:««r

/;/•?

j

^^——

-X

Comments

O»«- 7uAA^tc-

i» S-. *t*.*« •«*-» iai*jL ..1.Offc- * » S JL Mt0

o*c, Jr

/

sS

///

//^

"\^\

^\\

Ct t/»/i» ^\Xl

« • •*

i+

4-

4-

/

-

NR : redo , P : Aroclor seareh , * ; Plus ^vaVbh

cETC CORP. LAB CHRONICLE. Sample Preparation

JOB NO.

1 ft H'5 1 b/• A t/3 7 7

-NT•

»7C*1fc3c?£2^f«i

sicfc*O?7t»it*Ml?)7?»sDi

-Si

LOGLINK

IcO^ ¥••*"V

s.\

^v^

VEB: 'T SPi-t

U. "fc^0

ftf ^.30i\/ Sx ^«

V*1

S

ilf

tir

s,

UJ

j.f

/VY

SAMPLEAMT

mi gm

30.0VJO-03

sX,

_-

~*O£*t

MOIST

/ &/6

sX

_—

16/(;

DRYWGHT

gm

fH.^3iLT-JU

^s.

N

——

|W-W

• X T R A C T VOL trr..j

&*»/ 0

\-O

\x,

/-C ,

/ -O

/ - **

/ 0

Si'wOjtf.£

V

\

Jaoi«.c

ic.cju.b

N77

\X

——

11

*

c

t-

1IV

s,

V

/•»'•V

QC BATCH NO: Qg 7O^H^

REPEAT

ORIGINALJOB NO.

*

\\

^

ORIGINALOS. NO. .

*v

\\

v

ATYPES

i / '- 8 fbW/ffi)K[/ F B / f W / W

K.\\

COMMENTS.

*

PROCEDURE SIGNATURE DATE[3 CONTINUOUS A/ AO SEP. FUNNELp SOXMLET . . . V,2|"SONIF!CA TION vj Men Qa % 3c. ycD DILUTION ' j/AQ DERIVATION *, , . V/ifl CLEANUPjg SETUP

1 o/i,w . .ffti^fl ..j/ ycS. \wicm V-^o.yc'

r* CONCENTRATION jhffarfA Si.3C. VC

tUPERVISOR Sf-lyffu.\ tf-St-VO

MATRIX UPC-TES

Q 2 SOIL QwiPQ 3 COMPLEX nDON£ r/ / 0

SPIKE

irfi Ji*'*puu<y

44IP

Ifft PtWx^

*>

^s^"x^

; .SSj -..-=£

fcA^^ J'ufcfVP At"

VOL rni

/-cQ-%>

"^^

.'C-L "

to€-A

coNc«o"« LOT NUMBER

iecM** W C 7*i-O/^,0 ^A it '/*'/

"X^\

""^vC^t-».-. LOT •,.JWfT =

/C«7J«! tf%C^

J_o IP I ? 7

282

ETC Corp. LABORATORY CHRONICLE : GC-MS Department

Da t m £et>l»U^ kfa MfC l n « t r . Pi/

Page.

A-Type__=-Tune fil e ,Seq. file.Method f i l eID f i l e ' I?CB f i l e __Analys t

fCI

CP ofif

icwcd by/Date ^ifa+j^ 1^

Batch

_ Standards Updated.Da t e________Bv_____

aoe t , I n j . __u 1

StandardConeppm

5-0

Lot LotNo . Uo 1 .

1RI NAME

DATA i n i t .File ml/g

lire/a ;JFTP?

ALS*

2J_±._rJ_2_^_L;0///z

DilInj.Time Common t 3

R : redo , P : Aroclor search t * : Plus search283

ETC Corp.

Da t e

LABORATORY CHRONICLE : GC-MS Department

I na t r .

Page / of___

Tune f i le. file

Method f»ID f i l eCB f i l eAnalystReviewed by/Date

Batch *'a £t C 7&Z2f

I_ Standards Updated3w AV '

Tape * . I n j . __u 1

Standard

I. >7*0 5TP iz:

Coneppm

LotNo.

LotUol.

NAHEDATAF t 1 e

C A toft 6 tf<f72J

in 1 1 .ml/g

ALS* Dil

¥•MM*

r

a

12.If

Inj.Time Comment s

vredo , P : Aroc lor search , * : Plus a4a>Tth

ETC Corp.

Date

LABORATORY CHRONICLE : GC-MS Department

In&tr. -T _________

' *- / /Page / of /

A-Tune f ile

. f i l e KV5~Method fi l eID f i le __CB f i l e _Ana 1 ys t__pReviewed by/Date

Botch *'s

ape #

__ Standards Updated.Date______ Bv __

. I n j . __u 1

Standard

•

Coneppm

n" -T /

sf}-// ^-%-

LotNo.

*>f/

LotUol .

NAME1 DATA1 File

J>r77?

in 1 1 .ml/g

ALS* Dil

3«•*•«•

y

Inj.Time Comment s

\y

R : redo , P : Aroclor aeereh , * : Plus

VfeETC CORP. LAB CHRONICLE. Sample Preparation

JOB NO.

2ftV27fci"A '^377\"\

^*

»7C*1fc3c704Y£fii

Si

w*H 377 MSIfcMl?)7liDi

MS!

LOGLINK

10&> */^

•v\\

>

VER. ' r SPH.I

iif. W?°

i IT ii " O1 \J ^. JC'

V

5

f

ll

iC

X,

UJ

/.f

^K

SAMPLEAMT

ml gm

3°-C)li.30.03

s"X

*

_-"bar>yl?£ior

MOIST

/ S>16

\X

-

——

it'6

DRYwGnT

gm

K4AiJ.lA

V.

N

-•—

i"-^

E X T R A C T VOL cr..

OK A/ o1 O

r\X

/•o ,/ •O

/ - O/ 0

Si<iJQi*c

X

"N

Jac>jc.C

ic.c

N77

\N

—

77

*

c

J !

i

^

(//v

^»'/(^

QC BATCH NO: Qg 7O^H^j

REPEAT

ORIGINALJOB NO.

,

V\

x"

ORIGINALOS. NO. .

.

\

\,

ATYPES/ H'?>/WA/ftrfct

/ F B / f W / w

s.\\

COMMENTS;

PROCEDURE SIGNATURE DATEn CONTINUOUS A/,AD SEP. FUNP SOXHLE,£3" SONIFIC*D DILUTIOND DERiVAT£3 CLEANUF

tSET UPCONCENSUPER V

MA1

Q 1 WAT£

Cg 2 SOILn 3 COMP

NEL |r , vTION ^ VLU 4 fl ^ 3C. yc

I/AON . X)s A/4M S \/fa\d& t-ii v^

SVaj/n iAc.yc;TRATION i)l^(?Sjffq J 3D YC

SOR fef-C^felcx ^ f-Sl-VO

;RIX UPDATES

^ DOSQwiP

.EX ' Q DONE Q / ft

SPIKE

|/=ft fr)i ifUH^y

IFft ?o}x^

-. .scoi.fo/^W ,(SfcC

i,•

*s

SA

ijl

«P

iO

*>^""X.

TESlATV

I/OL mi

/•cy~\ ^

"X^

^CL. m

/ o0-A

CONC u9/»' LOT NUMBER

iecM°y 3 3. C 7

2.0/r.o ^A i^y

^xx^

^xC^r.C-9'»' UCT t.jMF = '-.

/o»/J«j ¥2^3*?o $PJL</1

n 4 riDr.ANir i 10286

ETC Corp.

Date.

LABORATORY CHRONICLE

In»tr._Att__ ______

GC Department 09

A-Type___Co 1umnCol . Lot_C a 1 i b . F i l eSeq. FilMethod f i l eID f i le___

P*T) fe

Con f jgu. £1leAna

____Standard Updated_Da t e O1/t>L S?£> B<J MbJ

ft In ul

Standard

MS_J.(f.ML

A/JJ32

Cone. 1 Lotppm 1 No.

J.6 I 70

9311

,3S

.se> \

Standard

-

Cone .ppm

LotNo.

NAHE

CAWtOG

I___Data File___IDetec.1 Detec.2

>A#/71>M/73

in it . IALS

•:•*-i'_LI

.ilL

.142.

n

Dil Comments

redo287

ETC Corp.

Date.

LABORATORY CHRONICLE

Inatr. QA

Standard

GC Department

Co 1umnCo!. Lot_Ca l i b .F i l eSeq. Fi lenet hod f i le______ID f i l e Z-JJ3 QfiConf igu. f i

Pewiewed bBatch * 's

70223.

ba t

____Standard UpdatedDa t e Q9/0L/9/> Bu

"ape #. . ? ul

XJg - 9

Cone .ppm

LotNo.

Q

StandardCone

ppmLotNo.

NAMEI ___Da t a F i 1 e___IDetec.l Detec.2

.LVfitA

CAVV77C

\>6M10

CAf377M

in it . IALSml/g| *

.i2LIw\33

|37

Oil Common ts

R : redo."288

technical memorandum no. 3a for remedial … · "standard methods for the examination of water...

Documents