technical report for wsp usa - ridgewood public schools

JD10224: Orchard School Soil Remediation, Ridgewood, NJ31402200.001
Report to:
WSP USA 600 East Crescent Avenue Suite 200 Upper Saddle River, NJ 07458 [email protected]
ATTN: Matt Ayers
Total number of pages in report:
Certifications: NJ(12129), NY(10983), CA, CT, FL, IL, IN, KS, KY, LA, MA, MD, ME, MN, NC,
OH VAP (CL0056), AK (UST-103), AZ (AZ0786), PA, RI, SC, TX, UT, VA, WV, DoD ELAP (ANAB L2248)
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 2235 Route 130 • Dayton, NJ 08810 • tel: 732-329-0200 • fax: 732-329-3499
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Victoria Pushkova 732-329-0200
Hemex Patel Appointed Deputy for GM
Dayton, NJ 07/28/20
902
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The results set forth herein are provided by SGS North America Inc.
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Sections:
Section 1: Sample Summary ................................................................................................... 4 Section 2: Case Narrative/Conformance Summary .............................................................. 5 Section 3: Summary of Hits .................................................................................................... 9 Section 4: Sample Results ........................................................................................................ 15
4.1: JD10224-1: TS (2) ........................................................................................................ 16 4.2: JD10224-2: TS (4) ........................................................................................................ 26 4.3: JD10224-3: TS (6) ........................................................................................................ 36 4.4: JD10224-4: TS (8) ........................................................................................................ 46 4.5: JD10224-5: TS (10) ...................................................................................................... 56
Section 5: Misc. Forms ............................................................................................................ 66 5.1: Chain of Custody ........................................................................................................... 67 5.2: Sample Tracking Chronicle ........................................................................................... 70 5.3: Internal Chain of Custody .............................................................................................. 72
Section 6: MS Volatiles - QC Data Summaries ..................................................................... 81 6.1: Method Blank Summary ................................................................................................ 82 6.2: Blank Spike Summary ................................................................................................... 84 6.3: Matrix Spike Summary .................................................................................................. 86 6.4: Duplicate Summary ....................................................................................................... 88 6.5: Instrument Performance Checks (BFB) ......................................................................... 90 6.6: Internal Standard Area Summaries ................................................................................ 92 6.7: Surrogate Recovery Summaries ..................................................................................... 93 6.8: Initial and Continuing Calibration Summaries .............................................................. 94 6.9: Run Sequence Reports ................................................................................................... 108
Section 7: MS Volatiles - Raw Data ........................................................................................ 110 7.1: Samples .......................................................................................................................... 111 7.2: Method Blanks ............................................................................................................... 145
Section 8: MS Semi-volatiles - QC Data Summaries ............................................................ 153 8.1: Method Blank Summary ................................................................................................ 154 8.2: Blank Spike Summary ................................................................................................... 160 8.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 163 8.4: Instrument Performance Checks (DFTPP) .................................................................... 166 8.5: Internal Standard Area Summaries ................................................................................ 181 8.6: Surrogate Recovery Summaries ..................................................................................... 184 8.7: Initial and Continuing Calibration Summaries .............................................................. 185 8.8: Run Sequence Reports ................................................................................................... 230
Section 9: MS Semi-volatiles - Raw Data ............................................................................... 242 9.1: Samples .......................................................................................................................... 243 9.2: Method Blanks ............................................................................................................... 468
Section 10: GC/LC Semi-volatiles - QC Data Summaries ................................................... 484 10.1: Method Blank Summary .............................................................................................. 485 10.2: Blank Spike Summary ................................................................................................. 489 10.3: Matrix Spike/Matrix Spike Duplicate Summary ......................................................... 492
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Sections:
10.4: Duplicate Summary ..................................................................................................... 495 10.5: Internal Standard Area Summaries .............................................................................. 496 10.6: DDT/Endrin Breakdown Checks ................................................................................. 497 10.7: GC Identification Summaries (Hits) ............................................................................ 499 10.8: Surrogate Recovery Summaries ................................................................................... 513 10.9: GC Surrogate Retention Time Summaries .................................................................. 516 10.10: Initial and Continuing Calibration Summaries .......................................................... 525 10.11: Run Sequence Reports ............................................................................................... 579
Section 11: GC/LC Semi-volatiles - Raw Data ...................................................................... 590 11.1: Samples ........................................................................................................................ 591 11.2: Method Blanks ............................................................................................................. 644 11.3: Blank Spikes (NJDEP EPH) ........................................................................................ 655 11.4: Initial and Continuing Calibrations (NJDEP EPH) ...................................................... 658 11.5: Reference Chromatograms ........................................................................................... 769
Section 12: Metals Analysis - QC Data Summaries .............................................................. 785 12.1: Inst QC MA49003: Al,Sb,As,Ba,Be,Cd,Ca,Cr,Co,Cu,Fe,Pb,Mg,Mn,Ni,K,Se,Ag,
Na,Tl,V,Zn ................................................................................................................... 786 12.2: Inst QC MA49009: Al,Ca,Fe ....................................................................................... 823 12.3: Inst QC MA49020: Hg ................................................................................................ 864 12.4: Prep QC MP21941: Al,Sb,As,Ba,Be,Cd,Ca,Cr,Co,Cu,Fe,Pb,Mg,Mn,Ni,K,Se,Ag,
Na,Tl,V,Zn ................................................................................................................... 878 12.5: Prep QC MP22018: Hg ................................................................................................ 890
Section 13: General Chemistry - QC Data Summaries ........................................................ 894 13.1: Method Blank and Spike Results Summary ................................................................ 895 13.2: Duplicate Results Summary ........................................................................................ 896 13.3: Matrix Spike Results Summary ................................................................................... 897 13.4: Inst QC GN9833: Cyanide ........................................................................................... 898 13.5: Percent Solids Raw Data Summary ............................................................................. 902
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Orchard School Soil Remediation, Ridgewood, NJ Project No: 31402200.001
Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies: Organics ND = Not detected above the MDL
JD10224-1 07/15/20 13:55 SZ 07/16/20 SO Soil TS (2)
JD10224-2 07/15/20 14:15 SZ 07/16/20 SO Soil TS (4)
JD10224-3 07/15/20 14:35 SZ 07/16/20 SO Soil TS (6)
JD10224-4 07/15/20 14:55 SZ 07/16/20 SO Soil TS (8)
JD10224-5 07/15/20 15:15 SZ 07/16/20 SO Soil TS (10)
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
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On 07/16/2020, 5 Sample(s), 0 Trip Blank(s) and 0 Field Blank(s) were received at SGS North America Inc. at a maximum corrected temperature of 2.7 C. Samples were intact and chemically preserved, unless noted below. A SGS North America Inc. Job Number of JD10224 was assigned to the project. Laboratory sample ID, client sample ID and dates of sample collection are detailed in the report’s Results Summary Section.
Specified quality control criteria were achieved for this job except as noted below. For more information, please refer to the analytical results and QC summary pages.
Client: WSP USA
Job No JD10224
CASE NARRATIVE / CONFORMANCE SUMMARY
Compounds qualified as out of range in the continuing calibration summary report are acceptable as per method requirements when there is a high bias but the sample result is non-detect.
MS Volatiles By Method SW846 8260C Matrix: SO Batch ID: V1C7559
All samples were analyzed within the recommended method holding time.
All method blanks for this batch meet method specific criteria.
Sample(s) JD10225-1MS, JD10225-2DUP were used as the QC samples indicated.
Matrix Spike Recovery(s) for Methyl Acetate are outside control limits. Outside control limits due to matrix interference.
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MS Semi-volatiles By Method SW846 8270D Matrix: SO Batch ID: OP28558
All samples were extracted within the recommended method holding time.
Sample(s) JD10054-7MS, JD10054-7MSD were used as the QC samples indicated.
JD10224-3 for Benzo(b)fluoranthene: Associated CCV outside of control limits high. Estimated value, due to corresponding failure in the batch associated CCV.
JD10224-3 for Butyl benzyl phthalate: Associated CCV outside of control limits high, sample was ND.
JD10224-2 for bis(2-Ethylhexyl)phthalate: Associated CCV outside of control limits high. Estimated value, due to corresponding failure in the batch associated CCV.
GC/LC Semi-volatiles By Method NJDEP EPH Matrix: SO Batch ID: OP28559
Sample(s) JD10224-1MS, JD10224-1MSD, JD10224-2DUP were used as the QC samples indicated.
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GC/LC Semi-volatiles By Method SW846 8081B Matrix: SO Batch ID: OP28562
Matrix Spike Recovery(s) for alpha-Chlordane are outside control limits. Outside control limits due to matrix interference.
Matrix Spike Duplicate Recovery(s) for alpha-BHC, alpha-Chlordane, Chlordane (alpha and gamma), gamma-BHC (Lindane), Methoxychlor are outside control limits. Outside control limits due to matrix interference.
RPD(s) for MSD for 4,4'-DDE, 4,4'-DDT, Aldrin, alpha-BHC, alpha-Chlordane, beta-BHC, Chlordane (alpha and gamma), delta-BHC, Endosulfan sulfate, Endosulfan-I, Endosulfan-II, Endrin aldehyde, gamma-BHC (Lindane), gamma-Chlordane, Heptachlor, Heptachlor epoxide, Methoxychlor are outside control limits for sample OP28562-MSD. Analytical precision exceeds in-house control limits.
JD10224-4 for alpha-BHC: Associated CCV outside of control limits high, sample was ND.
JD10224-3 for Decachlorobiphenyl: Outside control limits due to matrix interference.
JD10224-5 for 4,4'-DDE: More than 40 % RPD for detected concentrations between the two GC columns.
GC/LC Semi-volatiles By Method SW846 8082A Matrix: SO Batch ID: OP28561
Metals Analysis By Method SW846 6010D Matrix: SO Batch ID: MP21941
All samples were digested within the recommended method holding time.
Sample(s) JD10225-4MS, JD10225-4MSD, JD10225-4PS, JD10225-4SDL were used as the QC samples for metals.
Matrix Spike Recovery(s) for Aluminum, Antimony are outside control limits. Spike recovery indicates possible matrix interference and/or sample nonhomogeneity.
Matrix Spike Duplicate Recovery(s) for Aluminum, Antimony are outside control limits. Spike recovery indicates possible matrix interference and/or sample nonhomogeneity.
RPD(s) for Serial Dilution for Antimony, Arsenic, Beryllium, Cadmium, Silver are outside control limits for sample MP21941- SD1. Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
MP21941-SD1 for Manganese: Serial dilution indicates possible matrix interference.
MP21941-SD1 for Iron: Serial dilution indicates possible matrix interference.
MP21941-SD1 for Chromium: Serial dilution indicates possible matrix interference.
MP21941-SD1 for Zinc: Serial dilution indicates possible matrix interference.
Metals Analysis By Method SW846 7471B Matrix: SO Batch ID: MP22018
All samples were digested within the recommended method holding time.
Sample(s) JD10130-11MS, JD10130-11MSD were used as the QC samples for metals.
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General Chemistry By Method SM2540 G 18TH ED MOD Matrix: SO Batch ID: GN9719
Sample(s) JD10222-21DUP were used as the QC samples for Solids, Percent.
Matrix: SO Batch ID: GN9721
Sample(s) JD10295-1DUP were used as the QC samples for Solids, Percent.
General Chemistry By Method SW846 9012B/LACHAT Matrix: SO Batch ID: GP29160
All samples were prepared within the recommended method holding time.
Sample(s) JD10296-5DUP, JD10296-5MS were used as the QC samples for Cyanide.
SGS North America Inc. certifies that data reported for samples received, listed on the associated custody chain or analytical task order, were produced to specifications meeting the Quality System precision, accuracy and completeness objectives except as noted.
Estimated non-standard method measurement uncertainty data is available on request, based on quality control bias and implicit for standard methods. Acceptable uncertainty requires tested parameter quality control data to meet method criteria.
SGS North America Inc. is not responsible for data quality assumptions if partial reports are used and recommends that this report be used in its entirety. Data release is authorized by SGS North America Inc indicated via signature on the report cover
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Summary of Hits Page 1 of 6 Job Number: JD10224 Account: WSP USA Project: Orchard School Soil Remediation, Ridgewood, NJ Collected: 07/15/20
Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method
JD10224-1 TS (2)
Acetone 41.0 20 7.9 ug/kg SW846 8260C Total TIC, Volatile 11 J ug/kg 3&4-Methylphenol 875 94 38 ug/kg SW846 8270D Phenol 260 94 24 ug/kg SW846 8270D Acenaphthene 20.0 J 47 16 ug/kg SW846 8270D Acetophenone 61.9 J 230 10 ug/kg SW846 8270D Anthracene 48.3 47 29 ug/kg SW846 8270D Benzo(a)anthracene 216 47 13 ug/kg SW846 8270D Benzo(a)pyrene 198 47 21 ug/kg SW846 8270D Benzo(b)fluoranthene a 295 47 21 ug/kg SW846 8270D Benzo(g,h,i)perylene 155 47 23 ug/kg SW846 8270D Benzo(k)fluoranthene 91.4 47 22 ug/kg SW846 8270D 1,1'-Biphenyl 8.1 J 94 6.4 ug/kg SW846 8270D Carbazole 16.3 J 94 6.8 ug/kg SW846 8270D Chrysene 267 47 15 ug/kg SW846 8270D Dibenzo(a,h)anthracene 40.4 J 47 21 ug/kg SW846 8270D Dibenzofuran 24.3 J 94 19 ug/kg SW846 8270D bis(2-Ethylhexyl)phthalate a 129 94 11 ug/kg SW846 8270D Fluoranthene 475 47 21 ug/kg SW846 8270D Indeno(1,2,3-cd)pyrene 170 47 22 ug/kg SW846 8270D 2-Methylnaphthalene 11.2 J 47 11 ug/kg SW846 8270D Naphthalene 17.2 J 47 13 ug/kg SW846 8270D Phenanthrene 131 47 16 ug/kg SW846 8270D Pyrene 436 47 15 ug/kg SW846 8270D Total TIC, Semi-Volatile 62900 J ug/kg EPH (C9-C28) 126 9.4 2.8 mg/kg NJDEP EPH EPH (>C28-C40) 324 9.4 2.8 mg/kg NJDEP EPH Total EPH (C9-C40) 450 9.4 2.8 mg/kg NJDEP EPH 4,4'-DDE 6.3 0.93 0.82 ug/kg SW846 8081B Aluminum 6780 72 mg/kg SW846 6010D Arsenic 4.4 2.9 mg/kg SW846 6010D Barium 66.6 29 mg/kg SW846 6010D Beryllium 0.35 0.29 mg/kg SW846 6010D Calcium 7730 720 mg/kg SW846 6010D Chromium 14.5 1.4 mg/kg SW846 6010D Copper 29.2 3.6 mg/kg SW846 6010D Iron 11600 72 mg/kg SW846 6010D Lead 68.1 2.9 mg/kg SW846 6010D Magnesium 2720 720 mg/kg SW846 6010D Manganese 319 2.2 mg/kg SW846 6010D Mercury 0.12 0.037 mg/kg SW846 7471B Nickel 12.9 5.8 mg/kg SW846 6010D Potassium 4240 1400 mg/kg SW846 6010D
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Vanadium 18.0 7.2 mg/kg SW846 6010D Zinc 96.4 7.2 mg/kg SW846 6010D
JD10224-2 TS (4)
Acetone 20.5 16 6.5 ug/kg SW846 8260C 3&4-Methylphenol 364 91 38 ug/kg SW846 8270D Phenol 106 91 24 ug/kg SW846 8270D Acenaphthene 27.8 J 46 16 ug/kg SW846 8270D Acetophenone 39.1 J 230 9.8 ug/kg SW846 8270D Anthracene 59.8 46 28 ug/kg SW846 8270D Benzo(a)anthracene 204 46 13 ug/kg SW846 8270D Benzo(a)pyrene 188 46 21 ug/kg SW846 8270D Benzo(b)fluoranthene a 283 46 20 ug/kg SW846 8270D Benzo(g,h,i)perylene 154 46 23 ug/kg SW846 8270D Benzo(k)fluoranthene 89.7 46 21 ug/kg SW846 8270D 1,1'-Biphenyl 9.6 J 91 6.3 ug/kg SW846 8270D Benzaldehyde 102 J 230 11 ug/kg SW846 8270D Carbazole 16.5 J 91 6.6 ug/kg SW846 8270D Chrysene 253 46 14 ug/kg SW846 8270D Dibenzo(a,h)anthracene 38.8 J 46 20 ug/kg SW846 8270D Dibenzofuran 27.2 J 91 19 ug/kg SW846 8270D bis(2-Ethylhexyl)phthalate a 117 91 11 ug/kg SW846 8270D Fluoranthene 465 46 20 ug/kg SW846 8270D Fluorene 31.4 J 46 21 ug/kg SW846 8270D Indeno(1,2,3-cd)pyrene 163 46 21 ug/kg SW846 8270D 2-Methylnaphthalene 18.4 J 46 10 ug/kg SW846 8270D Naphthalene 24.3 J 46 13 ug/kg SW846 8270D Phenanthrene 267 46 15 ug/kg SW846 8270D Pyrene 452 46 15 ug/kg SW846 8270D Total TIC, Semi-Volatile 55220 J ug/kg EPH (C9-C28) 151 9.0 2.7 mg/kg NJDEP EPH EPH (>C28-C40) 288 9.0 2.7 mg/kg NJDEP EPH Total EPH (C9-C40) 439 9.0 2.7 mg/kg NJDEP EPH 4,4'-DDE 6.0 0.91 0.80 ug/kg SW846 8081B Aluminum 6340 68 mg/kg SW846 6010D Arsenic 3.9 2.7 mg/kg SW846 6010D Barium 59.8 27 mg/kg SW846 6010D Beryllium 0.33 0.27 mg/kg SW846 6010D Calcium 5210 680 mg/kg SW846 6010D Chromium 12.7 1.4 mg/kg SW846 6010D Copper 30.2 3.4 mg/kg SW846 6010D Iron 10800 68 mg/kg SW846 6010D Lead 61.1 2.7 mg/kg SW846 6010D Magnesium 2290 680 mg/kg SW846 6010D
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Manganese 264 2.0 mg/kg SW846 6010D Mercury 0.11 0.038 mg/kg SW846 7471B Nickel 12.7 5.4 mg/kg SW846 6010D Potassium 2570 1400 mg/kg SW846 6010D Vanadium 16.1 6.8 mg/kg SW846 6010D Zinc 83.9 6.8 mg/kg SW846 6010D
JD10224-3 TS (6)
Acetone 42.9 16 6.4 ug/kg SW846 8260C 3&4-Methylphenol 67.4 J 87 36 ug/kg SW846 8270D Phenol 41.7 J 87 23 ug/kg SW846 8270D Acenaphthene 21.0 J 43 15 ug/kg SW846 8270D Acetophenone 12.7 J 220 9.3 ug/kg SW846 8270D Anthracene 46.0 43 27 ug/kg SW846 8270D Benzo(a)anthracene 176 43 12 ug/kg SW846 8270D Benzo(a)pyrene 157 43 20 ug/kg SW846 8270D Benzo(b)fluoranthene a 222 43 19 ug/kg SW846 8270D Benzo(g,h,i)perylene 109 43 22 ug/kg SW846 8270D Benzo(k)fluoranthene 68.3 43 20 ug/kg SW846 8270D Benzaldehyde 39.2 J 220 11 ug/kg SW846 8270D Carbazole 20.2 J 87 6.3 ug/kg SW846 8270D Chrysene 199 43 14 ug/kg SW846 8270D Dibenzo(a,h)anthracene 26.7 J 43 19 ug/kg SW846 8270D Dibenzofuran 19.4 J 87 18 ug/kg SW846 8270D bis(2-Ethylhexyl)phthalate a 120 87 10 ug/kg SW846 8270D Fluoranthene 342 43 19 ug/kg SW846 8270D Fluorene 26.3 J 43 20 ug/kg SW846 8270D Indeno(1,2,3-cd)pyrene 126 43 20 ug/kg SW846 8270D Phenanthrene 235 43 15 ug/kg SW846 8270D Pyrene 316 43 14 ug/kg SW846 8270D Total TIC, Semi-Volatile 64050 J ug/kg EPH (C9-C28) 160 8.2 2.4 mg/kg NJDEP EPH EPH (>C28-C40) 409 8.2 2.4 mg/kg NJDEP EPH Total EPH (C9-C40) 569 8.2 2.4 mg/kg NJDEP EPH gamma-Chlordane 6.5 0.81 0.37 ug/kg SW846 8081B Chlordane (alpha and gamma) 6.5 0.81 0.37 ug/kg SW846 8081B 4,4'-DDE 3.3 0.81 0.71 ug/kg SW846 8081B Aluminum 6620 66 mg/kg SW846 6010D Arsenic 4.8 2.6 mg/kg SW846 6010D Barium 70.4 26 mg/kg SW846 6010D Beryllium 0.40 0.26 mg/kg SW846 6010D Calcium 12000 660 mg/kg SW846 6010D Chromium 14.3 1.3 mg/kg SW846 6010D Copper 22.6 3.3 mg/kg SW846 6010D
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Iron 12800 66 mg/kg SW846 6010D Lead 86.8 2.6 mg/kg SW846 6010D Magnesium 3110 660 mg/kg SW846 6010D Manganese 358 2.0 mg/kg SW846 6010D Mercury 0.091 0.035 mg/kg SW846 7471B Nickel 12.2 5.3 mg/kg SW846 6010D Potassium 2690 1300 mg/kg SW846 6010D Vanadium 18.9 6.6 mg/kg SW846 6010D Zinc 79.3 6.6 mg/kg SW846 6010D
JD10224-4 TS (8)
Phenol 25.3 J 92 24 ug/kg SW846 8270D Acetophenone 24.4 J 230 9.9 ug/kg SW846 8270D Benzo(a)anthracene 112 46 13 ug/kg SW846 8270D Benzo(a)pyrene 106 46 21 ug/kg SW846 8270D Benzo(b)fluoranthene a 192 46 20 ug/kg SW846 8270D Benzo(g,h,i)perylene 98.4 46 23 ug/kg SW846 8270D Benzo(k)fluoranthene 52.5 46 21 ug/kg SW846 8270D Benzaldehyde 126 J 230 11 ug/kg SW846 8270D Chrysene 155 46 14 ug/kg SW846 8270D Dibenzo(a,h)anthracene 24.0 J 46 20 ug/kg SW846 8270D bis(2-Ethylhexyl)phthalate a 70.0 J 92 11 ug/kg SW846 8270D Fluoranthene 213 46 20 ug/kg SW846 8270D Indeno(1,2,3-cd)pyrene 120 46 22 ug/kg SW846 8270D Phenanthrene 37.6 J 46 15 ug/kg SW846 8270D Pyrene 107 46 15 ug/kg SW846 8270D Total TIC, Semi-Volatile 54180 J ug/kg EPH (C9-C28) 104 9.1 2.7 mg/kg NJDEP EPH EPH (>C28-C40) 306 9.1 2.7 mg/kg NJDEP EPH Total EPH (C9-C40) 410 9.1 2.7 mg/kg NJDEP EPH Dieldrin 2.4 0.90 0.62 ug/kg SW846 8081B 4,4'-DDE 7.1 0.90 0.79 ug/kg SW846 8081B Aluminum 3950 72 mg/kg SW846 6010D Arsenic 3.1 2.9 mg/kg SW846 6010D Barium 50.4 29 mg/kg SW846 6010D Beryllium 0.29 0.29 mg/kg SW846 6010D Calcium 9230 720 mg/kg SW846 6010D Chromium 13.9 1.4 mg/kg SW846 6010D Copper 21.0 3.6 mg/kg SW846 6010D Iron 10100 72 mg/kg SW846 6010D Lead 40.4 2.9 mg/kg SW846 6010D Magnesium 3420 720 mg/kg SW846 6010D Manganese 276 2.2 mg/kg SW846 6010D Mercury 0.052 0.039 mg/kg SW846 7471B
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Nickel 16.8 5.7 mg/kg SW846 6010D Potassium 2800 1400 mg/kg SW846 6010D Vanadium 17.8 7.2 mg/kg SW846 6010D Zinc 72.9 7.2 mg/kg SW846 6010D
JD10224-5 TS (10)
Anthracene 56.9 38 23 ug/kg SW846 8270D Benzo(a)anthracene 166 38 11 ug/kg SW846 8270D Benzo(a)pyrene 156 38 17 ug/kg SW846 8270D Benzo(b)fluoranthene a 196 38 17 ug/kg SW846 8270D Benzo(g,h,i)perylene 110 38 19 ug/kg SW846 8270D Benzo(k)fluoranthene 68.9 38 18 ug/kg SW846 8270D Benzaldehyde 42.6 J 190 9.3 ug/kg SW846 8270D Carbazole 23.8 J 75 5.4 ug/kg SW846 8270D Chrysene 183 38 12 ug/kg SW846 8270D Dibenzo(a,h)anthracene 28.4 J 38 17 ug/kg SW846 8270D Dibenzofuran 17.1 J 75 15 ug/kg SW846 8270D bis(2-Ethylhexyl)phthalate a 77.7 75 8.8 ug/kg SW846 8270D Fluoranthene 334 38 17 ug/kg SW846 8270D Indeno(1,2,3-cd)pyrene 125 38 18 ug/kg SW846 8270D Phenanthrene 231 38 13 ug/kg SW846 8270D Pyrene 337 38 12 ug/kg SW846 8270D Total TIC, Semi-Volatile 36060 J ug/kg EPH (C9-C28) 81.4 7.5 2.2 mg/kg NJDEP EPH EPH (>C28-C40) 229 7.5 2.2 mg/kg NJDEP EPH Total EPH (C9-C40) 311 7.5 2.2 mg/kg NJDEP EPH gamma-Chlordane 2.7 0.73 0.33 ug/kg SW846 8081B Chlordane (alpha and gamma) 2.7 0.73 0.33 ug/kg SW846 8081B 4,4'-DDE b 1.5 0.73 0.64 ug/kg SW846 8081B Aluminum 7420 59 mg/kg SW846 6010D Arsenic 3.4 2.3 mg/kg SW846 6010D Barium 55.0 23 mg/kg SW846 6010D Beryllium 0.40 0.23 mg/kg SW846 6010D Calcium 3210 590 mg/kg SW846 6010D Chromium 15.9 1.2 mg/kg SW846 6010D Copper 18.6 2.9 mg/kg SW846 6010D Iron 12500 59 mg/kg SW846 6010D Lead 60.8 2.3 mg/kg SW846 6010D Magnesium 2350 590 mg/kg SW846 6010D Manganese 325 1.8 mg/kg SW846 6010D Mercury 0.10 0.032 mg/kg SW846 7471B Nickel 15.6 4.7 mg/kg SW846 6010D Potassium 1380 1200 mg/kg SW846 6010D Vanadium 18.6 5.9 mg/kg SW846 6010D
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Zinc 60.0 5.9 mg/kg SW846 6010D
(a) Associated CCV outside of control limits high. Estimated value, due to corresponding failure in the batch associated CCV.
(b) More than 40 % RPD for detected concentrations between the two GC columns.
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Report of Analysis Page 1 of 2
Client Sample ID: TS (2) Lab Sample ID: JD10224-1 Date Sampled: 07/15/20 Matrix: SO - Soil Date Received: 07/16/20 Method: SW846 8260C SW846 5035 Percent Solids: 70.7 Project: Orchard School Soil Remediation, Ridgewood, NJ
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1C172980.D 1 07/17/20 14:10 TDN 07/17/20 10:00 n/a V1C7559 Run #2
Initial Weight Run #1 3.6 g Run #2
VOA TCL List
CAS No. Compound Result RL MDL Units Q
67-64-1 Acetone 41.0 20 7.9 ug/kg 71-43-2 Benzene ND 0.98 0.89 ug/kg 74-97-5 Bromochloromethane ND 9.8 1.1 ug/kg 75-27-4 Bromodichloromethane ND 3.9 0.87 ug/kg 75-25-2 Bromoform ND 9.8 1.1 ug/kg 74-83-9 Bromomethane ND 9.8 2.0 ug/kg 78-93-3 2-Butanone (MEK) ND 20 7.3 ug/kg 75-15-0 Carbon disulfide ND 3.9 1.8 ug/kg 56-23-5 Carbon tetrachloride ND 3.9 1.2 ug/kg 108-90-7 Chlorobenzene ND 3.9 0.90 ug/kg 75-00-3 Chloroethane ND 9.8 1.2 ug/kg 67-66-3 Chloroform ND 3.9 0.96 ug/kg 74-87-3 Chloromethane ND 9.8 3.9 ug/kg 110-82-7 Cyclohexane ND 3.9 1.3 ug/kg 96-12-8 1,2-Dibromo-3-chloropropane ND 3.9 1.6 ug/kg 124-48-1 Dibromochloromethane ND 3.9 1.1 ug/kg 106-93-4 1,2-Dibromoethane ND 2.0 0.83 ug/kg 95-50-1 1,2-Dichlorobenzene ND 2.0 1.1 ug/kg 541-73-1 1,3-Dichlorobenzene ND 2.0 0.97 ug/kg 106-46-7 1,4-Dichlorobenzene ND 2.0 0.97 ug/kg 75-71-8 Dichlorodifluoromethane ND 9.8 1.4 ug/kg 75-34-3 1,1-Dichloroethane ND 2.0 0.97 ug/kg 107-06-2 1,2-Dichloroethane ND 2.0 0.92 ug/kg 75-35-4 1,1-Dichloroethene ND 2.0 1.3 ug/kg 156-59-2 cis-1,2-Dichloroethene ND 2.0 1.7 ug/kg 156-60-5 trans-1,2-Dichloroethene ND 2.0 1.2 ug/kg 78-87-5 1,2-Dichloropropane ND 3.9 0.93 ug/kg 10061-01-5 cis-1,3-Dichloropropene ND 3.9 0.93 ug/kg 10061-02-6 trans-1,3-Dichloropropene ND 3.9 0.90 ug/kg 100-41-4 Ethylbenzene ND 2.0 1.1 ug/kg 76-13-1 Freon 113 ND 9.8 2.0 ug/kg 591-78-6 2-Hexanone ND 9.8 4.2 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
Raw Data: 1C172980.D
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VOA TCL List
98-82-8 Isopropylbenzene ND 3.9 1.4 ug/kg 79-20-9 Methyl Acetate ND 9.8 2.7 ug/kg 108-87-2 Methylcyclohexane ND 3.9 1.7 ug/kg 1634-04-4 Methyl Tert Butyl Ether ND 2.0 0.92 ug/kg 108-10-1 4-Methyl-2-pentanone(MIBK) ND 9.8 4.5 ug/kg 75-09-2 Methylene chloride ND 9.8 4.9 ug/kg 100-42-5 Styrene ND 3.9 1.1 ug/kg 79-34-5 1,1,2,2-Tetrachloroethane ND 3.9 1.2 ug/kg 127-18-4 Tetrachloroethene ND 3.9 1.1 ug/kg 108-88-3 Toluene ND 2.0 1.0 ug/kg 87-61-6 1,2,3-Trichlorobenzene ND 9.8 4.9 ug/kg 120-82-1 1,2,4-Trichlorobenzene ND 9.8 4.9 ug/kg 71-55-6 1,1,1-Trichloroethane ND 3.9 0.95 ug/kg 79-00-5 1,1,2-Trichloroethane ND 3.9 1.1 ug/kg 79-01-6 Trichloroethene ND 2.0 1.5 ug/kg 75-69-4 Trichlorofluoromethane ND 9.8 1.3 ug/kg 75-01-4 Vinyl chloride ND 3.9 0.94 ug/kg
m,p-Xylene ND 2.0 1.8 ug/kg 95-47-6 o-Xylene ND 2.0 1.1 ug/kg 1330-20-7 Xylene (total) ND 2.0 1.1 ug/kg
CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 107% 75-127% 17060-07-0 1,2-Dichloroethane-D4 111% 75-130% 2037-26-5 Toluene-D8 101% 80-120% 460-00-4 4-Bromofluorobenzene 104% 79-127%
CAS No. Tentatively Identified Compounds R.T. Est. Conc. Units Q
75-18-3 Dimethyl sulfide 6.76 11 ug/kg JN Total TIC, Volatile 11 ug/kg J
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Client Sample ID: TS (2) Lab Sample ID: JD10224-1 Date Sampled: 07/15/20 Matrix: SO - Soil Date Received: 07/16/20 Method: SW846 8270D SW846 3546 Percent Solids: 70.7 Project: Orchard School Soil Remediation, Ridgewood, NJ
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2P95146.D 1 07/22/20 17:35 HSS 07/20/20 16:00 OP28558 E2P4228 Run #2
Initial Weight Final Volume Run #1 30.2 g 1.0 ml Run #2
ABN TCL List (SOM0 2.0)
95-57-8 2-Chlorophenol ND 94 23 ug/kg 59-50-7 4-Chloro-3-methyl phenol ND 230 29 ug/kg 120-83-2 2,4-Dichlorophenol ND 230 40 ug/kg 105-67-9 2,4-Dimethylphenol ND 230 83 ug/kg 51-28-5 2,4-Dinitrophenol ND 230 180 ug/kg 534-52-1 4,6-Dinitro-o-cresol ND 230 50 ug/kg 95-48-7 2-Methylphenol ND 94 30 ug/kg
3&4-Methylphenol 875 94 38 ug/kg 88-75-5 2-Nitrophenol ND 230 31 ug/kg 100-02-7 4-Nitrophenol ND 470 130 ug/kg 87-86-5 Pentachlorophenol ND 190 44 ug/kg 108-95-2 Phenol 260 94 24 ug/kg 58-90-2 2,3,4,6-Tetrachlorophenol ND 230 31 ug/kg 95-95-4 2,4,5-Trichlorophenol ND 230 35 ug/kg 88-06-2 2,4,6-Trichlorophenol ND 230 28 ug/kg 83-32-9 Acenaphthene 20.0 47 16 ug/kg J 208-96-8 Acenaphthylene ND 47 24 ug/kg 98-86-2 Acetophenone 61.9 230 10 ug/kg J 120-12-7 Anthracene 48.3 47 29 ug/kg 1912-24-9 Atrazine ND 94 20 ug/kg 56-55-3 Benzo(a)anthracene 216 47 13 ug/kg 50-32-8 Benzo(a)pyrene 198 47 21 ug/kg 205-99-2 Benzo(b)fluoranthene a 295 47 21 ug/kg 191-24-2 Benzo(g,h,i)perylene 155 47 23 ug/kg 207-08-9 Benzo(k)fluoranthene 91.4 47 22 ug/kg 101-55-3 4-Bromophenyl phenyl ether ND 94 18 ug/kg 85-68-7 Butyl benzyl phthalate b ND 94 11 ug/kg 92-52-4 1,1'-Biphenyl 8.1 94 6.4 ug/kg J 100-52-7 Benzaldehyde ND 230 12 ug/kg 91-58-7 2-Chloronaphthalene ND 94 11 ug/kg 106-47-8 4-Chloroaniline ND 230 17 ug/kg 86-74-8 Carbazole 16.3 94 6.8 ug/kg J
Raw Data: 2P95146.D
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105-60-2 Caprolactam ND 94 18 ug/kg 218-01-9 Chrysene 267 47 15 ug/kg 111-91-1 bis(2-Chloroethoxy)methane ND 94 10 ug/kg 111-44-4 bis(2-Chloroethyl)ether ND 94 20 ug/kg 108-60-1 2,2'-Oxybis(1-chloropropane) ND 94 17 ug/kg 7005-72-3 4-Chlorophenyl phenyl ether ND 94 15 ug/kg 121-14-2 2,4-Dinitrotoluene ND 47 15 ug/kg 606-20-2 2,6-Dinitrotoluene ND 47 24 ug/kg 91-94-1 3,3'-Dichlorobenzidine ND 94 39 ug/kg 123-91-1 1,4-Dioxane ND 47 31 ug/kg 53-70-3 Dibenzo(a,h)anthracene 40.4 47 21 ug/kg J 132-64-9 Dibenzofuran 24.3 94 19 ug/kg J 84-74-2 Di-n-butyl phthalate ND 94 7.6 ug/kg 117-84-0 Di-n-octyl phthalate ND 94 12 ug/kg 84-66-2 Diethyl phthalate ND 94 10 ug/kg 131-11-3 Dimethyl phthalate ND 94 8.3 ug/kg 117-81-7 bis(2-Ethylhexyl)phthalate a 129 94 11 ug/kg 206-44-0 Fluoranthene 475 47 21 ug/kg 86-73-7 Fluorene ND 47 21 ug/kg 118-74-1 Hexachlorobenzene ND 94 12 ug/kg 87-68-3 Hexachlorobutadiene ND 47 19 ug/kg 77-47-4 Hexachlorocyclopentadiene ND 470 19 ug/kg 67-72-1 Hexachloroethane ND 230 23 ug/kg 193-39-5 Indeno(1,2,3-cd)pyrene 170 47 22 ug/kg 78-59-1 Isophorone ND 94 10 ug/kg 91-57-6 2-Methylnaphthalene 11.2 47 11 ug/kg J 88-74-4 2-Nitroaniline ND 230 11 ug/kg 99-09-2 3-Nitroaniline ND 230 12 ug/kg 100-01-6 4-Nitroaniline ND 230 12 ug/kg 91-20-3 Naphthalene 17.2 47 13 ug/kg J 98-95-3 Nitrobenzene ND 94 18 ug/kg 621-64-7 N-Nitroso-di-n-propylamine ND 94 14 ug/kg 86-30-6 N-Nitrosodiphenylamine ND 230 17 ug/kg 85-01-8 Phenanthrene 131 47 16 ug/kg 129-00-0 Pyrene 436 47 15 ug/kg 95-94-3 1,2,4,5-Tetrachlorobenzene ND 230 12 ug/kg
367-12-4 2-Fluorophenol 34% 7-101%
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4165-62-2 Phenol-d5 35% 12-101% 118-79-6 2,4,6-Tribromophenol 42% 10-127% 4165-60-0 Nitrobenzene-d5 34% 15-114% 321-60-8 2-Fluorobiphenyl 38% 22-104% 1718-51-0 Terphenyl-d14 44% 23-121%
system artifact/aldol-condensation 3.26 4900 ug/kg J unknown 9.13 1300 ug/kg J unknown 9.75 2700 ug/kg J unknown 10.04 1300 ug/kg J
57-10-3 n-Hexadecanoic acid 10.62 3500 ug/kg JN unknown 10.81 750 ug/kg J
150-86-7 Phytol 11.52 1200 ug/kg JN unknown 14.71 730 ug/kg J unknown 16.49 850 ug/kg J alkane 16.52 1300 ug/kg J unknown 16.58 1200 ug/kg J
59-02-9 Vitamin E 16.69 1200 ug/kg JN unknown 17.24 980 ug/kg J
83-48-7 Stigmasterol 17.38 1800 ug/kg JN Sitosterol 17.75 13000 ug/kg J -Amyrin 18.02 4900 ug/kg J unknown 18.11 5800 ug/kg J unknown 18.32 9100 ug/kg J unknown 18.40 1000 ug/kg J unknown 18.50 1400 ug/kg J unknown 18.58 790 ug/kg J unknown 18.73 1700 ug/kg J unknown 18.83 1300 ug/kg J unknown 19.10 1200 ug/kg J unknown 19.23 3900 ug/kg J Total TIC, Semi-Volatile 62900 ug/kg J
(b) Associated CCV outside of control limits high, sample was ND.
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Client Sample ID: TS (2) Lab Sample ID: JD10224-1 Date Sampled: 07/15/20 Matrix: SO - Soil Date Received: 07/16/20 Method: SW846 8081B SW846 3546 Percent Solids: 70.7 Project: Orchard School Soil Remediation, Ridgewood, NJ
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1G163211.D 1 07/21/20 03:18 CP 07/20/20 15:40 OP28562 G1G5463 Run #2
Pesticide TCL List
309-00-2 Aldrin ND 0.93 0.77 ug/kg 319-84-6 alpha-BHC a ND 0.93 0.76 ug/kg 319-85-7 beta-BHC ND 0.93 0.84 ug/kg 319-86-8 delta-BHC ND 0.93 0.89 ug/kg 58-89-9 gamma-BHC (Lindane) ND 0.93 0.69 ug/kg 5103-71-9 alpha-Chlordane ND 0.93 0.75 ug/kg 5103-74-2 gamma-Chlordane ND 0.93 0.42 ug/kg 57-74-9 Chlordane (alpha and gamma) ND 0.93 0.42 ug/kg 60-57-1 Dieldrin ND 0.93 0.64 ug/kg 72-54-8 4,4'-DDD ND 0.93 0.85 ug/kg 72-55-9 4,4'-DDE 6.3 0.93 0.82 ug/kg 50-29-3 4,4'-DDT ND 0.93 0.82 ug/kg 72-20-8 Endrin ND 0.93 0.72 ug/kg 1031-07-8 Endosulfan sulfate ND 0.93 0.73 ug/kg 7421-93-4 Endrin aldehyde ND 0.93 0.53 ug/kg 959-98-8 Endosulfan-I ND 0.93 0.54 ug/kg 33213-65-9 Endosulfan-II ND 0.93 0.58 ug/kg 76-44-8 Heptachlor ND 0.93 0.80 ug/kg 1024-57-3 Heptachlor epoxide ND 0.93 0.65 ug/kg 72-43-5 Methoxychlor ND 1.9 0.74 ug/kg 53494-70-5 Endrin ketone ND 0.93 0.67 ug/kg 8001-35-2 Toxaphene ND 23 22 ug/kg
877-09-8 Tetrachloro-m-xylene 78% 25-135% 877-09-8 Tetrachloro-m-xylene 77% 25-135% 2051-24-3 Decachlorobiphenyl 102% 10-156% 2051-24-3 Decachlorobiphenyl 91% 10-156%
(a) Associated CCV outside of control limits high, sample was ND.
Raw Data: 1G163211.D
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Client Sample ID: TS (2) Lab Sample ID: JD10224-1 Date Sampled: 07/15/20 Matrix: SO - Soil Date Received: 07/16/20 Method: SW846 8082A SW846 3546 Percent Solids: 70.7 Project: Orchard School Soil Remediation, Ridgewood, NJ
PCB List
12674-11-2 Aroclor 1016 ND 47 22 ug/kg 11104-28-2 Aroclor 1221 ND 47 29 ug/kg 11141-16-5 Aroclor 1232 ND 47 30 ug/kg 53469-21-9 Aroclor 1242 ND 47 19 ug/kg 12672-29-6 Aroclor 1248 ND 47 42 ug/kg 11097-69-1 Aroclor 1254 ND 47 25 ug/kg 11096-82-5 Aroclor 1260 ND 47 20 ug/kg 11100-14-4 Aroclor 1268 ND 47 20 ug/kg 37324-23-5 Aroclor 1262 ND 47 30 ug/kg
Raw Data: 5G98192.D
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Client Sample ID: TS (2) Lab Sample ID: JD10224-1 Date Sampled: 07/15/20 Matrix: SO - Soil Date Received: 07/16/20 Method: NJDEP EPH SW846 3546 Percent Solids: 70.7 Project: Orchard School Soil Remediation, Ridgewood, NJ
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 5Y59422.D 1 07/22/20 17:57 TL 07/21/20 09:15 OP28559 G5Y3056 Run #2
NJDEP EPH List
EPH (C9-C28) 126 9.4 2.8 mg/kg EPH (>C28-C40) 324 9.4 2.8 mg/kg Total EPH (C9-C40) 450 9.4 2.8 mg/kg
84-15-1 o-Terphenyl 49% 40-140% 3386-33-2 1-Chlorooctadecane 50% 40-140%
Raw Data: 5Y59422.D
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Client Sample ID: TS (2) Lab Sample ID: JD10224-1 Date Sampled: 07/15/20 Matrix: SO - Soil Date Received: 07/16/20
Percent Solids: 70.7 Project: Orchard School Soil Remediation, Ridgewood, NJ
Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Aluminum 6780 72 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Antimony <2.9 2.9 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Arsenic 4.4 2.9 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Barium 66.6 29 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Beryllium 0.35 0.29 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Cadmium <0.72 0.72 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Calcium 7730 720 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Chromium 14.5 1.4 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Cobalt <7.2 7.2 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Copper 29.2 3.6 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Iron 11600 72 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Lead 68.1 2.9 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Magnesium 2720 720 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Manganese 319 2.2 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Mercury 0.12 0.037 mg/kg 1 07/22/20 07/22/20 LL SW846 7471B 2 SW846 7471B 4
Nickel 12.9 5.8 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Potassium 4240 1400 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Selenium <2.9 2.9 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Silver <0.72 0.72 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Sodium <1400 1400 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Thallium <1.4 1.4 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Vanadium 18.0 7.2 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
Zinc 96.4 7.2 mg/kg 1 07/17/20 07/17/20 ND SW846 6010D 1 SW846 3050B 3
(1) Instrument QC Batch: MA49003 (2) Instrument QC Batch: MA49020 (3) Prep QC Batch: MP21941 (4) Prep QC Batch: MP22018
RL = Reporting Limit
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General Chemistry
Cyanide <0.21 0.21 mg/kg 1 07/23/20 10:09 KI SW846 9012B/LACHAT
Solids, Percent 70.7 % 1 07/20/20 16:24 BG SM2540 G 18TH ED MOD
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VOA TCL List
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VOA TCL List
Total TIC, Volatile 0 ug/kg
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3&4-Methylphenol 364 91 38 ug/kg 88-75-5 2-Nitrophenol ND 230 30 ug/kg 100-02-7 4-Nitrophenol ND 460 120 ug/kg 87-86-5 Pentachlorophenol ND 180 43 ug/kg 108-95-2 Phenol 106 91 24 ug/kg 58-90-2 2,3,4,6-Tetrachlorophenol ND 230 30 ug/kg 95-95-4 2,4,5-Trichlorophenol ND 230 34 ug/kg 88-06-2 2,4,6-Trichlorophenol ND 230 27 ug/kg 83-32-9 Acenaphthene 27.8 46 16 ug/kg J 208-96-8 Acenaphthylene ND 46 23 ug/kg 98-86-2 Acetophenone 39.1 230 9.8 ug/kg J 120-12-7 Anthracene 59.8 46 28 ug/kg 1912-24-9 Atrazine ND 91 20 ug/kg 56-55-3 Benzo(a)anthracene 204 46 13 ug/kg 50-32-8 Benzo(a)pyrene 188 46 21 ug/kg 205-99-2 Benzo(b)fluoranthene a 283 46 20 ug/kg 191-24-2 Benzo(g,h,i)perylene 154 46 23 ug/kg 207-08-9 Benzo(k)fluoranthene 89.7 46 21 ug/kg 101-55-3 4-Bromophenyl phenyl ether ND 91 18 ug/kg 85-68-7 Butyl benzyl phthalate b ND 91 11 ug/kg 92-52-4 1,1'-Biphenyl 9.6 91 6.3 ug/kg J 100-52-7 Benzaldehyde 102 230 11 ug/kg J 91-58-7 2-Chloronaphthalene ND 91 11 ug/kg 106-47-8 4-Chloroaniline ND 230 16 ug/kg 86-74-8 Carbazole 16.5 91 6.6 ug/kg J
Raw Data: 2P95147.D
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105-60-2 Caprolactam ND 91 18 ug/kg 218-01-9 Chrysene 253 46 14 ug/kg 111-91-1 bis(2-Chloroethoxy)methane ND 91 9.8 ug/kg 111-44-4 bis(2-Chloroethyl)ether ND 91 20 ug/kg 108-60-1 2,2'-Oxybis(1-chloropropane) ND 91 16 ug/kg 7005-72-3 4-Chlorophenyl phenyl ether ND 91 15 ug/kg 121-14-2 2,4-Dinitrotoluene ND 46 14 ug/kg 606-20-2 2,6-Dinitrotoluene ND 46 23 ug/kg 91-94-1 3,3'-Dichlorobenzidine ND 91 38 ug/kg 123-91-1 1,4-Dioxane ND 46 30 ug/kg 53-70-3 Dibenzo(a,h)anthracene 38.8 46 20 ug/kg J 132-64-9 Dibenzofuran 27.2 91 19 ug/kg J 84-74-2 Di-n-butyl phthalate ND 91 7.5 ug/kg 117-84-0 Di-n-octyl phthalate ND 91 11 ug/kg 84-66-2 Diethyl phthalate ND 91 9.7 ug/kg 131-11-3 Dimethyl phthalate ND 91 8.1 ug/kg 117-81-7 bis(2-Ethylhexyl)phthalate a 117 91 11 ug/kg 206-44-0 Fluoranthene 465 46 20 ug/kg 86-73-7 Fluorene 31.4 46 21 ug/kg J 118-74-1 Hexachlorobenzene ND 91 12 ug/kg 87-68-3 Hexachlorobutadiene ND 46 18 ug/kg 77-47-4 Hexachlorocyclopentadiene ND 460 18 ug/kg 67-72-1 Hexachloroethane ND 230 23 ug/kg 193-39-5 Indeno(1,2,3-cd)pyrene 163 46 21 ug/kg 78-59-1 Isophorone ND 91 9.8 ug/kg 91-57-6 2-Methylnaphthalene 18.4 46 10 ug/kg J 88-74-4 2-Nitroaniline ND 230 11 ug/kg 99-09-2 3-Nitroaniline ND 230 11 ug/kg 100-01-6 4-Nitroaniline ND 230 12 ug/kg 91-20-3 Naphthalene 24.3 46 13 ug/kg J 98-95-3 Nitrobenzene ND 91 18 ug/kg 621-64-7 N-Nitroso-di-n-propylamine ND 91 13 ug/kg 86-30-6 N-Nitrosodiphenylamine ND 230 17 ug/kg 85-01-8 Phenanthrene 267 46 15 ug/kg 129-00-0 Pyrene 452 46 15 ug/kg 95-94-3 1,2,4,5-Tetrachlorobenzene ND 230 12 ug/kg
367-12-4 2-Fluorophenol 45% 7-101%
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System artifact/aldol-condensation 3.27 3600 ug/kg J Unknown 9.13 790 ug/kg J Unknown 9.76 1800 ug/kg J Unknown 10.04 710 ug/kg J Hexadecanoic acid 10.62 2700 ug/kg J Unknown 10.81 740 ug/kg J
150-86-7 Phytol 11.52 910 ug/kg JN Unknown 12.77 660 ug/kg J Docosene 14.71 640 ug/kg J Tocopherol 16.36 560 ug/kg J Unknown 16.49 580 ug/kg J Alkane 16.52 880 ug/kg J
59-02-9 Vitamin E 16.69 790 ug/kg JN Unknown 17.24 730 ug/kg J Unknown 17.38 1900 ug/kg J -Sitosterol 17.75 10000 ug/kg J -Amyrin 18.02 6400 ug/kg J Unknown 18.10 5300 ug/kg J Unknown 18.32 9900 ug/kg J Unknown 18.39 970 ug/kg J Unknown 18.50 980 ug/kg J Unknown 18.57 740 ug/kg J Unknown 18.73 1300 ug/kg J Unknown 18.82 640 ug/kg J Unknown 19.10 1600 ug/kg J Friedelanone 19.23 3000 ug/kg J Total TIC, Semi-Volatile 55220 ug/kg J
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Pesticide TCL List
309-00-2 Aldrin ND 0.91 0.75 ug/kg 319-84-6 alpha-BHC a ND 0.91 0.74 ug/kg 319-85-7 beta-BHC ND 0.91 0.82 ug/kg 319-86-8 delta-BHC ND 0.91 0.87 ug/kg 58-89-9 gamma-BHC (Lindane) ND 0.91 0.67 ug/kg 5103-71-9 alpha-Chlordane ND 0.91 0.74 ug/kg 5103-74-2 gamma-Chlordane ND 0.91 0.41 ug/kg 57-74-9 Chlordane (alpha and gamma) ND 0.91 0.41 ug/kg 60-57-1 Dieldrin ND 0.91 0.63 ug/kg 72-54-8 4,4'-DDD ND 0.91 0.84 ug/kg 72-55-9 4,4'-DDE 6.0 0.91 0.80 ug/kg 50-29-3 4,4'-DDT ND 0.91 0.81 ug/kg 72-20-8 Endrin ND 0.91 0.71 ug/kg 1031-07-8 Endosulfan sulfate ND 0.91 0.71 ug/kg 7421-93-4 Endrin aldehyde ND 0.91 0.52 ug/kg 959-98-8 Endosulfan-I ND 0.91 0.52 ug/kg 33213-65-9 Endosulfan-II ND 0.91 0.57 ug/kg 76-44-8 Heptachlor ND 0.91 0.79 ug/kg 1024-57-3 Heptachlor epoxide ND 0.91 0.64 ug/kg 72-43-5 Methoxychlor ND 1.8 0.72 ug/kg 53494-70-5 Endrin ketone ND 0.91 0.66 ug/kg 8001-35-2 Toxaphene ND 23 21 ug/kg
(a) Associated CCV outside of control limits high, sample was ND.
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PCB List
Raw Data: 5G98193.D
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File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 5Z59419.D 1 07/22/20 16:11 TL 07/21/20 09:15 OP28559 G5Z1933 Run #2
NJDEP EPH List
Raw Data: 5Z59419.D
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Metals Analysis
(1) Instrument QC Batch: MA49003 (2) Instrument QC Batch: MA49020 (3) Prep QC Batch: MP21941 (4) Prep QC Batch: MP22018
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General Chemistry
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VOA TCL List
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VOA TCL List
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3&4-Methylphenol 67.4 87 36 ug/kg J 88-75-5 2-Nitrophenol ND 220 29 ug/kg 100-02-7 4-Nitrophenol ND 430 120 ug/kg 87-86-5 Pentachlorophenol ND 170 41 ug/kg 108-95-2 Phenol 41.7 87 23 ug/kg J 58-90-2 2,3,4,6-Tetrachlorophenol ND 220 29 ug/kg 95-95-4 2,4,5-Trichlorophenol ND 220 32 ug/kg 88-06-2 2,4,6-Trichlorophenol ND 220 26 ug/kg 83-32-9 Acenaphthene 21.0 43 15 ug/kg J 208-96-8 Acenaphthylene ND 43 22 ug/kg 98-86-2 Acetophenone 12.7 220 9.3 ug/kg J 120-12-7 Anthracene 46.0 43 27 ug/kg 1912-24-9 Atrazine ND 87 19 ug/kg 56-55-3 Benzo(a)anthracene 176 43 12 ug/kg 50-32-8 Benzo(a)pyrene 157 43 20 ug/kg 205-99-2 Benzo(b)fluoranthene a 222 43 19 ug/kg 191-24-2 Benzo(g,h,i)perylene 109 43 22 ug/kg 207-08-9 Benzo(k)fluoranthene 68.3 43 20 ug/kg 101-55-3 4-Bromophenyl phenyl ether ND 87 17 ug/kg 85-68-7 Butyl benzyl phthalate b ND 87 11 ug/kg 92-52-4 1,1'-Biphenyl ND 87 5.9 ug/kg 100-52-7 Benzaldehyde 39.2 220 11 ug/kg J 91-58-7 2-Chloronaphthalene ND 87 10 ug/kg 106-47-8 4-Chloroaniline ND 220 16 ug/kg 86-74-8 Carbazole 20.2 87 6.3 ug/kg J
Raw Data: 2P95148.D
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105-60-2 Caprolactam ND 87 17 ug/kg 218-01-9 Chrysene 199 43 14 ug/kg 111-91-1 bis(2-Chloroethoxy)methane ND 87 9.3 ug/kg 111-44-4 bis(2-Chloroethyl)ether ND 87 19 ug/kg 108-60-1 2,2'-Oxybis(1-chloropropane) ND 87 16 ug/kg 7005-72-3 4-Chlorophenyl phenyl ether ND 87 14 ug/kg 121-14-2 2,4-Dinitrotoluene ND 43 13 ug/kg 606-20-2 2,6-Dinitrotoluene ND 43 22 ug/kg 91-94-1 3,3'-Dichlorobenzidine ND 87 36 ug/kg 123-91-1 1,4-Dioxane ND 43 29 ug/kg 53-70-3 Dibenzo(a,h)anthracene 26.7 43 19 ug/kg J 132-64-9 Dibenzofuran 19.4 87 18 ug/kg J 84-74-2 Di-n-butyl phthalate ND 87 7.1 ug/kg 117-84-0 Di-n-octyl phthalate ND 87 11 ug/kg 84-66-2 Diethyl phthalate ND 87 9.2 ug/kg 131-11-3 Dimethyl phthalate ND 87 7.7 ug/kg 117-81-7 bis(2-Ethylhexyl)phthalate a 120 87 10 ug/kg 206-44-0 Fluoranthene 342 43 19 ug/kg 86-73-7 Fluorene 26.3 43 20 ug/kg J 118-74-1 Hexachlorobenzene ND 87 11 ug/kg 87-68-3 Hexachlorobutadiene ND 43 17 ug/kg 77-47-4 Hexachlorocyclopentadiene ND 430 17 ug/kg 67-72-1 Hexachloroethane ND 220 21 ug/kg 193-39-5 Indeno(1,2,3-cd)pyrene 126 43 20 ug/kg 78-59-1 Isophorone ND 87 9.3 ug/kg 91-57-6 2-Methylnaphthalene ND 43 9.8 ug/kg 88-74-4 2-Nitroaniline ND 220 10 ug/kg 99-09-2 3-Nitroaniline ND 220 11 ug/kg 100-01-6 4-Nitroaniline ND 220 11 ug/kg 91-20-3 Naphthalene ND 43 12 ug/kg 98-95-3 Nitrobenzene ND 87 17 ug/kg 621-64-7 N-Nitroso-di-n-propylamine ND 87 13 ug/kg 86-30-6 N-Nitrosodiphenylamine ND 220 16 ug/kg 85-01-8 Phenanthrene 235 43 15 ug/kg 129-00-0 Pyrene 316 43 14 ug/kg 95-94-3 1,2,4,5-Tetrachlorobenzene ND 220 11 ug/kg
367-12-4 2-Fluorophenol 39% 7-101%
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System artifact/aldol-condensation 3.26 1100 ug/kg J (Hydroxypropenyl)methoxyphenol 9.14 1200 ug/kg J Unknown 9.75 860 ug/kg J Hexadecanoic acid 10.65 3900 ug/kg J Unknown 10.81 850 ug/kg J
150-86-7 Phytol 11.52 1400 ug/kg JN 1000351-81-4Dotriacontyl pentafluoropropionate 14.71 570 ug/kg JN
Unknown 15.50 540 ug/kg J Tocopherol 16.36 990 ug/kg J Alkane 16.52 1500 ug/kg J
59-02-9 Vitamin E 16.69 1300 ug/kg JN 83-48-7 Stigmasterol 17.38 1200 ug/kg JN
Sitosterol 17.75 7700 ug/kg J Unknown 17.81 5300 ug/kg J -Amyrin 18.02 5400 ug/kg J Unknown 18.12 9000 ug/kg J Unknown 18.22 640 ug/kg J Unknown 18.32 7800 ug/kg J Unknown 18.39 1600 ug/kg J Stigmastenone 18.53 3300 ug/kg J Unknown 18.58 1200 ug/kg J Unknown 18.75 1600 ug/kg J Unknown 18.83 1100 ug/kg J Unknown 19.10 1200 ug/kg J Unknown 19.25 2400 ug/kg J Unknown 19.71 1500 ug/kg J Total TIC, Semi-Volatile 64050 ug/kg J
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Pesticide TCL List
309-00-2 Aldrin ND 0.81 0.66 ug/kg 319-84-6 alpha-BHC ND 0.81 0.66 ug/kg 319-85-7 beta-BHC ND 0.81 0.73 ug/kg 319-86-8 delta-BHC ND 0.81 0.77 ug/kg 58-89-9 gamma-BHC (Lindane) ND 0.81 0.59 ug/kg 5103-71-9 alpha-Chlordane ND 0.81 0.65 ug/kg 5103-74-2 gamma-Chlordane 6.5 0.81 0.37 ug/kg 57-74-9 Chlordane (alpha and gamma) 6.5 0.81 0.37 ug/kg 60-57-1 Dieldrin ND 0.81 0.55 ug/kg 72-54-8 4,4'-DDD ND 0.81 0.74 ug/kg 72-55-9 4,4'-DDE 3.3 0.81 0.71 ug/kg 50-29-3 4,4'-DDT ND 0.81 0.71 ug/kg 72-20-8 Endrin ND 0.81 0.63 ug/kg 1031-07-8 Endosulfan sulfate ND 0.81 0.63 ug/kg 7421-93-4 Endrin aldehyde ND 0.81 0.46 ug/kg 959-98-8 Endosulfan-I ND 0.81 0.46 ug/kg 33213-65-9 Endosulfan-II ND 0.81 0.50 ug/kg 76-44-8 Heptachlor ND 0.81 0.69 ug/kg 1024-57-3 Heptachlor epoxide ND 0.81 0.56 ug/kg 72-43-5 Methoxychlor ND 1.6 0.64 ug/kg 53494-70-5 Endrin ketone ND 0.81 0.58 ug/kg 8001-35-2 Toxaphene ND 20 19 ug/kg
877-09-8 Tetrachloro-m-xylene 73% 25-135% 877-09-8 Tetrachloro-m-xylene 75% 25-135% 2051-24-3 Decachlorobiphenyl 103% 10-156% 2051-24-3 Decachlorobiphenyl 520% a 10-156%
(a) Outside control limits due to matrix interference.
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PCB List
Raw Data: 5G98178.D
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File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 5Z59421.D 1 07/22/20 17:22 TL 07/21/20 09:15 OP28559 G5Z1933 Run #2
NJDEP EPH List
Raw Data: 5Z59421.D
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Metals Analysis
(1) Instrument QC Batch: MA49003 (2) Instrument QC Batch: MA49009 (3) Instrument QC Batch: MA49020 (4) Prep QC Batch: MP21941 (5) Prep QC Batch: MP22018
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General Chemistry
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VOA TCL List
67-64-1 Acetone ND 18 7.2 ug/kg 71-43-2 Benzene ND 0.90 0.82 ug/kg 74-97-5 Bromochloromethane ND 9.0 1.0 ug/kg 75-27-4 Bromodichloromethane ND 3.6 0.80 ug/kg 75-25-2 Bromoform ND 9.0 1.0 ug/kg 74-83-9 Bromomethane ND 9.0 1.8 ug/kg 78-93-3 2-Butanone (MEK) ND 18 6.8 ug/kg 75-15-0 Carbon disulfide ND 3.6 1.7 ug/kg 56-23-5 Carbon tetrachloride ND 3.6 1.1 ug/kg 108-90-7 Chlorobenzene ND 3.6 0.83 ug/kg 75-00-3 Chloroethane ND 9.0 1.1 ug/kg 67-66-3 Chloroform ND 3.6 0.88 ug/kg 74-87-3 Chloromethane ND 9.0 3.5 ug/kg 110-82-7 Cyclohexane ND 3.6 1.2 ug/kg 96-12-8 1,2-Dibromo-3-chloropropane ND 3.6 1.5 ug/kg 124-48-1 Dibromochloromethane ND 3.6 1.0 ug/kg 106-93-4 1,2-Dibromoethane ND 1.8 0.76 ug/kg 95-50-1 1,2-Dichlorobenzene ND 1.8 0.99 ug/kg 541-73-1 1,3-Dichlorobenzene ND 1.8 0.90 ug/kg 106-46-7 1,4-Dichlorobenzene ND 1.8 0.89 ug/kg 75-71-8 Dichlorodifluoromethane ND 9.0 1.3 ug/kg 75-34-3 1,1-Dichloroethane ND 1.8 0.89 ug/kg 107-06-2 1,2-Dichloroethane ND 1.8 0.85 ug/kg 75-35-4 1,1-Dichloroethene ND 1.8 1.2 ug/kg 156-59-2 cis-1,2-Dichloroethene ND 1.8 1.5 ug/kg 156-60-5 trans-1,2-Dichloroethene ND 1.8 1.1 ug/kg 78-87-5 1,2-Dichloropropane ND 3.6 0.85 ug/kg 10061-01-5 cis-1,3-Dichloropropene ND 3.6 0.86 ug/kg 10061-02-6 trans-1,3-Dichloropropene ND 3.6 0.83 ug/kg 100-41-4 Ethylbenzene ND 1.8 1.0 ug/kg 76-13-1 Freon 113 ND 9.0 1.8 ug/kg 591-78-6 2-Hexanone ND 9.0 3.8 ug/kg
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VOA TCL List
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3&4-Methylphenol ND 92 38 ug/kg 88-75-5 2-Nitrophenol ND 230 30 ug/kg 100-02-7 4-Nitrophenol ND 460 120 ug/kg 87-86-5 Pentachlorophenol ND 180 43 ug/kg 108-95-2 Phenol 25.3 92 24 ug/kg J 58-90-2 2,3,4,6-Tetrachlorophenol ND 230 30 ug/kg 95-95-4 2,4,5-Trichlorophenol ND 230 34 ug/kg 88-06-2 2,4,6-Trichlorophenol ND 230 27 ug/kg 83-32-9 Acenaphthene ND 46 16 ug/kg 208-96-8 Acenaphthylene ND 46 23 ug/kg 98-86-2 Acetophenone 24.4 230 9.9 ug/kg J 120-12-7 Anthracene ND 46 28 ug/kg 1912-24-9 Atrazine ND 92 20 ug/kg 56-55-3 Benzo(a)anthracene 112 46 13 ug/kg 50-32-8 Benzo(a)pyrene 106 46 21 ug/kg 205-99-2 Benzo(b)fluoranthene a 192 46 20 ug/kg 191-24-2 Benzo(g,h,i)perylene 98.4 46 23 ug/kg 207-08-9 Benzo(k)fluoranthene 52.5 46 21 ug/kg 101-55-3 4-Bromophenyl phenyl ether ND 92 18 ug/kg 85-68-7 Butyl benzyl phthalate b ND 92 11 ug/kg 92-52-4 1,1'-Biphenyl ND 92 6.3 ug/kg 100-52-7 Benzaldehyde 126 230 11 ug/kg J 91-58-7 2-Chloronaphthalene ND 92 11 ug/kg 106-47-8 4-Chloroaniline ND 230 17 ug/kg 86-74-8 Carbazole ND 92 6.

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