technologies for volatile organic compounds (voc) recovery in … · 2014-02-17 · 4 introduction...
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Technologies forVolatile Organic Compounds (VOC)
Recovery in Petroleum Industryand JX’s Activities
in the Middle East Area
Hidemitsu SAITO
Overseas Business Department
February 5th, 2013
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Copyright 2010 JX Nippon Oil & Energy Corporation All Rights Reserved. 2
Contents1. JX-Group
and JX Nippon Oil & Energy Corporation
2. VOC Emission from Petroleum Industryand Air Pollution
3. JX’s Activities on VOC Recovery
3.1. Associated Gas Recovery at the Oil Field
3.2. VOC Recovery at the Crude Oil ShippingTerminal in Japan
3.3. VOC Recovery at the Gas Station by VRU inthe Middle East
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1. JX-Groupand
JX Nippon Oil &Energy Corporation
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Introduction of JX-Group
Listedsubsidiaries
JX NipponResearch Institute
・
・
・
Common groupfunction
companies
Independentcompanies
Share in the domestic fuelmarket
36 %
(No.1 in Japan)Paraxylene production
capacity2,620 thousand ton/ year
(No.1 supplier in Asia)
JX Nippon Oil & Energy
Copper Smelting & refining capacity
1,170 Thousand tons/year
Electronic Materials;Product Lines with World
No.1 Market Shares
Equity entitled copper mine production
Approx. 100 Thousand tons/year
JX Nippon Mining &Metals
JX Nippon Oil & GasExploration
Crude oil and natural gasproduction (a project company basis)
Worldwide businessactivities ranging from
crude oil to LNG and oilsand
Approx.130 thousand BD
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MarketingExplorating Importing Refining Distributing
Upstream -> Downstream
Business Strategy
Chita (Chemicals)
Osaka (115)
Mizushima (345)
Marifu (127)
Oita (136)
8 Refineries & 3 Plants
Wakayama Petroleum Refining(Lubricants)
Sendai (145)
Kashima (189)
Negishi (270)Kawasaki (Chemicals)Yokohama (Lubricants)
Taniguchi Petroleum Refining (Lubricants)
2 Affiliate Companies
Muroran (180)
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2. VOC Emissionfrom Petroleum Industry
andAir Pollution
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VOC Emission from Petroleum Industry
(1) Exploration and Transportation
Associatedgas flaring
Tanker gasemissionwith VOC
Hydrocarbon loss
CO2 Emission
ToConsumer
Hydrocarbon loss
Odor material dispersion
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(2) Oil Processing & Consuming
Vent andtank breathergas emission
Gasemissionwith VOC
Valuable products (gasoline and chemicals) loss
Air pollution and firing risk
VOC Emission from Petroleum Industry
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Photo-chemicalSmog
ThroatDisease
SOx
VOC
NOx
VOC
SPM (Suspended Particle Matter)
Secondary Particle
OH
O3(Ozone)
OH
Ultra-violetRays
Photo-chemical Oxidant
VOC and Air Pollution
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3. JX’s Activities on VOC Recovery
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VOC Emission from Petroleum Industry
(1) Exploration and Transportation
Associatedgas flaring
Tanker gasemissionwith VOC
Hydrocarbon loss
CO2 Emission
To Consumer
Hydrocarbon loss
Odor material dispersion
1. Associated Gas Recoveryat the Oil Field
2. Tanker Vapor Recoveryat KIIRE Staging Terminal
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(2) Oil Processing & Consuming
Vent andtank breathergas emission
Gasemissionwith VOC
Valuable products (gasoline and chemicals) loss
Air pollution and firing risk
VOC Emission from Petroleum Industry
3. VOC Recoveryat the Gas Station
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1. Associated Gas Recoveryat the Oil Field
- Rang Dong Project- Yety Project
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• Japan Vietnam Petroleum Corporation (JVPC)(Operator)
• ConocoPhillips• Petrovietnam• Petrovietnam Exploration & Production Company
Rang Dong Project
Location and project scheme
Project participants of CDM
Subsidiary of JXNippon OilExploration
Rang Dong oil field
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Rang Dong Project
Gasprocessing
plant
Back HoOil field
Rang Dong oil field
Oilwell
On-site consumption,Flaring
Recovered gas
Transportation
X
B
Condensate LPG Dry gas
X’C
Ca Ngu VangOil field
Su Tu VangOil field
X2
End of 2011 ~July 2008 ~
Aug 2008 ~
April 2009 ~
Production
2001 ~
Phuong Dongoil field
A1
Existing infrastructure in 2001
Supplying the associated gas from 2001 (= Rang Dong CDM)
New infrastructure (In process of revision of PDD)
A
Ca Ngu VangOil field
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16
•Joint Stock Company Gazprom Neft•JX Nippon Oil & Energy•Mitsubishi Corporation
Yety Project
Location
Project participants Project site
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Yety Project
Project scheme
VingapurovskayaGas processing plant
VingayahinskayaCompressor
station
Dry gas Stablenatural gasliquid
VGPPOther oil fields
Novogodnee oil field
Vingayahinskoe oil field
Yety-purovskoeoil field
Before the project
After the project
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2. VOC Recoveryat the Crude Oil Shipping
Terminal in Japan
KIIRE TerminalTanker Vapor Recovery Project
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Kiire Crude Oil Terminal( JX Nippon Oil & Energy Group )
Jetties ; 5Tanks ; 57Capacity ; 7 Million KL
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Domestic Tanker (100,000DWT Class)Now on loading crude oil
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Actual Vapor Emission from Tanker
Ocean Tanker
Crude Oil Tanks
Domestic Tanker
VaporEmission
Crude Loading31milion KL/year31milion m3
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Vapor[Bad Smell]
Residential zone
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Main Technology of VOC Treatment
System Burning Recovery Recovery Recovery
Method Direct Burning Absorption Adsorption Separation
Equipment Flare
Incinerator
Kerosene
etc.
Activated Carbon
or Silica Gel
Membrane
Large amount ofVOC
O O X X
VOC Recovery X O O O
VOC >= 5 % O O O O
VOC < 5 % O X O X
Removal of VOC O 50 ~ 95 % 90 ~ 99 % 70 ~ 90 %
Investment Cost Relatively cheap Medium Medium Relativelyexpensive
Others Auxiliary fuelneeded
Depend onabsorbent
Regeneration needed
( O ; Practicable )
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Basic design concept
Absorb with CrudeKiire terminal storage large amount of crudeand wide variety
(Instead of kerosene or other solvent)
Some crude have good absorbability
Flare CombustionCombustion unabsorbed Vapor
Complete decomposition odor and VOC
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800 OC
Absorber ConditionPress. ; 0.3 ~ 0.5 MpaTemp. ; 3 ~ 7 OC
70% RecoveryGround Flare
Off Gas
NH3
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TVR (Tanker Vapor Recovery) Plant
Ground Flare
Absorber
Tanker
May 2007 Operation Start
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Performance of TVR (2007 FY)
Items Amount Unit Utilization Rate
(A) Total Crude Oil of Shipment 32,080,000 KL
(B) Crude Oil Connected with TVR 28,594,000 KL (B) / (A) = 89.1 %
(C) Nos. of Ship Total 293
(D) Nos. of Ship connected with TVR 264 (D) / (C) = 90.1 %
(E) VOC Recovery Volume as Crude Oil 11,093 KL
(F) VOC Recovery Rate 70.8 % (E) / Feed Total-
Hydrocarbon
(G) Average VOC Concentration of TankerVapor
13.1 %
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3. VOC Recovery Demonstrationat a Gas Station
by Vapor Recovery Unitin the Middle East
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VOC Recovery at a Gas Station
Unloading at Gas Station
TankTruck
UndergroundGasoline Tank
Vapor return
TankTruck
Loading atTerminal
Shipping Point
TankTruck
TankTruck
Each Station
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Comparison of VOC Recovery Technologies
Type AdsorptionMembrane Condensation
Silicagel Activatedcarbon
Operation ◎ ◎ ◎ ○
Recovery rate ◎ ◎ ○ ▲
Initial Cost ○ ○ ▲ ○
Running Cost ◎ ◎ ◎ ▲
Area ◎ ◎ ○ ▲
Safety ◎ ▲ ◎ ◎
Disadvantage Flammableadsorbent
High InitialCost
IceFormation
◎:Best ○:Better ▲:Poor
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VRU Process Flow of Adsorption Process
Underground
Tanker
Heat exchanger
Measurement
tank
Adsorbent
(Silica gel)
Clean gas
to Atomosphere
Vapor
Liquid
Chiller
Gasoline
Chiller unit is not necesally required.
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VRU Process Flow of Desorption Process
Underground
Gasoline Tank
Tanker
Vacuumpump
Heat exchanger
Measurement
tank
Gasoline Vapor
Liquid
Chiller
Adsorbent
(Silica gel)
Chiller unit is not necesally required.
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Unloading Conditions, Adsorption /DesorptionConditions and Expected Performance of VRU
Descriptions Specifications
1. Unloading Conditions1.1. Unloading Volume from 1 Tanker 36KL1.2. Concentration of Hydrocarbon 45%1.3. Unloading Velocity 80m3/hour1.4. Unloading Period per 1 Tanker 60min1.5. Interval of Unloading 5 – 6hours
2. Adsorption Conditions2.1. Adsorption Temperature Ambient
2.2. Adsorption PressureSlightly Positive
(Almost less than 2KPa)
3. Desorption Conditions
3.1. Desorption PressureSlightly Positive
(Almost less than 2KPa)
3.2. Approximate Desorption Period 4-5 hours
4. Expected Performance4.1. Recovery Rate of Hydrocarbon More than 98%4.2. Recovery Amount More than 0.2%
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Summary of Trial Results
Descriptions Trial run results
1. Trial Run Period September - October, 2012
2. Total unloaded Volume 1,692KL (1,184Ton)
3. Recovery Amount of Hydrocarbon 2,122KG
4. Recovery Rate of Hydrocarbon 99.5% of Hydrocarbon Content (HC)
(Calculated by measured result of HCconcentration at VRU inlet and outlet)
5. Recovery Amount of Gasoline 0.2% of the unloaded volume
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Future Activities on VOC Recovery
JX-Group tries to continue activitieson VOC Recovery in the Middle East.
Acknowledgements
The demonstration of VOC recovery at a gas station wasconducted, based on the Joint Technical CooperationProgram with JCCP.JX appreciates the cooperation of JCCP
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Thank you for your attention.