the application of xrf to gold refining and coin ... anniversary... · internet sub title will go...
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The Application of XRF to The Application of XRF to Gold Refining and Coin
Manufacturing at the Royal Canadian Mint
Michael W. Hinds, Ph.D.
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The Business of the Mint
● Circulation Coins (Canada & Other Countries)Countries)
● Numismatic Coins (Sterling Silver & 22 ● Numismatic Coins (Sterling Silver & 22 Karat Gold )
● Investor Coins (99.99% Gold and Silver)
G ld R fi i S i● Gold Refining Services
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Ottawa
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Winnipeg
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Why XRF?
F t t d• Fast turnaround• Minimal sample preparation• Minimal labour• Minimal labour• Simple to use (for operators)• Some models have an auto-samplerSo e ode s a e a auto sa p e• Determination of major, minor, and trace
elements in one analysis• Can be used for unknown materials
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Overview of Applications
• Ag and P in Sterling Silver
• Au, Ag, Cu & Other Elements in Impure Gold and Silver to assist Fire Assay
• Ag and Cu in Chlorinated Gold as an Endpoint Indicator
• As, Cd, Hg, Se, & Te in Impure Gold and Silver coming into the Refinery
• Plated Layer Thickness in Circulation Coin Blanks
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XRF Spectrometers
Wavelength Dispersive XRFP l ti l PW2404 (1999 2010)● Panalytical PW2404 (1999 – 2010)
● Panalytical Axios (2010)
● Energy Dispersive● Spectro 200 Spect o 00● InnvoX Omega Xpress (portable)
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Sterling Silver Alloy
● Alloy: Ag 92.5%, P 700 ppm (max), Cu balance● Alloy: Ag 92.5%, P 700 ppm (max), Cu balance
● Used for Numismatic Coins
●Charges made from Ag Cu and P ●Charges made from Ag, Cu, and P
●Alloy is continuously cast (point of sampling)
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●Rolled, blanked, and stamped
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Analysis Criteria
● Silverprecision ± 0 03 % RSD (n 3)• precision ± 0.03 % RSD (n = 3)
• lower alloy limit 92.30%
● Phosphorous ● Phosphorous • precision ± 5% RSD (n = 3)• 700 ppm max.
● Copper • Balance• Balance
• Analysis time < 5 minutes
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Sample Handling Criteria
Sample Handling
Total sample analysis time < 5 minuteso 2 replicates & sample loading
Minimal change to sample cutting (Concast)
Minimal sample preparation (Assay)
Autosampler to handle sample block (30mm)3Autosampler to handle sample block (30mm)3
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Continuous Casting Furnace
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Continuous Casting Furnace
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Cutting a Sample
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Sample Loading into XRF
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XRF Parameters – Sterling Ag
Element Line X‐tal Detector TimeElement Line X tal Detector Time
(s) Ag Kα LiF 200 Duplex 80
Cu Kα LiF 200 Duplex 10
P Kα Ge111‐C Flow 20
Total Time 110 s Total Time 110 s
X‐ray tube settings PW2404 60 kV 66 A
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PW2404: 60 kV, 66 mAAxios 60 kV, 50 mA
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Achieving Exceptional Precision
● Measure using the same cup
• Long Counting Time
• Keep X-ray tube at set power for 2 – 4 hr
• Sample Surface Preparation
• Control Environment• Inside wall• Air conditioning
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Air conditioning
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Challenges for Ag 925 Samples
● Sample size to fill the aperture & fit the cupcup
● Constant sample size
● Sample labeling
● Smooth top - vacuum seal auto-sampler● Smooth top vacuum seal auto sampler
● Sample flatness on analysed side
● Timely delivery of the samples
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Sample Preparation
Polishing (old):● Analysed Side
● Lathe the face (flatness) or press flat● 1st wet polish 400 mesh SiC paper (20 s)● 1st wet polish 400 mesh SiC paper (20 s)● 2nd wet polish 125 mesh SiC paper (20 s)
● Opposite Side● Wet polish 400 mesh SiC paper (20 s)● Auto-sampler pick-up
Milling Machine (new):● Mill both surfaces● Analysed side more carefully done
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● Analysed side more carefully done
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Ag 925 Standards
● Collected accepted and rejected samples
● Ag determined by Gay Lusac Method● back titration (AgCl formation from excess Cl)● back titration (AgCl formation from excess Cl)
● P determined by solution ICP-AES ● 190.3 nm● matrix matched standards
● Cu by difference
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Ag Calibration: 85 – 94%Algorithm: De Jong (similar L-T)
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P Calibration: 0 – 700 ppmAlgorithm: De Jong (similar L-T)
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Ag Precision: QC 32-96 (4000W)
Time Period Precision Number ofTime Period PrecisionRSD
Number of Replicates
1 hour 0.02 % 10
8 h 0 02 % 208 hour 0.02 % 20
7 days 0.03 % 98y
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Cu Precision: QC 32-96 (4000W)
Time Period PrecisionRSD
Number of Replicates
1 hour 0.06% 10
8 hour 0.06% 20
d 0 06% 985 days 0.06% 98
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P Precision: QC 32-96 (330 ppm)
Time Period PrecisionRSD
Number of Replicates
1 hour 1.4% 10
8 hour 1.2% 20
d5 days 2.6% 98
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Accuracy: Ag (n=5 replicates)
Sample XRF Gay Lusac Sig DiffSample XRF Gay Lusac Sig. Diff.
277 925.6 ± 0.21 925.5 ± 0.4 No
282 923.4 ± 0.15 924.2 ± 0.5 No
287 925 7 ± 0 14 926 2 ± 0 34 No287 925.7 ± 0.14 926.2 ± 0.34 No
2A 921.3 ± 0.23 920.8 ± 0.35 No
4B 938.7 ± 0.15 939.2 ± 0.25 No
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P contamination – vacuum oil
QC Chart of Pin QCAg32-96 for 2002in QCAg32 96 for 2002
390410430
ess)
Re-polish
310330350370390
ntra
tion
(fine
ne
250270290310
ug ug ug ug ep ep ep ep
Con
cen
12-A
u
17-A
u
22-A
u
27-A
u
1-S
e
6-S
e
11-S
e
16-S
e
Date (dd-mm)
P UL Target LL
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Measuring Ag Alloy Coin Blanks
• One contract had blanks with diameter less than 27 mmless than 27 mm
• Must use 12 mm sample apertureMust use 12 mm sample aperture
• Lower counts from lower surface area
• Must increase counting time
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Blank compared to sample cups
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27 vs 12 mm Comparison
Parameter 27 mm 12 mm
Ag counts, kcps 800 120
Effective Diameter, 25 10,mm
25 10
Effective Area, mm2 491 78.5
Ratios 27 vs 12 mm Area 6.25 Count 6.67
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Precision: 12 vs 27 mm cupsAg 90% alloy; n =10
Parameter 12 mm 27 mm
Ag Counting Time, s 120(20 bkgd)
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Precision, %RSD 0 03 ‐ 0 04 0 02 ‐ 0 03Precision, %RSD 0.03 ‐ 0.04 0.02 ‐ 0.03
P Counting Time, s 30 (10 bk d)
20 (10 bk d)(10 bkgd) (10 bkgd)
Precision, % RSD 2 2
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Analysis of Impure Gold
• Settlement of Gold DepositAft lt • After melt mass
• Determine Au and Ag by Fire Assay
• Fire Assay:• Gravimetric• High precision and accuracy• Industry standard
• XRF used to streamline Fire Assay
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Overview of Fire Assay
Gold Sample
Button Fire Assay Firecupelled in Pb
Au and Ag
cupelled with Inquarted AgAg dissolved
Aug
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Traditional Fire Assay
Gold Sample
Button FireAu & Ag
InquartationVisual
Assay FireAu
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Fire Assay with XRF
Fire Assay
Button FireAu & Ag
EstimateAu & Ag
other elementsgXRF
Assay FireAu
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XRF for Ag Inquartation (FA)
• Measurement of Au and Ag used to add Inquartation Ag for the Assay Fireq g y• Ag Inq = ((2.5*Au)-Ag)/2
• Ag Inq must be within ± 50 mg AgAg Inq must be within ± 50 mg Ag
• Minimal sample and sample prep• Press small dip sample • Press small dip sample • Polish
• 3 minute analysis time• 3 minute analysis time
• Elements: Au, Ag, Cd, Cu, Fe, Ni, Pb, Pt, Pd, Te, Zn
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XRF for FA: Limitations
• Small sample size 12 mm aperture
• Automation required: large number cups
F t e o e• Fast response
• Personnel with minimal training
• 4000 W power (60 kV and 66mA)
• Must also have a 6 mm aperture program• Some samples break apart
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INQ12 Au Calibration (40–100%)
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INQ12 Ag Calibration (0-100%)
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Au & Ag Analytical Results
Standard: INQ12QC2, n= 38 determinations over 3 weeks
Au Ag
,Units: parts per thousand or fineness
Average 624.3 85.6Std Dev 0.7 1.7
RSD 0.1% 2%Certified Values 623.8 84.7
Difference 0.5 0.9% Error 0.1% 1%
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Au & Ag Analytical Results
Standard: QC60847, n= 5 determinations
Au Ag
,Units: parts per thousand or fineness
Average 644.5 73.5Std Dev 0.8 0.1
RSD 0.1% 0.1%Certified Values 646.0 75.5
Difference -1.5 -2.0% Error -0.2% -3%
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Observations
Good analytical results from XRF due to:S li lt t l • Sampling molten metal (induction melt)
• XRF application• Background, overlap corrections• Background, overlap corrections
• Calibration Standards• Produced in-house• Specially cast or use normal samples• Rigorously analysed
• Fire Assay• Fire Assay ICP-AES – Ag, Pd, & Pt (Cu & Pb)• ICP-AES• FAAS
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Overview
XRF very useful to refining and coin operations:operations:• Timely results• Analytical performance
• Accuracy (standards)• Precision
• Ease of use• Minimal sample preparation
XRF requires investment in:XRF requires investment in:• Standard manufacturing & analysis• Method development
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Acknowledgements
• Charlie WuAl d S f th• Alexander Seyfarth
• Maggi Loubser• Bruno Vrebos• Bruno Vrebos
• Royal Canadian Mint• Jon Forrest• Paul Laframboise• Robin Entwistle• Robin Entwistle
• James Willis and Andy Duncan
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