the following list contains the material safety data ...dlong/envengrinfo/total-ortho reactive...

The following list contains the Material Safety Data Sheets you requested. Please scoll down to view the requested MSDS(s).

Product MSDS Distributor Format Language Quantity

TNT844 TNT844A Hach Company OSHA English 1TNT844 TNT844B Hach Company OSHA English 1TNT844 TNT844C Hach Company OSHA English 1TNT844 TNT844R Hach Company OSHA English 1__________________________________________________________________________________________________________Total Enclosures: 4

World HeadquartersHach CompanyP.O.Box 389 MSDS No: M02444Loveland, CO USA 80539(970) 669-3050

MATERIAL SAFETY DATA SHEET_____________________________________________________________________________1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: TNT 844 ACatalog Number: TNT844A

Hach Company Emergency Telephone Numbers:P.O.Box 389 (Medical and Transportation)Loveland, CO USA 80539 (303) 623-5716 24 Hour Service(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M02444Chemical Name: Not applicableCAS No.: Not applicableChemical Formula: Not applicableChemical Family: Not applicableHazard: Allergen Causes irritation.Date of MSDS Preparation:

Day: 25Month: MayYear: 2007

_____________________________________________________________________________2. COMPOSITION / INFORMATION ON INGREDIENTS

Lithium SulfateCAS No.: 10102-25-7TSCA CAS Number: 103-48-7Percent Range: 1.0 - 10.0Percent Range Units: weight / weightLD50: Oral mouse LD50 = 1190 mg/kgLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: May cause irritation.

Sodium PersulfateCAS No.: 7775-27-1TSCA CAS Number: 7775-27-1Percent Range: 65.0 - 75.0Percent Range Units: weight / weightLD50: None reportedLC50: None reportedTLV: 0.1 mg/m3

PEL: Not establishedHazard: Causes severe eye irritation. Oxidizer. Allergen

Sodium MetaborateCAS No.: 7775-19-1TSCA CAS Number: 7775-19-1

Percent Range: 15.0 - 25.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 2330 mg/kgLC50: None reportedTLV: 10 mg/M3 Inhalable Particles; 3 mg/M3 Respirable ParticlesPEL: 15 mg/M3 Total Dust; 5 mg/M3 Respirable DustHazard: May cause irritation.

_____________________________________________________________________________3. HAZARDS IDENTIFICATION

Emergency Overview:Appearance: White powderOdor: None

CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATIONMAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTIONS

HMIS:Health: 2Flammability: 0Reactivity: 2Protective Equipment: X - See protective equipment, Section 8.

NFPA:Health: 1Flammability: 0Reactivity: 2Symbol: Not applicable

Potential Health Effects:Eye Contact: Causes severe irritationSkin Contact: Causes irritation May cause allergic reactionSkin Absorption: None reported Will be absorbed through abraded or broken skin. Effects similar to thoseof ingestion

Target Organs: None reported Kidneys Central nervous systemIngestion: May cause: gastrointestinal irritation nausea vomiting diarrhea muscular twitching lethargycirculatory disturbances central nervous system effects shock kidney damage

Target Organs: Kidneys Central nervous systemInhalation: May cause: allergic respiratory reaction Causes: respiratory tract irritation

Target Organs: None reportedMedical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditionsAllergies or sensitivity to potassium persulfate.Chronic Effects: Chronic overexposure may cause allergic skin reactions allergic respiratory reactionsweight loss anemiaCancer / Reproductive Toxicity Information:

This product does NOT contain any OSHA listed carcinogens.

This product does NOT contain any IARC listed chemicals.

This product does NOT contain any NTP listed chemicals.

Additional Cancer / Reproductive Toxicity Information: None reportedToxicologically Synergistic Products: None reported

_____________________________________________________________________________4. FIRST AID

Eye Contact: Immediately flush eyes with water for 15 minutes. Immediately flush eyes with water for 15minutes. Call physician. Call physician.Skin Contact (First Aid): Wash skin with soap and plenty of water. Remove contaminated clothing. Callphysician immediately. Wash skin with soap and plenty of water. Call physician if irritation develops.Ingestion (First Aid): Do not induce vomiting. Do not induce vomiting. Give 1-2 glasses of water. Callphysician immediately. Never give anything by mouth to an unconscious person.Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.

_____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: Contains oxidizer. Contact with combustible materials may cause a fire. During afire, corrosive and toxic gases may be generated by thermal decomposition. During a fire, corrosive and toxicgases may be generated by thermal decomposition.Flash Point: Not applicableMethod: Not applicableFlammability Limits:

Lower Explosion Limits: Not determinedUpper Explosion Limits: Not determined

Autoignition Temperature: Not determinedHazardous Combustion Products: Toxic fumes of: sulfur oxides. boron compoundsFire / Explosion Hazards: None reported May react violently with: strong reducers combustible materials

Static Discharge: None reported.Mechanical Impact: None reported

Extinguishing Media: Use media appropriate to surrounding fire conditions Water.Fire Fighting Instruction: Evacuate area and fight fire from a safe distance. As in any fire, wear self-contained breathing apparatus pressure-demand and full protective gear.

_____________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:Only persons properly qualified to respond to an emergency involving hazardous substances may respond to

a spill according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergencyresponse plan and guidelines/procedures. See Section 13, Special Instructions for disposal assistance.Containment Technique: Stop spilled material from being released to the environment. Cover spilled solidmaterial with sand or other inert material.Clean-up Technique: Remove all combustible materials from the spill area. Sweep up material. Work in anapproved fume hood. Working in small batches, dilute with excess water. Adjust to a pH between 6 and 9with an acid, such as sulfuric or citric. Filter to remove solids. Flush the spilled material to the drain with alarge excess of water. Decontaminate the area of the spill with a soap solution.Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergencyresponse plan) when: a pound or more of loose powder is spilled. If conditions warrant, increase the size ofthe evacuation.Special Instructions (for accidental release): Mixture contains a component which is regulated as hazardouswaste.304 EHS RQ (40 CFR 355): Not applicableD.O.T. Emergency Response Guide Number: --

_____________________________________________________________________________7. HANDLING / STORAGE

Handling:Storage: Store away from: Keep away from: combustible materials reducers oxidizable materials

Flammability Class: Not applicable_____________________________________________________________________________8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT

Engineering Controls: Use a fume hood to avoid exposure to dust, mist or vapor. Use general ventilation tominimize exposure to mist, vapor or dust. Maintain general industrial hygiene practices when using thisproduct.Personal Protective Equipment:

Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex glovesInhalation Protection: laboratory fume hood adequate ventilation

Precautionary Measures: Keep away from: oxidizable materials reducers Protect from: heat moistureTLV: Not established. 10 mg/M3 Inhalable particles; 3 mg/M3 Respirable Particles.PEL: Not established. 10 mg/M3 Total Dust; 3 mg/M3 Respirable Fraction.

_____________________________________________________________________________9. PHYSICAL / CHEMICAL PROPERTIES

Appearance: White powderPhysical State: PowderMolecular Weight: Not applicableOdor: NonepH: Solution pH: 1.5Vapor Pressure: Not applicableVapor Density (air = 1): Not applicableBoiling Point: Not applicableMelting Point: Not determinedSpecific Gravity (water = 1): >2.0 calculatedEvaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: None intentionally added.Partition Coefficient (n-octanol / water): Not applicableSolubility:

Water: SolubleAcid: Not determinedOther: Not determined

Metal Corrosivity:Steel: Not determinedAluminum: Not determined

_____________________________________________________________________________10. STABILITY / REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Conditions to Avoid: Exposure to air. Heating to decomposition. Excess moistureReactivity / Incompatibility: May react violently in contact with: oxidizable material reducers Incompatiblewith: aluminum reducersHazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: sodiumoxides sulfur oxidesHazardous Polymerization: Will not occur.

_____________________________________________________________________________11. TOXICOLOGICAL INFORMATION

Product Toxicological Data:LD50: None reportedLC50: None reportedDermal Toxicity Data: None reportedSkin and Eye Irritation Data: None reportedMutation Data: None reportedReproductive Effects Data: None reported

Ingredient Toxicological Data: Sodium metaborate: Oral rat LD50= 2330 mg/Kg; Lithium sulfate: Oralmouse LD50= 1190 mg/Kg

_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information:No ecological data available for this product.

Ingredient Ecological Information:No ecological data available for the ingredients of this product.

_____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: Not applicable as a powder.Special Instructions (Disposal): Dilute material with excess water making a weaker than 5% solution. Adjustto a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water tapcompletely, slowly pour the material to the drain. Allow cold water to run for 5 minutes to completely flushthe system. Work in an approved fume hood.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normaltrash. Rinsate from empty containers may contain sufficient product to require disposal as hazardous waste.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded bymore stringent state or local requirements. Please consult your local environmental regulators for moreinformation. In Europe: Chemical and analysis solutions must be disposed of in compliance with therespective national regulations. Product packaging must be disposed of in compliance with the country-specificregulations or must be passed to a packaging return system.

_____________________________________________________________________________14. TRANSPORT INFORMATION

D.O.T.:D.O.T. Proper Shipping Name: Not Currently Regulated

DOT Hazard Class: NADOT Subsidiary Risk: NADOT ID Number: NADOT Packing Group: NA

I.C.A.O.:I.C.A.O. Proper Shipping Name: Not Currently Regulated

ICAO Hazard Class: NAICAO Subsidiary Risk: NAICAO ID Number: NAICAO Packing Group: NA

I.M.O.:I.M.O. Proper Shipping Name: Not Currently Regulated

I.M.O. Hazard Class: NAI.M.O. Subsidiary Risk: NAI.M.O. ID Number: NAI.M.O. Packing Group: NA

Additional Information: There is a possibility that this product could be contained in a reagent set or kitcomposed of various compatible dangerous goods. If the item is NOT in a set or kit, the classification givenabove applies. If the item IS part of a set or kit, the classification would change to the following: UN3316Chemical Kit, Class 9, PG II or III. If the item is not regulated, the Chemical Kit classification does not apply.

_____________________________________________________________________________

15. REGULATORY INFORMATION

U.S. Federal Regulations:O.S.H.A.: This product meets the criteria for a hazardous substance as defined in the HazardCommunication Standard. (29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Delayed (Chronic) Health HazardImmediate (Acute) Health HazardS.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject tothe reporting requirements of Section 313 of Title III of SARA.

302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicableRCRA: Contains RCRA regulated substances. See Section 13, EPA Waste ID Number.

C.P.S.C.: Not applicableState Regulations:

California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s):

California Perchlorate Rule CCR Title 22 Chap 33:Trade Secret Registry: Not applicableNational Inventories:

U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).TSCA CAS Number: Not applicable

_____________________________________________________________________________16. OTHER INFORMATION

Intended Use: Laboratory ReagentReferences: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. AmericanConference of Governmental Industrial Hygienists, 1992. NIOSH Registry of Toxic Effects of ChemicalSubstances, 1985-86. Cincinnati: U.S. Department of Health and Human Services, April, 1987. The MerckIndex, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Vendor Information. Technical Judgment.Sax, N. Irving and Richard J. Lewis, Sr., revised by. Hawley's Condensed Chemical Dictionary, Eleventh Ed.New York: Van Nostrand Reinhold Co., 1987. Gosselin, R. E. et al. Clinical Toxicology of CommercialProducts, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Sax, N. Irving. Dangerous Properties ofIndustrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. In-house information. List ofDangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging andLabeling of Dangerous Substances, Amended July 1992. Technical Judgment. Air Contaminants, FederalRegister, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. Fire Protection Guide on HazardousMaterials, 10th Ed. Quincy, MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10thEd. Quincy, MA: National Fire Protection Association, 1991. CCINFO RTECS. Canadian Centre forOccupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. TLV's Threshold Limit Valuesand Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists,1992. CCINFO MSDS/FTSS. Canadian Centre for Occupational Health and Safety. Hamilton, OntarioCanada: 30 June 1993. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp.2332-2983. 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor).Revision Summary: New MSDS

_____________________________________________________________________________

Legend:NA - Not Applicable w/w - weight/weightND - Not Determined w/v - weight/volumeNV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individualsite safety programs in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OFTHESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2009



Product Name: Phosphorus HR TNT Reagent BCatalog Number: TNT844B


MSDS Number: M02456Chemical Name: Not applicableCAS No.: Not applicableChemical Formula: Not applicableChemical Family: Not applicableHazard: Harmful if inhaled. Contains a recognized carcinogen. Causes eye burns.Date of MSDS Preparation:



Ammonium MolybdateCAS No.: 12054-85-2TSCA CAS Number: 12027-67-7Percent Range: 0.5 - 3.0Percent Range Units: weight / volumeLD50: None reported.LC50: None reported.TLV: 5 mg/m³ as MoPEL: 5 mg/m³ as MoHazard: Toxic. May cause irritation.

Demineralized WaterCAS No.: 7732-18-5TSCA CAS Number: 7732-18-5Percent Range: 75.0 - 85.0Percent Range Units: volume / volumeLD50: None reportedLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: No effects anticipated.

Other componentCAS No.: Not applicable

TSCA CAS Number: Not applicablePercent Range: < 1.0Percent Range Units: weight / volumeLD50: Not applicableLC50: Not applicableTLV: Not establishedPEL: Not establishedHazard: Any ingredient(s) of this product listed as "Other component(s)" is not considered a health hazardto the user of this product.

Sulfuric acidCAS No.: 7664-93-9TSCA CAS Number: 7664-93-9Percent Range: 10.0 - 20.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 2140 mg/kg.LC50: Inhalation rat LC50 = 87 ppm/4 hrTLV: 1 mg/m³ (TWA); 3 mg/m³ (STEL)PEL: 1 mg/m³Hazard: Causes severe burns. Harmful if inhaled. Recognized carcinogen.


Emergency Overview:Appearance: ColorlessOdor: Odorless

CAUSES BURNS HARMFUL IF INHALEDCANCER HAZARD CONTAINS SULFURIC ACID WHICH CAN CAUSE CANCER


NFPA:Health: 3Flammability: 0Reactivity: 2Symbol: Water Reactive

Potential Health Effects:Eye Contact: Causes severe burnsSkin Contact: May cause irritiationSkin Absorption: None reported

Target Organs: None reportedIngestion: Causes: severe burns May cause: circulatory collapse rapid pulse and respirations diarrheanausea vomiting

Target Organs: None reportedInhalation: Causes: severe burns May cause: difficult breathing mouth soreness teeth erosion

Target Organs: LungsMedical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditionsChronic Effects: Chronic overexposure may cause erosion of the teeth chronic irritation or inflammationof the lungs cancerCancer / Reproductive Toxicity Information:


An ingredient of this mixture is: IARC Group 1: Recognized CarcinogenSulfuric Acid - The IARC evaluation was based on exposure to the mist or vapor of concentrated sulfuric

acid generated during chemical processes.This product does NOT contain any NTP listed chemicals.


_____________________________________________________________________________4. FIRST AID

Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing.Call physician immediately.Ingestion (First Aid): Give large quantities of water. Call physician immediately.Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.


Flammable Properties: Not Flammable, but reacts with most metals to form flammable hydrogen gas.During a fire, corrosive and toxic gases may be generated by thermal decomposition.Flash Point: Not applicableMethod: Not applicableFlammability Limits:

Lower Explosion Limits: Not applicableUpper Explosion Limits: Not applicable

Autoignition Temperature: Not applicableHazardous Combustion Products: This material will not burn.Fire / Explosion Hazards: Contact with metals gives off hydrogen gas which is flammable May reactviolently with: strong bases water


Extinguishing Media: Dry chemical.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and fullprotective gear.



a spill according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergencyresponse plan and guidelines/procedures. See Section 13, Special Instructions for disposal assistance.Containment Technique: Absorb spilled liquid with non-reactive sorbent material. Stop spilled material frombeing released to the environment. Dike large spills to keep spilled material from entering sewage and drainagesystems or bodies of water.Clean-up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoopup slurry into a large beaker. Adjust to a pH between 6 and 9. Use sulfuric or citric acid to lower pH. Use sodaash or sodium bicarbonate to increase pH. Flush reacted material to the drain with a large excess of water.Decontaminate the area of the spill with a soap solution.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergencyresponse plan) when: any quantity is spilled.Special Instructions (for accidental release): Mixture contains a component which is regulated as a waterpollutant. Product is regulated as RCRA hazardous waste.304 EHS RQ (40 CFR 355): Sulfuric Acid - RQ 1000 lbs.

D.O.T. Emergency Response Guide Number: 157_____________________________________________________________________________7. HANDLING / STORAGE

Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly afterhandling. Use with adequate ventilation. Maintain general industrial hygiene practices when using thisproduct.Storage: Keep away from: alkalies oxidizers reducers metals


Engineering Controls: Have a safety shower nearby. Have an eyewash station nearby. Use generalventilation to minimize exposure to mist, vapor or dust. Maintain general industrial hygiene practices whenusing this product.Personal Protective Equipment:

Eye Protection: chemical splash gogglesSkin Protection: lab coat disposable latex glovesInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Washthoroughly after handling. Use with adequate ventilation. Keep away from: alkalies reducers oxidizersmetalsTLV: Not establishedPEL: Not established


Appearance: ColorlessPhysical State: LiquidMolecular Weight: Not applicableOdor: OdorlesspH: <1Vapor Pressure: <20 hPa @ 20º CVapor Density (air = 1):Boiling Point:Melting Point:Specific Gravity (water = 1): 1.11 g/cm3

Evaporation Rate (water = 1): Not determinedVolatile Organic Compounds Content: None intentionally addedPartition Coefficient (n-octanol / water): Not applicableSolubility:

Water: MiscibleAcid: Not determinedOther: Not determined



Chemical Stability: Stable when stored under proper conditions.Conditions to Avoid: Extreme temperatures Heating to decomposition.Reactivity / Incompatibility: May react violently in contact with: acetic acid caustics chlorosulfonic acidoxidizers reducers Incompatible with: metals

Hazardous Decomposition: Contact with metals may release flammable hydrogen gas. Heating todecomposition releases toxic and/or corrosive fumes of: sulfur oxidesHazardous Polymerization: Will not occur.



Ingredient Toxicological Data: Ammonium molybdate: Oral rat LD50 = 333 mg/Kg; Sulfuric Acid: Oral ratLD50 = 2140 mg/Kg, Inhalation rat LC50= 510 mg/m3/2H



Ingredient Ecological Information:


EPA Waste ID Number: D002, CorrosivitySpecial Instructions (Disposal): Working in a large container, cautiously add small portions of the materialto cold water with agitation. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodiumbicarbonate. Open cold water tap completely, slowly pour the reacted material to the drain. Flush system withplenty of water.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normaltrash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded bymore stringent state or local requirements. Please consult your local environmental regulators for moreinformation.


D.O.T.:D.O.T. Proper Shipping Name: Sulphuric Acid

DOT Hazard Class: 8DOT Subsidiary Risk: NADOT ID Number: UN2796DOT Packing Group: II

I.C.A.O.:I.C.A.O. Proper Shipping Name: Sulphuric Acid

ICAO Hazard Class: 8ICAO Subsidiary Risk: NAICAO ID Number: UN2796ICAO Packing Group: II

I.M.O.:

I.M.O. Proper Shipping Name: Sulphuric Acid

I.M.O. Hazard Class: 8I.M.O. Subsidiary Risk: NAI.M.O. ID Number: UN2796I.M.O. Packing Group: II


_____________________________________________________________________________15. REGULATORY INFORMATION


S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Delayed (Chronic) Health HazardImmediate (Acute) Health Hazard ReactiveS.A.R.A. Title III Section 313 (40 CFR 372): This product contains a chemical(s) subject to thereporting requirements of Section 313 of Title III of SARA.Ammonia from dissociable ammonium compound; Sulfuric acid (acid aerosols including mists, vapors,

gas, fog, and other airborne forms of any particle size.)302 (EHS) TPQ (40 CFR 355): Sulfuric Acid 1000 lbs.304 CERCLA RQ (40 CFR 302.4): Sulfuric Acid 1000 lbs.304 EHS RQ (40 CFR 355): Sulfuric Acid - RQ 1000 lbs.Clean Water Act (40 CFR 116.4): Sulfuric acid - RQ 1000 lbs.RCRA: Contains RCRA regulated substances. See Section 13, EPA Waste ID Number.

C.P.S.C.: The label for this product bears the signal word "POISON" because the concentration of SulfuricAcid in the product is greater than/equal to 10%.

State Regulations:California Prop. 65: No Prop. 65 listed chemicals are present in this product.

Identification of Prop. 65 Ingredient(s):California Perchlorate Rule CCR Title 22 Chap 33:

Trade Secret Registry: Not applicableNational Inventories:

U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).TSCA CAS Number:


Intended Use: Orthophosphate DeterminationReferences: Vendor Information. TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. Sixth AnnualReport on Carcinogens, 1991. U.S. Department of Health and Human Services. Rockville, MD: TechnicalResources, Inc. 1991. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: VanNostrand Reinhold Co., 1989. List of Dangerous Substances Classified in Annex I of the EEC Directive(67/548) - Classification, Packaging and Labeling of Dangerous Substances, Amended July 1992. IARCMonographs on the Evaluation of the Carcinogenic Risks to Humans. World Health Organization (Volumes 1-42) Supplement 7. France: 1987. Cassaret and Doull's Toxicology, 3rd Ed. New York: MacmillanPublishing Co., Inc., 1986. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed.Baltimore: The Williams and Wilkins Co., 1984. CCINFO RTECS. Canadian Centre for Occupational Healthand Safety. Hamilton, Ontario Canada: 30 June 1993. Air Contaminants, Federal Register, Vol. 54, No. 12.Thursday, January 19, 1989. pp. 2332-2983. 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor).

Prager, Jan C. Environmental Contaminants Reference Databook, Volumes I and II. Van Nostrand ReinholdCompany, New York.Revision Summary: Updates in Section(s) 1, 14, 15,

_____________________________________________________________________________




HACH COMPANY ©2009



Product Name: Phosphorus HR TNT Reagent CCatalog Number: TNT844C


MSDS Number: M02446Chemical Name: Not applicableCAS No.: Not applicableChemical Formula: Not applicableChemical Family: MixtureHazard: May cause allergic reaction. May cause irritation.Date of MSDS Preparation:



DextranCAS No.: 9004-54-0TSCA CAS Number: 9004-54-0Percent Range: 10.0 - 20.0Percent Range Units: weight / weightLD50: None reportedLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: May cause allergic reaction. May cause irritation.

Ascorbic acidCAS No.: 50-81-7TSCA CAS Number: 50-81-7Percent Range: 50.0 - 60.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 11900 mg/kgLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: Practically non-toxic.

Sodium MetaborateCAS No.: 7775-19-1

TSCA CAS Number: 7775-19-1Percent Range: 20.0 - 30.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 2330 mg/kgLC50: None reportedTLV: 10 mg/M3 Inhalable Particles; 3 mg/M3 Respirable ParticlesPEL: 15 mg/M3 Total Dust; 5 mg/M3 Respirable DustHazard: May cause irritation.


Emergency Overview:Appearance: WhiteOdor: Not determined

MAY CAUSE ALLERGIC REACTION MAY CAUSE EYE IRRITATION



Potential Health Effects:Eye Contact: May cause irritiationSkin Contact: No effects are anticipatedSkin Absorption: No effects anticipated

Target Organs: Not applicableIngestion: Very large doses may cause: gastrointestinal irritation diarrhea

Target Organs: None reportedInhalation: No effects anticipated

Target Organs: Not applicableMedical Conditions Aggravated: None reportedChronic Effects: Chronic overexposure may cause allergic respiratory reactionsCancer / Reproductive Toxicity Information:

O.S.H.A. Listed: No

IARC Listed: No

NTP Listed: No

Additional Cancer / Reproductive Toxicity Information: Not applicableToxicologically Synergistic Products: None reported

_____________________________________________________________________________4. FIRST AID

Eye Contact: Flush eyes with water. Call physician if irritation develops.Skin Contact (First Aid): Wash skin with soap and plenty of water.Ingestion (First Aid): Give large quantities of water. Call physician immediately.

Inhalation: Remove to fresh air._____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: Can burn in fire, releasing toxic vapors.Flash Point: Not applicableMethod: Not applicableFlammability Limits:

Lower Explosion Limits: Not determinedUpper Explosion Limits: Not determined

Autoignition Temperature: Not determinedHazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.Fire / Explosion Hazards: May react violently with: strong oxidizers


Extinguishing Media: Carbon dioxide Dry chemical. Water.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and fullprotective gear.



a spill according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergencyresponse plan and guidelines/procedures. See Section 13, Special Instructions for disposal assistance.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pHbetween 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drainwith a large excess of water. Decontaminate the area of the spill with a soap solution.Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the sizeof the evacuation.Special Instructions (for accidental release): Not applicable304 EHS RQ (40 CFR 355): Not applicableD.O.T. Emergency Response Guide Number: --


Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain generalindustrial hygiene practices when using this product.Storage: Keep away from: oxidizers


Engineering Controls: Maintain general industrial hygiene practices when using this product.Personal Protective Equipment:

Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling.Keep away from: oxidizersTLV: Not established. Handle as dust.PEL: Not established. Handle as dust.

_____________________________________________________________________________

9. PHYSICAL / CHEMICAL PROPERTIES

Appearance: WhitePhysical State: SolidMolecular Weight: Not applicableOdor: Not determinedpH: Not determinedVapor Pressure: Not applicableVapor Density (air = 1): Not applicableBoiling Point: Not applicableMelting Point: 192º C (378º F)Specific Gravity (water = 1): 600 - 900 kg/cm3

Evaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: 70-80% Per 49 CFR definition. (Non-volatile)Partition Coefficient (n-octanol / water): Not applicableSolubility:

Water: 330 g/LAcid: Not determinedOther: Not determined



Chemical Stability: Stable when stored under proper conditions.Conditions to Avoid: Excess moistureReactivity / Incompatibility: Incompatible with: oxidizers alkalies copper ironHazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbondioxide.Hazardous Polymerization: Will not occur.



Ingredient Toxicological Data: Ascorbic acid: Oral rat LD50 = 11900 mg/Kg; Sodium metaborate: Oral ratLD50= 2330 mg/Kg;



Ingredient Ecological Information:No ecological data available for the ingredients of this product.


EPA Waste ID Number: Not applicableSpecial Instructions (Disposal): Work in an approved fume hood. Dilute to 3 to 5 times the volume with coldwater. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open coldwater tap completely, slowly pour the reacted material to the drain. Allow cold water to run for 5 minutes tocompletely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normaltrash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded bymore stringent state or local requirements. Please consult your local environmental regulators for moreinformation.











S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health HazardS.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject tothe reporting requirements of Section 313 of Title III of SARA.

302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicableRCRA: Contains no RCRA regulated substances.

C.P.S.C.: Not applicable

State Regulations:California Prop. 65: No Prop. 65 listed chemicals are present in this product.



U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).TSCA CAS Number:


Intended Use: Laboratory ReagentReferences: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register,Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and BiologicalExposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992. TheMerck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Sax, N. Irving. DangerousProperties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al.Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984.Vendor Information. In-house information. Technical Judgment.Revision Summary: New MSDS

_____________________________________________________________________________




HACH COMPANY ©2009



Product Name: Phosphorus HR TNT844RCatalog Number: TNT844R


MSDS Number: M01875Chemical Name: Not applicableCAS No.: Not applicableChemical Formula: Not applicableChemical Family: Not applicableHazard: Causes eye burns.Date of MSDS Preparation:



Demineralized WaterCAS No.: 7732-18-5TSCA CAS Number: 7732-18-5Percent Range: 90.0 - 100.0Percent Range Units: volume / volumeLD50: None reportedLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: No effects anticipated.

Sulfuric acidCAS No.: 7664-93-9TSCA CAS Number: 7664-93-9Percent Range: 1.0 - 5.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 2140 mg/kg.LC50: Inhalation rat LC50 = 87 ppm/4 hrTLV: 1 mg/m³ (TWA); 3 mg/m³ (STEL)PEL: 1 mg/m³Hazard: Causes severe burns. Harmful if inhaled. Recognized carcinogen.


Emergency Overview:Appearance: Clear, colorlessOdor: Acidic

CAUSES EYE BURNS MAY CAUSE RESPIRATORY TRACT IRRITATIONCANCER HAZARD CONTAINS SULFURIC ACID WHICH CAN CAUSE CANCER



Potential Health Effects:Eye Contact: Causes eye burns.Skin Contact: No effects are anticipatedSkin Absorption: None reported

Target Organs: None reportedIngestion: Causes: irritation of the mouth and esophagus May cause: vomiting diarrhea

Target Organs: None reportedInhalation: May cause: respiratory tract irritation teeth erosion mouth soreness difficult breathing

Target Organs: LungsMedical Conditions Aggravated: Pre-existing: Eye conditions Respiratory conditionsChronic Effects: Chronic overexposure may cause erosion of the teeth chronic irritation or inflammationof the lungs cancerCancer / Reproductive Toxicity Information:


An ingredient of this mixture is: IARC Group 1: Recognized CarcinogenSulfuric Acid - The IARC evaluation was based on exposure to the mist or vapor of concentrated sulfuric

acid generated during chemical processes.This product does NOT contain any NTP listed chemicals.


_____________________________________________________________________________4. FIRST AID

Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.Skin Contact (First Aid): Wash skin with plenty of water.Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately.Never give anything by mouth to an unconscious person.Inhalation: Remove to fresh air.


Flammable Properties: Material will not burn. During a fire, irritating and highly toxic gases may begenerated by thermal decomposition.Flash Point: Not applicableMethod: Not applicable

Flammability Limits:Lower Explosion Limits: Not applicableUpper Explosion Limits: Not applicable

Autoignition Temperature: Not applicableHazardous Combustion Products: This material will not burn.Fire / Explosion Hazards: This product will not burn or explode.


Extinguishing Media: Use media appropriate to surrounding fire conditionsFire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and fullprotective gear.



a spill according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergencyresponse plan and guidelines/procedures. See Section 13, Special Instructions for disposal assistance.Containment Technique: Absorb spilled liquid with non-reactive sorbent material. Stop spilled material frombeing released to the environment.Clean-up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoopup slurry into a large beaker. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodiumbicarbonate. Flush reacted material to the drain with a large excess of water. Decontaminate the area of thespill with a soap solution.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergencyresponse plan) when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.Special Instructions (for accidental release): Mixture contains a component which is regulated as a waterpollutant. Product is regulated as RCRA hazardous waste.304 EHS RQ (40 CFR 355): Sulfuric Acid - RQ 1000 lbs.D.O.T. Emergency Response Guide Number: Not applicable


Handling: Avoid contact with eyes Do not breathe mist or vapors. Use with adequate ventilation. Maintaingeneral industrial hygiene practices when using this product. Wash thoroughly after handling.Storage: Store between 10° and 25°C.

Flammability Class: Class IIIB_____________________________________________________________________________8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT

Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices whenusing this product. Use a fume hood to avoid exposure to dust, mist or vapor.Personal Protective Equipment:

Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes skin Do not breathe: mist/vapor Use with adequateventilation. Protect from: heatTLV: Not establishedPEL: Not established


Appearance: Clear, colorless

Physical State: LiquidMolecular Weight: Not applicableOdor: AcidicpH: 1.0Vapor Pressure: 15 hPaVapor Density (air = 1): Not determinedBoiling Point: Not determinedMelting Point: Not determinedSpecific Gravity (water = 1): 1.04Evaporation Rate (water = 1): Not determinedVolatile Organic Compounds Content: None addedPartition Coefficient (n-octanol / water): Not applicableSolubility:

Water: MiscibleAcid: MiscibleOther: Not determined



Chemical Stability: Stable when stored under proper conditions.Conditions to Avoid: Extreme temperatures Exposure to air. Heating to decomposition.Reactivity / Incompatibility: Incompatible with: alkalies oxidizers reducersHazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: sulfur oxidesHazardous Polymerization: Will not occur.



Ingredient Toxicological Data: Sulfuric Acid: Oral rat LD50 = 2140 mg/Kg, Inhalation rat LC50= 510mg/m3/2H



Ingredient Ecological Information:


EPA Waste ID Number: D002, CorrosivitySpecial Instructions (Disposal): Work in an approved fume hood. Dilute to 3 to 5 times the volume with coldwater. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold

water tap completely, slowly pour the reacted material to the drain. Allow cold water to run for 5 minutes tocompletely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normaltrash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded bymore stringent state or local requirements. Please consult your local environmental regulators for moreinformation.











S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health HazardDelayed (Chronic) Health HazardS.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject tothe reporting requirements of Section 313 of Title III of SARA.

302 (EHS) TPQ (40 CFR 355): Sulfuric Acid 1000 lbs.304 CERCLA RQ (40 CFR 302.4): Sulfuric Acid 1000 lbs.304 EHS RQ (40 CFR 355): Sulfuric Acid - RQ 1000 lbs.Clean Water Act (40 CFR 116.4): Sulfuric acid - RQ 1000 lbs.RCRA: Contains RCRA regulated substances. See Section 13, EPA Waste ID Number.

C.P.S.C.: Not applicableState Regulations:

California Prop. 65: No Prop. 65 listed chemicals are present in this product.



U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).TSCA CAS Number: Not applicable


Intended Use: Phosphate determinationReferences: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. AmericanConference of Governmental Industrial Hygienists, 1992. In-house information. Technical Judgment. AirContaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. VendorInformation. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans. World HealthOrganization (Volumes 1-42) Supplement 7. France: 1987.Revision Summary: New MSDS

_____________________________________________________________________________




HACH COMPANY ©2009

the following list contains the material safety data ...dlong/envengrinfo/total-ortho reactive...

Documents