اعداد / النفط. تكنولوجيا قسم الربيعي عجمي خالد د

التكنولوجية/ الجامعة

/ / . والتطوير البحث دائرة رسن هاشم محسن دالعالي التعليم وزارة

What is NORM?

NORM, or naturally occurring radioactive material, is found almost everywhere. In the exploration and extraction processes of oil and gas, the natural radionuclides 238U, 235U and 232Th, as well as the radium-radionuclides (223Ra, 224Ra, 226Ra and 228Ra) and 210Pb,.etc., are brought to the slurry surfaces and may contain levels of radioactivity above the surface background.

• The radionuclides of interest include long-lived radionuclides such as – uranium-238 (238U)– uranium-235 (235U)– thorium-232 (232Th)

and their radioactive decay products such as isotopes of – radium– radon– polonium– bismuth– lead

and individual long-lived radionuclides such as– potassium-40 (40K)– rubidium-87 (87Rb)– indium-115 (115In)

NORM in the Oil and Gas Industry

Oil and gas NORM is created in the production process, when produced fluids from reservoirs carry sulfates up to the surface of the Earth's crust. Barium, Calcium and Strontium sulfates are larger compounds, and the smaller atoms, such as Radium 226 and Radium 228 can fit into the empty spaces of the compound and be carried through the produced fluids. As the fluids approach the surface, changes in the temperature and pressure cause the Barium, Calcium, Strontium and Radium sulfates to precipitate out of solution and form scale on the inside, or on occasion, the outside of the tubulars and/or casing.

On the other hand, NORM accumulated with time as sluge in petroleum refinery units

Two decay series found in NORM deposits – from U-238 and Th-232.

• Uranium-238 emits alphas, betas and gammas decaying through protoactinium, thorium, radium, radon, polonium and bismuth to stable lead-206.

• Thorium-232 emits alphas, betas and gammas decaying through radium, actinium, radon, bismuth, polonium and thallium to stable lead-208.

Why is it a hazard.

• The naturally radioactive material is concentrated into these deposits.

• They become sufficiently active to require precautions to be taken when working with them. They emit alpha, beta and gamma radiation.

• They also require to be disposed of in a controlled manner under

International regulations.

Why NORM Occurs

• Reservoir rock contains small amounts of natural uranium and thorium and their radioactive daughters. One daughter, radium, is water soluble - dissolves in the reservoir water.

• Radium can precipitate with the barium and calcium ions to make any scales slightly radioactive. (NORM)

• Clay and fine particles can absorb the radium from the formation water.

FIXED IN PLACE

U-238Th-232

Ra-226

Ra-228

Soluble & mobile

Formation water

Rn-222

Oil and gas

U-238 Th-232

Fixed in place

Scal

e

Buildup of scale containing radium

Buildup of scale containing radium

Scale & Sludgecontaining radium

Radon gasRadium will decaygiving rise to manyradioactive daughters(NORM radionuclides)

Natural gas will contain a certainamount of radon

THE ORIGINS OF NORM

NORM in Gas Wells

• NORM can also be found in Gas Wells where no liquids are present.• Here it is due to radioactive lead-210 plating out on surfaces from the

gas.• The gas is radioactive because of the radioactive radon gas in the

formation accumulating in it.• This radon then decays to the lead-210• This layer is thin and cannot always be seen

• Stop inhalation or ingestion of scale particles-Stop dust being created

Stop dust becoming airborne

Stop dust from entering the body

Contain scale in one area and minimise contact

• To achieve this we -Adhere to Local Rules

Keep scale wet to stop dust rising

Wear personal protective equipment

Set up NORM Supervised Area and restrict contact

عدم إستنشاق أو بلع عدم إستنشاق أو بلع ضرورة ضرورةالجزيئات الدقيقةالجزيئات الدقيقة

للقشور ـ للقشور ـالتسبب بحدوث التسبب بحدوث دم دم ضرورة عضرورة ع

الغبارالغبارفي في الغبار الغبار عدم ترك عدم تركضرورةضرورة

مكانه حتى تحمله الرياحمكانه حتى تحمله الرياح للغبارللغبار عدم السماح عدم السماح ضرورةضرورة

بدخول الجسمبدخول الجسم حصر القشور في حصر القشور في ضرورةضرورة

للحد من لمسها للحد من لمسها منطقة واحدة منطقة واحدة ..إلى أدنى درجة ممكنةإلى أدنى درجة ممكنة

ذلك علينا ـ ذلك علينا ـلتحقيقلتحقيق قواعد واألنظمةقواعد واألنظمةاإللتزام بالاإللتزام بالالمحليةالمحلية

لمنع تصاعد لمنع تصاعد رطبة رطبة القشور القشورإبقاءإبقاءغبارغبارالال

إستخدام معدات الوقاية إستخدام معدات الوقاية الشخصيةالشخصية

منطقة لمراقبة المواد منطقة لمراقبة المواد تحديد تحديد المشعة طبيعية المنشأ ومنع المشعة طبيعية المنشأ ومنع

لمسها.لمسها.

NORM Management

Shell standard NORM meter for oil systems- Mini 900 with 44B probe.

• 5 cps above background is the lowest statistically reliable reading with the meter

• We identify contamination, we do not measure scale or deposits activity.

• Using the Mini 900 a reading of 5 cps above background is NORM.

• Science of protecting people and the environment from the harmful effects of ionizing radiation, which includes both particle radiation and high energy electromagnetic radiation

United States: still quarrelling between EPA and state departments who sits in the driving seat to regulate NORM (“How far should a risk-based approach in view of the natural background radiation dose be pushed. Latest CRCPD draft part N – 1999.

Malaysian 1996: skipped formerly issued ‘release concentrations for solids’. Especially for scale and sludge disposal a “Radiological Impact Assessment” demonstrating compliance with the ICRP public dose limit is required.

Canada 2000: previous guidelines reviewed and reissued nation-wide. “Unconditional Release Limits” derived from enveloping total-dose assessment scenarios provided for environmental media (air, water, soil). NORM dose constraint set at 300 Sv/y. Allowance for Conditional Release Limits by having carried out dedicated total-dose assessment scenarios.

European Union: 2000 implementation of EC Directive 96/29/Euratom and accompanying guidance documents did not (yet) achieve full harmonisation for member state E&P NORM regulations.

Middle East: several gas/oil producing states (Egypt, Oman, Syria, UAE) start to issue national E&P NORM Regulations.

NORM Regulations