the origin of petroleum in the oriente (ecuador)

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  • 8/9/2019 The origin of Petroleum in the Oriente (Ecuador)

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    The American Assoclatlon of Petroleum Geologists Bulletin

    V. 59 No.

    7

    July

    1975). P.

    1166-1

    175,

    2 Figs.

    2 Tables

    Origin

    of

    Petroleum in the Oriente

    of Ecuador

    bahcI Large reserves of petroleum in the Oriente of Ec-

    uador are prawnt in sedimentory racks deposited on a conti-

    nental h l f during the Cretaceous. The petroleum was not

    genwoted in these rocks but in the fino-grained terrigenous

    c h i c sediments of a contemporaneous continental-rise

    prism deposited in deeper water farther west. The rise sedi-

    ments subsequently were metamorphosed and are now part

    of the metamorphic rocks of the Eastern Cordillera of the

    Andes. At the beginning of deformation of the continentol-

    rise sediments caused by the onset of subduction during the

    Maostrichtion most of the petroleum in the northern part of

    the prism was driven upward ond eastward porallel with

    bedding. Thus much of the petroleum entered the shelf rocks

    lotorally. More complex deformation of the continental-rise

    sediments in the south prevented the escape of petroleum

    there. he trapped petroleum subsequently was converted to

    graphii by metamorphism. Quantitative wlculations show

    that

    the proposed mechanism is rwronoble and thus may

    have applications elsewhere and should be

    considered in

    planning exploration for petroleum in racks deposited an

    continental shelves. A single carbon analysis of metamorphic

    rocks from the south end of the Eastern Cordillera suggests

    that the graphite content also diminishes southward. If true

    this augurs well for the finding of oil in fields currently under

    explorotion toward the east in Peru.

    Tsch opp 1953) wrote a splen did summ ary of

    the geology of the Oriente of Ecuador based on

    12 years of detailed but unsuccessful exploration

    fo r petroleum by geologists of Th e Shell Com pa-

    ny of Ecu ado r, Ltd. decade later regional ex-

    ploration again was undertaken, but by a dozen

    companies new to the Oriente a nd each working a

    smaller concession than that originally held by

    Shell. On April 8, 1967, Texaco-G ulf co mpleted a

    producing well at Lago Agrio and discovered the

    first of many large fields now in produ ction in the

    north Oriente Fig. 1). Conco mitant exploration

    an d test drilling by other com panies in the south-

    e m Oriente, within a nd peripheral to the area ear-

    lier studied by Shell, again w ere unsuccessful.

    Tschopp 1953, p. 2345) an d most petroleum

    geologists currently at work in Ecuador ascribed

    the source of the Oriente petroleum to bitumi-

    nous shale and limestone the Napo Form ation;

    see following) tha t are present east of the Andes.

    Nevertheless, I shall show that these rocks are un-

    likely sources, an d instead propose herein that the

    oil was generated in and driven from a thick

    prism of fine-grained clastic terrigenous sedi-

    ments on the west, at the site of the present

    Andes. These sedim ents subsequently were meta-

    morphosed and now crop out as the schist, phyl-

    TOM SEININQEP

    Quito Ecuodor

    lite, slate, and quartzite of the Eastern Cordillera

    of the Ecuadorian Andes. If these metamorphic

    rocks were the source of the petroleum, the out-

    standing anomaly of petroleum occurrence in

    eastern Ecuador can be explained successfully-

    namely, the almost compleie restriction of peiro-

    leum to the north Oriente. Correlative potential

    reservoir rocks in the south Oriente, as thick as

    those on the north-and with similar structural,

    stratigraphic, and petrophysical characteristics-

    contain little or no petroleum.

    Geologically, eastern Ecuador consists of three

    parallel, approximately north-striking belts. F rom

    east to west these are I) the upper Amazon basin,

    2) the Andean foothills, an d 3) the Eastern Cor-

    dillera of the An des Fig. 1).

    Upper

    Amazon

    Basin

    Stretching from the eastern border of Ecuador

    west to the Andean foothills, the upper Amazon

    basin is a vast rain-forest-covered area of rela-

    tively little local relief. Regional surface gradients

    are east an d southeast, and elevations on the east-

    ern bord er of Ecuad or are less than 300 m. Th e

    area is draine d by large consequent rivers, such as

    the Napo and Pastaza Fig. l , and countless

    smaller tributarie s of th e Amazo n.

    Basement rocks of the eastern upper Amazon

    basin are granulite-facies metamorphic rocks of

    the Guyana shield. Nearer the Andean foothills

    wells have penetrated younger basement rocks:

    fossiliferous limestone and terrigenous clastic sed-

    imentary rocks of the Permian-Carboniferous

    ~ a c u m a ormation , and volcan ic and terr ige-

    nous clastic chiefly continental) sedimentary

    Q Copyright 1975. The American A ssocia tion of Petroleum

    Geologists. All rights reserved.

    IManuscript rece~v ed. une 17, 1974; accepted, October 31,

    1974.

    2Escuela Politecnica Nacional. Contribution no.

    I

    Depart-

    ment of Geology, Escuela Politecnica Nacional.

    My warm thanks go to Eugene Jarosewich, chief chemist, and

    analysts

    J.

    Norberg and P. Brenner, of the Department of Min-

    eral Sciences, Smithsonian Institution, for the chemical analy-

    ses. Geologic information helpful to me was graciously provided

    by Ben Fassett of Cayman del Ecuador, Robert Canfield of

    Texaco, and Britton Wherry. The lnstituto Geog rafico Militar,

    Quito, provided cartographic help.

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    Origin

    of

    Petroleum in the Oriente of Ecuador

    67

    rocks of the Jurassic ?) Chapiza Formation

    TSC~OPP,953, p. 23 10-2316).

    The basement rocks in turn are overlain uncon-

    formably by shallow-water marine sedimentary

    rocks of Cretaceous age, the basal Hollin Forma-

    tion and the overlying N a p Formation. The Hol-

    lin of Albian-Aptian age Tschopp, 1953, p. 2316-

    23 17; Campbell, 1970, p. 38) is composed of med-

    ium-grained, porous, white orthoquartzite with a

    few shale partings. The thickness of the Hollin

    shows little change, and through most of the Ori

    ente ranges only from 84 to 136 m. The conform-

    ably overlying Napo Formation is of Albian to

    Coniacian or Santonian age Tschopp, 1953, p.

    2317-2324; Campbell, 1970, p. 15). The middle

    Napo consists of a uniform fossiliferous lime-

    stone with shale partings) whose thickness ranges

    from 78 to 91 m Tschopp, 1953, Table 11); it is

    overlain and underlain by shale and glauconitic

    sandstone. Thickness of the entire Napo Forma-

    tion ranges from 200 to 400 m. In the eastern

    Oriente, the Napo thins and grades laterally into

    a sandy facies indistinguishable from the underly-

    ing Hollin Campbell, 1970, p. 15-16).

    Fold structures in the upper Amazon basin are

    broad warps. Basement faulting, chiefly Miocene

    or younger, and related to the final uplift of the

    modem Andes Campbell, 1970, p. 22), has juxta-

    posed the Hollin and N a p Formations in many

    places Tschopp, 1953, Fig. 7).

    The N a p Formation is overlain unconform-

    ably by a thick sequence of clastic, in part tuffa-

    ceous, poorly lithified, brackish-water to conti-

    nental sedimentary rocks of Maestrichtian and

    Tertiary ages. The basal part of this sequence is

    the Tena Formation. Post-Tena rocks have been

    given a profusion of local formation names. Tena

    and post-Tena rocks thin from a maximum of

    several kilometers

    in

    the west to 1,000 m or less at

    the eastern border of Ecuador Tschopp, 1953, p.

    2325-2342).

    Andean oothills

    belt of uplifts, in part with complex struc-

    tures, forms prominent but discontinuous ranges

    that separate the upper Amazon basin from the

    high Andes on the west Campbell, 1970, p. 27-

    29). These uplifts bring to the surface older rocks

    that range from the pre-Macuma lower Paleo-

    zoic ?) Pumbuiza Formation in the Cutucu uplift

    Fig. 1) to the Napo Formation throughout the

    foothills.

    The uplifts which produced the Andean foot-

    hills are young structures and formed at the end

    of the Miocene Campbell, 1970, p. 22). Many are

    bordered on the east by large reverse faults. Ex-

    tinct volcanoes stand atop parts of the Napo

    uplift Fig. l), culminating in Sumaco,a spectacu-

    lar fresh composite cone 3,900 m high, 55 km

    north-northeast of Puerto Napo.

    Eastern

    Cordillera

    The high Andes rise abruptly west of the foot-

    hills belt. The loftiest chain of the Ecuadorian

    Andes is the Eastern Cordillera with summit ele-

    vations commonly in excess of 4,000 m. Most of

    this cordillera is composed of pelitic and quartz-

    ose metamorphic rocks with steeply dipping folia-

    tion. These rocks are cut locally by intermediate

    to silicic stocks and small batholiths. Parts of the

    cordillera are crowned by active or dormant an-

    desite volcanoes more than 5,000 m high.

    All of the metamorphic rocks belong to the

    greenschist facies. The presence of abundant gar-

    net and chloritoid, the local occurrence of kyan-

    ite, and the absence of andalusite show that the

    rocks belong to the Barrovian, or medium-pres-

    sure-facies series of regional metamorphism.

    Rocks in the northern half of the Eastern Cor-

    dillera belong mainly to the upper greenschist fa-

    cies. They consist principally of thoroughly re-

    crystallized medium-grained mica schist. Rocks

    of lower grade, such as weakly recrystallized

    phyllite and slate, are present in a narrow belt

    adjacent to the Andean foothills. A few kilome-

    ters south of the Banos-Puyo road Fig. l), the

    grade of the metamorphic rocks of the Eastern

    Cordillera drops sharply and most are phyllite,

    slate, and fine-grained quartzite not unlike those

    adjacent to the foothills belt farther north.

    n outstanding feature of the low-grade rocks

    in the south is their abundance of graphite. The

    dominant dark-gray phyllite and slate are sooty,

    even coally; where weathered, they readily soil

    the hands. Correlative rocks of higher metamor-

    phic grade in the north are far less graphitic, light

    colored, and with little obvious graphite. The con-

    trast in graphite content of metamorphic rocks

    from the northern and southern partsof the East-

    ern Cordillera is brought out in chemical analyses

    Table 1).

    Ceologic Synthesis of Cretaceous-Tertiary of

    astern

    cuador

    The Hollin and Napo Formations were depos-

    ited in a shallow sea which transgressed from the

    west. The source of the clastic sedifnents was the

    deeply weathered Guyana shield on the east. The

    limestone beds of the Napo Formation are chiefly

    bioclastic rocks deposited during periods of di-

    minished influx of terrigenous clastic sediments.

    The shoreline zone of this sea is indicated by the

    sandy facies of the Napo Formation in eastern

    Oriente.

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    68 Tom s Feininger

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    Origin

    of

    Petroleum in the Oriente of cuador

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    Torn

    Feininger

    Table 1. Noncarbonate Carbon Content weight-percent) of

    Metamorphic Rocks from Eastern Cordillera, Ecuador*

    Sample Location Percent Carbon

    1. Saraurcu

    2. Papallacta-Baeza road

    3. Banos-Puyo road

    0.13

    0.33 average 0.25

    0.30

    4.

    East of Cuenca

    5. San Lucas verage 0.65

    *Analysts: J. Norberg (1. 2. 4. 5) and P. Brenner 3). Department of

    Mineral Sciences. Smithsonian Institution. Washington, D.C.

    Samples listed from north to south see Fig. 1): 1. Composite of 10

    chips of schist from south and west of Saraurcu, Pichincha Province.

    2.

    Composite of

    35

    chips of schist and phyllite from cuts in road

    from Papallacta to Baeza.

    Napo Province. 3.

    Composite of 20 chips of

    schist and phyllite from cuts

    in Banos-Puyo road between Banos and the

    Rio Zunac, Tungurahua Province. 4. Representative sample of phyllite

    from east of Cuenca, Morona-Santiago Province. 5. Composite of 20

    chipa of phyllite from the San Lucas area, Loja Province.

    The metamorphic rocks of the Eastern Cordil-

    lera are traditionally interpreted to be Paleozoic

    and F'rcuunbrian(?) (Tschopp, 1953; Sauer, 1965,

    p. 26; W c i o Nacional de Geologia y Mineria,

    1969; Campbell, 1970, p. 25). The arguments

    mustere

    to

    support the proposed antiquity of

    these rocks are that they are metamorphic, struc-

    turally

    complex, and not in any way correlative

    li thologidy with the relatively orderly sequence

    of supposedly younger rocks of the upper Ama-

    zon basin farther east. This age interpretation is

    here considered erroneous. Rather, I intend to

    show that the parent sediments of the metamor-

    phic rocks are contemporaneous with the Hollin

    and Napo Formations. Similar suggestions have

    been advanced by Liddle

    in

    Liddle and Palmer,

    1941, p. 14) and Faucher et al (1968, p. 46 .

    The traditional paleogeologic reconstruction of

    eastem Ecuador during the time of Hollin-Napo

    deposition has been to show ,the area of the pre-

    sent

    ndean

    foothills and upper Amazon basin as

    a broad shallow seaway, bounded on the east by

    the emergent Guyana shield, and on the west by

    the similarly emergent Eastern Cordillera (Sauer,

    1965, p. 66-61; Campbell, 1970, p. 14 . A strong

    argument against this interpretation is the ab-

    sence o evidence indicating the proximity of land

    on the west. In fact, the westernmost outcrops of

    the Hollin and Napo Formations suggest that

    they were deposited in deeper water than were

    rocks of the same formations farther east. The

    Hollin, for example, contains increasingly abun-

    dant shale partings westward, and the sandstone

    bodies in the Napo Formation on the east are

    replaced

    toward the west by shale and limestone

    (Campbell, 1970, p. 15-16).

    A more likely paleogeologic reconstruction

    (Fig. 2A) is that the Hollin and Napo Formations

    were deposited in a shallow continental-shelf sea

    with a shoreline only on the east, next to

    an

    emer-

    gent Guyana shield. On the west, roughly coinci-

    dent with the base of the present Eastern Cordill-

    era, lay a shelf edge beyond which, in the deeper

    waters of an open ocean, was deposited an enor-

    mous volume of fine-grained temgenous clastic

    sediment as a continental rise prism, or miogeo-

    cline in the sense af Dietz and Holden (1966).

    During the time of Hollin and N a p deposition,

    the coast of this part of the South American con-

    tinent was of the Atlantic type, in which the

    continental plate underlying the shelf was cou-

    pled to and moving with the adjacent oceanic

    plate. Stable shelf-rise conditions were terminated

    abruptly during the Maestrichtian by the decou-

    pling of the continental and oceanic plates, the

    onset of subduction, and the creation of

    a

    Benioff

    zone dipping eastward from a trench in the west,

    at the site of the present Western Cordillera of the

    Ecuadorian Andes. The sediments of the conti-

    nental-rise prism overlying the Benioff zone were

    deformed and subsequently metamorphosed in

    response to the rise of isogeothermal surfaces

    (Fig. 2B). In early Tertiary time the location of

    the trench shifted westward, probably to its pre-

    sent offshore location. In the Oriente of Ecuador,

    the depositional record of this orogeny is the east-

    ward-thinning wedge of Maestrichtian and Ter-

    tiary tuffaceous, brackish-water and continental,

    terrigenous clastic sedimentary rocks beginning

    with the basal Tena Formation. These rocks are

    an exogeosynclinal wedge, or back-arc deposit

    shed eastward from the erosion of a rising volca-

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    Origin of Petroleum in the Oriente of Ecuador 1171

    FIG. 2--Schematic cross sections along line A-B of Fig. 1: A) at close of Napo deposition;

    B)

    at beginning

    of Tena deposition;

    C)

    at close of Tena deposition. Symbols: hachures, continental basement; x s, oceanic

    basement; ruled and dotted, sediments and metamorphic rocks (in C) of continental-rise prism; black, Napo

    Formation excluding sandy facies; blank, Hollin Formation and sandy facies of Napo; crosses, intrusive rocks;

    checks, volcanic rocks; dotted, Tena Formation and equivalent sediments shed westward; upper fine line, sea

    level; heavy line,

    25 C

    isogeotherm. Note: Benioff zone greatly oversteepened because of vertical exaggeration

    of sections.

    nic orogen-the first vestige of the modem

    Andes-at the site of the present Eastern Cordil-

    lera (Fig. 2C).

    Recent findings from the Cuenca basin in the

    high Andes of southern Ecuador strongly support

    this proposed series of events. Here, Bristow

    (1973, p. 1 ) traced without interruption the lat-

    eral passage of fine-grained schist and phyllite of

    the Eastern Cordillera into pelitic and sandy, tur-

    biditic, sediments of the fossiliferous Upper Cre-

    taceous Yunguilla Formation. The Yunguilla here

    is interpreted as the distal western part of the con-

    tinental-rise prism that was pushed eastward dur-

    ing telescoping of the prism that accompanied de-

    formation and metamorphism (Fig. 2C).

    Geologic mapping farther west is less detailed.

    East of Cuenca, however, passage of the Hollin

    and Napo Formations into low-grade metamor-

    phic rocks t

    the base of the Eastern Cordillera

    appears gradational (Faucher et al, 1968,

    p.

    46;

    Rudolph Trouw, written commun., 1974). Signifi-

    cantly, no geologist during more than one-half

    century of exploration for oil has reported rocks

    of either the Hollin or Napo Formations lying

    unconformably on metamorphic rocks of the

    Eastern Cordillera.

    ORIGIN

    F

    P TROL UM

    N TH

    ORI NT

    The petroleum fields of the Ecuadorian Oriente

    are entirely in the north (Fig. 1). Preliminary esti-

    mates of in situ oil (Table 2) show that 98 percent

    are north of lat. 1

    S.

    Most production is from the

    top of the Hollin Formation, although the sandy

    facies of the Napo is the chief producer in the

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    Tom Feininger

    Table

    2 .

    Estimated in s it u

    i l i n

    Oriente

    of

    Ecuador

    ( b i l l ions of barre l s ) *

    Proved Probable Tot al of Total

    North of l a t . 1S. 3.948

    2.744 6.692 98

    South of l a t . 1s.

    0 .013

    0.128 0.141

    Total 3.961 2.872 6.833 100

    . .

    Direm ion General

    e

    Hidrocarburos, Quito.

    eastern fields. Rocks older than the Hollin and

    younger than the Napo are barren.

    Inadequacy of

    Napo Formation s Source

    ock

    Th e Napo Forma tion is cited repeatedly as the

    source of the Oriente petroleum. I t is a n attractive

    candidate, being composed of bituminous shale,

    sandstone, a nd richly fossiliferous dark limestone.

    Most freshly broken samples of limestone or

    shale from the N ap o emit a strong smell of petro-

    leum, an d nodules of asphalt are widespread. Im -

    pregnation of Na po sandstone by asphaltic oil is

    common. Moreover, the Napo is present in all

    fields of the Oriente of Ecuador.

    Nevertheless, the Napo is an unlikely source

    rock. In the north O riente, nearest the large petro-

    leum reserves, Na po limestone an d shale beds ar e

    especially rich in oil. They are so saturated that it

    is unlikely that they ever could have held more

    oil. Rather than being a source rock, they consti-

    tute an impermeable and unexploitable reservoir

    rock. Moreover, if the Napo was the source rock,

    migration of oil into the underlying Hollin For-

    mation would have been downward. This would

    be very unlikely in these water-saturated form a-

    tions. Normal upward migration of oil would

    have produced saturation in at least the lower

    part of the Tena Formation. The Tena, however,

    is nearly barren throughou t the Oriente Robert

    Canfield, personal comm un., 1974). critical

    evaluation of these observations leads one to dis-

    card the Napo Formation and look elsewhere for

    the sou rce of the Oriente petroleum.

    Graphite in

    Metamorphic

    ocks

    of Eastern

    Cordillera

    The low-grade metamorphic rocks in the south

    of the Ea stern Cordillera a re richly graphitic. The

    origin of the graphite is enigmatic. vegetal ori-

    gin is doubtful, because a continental rise far

    from land is a n unlikely environment for the ac-

    cumulation of plant remains. Also, my own

    searches during the past six years have failed to

    reveal a single plant fossil. The graphite in these

    rocks is uniformly distributed a s microscopic dus t

    along foliation and parallel bedding planes.

    Graphite content varies markedly only across

    bedding.

    Th e absence of plant fossils an d the distribu-

    tion of the exceedingly fine-grained graph ite lead

    me to the conclusion that the graphite represents

    a petroleum residue once contained in the sedi-

    mentary precursors of these rocks. Metamor-

    phism destructively distilled the petroleum, leav-

    ing only a graphite residue. The ability of

    metamorphism to convert coal to graphite is well

    docum ented Quinn and Glass, 1958).

    Spatia l Distribution of Graphitic Metamorphic

    ocks and Petroleum in the Oriente

    Known oil reserves Table 2) and producing

    fields Fig. 1) are present only in north Oriente,

    almost entirely north of lat.

    1 s.

    From the Co-

    lomb ian border to somew here south of the Ba-

    nos-Puyo road lat. 1

    25'S),

    the metamorphic

    rocks of the Easte rn Cordillera are relatively poor

    in graphite. Far ther so uth, the metamorphic rocks

    are markedly graphitic and on the average con-

    tain two and a half times more graphite than

    those in the north Table 1). Th e petroleum re-

    serves of the O riente a re exclusively in the region

    east of graphite-poor metamorphic rocks.

    Proposed Mechanism

    Petroleum was generated contemporaneously

    with or closely following deposition throughout

    the entire fine-grained sequence that constituted

    the continental-rise prism. Th is is the basic prem-

    ise of my p roposed mechanism of origin,3 and it is

    strongly corroborated by observations made in

    the Cuenca basin. Here, the distal western part of

    the continental-rise prism, which escaped meta-

    morphism, is exposed as the Yunguilla Forma-

    tion. Many seeps of heavy oil are known in the

    Yunguilla Bristow , 1973, p. 36-37). It indeed

    )In a paper that postdates the writing of the present manu-

    script, Dickinson (1974) proposed a somewhat similar mecha-

    nism to accou nt for the accumu lation of oil elsew here. He sug-

    gested that late Tertiary continental collision in part induced

    lateral migration of petroleum from distant source rocks to form

    the proli fic reserves of the Persian Gulf area.

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    Origin of Petroleum in the Oriente of Ecuador

    73

    would be unlikely that the only petroleum in a

    continental-rise prism would be at its oceanward

    distal end. On the contrary, the presence of petro-

    leum in the distal part of the prism is considered

    here as compelling evidence that petroleum oc-

    curred throughout the prism prior to its meta-

    morphism.

    During the Maestrichtian the onset of subduc-

    tion initiated deformation and raised pressures of

    the pore fluids (oil and connate water) in the con-

    tinental-rise sediments. Where the initial defor-

    mation produced relatively simple open folds, the

    fluids were driven upward and eastward along

    bedding, away from the trench. At the former

    shelf edge, the fluids present in the lower part of

    the continental-rise prism found easy access into

    the correlative Hollin Formation. They entered

    this porous formation laterally from the west and

    progressively displaced eastward the connate wa-

    ter in the Hollin. Upward escape of fluids was

    hindered by the largely impervious shale and

    limestone of the overlying Napo Formation. Oil

    saturation of the Napo occurred later, caused by

    slow upward permeation of oil from the underly-

    ing Hollin. Fluids in the stratigraphically higher

    part of the continental-rise prism were not able to

    enter the correlative Napo because of the im-

    permeability of that formation. Here fluids were

    concentrated in the continental-rise sediments

    just west of the shelf edge.

    As deformation of the continental rise prism

    proceeded, folds became tighter and beds increas-

    ingly were crumpled and broken by faults. Fur-

    ther migration of fluids was now impossible. Si-

    multaneously, isogeothermal surfaces over the

    subjacent

    Benioff zone rose, and increasingly de-

    formation was accompaliied by metamorphism.

    Petroleum in the fluids which were unable to es-

    c pe was distilled destructively to leave a graphite

    residue. The concentration of oil in the continen-

    tal-rise sediments that abutted the impermeable

    N a p Formation left particularly abundant resi-

    dues of graphite upon metamorphism. One such

    remarkable graphite muck has been noted by

    Britton Wherry (oral commun., 1974) between the

    westernmost outcrops of the N a p Formation

    and schists of the Eastern Cordillera in the Rio

    Antisana, located

    30

    km northwest of Puerto

    N a p (Fig. 1 .

    Where the onset of deformation of the conti-

    nental-rise sediments produced not simple open

    folds, but complex folds and myriads of small

    faults, migration of fluids was not possible. With

    the onset of metamorphism, the oil contained in

    the fluids was destroyed and left a uniformly dis-

    persed graphite residue in the rocks.

    Clearly, it is no coincidence that the prolific

    petroleum reserves of the Oriente are related spa-

    tially

    so

    directly to the graphite-poor metamor-

    phic rocks of the Eastern Cordillera. The pore

    fluids including the contained oil were in large

    part expelled eastward from the continental-rise

    sediments into the Hollin Formation in the north,

    where the metamorphic rocks of the Eastern Cor-

    dillera are relatively improverished in graphite. In

    the south, fluids were unable to escape and the

    entrapped oil was converted to graphite upon

    metamorphism.

    A question to be answered is why the low-grade

    rocks in the south are graphitic. Why, in this pro-

    posed mechanism, were pore fluids driven prefer-

    entially from the sediments that today are the rel-

    atively higher grade metamorphic rocks in the

    north?

    The metamorphic rocks in the south are decid-

    edly more intensely deformed than are those in

    the north. From the Banos-Puyo road north, foli-

    ation and bedding generally are planar, whereas

    in the south the rocks are so thoroughly crumpled

    that structural attitudes other than axes of minor

    folds can be measured in very few places. It is the

    relatively greater degree of deformation of the

    rocks in the south that there impeded the escape

    of pore fluids. Two possible causes for this

    inequality of deformation north and south come

    to mind.

    One may have been that subduction and defor-

    mation began in the north, to quicken later in

    pace and migrate southward. Rocks in the north

    thus would have had a longer metamorphic histo-

    ry and achieved a higher grade than those in the

    south prior to the seaward jump of the trench in

    the early Tertiary. Initial deformation of rocks in

    the south therefore would have been more intense

    and accompanied by more faulting than would

    have been true for rocks in the north.

    Another cause of the more intense deformation

    of the metamorphic rocks in the south could have

    been the influence of the Canonaco arch (Camp-

    bell,

    1970,

    p.

    8).

    This broad, deeply buried, base-

    ment swell protrudes westward from the Guyana

    shield to impinge on the Eastern Cordillera a few

    kilometers south of Puyo (Fig.

    1). The arch may

    have offered greater mechanical resistance during

    deformation than was offered by basement rocks

    under the continental-rise prism sediments far-

    ther north. Forced against a relatively unyielding

    basement, the continental-rise sediments in the

    south would have been more intensely deformed

    than those farther north. Also, if the arch is re-

    flected at depth by a root, the greater thickness of

    basement under the arch could have partly insu-

    lated the overlying rocks from the rise of iso-

    geothermal surfaces during subduction. This

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    1174 Tom Feininger

    would account for the relatively low grade of the

    metamorphic rocks of the Eastern Cordillera in

    the south.

    Quantitative

    Calculations

    To be considered seriously, the hypothesis pro-

    posed here must be quantitatively reasonable. A

    few simple calculations show that it is.

    The proved and probable oil reserves of the

    Oriente are 6.833 109 bbl (Table 2). The aver-

    age API gravity of Oriente oil is

    30 (Direccion

    General de Hidrocarburos, @to, oral commun.).

    At 100F, the density of the Oriente oil is 0.8618

    g/cc (Levorsen, 1954, Tables A-3, 8-14). The

    weight of the reserves is therefore 9.36 x I@ me-

    tric tons.

    Little or no petroleum is known in south Ori-

    ente.

    I

    assume therefore that the graphite content

    of the metamorphic rocks south of the Banos-

    Puyo road, 0.65 percent by weight (Table I , is

    the residue of n initial petroleum content repre-

    sentative of the entire continental-rise prism

    north to the Colombian border. The average car-

    bon content of the metamorphic rocks from the

    Banos-Puyo road north is only 0.25 percent by

    weight (Table I), a difference of 0.40 percent.

    Each cubic kilometer of metamorphic rock in the

    north thus contains 1.076

    X

    107 metric tons less

    carbon than in the south (average measured rock

    density 2.69 g/cc). If one assigns the difference to

    oil with 85 percent carbon (Mason, 1966, p. 238)

    that was lost by being driven out toward the east

    during deformation of the continental-rise sedi-

    ments prior to metamorphism, each cubic kilome-

    ter of carbon-depleted metamorphic rock is the

    source of 1.266 107 metric tons of oil. The oil

    reserves of the Oriente thus can have come from

    only 73.9 cu

    km

    of metamorphic rock as now ex-

    posed in the Eastern Cordillera from the Banos-

    Puyo road north.

    Metamorphic rocks underlie 720 sq km of the

    Eastern Cordillera between the Banos-Puyo road

    and the Colombian border (Servicio Nacional de

    Geologia

    y

    Mineria, 1969). At first glance, the

    source rock here proposed appears overly prolif-

    ic; the volume of rock required, integrated over

    the area of outcrop, is a layer only 103 m thick. It

    must

    be

    kept in mind, however, that the reserve

    figures (Table 2) are but a fraction of the total

    amount of petroleum involved. For example, the

    figures exclude the tens of millions of tons of as-

    phalt that impregnate the Hollin as economic de-

    posits in outcrops on the Napo uplift in the vicini-

    ty of Puerto N a p (Britton Wherry, unpub. rept.).

    The figures also exclude the rich but noneconom-

    ic oil impregnation of the Napo Formation that

    underlies 20,000 sq km of the western Oriente

    north of

    lat. 1S. If the petroleum content of this

    250-m-thick formation is only 0.5 percent by

    weight, a conservative figure based on field obser-

    vations, its petroleum content would be 67.25

    109 metric tons (using the same densities for rock

    and oil as above). This is more than 70 times the

    reserves given in Table 2. Furthermore, a s igdi-

    cant part of the oil driven eastward in the conti-

    nental-rise prism was blocked by the impermea-

    ble Napo Formation. Much of this oil was

    destroyed by metamorphism to leave graphite

    masses like that exposed in outcrops along the

    Rio Antisana, but perhaps the greatest part es-

    caped upward along faults and fractures to be

    lost at the surface.

    The total amount of oil yielded by the conti-

    nental-rise prism in the north is probably more

    than 100 and may exceed 250 times the calculated

    reserves of oil in the northern Oriente. The thick-

    ness of the metamorphic rocks required as a

    source for these quantities of oil, integrated over

    the area of outcrop in the northern Eastern Cor-

    dillera, is between 10.3 and 25.5

    km

    The thick-

    ness of the metamorphosed continental-rise prism

    prior to erosion probably was between these val-

    ues. The absence of andalusite in the metamor-

    phic rocks of the Eastern Cordillera and the local

    presence of kyanite show that at least 20 km of

    rock have been removed by erosion subsequent to

    metamorphism (Miyashiro, 1973, p. 72). Part of

    that cover was composed of volcanic-arc rocks,

    but the great thickness of the metamorphic rocks

    themselves is evident. The possibility that they

    are the source rocks of the petroleum in the Ori-

    ente of Ecuador is firmly established.

    The geologic events leading to the accumula-

    tion of petroleum in the Oriente of Ecuador

    in

    all

    likelihood occurred elsewhere. In the search for

    petroleum in rocks deposited on continental

    shelves, the nature and composition of the associ-

    ated continental-rise sediments, be they meta-

    morphosed or not, must be evaluated critically in

    planning exploration.

    Southernmost Ecuador and neighboring Peru

    may yield an interesting test of the ideas set forth

    here. Somewhat southeast of San Lucas (Fig. 1)

    the metamorphic rocks of the Eastern Cordillera

    increase in grade and become less graphitic, like

    those from the Banos-Puyo road northward. A

    chemical analysis of a composite sample of phyl-

    lite and schist from the road between Loja and

    Zamora shows

    a

    carbon content of only 0.19 per-

    cent by weight.4 This value is similar to the car-

    bon content of the metamorphic rocks in the

    4 ~ n a l y s t : . Norberg, Smithsonian Institution.

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    Origin

    of

    Petroleum in the Oriente of cuador

    north Table 1). South of the Loja-Zamora road

    the metamorphic rocks of the Eastern Cordillera

    are not very accessible and have not been studied.

    Should they maintain a low graphite content, it

    would favor the hypothesis that it was the influ-

    ence of the Conanaco arch that prevented the es-

    cape of pore fluids east of Cuenca and at San

    Lucas.

    East of Zamora the international border is in

    the Andean foothills, and the upper Amazon ba-

    sin is in Peru, south of the Ecuadorian border.

    Here in the basin, the Capahuari, Shiviyacu, and

    Trompeteros fields are currently under explora-

    tion. The diminished graphite content of the

    metamorphic rocks on the west, a speculative ob-

    servation based on a single analysis, augurs well

    for the discovery of economic reserves in these

    fields.

    Bristow, C. R., 1973, Guide to the geology of the Cuen-

    c basin, southern Ecuador: Ecuador Geol. Geophys.

    Soc.

    54 p.

    Campbell, C.

    J.,

    1970, Guide to the Puerto Napo area,

    eastern Ecuador with notes on the regional geology of

    the Oriente basin: Ecuador Geol. Geophys. Soc.,

    40

    P.

    Dickinson, W. R., 1974, Subduction and oil migration:

    Geology, v. 2, p. 42 1-424.

    Dietz, R. S., and J. C. Holden, 1966, Miogeoclines mio-

    geosynlines) in space and time: Jour. Geology, v. 74,

    p. 566-583.

    Faucher, B., R. Joyes, F. Magne, J Sigal, R. Vernet, J.

    C. Granja V., J. C. Granja B., R. Castro, and G.

    Guevara, 1968, Estudio preliminar sobre 10s princi-

    pales problemas geologicos concernientes a la explo-

    ration petrolera del Oriente Equatoriano: Ecuador

    Min. de Indust. y Com., 53 p.

    Levorsen, A. I. 1954, Geology of petroleum: San Fran-

    cisco,W. H. Freeman, 703 p.

    Liddle, R. A. and K. V. W. Palmer, 1941, The geology

    and

    paleontology of the Cuenca-Azogues-Biblian re-

    gion, Provinces of Canar and Azuay, Ecuador: Am.

    Paleontology Bull.,

    v.

    26, p. 360-421.

    Mason, B. 1966, Principles of geochemistry, 3d ed.:

    New York, John Wiley, 329 p.

    Miyashiro, A. 1973, Metamorphism and metamorphic

    belts: New York, Halsted Press, 492

    p.

    Quinn, A. W., and H. D. Glass, 1958, Rank of coal and

    metamorphic grade of rocks of the Narragansett ba-

    sin of Rhode Island: Econ. Geology, v. 53, p. 563-

    576.

    Sauer, W., 1965, Geologia del Ecuador: Ecuador Edit.

    Min. de Educacion, 383 p.

    Servicio Nacional de Geologia y Mineria, 1969, Mapa

    geologico de la Republica del Ecuador, scale I:l,

    000,000: Quito.

    Tschopp, H. J., 1953, Oil explorations in the Oriente of

    Ecuador, 1938-1950: AAPG Bull., v. 37, p. 2303-2347.