the property of viscosity is seen in the following ... · glycerine, etc., have a larger viscosity...

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PROPERTIES OF FLUIDSavte.in

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VISCOSITYWhen a solid body slides over another solid body, a frictional force beings to act between them. This

force opposes the relative motion of the bodies. Similarly, when a layer of a liquid slides over another layer ofthe same liquid, a frictional force acts between them which opposes the relative motion between the layers.This force is called ‘internal frictional force’.

The property of the liquid by virtue of which it opposes the relative motion between its adjacent layersis known as ‘viscosity’.The property of viscosity is seen in the following examples:

1. A stirred liquid, when left, comes to rest on account of viscosity. Thicker liquid such as honey, coal tar,glycerine, etc., have a larger viscosity than thinner ones such as water. If we pour coal tar and water ona table, the coal tar will stop soon while the water will flow up to quite a large distance.

2. The cloud particles fall down very slowly because of the viscosity of air and hence appear floating in thesky.Viscosity comes into play only when there is a relative motion between the layers of the same materia.

This is why it does not act in solids.

FLOW OF LIQUID IN A TUBE: CRITICAL VELOCITYIf all particles of the liquid passing through a particular point in the tube, move along the same path, the

flow of the liquid is called ‘streamlined flow’. This occurs only when the velocity of flow of liquid is below acertain limiting value called ‘critical velocity’. When the velocity of flow exceeds the critical velocity, the flowis no longer streamlined but becomes turbulent. In this type of flow, the motion of the liquid becomes zigzagand eddy currents are developed in it.

Reynolds proved that the critical velocity for a liquid flowing in a tube is c = /a, where is densityand is viscosity of the liquid, a is radius of the tube and k is ‘Reynolds number’ (whose value for a narrowtube and for water is about 1000). When the velocity of flow of the liquid is less than the critical velocity, thenthe flow of the liquid is controlled by the viscosity, the density having no effect on it. But when the velocity offlow is greater than the critical velocity, the flow is mainly governed by the density, the effect of viscositybecoming less important. It is because of this reason that when a volanco erupts, the lava coming out of itflows speedily in spite of being very thick (i.e., of large viscosity).

VISCOSITY IN FLUIDSViscosity is a measure of frictional forces between the adjacent layers of a fluid with which it opposes

the relative motion between them. The frictional resistance of fluids is also observed when a solid body moveswithin the body of a fluid. Viscous forces are present both in liquids and gases. Obviously the liquids are moreviscous than gases.

Assignment

Class XI Physics

Properties of Fluids

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NEWTON’S FORMULAThe basic formula for the frictional (or viscous force) F in a liquid was first suggest by Newton. He

observed that larger the area A of the surface of liquid considered, larger was the frictional force F; larger thegradient of velocity dv/dy across the layers of liquid, larger was the frictional force F. That is,

dvF Ady

Due to relative motion between the adjacent layers of the liquid there exists a frictional resistance,which according to Newton is given by

d dF A or F Ady dy

is called coefficient of viscosity. Negative sign shows that the direction of viscous drag (F) is justopposite to the direction of the motion of the liquid.

Similarities and differences between viscosity and sliding frictionSimilarities:1. Both viscosity and sliding friction oppose relative motion. Whereas viscosity opposes the relative motion

between two adjacent liquid layers, sliding friction opposes the relative motion between two solid layers.2. Both come into play whenever there is a relative motion between layers of liquid or solid surfaces as the

case may be.3. Both are due to molecular attractions.

Dissimilarities:

Some Applications of ViscosityKnowledge of viscosity of various liquids and gases have been put to use in daily life. Some applica-

tions of its knowledge are discussed as follows:1. As the viscosity of liquids very with temperature, proper choice of lubricant is made depending upon

season.2. Liquid of high viscosity are used in shock absorbers and buffers at railway stations.3. The phenomenon of viscosity of air and liquid is used to damp the motion of some instruments.4. The knowledge of the coefficient of viscosity of organic liquids is used in determining the molecular

weight and shape of the organic molecules.5. It finds an important use in the circulation of blood through the arteries and veins of human body.

Viscosity1. Viscosity (or viscousdrag) between layers

of liquid is directly proportional to thearea of the liquid layers.

2. Viscous drag is proportional to therelative velocity between two layers ofliquid.

3. Viscous drag is independent

ViscosityFriction between two solids is independent ofthe area of solid surfaces in contact.

Friction is independent of the relative velocitybetween two surfaces.

Friction is directly proportional to the normalreaction between two surfaces in contact.

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UNITS OF COEFFICIENT OF VISCOSITYIn CGS system, the unit of coefficient of viscosity is dyn s cm-2 and is called poise. In SI the unit of

coefficient of viscosity is N s m-2 and is called poise. In SI unit of coefficient of viscosity is N s m-2 and is calleddecapoise.

1 decapoise = 1 N s m-2 = (105 dyn) × s × (102 cm)-2

= 10 dyn s cm-2 = 10 poise

EFFECT OF TEMPERATURE ON VISCOSITYExperiments show that of a liquid decreases sharply with increases in its temperature and becomes

zero at its boiling point.The viscosity of liquids decreases with increase in temperature and increases with the decrease in

temperature. That is, 1/ T . On the other hand, the value of viscosity of gases increases with the increasein temperature and vice versa. That is, / T .

STOKE’S LAW

The streamlines for a fluid flowing slowly past a stationary solid sphere are shown in Figure.

When the sphere moves slowly as compared to the fluid, the pattern is similar but the streamlines thenflow in such a way that the apparent motion of the fluid particles is as seen by someone on the movingsphere. In this latter case, it is known that the layer of fluid in contact with the sphere moves with it, thuscreating a velocity gradient between this layer and other layers of fluid. Viscous forces are thereby broughtinto play and constitute the resistance experienced by the moving sphere. If we make the plausible assumptionthat the viscous, retarding force F depends on the size of the body, the velocity with which it moves, theviscosity of the fluid and mass density of the fluid, then an expressional an be derived for F by the method ofdimensions. Thus,

F = k x y rz

where x, y and z are the indices to be found and k is a dimensionless constant. The dimensional equation is[MLT-2] = [ML-1 T-1]x [LT-1]y [LT-1]y [L]z

Equating indices of M, L and T on both sides, we have1 = x1 = -x + y + z-2 = -x - y

Solving, we get x = 1, y = 1 and z = 1. Hence F = krA detailed treatment, first dozen by Stokes, give k = 6 and so F = 6vr.

A detailed treatment, first done by Strokes’ law, only holds for steady motion in a fluid of infinite extent(other wise the walls and bottom of the vessel affect the resisting force).

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TERMINAL VELOCITYWhen a body dropped in a viscous fluid, it is first accelerated and then its acceleration becomes zero

and it attains a constant velocity called terminal velocity. Consider a small ball of radius r, which is gentlydropped into liquid of infinite extent. As the steel ball falls, it experiences three forces: the force of gravity W;the buoyant force FB; the drag force FD.

The free-body diagram of the ball is shown in Figure. If 0 be the density of the body and be thedensity of the liquid, then

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4W r g3

and 3B

4F r g3

The magnitude of the drag force is FD = 6r.As the ball falls under gravity, its net weight W – FB is opposed by liquid resistance FD. initially, thedrag force is small and as the body gains velocity, called the terminal velocity, the magnitude of dragforce becomes equal to the effective weight of the body. At this moment, the net force on the ball becomeszero and it moves with a constant velocity. That is,

FD = W – FB

If we plot the variation of velocity of the falling sphere with time, we obtain a graph as shown inFigure. Following points can be noted:

1. Initially the velocity of the ball increases at a fast rate.2. The rate of increase of velocity decreases with time.3. Finally, the rate of increases of velocity becomes zero and the sphere acquires a terminal velocity.

Examples of terminal VelocitySome examples of terminal velocity are discussed as follows:1. Determining the electronic charge by Millikan’s experiment: Strokes formula is used in Millikan’s method

for determining the electronic charge. In this method, the formula is applied for finding out the radii ofsmall oil drops by measuring their terminal velocities in air.

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2. Velocity of rain drops: Rain drops are formed by the condensation of water vapour on dust particles.When they fall under gravity, their motion is opposed by the viscous drag in air. As the velocity of theirfall increases, the viscous drag also increases and finally becomes equal to the effective force of gravity.The drops then attain (constant) terminal velocity which is directly proportional to the square of theradius of the drops. In the beginning, the rain drops are very small in size and so they fall with such asmall velocity that they appear floating in the sky as cloud. As they grow in size by further condensation,they reach the earth with appreciable velocity.

3. Falling down with the help of a parachute: When a person jump down from a flying aeroplane, hisparachute is closed. Hence, initially his velocity increases very rapidly while the viscosity of air tries toreduce his velocity. When the parachute opens, the viscosity of air exerts greater viscous force in upwarddirection (since viscous force is directly proportional to surface area), due to which the velocity of thepersons begins to decrease and finally he attains the terminal velocity and reaches safely on ground.

4. Formation of clouds: When water vapours present in the atmosphere condense, small droplets areformed. The weight of these droplets in air is very small. Therefore, they attain the terminal velocityvery soon due to viscosity of air. Because the value of their terminal velocity is very small, they appearto float in the sky as clouds.

SURFACE TENSIONSurface tension is a property of liquid at rest by virtue of which a liquid surface gets contracted to a

minimum area and behaves like a stretched membrane.

Surface tension of a liquid is measured by force per unit length on either side of any imaginary linedrawn tangentially over the liquid surface, force being normal to the imaginary line as shown in Fig. 5.59.Mathematically, surface tension is defined as

Total forceon eithersideof theimaginaryline(F)TLength of the line(l)

In CGS system the unit of surface tension is dyn/cm (dyn cm-1) and in SI system its units in Nm-1

Causes of Surface TensionThe free surface of a liquid acts like a stretched membrane, i.e., is, the surface of a liquid is in a state of tensionas the surface of an inflated balloon.Surface tension is due to intermolecular attraction.Note:• The magnitude of T depends on the temperature of the liquid and on the medium on the other side of

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the free surface. The surface tension of a liquid decreases by increasing temperature.• The surface tension of a liquid decreases by adding impurities.

FORCE OF COHESIONThe force of attraction between the molecules of the same substance is called cohesion. In case of solids,

the force of cohesion is very large and due to this solids have definite shape and size. On the another hand,the force of cohesion is very large and due to this solids have definite shape and size. On the other hand, theforce of cohesion in case of liquids is weaker than that of solids. Hence, liquids do not have definite shape buthave definite volume. The force of cohesion is negligible in case of gases. Because of this, gases have neitherfixed shape nor fixed volume.

Examples1. Two drops of a liquid coalesce into one when brought in mutual contact because of the cohesive force.2. It is difficult to separate two sticky plates of glass wetted with water because a large has to be applied

against the cohesive force between the molecules of water.3. It is very difficult to break a drop of mercury into small droplets because of large cohesive force between

mercury molecules.

FORCE OF ADHESIONThe force of attraction between molecules of different substances is called adhesion.Examples:1. Adhesive force enables us to write on the black board with a chalk.2. Adhesive force helps us to write on the paper with ink.3. Large force of adhesion between cement and bricks helps up in construction work.4. Due to force of adhesion, water wets the glass plate.5. Fevicol and gum are used in gluing two surfaces together because of adhesive force.

SOME OBSERVED PHENOMENA BASED ON SURFACE TENSION1. Lead balls are spherical in shape.2. Rain drops and a globule of mercury placed on glass plate are spherical.3. Hair of a shaving brush/painting brush, when dipped in water spread out, but as soon as it is taken out,

its hair stick together.4. A greased needle placed gently on the free surface of water in a beaker does not sink.5. Similarly, insects can walk on the free surface of water without drowning.

SURFACE ENERGY

We know that the molecules on the liquid surface experience net downward force. So to bring a moleculefrom the interior of the liquid to the free surface, some work is required to be done against the intermolecularforce of attraction, which will be stored as potential energy of the molecule on the surface.The potential energy of surface molecules per unit area of the surface molecules per unit area of the surface iscalled surface energy.

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Unit of surface energy erg cm-2 in CGS system and J m-2 in SI system. Dimensional formula of surfaceenergy is [ML0T-2]. Surface energy depends on number of surfaces, e.g., a liquid drop is having one liquid airsurface while bubble is having two liquids air surfaces.

RELATION BETWEEN SURFACE TENSION AND SURFACE ENERGYConsider a rectangular frame PQSR of wire, whose arm RS can slide on the arm PR and QS. If this frame

is dipped in a soap solution, then a soap film is produced in the frame PQSR in Figure. Due to surface tension(T), the film exerts a force on the frame towards the interior of the film). Let l be the length of the arm RS. Thenthe force acting on the arm RS towards the film is F = T × 2l (since soap film has two surfaces, the length istaken twice).

Let the arm RS be displaced to a new position R’S’ through a distance x. Then work done, W = Fx = 2TlxIncrease is potential energy of the soap film is given by EA = 2Elx = work done in increasing the area

(W) where E = surface energy of the soap film per unit area.According to the law of conservation of energy, the work done must be equal to the increase in the

potential energy.i.e., 2Tlx = 2Elx

orWT E

A

Thus, surface tension is numerically equal to surface energy or work done per unit increase of surfacearea.

ANGLE OF CONTACTThe angle which the tangent to the liquid surface at the point of contact makes with the solid surface

inside the liquid is called angle of contact. Those liquids, which wet the walls of the container (say in case ofwater and glass), have meniscus concave upwards the their value of angle of contact is less than 90° (alsocalled acute angle). However, those liquids, which do not wet the wall of the container (say in case of mercuryand glass), have meniscus convex upwards and their value of angle of contact is greater than 90° (also calledobtuse angle). The angle of contact of mercury with the glass is about 140°, whereas the angle of contact ofwater with glass is about 8°. But, for pure water, the angle of contact with glass is taken as 0°.

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SHAPE OF LIQUIDS MENISCUSWhen a capillary tube or a tube is dipped in a liquid, the liquid surface becomes curved near the point

of contact. This curved surface is due to two forces, viz., (i) the force of cohesion and (ii) the force of adhesion.The curved surface of the liquid is called meniscus of the liquid. Various forces acting on molecules A(Figure) are as follows:

1. Force F1 due to force of adhesion which acts outwards at right angle to wall of the tube. This force isrepresented by AB.

2. Force F2 due to force of cohesion which acts at an angle of 45° to the vertical. This force is represented byAD.

3. The weight of the molecule A which acts vertically downward along the wall of the tube.Since the weight of the molecule is negligible as compared to F1 and F2, so it can be neglected. Thus,there are only two forces (F1 and F2) acting on the liquid molecules. These forces are inclined at an angleof 135°.The resultant force represented by AC will depend upon the values of F1 and F2. Let the resultant forcemake the angle with F1.

SPECIAL CASES

1. If 2 1F 2 F , then tan = , = 90°.

Then the resultant force will act vertically downward and hence the meniscus will be plane or horizontalas shown in Figure. For example, pure water contained in silver capillary tube.

2. If 2 1F 2 F , then tan is positive. Hence, a is the acute angle.

3. If 2 1F 2 F , then tan is negative. Therefore, is obtuse angle. Thus, the resultant will be directed

inside the liquid and hence the meniscus will be convex upward as shown in Figure. THis is possible incase of liquids which do not wet the walls of the capillary tube.

EXCESS PRESSURE INSIDE A CURVED SURFACESome example of plane and curved surfaces (cavities, drop and bubbles) are shown in Figure.

The bubbles, such as soap bubbles, are like blown-up balloons, air inside and air outside with a thinliquid film in between them. This thin film naturally has two free surfaces, one inside and the other outside.Cavities generally have air or some other gas outside them. They too have one exposed surface.

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PLANE SURFACEIn the surface of the liquid is plane [as shown in Figure] the molecule on the liquid surface is attracted equallyin all directions. The resultant force due to surface tension is zero. The pressure, therefore, on the liquidsurface is normal.

CONCAVE SURFACEIt the surface is concave upwards [as shown in Figure], there will be upward resultant force due to

surface tension acting on the molecule. Since the molecule on the surface is in equilibrium, there must be anexcess of pressure on the concave side.

CONVEX SURFACEIf the surface is convex [as shown in Figure], the resultant force due to surface tension acts in the

downward direction. Since the molecules on the surface is in equilibrium, there must be an excess of pressureon the concave side of the surface acting in the upward direction to balance the downward resultant force ofsurface tension. Hence, there is always an excess of pressure on concave side of a curved surface over that onthe convex side.

EXCESS PRESSURE INSIDE A LIQUID DROP AND A BUBBLEOn the concave face of a curved surface there is always an excess pressure over the convex face of the

surface. The magnitude of excess pressure can be obtained by studying the formation of air and soap bubbles.

EXCESS PRESSURE IN AN AIR BUBBLE IN LIQUIDFigure shows on-half cross section of an air bubble formed inside liquid. It is in equilibrium under the

action of three forces:1. due to external pressure p1 2. due to internal pressure p23. due to surface tension of the liquid

If R is the radius of the air bubble, then the forces due to external and internal pressure are p1(R2) andp2(R2), respectively. Since the surface tension acts around the circumference of the bubble, therefore,the force of surface tension is (2R).

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Thus, from the condition of equilibrium,p2(R2) = p1(R2) + T(2R2)

or 2 12Tp pR

Note:• A curved surface always maintains a pressure difference, which depends on the radius of the curved

surface and surface tension of the liquid.• The concave side of the surface always possesses greater pressure. If the angle of contact is zero, then

the excess pressure is given by p = 2T/R.

EXCESS PRESSURE IN SOAP BUBBLEA soap bubble forms two liquids surfaces in contact with air, one inside the bubbles and the other

outside the bubble. Figure shows one-half cross section of the soap bubble. By considering its equilibrium, weget

The cross section of an air bubble of radius R.p2( R2) = p1(pR2) + T[2(2 R)]

= 2 14tp pR

EXCESS PRESSURE ON CURVED SURFACES IN GENERALThe pressure on the concave side (whatever be on its left or right) is always greater than the pressure on

the convex side. such that

concave convex1 2

1 1P – P TR R

where = surface tension.This formula is same as what we derived earlier, i.e.,

i 02T 1 1p p TR R R

1. For a single spherical surface, e.g. drops, cavities, etc.,R1 = R2 = R (say)Then

i 01 1 2Tp p TR R R

2. For spherical film, e.g,, soap bubble,

i 01 1 4Tp p (2T)R R R

because it has two free surfaces.

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3. For a single cylindrical surface, R1 = R, R2 =

i 01 1 Tp p (T)R R

CAPILLARITYIf a narrow glass tube open at both ends is pushed in water as shown in Figure, water rises in the tube to

a height above its surface. The narrower the tube, the greater is the height to which water rises. This phenomenonis known as capillarity. When the same capillary tubes are placed in mercury, the liquid is depressed belowthe outside level. The depression increases as the diameter of the capillary tube decreases. A close observationof the capillary phenomenon reveals the following facts.

The free surface (meniscus) of the liquid which rises in the capillary tube is concave upward. The meniscusof liquid which falls in the capillary tube is convex upward.

WETTING AND NON-WETTEING LIQUIDSThe liquids which rise in a capillary are called wetting liquids; and the liquids which fall in the capillary arecalled non-wetting liquids. The wetting and non-wettine action of a liquid can be explained in terms of thecohesive and adhesive forces.

WETTING AND NON-WETTEING LIQUIDSAdhesion is the attractive force between the molecules of solids and liquids or between the molecules

of two different liquids.Cohesion is the attractive force among the molecules of the same liquid.If the adhesive forces are stronger than the cohesive forces then the liquids wet the solid surface, as

water wets the surface of glass. If the cohesive forces are stronger than the adhesive forces, then the liquids donot wet the solid surface, as mercury does not wet the surface of glass.

The wetting and non-wetting action of a liquid can also be explained in terms of the angle of contact. Ifa tangent is drawn on the meniscus of the liquid at the line of contract between the liquid and the surface, asshown in Figure, then the angle of contact is defined as the angle between the tangent and the solid surfacemeasured through the liquid.

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If the angle of contact is acute, i.e., < 90°, then the liquid wets the surface. If the angle of contact isobtuse, i.e., > 90°, then the liquid does not wet the surface. The angle of contact between water and cleanglass is zero, but when the glass is not clean the angle of contact may be about 8°.

DETERMINATION OF CAPILLARY RISEFigure shows a magnitude cross section of a capillary tube of radius R. Since the angle of contact is acute,water tends to maximize its area of contact with the glass surface. Thus, it rises in the capillary tube.

ALTERNATIVE METHODLet us take four points A, B, C and D as shown in Figure. A and B are the points just above and just below themeniscus, respectively.

Now, we have A B2TP PR

where R = radius of curvature of liquids meniscus. Substituting PA = P0, we have

B 02TP PR

If C is the point at the bottom of the excess liquid column,

we have

PC = PB + gh

where h = height of the excess liquid column.

Substituting PC = PD = P0, we have

PB = P0 - gh

Using Equations (i) and (ii), we have

0 02Tp gh PR

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This gives 2ThgR

where rRcos

Then 2T coshgr

RISE OF LIQUID IN A CAPILLARY OF IN SUFFICIENT LENGTHThe expression of capillary rise is given as

2Tcoshgr

Substituting r/cos = R (radius of curvature of the liquid meniscus), we have2ThR Cons tan t

g

Since T, and g are constant, we have hR = C (constant = h0R0 (say), where h = free height of the liquidand R = radius of curvature of free meniscus of liquid.

If we slowly push the capillary tube vertically down (into) the liquid, the height of the liquid columnremains the same till the length of the tube above the liquid surface is equal to 2T cos/(gr) (=h). Therefore,the liquid meniscus gets flatt-ened gradually by increasing its radius of curvature to obey the law hR = constant.It means that hr = h1r1 = h2r2 = .....

When the capillary tube just sinks, i.e., h = 0, we can see that the meniscus becomes flat, radius ofcurvature r a.

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APPLICATIONS OF SURFACE TENSIONCertain applications of surface tension are discussed as follows:1. The wetting property is made use of in detergents and waterproofing. When the detergent materials are

added to liquids, the age of contact decreases and hence the wettability increases. On the other hand,when waterproofing material is added to a fabric, it increases the angle of contact, making the fabricwater-repellant.

2. The antiseptics have very low value of surface tension.The low value of surface tension prevents the formation of drops that may otherwise block the entranceto skin or a wound. Due to low surface tension the antiseptic spreads property over the wound. Thelubricating oils and paints also have low surface tension. So they can spread properly.

3. Surface tension of all lubricating oils and paints is kept low so that they spread over a large area.4. Oil spreads over the surface of water because the surface tension of oil is less than the surface tension of

cold water.5. A rough sea can be calmed by pouring oil on its surface tension of oil is less than the surface tension of

cold water.

PRACTICAL APPLICATIONS OF CAPILLARITY1. The oil in a lamp rises in the wick by capillary action.2. The tip of nib of a pen is split up to make a narrow capillary so that the ink rises up to the tin or nib

continuously.3. Sap and water rise up up to the top of the leaves of the tree by capillary action.4. If one end of the towel dips into a bucket of water and the other end hangs over the bucket the towel

soon becomes wet throughout due to capillary action.5. Ink is absorbed by the blotter due to capillary action.6. Sandy soil is more drier than clay. It is because the capillaries between sand particles are not so fine as

to draw the water up by capillaries.7. The moisture rises in the capillaries of soil to the surface, where it evaporates. To preserve the moisture

in the soil, capillaries must be broken up. This is done by ploughing and levelling the fields.8. Bricks are porous and behave like capillaries.

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the property of viscosity is seen in the following ... · glycerine, etc., have a larger viscosity...

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