the role of process integration in the ghg and haze/smog ... · 1990 – 2004. centre for process...

97
The role of Process Integration in the GHG and Haze/Smog Emissions Reduction Jiří Jaromír Klemeš, Yee Van Fan, Petar Sabev Varbanov Sustainable Process Integration Laboratory (SPIL), NETME CENTRE, Brno University of Technology, VUT – Brno, Czech Republic

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Page 1: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

The role of Process Integration in the GHG and HazeSmog

Emissions Reduction

Jiřiacute Jaromiacuter Klemeš Yee Van Fan Petar Sabev VarbanovSustainable Process Integration Laboratory (SPIL) NETME CENTRE Brno

University of Technology VUT ndash Brno Czech Republic

The RouteUnited Kingdomrarr Hungary rarr Czech Republic

Edinburgh

Manchester

Brno

BudapestVeszprem

UMIST ndash Pioneering Pinch AnalysisDepartment of Process Integration at UMIST

1990 ndash 2004

Centre for Process Integration and Intensification - CPI2

University of Pannonia Hungary

PhD and Graduates

Dr Anja Kostevšek Jun Yow Yong楊俊耀

Dr Wan NorlindaRoshana bt Mohd Nawi

Dr Xia Liu刘 霞

Dr Luca De Benedetto

SUMMA CUM LAUDE

DDr Hon Loong Lam

林汉龙SUMMA CUM LAUDE

Dr Laacuteszloacute SikosSUMMA CUM LAUDE

Dr Zsoacutefia FodorCUM LAUDE

Dr Kew Hong Chew

周桂凤DEANS AWARD

BEST PhD

Dr Peng Yen Liew

廖炳彥UTM CHANCELLOR AWARD - BEST PhD

Dr Lidija ČučekSUMMA CUM LAUDE

DDr Andreja NemetCUM LAUDE

Dr Nor Erniza BtMohammad Rozali

UTM PRO-CHANCELLOR

AWARD

Prof Jiřiacute KlemešCPI2 Head

Dr Petar VarbanovCPI2 Deputy Head

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Ir Dr Sharifah RafidahWan Alwi

Prof ZainuddinAbdul Manan

Universiti Teknologi Malaysia

Prof Yu Qian钱 宇

South China University of Technology

Dr SiYu Yang杨思宇

Brno

Mahen Theatre

Petrov

Freedom Square

Vegetable Market

View of Brno

Spilberk Castle

Old Town Hall + Information centre

Jošt horse statue

Tramvaj-Christmas market

HodyTraditional Moravian Celebration

Punkva Caves

Morzart Statue and Reduta theatre

The second largest city of Czech Republic

6

Sustainable Process Integration Laboratory (SPIL)

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Prof Ferenc Friedler

PPKE BudapestHungary

Prof Zainuddin Abd Manan

Universiti Teknologi Malaysia

Prof Chew Tin Lee

Universiti Teknologi Malaysia

Prof Zhiyong Liu刘智勇教授

Hebei University of TechnologyTianjin PR China

Prof Robin Smith

The University of ManchesterUK

Prof Sharifah Rafidah Wan Alwi

Universiti Teknologi Malaysia

Prof Yutao Wang王玉涛教授

Fudan UniversityShanghai PR China

Prof Michael Walmsley

The University of WaikatoHamilton New Zealand

Prof Dr Jiřiacute Jaromiacuter KlemešSPIL Head

Dr Lubomiacuter KlimešJunior Researcher

Michal ŠpilaacutečekJunior Researcher

Xuexiu Jia 贾学秀

Junior Researcher

Collaborators

Assoc Prof Dr Petar Sabev VarbanovSPIL Deputy Head

Dr Šaacuterka ZemanovaacuteAssistant to Prof Klemeš

Assoc Prof Dr Jiřiacute PospiacutešilSenior Researcher

Assoc Prof DrTimothy Gordon Walmsley

Researcher

Dr Martin PavlasSenior Researcher

Dr AbdoulmohammadGholamzadeh Chofreh

Researcher

Prof Qiuwang Wang王秋旺教授

Xian Jiaotong UniversityXirsquoan PR China

Dr Radovan ŠomplaacutekJunior Researcher

Dr Vojtěch TurekJunior Researcher

Xuechao Wang 王雪超

Junior Researcher

Yee Van Fan 范忆雯

Junior Researcher

Hon Huin Chin钱汉轩

Junior Researcher

Prof Raymond Tan

De La Salle University Philippines

Dr Kathleen Aviso

De La Salle University Philippines

Prof Olga Petrivna

ArsenyevaNational Technical University Kharkiv

Ukraine

Prof Petro Oleksiyovich

KapustenkoNational TechnicalUniversity Kharkiv

UkraineLimei Gai盖丽梅

Junior Researcher

Assoc Prof Dr Yiming Wu

Prof Dr Jiřiacute Jaromiacuter Klemeš DScProject Coordinator (VUT)

Xue-Chao Wang王雪超

Researcher

Hon Huin Chin钱汉轩

Researcher

Ing Milan HemzalCoordinating Researcher

Dr Šaacuterka ZemanovaacuteAssistant of Prof Klemeš

Assoc Prof Dr Petar Sabev Varbanov

Project Manager

Bohong Wang王博弘

Researcher

Dr Feybi Ariani GoniResearcher

Eng Jan Hanus

Prof Dr Petr Stehliacutek

Eng Viacutet Freisleben

Prof Min ZengProject Coordinator (XJTU)

Assoc Prof Dr Ting Ma

Xuan Tong Nianqi Li Wei Li Pengbo Zhao Chaodong Jian

Prof Weisheng Yang

Dr Xia Liu Prof Laibing He

Eng Yi Guo Eng De Pan Eng Peng Zhao

CZ-CN INTER-ACTION Project

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 2: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

The RouteUnited Kingdomrarr Hungary rarr Czech Republic

Edinburgh

Manchester

Brno

BudapestVeszprem

UMIST ndash Pioneering Pinch AnalysisDepartment of Process Integration at UMIST

1990 ndash 2004

Centre for Process Integration and Intensification - CPI2

University of Pannonia Hungary

PhD and Graduates

Dr Anja Kostevšek Jun Yow Yong楊俊耀

Dr Wan NorlindaRoshana bt Mohd Nawi

Dr Xia Liu刘 霞

Dr Luca De Benedetto

SUMMA CUM LAUDE

DDr Hon Loong Lam

林汉龙SUMMA CUM LAUDE

Dr Laacuteszloacute SikosSUMMA CUM LAUDE

Dr Zsoacutefia FodorCUM LAUDE

Dr Kew Hong Chew

周桂凤DEANS AWARD

BEST PhD

Dr Peng Yen Liew

廖炳彥UTM CHANCELLOR AWARD - BEST PhD

Dr Lidija ČučekSUMMA CUM LAUDE

DDr Andreja NemetCUM LAUDE

Dr Nor Erniza BtMohammad Rozali

UTM PRO-CHANCELLOR

AWARD

Prof Jiřiacute KlemešCPI2 Head

Dr Petar VarbanovCPI2 Deputy Head

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Ir Dr Sharifah RafidahWan Alwi

Prof ZainuddinAbdul Manan

Universiti Teknologi Malaysia

Prof Yu Qian钱 宇

South China University of Technology

Dr SiYu Yang杨思宇

Brno

Mahen Theatre

Petrov

Freedom Square

Vegetable Market

View of Brno

Spilberk Castle

Old Town Hall + Information centre

Jošt horse statue

Tramvaj-Christmas market

HodyTraditional Moravian Celebration

Punkva Caves

Morzart Statue and Reduta theatre

The second largest city of Czech Republic

6

Sustainable Process Integration Laboratory (SPIL)

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Prof Ferenc Friedler

PPKE BudapestHungary

Prof Zainuddin Abd Manan

Universiti Teknologi Malaysia

Prof Chew Tin Lee

Universiti Teknologi Malaysia

Prof Zhiyong Liu刘智勇教授

Hebei University of TechnologyTianjin PR China

Prof Robin Smith

The University of ManchesterUK

Prof Sharifah Rafidah Wan Alwi

Universiti Teknologi Malaysia

Prof Yutao Wang王玉涛教授

Fudan UniversityShanghai PR China

Prof Michael Walmsley

The University of WaikatoHamilton New Zealand

Prof Dr Jiřiacute Jaromiacuter KlemešSPIL Head

Dr Lubomiacuter KlimešJunior Researcher

Michal ŠpilaacutečekJunior Researcher

Xuexiu Jia 贾学秀

Junior Researcher

Collaborators

Assoc Prof Dr Petar Sabev VarbanovSPIL Deputy Head

Dr Šaacuterka ZemanovaacuteAssistant to Prof Klemeš

Assoc Prof Dr Jiřiacute PospiacutešilSenior Researcher

Assoc Prof DrTimothy Gordon Walmsley

Researcher

Dr Martin PavlasSenior Researcher

Dr AbdoulmohammadGholamzadeh Chofreh

Researcher

Prof Qiuwang Wang王秋旺教授

Xian Jiaotong UniversityXirsquoan PR China

Dr Radovan ŠomplaacutekJunior Researcher

Dr Vojtěch TurekJunior Researcher

Xuechao Wang 王雪超

Junior Researcher

Yee Van Fan 范忆雯

Junior Researcher

Hon Huin Chin钱汉轩

Junior Researcher

Prof Raymond Tan

De La Salle University Philippines

Dr Kathleen Aviso

De La Salle University Philippines

Prof Olga Petrivna

ArsenyevaNational Technical University Kharkiv

Ukraine

Prof Petro Oleksiyovich

KapustenkoNational TechnicalUniversity Kharkiv

UkraineLimei Gai盖丽梅

Junior Researcher

Assoc Prof Dr Yiming Wu

Prof Dr Jiřiacute Jaromiacuter Klemeš DScProject Coordinator (VUT)

Xue-Chao Wang王雪超

Researcher

Hon Huin Chin钱汉轩

Researcher

Ing Milan HemzalCoordinating Researcher

Dr Šaacuterka ZemanovaacuteAssistant of Prof Klemeš

Assoc Prof Dr Petar Sabev Varbanov

Project Manager

Bohong Wang王博弘

Researcher

Dr Feybi Ariani GoniResearcher

Eng Jan Hanus

Prof Dr Petr Stehliacutek

Eng Viacutet Freisleben

Prof Min ZengProject Coordinator (XJTU)

Assoc Prof Dr Ting Ma

Xuan Tong Nianqi Li Wei Li Pengbo Zhao Chaodong Jian

Prof Weisheng Yang

Dr Xia Liu Prof Laibing He

Eng Yi Guo Eng De Pan Eng Peng Zhao

CZ-CN INTER-ACTION Project

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 3: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

UMIST ndash Pioneering Pinch AnalysisDepartment of Process Integration at UMIST

1990 ndash 2004

Centre for Process Integration and Intensification - CPI2

University of Pannonia Hungary

PhD and Graduates

Dr Anja Kostevšek Jun Yow Yong楊俊耀

Dr Wan NorlindaRoshana bt Mohd Nawi

Dr Xia Liu刘 霞

Dr Luca De Benedetto

SUMMA CUM LAUDE

DDr Hon Loong Lam

林汉龙SUMMA CUM LAUDE

Dr Laacuteszloacute SikosSUMMA CUM LAUDE

Dr Zsoacutefia FodorCUM LAUDE

Dr Kew Hong Chew

周桂凤DEANS AWARD

BEST PhD

Dr Peng Yen Liew

廖炳彥UTM CHANCELLOR AWARD - BEST PhD

Dr Lidija ČučekSUMMA CUM LAUDE

DDr Andreja NemetCUM LAUDE

Dr Nor Erniza BtMohammad Rozali

UTM PRO-CHANCELLOR

AWARD

Prof Jiřiacute KlemešCPI2 Head

Dr Petar VarbanovCPI2 Deputy Head

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Ir Dr Sharifah RafidahWan Alwi

Prof ZainuddinAbdul Manan

Universiti Teknologi Malaysia

Prof Yu Qian钱 宇

South China University of Technology

Dr SiYu Yang杨思宇

Brno

Mahen Theatre

Petrov

Freedom Square

Vegetable Market

View of Brno

Spilberk Castle

Old Town Hall + Information centre

Jošt horse statue

Tramvaj-Christmas market

HodyTraditional Moravian Celebration

Punkva Caves

Morzart Statue and Reduta theatre

The second largest city of Czech Republic

6

Sustainable Process Integration Laboratory (SPIL)

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Prof Ferenc Friedler

PPKE BudapestHungary

Prof Zainuddin Abd Manan

Universiti Teknologi Malaysia

Prof Chew Tin Lee

Universiti Teknologi Malaysia

Prof Zhiyong Liu刘智勇教授

Hebei University of TechnologyTianjin PR China

Prof Robin Smith

The University of ManchesterUK

Prof Sharifah Rafidah Wan Alwi

Universiti Teknologi Malaysia

Prof Yutao Wang王玉涛教授

Fudan UniversityShanghai PR China

Prof Michael Walmsley

The University of WaikatoHamilton New Zealand

Prof Dr Jiřiacute Jaromiacuter KlemešSPIL Head

Dr Lubomiacuter KlimešJunior Researcher

Michal ŠpilaacutečekJunior Researcher

Xuexiu Jia 贾学秀

Junior Researcher

Collaborators

Assoc Prof Dr Petar Sabev VarbanovSPIL Deputy Head

Dr Šaacuterka ZemanovaacuteAssistant to Prof Klemeš

Assoc Prof Dr Jiřiacute PospiacutešilSenior Researcher

Assoc Prof DrTimothy Gordon Walmsley

Researcher

Dr Martin PavlasSenior Researcher

Dr AbdoulmohammadGholamzadeh Chofreh

Researcher

Prof Qiuwang Wang王秋旺教授

Xian Jiaotong UniversityXirsquoan PR China

Dr Radovan ŠomplaacutekJunior Researcher

Dr Vojtěch TurekJunior Researcher

Xuechao Wang 王雪超

Junior Researcher

Yee Van Fan 范忆雯

Junior Researcher

Hon Huin Chin钱汉轩

Junior Researcher

Prof Raymond Tan

De La Salle University Philippines

Dr Kathleen Aviso

De La Salle University Philippines

Prof Olga Petrivna

ArsenyevaNational Technical University Kharkiv

Ukraine

Prof Petro Oleksiyovich

KapustenkoNational TechnicalUniversity Kharkiv

UkraineLimei Gai盖丽梅

Junior Researcher

Assoc Prof Dr Yiming Wu

Prof Dr Jiřiacute Jaromiacuter Klemeš DScProject Coordinator (VUT)

Xue-Chao Wang王雪超

Researcher

Hon Huin Chin钱汉轩

Researcher

Ing Milan HemzalCoordinating Researcher

Dr Šaacuterka ZemanovaacuteAssistant of Prof Klemeš

Assoc Prof Dr Petar Sabev Varbanov

Project Manager

Bohong Wang王博弘

Researcher

Dr Feybi Ariani GoniResearcher

Eng Jan Hanus

Prof Dr Petr Stehliacutek

Eng Viacutet Freisleben

Prof Min ZengProject Coordinator (XJTU)

Assoc Prof Dr Ting Ma

Xuan Tong Nianqi Li Wei Li Pengbo Zhao Chaodong Jian

Prof Weisheng Yang

Dr Xia Liu Prof Laibing He

Eng Yi Guo Eng De Pan Eng Peng Zhao

CZ-CN INTER-ACTION Project

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 4: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Centre for Process Integration and Intensification - CPI2

University of Pannonia Hungary

PhD and Graduates

Dr Anja Kostevšek Jun Yow Yong楊俊耀

Dr Wan NorlindaRoshana bt Mohd Nawi

Dr Xia Liu刘 霞

Dr Luca De Benedetto

SUMMA CUM LAUDE

DDr Hon Loong Lam

林汉龙SUMMA CUM LAUDE

Dr Laacuteszloacute SikosSUMMA CUM LAUDE

Dr Zsoacutefia FodorCUM LAUDE

Dr Kew Hong Chew

周桂凤DEANS AWARD

BEST PhD

Dr Peng Yen Liew

廖炳彥UTM CHANCELLOR AWARD - BEST PhD

Dr Lidija ČučekSUMMA CUM LAUDE

DDr Andreja NemetCUM LAUDE

Dr Nor Erniza BtMohammad Rozali

UTM PRO-CHANCELLOR

AWARD

Prof Jiřiacute KlemešCPI2 Head

Dr Petar VarbanovCPI2 Deputy Head

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Ir Dr Sharifah RafidahWan Alwi

Prof ZainuddinAbdul Manan

Universiti Teknologi Malaysia

Prof Yu Qian钱 宇

South China University of Technology

Dr SiYu Yang杨思宇

Brno

Mahen Theatre

Petrov

Freedom Square

Vegetable Market

View of Brno

Spilberk Castle

Old Town Hall + Information centre

Jošt horse statue

Tramvaj-Christmas market

HodyTraditional Moravian Celebration

Punkva Caves

Morzart Statue and Reduta theatre

The second largest city of Czech Republic

6

Sustainable Process Integration Laboratory (SPIL)

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Prof Ferenc Friedler

PPKE BudapestHungary

Prof Zainuddin Abd Manan

Universiti Teknologi Malaysia

Prof Chew Tin Lee

Universiti Teknologi Malaysia

Prof Zhiyong Liu刘智勇教授

Hebei University of TechnologyTianjin PR China

Prof Robin Smith

The University of ManchesterUK

Prof Sharifah Rafidah Wan Alwi

Universiti Teknologi Malaysia

Prof Yutao Wang王玉涛教授

Fudan UniversityShanghai PR China

Prof Michael Walmsley

The University of WaikatoHamilton New Zealand

Prof Dr Jiřiacute Jaromiacuter KlemešSPIL Head

Dr Lubomiacuter KlimešJunior Researcher

Michal ŠpilaacutečekJunior Researcher

Xuexiu Jia 贾学秀

Junior Researcher

Collaborators

Assoc Prof Dr Petar Sabev VarbanovSPIL Deputy Head

Dr Šaacuterka ZemanovaacuteAssistant to Prof Klemeš

Assoc Prof Dr Jiřiacute PospiacutešilSenior Researcher

Assoc Prof DrTimothy Gordon Walmsley

Researcher

Dr Martin PavlasSenior Researcher

Dr AbdoulmohammadGholamzadeh Chofreh

Researcher

Prof Qiuwang Wang王秋旺教授

Xian Jiaotong UniversityXirsquoan PR China

Dr Radovan ŠomplaacutekJunior Researcher

Dr Vojtěch TurekJunior Researcher

Xuechao Wang 王雪超

Junior Researcher

Yee Van Fan 范忆雯

Junior Researcher

Hon Huin Chin钱汉轩

Junior Researcher

Prof Raymond Tan

De La Salle University Philippines

Dr Kathleen Aviso

De La Salle University Philippines

Prof Olga Petrivna

ArsenyevaNational Technical University Kharkiv

Ukraine

Prof Petro Oleksiyovich

KapustenkoNational TechnicalUniversity Kharkiv

UkraineLimei Gai盖丽梅

Junior Researcher

Assoc Prof Dr Yiming Wu

Prof Dr Jiřiacute Jaromiacuter Klemeš DScProject Coordinator (VUT)

Xue-Chao Wang王雪超

Researcher

Hon Huin Chin钱汉轩

Researcher

Ing Milan HemzalCoordinating Researcher

Dr Šaacuterka ZemanovaacuteAssistant of Prof Klemeš

Assoc Prof Dr Petar Sabev Varbanov

Project Manager

Bohong Wang王博弘

Researcher

Dr Feybi Ariani GoniResearcher

Eng Jan Hanus

Prof Dr Petr Stehliacutek

Eng Viacutet Freisleben

Prof Min ZengProject Coordinator (XJTU)

Assoc Prof Dr Ting Ma

Xuan Tong Nianqi Li Wei Li Pengbo Zhao Chaodong Jian

Prof Weisheng Yang

Dr Xia Liu Prof Laibing He

Eng Yi Guo Eng De Pan Eng Peng Zhao

CZ-CN INTER-ACTION Project

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 5: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Brno

Mahen Theatre

Petrov

Freedom Square

Vegetable Market

View of Brno

Spilberk Castle

Old Town Hall + Information centre

Jošt horse statue

Tramvaj-Christmas market

HodyTraditional Moravian Celebration

Punkva Caves

Morzart Statue and Reduta theatre

The second largest city of Czech Republic

6

Sustainable Process Integration Laboratory (SPIL)

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Prof Ferenc Friedler

PPKE BudapestHungary

Prof Zainuddin Abd Manan

Universiti Teknologi Malaysia

Prof Chew Tin Lee

Universiti Teknologi Malaysia

Prof Zhiyong Liu刘智勇教授

Hebei University of TechnologyTianjin PR China

Prof Robin Smith

The University of ManchesterUK

Prof Sharifah Rafidah Wan Alwi

Universiti Teknologi Malaysia

Prof Yutao Wang王玉涛教授

Fudan UniversityShanghai PR China

Prof Michael Walmsley

The University of WaikatoHamilton New Zealand

Prof Dr Jiřiacute Jaromiacuter KlemešSPIL Head

Dr Lubomiacuter KlimešJunior Researcher

Michal ŠpilaacutečekJunior Researcher

Xuexiu Jia 贾学秀

Junior Researcher

Collaborators

Assoc Prof Dr Petar Sabev VarbanovSPIL Deputy Head

Dr Šaacuterka ZemanovaacuteAssistant to Prof Klemeš

Assoc Prof Dr Jiřiacute PospiacutešilSenior Researcher

Assoc Prof DrTimothy Gordon Walmsley

Researcher

Dr Martin PavlasSenior Researcher

Dr AbdoulmohammadGholamzadeh Chofreh

Researcher

Prof Qiuwang Wang王秋旺教授

Xian Jiaotong UniversityXirsquoan PR China

Dr Radovan ŠomplaacutekJunior Researcher

Dr Vojtěch TurekJunior Researcher

Xuechao Wang 王雪超

Junior Researcher

Yee Van Fan 范忆雯

Junior Researcher

Hon Huin Chin钱汉轩

Junior Researcher

Prof Raymond Tan

De La Salle University Philippines

Dr Kathleen Aviso

De La Salle University Philippines

Prof Olga Petrivna

ArsenyevaNational Technical University Kharkiv

Ukraine

Prof Petro Oleksiyovich

KapustenkoNational TechnicalUniversity Kharkiv

UkraineLimei Gai盖丽梅

Junior Researcher

Assoc Prof Dr Yiming Wu

Prof Dr Jiřiacute Jaromiacuter Klemeš DScProject Coordinator (VUT)

Xue-Chao Wang王雪超

Researcher

Hon Huin Chin钱汉轩

Researcher

Ing Milan HemzalCoordinating Researcher

Dr Šaacuterka ZemanovaacuteAssistant of Prof Klemeš

Assoc Prof Dr Petar Sabev Varbanov

Project Manager

Bohong Wang王博弘

Researcher

Dr Feybi Ariani GoniResearcher

Eng Jan Hanus

Prof Dr Petr Stehliacutek

Eng Viacutet Freisleben

Prof Min ZengProject Coordinator (XJTU)

Assoc Prof Dr Ting Ma

Xuan Tong Nianqi Li Wei Li Pengbo Zhao Chaodong Jian

Prof Weisheng Yang

Dr Xia Liu Prof Laibing He

Eng Yi Guo Eng De Pan Eng Peng Zhao

CZ-CN INTER-ACTION Project

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 6: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

6

Sustainable Process Integration Laboratory (SPIL)

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Prof Ferenc Friedler

PPKE BudapestHungary

Prof Zainuddin Abd Manan

Universiti Teknologi Malaysia

Prof Chew Tin Lee

Universiti Teknologi Malaysia

Prof Zhiyong Liu刘智勇教授

Hebei University of TechnologyTianjin PR China

Prof Robin Smith

The University of ManchesterUK

Prof Sharifah Rafidah Wan Alwi

Universiti Teknologi Malaysia

Prof Yutao Wang王玉涛教授

Fudan UniversityShanghai PR China

Prof Michael Walmsley

The University of WaikatoHamilton New Zealand

Prof Dr Jiřiacute Jaromiacuter KlemešSPIL Head

Dr Lubomiacuter KlimešJunior Researcher

Michal ŠpilaacutečekJunior Researcher

Xuexiu Jia 贾学秀

Junior Researcher

Collaborators

Assoc Prof Dr Petar Sabev VarbanovSPIL Deputy Head

Dr Šaacuterka ZemanovaacuteAssistant to Prof Klemeš

Assoc Prof Dr Jiřiacute PospiacutešilSenior Researcher

Assoc Prof DrTimothy Gordon Walmsley

Researcher

Dr Martin PavlasSenior Researcher

Dr AbdoulmohammadGholamzadeh Chofreh

Researcher

Prof Qiuwang Wang王秋旺教授

Xian Jiaotong UniversityXirsquoan PR China

Dr Radovan ŠomplaacutekJunior Researcher

Dr Vojtěch TurekJunior Researcher

Xuechao Wang 王雪超

Junior Researcher

Yee Van Fan 范忆雯

Junior Researcher

Hon Huin Chin钱汉轩

Junior Researcher

Prof Raymond Tan

De La Salle University Philippines

Dr Kathleen Aviso

De La Salle University Philippines

Prof Olga Petrivna

ArsenyevaNational Technical University Kharkiv

Ukraine

Prof Petro Oleksiyovich

KapustenkoNational TechnicalUniversity Kharkiv

UkraineLimei Gai盖丽梅

Junior Researcher

Assoc Prof Dr Yiming Wu

Prof Dr Jiřiacute Jaromiacuter Klemeš DScProject Coordinator (VUT)

Xue-Chao Wang王雪超

Researcher

Hon Huin Chin钱汉轩

Researcher

Ing Milan HemzalCoordinating Researcher

Dr Šaacuterka ZemanovaacuteAssistant of Prof Klemeš

Assoc Prof Dr Petar Sabev Varbanov

Project Manager

Bohong Wang王博弘

Researcher

Dr Feybi Ariani GoniResearcher

Eng Jan Hanus

Prof Dr Petr Stehliacutek

Eng Viacutet Freisleben

Prof Min ZengProject Coordinator (XJTU)

Assoc Prof Dr Ting Ma

Xuan Tong Nianqi Li Wei Li Pengbo Zhao Chaodong Jian

Prof Weisheng Yang

Dr Xia Liu Prof Laibing He

Eng Yi Guo Eng De Pan Eng Peng Zhao

CZ-CN INTER-ACTION Project

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 7: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Sustainable Process Integration Laboratory (SPIL)

Prof Zdravko KravanjaUniversity of Maribor

Slovenia

Prof Ferenc Friedler

PPKE BudapestHungary

Prof Zainuddin Abd Manan

Universiti Teknologi Malaysia

Prof Chew Tin Lee

Universiti Teknologi Malaysia

Prof Zhiyong Liu刘智勇教授

Hebei University of TechnologyTianjin PR China

Prof Robin Smith

The University of ManchesterUK

Prof Sharifah Rafidah Wan Alwi

Universiti Teknologi Malaysia

Prof Yutao Wang王玉涛教授

Fudan UniversityShanghai PR China

Prof Michael Walmsley

The University of WaikatoHamilton New Zealand

Prof Dr Jiřiacute Jaromiacuter KlemešSPIL Head

Dr Lubomiacuter KlimešJunior Researcher

Michal ŠpilaacutečekJunior Researcher

Xuexiu Jia 贾学秀

Junior Researcher

Collaborators

Assoc Prof Dr Petar Sabev VarbanovSPIL Deputy Head

Dr Šaacuterka ZemanovaacuteAssistant to Prof Klemeš

Assoc Prof Dr Jiřiacute PospiacutešilSenior Researcher

Assoc Prof DrTimothy Gordon Walmsley

Researcher

Dr Martin PavlasSenior Researcher

Dr AbdoulmohammadGholamzadeh Chofreh

Researcher

Prof Qiuwang Wang王秋旺教授

Xian Jiaotong UniversityXirsquoan PR China

Dr Radovan ŠomplaacutekJunior Researcher

Dr Vojtěch TurekJunior Researcher

Xuechao Wang 王雪超

Junior Researcher

Yee Van Fan 范忆雯

Junior Researcher

Hon Huin Chin钱汉轩

Junior Researcher

Prof Raymond Tan

De La Salle University Philippines

Dr Kathleen Aviso

De La Salle University Philippines

Prof Olga Petrivna

ArsenyevaNational Technical University Kharkiv

Ukraine

Prof Petro Oleksiyovich

KapustenkoNational TechnicalUniversity Kharkiv

UkraineLimei Gai盖丽梅

Junior Researcher

Assoc Prof Dr Yiming Wu

Prof Dr Jiřiacute Jaromiacuter Klemeš DScProject Coordinator (VUT)

Xue-Chao Wang王雪超

Researcher

Hon Huin Chin钱汉轩

Researcher

Ing Milan HemzalCoordinating Researcher

Dr Šaacuterka ZemanovaacuteAssistant of Prof Klemeš

Assoc Prof Dr Petar Sabev Varbanov

Project Manager

Bohong Wang王博弘

Researcher

Dr Feybi Ariani GoniResearcher

Eng Jan Hanus

Prof Dr Petr Stehliacutek

Eng Viacutet Freisleben

Prof Min ZengProject Coordinator (XJTU)

Assoc Prof Dr Ting Ma

Xuan Tong Nianqi Li Wei Li Pengbo Zhao Chaodong Jian

Prof Weisheng Yang

Dr Xia Liu Prof Laibing He

Eng Yi Guo Eng De Pan Eng Peng Zhao

CZ-CN INTER-ACTION Project

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 8: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Assoc Prof Dr Yiming Wu

Prof Dr Jiřiacute Jaromiacuter Klemeš DScProject Coordinator (VUT)

Xue-Chao Wang王雪超

Researcher

Hon Huin Chin钱汉轩

Researcher

Ing Milan HemzalCoordinating Researcher

Dr Šaacuterka ZemanovaacuteAssistant of Prof Klemeš

Assoc Prof Dr Petar Sabev Varbanov

Project Manager

Bohong Wang王博弘

Researcher

Dr Feybi Ariani GoniResearcher

Eng Jan Hanus

Prof Dr Petr Stehliacutek

Eng Viacutet Freisleben

Prof Min ZengProject Coordinator (XJTU)

Assoc Prof Dr Ting Ma

Xuan Tong Nianqi Li Wei Li Pengbo Zhao Chaodong Jian

Prof Weisheng Yang

Dr Xia Liu Prof Laibing He

Eng Yi Guo Eng De Pan Eng Peng Zhao

CZ-CN INTER-ACTION Project

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 9: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Cooperation with Foreign Universities

SLOVENIAUKHUNGARY

CHINA (HeBei)

NEW ZEALAND

CHINA (Fudan)

MALAYSIA

CHINA (Xirsquoan)

PHILIPPINES

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 10: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Google Scholar

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 11: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Mendeley

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 12: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Speed up research by harnessing the power of peer review

98th Percentile

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 13: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Currently serves on 20 editorial boardsTotally serves on 25 editorial boards

Editor-in-Chief President

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 14: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Has reviewed for 106 journals

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 15: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

High Citations Papers

Web of Sciencehttpappswebofknowledgecom

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 16: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Journal of Cleaner Production

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 17: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

17

JCLP Co-Editors-in-Chief

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 18: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

18

JCLP Impact

Total Articles

Total Cites

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 19: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

19

JCLP ndash Contributors

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 20: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

20

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 21: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Main Co-Authors of this lectureS Bandyopadhyay Indian Institute of Technology INCY Chang National Cheng Kung University Tainan TPQ Wang X Feng Xirsquoan Jiaotong Univ ampChina Univ of Petroleum I E Grossmann Carnegie Mellon University Pittsburgh PA UST Gundersen NUST Trondheim Norway NOJ-K Kim Hanyang University Seoul KRH Matos Instituto Superior TeacutecnicoUniversidade de Lisboa PTT Majozi University of the Witwatersrand Johannesburg ZAF Mareacutechal EacutePFL Lausanne Sion CHHL Lam D Ng D C Y Foo Uni of Nottingham MY Campus KL Panjeshahi N Tahouni University of Tehran IR M Picoacuten-Nuacutentildeez University of Guanajuato Mexico MXSR Wan Alvi Z A Manan UTM Johor Bahru amp KLCC MYU Shenoy Synew Technologies Mumbai INR Smith I Bulatov UMIST amp The University of Manchester UKR Tan K Aviso University De La Salle Manila PHM Walmsley University of Waikato Hamilton NZT Zhelev dagger University of Limerick IR

21

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 22: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

World Coverage Co-Authors

22

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 23: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Heat Integration using Pinch Analysis

23

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 24: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

UMIST History

1824 Created by industrialists as the Manchester Mechanics Institution

1905 Faculty of Technology University of Manchester

1956 Royal Charter granted to Manchester College of Science and Technology

1965 University of Manchester Institute of Science and Technology

image1wmf

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 25: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

The First Steps ndash HEN synthesisPinch Analysis Hohmann E C 1971 Optimum networks for heat exchange PhD thesis University of Southern California LA USALinnhoff B Flower JR 1978 Synthesis of heat exchanger networks I Systematic generation of energy optimal networks AIChE Journal 24(4) 633ndash642Umeda T Harada T Shiroko KA 1979 Thermodynamic approach to the synthesis of heat integration systems in chemical processes Computers amp Chemical Engineering 3(1-4) 273ndash282

Heuristic methodsPonton J W Donaldson R A B 1974 A fast method for the synthesis of optimal heat exchanger networks ChemEngSci 29 2375-2377 (1974)

Mathematical programing Papoulias SA Grossmann IE1983 A structural optimization approach in process synthesis-II Heat recovery networks CompChemEng 7 (6) 707-721Yee TF Grossmann IE1990 Optimization models for heat integrationmdashII Heat exchanger network synthesis ComputChemEng 14 1165ndash1184

25

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 26: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

The Roots of Pinch Analysis

bull Hohmann E C (1971) Optimum networks for heat exchange PhD thesis University of Southern California Los Angeles USA

bull Linnhoff B (1972) Thermodynamic analysis of the cement burning process (Thermodynamische Analyse des Zementbrennprozesses) Diploma work Abteilung IIIa ETH Zurich (1972) (in German)

bull Hohmann E C Lockhart F J (1976) Optimum heat exchanger network synthesis AIChE 82nd National Meeting Atlantic City NJ USA Paper No 22a

26

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 27: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

The ldquoRed Bookrdquo27

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 28: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

SPIL VUT Brno 2 May 2018Prof Bodo Linnhoff Pioneer of Pinch Analysis

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 29: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

What is Process (Heat) Integration

29

A family of methodologies for combining several processes to reduce consumption of resources andor harmful emissions to the environment

It started as Heat Integration stimulated by the energy crisis in the 1970s

Definition of Process Integration by IEASystematic and General Methods for Designing Integrated Production Systems ranging from Individual Processes to Total Sites with special emphasis on the Efficient Use of Energy and reducing Environmental Effects

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 30: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Pinch based approach

T

H (Enthapy)

QH

QC

Hot Composite Curve

Cold Composite Curve

Complicated Flowsheet Simple Diagram

Composite Curves

Pinch

30

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 31: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Mathematical Programming OR Pinch

31

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 32: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Pinch AND Mathematical Programming

32

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 33: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Benefits of Process Integration

33

Heat Integration roots

minus Identify heat recovery targets and aid in synthesizingmaximum heat recovery systems

minus Minimise utility demands and CO2 emissions of a process

Minimisation of resource consumption

minus Total Sites Optimisationminus Supply Chainsminus Optimal time scheduling and tracking

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 34: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

34

Research Consortium MembersPresent and Past Members

Air Products - USAAspen UK Ltd - UKBOC - UKBP Amoco - UKCanmet - CanadaChinese Petroleum Corp - TaiwanDegussa - GermanyEngineers India - IndiaExxonMobil - USAInstitut Francais du Petrole - FranceITRI - TaiwanJGC Corporation - JapanLinnhoff March KCB - UK USMitsubishi Chemical Co - Japan

MW Kellogg - UK USNorsk Hydro - NorwayPetrobras - BrazilUT Petronas - MalaysiaPetrom - RomaniaPowerGen - UKSaudi Aramco - Saudi ArabiaShell Global Solutions - NetherlandsSinopec Tech - ChinaTechnip Benelux - NetherlandsTotal - FrancelsquoPolitechnicarsquo Bucharest - RomaniaUOP - USA UKVito - Belgium

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 35: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Handbook of Process Integration (PI)Minimisation of energy and water use waste and

emissionsHandbook of Process Integration (PI) Minimisation of energy and water use waste and emissionsEdited by J Klemes University of Pannonia Hungary

Woodhead Publishing Series in Energy No 61

ISBN 0 85709 593 5ISBN-13 978 0 85709 593 0July 20131184 pages 234 x 156mm hardback

ltwwwwoodheadpublishingcomenbookaspxbookID=2687gt

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 36: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Composite Curves - ΔTmin = 10 degC

QCmin = 1000 QREC = 5150 QHmin = 750

H (kW)

T(degC)

250

200

150

100

50

0

Pinch

∆Tmin=10deg

36

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 37: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Pinch Design Principle37

ΔH

PINCH

T

1 Start at the Pinch

2 Then move AWAY

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 38: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Pinch Analysis More in ndash More out

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 Process Integration and IntensificationSaving Energy Water and Resources De Gruyter Berlin Germany 38

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 39: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

A Comprehensive Textbook

PublisherWalter de Gruyter GmbHBerlin GermanyISBN 978-3-11-030685-9

ltwwwdegruytercomviewproduct204103gt

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z 2014 2nd ed 2018 Process Integration and Intensification Saving Energy Water and Resources De Gruyter Berlin Germany

39

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 40: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Pinch Design Method40

PINCH

2

4

1

3

250 ordm40 ordm

200 ordm80 ordm

180 ordm

230 ordm

20 ordm

140 ordm

CPkW bull (ordmC)-1

15

25

20

30

QHmin = 750 kW QCmin = 1000 kW

150 ordm

150 ordm

140 ordm

800 kW

2033 ordm

1817 ordm

700 kW

H205 ordm

750 kW

1750 kW

525 ordm

650 kW

C 1067 ordm

1000 kW

1250 kW

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 41: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Grand Composite Curves41

ΔH (kW)

T [degC]

0

100

300

2000 4000 6000 8000

200

1000

1200

1400

400300

900

750

ΔH (kW)0

T [degC]

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 42: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

The Grand Composite Curve (GCC)

42

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 43: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

CC ndash Sugar and Ethanol Production

43

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 44: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

PA for Integration of Heat Exchanger Networks with Heat

Pumps

Multi-HPs strategy Heat pumps can be set across the new Pinch Point Heat pumps can be used to change the pinch temperature to facilitate

the heat integration of background process with distillation

T

H0

PHP

Q2

Q1

GCC

W

NewGCC

T1

T2

P1

Hpoc H2

QHmin-Hpoc

QCmin-(Q2-(Q1-Hpoc))

H1

New pinch

Pinch

Changes of Pinch Pemperature

T

0

P

QHmin

Qcond

Qreb

QCmin

QC=QCmin+Qcond

QH=QHmin+Qreb

(a)

BPGCC

(b)H0

BPGCC

NewBPGCC

T

Qcond

Qreb

P1

P

Heat integration with distillation

44

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 45: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

45

Tube-side intensification (tube inserts)

HEN retrofit with intensification

hiTRANreg

Coiled Wire

Twisted Tape

Gough M J (2012) Process heat transfer enhancement to upgrade performancethroughput and reduced energy use Chemical Engineering Transactions 29 1-6

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 46: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Intensification of Heat Transfer In Process Industries

Kapustenko P Kukulka D Arsenyeva O 2015 Intensification of heat transfer processes Chemical Engineering Transactions 45 1729-1734 Klemes JJ Arsenyeva O Kapustenko P Tovazhnyanskyy L 2015 Compact heat exchangers for energy transfer intensification low grade heat and fouling mitigation CRC Press Boca Raton FL USA 46

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 47: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

47

000 005 010 015 020 025 030 035 040 045000

005

010

015

020

025

030

035

040

045

f p

redi

cted

f numerical data

+10

-10

+5-5

bull With the increase of Re the Nuincreases while f decreases but the Nu and f change little when the row number is greater than 9

bull Both the Nu and f decrease with the increase of transverse pitch and longitudinal pitch

bull Multiple correlations of Nu and fare fitted

Li L Ma T Xu XY Zeng M Wang QW 2014 Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped Printed Circuit Heat Exchanger Chemical Engineering Transactions 39 895-900

Study on Heat Transfer and Pressure Drop Performances of Airfoil-Shaped

Printed Circuit HE

Airfoil PCHE plate Numerical model

f comparison between predicted and numerical results

10 15 20 25 30 35 40 45 5010

15

20

25

30

35

40

45

50

Nu p

redi

cted

Nu numerical data

+5

-5

Nu comparison between predicted and numerical results

035035 049475 1033682 07264934700654 Re ( ) ( )t l

h lf NP P

minus minus=

010518 0615001 0268556 0155274020756 Re ( ) ( )t l

h lNu NP P

minus=

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 48: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Multi-Stream Heat Exchangers Thermo-hydraulic design of MSHE using GA (based on Pinch) Considering variable physical properties Minimizing the number of sections required for a given duty

Panjeshahi M H Joda F Tahouni N Pressure Drop Optimization in Multi-Stream Heat Exchanger Networksby Genetic Algorithms Chemical Engineering Transactions 21 247-253 2010Tahouni N Miryahyaie S Joda F Fallahi H R Panjeshahi M H Pressure Drop Optimization in Design ofMulti-Stream Plate-Fin Heat Exchangers Considering Variable Physical Properties The Canadian Journal ofChemical Engineering 91 1650-1659 2013

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 49: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Total Site (Site-wide) Integration

49

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 50: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

An Industrial Site

Fuel

Fuel

Fuel PROCESS A PROCESS BFuel

POWER

HIGH PRESS

MED PRESS

LOW PRESS

PROCESS C

COOLING WATER

COND

AirW

Raissi K 1994 Total Site Integration PhD Thesis UMIST Manchester UK

Klemeš J DholeVR Raissi K Perry SJ Puigjaner L 1997 Targeting and Design Methodology for Reduction of Fuel Power and CO2 on Total Sites Applied Thermal Engineering 17(810) 993-1003

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 51: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Maximising Total Site Heat Recovery

51

T

HTotal Site Profiles

Site Source Profile Site Sink ProfileT

Process A

Process B

T H

H

-ΔTmin2 +ΔTmin2T1

T1

T4

T2

T2

T3

T3

T4

T5

T6

T5

T6

T7

T8

T9

T10

T11T12

T7

T8

T9

T10

T11

T12

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 52: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Total Site Profiles52

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 53: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Integrating Renewable Energy Sources into Extended Total Sites

Perry S Klemeš J Bulatov I Chemical Engineering Transactions 12 2007 593-598Perry S Klemeš J Bulatov I Energy 33 1489-1497 2008

53

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 54: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Industrial Implementations of TSHI methodology

a) Oil and Petrochemicalsb) Pulp and Paperc) Low temperature Refrigeration d) Large Utility Hubse) Food and Drinkf) Locally Integrated Energy Systemsg) CHP including Renewablesh) Desalinationi) helliphelliphelliphellipKlemeš JJ (ed) 2013 Handbook of Process Integration (PI) Minimisation of Energy and Water Use Waste

and Emissions WoodheadElsevier Cambridge UK 1184 ps

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 55: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Mass and Water Integration

55

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 56: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Water Pinch The Foundation

C (ppm)

∆m (kgh)2191

50100

400

Pinch Point

800

Limiting Composite Curve

Water supply line

56

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 57: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

57Setting the Water Recovery Target

Minimum fresh resource

Maximum recovery

Minimum waste

discharge

PinchPinch sets

Absolute Limits for

Process Water

Recovery

Cum flowrate(th)

Cum

ulat

ive

load

(kg

h)

Sink Composite

Curve

Source Composite

Curve

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 58: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Decomposing the Pinch Problem

Minimum fresh resource

Minimum waste

discharge

Pinch

Cumulative flowrate (th)

Cum

ulat

ive

load

(kg

h)

Above Pinch Region

Below Pinch Region

Klemeš JJ Varbanov PS Wan Alwi SR Abdul Manan Z (2014) Process Integration and Intensification Saving Energy Water and Resources Series De Gruyter Textbook De Gruyter Berlin Germany

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 59: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Improved Pinch to Target Regeneration ReuseRecycle

Water Networks

0

20

40

60

80

100

120

140

1 2 3 4 5 6 7Cumulative Massload (kgh)

Impu

rity

Con

cent

ratio

n (m

gL)

A

B

C

E G

D

F

J

I

outRC

inRC

H J

K

L

Limiting Composite Curve

Optimal Water Supply Line (Direct Reuse)

Optimal Water Supply Line (Regeneration ReuseRecycle)

Regeneration Process

Regeneration Concentration

Post-Regeneration Concentration

Water Pinch(Direct Reuse)

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

Operation 1

Operation 2

Operation 3

Wastewater Fresh Water

(a) Direct Reuse

(b) Regeneration Reuse

(c) Regeneration Recycle

Regeneration

Regeneration

Optimal regeneration concentration would Equal Less than or Greater than the pinch concentration (Direct Reuse)

59

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 60: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Combined Energy and Water Integration

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 61: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Renewables Integration

61

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 62: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Targeting Time Slice 1

1363 kWh inSTORAGE

bull 12454 kWh MP steambull 15379 kWh Cooling Water

Varbanov P Klemeš J 2010 Total Sites Integrating Renewables with Extended Heat Transfer andRecovery Heat Transfer Engineering 31(9) 733 ndash 741

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 63: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Breakthrough in Energy Storage

ltelectrekco20180511tesla-giant-battery-australia-reduced-grid-service-costgt accessed 19 May 2018

bull 100 MWh lithium ion batterybull Stores huge amounts of energy from renewable sources and funnels it out

to the grid when usage is high

TESLA giant Powerpack battery in Australia

In successful operation for 6 months now

Reduced the cost of the grid service that it performs by 90

Rapid accurate cheaper and with low emissions

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 64: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Assessment and System Design

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 65: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

bull Footprint is a quantitative measure showing theappropriation of natural resources by human beings

Classification of Footprintbull Environmentalbull Socialbull Economical bull Combinedbull Composite

Footprints

Hoekstra A Y 2008 Water neutral Reducing and offsetting the impacts of water footprints Value of Water Research Report Series No 28 UNESCO-IHE Delft the Netherlands

Čuček L Klemeš J J amp Kravanja Z (2012) A review of footprint analysis tools for monitoring impacts on sustainability Journal of Cleaner Production 34 9-20

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 66: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Environmental Footprint

Carbon footprint (CFP)

Nitrogen footprint (NFP)

Water footprint (WFP)

Ecological footprint (ECOFP)

Energy footprint (EFP)

Land footprint (LFP)

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 67: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Virtual GHGs Emissions Flows in the International Trade

1

2

5

6

8

9

47

3

10

375

368

322

175

172238157

149

141

137

1 China to US (Queacutereacute et al 2014) 2 China to EU ( Carbon Trust 2011) 3 China to Rest of Asia (Carbon Trust 2011)5 Russian Federation to EU (Peters et al 2012) 6 China to Japan (Carbon Trust 2011)

4 Rest of Asia to EU (Peters et al 2012)

8 US to EU (Peters et al 2012) 9 Canada to EU (Petar et al 2012)7 Africa to EU (Peters et al 2012)10 EU to US (Petar et al 2012)

Liu X Klemeš J J Varbanov P S Čuček L Qian Y (2017) Virtual carbon and water flows embodied in international trade a review on consumption-based analysis Journal of Cleaner Production 146 20-28

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 68: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

System DesignEngineering ModelProcess Integration (Heat Water CO2 amp GHG Emissions )A strong tool for Circular EconomyHeat Integration roots

bull Identify heat recovery targets and aid in synthesizing maximum heat recovery systems

bull Minimise utility demands and CO2 emissions of a process

bull Minimisation of resource consumption

bull Total Sites Optimisation

bull Supply Chains

bull Optimal time scheduling and tracking

Klemeš JJ Varbanov PV Walmsley TG Jia XX 2018 New directions in the implementation of Pinch Methodology (PM) Renewable and Sustainable Energy Reviews 98 439-468

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 69: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Global Energy Use

Forman C Muritala I K Pardemann R Meyer B (2016) Estimating the global waste heatpotential Renewable and Sustainable Energy Reviews 57 1568-1579

718

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 70: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

ltnewsletterspectatorcoukq122MWckxFYqrhfpswu45wvgt accessed 14 April 2018

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 71: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

CO2 GHG Emission Integration

71

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 72: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

The Total Annual AnthropogenicGHG Emissions

72

(FOLU - Forestry and Other Land Use F-Gases = Fluorinated Gases)

IPCC (Intergovernmental Panel on Climate Change) Developed from Climate Change 2014Synthesis Report Report Graphic IPCC Secretariat World Meteorological Organization Geneva Switzerland

ltwwwipccchreportgraphicsindexphpt=Assessment20Reportsampr=AR520-20Synthesis20Reportampf=Topic 203gt

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 73: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage

Header Geological reservoir storage

S1 S2 S3 S4

D2D1S CO2 SourceD CO2 Demand

Captured CO2 injected into dedicated header along to be utilised in Demands or sent to geological storage

Remaining CO2 captured after utilised are injected into dedicated storage

Mohd Nawi W N R Wan Alwi S R Manan ZA Klemeš J J 2016 Pinch Analysis Targeting for CO2 TotalSite Planning Clean Technologies and Environmental Policy doi 101007s10098-016-1154-7 73

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 74: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Carbon Emissions Pinch Analysis

0

100

200

300

400

500

600

0 50 100 150 200 250 300 350 400

Cum

Mas

s Lo

ad (T

hr)

Cum CO2 Flowrate (Thr)

Demand Composite

Source Composite

D1D2

D3

D4

S1

S2

S3

S4

S5

S6

Pinch

Emitted CO2 = 9917 Thr

Fresh CO2 = 8966 Thr

Typical Gas Pinch Analysis would use lsquoCum Gas Flowratersquo

This mass load correspond to amount of other gases aside from CO2 in the flue gas

Sadiq M M Manan Z A Wan Alwi S R 2012 Holistic Carbon Planning for Industrial Parks - A Waste-to-Resources Process Integration Approach Journal of Cleaner Production 33 74-85

Cum

Mas

s Lo

ad (t

h)

Cum CO2 Flowrate (th)

74

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 75: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Matching of CO2 Sources amp Sinks

5

10

15

0 100

20

25

200 300 400 500 600 700 800 900

Amount of CO2 (Mt)

Sink composite

curve

Flow

rate

of C

O2

Mty

)

250 Mt surplus storage capacity

30

35

40

45

1000 1100

Source composite

curvePinch

125 Mty surplus

injectivity

50 Mt uncaptured CO2

75

Diamante J A R Tan R R Foo D C Y Ng D K S Aviso K B Bandyopadhyay S 2013 A Graphical Approach to Pinch-Based Source-Sink Matching and Sensitivity Analysis in Carbon Capture and Storage Systems Industrial amp Engineering Chemistry Research 52(22) 7211-7222

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 76: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Industrial and Practical Issues

76

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 77: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

77

Process Integration Research and Applications in Industries

PRESrsquo01 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Process integration in coal-tar productionPRESrsquo02 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Heat integration improvement for EasternEuropean sugarPRESrsquo03 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Optimal heat recovery system for coal tardistillationPRESrsquo04 ndash Tovazhnyansky L Kapustenko P Perevertaylenko O Boldyryev SO Garev AO Energy saving retrofitof refrigerating section of dairy factoryPRESrsquo05 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Tarnovsky M 2005 Energy integration of theearly crude oil units with take into account different regimes Chemical Engineering Transactions 7 103-108PRESrsquo06 ndash Kapustenko P Ulyev L Boldyryev S Garev A 2008 Integration of heat pump into the heat supplysystem of cheese production plant Energy 33(6) 882-889PRESrsquo07 ndash Tovazhnyanskyy L Sherstyuk V Kapustenko P Khavin G Perevertaylenko O Boldyrev S Garev A2007 Plate heat exchangers for environmentally friendly heat pumps Chemical Engineering Transactions 12213 217

Results

INDUSTRY Saving PaybackmonthsHeating Cooling

ChemicalTitanium dioxide production 81 89 14

Oil and GasReforming 55 90 10Crude oil distillation 45 55 12

Coke to chemicalsCoal tar distillation 52 67 12Benzene hydrocarbons production 32 12 12

Food and beveragesSugar production 17 32 4Cheese production (cooling cycle HWS) 100 64 10Vegetable oils purification 67 71 5Ethanol production 13 36 11

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT YlaquoKHPIraquo

AO SODRUGESTVO-T

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 78: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

78

Integrated Processes for Phosphorous Containing Chemicals

PRESrsquo08 ndash Kapustenko P Boldyryev S Arsenyeva O Khavin G 2009 The use of plate heat exchangers toimprove energy efficiency in phosphoric acid production Journal of Cleaner Production 17 951ndash958PRESrsquo09 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2009 Synthesis of energy saving integratedflowsheet for sodium hypophosphite production Chemical Engineering Transactions 18 93-98PRESrsquo10 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S Arsenyeva O 2010 Process integration ofsodium hypophosphite production Applied Thermal Engineering 30 (16) 2306-2314PRESrsquo11 ndash Tovazhnyansky L Kapustenko P Ulyev L Boldyryev S 2011 Heat Integration Improvement forBenzene Hydrocarbons Extraction from Coke-Oven Gas Chemical Engineering Transaction 25 153-158

laquoKH

AR

KIV

POLYTECHNIC INSTITU

TE

raquoNAT

IONA

L TECHNICAL UNIVERSIT Y

laquoKHPIraquoAO SODRUGESTVO-T

Dependence of total surface area of heat exchanger network from ∆Tmin 1 ndash shell and tube type 2 ndash plate type

Integrated sodium hypophosphite production

The optimised design is expected to yield reduction 55 of hot and 70 of cold utilities

Plate types

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 79: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

TSI for Industrial Milk Drying

Keys to Energy Savings

bull Increased heat recovery (dryer amp boiler exhausts)

bull Correct placement of heat pumps (MVR)

bull Smart HEN design for process and utility (BFW coolingheating)

bull Emerging technology (new integration problem)

bull High efficiency utility system design

Ultra-low energy design -515 fuel (NG) -190 electricity -486 GHG emissions

Walmsley TG Atkins MJ Neale JR Walmsley MRW Philipp M Peesel RH Schumm G 2016 Total Site Utility Systems Optimisation for Milk Powder Production Chemical Engineering Transactions 52 235-240Walmsley TG Atkins MJ MRW Walmsley MRW Philipp M Peesel RH 2017 Process and Utility Systems Integration and Optimisation for Ultra-Low Energy Milk Powder Production Energy DOI 101016jenergy201704142

Current

Future

79

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 80: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Process IntegrationUltra-low Energy Dairy Processing

Aim To develop highly energy efficient dairy processes using advanced energy recovery techniques such as vapour compression

New Integrated Milk Evaporator Design Spray Dryer Exhaust Heat RecoveryPilot Plant Performance Testing

Effect 1 Effect 2

Milk247 th

Cold CowStorage

HotCold

MVR

Concentrate

Condenser

8degC

61degC

13degC

68degC

79degC

84degC

68degC

56degC

73degC 61degC

51degC

VapourBleed

H

Cow69degC

FlashVessel

84degC

68degC

DSI

2210 kW

A

MVR

117 kW

230kW

MVR

95degC

80

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 81: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

81

bull The sinter strength is very sensitive to the operating parameters of fixed carbon content sintering pressure and fuel reactivity

bull A sinter quality on-line control system is designed to reduce sinter strength fluctuation and achieve uniform sintering

bull Bi-objective optimization of major variables in the sinter cooler for waste heat recovery is conducted based on the decision making process

Liu Y Yang J Wang J Cheng ZL Wang QW 2014 Cost benefits analysis for waste heat utilization in sinter cooling bed Chemical Engineering Transactions 39 841-846 Cheng ZL Yang J Zhou L Li WX Liu Y Wang QW 2015 Experimental study on characteristics of flame front in the iron ore sintering process Chemical Engineering Transactions 45 877-882

Efficient iron ore sintering and waste heat recovery of hot sinters

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 82: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Industrial Implementation Issues of Total Site Heat Integration

Highly Cited Top 1 Referenced Work (Report from Web of Science Thomson Reuters on

MarchAprilSeptOct 2015)

82

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 83: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

CO2 Emission Pinch Analysis

D1 = production facility eg carbonated

plant

D2=EOR

S1 = Factories

Targeted Fresh CO2 Excess Emissions-amount of

energyemissionsreduction

Pinch point

Cum CO2 th

D3=natural sink ndash flora

S2 = Buildings

S3 = Vehicles sewage waste

Carbon Demand

Cum f

low

of o

ther

ga

ses

th

Baseline Fresh CO2 Demand

Baseline Total CO2 Source

Carbon Source

Maximum Carbon Exchange (MCE)

Carbon Source

Carbon Demand

Sadiq MM Manan ZA Wan Alwi SR 2012 Holistic carbon planning for industrial parks - A waste-to-resources process integration approach Journal of Cleaner Production 33 74-85 83

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 84: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Challengesbull Huge and growing energy and water demandsbull Subject of considerable losses and a potential danger

for the environment

Combination of large volumes and large loss rates

bull There are implications and opportunities at several levels ranging from plantsite level up to regional and country level

84

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 85: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Scales of Material and Energy Cycles

85

Need

Opportunitiesamp

Losses

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 86: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Exploit System Links as Synergies

bull Example Energy-Water Nexusbull Works both ways ndash not only in the direction of

causing problemsbull Energy and water savings amplify each otherbull Potential synergy mechanismbull So far applied mainly at process level by the

discussed methodologiesbull Extend the scope of energywater integration to

site and supply chain level

86

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 87: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Conclusionsbull Sustainability requirements increase the challenges

before industrial deign and operationbull Industrial systems have to be optimised ndash a

complex taskbull Process Integration provides performance targetsbull Guides the designbull New applications of the method

bull Trade-offs between quality and quantitybull Need to have the full tool set ndash from targeting to

designbull Needs to track other indicators beside energy

and water demandsbull An example specific GHG footprint

87

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 88: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

ltwwwnaturecomnewspollution-three-steps-to-a-green-shipping-industry-119369gt

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 89: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Conclusion

bull Need of Assessment Action and Appropriate Implementationbull Rather than having circularity as a goal a more pragmatic

vision for a material future would be aim to meet human needs (demand) while minimising the environmental impact

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 90: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Handbooks and the TextbooksBook Title Editors Publication

1 Handbook of water and energy management in food processing (English and Chinese version)

Jiřiacute Klemeš Robin Smith and Jin-Kuk

Kim

Woodhead Publishing Ltd Elsevier

中国轻工业出版社

2 Handbook of Process Integration (PI) Minimisation of energy and water use waste and emissions

Jiřiacute Klemeš Woodhead Publishing Series in Energy No

61

3 Sustainability in the process industry Jiřiacute Klemeš Ferenc Friedler

Igor Bulatov Petar Varbanov

McGraw-Hill Professional

4 Process integration and intensification Jiriacute Jaromiacuter Klemeš Petar Varbanov

Sharifah Rafidah Wan Wan Alwi Zainuddin

Abdul

De Gruyter

5 Assessing and Measuring Environmental Impact and Sustainability

Jiriacute Jaromiacuter Klemeš Butterworth-HeinemannElsevier

6 Compact heat exchangers for energy transfer intensification Low grade heat and fouling mitigation

Jiriacute Jaromiacuter Klemeš Olga ArsenyevaPetro Kapustenko Leonid Tovazhnyanskyy

CRC Press Taylor and Francis Group

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 91: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

20ndash23 October 2019Crete Greece

ltconferenceprescomgt | ltpres2019cpericerthgrgt

22nd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 92: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

17ndash21 August 2019Xirsquoan China

ltconferenceprescomgt

23rd Conference Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction

IF=10556 IF=6395 IF=5537 IF=2707

(open access)

IF=1092

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 93: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Special Session InvitationSDEWES 2020 Gold Coast Australia

ltwwwgoldcoast2020sdewesorggt 1st Asia Pacific SDEWES (Sustainable Development on Energy and Water Systems)

Engineering a Sustainable Circular Economy Materials Energy and Infrastructure Integration for Smart Cities and Industry

Timothy Gordon Walmsley Jiřiacute Jaromiacuter Klemeš Kim Pickering Petar Sabev VarbanovCorresponding email spilfmevutbrcz

Abstract submission (session invitation code) gc2020esce

6 - 9 April 2020

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 94: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Special Session InvitationSEE 2020 Bosnia and

Herzegovina

ltwwwsarajevo2020sdewesorggtIntegration of Smart cities and Smart Industry for Circular Economy Energy Water and Waste to Secondary raw material for Sustainable FutureContact us for invitation email and more informationYee Van Fan fanfmevutbrcz Jiřiacute Jaromiacuter Klemeš jiriklemesvutbrczPetar Sabev Varbanov varbanovfmevutbrcz

abstract submission (session invitation code)

sdsee20scsi

28 June - 2 July 2020

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 95: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Acknowledgement

bull To all contributors from 27 partner institutions fromthe academia and industry

bull To the EC project Sustainable Process IntegrationLaboratory ndash SPIL funded as project NoCZ02101000015_0030000456 by CzechRepublic Operational Programme Research andDevelopment Education Priority 1 Strengtheningcapacity for quality research and by the collaborationagreement with the Universiti Teknologi Malaysia(UTM) The University of Manchester UKUniversity of Maribor Slovenia Hebei Universityof Technology Tianjin China and Paacutezmaacuteny PeacuteterCatholic University Hungary based on the SPILproject

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 96: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

AcknowledgmentThe presented research results have been supported by the project LTACH19033 ldquoTransmission Enhancement and Energy Optimised Integration of Heat Exchangers in Petrochemical Industry Waste Heat Utilisationrdquo under the bilateral collaboration of the PR China and the Czech Republic and (partners Xian Jiao Tong University and Sinopec Research Institute Shanghai SPIL VUT Brno University of Technology and EVECO sro Brno) programme INTER-EXCELLENCE INTER-ACTION of the Czech Ministry of Education Youth and Sports

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97
Page 97: The role of Process Integration in the GHG and Haze/Smog ... · 1990 – 2004. Centre for Process Integration and Intensification - CPI 2. University of Pannonia, Hungary. PhD and

Thank you 97

  • The role of Process Integration in the GHG and HazeSmog Emissions Reduction
  • The RouteUnited Kingdomrarr Hungary rarr Czech Republic
  • UMIST ndash Pioneering Pinch Analysis
  • Slide Number 4
  • Slide Number 5
  • Slide Number 6
  • Slide Number 7
  • Slide Number 8
  • Cooperation with Foreign Universities
  • Google Scholar
  • Slide Number 11
  • Slide Number 12
  • Slide Number 13
  • Slide Number 14
  • Web of Sciencehttpappswebofknowledgecom
  • Slide Number 16
  • Slide Number 17
  • Slide Number 18
  • Slide Number 19
  • Slide Number 20
  • Main Co-Authors of this lecture
  • World Coverage Co-Authors
  • Heat Integration using Pinch Analysis
  • Slide Number 24
  • The First Steps ndash HEN synthesis
  • The Roots of Pinch Analysis
  • The ldquoRed Bookrdquo
  • SPIL VUT Brno 2 May 2018
  • What is Process (Heat) Integration
  • Pinch based approach
  • Mathematical Programming OR Pinch
  • Pinch AND Mathematical Programming
  • Benefits of Process Integration
  • Slide Number 34
  • Handbook of Process Integration (PI)
  • Composite Curves - ΔTmin = 10 degC
  • Pinch Design Principle
  • Pinch Analysis More in ndash More out
  • A Comprehensive Textbook
  • Pinch Design Method
  • Grand Composite Curves
  • The Grand Composite Curve (GCC)
  • Slide Number 43
  • PA for Integration of Heat Exchanger Networks with Heat Pumps
  • Slide Number 45
  • Intensification of Heat Transfer In Process Industries
  • Slide Number 47
  • Multi-Stream Heat Exchangers
  • Total Site (Site-wide) Integration
  • An Industrial Site
  • Maximising Total Site Heat Recovery
  • Total Site Profiles
  • Integrating Renewable Energy Sources into Extended Total Sites
  • Industrial Implementations of TSHI methodology
  • Mass and Water Integration
  • Water Pinch The Foundation
  • Setting the Water Recovery Target
  • Decomposing the Pinch Problem
  • Improved Pinch to Target Regeneration ReuseRecycle Water Networks
  • Combined Energy and Water Integration
  • Renewables Integration
  • Targeting Time Slice 1
  • Breakthrough in Energy Storage
  • Assessment and System Design
  • Footprints
  • Environmental Footprint
  • Virtual GHGs Emissions Flows in the International Trade
  • System DesignEngineering Model
  • Global Energy Use
  • Slide Number 70
  • CO2 GHG Emission Integration
  • The Total Annual AnthropogenicGHG Emissions
  • Pinch Analysis Tool for Optimising CO2 Capture Utilisation and Storage
  • Carbon Emissions Pinch Analysis
  • Matching of CO2 Sources amp Sinks
  • Industrial and Practical Issues
  • Process Integration Research and Applications in Industries
  • Slide Number 78
  • TSI for Industrial Milk Drying
  • Process IntegrationUltra-low Energy Dairy Processing
  • Slide Number 81
  • Industrial Implementation Issues of Total Site Heat Integration
  • CO2 Emission Pinch Analysis
  • Challenges
  • Scales of Material and Energy Cycles
  • Exploit System Links as Synergies
  • Conclusions
  • Slide Number 88
  • Conclusion
  • Handbooks and the Textbooks
  • Slide Number 91
  • Slide Number 92
  • Special Session InvitationSDEWES 2020 Gold Coast Australia
  • Special Session InvitationSEE 2020 Bosnia and Herzegovina
  • Acknowledgement
  • Acknowledgment
  • Slide Number 97