the schaeffler
TRANSCRIPT
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The Schaeffler-de-Long Diagram for estimating weldabilityThe Schaeffler-de-Long diagram
An aid in determining which structural constituents can occur in a weld metal is the
Schaeffler-de-Long diagram. With knowledge of the properties of different phases, it
is possible to judge the extent to which they affect the service life of the weld. The
diagram can be used for rough estimates of the weldability of different steel grades
as well as when welding dissimilar steels to each other.
Click for large Schaeffler-de-Long diagram
Weldability of Martensitic Steels
The quantity of martensite and its hardness are the main causes of the
weldability problems encountered with these steels. The fully martensitic
steels are air hardening. The steels are therefore very susceptible to hydrogen
embrittlement.
By welding at an elevated temperature (= the steel's Ms temperature), the HAZ can
be kept austenitic and tough throughout the welding process. After cooling, the
formed martensite must always be tempered at about 650-850 C, preferably as a
concluding heat treatment. However, the weld must first have been allowed to cool to
below about 150 C.
Martensitic-austenitic steels, such as 13Cr/6Ni and 16Cr/5Ni/2Mo, can often be
welded without preheating and without post-weld annealing. Steels of the 13Cr/4Ni
type with low austenite content must, however, be preheated to a working
temperature of about 100 C.
If optimal strength properties are desired, they can be heat treated at 600 C after
welding. The steels are welded with matching or austenitic filler metals.
Weldability of Ferritic Steels
These steels are generally more difficult to weld than austenitic steels. This is
the main reason they are not used to the same extent as austenitic steels.
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The older types, such as AISI 430, had greatly
reduced ductility in the weld. This was mainly
due to strong grain growth in the heat-affected
zone (HAZ), but also due to precipitation of
martensite in the HAZ. They were also
susceptible to intergranular corrosion after
welding. These steels are therefore often welded
with preheating and post-weld annealing.
Today's ferritic steels of type S44400 and
S44635 have considerably better weldability due to low carbon and nitrogen contents
and stabilisation with titanium/niobium. However, there is always a risk of
unfavourable grain enlargement if they are not welded under controlled conditions
using a low heat input. They do not normally have to be annealed after welding.
Weldability of Ferritic-Austenitic Steels
Today's ferritic-austenitic steels have considerably better weldability than
earlier grades. They can be welded more or less as common austenitic steels.
Besides being susceptible to intergranular
corrosion, the old steels were also susceptible
to ferrite grain growth in the heat affected
zone (HAZ) and poor ferrite to austenite
transformation, resulting in reduced ductility.
Today's steels, which have higher nickel
content and are alloyed with nitrogen, exhibit
austenite transformation in the HAZ that is sufficient in most cases. However,
extremely rapid cooling after welding, for example in a tack or in a strike mark, can
lead to unfavorably high ferrite content. Extremely high heat input can also lead to
heavy ferrite grain growth in the HAZ.
When welding UNS S31803 (AvestaPolarit 2205) in a conventional way (0.6-2.0
kJ/mm) and using filler metals at the same time, a satisfactory ferrite-austenite
balance can be obtained. For the super duplex stainless steel (AvestaPolarit SAF
2507) a somewhat different heat input is recommended (0.2-1.5 kJ/mm). The reason
for lowering the minimum value is that this steel has much higher nitrogen content
than 2205. The nitrogen favours a fast reformation of austenite, which is important
when welding with a low heat input. The maximum level is lowered in order to
A typical macroscopic
image of a weld bead.
These steels are welded
with matching or austenitic
super-alloyed filler metal
(such as AvestaPolarit P 5).
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minimize the risk of secondary phases.
The steels are welded with ferritic-austenitic or austenitic filler metals. Welding
without filler metal is not recommended without subsequent quench annealing.
Nitrogen affects not only the microstructure, but also the weld pool penetration.
Increased nitrogen content reduces the penetration into the parent metal. To avoid
porosity in TIG welding it is recommended to produce thin beads. To achieve the
highest possible pitting corrosion resistance at the root side in ordinary 2205 weld
metals, the root gas should be Ar+ N2 or Ar+ N2 + H2. The use of H2 in the shielding
gas is not recommended when welding super duplex steels. When welding 2205 with
plasma, a shielding gas containing Ar+5% H2 is sometimes used in combination with
filler metal and followed by quench annealing.
Weldability of Austenitic SteelsThe steels of type ASTM 304, 316, 304L, and 316L have very good weldability.
The old problem of intergranular corrosion after welding is very seldom
encountered today. The steels suitable for wet corrosion either have carbon
contents below 0.05% or are niobium or titanium stabilised.
They are also very unsusceptible to
hot cracking, mainly because they
solidify with a high ferrite content. The
higher-alloy steels such as 310S and
N08904 solidify with a fully austenitic
structure when welded. They should
therefore be welded using a controlled
heat input. Steel and weld metal with
high chromium and molybdenum
contents may undergo precipitation of
brittle sigma phase in their
microstructure if they are exposed to
high temperatures for a certain length of time. The transformation from ferrite to
sigma or directly from austenite to sigma proceeds most rapidly within thetemperature range 750-850 C. Welding with a high heat input leads to slow cooling,
especially in light-gauge welds. The weld's holding time between 750-850 C then
increases, and along with it the risk of sigma phase formation.
Weldability of Martensitic Steels
The quantity of martensite and its hardness are the main causes of the
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weldability problems encountered with these steels. The fully martensitic
steels are air hardening. The steels are therefore very susceptible to hydrogen
embrittlement.
By welding at an elevated temperature (= the steel's Ms temperature), the HAZ can
be kept austenitic and tough throughout the welding process. After cooling, theformed martensite must always be tempered at about 650-850 C, preferably as a
concluding heat treatment. However, the weld must first have been allowed to cool to
below about 150 C.
Martensitic-austenitic steels, such as 13Cr/6Ni and 16Cr/5Ni/2Mo, can often be
welded without preheating and without post-weld annealing. Steels of the 13Cr/4Ni
type with low austenite content must, however, be preheated to a working
temperature of about 100 C.
If optimal strength properties are desired, they can be heat treated at 600 C after
welding. The steels are welded with matching or austenitic filler metals.
Austenitic Stainless Steels
This type of stainless steel is dominant in the market. The group includes the
very common AISI 304 and AISI 316 steels, but also the higher-alloy AISI
310S and ASTM N08904.
Austenitic steels are characterized by their
high content of austenite-formers, especially
nickel. They are also alloyed with chromium,
molybdenum and sometimes with copper,
titanium, niobium and nitrogen. Alloying with
nitrogen raises the yield strength of the
steels.
Austenitic stainless steels have a very wide
range of applications, e.g. in the chemical
industry and the food processing industry.
The molybdenum-free steels also have very good high-temperature properties and
are therefore used in furnaces and heat exchangers. Their good impact strength at
low temperatures is often exploited in apparatus such as vessels for cryogenic liquids.
Austenitic steels cannot be hardened by heat treatment. They are normally supplied
in the quench-annealed state, which means that they are soft and highly formable.
The image shows the microstructure of an
austenitic stainless steel, type ASTM 304L.
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Cold working increases their hardness and strength. Certain steel grades are
therefore supplied in the cold stretched or hard rolled condition.
Martensitic Stainless Steels
Martensitic steels have the highest strength but also the lowest corrosion
resistance of the stainless steels.
Martensitic steels with high carbon
contents are used for tool steels.
Due to their high strength in
combination with some corrosion
resistance, martensitic steels are
suitable for applications where thematerial is subjected to both corrosion
and wear. An example is in
hydroelectric turbines.
Mechanical Properties of Martensitic SteelsRoom Temperature
Martensitic and ferritic-martensitic steels are characterised by their high strength and
the fact that the strength is strongly affected by heat treatment.
Martensitic steels are usually used in a hardened and tempered condition. In this
condition the strength of the steels increases with the carbon content.
The ductility of martensitic steels is relatively low. Ferritic-martensitic steels have a
high strength in the hardened and tempered condition in spite of their relatively low
carbon contents, and good ductility. They also possess excellent hardenability: even
thick sections can be fully hardened and these steels will thus retain their good
mechanical properties even in applications where thick sections are used.
Elevated Temperatures
Martensitic and martensitic-austenitic steels in the hardened and tempered condition
exhibit high strength at moderately elevated temperatures. However, the useful
upper service temperature is limited by the risk of over-tempering and embrittlement.
The creep strength is low and this type of stainless steel is normally not used above
Microstructure image of a
martensitic stainless steel
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300 C. However, certain martensitic grades are used at higher temperatures. The
wide range of elevated temperature strength is due to the wide range of strength
levels offered by different grades and heat treatments.
Mechanical Properties of Ferritic-Austenitic SteelsRoom Temperature
Ferritic-austenitic steels have a high yield stress which increases with
increasing carbon and nitrogen levels. Increased ferrite content will, within
limits, also increase the strength of duplex steels.
Their ductility is good and they exhibit strong work hardening.
Elevated Temperatures
Ferritic-austenitic steels have a high yield stress which increases with
increasing carbon and nitrogen levels. Increased ferrite content will, within
limits, also increase the strength of duplex steels.
Their ductility is good and they exhibit strong work hardening.
Mechanical Properties of Ferritic SteelsRoom Temperature
Ferritic steels have relatively low yield strength and the work hardening of thesesteels is limited. Their strength increases with increasing carbon content, but the
effect of chromium on strength is negligible. However, ductility is lower in steels with
high chromium content and for optimum ductility, the levels of carbon and nitrogen
must be kept to a minimum.
Elevated Temperatures
Ferritic steels have relatively high strength up to 500 C. The creep strength, which is
usually the determining factor at temperatures above 500 C, is low. The normal
upper service temperature limit is set by the risk of embrittlement at temperaturesabove 350 C. However, due to the good resistance of chromium steels to high
temperature sulphidation and oxidation, a few high chromium-alloyed grades are
used at higher temperatures.
Mechanical Properties of Austenitic SteelsRoom Temperature
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Austenitic steels generally have a relatively low yield stress and are characterised by
strong work hardening. The strength of austenitic steels increases with increasing
levels of carbon, nitrogen and, to a certain extent, also molybdenum. Austenitic steels
exhibit very high ductility and toughness.
Elevated Temperatures
Most austenitic steels have lower strength than other types of stainless steels
when used at temperatures up to about 500 C.
The highest elevated temperature strength among austenitic steels is
exhibited by nitrogen-alloyed steels and those containing titanium or
niobium.
A few high alloyed and nitrogen alloyed austenitic steels have elevated
temperature strengths that are almost as high as those of duplex steels.
In terms of creep strength austenitic stainless steels are superior to all other
types of stainless steel.
Toughness of Stainless Steels
The toughness of the different types of stainless steels shows considerable
variation, ranging from excellent toughness at all temperatures for austenitic
steels to the relatively brittle behaviour of martensitic steels. Toughness is
dependent on temperature and generally improves with increasing
temperatures.
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One measure of toughness is
the impact toughness, i.e. the
toughness measured on rapid
loading. The figure shows
categories of stainless steel at
temperatures from -200C to +
100C.
It is apparent from the diagram
that there is a fundamental
difference at low temperatures
between austenitic steels on
the one hand and martensitic,
ferritic and ferritic-austeniticsteels on the other.
Martensitic, ferritic and ferritic-austenitic steels are characterised by a transition in
toughness, from tough to brittle behaviour, at a certain temperature, the transition
temperature.
For ferritic steel the transition temperature increases with increasing carbon and
nitrogen content, i.e. the steel becomes brittle at successively higher temperatures.
For ferritic-austenitic steels, an increased ferrite content gives a higher transition
temperature, i.e. more brittle behaviour.
Martensitic stainless steels have transition temperatures around or slightly below
room temperature, while those for ferritic and ferritic-austenitic steels are in the
range 0 to - 50C, with ferritic steels in the upper part of this range.
Austenitic steels do not exhibit a toughness transition as do the other steel types, but
have excellent toughness at all temperatures, although the toughness decreases
slightly with decreasing temperature.
Corrosion Resistance of Austenitic Steels
Wet Corrosion
These steels are mainly used in wet environments. With increasing chromium and
molybdenum contents, the steels become increasingly resistant to aggressive
solutions. The higher nickel content reduces the risk of stress corrosion cracking.
The figure shows categories of stainless steel at
temperatures from -200C to + 100C
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Austenitic steels are more or less resistant to general corrosion, crevice corrosion and
pitting, depending on the quantity of alloying elements. Resistance to pitting and
crevice corrosion is very important if the steel is to be used in chloride-containing
environments.
Resistance to pitting and crevice corrosion increases with increasing contents of
chromium, molybdenum and nitrogen.
The rich chloride content of seawater makes it a particularly harsh environment,
which can attack stainless steel by causing pitting and crevice corrosion. However,
two stainless steel grades designed to cope with this environment have been
developed by AvestaPolarit - 254 SMO and 654 SMO.
254 SMO has a long record of successful installations for seawater handling within
offshore, desalination, and coastal located process industries.
Some crevice corrosion has still been reported and for more severe situations, i.e.
severe crevice geometries and elevated temperatures, the natural selection should be
654 SMO.
High Temperature Corrosion
Most molybdenum-free steels can be used at high temperatures in contact with hot
gases.
An adhesive oxide layer then forms on the surface of the steel. It is important that
the oxide is impervious so that further oxidation is prevented and the oxide film
adheres tightly to the steel.
At very high temperatures, the oxide begins to loosen (scaling temperature). This
temperature increases with increasing chromium content.
A common high-temperature steel is 310S. Another steel that has proved to be very
good at high temperatures is AvestaPolarit 253 MA. Due to a balanced composition
and the addition of cerium, among other elements, the steel can be used at
temperatures of up to 1150-1200 C in air.
Corrosion Resistance of Ferritic Steels
Wet Corrosion
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The modern molybdenum-alloyed ferritic steels have largely the same corrosion
resistance as AISI 316 but are superior to most austenitic steels in terms of their
resistance to stress corrosion cracking. A typical application example for these steels
is hot-water heaters.
For chlorine-containing environments, where there is a particular risk of pitting, for
instance in seawater, the high-alloy steel S44635 (25Cr 4Ni 4Mo) can be used.
High Temperature Corrosion
Ferritic steels with high chromium contents have good high-temperature properties.
As mentioned previously, the steels readily form a brittle sigma phase within the
temperature range 550-950 C, but this is of minor importance as long as the
product, such as a furnace, operates at its service temperature.
AISI446 with 27% chromium has a scaling temperature in air of about 1070 C.
Corrosion Resistance of Austenitic Steels
Wet Corrosion
These steels are mainly used in wet environments. With increasing chromium and
molybdenum contents, the steels become increasingly resistant to aggressive
solutions. The higher nickel content reduces the risk of stress corrosion cracking.
Austenitic steels are more or less resistant to general corrosion, crevice corrosion and
pitting, depending on the quantity of alloying elements. Resistance to pitting and
crevice corrosion is very important if the steel is to be used in chloride-containing
environments.
Resistance to pitting and crevice corrosion increases with increasing contents of
chromium, molybdenum and nitrogen.
The rich chloride content of seawater makes it a particularly harsh environment,
which can attack stainless steel by causing pitting and crevice corrosion. However,
two stainless steel grades designed to cope with this environment have been
developed by AvestaPolarit - 254 SMO and 654 SMO.
254 SMO has a long record of successful installations for seawater handling within
offshore, desalination, and coastal located process industries.
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Some crevice corrosion has still been reported and for more severe situations, i.e.
severe crevice geometries and elevated temperatures, the natural selection should be
654 SMO.
High Temperature Corrosion
Most molybdenum-free steels can be used at high temperatures in contact with hot
gases.
An adhesive oxide layer then forms on the surface of the steel. It is important that
the oxide is impervious so that further oxidation is prevented and the oxide film
adheres tightly to the steel.
At very high temperatures, the oxide begins to loosen (scaling temperature). This
temperature increases with increasing chromium content.
A common high-temperature steel is 310S. Another steel that has proved to be very
good at high temperatures is AvestaPolarit 253 MA. Due to a balanced composition
and the addition of cerium, among other elements, the steel can be used at
temperatures of up to 1150-1200 C in air.
Considerable Work-Hardening
Work-hardening means that the hardness increases considerably as the
material is deformed, e.g. during the process of producing chips.
It also means that, after a
first pass, the machined
surface has become harder,
changing the working
conditions for the cutting
edge during subsequent
posses, as the edge then
has to work in a hard
surface layer.
Austenitic and ferritic-
austenitic steels have the
greatest tendency to work-
harden, which results in both high cutting forces and a high hardness of the machined
surface, see figure. This means that the cutting edge has to work in a material that is
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much harder than is indicated by the hardness of the base material. This often results
in problems during finishing, as the depth of cut is then often so small that the
cutting edge is working entirely in the work-hardened layer.
It is, of course, not only cutting that causes work-hardening, but also all other types
of cold working. Shot or sand blasting, for example, or a straightening operation can
all produce a hard surface layer that affects machinability. In such cases, the
hardness gradient is similar in principle to that resulting from machining, but the
increase in hardness can extend to a greater depth into the metal. After a substantial
straightening operation the increase in hardness can extend to a depth of 2-4 mm
below the surface.
Low Thermal Conductivity
Stainless steels are poor conductors of heat, and the thermal conductivity ofall types of stainless steel falls off with increasing alloy, see table below.
Austenitic steels have the lowest thermal conductivity, while ferritic and martensitic
steels have better conductivity.
Steel Grade Thermal conductivity at 400 C
(W/m, K)
Carbon steel 35
420 26.5
444 26.5
304 20.0
316L 18.52205 24.0
904L 18.0
The low thermal conductivity means that, for a given machining operation, the cutting
edge temperatures are higher in stainless steel than in carbon steel. This naturally
imposes severe requirements on the high-temperature hardness of the cutting edge
and on its ability to withstand high temperatures.
High ToughnessAustenitic stainless steels in particular have very high toughness which means
that a considerable amount of energy is required to form each chip.
This, in combination with work hardening, results in a high power requirement for
machining stainless steels. This applies particularly for austenitic steels. The high
cutting forces, in combination with the low thermal conductivity, impose very severe
requirements on the strength of the cutting edge.
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Tendency to Stickyness
This tendency is most marked in austenitic stainless steels, although both
ferritic and ferritic-austenitic steels give rise to chip sticking and built-up
edges on the cutting tool.
The formation of a built-up edge results in a poor surface finish on the work piece and
very high stresses on the cutting edge. The formation of a built-up edge can often
result in failure of the cutting edge, resulting in tool failure.
Formation of a built-up edge and chip sticking can also occur when machining
ordinary structural steels and other carbon steels, although in such cases (as opposed
to the stainless steels) it is often sufficient to increase the cutting speed in order to
get out of the built-up edge range. When machining stainless steels it can, in certain
cases, be difficult to find a cutting speed range where built-up edge formation does
not occur.
Low Chip-breaking Characteristics
The high toughness of many stainless steels, and particularly of austenitic
steels, means that it is very difficult to break the chips formed during
machining.
This often causes considerable problems in removing the chips from the tool area, or
when a machining operation is to be automated. In the latter case, tangled chips
around the work piece can mean that, say, portal loaders and/or measuring stations
cannot be operated unmanned.
Some Rules of Thumb for Machining Stainless Steels
There are some general rules of thumb that can be applied when machining
stainless steels, to avoid (to some extent) the problems described, or at least
to minimise them.
These rules are particularly important when machining austenitic and ferritic-
austenitic stainless steels.
Always use rigid machine tools, as the machining of stainless steels
involves high cutting forces. Tools and work pieces must be firmly clamped, and the tool overhang mustbe as small as possible. (Long overhangs, or unstable machining conditions,increase the already substantial risk of vibration when machining stainlesssteels.)
Do not use too great a nose radius, as this can cause vibration.
Use tools with good edge sharpness and high edge strength. (Cemented
carbide tools should have a positive cutting edge, with a protective negative land,although this must not be greater than necessary to ensure that the edge is
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effectively sharp. At the same time, the edge must be strong, which means that itis necessary to find a compromise between strength and sharpness of the edge.)
Use sufficient cutting depths, so that the cutting edge tip reaches below thework-hardened zone from the previous cut.
Replace the insert more frequently than when machining carbon steel, as adull edge produces greater work-hardening than does a sharp edge.
When using cutting fluid, ensure that it is always applied. (If possible use
oils and emulsions with EP additive.)
Defintions of Surface Finish
In considering the concept of surface finish,
we will disregard any sporadic surface
defects, which have mechanical or
metallurgical causes. Instead, we will
concentrate on the minute, evenly
distributed irregularities in the surface layer,
which are characteristic of the different
means of production and finishing of the steel product. In terms of strict definition,
the concept "surface finish" can be said to describe the deviation from the ideal flat
surface. This deviation is normally expressed in terms such as roughness, lay and
waviness, which in turn may be defined as:
Roughness represents the size of the finely distributed surface pattern
deviations from the smooth surface.
Lay represents the dominant direction of the surface pattern, such asgrinding scores.
Waviness represents deviations, which are relatively far apart.
Of these, waviness is the most difficult to detect with the naked eye.
Definition of Surface Roughness
Roughness is measured by special precision instruments that measure the vertical
deviations when traversing the metal surface. The measurement is carried out in the
direction that gives the greatest measured values, that is, at right angles to the ray.
In accordance with the relevant international standard (ISO), the instrument
measures and calculates the mean deviation from the average line over a given
measured distance, the reference length (cut-off length), usually 0.8 or 0.25 mm.
The measured value, abbreviated as Ra or CLA (centre line average), is expressed in
m (thousands of a millimetre).
Y=Roughness, S=Lay, V=Waviness
Definition of the mean deviation
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Surface Finishes
Abbreviation2)Type of process
routeSurface finish Notes
Hot
rolled1U
Hot rolled, not
heat treated, not
descaled
Covered with the
rolling scale
Suitable for products which are to be
further worked e.g. strip for re-rolling
1C
Hotrolled,
heat
treated,
not
descaled
Covered
with the
rolling
scale
Suitable for parts which will
be descaled or machined in
subsequent production or for
certain heat-resisting
applications
1E
Hot rolled, heat
treated,
mechanically
descaled
Free of scale
The type of mechanical descaling, e. g.
coarse grinding or shot blasting,
depends on the steel grade and the
product and is left to the manufacturer's
discretion, unless otherwise agreed
1DHot rolled, heat
treated, pickledFree of scale
Usually standard for most steel types to
ensure good corrosion resistance; also
common finish for further processing.
It is permissible for grinding marks to
be present. Not as smooth as 2D or 2B
Cold
rolled2H Work hardened Bright
Cold worked to obtain higher strength
level
2C
Cold rolled, heat
treated, not
descaled
Smooth with scale
from heat treatment
Suitable for parts which will be
descaled or machined in subsequent
production or for certain heat-resisting
applications
2E
Cold rolled, heat
treated,
mechanically
descaled
Rough and dull
Usually applied to steels with a scale
which is very resistant to pickling
solutions. May be followed by
pickling.
2DCold rolled, heat
treated, pickledSmooth
Finish for good ductility, but not as
smooth as 2B or 2R
2B
Cold rolled, heat
treated, pickled,
skin passed
Smoother than 2D
Most common finish for most steeltypes to ensure good corrosion
resistance, smoothness and flatness.
Also common finish for further
processing. Skin passing may be by
tension levelling
2RCold rolled, bright
annealed2)Smooth, bright,
reflective
Smoother and brighter than 2B. Also
common finish for further processing
2Q
Cold rolled,
hardened and
tempered, scale
free
Free of scale
Either hardened and tempered in a
protective atmosphere or descaled after
heat treatment
Special
finishes
1G
or
2G
Ground4) See footnote 5
Grade of grit or surface roughness can
be specified. Unidirectional texture, not
very reflective
1J
or
2J
Brushed4) or dull
polished4)
Smoother than
ground. See footnote
5
Grade of brush or polishing belt or
surface roughness can be specified.
Undirectional texture, not very
reflective
1K
or
2K
Satin polish4) See footnote 5
Additional specific requirements to a
"J" type finish, in order to achieve
adequate corrosion resistance for
marine and external architectural
applications. Transverse Ra >0,5 m
with clean cut surface finish
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1P
or
2P
Bright polished 4) See footnote 5
Mechanical polishing. Process or
surface roughness can be specified.
Non-directional finish, reflective with
high degree of image clarity
2F
Cold rolled, heat
treated, skin
passed on
roughened rolls
Uniform non-
reflective matt
surface
Heat treatment by bright annealing or
by annealing and pickling
1M PatternedDesign to agreed; 2nd
surface flatChequer plates used for floors
2M PatternedDesign to agreed; 2nd
surface flat
A fine texture finish mainly used for
architectural applications
2W Corrugated Design to be agreedUsed to increase strength and/or for
cosmetic effect
2L Coloured4) Colour to be agreed
1S
or
2SSurface coated4)
Coated with e. g. tin, aluminium,
titanium
4) Not all process routes and surface finishes are available for all steels
4) First digit 1 = hot rolled 2= cold rolled
4) May be skin passed
4) One surface only, unless specifically agreed at the time of enquiry or order
4) Within each finish description the surface characteristics can vary, and more specific requirements may need to be agreed between manufacturer and purchaser (e. g. grade of grit or surface roughness)
Hot Rolled Plate and Sheet
All steel plate and sheet is hot-rolled as a first rolling step, after which it is annealed
in order to attain homogeneous material characteristics. Annealing produces an oxide
coating on the steel, which is removed by shot blasting and by pickling in an acid
bath. As a result of these manufacturing operations, the steel acquires a relatively
coarse, matt grey surface with an Ra value in the order of 2-8 m; the thicker the
plate the coarser the surface, and the higher the Ra value. Localised grinding marksmay appear on the surface, but have no practical implications for the use of the steel.
Hot rolled plate of this finish is mostly used for heavy process equipment and in
thickness from around 5 mm and upward.
Cold Rolled Sheet and Coil
Finishes:
Annealed and pickled finish - 2D
Skinpass rolled finish - 2B Bright annealed finish - BA
Polished
Brushed Patterned
Annealed and pickled finish - 2D
By means of further rolling of the steel in a cold state, both its surface smoothness
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substances do not attach as easily to wet polished surfaces.
The ground or polished surface has more or less clearly visible scoring, which also
makes scratches from daily wear and tear less visible. A polished surface is also easy
to re-create, for example after repairs or welding work, compared with a 2B or 20
surface. Polished sheet is used for purposes where quality of appearance and hygiene
are very important, such as in commercial kitchens (work surfaces, cooking utensils,
dishwashers, freezers) , in house- holds (cooking vessels), and in public places
(sanitary facilities, hospital equipment, kick-plates).Brushed
The use of brushing (with Scotch Brite, for example), usually on a 2B surface,
provides a silky-matt finish without grinding scores. A brushed surface also has the
advantage that it can easily be re-created. Brushed stainless steel sheet is used in
situations where appearance is an important factor, such as in the building industry
(sheet metal cladding and lift interiors), the vehicle industry (car hub caps, wall
panels for express trains) and the home (sink units). The Ra value for brushed sheetcan be around 0.2-0.4 m.
Patterned
Patterned sheet is produced by means of extra rolling of cold-rolled brushed sheet
coils between special imprinted rolls. In this way, a waffle-type pattern can be
obtained on both sides of the sheet. At the same time, the rigidity and strength of the
material is increased by almost 50%. This means that it is possible to use a thinner
sheet, and thus obtain a lower weight.
Cleaning of Stainless Steels
A stainless steel may be discoloured by rust
if it is exposed to a more aggressive environment than that is intended for
a particular grade of steel , e.g. highly polluted air, salt solutions or residues of
cleaning agents containing chlorine
if it has a rough surface finish that provides a foothold for corrosivesubstances and corrosion products from the surroundings
if the design of the structure is inappropriate, with pockets and narrow gaps
if the surface is contaminated by grinding swarf and other iron particles from
tools used in the installation work
if fasteners of ordinary steel are used for securing the material, or if thematerial comes into direct contact with adjacent components made of plain
carbon steel in wet or humid conditions.
The risk of corrosion in the first three situations is highest for the lower-alloy stainless
steel grades and can be reduced substantially right from the start by specifying
molybdenum alloyed stainless grades (such as type 1.4401). In the last two cases,
the surface of the stainless steel will be discoloured by rust from the plain carbon
steel.
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Removal of stains and discolourationsStain Type Cleaning agent and method
FingerprintsWash with alcohol, thinner, thrichlorethylene or acetone, rinse with clean cold water, and
wipe dry.
Oil and greaseWash with organic solvents, such as those mentioned above, then wash with soap or mild
detergent and water, rinse with clean cold water, and wipe dry.
More stubborn stains
and discolourations
Wash with a mild abrasive detergent, rub in the direction of the visible surface structure, rinse
with clean cold water, and wipe dry.
Or:
Wash with a 10% phosphoric acid solution, rinse with ammonia solution, then with clean
cold water, and wipe dry.
Temper colour and
more serious stains
Wash with an abrasive detergent as described above.
Or:
Rub with Scotch Brite sponge in the direction of the visible structure, rinse with clean cold
water, and wipe dry.
Rust stains
Wet the surface with oxalic acid solution, leave it for 15-20 minutes, rinse with clean cold
water, and wipe dry. If necessary, repeat the washing procedure with an abrasive detergent as
described above.
Paint
Wash with paint solvent (use a soft nylon brush), and then rinse with clean cold water, and
wipe dry.
Scratches on a ground
or brushed surface
Polish with a polishing wheel (using an iron-free abrasive) in the direction of the structure,
wash with soap or mild detergent and water, rinse with clean cold water, and wipe dry. N.B.
The method must not be used for material with a 2B or 2D finish, or on patterned or
decorated surfaces.
Preventive Measures in Project Design, Production, andInstallation
All stainless steels are clean and passivated when they are delivered by the
steel manufacturer. In other words, the material has a natural corrosion
resistant film over its entire surface.
The following instructions should be taken into account from the moment of project
design, through to the production and installation stages, particularly for building
components installed outdoors, in order to maintain as much as possible of the
original appearance and corrosion resistance of the stainless material.
Do not use steel brushes or steel tools made of plain carbon steel.
Do not carry out shot blasting using ordinary steel shot or sand that has used for shot blasting plain
carbon steels
Do not use hydrochloric acid to remove residues of cement or mortar on steel. Instead use water to wash
off the mortar before it dries. Hydrochloric acid may not be used for cleaning of stainless steels.
Specify the correct grade of steel, taking into account the occurrence of
deposits and air pollutants such as soot, sulphur dioxide, salt water or road salt
in the immediate surroundings.
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welding due to their speed and reliability. These are employed predominantly in batch
production.
Electrodes - SMAW
Shielded metal-arc welding (SMAW) with covered electrodes is the most common
method of welding stainless steels. It is suited to all weldable grades, in thicknesses of
1 mm and upwards. In principle, there is no upper limit of thickness. However, for
heavier material, the automatic wire processes are often more economical.
When correctly carried out, the heat supply is concentrated and the heat affected zone
(HAZ) on either side of the joint is relatively narrow.
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Gas Metal-Arc Welding - GMAW
In GMAW the arc is struck between the filler wire and the workpieceThe uncovered filler wire is automatically fed through the centre of the gun. The
shielding gas is supplied through the gun and surrounds the arc pool during welding,
thus protecting the weld from the atmosphere. The gas usually consists of argon with
an added 1-2% oxygen or of pure argon.
A distinction is drawn between spray-arc welding and short-arc welding. The latter
method is suitable for welding light-gauge sheet as well as for welding root beads in
heavier material. It is also suitable for position welding. This process takes place at a
lower voltage and current than in the case of spray-arc welding. A thin filler wire (0.8
mm) is used. The arc is short, hence the name, and metal transfer is in the form of big
drops shortcircuiting the arc. This provides rapid alternation between arc heating and
resistance heating.
By contrast, in spray-arc welding, the metal is transferred in the form of a fine mist of
droplets which do not short-circuit the arc. The process, which derives its name from
this feature, is suitable for material thicknesses of 3 mm and upwards.
The GMAW process is either semi-automatic or fully automatic. In many cases, it is
more economical than welding with covered electrodes. However, all gas-shielded
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processes are sensitive to draughts. Thus, they are not suitable for outdoor work or for
welding in open vessels in which a chimney effect may easily occur.
Pickling methods
In most workshops there will typically be the same sequence of operations even if
the type of pickling process may vary:
Pre-cleaning
Pickling
- Brush pickling with paste
- Spray pickling with solution
- Immersion pickling in a bath
Rinsing
Passivation, if necessary
Neutralisation
Drying
Inspection
The choice of pickling method depends on:
The steel grade and type of component to be pickled
The requirements of the specification
The requirements on the visual appearance of the surface
The functional requirements on the surface
The automation potential
The environmental and worker safety aspects
The costs
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