the submillimeter spectrum of the orion star forming region mary l. radhuber, jay a. kroll, susanna...
DESCRIPTION
2 atoms3 atoms4 atoms5 atoms6 atoms7 atoms8 atoms9 atoms10 atoms11 atoms12 atoms13 atoms H2H2 C3C3 c-C 3 HC5C5 C5HC5HC6HC6HCH 3 C 3 NCH 3 C 4 HCH 3 C 5 NHC 9 NC6H6C6H6 HC 11 N AlFC2HC2Hl-C 3 HC4HC4Hl-H 2 C 4 CH 2 CHCNHC(O)OCH 3 CH 3 CH 2 CN(CH 3 ) 2 COCH 3 C 6 HC 2 H 5 OCH 3 AlClC2OC2OC3NC3NC 4 SiC2H4C2H4 CH 3 C 2 HCH 3 COOH(CH 3 ) 2 O(CH 2 OH) 2 C2C2 C2SC2SC3OC3Ol-C 3 H 2 CH 3 CNHC 5 NC7HC7HCH 3 CH 2 OHCH 3 CH 2 CHO CHCH 2 C3SC3Sc-C 3 H 2 CH 3 NCCH 3 CHOH2C6H2C6 HC 7 N CH + HCNC2H2C2H2 H 2 CCNCH 3 OHCH 3 NH 2 CH 2 OHCHOC8HC8H CNHCONH 3 CH 4 CH 3 SHc-C 2 H 4 Ol-HC 6 HCH 3 C(O)NH 2 COHCO + HCCNHC 3 NHC 3 NH + H 2 CCHOHCH 2 CHCHOC8H–C8H– CO + HCS + HCNH + HC 2 NCHC 2 CHOC6H–C6H– CH 2 CCHCNC3H6C3H6 CPHOC + HNCOHCOOHNH 2 CHO SiCH2OH2OHNCSH 2 CNHC5NC5N HClH2SH2SHOCO + H2C2OH2C2Ol-HC 4 H KClHNCH 2 COH 2 NCNl-HC 4 N NHHNOH 2 CNHNC 3 c-H 2 C 3 O NOMgCNH 2 CSSiH 4 H 2 CCNH NSMgNCH3O+H3O+ H 2 COH + NaClN2H+N2H+ c-SiC 3 C4H–C4H– OHN2ON2OCH 3 PNNaCN SOOCS SO + SO 2 SiNc-SiC 2 SiOCO 2 SiSNH 2 CSH3+H3+ HFH 2 D +, HD 2 + SHSiCN HDAlNC FeOSiNC O2O2 HCP CF + SiH PO >150 Molecules Detected H. S. P. Müller, F. Schlöder, J. Stutzki, and G. Winnewisser, J. Mol. Struct. 742, 215–227 (2005) H. S. P. Müller, S. Thorwirth, D. A. Roth, and G. Winnewisser, Astron. Astrophys. 370, L49–L52 (2001)TRANSCRIPT
The Submillimeter Spectrum of the Orion Star Forming Region
Mary L. Radhuber, Jay A. Kroll, Susanna L. Widicus WeaverDepartment of Chemistry
Emory University
Why Line Surveys?
Large swaths of frequency covered in single observations
More observed transitions leads to better identification certainty.
Large amounts of data are acquired in short amounts of time.
Similar instrument and calibration conditions for an entire observation
Better internal consistency of intensity measurements leads to a more accurate measurement of physical conditions.
2 atoms
3 atoms
4 atoms
5 atoms
6 atoms
7 atoms
8 atoms
9 atoms
10 atoms
11 atoms
12 atoms
13 atoms
H2 C3 c-C3H C5 C5H C6H CH3C3N CH3C4H CH3C5N HC9N C6H6 HC11N
AlF C2H l-C3H C4H l-H2C4 CH2CHCN HC(O)OCH3 CH3CH2CN (CH3)2CO CH3C6H C2H5OCH3
AlCl C2O C3N C4Si C2H4 CH3C2H CH3COOH (CH3)2O (CH2OH)2
C2 C2S C3O l-C3H2 CH3CN HC5N C7H CH3CH2OH CH3CH2CHO
CH CH2 C3S c-C3H2 CH3NC CH3CHO H2C6 HC7N
CH+ HCN C2H2 H2CCN CH3OH CH3NH2 CH2OHCHO C8H
CN HCO NH3 CH4 CH3SH c-C2H4O l-HC6H CH3C(O)NH2
CO HCO+ HCCN HC3N HC3NH+ H2CCHOH CH2CHCHO C8H–
CO+ HCS+ HCNH+ HC2NC HC2CHO C6H– CH2CCHCN C3H6
CP HOC+ HNCO HCOOH NH2CHO
SiC H2O HNCS H2CNH C5N
HCl H2S HOCO+ H2C2O l-HC4H
KCl HNC H2CO H2NCN l-HC4N
NH HNO H2CN HNC3 c-H2C3O
NO MgCN H2CS SiH4 H2CCNH
NS MgNC H3O+ H2COH+
NaCl N2H+ c-SiC3 C4H–
OH N2O CH3
PN NaCN
SO OCS
SO+ SO2
SiN c-SiC2
SiO CO2
SiS NH2
CS H3+
HF H2D+, HD2+
SH SiCN
HD AlNC
FeO SiNC
O2 HCP
CF+
SiH
PO
>150 Molecules Detected
H. S. P. Müller, F. Schlöder, J. Stutzki, and G. Winnewisser,J. Mol. Struct. 742, 215–227 (2005)
H. S. P. Müller, S. Thorwirth, D. A. Roth, and G. Winnewisser,Astron. Astrophys. 370, L49–L52 (2001)
Previous Surveys of Orion KLOVRO survey
215 – 263 GHzRMS ~150 mK
800 resolved spectral features29 molecular species IDed
CSO survey325 – 360 GHzRMS ~250 mK
717 resolved spectral features34 molecular species IDed
IRAM 30m survey80-115.5, 130-178, 197-281 GHz
RMS ~20 mK14,400 resolved spectral features
191 molecular species IDed
Assignment Progress
Lines Observed 5378
Lines Identified 1094 (20.34%)
Unidentified Lines 4284 (79.66%)
RMS 30 mKSimilar Surveys Completed for 4 other star forming regions and partial coverage on 7 other sources
Molecule Previously Observed Transitions Newly Observed Transitions
HDO 2 1
CN 11 1
CO 2 0
DNC 1 0
C17O 1 0
H2CO 1 1
CH3CCH 2 4
HNCO 3 0
C33S 1 013CS 1 1
C34S 1 1
CH3CHO 4 45
CH3OH 43 3813CH3OH 11 39
HCOOCH3 105 169
CH3OCH3 13 64
HC3N 7 28
C2H3CN 30 46
Assignment Progress
Assignment ProgressMolecule Previously Observed Transitions Newly Observed Transitions
13CH3CN 7 3
CH313CN 1 2
CH2CO 1 2
H2CS 7 2
CH3CN 20 7
HCOOH 7 6
C2H5CN 55 19
OCS 2 0
O13CS 1 1
OC34S 1 2
SO2 19 834SO2 8 12
CH3NH2 0 12
CH3NO 0 12
CH3CH2OH 0 74
C3H6O 0 70
C2H6O2 0 28
CH2DCN 0 15
Other Observatories
ALMA (ESO / NAOJ / NRAO) photo by Nick Whyborn, 3 June 2010.
ALMA
Herschel/HIFI
SOFIA
http://www.sofia.usra.edu/
http://www.esa.int/esaSC/SEMIO99L6VE_index_0.html
Existing Laboratory Analysis Programs
• Do not account for observational parameters (beam properties, telescope efficiency)
• Cannot input or determine physical parameters of source (temperature, column density, velocity, structure)
Existing Observational Analysis Programs
• Can only fit physical parameters for one molecule at a time
• Restricted options for spectral simulation and fitting
• Relies on older versions of catalogs
Program Requirements
• Automated line identification for multiple species
• Least squares analysis of spectrum for multiple species with multiple physical parameters
• Automated global analysis of physical conditions
• Ability to update laboratory spectral data for observational comparison
Assignment Methods
Assignment Methods
Assignment Methods
• Automated Line Identification
• Automated Line Fitting
• Automated Boltzmann Analysis
Program Goals
AcknowledgementsThe Widicus Weaver Group:
Thomas AndersonBrandon CarrollJay KrollJacob LaasPatrick LanterBrett McGuireSusanna Widicus Weaver
Caltech/CSO:
Matthew SumnerDarek LisFrank RiceTom PhillipsGeoffrey BlakeCSO Local Staff