thermo gravimetric analysis (tga)
TRANSCRIPT
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Thermo Gravimetric Analysis (TGA)
SAIKRISHNA UGGULecturer in Chemistry
P. R. Govt. College (A)KAKINADA
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Contents…
➢Thermal Methods introduction & Classification
➢TGA, DTA, DSC & EGA - Definitions
➢TGA Principle
➢Thermogram & Different types of TG curves
➢Mechanism of weight change in TGA
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What are Thermal Methods ?
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Thermal Methods
Heat
Change in Physical Property
Applied Thermal analysis techniques
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Thermal Methods…
Thermal methods of analysis, comprises ofgroup of analytical techniques in whichchanges in physical or chemical properties of asubstance are measured as a function oftemperature.
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Types of Thermal Methods
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TGA
Thermo gravimetric analysis (TGA) isa technique in which a change inweight of a substance is measured asa function of temperature.
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DTA
Differential thermal analysis is atechnique in which the temperaturedifference between a substance and areference material is measured as afunction of temperature.
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DSC
Differential scanning calorimetry is atechnique in which a change in heatenergy between a substance and areference material is measured as afunction of temperature.
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EGA
Evolved gas analysis, in which qualitativeand quantitative evaluations of volatileproducts formed during thermal analysisof TGA or DTA or DSC interfaced with FTIRor MS.
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What is TGA?
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Principle of TGA….
Principle of Thermo Gravimetry:
Thermo Gravimetry (TG) or Thermo GravimetricAnalysis(TGA), is an analytical technique inwhich a change in the weight of a substance isrecorded as a function of temperature.
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Thermogram or TG Curve….
Thermo gravimetric analysis results areexpressed in the form of, a thermogram ora thermo gravimetric curve, which is a plot ofweight percentage Vs. temperature
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Derivative TG Curve…
Derivative thermo gravimetric (DTG) curveis the plot of first derivative of the TGcurve vs. temperature. It is also known asa decomposition curve.
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Thermogram
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Different regions in TG Curve
Horizontal portions (Plateaus) indicateregions where there is no weight loss.
Curved portions indicate regions ofweight loss.
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TG Curve - Regions
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Different types of TG Curves
(i). No Decomposition with loss of
volatile products
(ii). Rapid initial mass loss characteristic
of desorption or drying
(iii). Decomposition in single stage
(iv). Multi stage decomposition
(v). Multi stage decomposition but no
stable intermediate
(vi). Gain in weight due to sample
reaction
(vii). Reaction product decompose
again.
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Significance of TG Curve
The measured weight change in TGcurve gives information about,
➢ Sample composition
➢ Thermal stability of the compound
➢ Material Characterization
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Mechanism of weight change in TGA
Weight Loss due to,
➢ Decomposition
➢ Evaporation
➢ Reduction
➢ Desorption.
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Mechanism of weight change in TGA
Weight Gain due to,
➢ Oxidation
➢ Absorption
➢ Adsorption
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Thank You……