thermo1 kef 1b thermokrasia diergasies notes
TRANSCRIPT
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 1
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I
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1
2
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1, 2, 2
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1, 2, 3
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T1
T1
T2
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1, 2, 4
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,,
T1TT11
T2TT22
,,
T1TT11
T2TT22
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1, 2, 5
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TT11TT22
21 TT >
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..
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1, 2, 8
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...
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 9
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, , CC
BB
DD
AA
DD
CC()()
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1, 2, 10
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, ,
..
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 11
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:
2
X1,Y1
X2,Y2
X3,Y3
X1,Y1
X
Y
X2,Y2
X3,Y3
X4,Y4
Y
X
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 12
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()
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 13
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 14
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1-1 : .
P
(
' R
(
)
emf
L
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 15
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()= () (1) = 273.16 (2)
(1) (2) --> 273.16 = t --> = 273.16 / t (3)
(1) (3) --> ()= 273.16 / t
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 16
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,
Pt
t0P P
Plim16.273
t
=
Pt (mm Hg)
tP
P16.273P)( =
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 17
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R=Ro(1+A t +B t2) t C,
Ro0C
(Thermal Sensitive
Resistor)
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 18
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Kelvin
P = 1 atm
T = 273.16 K
P = 1 atm
T = 273.15 K
P = 1 atm
T = 373.15 K
KelvinKelvin
P = 1 atmP = 1 atm
T = 273.1T = 273.166 KK
P = 1P = 1 atmatm
T = 273.1T = 273.155 KK
P = 1 atmP = 1 atm
T = 373.15 KT = 373.15 K
Celsius
P = 1 atm
T = 0.1 oC
P = 1 atm
T = 0 oC
P = 1 atm
T = 100 oC
1 oC = 1 K
CelsiusCelsius
P = 1 atmP = 1 atm
T = 0T = 0.1.1 ooCC
P = 1P = 1 atmatm
T =T = 00 ooCC
P = 1 atmP = 1 atm
T = 100T = 100 ooCC
11 ooC = 1 KC = 1 K
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1, 2, 19
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T(K) = T(oC) + 273.15
T(R) = T(oF) + 459.67
T(R) = 1.8 T(K)
T(oF) = 1.8 T(oC) + 32
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1, 2, 20
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1, 2, 21
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..
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..
mol
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 22
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,, (2 1 )
P,V,T
, , .
()
,
,
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 23
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** (..)
(- )
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1, 2, 24
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P, V, T
2
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 25
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()
.
()
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 26
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.
.
. Pv=RT
......V
C(T)
V
)(1
RT
PV2
++
+=
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 27
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,p
, V
, T
f(P,V,T) = 0f(P,V,T) = 0
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 28
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 29
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1
2
p
V
T
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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.
1, 2, 30
--
:
.
T1 T1+dT T 1+2dT T 2
T1 T1+dT T 1+2dT T 2
.
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 31
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::
()()
T
T
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1, 2, 32
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T
T
,,
T
T
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 33
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;
;
p
V
T
S1
S2
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 34
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T
1
2
1p
V 2
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 35
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P1
P2
1 2
I
II
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 36
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::
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 37
--
PVT
-PVT
- dV, dP ,
.
- V=V(T,P)
() :
dPP
VdT
T
VdV
TP
+
=
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 38
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PVT
dPP
VdT
T
VdV
TP
+
=
1 V V T= =
----> 0
( ) PT
V
V
1
=
TP
V
V
1
=
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 39
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yz
x xdx dy dz
y z
= +
x z
y ydy dz dx
z x
= +
1
z zz z
x y x y=1 (1)y x y x
=
f(x,y,z)=0 x(y,z) y(z,x)
y xz
x x z (2)
y z x
=
zz z
x x w (3)
y w y
=
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 40
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=(,) ddTT
dT
+
=
T
=
=
d
1
dTd +=
(KN/m2) KPa
d dL / L L:
(K)
Hook = (=)
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7/23/2019 Thermo1 Kef 1b Thermokrasia Diergasies Notes
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1, 2, 41
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= F /2b
: (dyn/cm)
, A, T