Tins PUlles

Tinus Pulles

Guidebook revisionPriorities for scientific improvements

What we have

• Many chapters in zero order drafts ready. Each of these chapters has

• Process descriptions• Decision trees• Tier 1 methods and default values• SNAP translated in Tier 2 methds• Some Tier 3

• ESPREME• Heavy metals

• TNO projects• POPs

• Other information?

What we need

• Complete all Tier 1 tables• All relevant pollutants• Uncertainty ranges• References, where possible

• Complete Tier 2 tables, where we need those• All tables cover all relevant pollutants• Uncertainty ranges• References, where possible

2.C.1 Iron and Steel

Blast FurnacePig iron

productionIron Ore Add.

Coke oven gas

Steelmaking(Basic Oxygen

Furnace) Steel to Steel Processing

CokePlant

SinterPlant

PelletizingPlant

Coke breezeIron Ore Add.

Coking coal

Basic Oxygen Furnace Gas

Pig Iron to Iron Processing

Coal injection

Code

NFR Source Category 2.C.1

Fuel NA

Lower Upper

Particulates

Total suspended particulate 1.6 kg/Mg steel

PM10 1.0 kg/Mg steel

PM2.5 0.8 kg/Mg steel

Heavy metals

Arsenic 0.1 g/Mg steel

Cadmium 0.2 g/Mg steel

Chromium 0.9 g/Mg steel

Copper 1.2 g/Mg steel

Mercury 0.1 g/Mg steel

Nickel 0.5 g/Mg steel

Lead 7.9 g/Mg steel

Selenium 0.0 g/Mg steel

Zinc 6.0 g/Mg steel

Persistant Organic Pollutants

Dioxins and furans 24 μg TEQ/Mg steel

Hexachlorobenzene 51 μg/Mg steel

Polychlorinated biphenyls 0.32 mg/Mg steel

Polyaromatic hydrocarbons 2.8 g/Mg steel

Aromatic hydrocarbons (incl. benzene) 14.3 g/Mg steel

Benzene 0.45 g/Mg steel

Pollutant Value Unit

95% confidence interval

Tier 1 default emission factorsName

Iron and Steel production

not applicable

2.C.1 Iron and SteelTier 1

Code

NFR Source Category 2.C.1

Fuel NA

Lower Upper

Particulates

Total suspended particulate 1.6 kg/Mg steel

PM10 1.0 kg/Mg steel

PM2.5 0.8 kg/Mg steel

Heavy metals

Arsenic 0.1 g/Mg steel

Cadmium 0.2 g/Mg steel

Chromium 0.9 g/Mg steel

Copper 1.2 g/Mg steel

Mercury 0.1 g/Mg steel

Nickel 0.5 g/Mg steel

Lead 7.9 g/Mg steel

Selenium 0.0 g/Mg steel

Zinc 6.0 g/Mg steel

Persistant Organic Pollutants

Dioxins and furans 24 μg TEQ/Mg steel

Hexachlorobenzene 51 μg/Mg steel

Polychlorinated biphenyls 0.32 mg/Mg steel

Polyaromatic hydrocarbons 2.8 g/Mg steel

Aromatic hydrocarbons (incl. benzene) 14.3 g/Mg steel

Benzene 0.45 g/Mg steel

Pollutant Value Unit

95% confidence interval

Tier 1 default emission factorsName

Iron and Steel production

not applicable

2.C.1 Iron and SteelTier 2

Code

NFR Source Category 2.C.1

Fuel NA

SNAP (if applicable) 040202040203

Technologies/Practices

Region or regional conditions

Abatement technologies

Other

Lower Upper

Particulates

TSP 0.24 kg/Mg pig iron 0.12 0.48

PM10 0.192 kg/Mg pig iron 0.096 0.384

PM2.5 0.12 kg/Mg pig iron 0.06 0.24

Heavy Metals

Arsenic 0.0003 g/Mg pig iron produced

Cadmium 0.0093 g/Mg pig iron produced

Chromium 0.015 g/Mg pig iron produced

Copper 0.015 g/Mg pig iron produced

Mercury 0.003 g/Mg pig iron produced

Nickel 0.052 g/Mg pig iron produced

Lead 0.043 g/Mg pig iron produced

Zinc 0.601 g/Mg pig iron produced

POPs

Poly-aromatic hydrocarbons 2.5 g/Mg pig iron

Aromatic hydrocarbons (incl. benzene) 14.3 g/Mg pig iron

Benzene 0.45 g/Mg pig iron

Pollutant Value Unit 95% confidence interval

Tier 2 emission factorsName

Iron and Steel Production

not applicable

Blast Furnace ChargingPig Iron Tapping

Pig Iron production

So: what science do we need

• We need to complete all tables• Heavy Metals:

• Jochen Teloke will support on a bidget provided by Germany• POPs

• Hugo Denier van der Gon will provide POP EFs.

And in the end…we might win a Nobel Prize

IPCC celebrating the 2007 Nobe Peace PrizeGeneva, October 17th 2007