title 正方格子量子スピン系で実現した113磁化 プラ … · title...

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Title <研究ノート>正方格子量子スピン系で実現した113磁化 プラトー Author(s) 辻本, 吉廣; 陰山, 洋; 網代, 芳民; 吉村, 一良 Citation 低温物質科学研究センター誌 : LTMセンター誌 (2008), 12: 12-20 Issue Date 2008-06-01 URL https://doi.org/10.14989/153219 Right Type Departmental Bulletin Paper Textversion publisher Kyoto University

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Title <研究ノート>正方格子量子スピン系で実現した113磁化プラトー

Author(s) 辻本, 吉廣; 陰山, 洋; 網代, 芳民; 吉村, 一良

Citation 低温物質科学研究センター誌 : LTMセンター誌 (2008),12: 12-20

Issue Date 2008-06-01

URL https://doi.org/10.14989/153219

Right

Type Departmental Bulletin Paper

Textversion publisher

Kyoto University

DEF+*+678)GHIJK1/3LMNO<-

Realization of the 1/3 Magnetization Plateau in Square-Lattice Quantum Spin systems

PQRSTUVWTXYZ[TR\] ̂ÁÂÃ�Ã�ù ñ���� M�¸û

Yoshihiro Tsujimoto, Hiroshi Kageyama, Yoshitami Ajiro, Kazuyoshi Yoshimura Department of Chemistry, Graduate School of Science, Kyoto University

A new triple-layered perovskite (CuBr)Sr2Nb3O10 with the S = 1/2 square lattice, has been prepared by the topotactic ion-exchange reactions. Specific heat measurements in zero fields revealed two anomalies at low temperatures, suggesting the presence of successive phase transitions due to the competing ferro- and antiferromagnetic interactions in the layer. When the magnetic field is switched on, a novel phase appears which is characterized by a 1/3-plateau of the full magnetization, which has only been theoretically expected for triangular-based lattices.

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ÍdØ`àJÏJ, 16 ÅVKÅ32 ÅNdædÊdK�0^Ä#0^sbÉÊÎE°÷4Ä, 1/3LMNO

<-bS`0 (2.4 < H < 8.2 T) �Ãð`ª«LÍ (Hs = 14.4 T)Îf�÷4áÄÅábQR.GÅÀt

uGßÏÙàL×'(Î��41Å, LͳGb³�+u��NMRââ΢ØÙî�Óß4à

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[1] A. P. Ramirez, Annu. Rev. Mater. Sci. 24, 453 (1994).

[2] H. Kageyama, Frontiers in Magnetic Materials, ed. A. N. Narlikar, p. 611 (Springer, Germany, 2005).

[3] S. Kini, E. Kaul and C Geibel, J. Phys.: Condens. Mater 18, 1303 (2006). [4] H. Kageyama, T. Kitano, N. Oba, M. Nishi, S. Nagai, K. Hirota, L. Viciu, J. B. Wiley, J. Yasuda, Y. Baba, Y.

Ajiro and K. Yoshimura, J. Phys. Soc. Jpn. 74, 1702, (2005). H. Kageyama, J. Yasuda, T. Kitano, K. Totsuka,

Y. Narumi, M. Hagiwara, K. Kindo, Y. Baba, N. Oba, Y. Ajiro and K. Yoshimura: J. Phys. Soc. Jpn. 74, 3155, (2005). A. Kitada, Z. Hiroi, Y. Tsujimoto, T. Kitano, H. Kageyama, Y. Ajiro and K. Yoshimura: J.

Phys. Soc. Jpn. 75, 113601 (2006).

[5] N. Oba, H. Kageyama, T. Kitano, J. Yasuda, Y. Baba, M. Nishi, K. Hirota, Y. Narumi, M. Hagiwara, K.

Kindo, T. Saito, Y. Ajiro and K. Yoshimura: J. Phys. Soc. Jpn. 75, 11360 (2006). [6] Y. Tsujimoto, Y. Baba, N. Oba, H. Kageyama, T. Fukui, Y. Narumi, K. Kindo, T. Saito, M. Takano, Y. Ajiro

and K. Yoshimura: J. Phys. Soc. Jpn. 76, 063711 (2007).

[7] T. A. Kodenkandath, J. N. Lalena, W. L. Zhou, E. E. Carpenter, C. Sangregorio, A. U. Falster, W. B.

Simmons, Jr., Charles J. O’Connor and J. B. Wiley, J. Am. Chem. Soc. 121, 10743 (1999). [8] T. A. Kodenkandath, A. S. Kumbhar, W. L. Zhou and J. B. Wiley: Inorg. Chem. 40, 710 (2001). [9] M. F. Collins and O. A. Petrenko: Can. J. Phys. 75, 605 (1997).

[10] T. Ono, H. Tanaka, O. Kolomiyets, H. Mitamura, T. Goto, K. Nakajima, A. Oosawa, Y. Koike, K. Kakurai, J.

Klenke, P. Smeibidle and M. MeiKner: J. Phy.: Condens. Matter. 16, S773 (2004). [11] H. Kikuchi, Y. Fujii, M. Chiba, S. Mitsudo, T. Idehara, T. Tonegewa, K. Okamoto, T. Sakai, T. Kuwai and H.

Ohta: Phys. Rev. Lett. 94, 227201 (2005).

[12] M. Yoshida, N. Ogata, M. Takigawa, J. Yamaura, M. Ichihara, T. Kitano, H. Kageyama, Y. Ajiro and K.

Yoshimura: J. Phys. Soc. Jpn. 76, 104703 (2006).

[13] T. Momoi, N. Shannon, P. Sindzingre: Meeting Abstracts of the Physical Society of Japan. 63, 505, (2008).

[14] M. Oshikawa, M. Yamanaka and I. Affleck: Phys. Rev. Lett. 78, 1984, (1997). [15] S. Nakatsuji, Y. Nambu, H. Tonomura, O. Sakai, S. Jonas, C. Broholm, H. Tsunetsugu, Y. Qiu and Y.

Maeno: Science 309, 1697 (2005).

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