titrations worksheet...a. equal to 7 b. less than 7 c. greater than 7 11. at the equivalence point,...

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Titrations Worksheet In an acidbase titration, a solution containing a known concentration of base is slowly added to an acid (or the acid is added to the base). Acidbase indicators can be used to signal the equivalence point of a titration (the point at which stoichiometrically equivalent quantities of acid and base have been brought together). The shape of the titration curve makes it possible to determine the equivalence point. The curve can also be used to select suitable indicators and to determine the K a of the weak acid or the K b of the weak base being titrated.1. What is the purpose of a titration? 2. What does the phrase stoichiometrically equivalentmean? 3. When you draw a titration curve what is on the X-axis? And the Y-axis? 4. Match the following words and definitions: a. Titrant b. Analyte c. Standardized d. Equivalence Point e. End Point f. Indicator 5. A) On the titration curve on the back of this sheet is there a buffer region? B) In what 2 combinations of analyte/titrant do we see this region arise? C) What is the significance of the Half-equivalence point? 6. Fill in the following table: Analyte/Titrant pH at equivalence point SA/SB pH=7 pH>7 WB/SA 7. What are the 4 considerations when choosing an indicator? i. Known to good precision ii. Where the titration is theoretically done iii. Stuff in the burrette iv. What is being analyzed v. How we see the reaction is over vi. Where we see the reaction is over

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Page 1: Titrations Worksheet...A. equal to 7 B. less than 7 C. greater than 7 11. At the equivalence point, what is in the flask? A.CH 3 COOH, H 2 O and KCH 3 COO B.KOH, CH 3 COOH and H 2

Titrations Worksheet

“In an acid–base titration, a solution containing a known concentration of base is slowly added to an acid (or

the acid is added to the base). Acid–base indicators can be used to signal the equivalence point of a titration

(the point at which stoichiometrically equivalent quantities of acid and base have been brought together). The

shape of the titration curve makes it possible to determine the equivalence point. The curve can also be used to

select suitable indicators and to determine the Ka of the weak acid or the Kb of the weak base being titrated.”

1. What is the purpose of a titration?

2. What does the phrase “stoichiometrically equivalent” mean?

3. When you draw a titration curve what is on the X-axis? And the Y-axis?

4. Match the following words and definitions:

a. Titrant

b. Analyte

c. Standardized

d. Equivalence Point

e. End Point

f. Indicator

5. A) On the titration curve on the back of this sheet is there a “buffer region”? B) In what 2 combinations

of analyte/titrant do we see this region arise? C) What is the significance of the “Half-equivalence

point”?

6. Fill in the following table:

Analyte/Titrant pH at equivalence point

SA/SB

pH=7

pH>7

WB/SA

7. What are the 4 considerations when choosing an indicator?

i. Known to good precision

ii. Where the titration is theoretically done

iii. Stuff in the burrette

iv. What is being analyzed

v. How we see the reaction is over

vi. Where we see the reaction is over

Page 2: Titrations Worksheet...A. equal to 7 B. less than 7 C. greater than 7 11. At the equivalence point, what is in the flask? A.CH 3 COOH, H 2 O and KCH 3 COO B.KOH, CH 3 COOH and H 2

8. What type of acid yields a weird 2 humped titration curve?

9. Calculate the pH at the equivalence point in the titration of 50.0 mL of 0.100 M CH3COOH with 0.100

M NaOH. (Ka=1.8 ∙ 10-5

)

The next 3 questions are concerning the titration of CH3COOH with KOH.

10. The pH at the equivalence point will be ___.

A. equal to 7

B. less than 7

C. greater than 7

11. At the equivalence point, what is in the flask?

A.CH3COOH, H2O and KCH3COO

B.KOH, CH3COOH and H2O

C.KOH, KCH3COO and H2O

D.CH3COOH and H2O

E.H2O and KCH3COO

F.KOH, CH3COOH, H2O and KCH3COO

12. True or false. A titration curve of this titration (CH3COOH with KOH) would not have a buffer region.

13. What type of titration is this? ( SA/SB, SB/SA, WA/SB, or WB/SA)

14. Which point on the curve represents the equivalence point?

15. At which point is the pH equal to the pKa?