today’s lecture 1/10/08 (3)

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Today’s Lecture 1/10/08 (3) • Block 1: Mole Balances (Review) Size CSTRs and PFRs given –r A =f(X) Conversion for Reactors in Series • Block 2: Rate Laws Reaction Orders Arrhenius Equation Activation Energy Effect of Temperature

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Today’s Lecture 1/10/08 (3). Block 1: Mole Balances (Review) Size CSTRs and PFRs given –r A =f(X) Conversion for Reactors in Series Block 2: Rate Laws Reaction Orders Arrhenius Equation Activation Energy Effect of Temperature. Levenspiel Plot. CSTR. - PowerPoint PPT Presentation

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Page 1: Today’s Lecture 1/10/08 (3)

Today’s Lecture 1/10/08 (3)

• Block 1: Mole Balances (Review)

Size CSTRs and PFRs given –rA=f(X)

Conversion for Reactors in Series

• Block 2: Rate Laws

Reaction Orders

Arrhenius Equation

Activation Energy

Effect of Temperature

Page 2: Today’s Lecture 1/10/08 (3)
Page 3: Today’s Lecture 1/10/08 (3)

fedA moles

reactedA moles X

D a

d C

a

c B

a

b A

ncalculatio of basis asA reactant limiting Choose

D d C c B b A a

Page 4: Today’s Lecture 1/10/08 (3)
Page 5: Today’s Lecture 1/10/08 (3)

Levenspiel Plot

FA 0

rA

X

Page 6: Today’s Lecture 1/10/08 (3)

CSTR

FA 0

rA

X

Area = Volume of CSTR

X1

V FA 0

rA

X1

X1

Page 7: Today’s Lecture 1/10/08 (3)

PFR

FA 0

rA

Area = Volume of PFR

V 0

X1FA 0

rA

dX

X1

Page 8: Today’s Lecture 1/10/08 (3)

•Review of Lecture 1

Page 9: Today’s Lecture 1/10/08 (3)

Two steps to get                   

Step 1: Rate Law

Step 2: Stoichiometry

Step 3: Combine to get

rA f X

rA g Ci

Ci h X

rA f X

Page 10: Today’s Lecture 1/10/08 (3)
Page 11: Today’s Lecture 1/10/08 (3)
Page 12: Today’s Lecture 1/10/08 (3)

Arrhenius Equation

Page 13: Today’s Lecture 1/10/08 (3)

Reaction Coordinate

Page 14: Today’s Lecture 1/10/08 (3)
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