(unit 1 - introduction) · pdf filee l e m en t s u s e sy m bo l s t o r ep r e s en t t he m...

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Ch

em

Re

vie

w P

t 1

Wha

t is

Che

mis

try?

�S

tud

y o

f p

rop

ert

ies o

f m

ate

ria

ls a

nd

th

e

ch

an

ge

s t

ha

t th

ey u

nd

erg

o

Wh

y S

tud

y C

hem

istr

y?

�S

atisfy

cu

riosity

�H

elp

s w

ith

:

�P

harm

aceuticals

�F

ert

ilizers

�P

art

of

the c

urr

iculu

m

�B

ridg

es t

he g

ap b

etw

een

vari

ous d

iscip

line

s

De

fin

itio

ns

�M

att

er

� a

nyth

ing

th

at

ha

s m

ass a

nd

take

s u

p

sp

ace

�C

lassifie

d in

to t

hre

e s

tate

s:

�G

as

�Liq

uid

�S

olid

�E

lem

en

ts �

su

bsta

nce t

ha

t ca

nn

ot

be

bro

ke

n d

ow

n

into

sim

ple

r su

bsta

nces

�A

tom

s �

sm

alle

st re

pre

sen

tative

part

icle

of

an

ele

me

nt

Sta

tes o

f M

att

er

Sta

te o

f M

att

er

Volu

me

Shap

eC

om

pre

ssib

ility

Dis

tance

B

etw

een

M

ole

cule

s

Gas

Vari

able

Vari

ab

leC

om

pre

ssib

leF

ar

apart

Liq

uid

Fix

ed

Vari

ab

leN

ot

com

pre

ssib

leC

loser

tog

eth

er

So

lidF

ixed

Fix

ed

Not

com

pre

ssib

leC

losest, H

eld

to

ge

the

r

De

fin

itio

ns

�P

ure

su

bsta

nce

� m

att

er

tha

t h

as d

istin

ct

pro

pe

rtie

s a

nd

a c

om

po

sitio

n t

ha

t d

oe

s n

ot

va

ry

fro

m s

am

ple

to

sa

mp

le

�E

lem

en

ts

�C

om

po

un

ds

�M

ixtu

res �

co

mb

ina

tio

n o

f 2

or

mo

re

su

bsta

nce

s w

he

re t

he

y r

eta

in t

he

ir p

rop

ert

ies

�H

om

og

en

eo

us (

aka

so

lutio

ns)

�H

ete

roge

ne

ou

s

Ele

me

nts

�U

se

sym

bo

ls t

o r

ep

rese

nt

the

m a

nd

pe

rio

dic

ta

ble

to

arr

an

ge

th

em

�11

7 k

no

wn

ele

me

nts

�1

to

82

are

sta

ble

exce

pt

43

& 6

1

�8

3 t

o 1

18

are

ra

dio

active

�1

to

94

occu

r n

atu

rally

�1

to

111

are

IU

PA

C c

ert

ifie

d

�11

2 to

11

6 a

nd

11

8 h

ave

be

en

ma

de

�11

7 h

as b

ee

n c

rea

ted

ye

t

Ma

tter

Uniform

T

hro

ugh

out

Ho

mog

en

eou

sH

ete

roge

neo

us

Hom

oge

ne

ous

Mix

ture

Pure

Substa

nce

Ca

n it

be s

ep

ara

ted into

sim

ple

r substa

nces?

Com

po

und

Ele

ment

Do

es c

om

positio

n

va

ry?

Pro

pert

ies o

f M

atte

r

�P

hysic

al p

rop

ert

ies c

an b

e m

ea

su

re o

r o

bserv

ed w

ithou

t chan

gin

g

the ide

ntity

or

co

mpositio

n o

f sub

sta

nce

�C

olo

r

�D

en

sity

�O

dor

�F

reezin

g P

oin

t

�M

eltin

g P

oin

t

�B

oili

ng

Poin

t

�H

ard

ne

ss

�C

hem

ica

l P

ropert

ies d

escri

be

ho

w a

co

mpou

nd

will

rea

ct

or

ch

ang

e

to form

new

substa

nce

s.

�F

lam

ma

bili

ty

�R

ea

ctivity w

ith W

ate

r

Pro

pert

ies o

f M

atte

r

�P

hysic

al P

rope

rtie

s fall

into

tw

o c

ate

go

ries

�In

ten

siv

e �

Do

es n

ot d

ep

end

on a

mo

un

t p

rese

nt

�D

en

sity

�V

isco

sity

�Te

mp

era

ture

�S

pe

cific

He

at

Ca

pa

city

�E

xte

nsiv

e �

Do

es d

epen

d o

n a

mou

nt pre

sen

t

�M

ass

�V

olu

me

�L

en

gth

�E

ne

rgy

Ch

ang

es in M

att

er

�P

hysic

al C

ha

ng

e �

ch

an

ge

in

ap

pe

ara

nce

bu

t n

ot

co

mp

ositio

n

�E

vap

ora

tio

n

�C

he

mic

al C

ha

ng

e �

ch

an

ge

in

co

mp

ositio

n

cre

atin

g a

ne

w s

ub

sta

nce

�Ir

on

re

actin

g w

ith

oxyg

en

to

fo

rm r

ust

�P

en

ny in

Nitri

c A

cid

Se

pa

rating

Mix

ture

s

�S

ep

ara

te m

ixtu

res b

ase

d u

po

n u

niq

ue

p

rop

ert

ies

�H

ow

wo

uld

yo

u s

ep

ara

te g

old

fro

m iro

n?

�B

y c

olo

r

�B

y m

ag

ne

tism

� I

ron

is m

ag

ne

tic,

go

ld is n

ot

�B

y a

dd

ing

acid

s �

Iro

n w

ill r

ea

ct,

gold

will

not

�H

ow

wo

uld

se

pa

rate

sa

lt w

ate

r?

�B

oili

ng

, C

on

de

nsin

g

�C

hro

ma

tog

rap

hy

Scie

ntific M

eth

od

�C

olle

ct

Info

rma

tio

n/o

bse

rva

tio

ns t

o fin

d a

pa

tte

rn

�H

yp

oth

esis

� t

en

tative

exp

lan

atio

n o

f a

se

rie

s o

f o

bse

rva

tio

ns

�E

xp

eri

me

nt

� to

te

st h

yp

oth

esis

�C

ontr

ols

�V

ariable

s

�A

na

lysis

� lo

ok o

ve

r a

nd

in

terp

ret

da

ta

�C

on

clu

sio

n �

do

es y

ou

r d

ata

ag

ree

with

yo

ur

hyp

oth

esis

�L

aw

� v

erb

al sta

tem

en

t o

r m

ath

em

atica

l e

qu

atio

n t

ha

t su

mm

ari

ze

s a

bro

ad

va

rie

ty o

f o

bse

rva

tio

ns

�T

he

ory

� E

xp

lan

atio

n o

f g

en

era

l p

rin

cip

les o

f p

he

no

me

na

with

co

nsid

era

ble

evid

en

ce

to

su

pp

ort

it th

at ca

n b

e u

se

d t

o m

ake

p

red

ictio

ns.

Ca

n n

ot

be

pro

ve

n.

Un

its o

f M

easu

rem

en

t

�Q

ualit

ative v

ers

us Q

uantita

tive

�C

oo

l vs.

65

ºF

�N

um

bers

must have u

nits

�7 B

ase U

nits

�M

ass �

kg

�L

eng

th �

m

�T

ime

� s

�Tem

pe

ratu

re �

K

�A

mo

un

t �

mol

�C

urr

ent

� A

�L

um

inous I

nte

nsity -

cd

Pre

fixe

s

�P

refixe

s s

ho

w d

eg

ree

�1

09

gig

a

- G

�1

06

me

ga

- M

�1

03

kilo

- k

�1

0-1

de

ci

-

d

�1

0-2

ce

nti

-

c

�1

0-3

mill

i

- m

�1

0-6

mic

ro

- �

�1

0-9

na

no

-

n

�1

0-12

pic

o

- p

�1

0-15

fem

to

- f

Co

nve

rsio

n P

ractice

�H

ow

ma

ny in

ch

es a

re t

he

re in

85

0 m

m?

�H

ow

ma

ny m

iles a

re t

he

re in

5.4

x1

06 c

m?

�H

ow

ma

ny p

ou

nd

s a

re t

he

re in

28

90

g?

Te

mpe

ratu

re a

nd D

eri

ve

d U

nits

�C

on

ve

rt b

etw

ee

n º

C a

nd

K

�ºC

+ 2

73.1

5 =

K

�D

eri

ve

d U

nits c

om

e f

rom

a c

om

bin

atio

n o

f b

ase

u

nits.

�V

elo

city �

m/s

�V

olu

me

� c

m3

�D

ensity �

g/m

L

De

nsity P

ractice

�W

ill b

all

with

a r

ad

ius o

f 0

.50

cm

an

d a

ma

ss o

f 2

.0 g

flo

at

in w

ate

r? T

he

de

nsity o

f w

ate

r is

1

g/m

L a

nd

th

e v

olu

me

of

a s

ph

ere

is 4

/3�

r3 .

�T

he

de

nsity o

f p

ure

silv

er

is 1

0.5

g/c

m3 a

t 2

0ºC

. If

5.2

5 g

of

pu

re s

ilve

r is

ad

de

d t

o a

gra

du

ate

d

cylin

de

r co

nta

inin

g 1

1.2

mL o

f w

ate

r, w

ha

t w

ill

the

fin

al vo

lum

e in

th

e c

ylin

de

r b

e?

Un

cert

ain

ty in

Me

asu

rem

ents

�E

xa

ct

Me

asu

rem

en

ts

�A

re k

no

wn

exa

ctly

�1

2 e

ggs in a

doze

n

�1

000

g in 1

kg

�2

.54 c

m in

1 in.

�In

exa

ct

Me

asu

rem

en

ts

�G

et

fro

m m

ea

su

rin

g y

ou

rse

lf

Pre

cis

ion a

nd

Accu

racy

�P

recis

e �

ho

w

me

asu

res a

re to

ea

ch

o

the

r

�A

ccu

rate

� h

ow

clo

se

m

ea

su

rem

en

ts a

re t

o

the

tru

e v

alu

e

Sig

nific

an

t F

igu

res

�S

ignific

ant F

igure

s �

write

mea

su

rem

en

ts s

o th

at on

ly th

e

last dig

it is u

ncert

ain

�R

ule

s

�0's

betw

ee

n n

on z

ero

un

its a

re s

ignific

an

t

�1

05

kg,

2000

5 m

L

�0's

at th

e b

egin

nin

g o

f a n

um

ber

are

not sig

nific

ant

�0

.0003

mg

�0's

at th

e e

nd o

f a n

um

be

r a

nd a

fte

r a

decim

al pla

ce

are

sig

nific

an

t

�0

.0500

m

�W

he

n a

num

ber

end

s in 0

's w

/o a

de

cim

al p

oin

t th

e 0

's m

ay o

r m

ay n

ot be

sig

nific

an

t

Sig

nific

an

t F

igu

res in

Ca

lcu

latio

ns

�M

ultip

lica

tio

n/D

ivis

ion

�A

nsw

er

ha

s a

ma

ny s

igfig

s a

s t

he

nu

mbe

r w

ith

the

fe

we

st

sig

figs

�A

dd

itio

n/S

ub

tra

ctio

n

�A

nsw

er

ca

n h

ave

as m

an

y d

ecim

al p

laces a

s t

he

n

um

be

r w

ith

th

e f

ew

est

decim

al p

lace

s

Sig

nific

an

t F

igu

res P

ractice

�C

alc

ula

te t

he

an

sw

er

to t

he

co

rre

ct

nu

mb

er

of

sig

nific

an

t fig

ure

s

1.0

028

+ 0

.22

1 +

0.0

103

37

7.2

55 �

6.8

35

0

(0.1

02

x 0

.08

21

x 2

73

)/1

.01

4.0

x1

04 x

5.0

21x1

0-3 x

7.3

499

3x1

02

Dim

en

sio

nal A

na

lysis

�M

eth

od

of

pro

ble

m s

olv

ing

wh

ere

un

its a

re

ca

rrie

d th

rou

gh

ou

t ca

lcu

latio

ns.

�U

se

co

nve

rsio

n f

acto

rs

�G

ive

n u

nit x

De

sir

ed

Un

it

G

ive

n U

nit

�E

xa

mp

le c

on

ve

rt 6

5 c

m t

o in

ch

es

65

cm

x

1

in

2

.54

cm

Dim

en

sio

na

l An

aly

sis

Pra

ctice

�H

ow

ma

ny s

eco

nd

s a

re t

he

re in

3 y

ea

rs?

�W

ill a

blo

ck o

f u

nkn

ow

n s

ub

sta

nce

with

a

vo

lum

e o

f 1

.2x1

04 i

n3 a

nd

a m

ass o

f 3

50

lb

flo

at

in w

ate

r?

Hom

ew

ork

�C

ha

pte

r 1

2,

12

, 1

4,

18,

20

, 2

4,

32

, 4

0,

46,

57