u.s. epa, pesticide product label, 3336 wp turf and ...user safely recommenim'!,ions:-wasir...

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IIII III 1111111 001001-00063-050799 Printed: 07:47:26 Tuesday, 08 Jun, 1999 # 18 / 3230 systems Integration Group, Inc.

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Page 1: U.S. EPA, Pesticide Product Label, 3336 WP TURF AND ...USER SAFElY RECOMMENIM'!,IONS:-WasIr hands-befOIe eating, dIinking; cirewinggmn; using tobacco or using the toilet Remove clothing

IIII III 1111111 001001-00063-050799

Printed: 07:47:26 Tuesday, 08 Jun, 1999 # 18 / 3230

systems Integration Group, Inc.

Page 2: U.S. EPA, Pesticide Product Label, 3336 WP TURF AND ...USER SAFElY RECOMMENIM'!,IONS:-WasIr hands-befOIe eating, dIinking; cirewinggmn; using tobacco or using the toilet Remove clothing

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100/ --63 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHINGTON. D.C. 20460

IMO

MAY 7 ~ OFFICE OF

PAE'IHlTlON. PESTICIDES AND TOXIC SUBSTANCES

Richard F. Fletcher Technical & Regulatory Manager Cleary Chemical Corporation 178 Ridge Road, S .... ·'+e A.

Dayton, NJ 08810

Dear Mr. Fletcher:

Subject: EPA Reg. No. 1001-63 3336 WP; Label Amendment Your Submission dated February I, 1999

The labeling referred to above, submitted in connection with the registration under Federal Insecticide, Fungicide, and Rodenticide Act, as amended, is acceptable provided you make the following changes on page 4:

1. Replace the 4th sentence, "Add required amount of 336 WP .... amount of water" with" Add required amount of 3336 WP to a partially filled tank ('h total volume) and agitate by mechanical or hydraulic means while adding the remaining required amount of water. Once the water soluble bags have completely dissolved add tank mix product if used (see below)". It is important that the water soluble bags are completely dispersed in the required amount of water before adding any tank mixes for uniform mixing and to prevent precipitation of dissolved water soluble bag film.

2. Add "water soluble bags" before "wettable powders, ... " in the second sentence under Tank Mixing Directions.

3. Add at the end of Tank Mixing Instructions, "Tank mix products containing boron or releasable free chlorine will affect the solubility of water soluble (PV A) film. Thoroughly rinse the spray tank of any boron containing spray solution prior to adding any water soluble bags. Even minimal carryover concentrations of boron in the spray tank may cause the water soluble bag material dissolved in water to precipitate and form insoluble residue inside the spray tank" .

.. continued ..

R.cyclld'R.cyclable • Pmted wllh VegetabM 011 Based Inks on 1ClO'% Recyc~ Paper (40% Poslconsumef)

Page 3: U.S. EPA, Pesticide Product Label, 3336 WP TURF AND ...USER SAFElY RECOMMENIM'!,IONS:-WasIr hands-befOIe eating, dIinking; cirewinggmn; using tobacco or using the toilet Remove clothing

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EPA Reg. No. 1001-63, can/d ...

A stamped copy of the label is enclosed for your records, Submit one (1) copy of your final printed labeling before you release the product for shipment, Your release for shipment of the product bearing the amended labeling constitutes acceptance of these conditions. If these conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA section 6( e). Should you have any questions, do not hesitate to contact Dr. S (Oonni) Oonnithan at 703-605-0368.

Encl.

Sincerely,

IZIvr;/uJdf~ Mary L. Waller Product Manager 21 Fungicide Branch Registration Division (7505C)

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Page 4: U.S. EPA, Pesticide Product Label, 3336 WP TURF AND ...USER SAFElY RECOMMENIM'!,IONS:-WasIr hands-befOIe eating, dIinking; cirewinggmn; using tobacco or using the toilet Remove clothing

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EPA Reg. No.1 00 1-63 AMEND 3336WPIWSB 02/01/99 I

ACCEPTED with COMMENTS

In V~ Le"'f~ted:

3336.WP MAY 7 1999

TURF AND ORNAMENTAL SYSTEMIC FUNGICIDE IN WA:rER. SOWBLE- BAGS

.

For the.. prevention.. and. control of turf diseases and. the. diseases.. of annual and. perennial fuwe:rs,. bedding plants, foliage plants, ground covers, plus deciduous and evergreen trees and shrubs.

ACTIVE INGREDIEN,T: Tbiophanate"mclhyl (dimeth¥i 4,4' -o--pheny1enebis[JAhioallophanate.]) .. __ . __ ... _ ...... _ . .50''10_

INERT INGREDIENTS ................................................................................................................ 50% TOTAL. ................................... .. 100"A

Keep Out Of Reach Of Children

CAUTION

FIRST AID IF SWALLOWED: Induce vomiting immediately by giving two glasses of water and sticking finger down throat. Contact a physician Qf poison control center. Never give anything by mouth to an unconscIous person. IF IN EYES: Immediately flush-eyes withpleflty of water for at least 15 minutes. Get medicaJatte.ntion if irritation persists. IF ON SKIN: Wash exposed areas with soap and water. Seek medical attention as needed. IF INHALED: Remove exposed person. toJi:esh.air_ Ifnot breathing, give artifi.cialrespiratiolL Get medical attention.

Cleary Chemical Corporation

17S Ridge.Road,.SuiteA,.D~New Jersey 08810-15.01

732-329-8399 800-524-1662

NET CONTENTS: 2.PoUDd£ (0.9 Kg) (CONTAINING 4 - 8 OUNCE WATER SOLUBLE BAGS)

EPA Reg. No. 100L-63 EPA EsL No. 33967-NJcl

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EPARe& No. 1001-63 AMEND 3336 Wl'IWSR

PRECAUTIONARY STATEMENTS HAZARDS.TO HUMANS. AND-DOMES.TK: ANIMAlS-

Q2/0lJ99 2

CAUTION: Harmful if swallowed, inhaled, or absorbed through the skin. May cause irritation of eyes, nose,.throa1,-and skin. Alioidrontact witheyes..aruLskiIL AYoid.breatbing dust or.spray mist.

PERSONAL PROTECTIVE EQUIPMENT (PPE)

WI'S Uses: Applicators and other handlers-who handle this.. pesticide- for any use covered-hy the­Worker Protection Standard, 40 CFR Part 170, must wear: long-sleeved shirt, long pants, and sheeswitb-sock,s. NON-WI'S Uses: Applicators and. other handlers who handle. this pesticide- foL any US~ NOT covered by the Worker Protection Standard, 40 CFR Part 170, should wear: long-sleeved shirt, long. pants,. and shoes with socks.. Fellow manllfactmer's instructions fOL cleaning/maintaining PPE~ If no such. instructions foL washables, use detergent and hot water. Keep and wash PPE separately from other laundry.

USER SAFElY RECOMMENIM'!,IONS:-WasIr hands-befOIe eating, dIinking; cirewinggmn; using tobacco or using the toilet Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling this product. As soon as·possible, wash thoroughly and change into clean clothing.

ENVlRONMENTALHAZARDS..

This pesticide is toxic to fish. Do not apply directly to wa!er.,cor to areas wheresurfucewater is.present.­or to intertidal areas below the mean high water mark. Do not contaminate water by disposal of equipment.washwaters. Do not apply, allow to driii,.-or draiJLor fiuslLequipmentonto non-target=-

STORAGE AND DISPOSAL Do. not rontaminate water, food,.-or feed by stor~or disposal Storage: Store in the original container in a dry, temperature controlled area. Do not store in a manner where cross-contamination with other pesticides,Jertilizers, fuodor feedcouldoccUL Ifspi1leddming .. storage or handling, contain/re-capture spillage and dispose of in accordance with the Pesticide Disposal Instructions listed below. Pesticidellisposal: Wastes res! l!ting from theuse of this. product are toxic and may be. disposed of OD..

site or at an approved waste disposal facility. Container Disposal: When all water soluble b3g.S-are used,.-dispose. of empty foil package in a sanitary landfill, or by incineration, or, if allowed by State and local authorities, by burning. If burned, stay out of smoke.

DIRECTIONS FOR USE

IT IS A VIOLATION OF FEDERAL LAW TO USE THIS PRODUCT IN A MANNER INCONSISTENT WITH ITS LABELING. Do not apply this product in a way that will contact workers or other persons, either: directly O[ through. drifL Only protected handlers. IDay be in the arelL

during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide-regJ dation.

!AGRICULTURAL USE REQUIREMENTS

1" fo

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EPA Reg.. No, 1001-63 AMEND 3336 Wl'iWSIJ 02/01199 3

Use this product only in accordance with its labeling, and with the Worker Protection Standard, 40 CFR part 170. This standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE); and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard.

Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. Exemption: !fthe product is applied by drenching, the Worker Protection Standard, under certain cireumstances-, allows wOfkers-to enter the treated area ifthere will be ne contact with anything that has been treated.

PPE required for early entrytu tIeatai areas thatis pellnitted millet the WorkerPlOtection Standard­and that involves contact with anything that has been treated, such as plants, soil, or water, is: coveralls, waterproof gloves, and shoes with socks.

NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box only apply to uses ofthis product that are NOT within the scope of the Worker Protection Standard for agricultural pesticides (40 CFR part 170). The WPS applies when this product is used to produce agricultural plants-on fanus, forests, nurseries, or greenhouses.

Turf and Landscape Uses: Keep children and pets out of treated areas until sprays have dried.

GENERAL INFORMA nON 3336 WP is a broa£ispectrum fungicide-exbibiting preventative, curative and systemic. prop~ It Ls­useful on a wide variety of turf and ornamental disease problems. Apply 3336 WP with ground or aerial equipment, llSing.-sufficient volume of spray to provide. thorough. coverage.. Use the higher. rates. under conditions of severe disease pressure. Also, see local State Extension Service recommendations for applicatioa schedules. Chemigation instructions follow "Directions For Use". Reruian(ifullow these instructions carefully for this method of application. Resistance.Management- To lUloilLthe developrnentoftolerant strains of~3336. WP should. be used with fungicides of different modes of action. Cleary Chemical does not recommend the use of products containing benomyl, or tbiabendazole in combination ot: rotation with 3336 WP. These utili.za similar chemistry and mode of action and can contribute to development of disease tolerance. If, after using 3336 WP as recommended,. the. treattnent is not effuctive, a tolerant strain of fungi. may be. present. Consult your local Cleary Chemical representative, your State Agricultural Experiment Station,. or your State Cooperative Extension Service fur. proper disease identification ami arlvice on the prompt use of some other suitable fungicide or disease control strategy. As long as recommended precautionsarefullowed, 3336 WP can remain useful fur. disease. controL Mixing Instructions: 3336 WP consists of a protective outer resealable package containing water soluble bags. Do not allow the. bags to become- wet prior. to addin~to the tank. Do nol handle water soluble bags with wet hands or wet gloves. Depending on the degree of agitation and water temperature, the water soluble bas-should be-completely dissolved within five minutes.

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EPA Reg. No. lOOl.(i3AMEND 33J6WPIWSB 02I0Lm I 4

Avoid adding bags near recirculation outlets as they might block outlets before completely dissolving. High pH environments cause a shortened tlUllL life. for suspended. producL Tk buffering of tank water to pH 6-7 prior to the addition of 3336 WP is recommended. Add required.amount of3336 WP to a partially fiIl.ecLtlUllL(U2.totaLvolume), agitate by mecbanical or hydraulic means, add tank mix product ifused (see below), agitate again and then add remaining required. amount of water. Continuous agitation is. recommended. to keep the.material in propeL suspension. For best results, use spray mixture the same day it is prepared. Tank.Mixing.lnstructions~3336. WP is.compahble.witb most commonly us.edpesticides . If tank mixing with other materials, add products in the following order: wettable powders, dry flowables, liquid.fluwables,. emllisifiableconcentrates, and s.olllble materials s.uciLas fertilizers.. No claim of compatibility with other products is implied. Do not tank mix with copper-containing materials or with highly alkaline pesticides,.s.uciLas..Bordeallx mixhlre or lime.sulfuL Consult the intended tlUIILmix partner product label for appropriate application rates and use instructions. Follow the label directions fur the mos.t restrictive. of label. precm Itions and limitations.. This. product cannot be. rnixedwitb. any product containing a label prohibition against such mixing. Read and observe the most restrictive prec8J Itionary statements.and.other infonnation appearing on pmdllct labels us.edin.~ 3316 WP may be applied in conjunction with chemically neutral liquid fertilizers. Application in conjunction with highly alkaline fertilizers,.-s.uciLas.aqueous ammonia,. may cause a degradation of the pesticide,. resulting in reduced performance and should be avoided. CHEMIGATION Generic Requirements 1. Apply this product only through the follo\\1ng.types of systems: sprinkler including. .center pivot,­

lateral move, end tow, side (wheel) roll, traveler, solid set, or hand move; flood (basin); or drip (trickle) irrigation systern(s>-. Do not apply this productthroughany other type. of irrigation system

2. Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from non-

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uniform distribution of treated water. If you have questions about calibration, you should contact State Extension Service specialists, equipmentmanllfactmers or other experts. Do not connect an irrigation system (including greenhouse systems) used for pesticide application to a public. water system unless the pesticide Label-prescribed. safety devices for public. water systems are in place. A person knowledgeable. of the cbemigation systenund.responsible for its operatioIl"or under the supervision of the responsible person, shall shut the system down and make necessary adjustments shook! the need arise.

Specific Requirements 1. Public water system means a system for the provision to the public of piped water for. human

consumption if such system has at least 15 service connections or regularly serves an average of at least25 individuals daily atleast.60 days. out of they ear.

2. Chemigation systems connected to public water systems must contain a functional, reduced­pressure zone, backflow· preventer (RPZ~ or the functional equivalent in the water supply line. upstream from the point of pesticide introduction. As an option to the RPZ, the water from the public. water system should be. discharged into a reservoir tank prior to pesticide. introduction. There shall be a complete physical break (air gap) between the outlet end of the fill pipe and the top or overflow rim of the reservoir tank of at least twice. the. inside diameter of the fill pipe.

(off)

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EPA Reg. No. 1001-63 AMEND 3336 WP/wsB . 02101/99 5

3. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back towards.the.injection pump.

4. The pesticide injection pipeline must contain a functional, normally closed, solenoid-operated valve located on. the intake side of the-injection. pump and. connected to the system. interlock. to prevent. fluid from being drawn from the supply tank when the irrigation system is either automatically or mam wily shut.dn.wn.

5. The system. must contain functional interlocking control£ to automatiCJllly shut off the. pesticide injection pump when the water pump motor stops, or in cases where there is no water pump, when the water pressuredecreasestothe.poinLwhere.pesticidedistributionis.adYersely affected.

6. Systems must use a metering pump, such as a positive displacement injection pump (e.g. diaphragm. pUDl}l),. effectively designed andmnstDlcted .. of materials that are. compatible with. pesticides and capable of being fitted with a system interlock.

7. Do not apply when wind.speed favors.drift.beyond tbeareaintended for treatment Non Specific Requirements I. Remove. sca1e,. pesticide. resid"e, and.. other. foreigrL matter. from. the chenJical .. tank. and. entire

injector system. Flush with clean water. 2. Preparea.sllspension of product in the.mix. tank.OLStock.bncket Fill the tank. with. U201:.314 of the

desired amount of water. Start agitation and add the required amount of product to the solution along. with. the. renJaining volume of water..

3. Maintain a gentle agitation in the mix tank during application to assure a uniform suspension. Follow mixinginstructions and tank. mixing instructions previously indicated..

4. Start system and then uniformly inject the suspension of3336 WP into the irrigation line so as to deliver the desired- rate per. acre.. Allow sufficient time for. pesticide. to be flushe(Lthroughalllines and all nozzles before turning off irrigation system.

5. Greater accuracy in calibrationand.dis.tribution will be acbie.vedby injecting.a.larger volume. of a more dilute suspension per unit time.

t>. The suspension of 3336 WP should he.injecteci with. a positive dis.placement pump into the. main. line ahead of a right angle tum to insure adequate mixing.

Sprinkler (Overhead) Chemigation... Cbserve all instructions in the. General and. Specific. requirements sections above- and. the

following additional requirements: 1. The system must contain a functional check valve,. vacuum relief valve, and. low pressure drain

appropriately located on the irrigation pipeline to prevent water source contamination from bac~w

2. The irrigation line or water pump. must include. a Ii mctional pressure switch which will. stop the. water pump motor when the water pressure decreases to the point where pesticide distribution is adYersely affuc~d

Set sprinkler system to deliver 1110 to lL4 inclJes of water per. acre.. Volumes of water higher than this. may reduce efficacy. Application of more than recommended quantities of irrigation water per acre may result in decreased product performance.. Where. sprinkler distribution patterns do not overlap. sufficiently, unacceptable disease control may result. When system connections or fittings. leak,. when. nozzles dn. not provide. uniform distribution or when lines containing the product cannot be flushed and must be dismantled and drained in a center pivot system, block. the nozzle set nearest the. well pivot injection unit to prevent spray. bein&-applied to this.

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EPA R<g..No. 1001';;3 AMEND 3336WPJWSB Q2IOL99 6

area. Allow sufficient time for pesticides to be flushed through all lines and all nozzles before turning off irrigation wateL Flood (Basin) Chemigation 1. Systems using.a.grIDlity flow pesticide dispensingsystenwlUst meter the. pesticide into.the.wateLai.

the head of the field and down stream of a hydraulic discontinuity such as a drop structure of weir box to decreasepotential.for water source contamination frombackflow if water flow s1oJls--

2. Systems utilizing a pressurized water and pesticide injection system must meet the following requirements:. Observe aIlinstO!ctious-in the.General and Specific requirements sections above. and. items 1 and 2 of the sprinkler irrigation requirements.

Drip.(Trickle) Cbemigat\on Observe. all instruction& in the. C-.eneral and.Specific req"irementssections above-

TURF APPUCA nONS 3336 WP may be. u=Lan all fine. turf applications ~ascornmercial and residential lawns,. parks,. athletic fields, golf course greens, tees, and fairways, cemeteries, and sod farms of cool and warm season grasses such as Bentgrass, Blnegrass, Bermndagrass,Eescue., Ryegrass,. St. Angnstinegrass,­Zoysiagrass, or their mixtures. 3336 WP is not phytotoxic to any of the above mentioned grasses when use.dinacmrdance with the. label 3336 WP ism be.use.dSor the. prevention and controLoftb.e..diseases. mentioned below. It has both preventative and curative activity. Do not graze animals on treated turf Do not feed clippings to livestock or poultry. Do not exceed arnaxirnum.ofthre.e. (3) pounds active. ingredient per 1000 square feet per season from any thiophanate-methyl containing product.

Ground Application Instructions:Apply material with properly calibrated. hand. held,.. mechanical or motorized spray equipment or by chemigation through appropriate sprinkler irrigation systems. Spray uniformly over the. area to be treated Apply recommended amounts in sufficient water to obtain thorough coverage of treatment area (2-4 gal per 1,000 sq ft is suggested). When treating golf greens, alway& treat aprons and approache&. U&e. the. highest. recommended [ale.-under condition&.. of geye.re disease pressure. For best results, apply afler mowing or avoid mowing twelve hours afler application. Lightly water the treatment area to move the. fungicide. into active. root zone with one. to two te.nth& inch of water. Excessive irrigation may move application below active root zone and reduce application effectiveness. Green design and drainage will influence.. irrigation. practices. When. tank mixing with contact action fungicides for foliar diseases, applications should be allowed to dry on leaf surfaces. Normal watering may proceed afler sprays have.dried.

Disease(s) Rate of 3336 WP Controlled oz/I ,000 SIt It Remarks-

Anthracnose, basal 4-8 For prevention in historic areas of disease pressure, apply Colleloln"chum grcminico/a twice at 14 day (d) intervals when soil tellllX"atme reaches-

Anthracnose, foliar 2-1 60°F. For curative oontrol, apply when disease fin;! appears Colletotrichum graminico/a and oontinue at 7·14 d intervals as needed Rotations and/or

tank mix oombinations with chlorothalonil or triadimefon can be utilized

Bennudagrass Decline 4-8 Apply in mid-July or when disease S}'IllptOms first appear Gaeumannomyces graminis var. and repeat at 7-14 d intervals for suppressioll. Usc higher graminis rates under most severe disease expression. Follow proper

Take-All-Patch agronomic recommendations to maintain plant vigor. Gaeumannomycesffaminis val..

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EPA Reg, No. 1001-<;3 AMEND

avenae Cool Scasort Brown-Patch 4-8-

Rhizoctonia cerealis Na:rotil; RirrgSpor

Leptosphaeria korrea Spring Dead Spot Leptosphaeria korrea

Coprinus Snow Mold 4-8 Coprinus psychromorbidus

Dollar spot 2-4 Moellerodiscus, Lamia

Large Brown Patch Rhizoctoniasolani

Ascochyta Leaf Blight Ascochyta

Copper Spot Gloeocerc05pom serghi

Fusariuill Patch Fusarium nivale

Red Thread Corneum jucijiJrme

Zoysia Patch /?hlzoctonia sofani

Fusarium Blight 4-8 Fusarium roseum, F. triticum

Gray Leaf Spot (Blast) 4-8 Pyricufaria grisea

Leaf Spot 4-8 Dreehslera

Leaf, crown, and root diseases Bipo/aris, Curvu/aria.ExserDhi/um

Pink Snow Mold 2-4 Micm-odochi-um nivale

Rusts .t-8 Puccinia. Uromyces

Stripe Smut 4-8 l)sttla!{o stri~fon1Jis

Summer Patch 4-8 Magnaporthe poae

HORTICULTURAL APPLICATIONS

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3336WPIWSB 02I0li99 7

For prevention; apply in Fall-before-tutf has stoppedall-growth activity. Apply second application in early Spring wilen soittemperatures reach 55.{i()"F or when disease first appears. For curative action, apply when disease first appears in early Spring and continue at 7-14 d intervals.

Apply 2 treatments at 21 d intervals in late Fall to early Winter, with the last application made jrrst prior 10 first permanent snow coveL Rotations and/or tank mix combinations with DefendT" can be utilized Apply when disease first appears and continue at 7-14 d intervals. Rotations andlor tank mix combinations with chlorothalonil, iprodione, or Protect T lOT" can be utilized

Apply when disease first appears at 7-14 d inteIVals.

Apply preventative application before expected period of disease development Continue applications at 7-14 d intervals. Apply when disease first appears and make applications at 7-l4 d intervals as needed Rotations and/or tank mix_ combinations with chlorothalonil. iprodione, or Protect T 10 are. rccommendedundcr severe-conditions. Apply in late Fall to early Winter before turf has stopped all growth activity. A S€COnd application may· be used in combination \\1th chlorothalonil, DefendT", or SpotretcT" at =mmended rates before snow covet' Of during Spring thaw_ Make2 applications at i-I4 dintervaIswhen disease first appears. Rotations andlor tank mix combinations with chlorothalonil or Protect TIOTM are recommended Apply at 7-14 d intervals when disease first appears. For prevention, apply in spring and fall For prevention, aPQly 3 applications starling late April or early May using 21 d inteIVals. Rotations andlor tank mix combinations may be used as pan of the tluec application program. For suppression, apply at 7-14 d inteIVals when disease first

Nursery, Greenhouse, Landscape & Interiorscape

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EPA Reg.. Ne. -1001-63- M4END- 02lOlm 8

Annual and Perennial Flowers, Bedding Plants, Foliage Plants, Ground Covers, plus Deciduous and Evergreen Trees and Shrubs 3336 WP is a broad spectrum systemic fimgicidewbiciLControls a variel¥ of fo~ stein,- aru:l rooL diseases on a wide range of commercially important plants. 3336 WP is also effective as a pre-plant dip on cuttings and bulbs. For soil drench applications,. best crar- protection. is achieved.with preYentative. treatments repeated every 21-28 days. For foliar applications, begin treatments when disease first appears, or during suspectecL periods of ilisease. incidence Apply adrlitionaL applications ev~ 7-14 days or as otherwise instructed for the prevention or control of the listed diseases. Use of a wetting agent. is recommended fur plants that haveiealies that are. difficult to. wet properly. U~of aspreadeL­sticker is recommended to enhance product performance in wet weather conditions or during periods of overbead irrigation 3336 WP may be.use<L to contro1 IistecL diseases. on. "backyard" (IlOD.o commercial) fruit trees such as almond, apple, apricot, cherry, nectarine, peach, pecan, plum, and prune trees. Do not apply within J day (24 hr} ofbarvesL 3336 WP may be.appliedllS aground applicatioQ using hand held, mechanical or motorized spray equipment, or as a chemigation spray or through an applicable. sprinkler irrigation system;.. or as- an aerial application. where. applicable See specific instructions below. For foliar applications, do not exceed thirty six (36) pounds active ingredient per acre. per crop season from ail thiophanate,.methyl containing products. FOL soil drenclLapplications, d.u not exceed 300 pounds active ingredient per acre per crop season from all thiophanate-methyl containing produ"ts Note: The "Directions For Use" of thli product reflect the cumulative. inputs from both- historical fiel.Li use and product testing programs. However, it is impossible to test this product on all species and cultivars. A preliminary triali&slIggestedon asma1Lscale be.fore.a fulL treatment is applied to any plant type not shown on this label but found in a similar use site with a listed disease problem. Wait 5-7 days after treatment to evaluate. results. This. product is not recommendecL for use on Swedish Ivy (Nephrolepis exhalta), Boston Fern (Plee/ranthus aus/ralis), and Easter Cactus (Ha/iora gaer/llcri).

Ground Application Instructions:. Apply material.with properly calibratedhand h.eld, mechanic<ll or motorized spray equipment or by chemigation thorough appropriate sprinkler irrigation, flood, or drip systems. Beginapplications when disease first appears.aru:lrepeat at 7-14 dintervaIs or as needed during the growing season. Use the shortest interval when conditions are unusually favorable for the development of disease. For hamih.eld,mecbanical, or motorized applications, mix.&-240z of3336 WP per \00 gal water (1-3 water soluble bags) and apply as a full coverage spray to drip for the prevention and control of the diseases IistecLbelow.5pray volume. may range. up to 400 gallons of finished spray per acre depending upon plant species and plant growth stage. For applications through irrigation systems, refer to aeriaI use.rates indicated in.the. fuliar applicationcharL Special Instructions For Proportional Injectors (e.g. Dosatron, Dosmatic, Anderson, and similar Ilqnipm e'1,t) Determine the treatment rate. as. indicated below in the. ground application column for crop and.. pathogen. Determine the injection ratio for the individual system to be used for application. For systems using. a l: J 00 ratio, measure. ami adrl the. exact amount of recommended material per LOO gallons to each gallon of water in a stock bucket or tank. For systems using a 1200 ratio, multiply the reconunended amount pel' 100 gallons. by 2.. For systems using. a I: 50 ratio, divide. the. recommended amount per 100 gallons added by 2. For systems using a 1: 16 ratio, divide the recommended amount pel' 100 gallons by 6. Greater accuracy in calibration and distribution will be achie.ved by injecting a

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EPA Reg. No. lOOl-63 AMEND 3336 wrlWSB 02101199 9

larger volume of a more dilute suspension per unit time. An injection ratio of I: I 00 is recommended for most greenhouse-andnurseI}' systems Aerial Application Instructions: Apply with fixed wing or helicopter equipment to appropriate nursery sites (field-amLcootainer).. Use-atrate.indic.ated in sufficient wateLfor. thorougILoovenJge-ora­minimum of 3 gallons per acre for low growing crops and a minimum of 10 gallons per acre for larger shrubs. and trees. U~ a- spre.ader-sticker at recommended rates as. needed. to enhance producL performance. Add product slowly to water in the spray tank with agitation or premix thoroughly in separate holding taIlkfor concentrate ,ocaircraft spr8.¥er8..._ContjmJoIJS agitation 1s-uxp 1ireA tn keep the. product in suspension.

FOUARAl'PLI(:;A11ON: Use ouncelAcrexate for Aerial a~~lications.aruiounceLlOO gallon.ratefor Ground a~~lications Dise.ases 3336 WP Use Rate Controlled Ground Aerial RemarkS Anthracnose. 12-16 48-64 Apply as buds. break ocat first sign of

ozllOO ozlAcre disease. Repeat at 7-14 day (d) gallon. interv.alsasneeded during disease

Eeriod. Black Spot of Rose 12-16 48-64 Apply early summer or at first sign of Diplocarpol/ rosae ozllOO ozlAcre disease. Repeat every 7-14 d as

gallon needed dllring disease-period... Brown Rot and Blight 12-16 48-64 Apply late Spring or at first sign of MOllilillia, Sclerotillia, Whetzemllia ozl100 ozlAcre disease. Repeat every T- r <[ d as

gallon needed during disease- p:erio{L Fusicladium and Venturia Leaf Scabs on: 12-16 48-64 Apply as buds break. Repeat every 7-

Crabappfe, HaWthorn, )Year, Mountain ozllOO ozlAcre 14 d as needed during disease period: Ash, Pyracantha,-elc- gallon Effective control require& coverage-.

during leaf expansion. Rotations and/or tank mix combinations with Protect TIO, chlorothalonil or proQiconazolecanbellti1ize-d

Leaf Spots and Blights caused by: 12-16 48-64 Apply when disease symptoms first Ascochyta, Blumeriella, Botrytis, ozlrOO ozlAcre appear. Repeat every 7-14 d as needed

Cercospora, Coccomyces, Caryne.spora,. gallon. during disease perio£L Rotations Curvu/aria, Didymellilla, andlor tank mix combinations with Entomosporium.,.Fabraea, Fusarium, Protect T 10 or chlorothalonil can hi!-Ramularia, Rhizoctollia, Marssollilla, utilized. Mycosphaerefla,Myrothecium,.phom£4. Physalospora, Schizothyrium, Septoria, Sphacelo1!1.a 0vuIinia Blight 8·l6 32-64 Apply as flowers open. Repeat every

ozl10Q oz!AJ:;re. 7-14 d as needed during. disease gallon Eeriod.

Powdery Mildews 12-24 48-% AEEIy when disease-first aEpears and

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EPA Reg. No.·lOOI-63 AMEND 33J.6. WPIWSB 9liOII9'> 10

Erysiphe, Microsphaera, Phyllactillia, Podosphaera, Oidium, Sphaerotheca

ozilOO gaIron

Rust Diseases caused by: 12-16 Puccillia, Gyn1l1osporangium, Uromyces ozilOO

gallon

Tip Blight of Pine Sphaeropsis sapinea, Diplodia pinea

Twig Blights, Cankers, and Diebacks Diaporthe, Kabatilla, Phama,

Phfmwpsis.

smL DRENCH APPLICA noN Diseases Controlled

Stem, Crown, and Root Rots. callsed by: Bofrytis, Cylilldrocladillm, Fusarium, GliocJadilml, MyrothecilJJ1l,. Penicillium, Ramulw"ia, Rhizoclollia, ScJerotinia

Black Root Rot Thielaviopsis

16-24 ozilOO gallon

16-24 ozilOO gallon

oziA repeat every 7-14 d during disease period. Rotations andlor tank mix combinations. wifuProtecl TlO OL

triadimefon can be utilized. 48-64 Apply late Spring or when symptoms ozf Acre first appear. Repeat every T- 14" d as

needed. dllling disease. periruL Rotations and/or tank mix combinations-with Protect T 10-01' chlorothalonil are recommended.

64-96 Begin application in spring when new ozi A growth starts. Make a second

applicatiDnjust..hefore.needles emerge from the sheath and a third application l4-dlater. Thoroughco\lerageiS­essential for optimal disease control.

64-96 Apply when symptoms first appear. ozl Acre Repeat every 7-14 d as needed during

disease. period.

Rate of 3336 WP Remarks ozilOO gal

8-16 Apply asa drench or directed spray using hand held, mechanical, or motorized spray. equipement, or as a chemigation drench or directed spray using.applicable sprinkler irrigation systems, after seeding or sticking of cuttings (8 oz) or after transplanting (12-16 oz) to propagation beds,. containers,. pots, trays, or nursery or landscape beds at a rate to thoroughly soak the. growing. media through the root zone. A general guide.is Y. -3 pints offinished.mixture. per sq ft depending on the media type and. depth (about 4 oz per 4 inch pot OL 8. oz per 6 inch pot). Repeat every 21-28 d for adequate crop protection. Note:. 3336 WP does not control Pythium or Phytophthora. Tank. mix. combinations. with metalaxyl, mefenoxam, etridiazole, fosetyl-Al or propamocarb are required

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EPAR<g Ne. \OO\";~AMEND

PLANT J)W AI>I'LICA 'I1ON-Diseases Controlled

Plant {}I' Cutting.Diseases cal ISed by~ Botrytis, Cylindrocladium, Fusarium, Glioc/adjum ,Myrothecium,.Pen;ciWlIJ'D.,. Ramu/aria, Rhizoctonia, Sclerotinia, ThielaYiopsis

BnIb, Corm, anti RhizoIJl{7 Rots caused by: Botrytis, Cylindrocladium, Fusarium, Gliocladium, Myrothecium, PeniCillium, Ramularia, Rhizoctonia, Sc/erotinia; Thielaviopsis

LIMITED WARRANTY AND DISCLAIMER

Rate of

for the control of Pythium and Phytophthora.

3336 WP Remarks ozllOO gal

I6.-Zit

16-24

Immerse.plants.or cnttings for We 15 min. Remove and allow to drain. Note:. Follaw accepted.bygi.ene..practices to minimize the introduction and spread oj water borne. bacterial and water mold fimgal diseases. Soak cleaned bulbs for 15·3Bminin warm solution (80-85° F). For storage disease prevention, treat bulbs preferably within 48 h-after digging Met' treatment, dry well before storing. If bulbs are for forcing, treat bulbs that have-been heaHured, Note: Follow accepted hygiene practices to.minimize the i1ltroduction and spread {)f water bome bacterial and water mold fungal diseases..

CLEARY CHEMICAL CORPORATION warrants that this material conforms to the chemical description on the label and is reasonably fit. for the purposes referred. to in tbe.Directions for U5er subject to the risks referred to therein. CLEARY CHEMICAL CORPORATION makes no other expressed.or implied warranty of fit.ness or merchantability or any other expressed. or.implied. warranty. In no case shall CLEARY CHEMICAL or seller be liable for consequential, special or indirect damages resu1ting.from the use or.hand1ing of this.product including, but not limited. to, loss. of profits,.. business reputation, or customers, labor costs, or other expenses incurred in planting or harvesting. CLEARY CHEMICAL and. seller oJfer this product. and. the. buyer and user accept it. subject. to the foregoing conditions of sale and warranty which may be varied only by agreement in writing signed by a duly authorized..representative. of CLEAR-Y CHEMICALCORl'ORA TION,

Cleary Chemical Corporation 178. Rid.ge.RDad,. SuiteA

Dayton, New Jersey 08810-1501 732-329-8399- 800-524-..1662

Effective: 2/99 Replaces 11/95