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PROTECTING THE WACCAMAW WATERSHED …
Water Quality Monitoring
Christine EllisWaccamaw RIVERKEEPER®
A Program of Winyah Rivers Foundation
Waccamaw RIVERKEEPER® Program Volunteer Water Quality Monitoring Project
Waccamaw River Volunteer Monitoring Project in SC
Funding Partners:
US Environmental Protection Agency
City of Conway
Horry County
Georgetown County
International Paper
Project Administration:
Waccamaw Watershed Academy
Waccamaw RIVERKEEPER® Program
Waccamaw RIVERKEEPER® Program Volunteer Water Quality Monitoring Project
SC Objectives:
1.
Address NPDES (National Pollutant Discharge Elimination System) Phase II program measures for public education and involvement
2.
Assist in illicit discharge detection3.
Increase geographic and temporal coverage of water quality monitoring to assist in development of site specific water quality standards
Waccamaw River in SC Volunteer Water Monitoring
Volunteers:Volunteers: 35+ volunteers in 6 sampling teams35+ volunteers in 6 sampling teams
Sample twice monthly year roundSample twice monthly year round
What do we monitor for?What do we monitor for? ConductivityConductivity
Dissolved OxygenDissolved Oxygen
pHpH
Ammonia, Nitrate, NitriteAmmonia, Nitrate, Nitrite
TurbidityTurbidity
E. coliE. coli
Water Quality Testing
Dissolved Oxygen- a measure of the amount of elemental oxygen, the form required by animals & aerobic bacteria
- meter uses an oxidation-reduction reaction to detect the presence and quantity of oxygen (extremely temperature dependent)
- river water values vary from 40% (4 ppm) in the summer to 80% (8 ppm) in the winter
- DO limit for the river is 4 ppm; fish and other oxygen dependent animals experience stress below this level Hach sensION156 Portable
Dissolved Oxygen Meter, with DO probe (1-meter cables)
Water Quality Testing
pH- a measure of the acid content of the water sample
- the meter also uses an oxidation-reduction reaction to detect the presence and amount of hydrogen ion (H+) in the sample
- typical river water values range from 5 to 7
- sites with high conductivity often have a pH as high as 8.2
- fish experience stress at a pH below 5
Hach sensION156 Portable pH Meter, with Gel-filled pH Electrode (1-meter cables)
Water Quality Testing
Conductivity- a measure of the amount of dissolved solids which are primarily ions
- meter detects the amount of electricity that is conducted by the water sample (the larger the amount of ions, the greater the amount of electricity conducted and hence conductivity of the sample)
- values typically range from 40 to 140 µS⁄cm in the river
- sites greatly impacted by stormwater (runoff which contains high levels of dissolved solids) have values as high as 600)
Hach sensION5 Conductivity Meter, with electrode, 1-meter cable
Water Quality Testing
Turbidity- a measure of the particle content of the water sample
- meter detects the amount of light reflected by the particles
- typical river water values range from 5 to 10 NTUs (nephelometric turbidity units)
- values in excess of 10 NTUs indicate a soil erosion event
- high particle concentrations are stressful to fish and filter feeding microorganisms because it clogs their gills and can affect the bottom dwelling organisms as the particles settle out and blanket the river bottom
2100P Portable Turbidimeter
Water Quality Testing
Nutrients- Nitrogen compounds (nitrate, nitrite, ammonia) are products of nitrification
- the simplest way to denote nitrification is as follows: Dissolved organic matter nitrogen ==> Ammonium ==> Nitrite ==> Nitrate
- typical river water nitrate values range from 0 to 0.2 mg N per liter of sample (or ppm N)
- concentrations greater than 1 ppm N are usually the result of stormwater runoff associated with sewage or fertilizers (the degradation of sewage generates dissolved nitrogen as nitrate and fertilizers contain nitrogen as nitrate)
- high nitrate levels can stimulate algal growth and lead to eutrophication
Ammonia Test Strips
Nitrate/Nitrite Test Strips
Water Quality Testing
Bacteria (E. coli)- a measure of the levels of pathogenic microbes that are present in the water
- E. coli bacteria are present in the feces of warm-blooded animals
- EPA recommends measurement of E. coli as an indicator of pathogen presence in freshwaters
- water quality standard is 235 CFU/100 mL for single samples (waters with greater values are considered polluted, with swimmers being at increased risk of contracting gasteroenteritis)
Waccamaw RIVERKEEPER® Program Volunteer Water Quality Monitoring Project
Expansion into NC partnership:Expansion into NC partnership:
Lake Lake WaccamawWaccamaw State ParkState Park
WaccamawWaccamaw RIVERKEEPERRIVERKEEPER®®
Southeastern Community CollegeSoutheastern Community College
Town of Lake Town of Lake WaccamawWaccamaw
NC Division of Water QualityNC Division of Water Quality
Columbus County Health DepartmentColumbus County Health Department
Local community groups (Friends of Lake Local community groups (Friends of Lake WaccamawWaccamaw State Park, Friends of the Green State Park, Friends of the Green Swamp)Swamp)
University of NC University of NC –– WilmingtonWilmington
Coastal Carolina UniversityCoastal Carolina University’’s s WaccamawWaccamaw Watershed AcademyWatershed Academy
4 monitoring sites on Lake 4 monitoring sites on Lake WaccamawWaccamaw
Conductivity, Total Dissolved Conductivity, Total Dissolved Solids, pH, Dissolved Oxygen, Solids, pH, Dissolved Oxygen, Temperature, Turbidity, Nitrate, Temperature, Turbidity, Nitrate, Nitrite, Ammonia, Phosphorus, E. Nitrite, Ammonia, Phosphorus, E. coli, Fecal Coliformcoli, Fecal Coliform
14 monitoring sites on 14 monitoring sites on WaccamawWaccamaw River River (2 in NC, 12 (2 in NC, 12 in SC)in SC)
Conductivity, Total Dissolved Conductivity, Total Dissolved Solids, pH, Dissolved Oxygen, Solids, pH, Dissolved Oxygen, Temperature, Turbidity, Nitrate, Temperature, Turbidity, Nitrate, Nitrite, Ammonia, E. coliNitrite, Ammonia, E. coli
Waccamaw RIVERKEEPER® Program Volunteer Water Quality Monitoring Project
Volunteer Monitoring Volunteer Monitoring -- Equipment CostsEquipment Costs
ItemItem Cost of itemCost of itemDissolved Oxygen/ pH (Dissolved Oxygen/ pH (HachHach Meter Meter
sensIONsensION 5)5)$ 1350$ 1350
Conductivity/ Total Dissolved Conductivity/ Total Dissolved SolidsSolids-- ((HachHach Meter Meter sensIONsensION 5)5)
$625$625
TurbidityTurbidity-- ((HachHach Meter 2100 P)Meter 2100 P) $925$925Meter batteriesMeter batteries $20$20
E. Coli incubator ( 2 needed)E. Coli incubator ( 2 needed) $ 1300 ($ 650 per incubator) $ 1300 ($ 650 per incubator) BlacklightBlacklight $150$150DI bottleDI bottle $10$10
StopwatchStopwatch $20$20Sampling TableSampling Table $20$20
Cooler with ice pack/thermometerCooler with ice pack/thermometer $50$50Informational BinderInformational Binder $100$100
Sample pole/Sample bottleSample pole/Sample bottle $60$60
TotalTotal $4630$4630
Volunteer Volunteer Monitoring -- ConsumablesConsumablesItem Item Cost of itemCost of itemNitrate/ Nitrite test stripsNitrate/ Nitrite test strips $2 per strip x 24 = $48$2 per strip x 24 = $48
Ammonia test stripsAmmonia test strips $2 per strip x 24 = $48$2 per strip x 24 = $48E. Coli bacteria supplies (sterile E. Coli bacteria supplies (sterile bottle, dropper, bottle, dropper, ColiScanColiScan Easy Gel)Easy Gel)
$2 per sample x 24 = $48$2 per sample x 24 = $48
Volunteer Monitoring - Analytical Costs
ItemItem Cost of ItemCost of Item
PhosphorousPhosphorous $11.20 per sample x 84 samples = $11.20 per sample x 84 samples = $941$941
Fecal ColiformFecal Coliform $11.90 per sample x 84 samples = $11.90 per sample x 84 samples = $1000$1000
Volunteer Monitoring Volunteer Monitoring -- Project CostsProject Costs
Equipment Equipment CostsCosts
Cost of Cost of ConsumablesConsumables
Analytical Analytical CostsCosts
Data QA/QCData QA/QC TotalsTotals
$3200/kit X 3 $3200/kit X 3 kits= $9,600kits= $9,600$650/incubator X $650/incubator X 2 incubators = 2 incubators = $1,300/blacklight $1,300/blacklight X 1 = $150X 1 = $150
Lake: $6 x 7 x 12= Lake: $6 x 7 x 12= $504$504River: $6 x 4 x12= River: $6 x 4 x12= $288$288
Lake: ($11.20 + Lake: ($11.20 + $11.90) x 7 x $11.90) x 7 x 12= 12= $1941$1941River= noneRiver= none
($25 per hr) x (15 ($25 per hr) x (15 hrs per month) x hrs per month) x 12 = $450012 = $4500
$ 11,050$ 11,050 $ 812$ 812 $ 1,941$ 1,941 $ 4,500$ 4,500 $ 18,303$ 18,303