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    Wrtsil

    INTERNAL USE ONLY

    Liquid Bio Fuels

    Vesa Riihimki, Vice President

    Presented by Kristoffer SandelinPower Plant Technology

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    1970 1980 1990 2000 2010

    Diesel Oil (LFO)

    Heavy Fuel Oil (HFO)

    Natural Gas (NG)

    Crude Oil (CRO)

    Liquid Biofuels (LBF)

    Emulsified Fuels

    High Viscosity HFO

    Wrtsil Fuel Versatility

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    The LBF Portfolio

    Plant ranges & Engine portfolio

    300200100

    Plant size

    501051

    W20

    W32

    W50DF

    W32DF

    = Biodiesel approved as pilot and back-up fuelBio oils not approved and to be checked case by case

    6, (8, 9L) (12, 16) 18V

    6, 9L, 12, 16, 18, (20V)

    (6L,12V) 18V

    6, 9L

    W46 6, 9L, 12, 16, 18

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    The Variety of Liquid Bio Fuels

    Liquid Bio Fuels

    A great varation of bio fuels canbe found

    Approved by Wrtsil are: Vegetable based bio fuels:

    Palm oil, Palm stearin, Rapeseed oil, etc.

    Transesterified bio oils(biodiesel)

    Animal based not approved DME (Di-Methyl Ether) not

    approved Methanol & Ethanol not approved Bio oil alcohol mixes not

    approved

    Lower Heating value => Outputreduction

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    Sources of Liquid Bio Fuels

    Sources of vegetable oils (2003) Palm oil (28.3M tons/year)

    Malaysia (47%) Indonesia (37%)

    Soy Bean (31M tons) USA Sourth Europe

    Rapeseed (12.3M tons) North Europe

    Sunflower (8.6M tons) South Europe

    Total Oils&Fat production

    2003: 123.5 million tonnes Animal fats 23M tons

    28.3 Mtons is enough for 14000MW continous

    power generation

    Source:Oil World, Hamburg

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    Prices of Liquid Bio Fuels

    Price development Palm oil price development

    has been positive over longterm trend With HFO at 250 300 $/ton

    and Palm oil at 400$/ton, thepower generation market

    requires subsidies to becomecommercially attractive CO2 trading and incentives in

    Italy, Holland and Germanyhave created local markets

    for LBF power plants 0

    200

    400

    600

    800

    1000

    1200

    1400

    1994

    1996

    1998

    2000

    2002

    2004

    $

    /ton

    SOYBEAN OIL ,U.S.

    SOYBEAN OIL ,ROTT

    PALM OIL ,MALAYSIA

    RAPESEED OIL ,ROTT

    PEANUT OIL ,U.S.

    PEANUT OIL ,ROTT

    COCONUT OIL ,ROTT

    CORN OIL ,U.S.

    Source: United States Department of Agriculture

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    Characteristics of vegetable oils

    Varying characteristics Ash content

    Clear oil & dark oils havedifferent level of ash

    Influence on particulateemissions

    Viscosity is highlytemperature dependant

    Too cold -> wax Too hot -> polymerization

    Phosphorus content Lifetime of DeNOx &

    OxiCat

    Acid number Influence on fuel oil system

    wear & tear

    Palm Oil 22C Palm Oil 60C

    Palm Stearin 22C Palm Stearin 60C

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    Emissions and Liquid Bio Fuels

    Refined Palm Olive

    Emission Unit LFO HFO Palm Oil Stearin Olein

    NOx ppm, dry 15 % O2 860 970 1050 960 930

    CO ppm, dry 15 % O2 40 40 30 40 40

    THC (as CH 4) ppm, dry 15 % O2 170 80 30 20 15

    SO2 ppm, dry 15 % O2 118 463 < 2 < 2 < 2

    CO2 vol % 5.3 5.46 0.0 0.0 0.0

    Particulates mg/Nm

    3

    , dry 15% O2

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    Wrtsil LBF experience

    Val Senales

    PentesileaMonopoli

    Unigra

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    MW in operation

    MW development The introduction of incentives

    in Italy has created a fastgrowing installed base of LBFplants

    Projected estimates suggestthat up to 500MW of LBF

    plants could be in operationby end of this decade

    0

    20

    40

    60

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    200

    Jan-03

    May-03

    Sep-03

    Jan-04

    May-04

    Sep-04

    Jan-05

    May-05

    Sep-05

    Jan-06

    May-06

    Sep-06

    Jan-07

    May-07

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    LBF business models

    Four models Crudel Vegetable Oils

    The primary model for using

    LBF. Bio diesel

    Today very expensive, notreally feasible for powergeneration

    Waste oils from food industry

    Karlburg plant model, but waslater changed to by products.Problem: Emissions

    Waste or fuel? Which EUdirectives are to be used?

    By-products

    Main customers are companiesoperating in Bio-oil refinerybusiness

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    HFO to BIO Future proof concept?