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Water

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Water. Earth the Water Planet. Earth the Water Planet. Special Properties of Water. Universal Solvent Transparency Three Physical Phases Density and Temperature High Specific Heat High Heat of Vaporization Low Compressibility “Stickiness” of Water Molecules Viscosity. - PowerPoint PPT Presentation

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Page 1: Water

Water

Page 2: Water

Earth the Water Planet

Page 3: Water

Earth the Water Planet

Page 4: Water

Special Properties of Water Universal Solvent Transparency Three Physical Phases Density and Temperature High Specific Heat High Heat of Vaporization Low Compressibility “Stickiness” of Water Molecules Viscosity

Page 5: Water

Polarity of Water Molecules

Page 6: Water

Hydrogen Bonding Between Water Molecules

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Page 8: Water
Page 9: Water

Hydrogen Bonding Between Different Molecules

Page 10: Water

Universal Solvent

Page 11: Water

Solution = A liquid in which two or more substances are homogeneously mixed.

Solvent = Fluid portion of a solution into which other substances are dissolved.

Solute = A substance that is dissolved into a solvent to produce a solution.

Universal Solvent

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NaCl (sodium chloride)Dissolving Into Water

Universal Solvent

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Universal SolventNaCl Dissolving Into Water

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Universal SolventNaCl Dissolving Into Water

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Protein Dissolving Into Water

Universal Solvent

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Solubility of Solids In general, the solubility of solids increases

with increases in temperature.

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Solubility of Gases In general, the solubility of gases decrease

with increases in temperature.

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Importance to Living Things

Water is the solvent in which most of the chemistry of life takes place.

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Transparency

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Electromagnetic Radiation

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Electromagnetic Radiation

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Light Intensity and Depth in the Ocean

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Spectral Characteristics of Light with Depth

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Aquatic plants are able to live and photosynthesize beneath the surface of the water.

Animals are able to see below the surface of the water.

Changing spectral distribution of light with depth influences physiology and behavior of living things.

Importance to Living Things

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Three Phases of Water

liquid gas

solid

Page 26: Water

Three Phases of Water

liquid gassolid

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Ice vs Liquid Water

liquidicehydrogen bonds

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Melting and Boiling Temperatures of Water

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Colligative Properties Dissolved solids increase the boiling point

and decrease the freezing point.

Page 30: Water

Water exists in all three phases at temperatures found on Earth.

If water behaved like substances with similar molecular weight, water would exist only as a gas and it’s likely that the Earth’s gravity wouldn’t retain water.

Importance to Living Things

Page 31: Water

Density and Temperature Above 4°C the density of liquid water

decreases as the temperature increases.

As the temperature is decreased from 4°C to 0°C, the density decreases.

Water exhibits a density maximum of 1.0 grams/milliliter (g/mL) at 4°C.

Ice is less dense than water.

Page 32: Water

Density Behavior of Water

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Specific Gravity

Page 34: Water

Ice floats on top of liquid water. If ice were more dense than liquid

water, then ice would sink, leading to a freezing-over of many lakes and streams.

Importance to Living Things

Page 35: Water

Ice Floats!

Page 36: Water

High Specific Heat

1.0 calories of absorbed heat energy will raise the temperature of 1.0 gram of water by 1.0°C.

Page 37: Water

Water can buffer the environment and living things against extreme changes in temperature.

Importance to Living Things

Page 38: Water

High Heat of Vaporization At 25°C, 1.0 gram of water must

absorb 580 calories of heat energy in order to be converted from a liquid to a gas.

Page 39: Water

Water vapor in the atmosphere moderates the Earth’s climate.

Living things may moderate their body temperatures via evaporation of water from their surfaces (evaporative cooling).

Importance to Living Things

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Low Compressibility

Liquid water does not compress significantly into a smaller volume.

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Water can provide shape and form to a living thing (hydrostatic skeleton). For some organisms a hydrostatic skeleton may facilitate movement.

Aquatic organisms may swim.

Importance to Living Things

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Low Compressibility

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“Stickiness” of Water Molecules

Cohesion

Adhesion

Surface Tension

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Cohesion The binding together of like

molecules; the binding together of water molecules to each other via hydrogen bonds.

Page 45: Water

Adhesion The binding together of different

molecules; the binding of water molecules to other substances via hydrogen bonds.

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Cohesion + Adhesion

Capillarity

Page 47: Water

Cohesion and Adhesion in Water Transport in a Plant

Importance to Living Things

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Surface Tension

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Importance to Living Things

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Resistance of a Fluid to Flow

Viscosity

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Colloids and Suspensions

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The viscosity of water may be a significant force resisting movement in very tiny aquatic organisms.

The viscosity of water retards the rate at which small suspended particles may settle through it.

The viscosity of water may influence transport of fluids throughout an organism.

Importance to Living Things

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Decomposition of WaterH2O H+ + OH-

1 in 107 water molecules will decompose this way in a container of pure water ( [H+] = 10-7 M).

Note that the concentration of H+ is equal to the concentration of OH-)

Page 54: Water

Definition of pH

pH = -log[H+]

pH of pure water = -log[10-7] = 7

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Acids

HCl H+ + Cl-

Add excess H+ to the solution such that [H+] > [OH-].

Page 56: Water

Bases

NaOH Na+ + OH-

Remove H+ from the solution such that [H+] < [OH-].

Page 57: Water

pH Scale

Neutral 7Acidic <7Basic (alkaline) >7

Type of Solution pH Value

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pH Scale

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Buffers

Chemicals that minimize changes in the pH of a solution.

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Enzymes (enzymes regulate chemical pathways in cells and tissues) and other proteins of living things are pH-sensitive.

The pH of physiological solutions may influence chemical equilibria.

Importance to Living Things