welcome to alternative buffer material · performed buffer analysis uptake and planned analysis...

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T C LAY ECHNOLOGY AB ABM PM December 04, 2008 Page 1 Welcome to Alternative Buffer Material Project meeting 2008-12-04, Lund

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Page 1: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 1

Welcome toAlternative Buffer Material

Project meeting2008-12-04, Lund

Page 2: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 2Agenda08:30 General project information

Torbjörn Sandén Introduction to Analysis and SKB part Daniel Svensson AECL Microbe Study Daniel Svensson

10:00 Coffee 10:15 Presentations on ABM analyses

Posiva

Arto Muurinen Posiva/BTech Sirpa Kompulainen

BGR Reiner Dohrman and Stephan Kaufhold SKB Microbe study Karsten Pedersen

Page 3: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 3Agenda12:00 Lunch 13:00 Reserved time for any other Posiva Petri Korkeakoski 13:30 Discussion Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite project: Concrete and Clay Patrik Sellin 15:45 Reserved time for recent iron-bentonite research related to the planning of ABM analysis

and/or excavation. Nicolas Michau and Urs Mäder Characterisation of 8 year old Fe-bentonite specimens Sirpa Kompulainen Posiva Fe-bentonite research plan Paul Wersin 17:30 End of meeting

Page 4: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 4

Torbjörn Sandén, Clay Technology AB

Introduction to the ABM project

Page 5: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 5

•Objectives with the tests•Experiment design•Results from measurements in field•Termination of package 1

This presentation

Page 6: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 6Objectives

Detect and describe differences between different clay materials regarding:

•Manufacturing and handling of blocks•Mineral stability•Physical properties

Page 7: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 7Experiment design

1 2 34 m4 m

Short-time (1-2 years).Heated from start.Artificial saturation from start.

Medium-time (2-4 years).Heating started when buffer was saturated.Artificial saturation from start.

Long-term (≥ 5 years).Heated from start.No artificial saturation.

Experiment design based on LOT with some modifications:

• Different materials are tested • Less instrumentation• Shorter deposit holes (3m)• Complete package length heated• Central tube made of steel• No inserts or tracers

4 x T

4 x T

4 x T

4 x T

4 x T

MX-80

MX-80

Ibeco SealDeponit

Ikosorb

Friedland

Asha 505Calcigel

Callovo-OxfordianFebex

MX-80 granulate

MX-80 granulate+quarz

Kunigel V1

Rokle

DeponitAsha 505

Rokle

Callovo-Oxfordian

MX-80

MX-80

IkosorbFriedland

Febex

Ibeco Seal

Calcigel

Kunigel V1

MX-80 granulate+quarz

MX-80 granulate

MX-80MX-80

Page 8: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 8ABM. Test layout, Package 1

Installed materials:MX-80 6MX-80 granulate 2MX-80 gr.+ quarz 2Ikosorb 2Deponit CA-N 2Ibeco SEAL M-90 2Friedland 2Asha 505 2Calcigel 2Callovo Oxfordian 2Febex 2Kunigel V1 2Rokle 2

Total 30 blocks

MX-80MX-80

MX-80 granulate

MX-80 granulate+quarz

Kunigel V1

Calcigel

Ibeco Seal

Febex

FriedlandIkosorb

MX-80

MX-80

Callovo-Oxfordian

Rokle

Asha 505Deponit

Rokle

Kunigel V1

MX-80 granulate+quarz

MX-80 granulate

FebexCallovo-Oxfordian

CalcigelAsha 505

Friedland

Ikosorb

DeponitIbeco Seal

MX-80

MX-80

3000

300

Top

heat

er (5

00 W

)B

otto

m h

eate

r (50

0 W

)

Mai

n he

ater

(100

0 W

)

4 x T

4 x T

4 x T

4 x T

4 x T

Thermocouples at 5 levels:Inside tube and 5, 40 and 60 mm from tube(2 temperature indicators between each block)

Sand layer between blocks and rock

Central tube (steel)

Heaters (central, top and bottom)

Bentonite pellets

Page 9: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 9Package 1, Temperature developement

4 x T

4 x T

4 x T

4 x T

4 x T

MX-80

MX-80

Ibeco SealDeponit

Ikosorb

Friedland

Asha 505Calcigel

Callovo-OxfordianFebex

MX-80 granulate

MX-80 granulate+quarz

Kunigel V1

Rokle

DeponitAsha 505

Rokle

Callovo-Oxfordian

MX-80

MX-80

IkosorbFriedland

Febex

Ibeco Seal

Calcigel

Kunigel V1

MX-80 granulate+quarz

MX-80 granulate

MX-80MX-80

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

Package 1:

•Artificial saturation from start

•Heated from start

Page 10: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 10Package 1, Temperature distribution

4 x T

4 x T

4 x T

4 x T

4 x T

MX-80

MX-80

Ibeco SealDeponit

Ikosorb

Friedland

Asha 505Calcigel

Callovo-OxfordianFebex

MX-80 granulate

MX-80 granulate+quarz

Kunigel V1

Rokle

DeponitAsha 505

Rokle

Callovo-Oxfordian

MX-80

MX-80

IkosorbFriedland

Febex

Ibeco Seal

Calcigel

Kunigel V1

MX-80 granulate+quarz

MX-80 granulate

MX-80MX-80

Page 11: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 11Artificial water saturation.

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

0 100 200 300 400 500 600 700 800Time, days

Pre

ssu

re,

ba

0

100

200

300

400

500

600

700

800

900

Inje

vte

d w

ate

r vo

lum

Water pressureInjected water

No artificial water injection.

•One system is supplying both package 1 and 2 with water•Total amount of water injected is higher than the volume needed for saturation (less than 100 l)•By closing the water supply to package 2 for some days it was detected that leakages are in package 1.• The water pressure applied is not high enough in order to avoid boiling (1.8 bar is enough to avoid boiling at 117°C while 2.7 bar is needed for 130°).

Page 12: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 12Artificial water saturation.

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

0 100 200 300 400 500 600 700 800Time, days

Pre

ssu

re,

ba

0

100

200

300

400

500

600

700

800

900

Inje

vte

d w

ate

r vo

lum

Water pressureInjected water

No artificial water injection.

Depending on the boiling, parts of the bentonite are affected by other processes (vapour transport and condensation)

Page 13: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 13Package 2, Humidity

Package 2:

•Artificial saturation from start

•Heating starts after saturation

1 x RH

1 x RH

1 x RH

1 x RH

Package 2, Relative Humidity (scatter in measurements removed)

80

85

90

95

100

105

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Re

lativ

e H

umid

ity

RH block 3RH block 9RH block 22RH block 28

Page 14: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 14Package 2, Temperature developement

4 x T

4 x T

4 x T

4 x T

4 x T

Heaters were started19 August 2008

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

Page 15: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 15Package 2, Cracking

4 x T

4 x T

4 x T

4 x T

4 x T

The concrete block at the top has crackedand will be reinforced before increasing the temperature.

Page 16: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 16Package 3, Temperature developement

4 x T

4 x T

4 x T

4 x T

4 x T

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

Package 3:

•No artificial saturation

•Heated from start

Page 17: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 17Package 3, Temperature distribution

4 x T

4 x T

4 x T

4 x T

4 x T

Page 18: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 18Termination of Package 1?

• The target temperature, 130°C, was reached the 4th of december 2007.

• The temperature wasdecreased to 100°C for about 120 days dependingon high water inflow and a decrease of the water pressure.

• The termination will be made with the same technique as used in the LOT project with someexceptions.

0

20

40

60

80

100

120

140

0 100 200 300 400 500 600 700 800

Time, days (Day 0-4 dec 2006)

Te

mp

era

ture

,

5 mm from pipe40 mm from pipe60 mm from pipe

Page 19: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 19Termination of Package 1

• Heater decreaseduring 1 month.

• 2 x core drilled holes(d=300 mm)

• Overlapping drilling around the hole(percussion drilling, d=125 mm)

• Wire sawing in order to release the package in the bottom

Page 20: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 20Termination of Package 1

• In order to stabilize the rock column during lifting, beamsare positioned around it and straps are used to keepeverything in place

• The lifting is made by use of steel wires placed in threedirections around the package

• Due to the sand filter in ABM, it is important to secure the steel tube and the bentonite relative the rock parcel. A scenario could otherwise be that the bottom of the rock column falls of and the bentonite and tube with it.

Page 21: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 21Transport to a dry niche

Page 22: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 22Releasing the bentonite from the rock

Page 23: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 23Laboratory tests1

35

79

A

B

C

NW

SE

Scope of laboratory tests after termination is not decided.

• Water ratio distribution• Density distribution• Swelling pressure• Hydraulic conductivity• Rheological properties • Mineralogy (ICP/AES, CEC, XRD etc.)

• Pore water chemistry• Iron –bentonite

4 x T

4 x T

4 x T

4 x T

4 x T

MX-80

MX-80

Ibeco SealDeponit

Ikosorb

Friedland

Asha 505

Calcigel

Callovo-Oxfordian

Febex

MX-80 granulate

MX-80 granulate+quarz

Kunigel V1

Rokle

DeponitAsha 505

Rokle

Callovo-Oxfordian

MX-80

MX-80

IkosorbFriedland

Febex

Ibeco Seal

Calcigel

Kunigel V1

MX-80 granulate+quarz

MX-80 granulate

MX-80MX-80

Page 24: Welcome to Alternative Buffer Material · Performed buffer analysis Uptake and planned analysis Next meeting 15:00 End of meeting, ABM - Coffee 15:15 Presentation of new cement-bentonite

TC LAYECHNOLOGY AB

ABM PM December 04, 2008

Page 24Compilation of test status

• Package 1. When are we going to terminate the test? Scope of laboratory investigations?

• Package 2. After reinforcement of the concrete at the top, the temperature will be increased.

• Package 3. Have been running at target temperature for one year.