w.w.g.c.s.a. pesticide seminar – 2009 the process of calibration & understanding and reading...

W.W.G.C.S.A. Pesticide Seminar – W.W.G.C.S.A. Pesticide Seminar – 20092009 The Process of Calibration & The Process of Calibration &

Understanding and Reading Pesticide Understanding and Reading Pesticide LabelsLabels

AndBill Griffith

W.W.G.C.S.A. Pesticide Seminar – W.W.G.C.S.A. Pesticide Seminar – 20092009

Presented by:Bill Griffith

& Walla Walla Community College

Understanding and Reading Pesticide Understanding and Reading Pesticide Labels & MSDSLabels & MSDS


Pesticide Labels I. Background A. Time and Effort

1. Years of research 2. 6 years minimum

B. Cost 1. Millions of dollars

C. Testing 1. Toxicological 2. Performance 3. Degradation, mobility, and residue 4. Effects on wildlife and environment

D. EPA label review 1. Use registration

Understanding and Reading Pesticide Understanding and Reading Pesticide Labels and MSDSLabels and MSDS


Pesticide Labels II. Parts of the label

A. Trade, Brand, or Product names1. Usually trademark protected

2. Must be plainly visible on the front of the panel 3. Can include the formulation

B. Ingredient Statement 1. Active ingredient by name and percentage 2. Inert ingredient(s) by percentage 3. Common and chemical name(s)

C. Use Classification Statement 1. Restricted use - statement 2. State may restrict the use of an unrestricted pesticide




D. Type of Pesticide1. Short statement in general terms of control

E. Formulation Statement 1. If not listed separately, would be in directions for use

F. Net Contents G. Name and address of the manufacturer H. Registration Numbers

1. Can include special designations, such as special useG. Establishment Numbers

1. Identifies the facility where the product was produced




H. Signal Words1. Danger/Poison, Warning, Caution, and Keep out of …..

I. Precautionary Statements 1. Routes of entry - specific action statements 2. Protective clothing's and equipment statements 3. Other precautionary statements

J. Statement of Practical Treatment 1. First aid treatment - note to M.D. - possible antidote

K. Physical or Chemical Hazards




L. Reentry Statement1. How much time must pass before workers can enter

2. Minimum reentry for others 3. Worker safety precautions

M. Storage and Disposal 1. General directions, specific directions may be included elsewhere

N. Endangered Species Directions




O. Directions for Use1. Controlled pests

2. Plant, crop, animal, or site the product is intended to protect 3. Proper equipment 4. Rate of application and frequency5. Compatibility6. Phytotoxicity (injury to plants)7. Where and when pesticide should be applied8. Chemigation



Pesticide Labels III. Important Things to Look For

1. Dosage Range – Maximum Dosage per Year

2. Site Restrictions

3. Safety Precautions

4. First Aid – Protective Clothing's

5. Adjuvants

6. Weather, Temp or Other7. Formulation Considerations8. Disposal



MSDS


1. PRODUCT IDENTIFICATION

Product Name: HERITAGE FUNGICIDE Product No.: A12704A

EPA Signal Word: Caution

Chemical Name: Methyl (E)-2-{2-[6-(2-cyanophenoxy)pyrimidin-4-yloxy]phenyl}-3-methoxyacrylateChemical Class: A beta-methyoxyacrylate fungicideActive Ingredient(%): Azoxystrobin Technical (50.0%)

EPA Registration Number(s): 100-1093 (formerly 10182-408)


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2. COMPOSITION/INFORMATION ON INGREDIENTS

3. HAZARDS IDENTIFICATION

Symptoms of Acute Exposure Causes moderate eye irritation. Dust may be irritating to nose and throat.Hazardous Decomposition ProductsCan decompose at high temperatures forming toxic gases.Physical Properties - Appearance: Beige to brown granulesOdor: No characteristic odorUnusual Fire, Explosion and Reactivity HazardsThis product is a combustible powder and like all combustible powders can ignite, burn and form explosive mixtures with air if not handled correctly. Mixtures of powder in air with flammable solvent vapors should be avoided. This product has a minimum ignition energy between 3 and 10 millijoules. Static electricity, mechanical sparks, open flames and certain hot surfaces (greater than 707°F [375°C]) can serve as ignition sources for this material.During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.


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4. FIRST AID MEASURES Product Name: HERITAGE FUNGICIDE

Have the product container, label or Material Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment.If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person.If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice.Notes to PhysicianMedical Condition Likely to be Aggravated by ExposureAsthma or other respiratory conditions aggravated by chemical irritants.


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5. FIRE FIGHTING MEASURES

Unusual Fire, Explosion and Reactivity HazardsThis product is a combustible powder and like all combustible powders can ignite, burn and form explosive mixtures with air if not handled correctly. Mixtures of powder in air with flammable solvent vapors should be avoided. This product has a minimum ignition energy between 3 and 10 millijoules. Static electricity, mechanical sparks, open flames and certain hot surfaces (greater than 707°F [375°C]) can serve as ignition sources for this material.During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.In Case of FireUse dry chemical, foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause environmental damage. If water is used to fight fire, dike and collect runoff.


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6. ACCIDENTAL RELEASE MEASURES

In Case of Spill or LeakControl the spill at its source. Contain the spill to prevent it from spreading, contaminating soil, or entering sewage anddrainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. If asolid, sweep up material and place in a compatible disposal container. If a liquid, cover entire spill with absorbingmaterial and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial productssuch as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposalcontainer. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition.


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7. HANDLING AND STORAGE

Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.

Handle this material only in electrically conductive equipment. Electrically ground and bond this equipment as well as any worker who could contact a dust cloud formed of this material. Eliminate the presence of mechanical sparks and other ignition sources where dust clouds of this material could form. Bulk bags (FIBC) used to contain this material should be either type B or type C. If type C bags are used make sure they are electrically grounded before powder is discharged from the bag.


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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL.


MSDS


Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.

Where eye contact is likely, use chemical splash goggles. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

Where contact is likely, wear chemical-resistant (such as nitrile or butyl) gloves, coveralls, socks andchemical-resistant footwear. For overhead exposure, wear chemical-resistant headgear.

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below exposure limits. A NIOSH-certified combination air-purifying respirator with an N, P or R 95 or HE class filter and an organic vapor cartridge may be permissible under certain circumstances where airborneconcentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a pressure demand atmosphere-supplying respirator if there is any potential for uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators

Ingestion

Eye Contact

Skin Contact

Inhalation


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9. PHYSICAL AND CHEMICAL PROPERTIES

Melting Point:Boiling Point:Specific Gravity/Density:237.2 - 240.8°FNot Available31.2 - 43.7 lbs./cu.ft.Appearance:Odor:pH: 5 - 8


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http://www.msdshazcom.com/


Bill [email protected]

Questions and Comments



byBill Griffith


w.w.g.c.s.a. pesticide seminar – 2009 the process of calibration & understanding and reading...

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